Petrokemija d.d., Kutina

Hrvatska

Authors:Marijan Lonarevi, M.Sc.

Darko Vinicki, B.Sc.

Grozdana Avirovi, B.SC.Chem.E. - Head EMS

Stjepan Leakovi, Ph.D.(Chem.E.) - Board representative for QMS & EMS

Contact :

e-mail: marijan.loncarevic@petrokemija.hr

Petrokemija d.d.

Legal basis

Activity plan

List of chemicals and installations

Safety Report

MAPP, SMS

Identification of installation

Example-ammonia release

Petrokemija d.d.

Zakonske osnove

Plan aktivnosti

Popis kemikalija i postrojenja

Izvjee o sigurnosti

MAPP, SMS

Identifikacija postrojenja

Primjerproboj amonijaka

3Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

Petrokemija d.d. Kutina, Hrvatska Legal and ownership framework

From 1968 to 1996 Petrokemija in various organization types within INA Zagreb;

1991 Petrokemija d.d. founded, 100% owned by INA Oil Industry, Zagreb;

1998 voucher privatization;

Since 2003 listed on the Zagreb Stock Exchange;

Ownership structure:

50,6% Croatian Privatization Fund and Government of Croatia,

49,4% investment funds and private investors.

4Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

Petrokemija in figures: Petrokemija Kutina Croatian and regional brand: 900 million kn in capital; 2 billion kn in total revenues; Capacity:

1,350,000 t / y mineral fertilizers, 32,000 t / y carbon black, 50,000 t / y bentonite-based products;

2370 employees. One of largest Croatian industrial producers; At the very top in chemical and pharmaceutical industry, immediately

following Pliva; 3rd largest Croatian exporter; 20th largest employer; Ranks 18th on the domestic companies' total revenues list.

5Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

Sales of Products wide product range of high-quality products:

Complex NPK fertilizer (with nutrients and micro-nutrients),

Nitrogen fertilizers (prilled and granular CAN, AN and prilled UREA),

Liquid fertilizers, Various carbon black grades, Products for the foundry industry, Animal feed supplements, and Other bentonite-based products.

own pallet production; maintenance activities;

6Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

Elementarni sumpor

Postrojenje: KAN

Postrojenje Urea

Postrojenje:Amonijak

CO2

Postrojenje: Duina kiselina

Prirodni plin, zrak, vodena para

Postrojenje: Sumporna kiselina

Sirovi fosfat

Postrojenje: Fosforna kiselina

Postrojenje: NPK

Dolomit

KCl

MAP

7Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

postrojenje sirovine

Our Product - Synonym for Quality The name Petrokemija is a synonym for high

quality producer;

We use best market available raw materials in our production processes;

ISO 9001:2008 Quality Management System is used in all our production and business processes;

The best quality "controller" is the market;

Our products are sold to: domestic market (40%),

world markets (60%).

8Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

We take care of environmental protection and pollution, confirmed by Environmental Management System, in line with the ISO 14001:2004 standard;

We have a long term strategy of investments into environmental protection;

Environmental protection is carried out through application activities and soil analysis we give advice on type of fertilization, taking into account optimum yields and soil preservation.

9Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

EC Directive 96/82 (Seveso II) on the control of major-accident hazards involving dangerous substances

Implementation of Directive 2003/105/EC amending Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances

Law on ratiffication of Convention on the transboundary effects of industrial accidents , MU 7/99

Law on Environmental Protection, NN 110/07

Law on chemicals, NN 150/05, 53/08

National chemical safety strategy 2008/11/28

Regulation on the control of major-accident hazards involving dangerous substances, NN 114/08

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Defining dangerous substances from Annex I

and II, EC Directive) What dangerous substances

do we have on our plant site?

What quantities?

Obligations according to criteria from Annex I and II

Notification

Drafting Safety Report

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Processing demands from Annex I and II

Dangerous substances inventory creation with quantities and location in facilities, in cooperation with Environmental Protection Department and Head of facilities.

Creation of Notification for dangerous substances in terms of Annex I, Part 1 table.

List of dangerous substances for creation of Safety Report

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13Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

14

Redbr.

Kemijski naziv

CAS broj Naziv poIUPAC

Najvea koliina

Lokacija

1 Amonijak 7664-41-7 Amonijak 17.000 tona Skladite Amonijaka

2. Duina kiselina 50-60%

7697-37-2 Duina kiselina

1.200 t

1.200 t

DUKI-1

DUKI-2

3. Amonijev nitrat 6484-52-2 Amonijev nitrat

XXXX Skladite amonijevog nitrata

5. Srednje lo ulje LUS II

68553-00-4 Loivo ulje, No. 6

19.000 t Energana

6. SO2 od izgaranja elementarnog sumpora

7446-09-5 Sumporov (IV) oksid

50.000 t Skladite sumpora

Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

7. Dekantirano ulje + LUS II

64741-62-468553-00-4

Dekantirano uljeLoivo ulje, No.6

1.600 t Proizvodnja ae

8. Antracensko ulje

90640-86-1 Antracensko ulje

2.000 t Proizvodnja ae

9. Pirolizno ulje

68513-69-9 Pirolizno ulje

3.000 t Proizvodnja ae

10. Procesna mjeavina ulja pod 7,8,9

64741-62-468553-00-490640-86-168513-69-9

Procesna mjeavina

1.600 t Proizvodnja ae

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Delivering information to the State Ministry in accordance with demands of Annex I and II

On formal template in Annex II: ( description of the site

and location of the facilities, measures for disenabling and mitigation of sudden event, data for hazard substances on facilities)

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Adopted formally

OBJECTIVE: Our objective is to work without injuries, professional illness, harmful effects of work on employees health, as well as protection of properties by implementation of rules and regulation of Safety, Fire protection, Security and other mentioned principles in accident-freeenvironment.

18Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

Company has to be a safe workplace for all employees, contractors and visitors.

Responsibility for Safety is not transferable. Each employee of Petrokemija is fully responsible for personal safety and for the safety of his surroundings.

Petrokemija shall not make any business decision that lowers orjeopardize the concern about safety of work and environment.

Written procedures for conducting extraordinarory events shall be continuouosely practised, analised and constantly improved.

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Addresses all 7 aspects as in Annex III

organization and

personnel

identification and

evaluation of major

hazards

operational control

management of change

emergency planning and

response

monitoring

audit and review

20Petrokemija d.d., Kutina Safety Report / Izvjee o sigurnosti Petrokemije d.d., Kutina

Facility location description

Middle region of Croatia

By the south side of Moslavina mountain

Near the Nature park

Plant site decription and it`s environment

On approx. 130 ha

Geographyc location

Approx. 1.2 km SE from the City

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Meteorological, geological and hydrographic conditions Wind rose

Geologicall data

70% subsurface area till 30 m depth consists of medium plastic clay

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Tanks for:

Ammonia

Sulphuric acid

Nitric acid

Power plant- fuel oil

Oil feedstok on Carbon Black Plant

Storages:

Sulphur

Ammonium nitrate

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(II C) Description of areas

with possible Domino effect in case of major-acciden