Petrokemija d.d., Kutina Hrvatska - unece.· Petrokemija d.d. Kutina, Hrvatska Legal and ownership

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  • Petrokemija d.d., Kutina

    Hrvatska

  • Authors:Marijan Lonarevi, M.Sc.

    Darko Vinicki, B.Sc.

    Grozdana Avirovi, B.SC.Chem.E. - Head EMS

    Stjepan Leakovi, Ph.D.(Chem.E.) - Board representative for QMS & EMS

    Contact :

    e-mail: marijan.loncarevic@petrokemija.hr

  • Petrokemija d.d.

    Legal basis

    Activity plan

    List of chemicals and installations

    Safety Report

    MAPP, SMS

    Identification of installation

    Example-ammonia release

    Petrokemija d.d.

    Zakonske osnove

    Plan aktivnosti

    Popis kemikalija i postrojenja

    Izvjee o sigurnosti

    MAPP, SMS

    Identifikacija postrojenja

    Primjerproboj amonijaka

    3Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Petrokemija d.d. Kutina, Hrvatska Legal and ownership framework

    From 1968 to 1996 Petrokemija in various organization types within INA Zagreb;

    1991 Petrokemija d.d. founded, 100% owned by INA Oil Industry, Zagreb;

    1998 voucher privatization;

    Since 2003 listed on the Zagreb Stock Exchange;

    Ownership structure:

    50,6% Croatian Privatization Fund and Government of Croatia,

    49,4% investment funds and private investors.

    4Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Petrokemija in figures: Petrokemija Kutina Croatian and regional brand: 900 million kn in capital; 2 billion kn in total revenues; Capacity:

    1,350,000 t / y mineral fertilizers, 32,000 t / y carbon black, 50,000 t / y bentonite-based products;

    2370 employees. One of largest Croatian industrial producers; At the very top in chemical and pharmaceutical industry, immediately

    following Pliva; 3rd largest Croatian exporter; 20th largest employer; Ranks 18th on the domestic companies' total revenues list.

    5Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Sales of Products wide product range of high-quality products:

    Complex NPK fertilizer (with nutrients and micro-nutrients),

    Nitrogen fertilizers (prilled and granular CAN, AN and prilled UREA),

    Liquid fertilizers, Various carbon black grades, Products for the foundry industry, Animal feed supplements, and Other bentonite-based products.

    own pallet production; maintenance activities;

    6Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Elementarni sumpor

    Postrojenje: KAN

    Postrojenje Urea

    Postrojenje:Amonijak

    CO2

    Postrojenje: Duina kiselina

    Prirodni plin, zrak, vodena para

    Postrojenje: Sumporna kiselina

    Sirovi fosfat

    Postrojenje: Fosforna kiselina

    Postrojenje: NPK

    Dolomit

    KCl

    MAP

    7Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

    postrojenje sirovine

  • Our Product - Synonym for Quality The name Petrokemija is a synonym for high

    quality producer;

    We use best market available raw materials in our production processes;

    ISO 9001:2008 Quality Management System is used in all our production and business processes;

    The best quality "controller" is the market;

    Our products are sold to: domestic market (40%),

    world markets (60%).

    8Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • We take care of environmental protection and pollution, confirmed by Environmental Management System, in line with the ISO 14001:2004 standard;

    We have a long term strategy of investments into environmental protection;

    Environmental protection is carried out through application activities and soil analysis we give advice on type of fertilization, taking into account optimum yields and soil preservation.

    9Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • EC Directive 96/82 (Seveso II) on the control of major-accident hazards involving dangerous substances

    Implementation of Directive 2003/105/EC amending Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances

    Law on ratiffication of Convention on the transboundary effects of industrial accidents , MU 7/99

    Law on Environmental Protection, NN 110/07

    Law on chemicals, NN 150/05, 53/08

    National chemical safety strategy 2008/11/28

    Regulation on the control of major-accident hazards involving dangerous substances, NN 114/08

    10Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Defining dangerous substances from Annex I

    and II, EC Directive) What dangerous substances

    do we have on our plant site?

    What quantities?

    Obligations according to criteria from Annex I and II

    Notification

    Drafting Safety Report

    11Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Processing demands from Annex I and II

    Dangerous substances inventory creation with quantities and location in facilities, in cooperation with Environmental Protection Department and Head of facilities.

    Creation of Notification for dangerous substances in terms of Annex I, Part 1 table.

    List of dangerous substances for creation of Safety Report

    12Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • 13Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • 14

    Redbr.

    Kemijski naziv

    CAS broj Naziv poIUPAC

    Najvea koliina

    Lokacija

    1 Amonijak 7664-41-7 Amonijak 17.000 tona Skladite Amonijaka

    2. Duina kiselina 50-60%

    7697-37-2 Duina kiselina

    1.200 t

    1.200 t

    DUKI-1

    DUKI-2

    3. Amonijev nitrat 6484-52-2 Amonijev nitrat

    XXXX Skladite amonijevog nitrata

    5. Srednje lo ulje LUS II

    68553-00-4 Loivo ulje, No. 6

    19.000 t Energana

    6. SO2 od izgaranja elementarnog sumpora

    7446-09-5 Sumporov (IV) oksid

    50.000 t Skladite sumpora

    Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • 7. Dekantirano ulje + LUS II

    64741-62-468553-00-4

    Dekantirano uljeLoivo ulje, No.6

    1.600 t Proizvodnja ae

    8. Antracensko ulje

    90640-86-1 Antracensko ulje

    2.000 t Proizvodnja ae

    9. Pirolizno ulje

    68513-69-9 Pirolizno ulje

    3.000 t Proizvodnja ae

    10. Procesna mjeavina ulja pod 7,8,9

    64741-62-468553-00-490640-86-168513-69-9

    Procesna mjeavina

    1.600 t Proizvodnja ae

    15Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Delivering information to the State Ministry in accordance with demands of Annex I and II

    On formal template in Annex II: ( description of the site

    and location of the facilities, measures for disenabling and mitigation of sudden event, data for hazard substances on facilities)

    16Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Adopted formally

    OBJECTIVE: Our objective is to work without injuries, professional illness, harmful effects of work on employees health, as well as protection of properties by implementation of rules and regulation of Safety, Fire protection, Security and other mentioned principles in accident-freeenvironment.

    18Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Company has to be a safe workplace for all employees, contractors and visitors.

    Responsibility for Safety is not transferable. Each employee of Petrokemija is fully responsible for personal safety and for the safety of his surroundings.

    Petrokemija shall not make any business decision that lowers orjeopardize the concern about safety of work and environment.

    Written procedures for conducting extraordinarory events shall be continuouosely practised, analised and constantly improved.

    19Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Addresses all 7 aspects as in Annex III

    organization and

    personnel

    identification and

    evaluation of major

    hazards

    operational control

    management of change

    emergency planning and

    response

    monitoring

    audit and review

    20Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Facility location description

    Middle region of Croatia

    By the south side of Moslavina mountain

    Near the Nature park

    Plant site decription and it`s environment

    On approx. 130 ha

    Geographyc location

    Approx. 1.2 km SE from the City

    21Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Meteorological, geological and hydrographic conditions Wind rose

    Geologicall data

    70% subsurface area till 30 m depth consists of medium plastic clay

    22Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • Tanks for:

    Ammonia

    Sulphuric acid

    Nitric acid

    Power plant- fuel oil

    Oil feedstok on Carbon Black Plant

    Storages:

    Sulphur

    Ammonium nitrate

    23Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

  • (II C) Description of areas

    with possible Domino effect in case of major-acciden