Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4,...

62
WDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS AND COMPANY IDENTIFICATION Chemical Identifier Product Code Company Name Address Company Contact Phone Number Fax Number Mail Address Emergency Phone Number Recommended Use and Restriction on Use Section 2 - HAZARDS IDENTIFICATION GHS Classification Health Hazards Environmental Hazards GHS Label Elements Symbols Signal Word Hazard Statements Precautionary Statements Prevention Precautionary Statements H373 May cause damage to respiratory apparatus,heart,central nervous system thro prolonged or repeated exposure H411 Toxic to aquatic life with long lastin Do not get in eyes, on skin, or on clothing Hazard to the aquatic environment (acute ha Category 2 Hazard to the aquatic environment (long-ter hazard) Category 2 Other hazards than mentioned above are Not applicable or No data available. Warning H320 Causes eye irritation H371 May cause damage to respiratory apparatus,heart,kidney,central nervous syst 048-928-6668 ink LRN5/7,LRN5H,LRNT5,LR7/10,BLN15/23/25/75/ 105,BL17/27/30/57/77/107,BL60,BL80,BL110-A Serious eye damage/eye irritation Category Specific target organ toxicity (single expos Category 2(respiratory apparatus,heart,kidney,central nervous syst Specific target organ toxicity (repeated ex Category 2(respiratory apparatus,heart,cent nervous system) 048-928-6668 048-928-9190 [email protected] Safety Data Sheet (SDS) WDR11-A WDR11A0001 PENTEL CO., LTD. 7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYO QUALITY ASSURANCE DEPARTMENT I

Transcript of Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4,...

Page 1: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5

Preparation Date  2013/04/20Revision Date 2016/01/12

Section 1 - CHEMICALS AND COMPANY IDENTIFICATIONChemical IdentifierProduct CodeCompany NameAddressCompany ContactPhone NumberFax NumberMail AddressEmergency PhoneNumberRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Health Hazards

EnvironmentalHazards

GHS Label Elements

Symbols

Signal WordHazard Statements

PrecautionaryStatementsPreventionPrecautionaryStatements

H373 May cause damage to respiratoryapparatus,heart,central nervous system throughprolonged or repeated exposureH411 Toxic to aquatic life with long lasting effec

Do not get in eyes, on skin, or on clothing.(P262)

Hazard to the aquatic environment (acute hazarCategory 2Hazard to the aquatic environment (long-termhazard) Category 2Other hazards than mentioned above are Notapplicable or No data available.

WarningH320 Causes eye irritationH371 May cause damage to respiratoryapparatus,heart,kidney,central nervous system

048-928-6668

ink

LRN5/7,LRN5H,LRNT5,LR7/10,BLN15/23/25/75/105,BL17/27/30/57/77/107,BL60,BL80,BL110-A

Serious eye damage/eye irritation Category 2BSpecific target organ toxicity (single exposure)Category 2(respiratoryapparatus,heart,kidney,central nervous systemSpecific target organ toxicity (repeated exposure)Category 2(respiratory apparatus,heart,centralnervous system)

[email protected]

Safety Data Sheet (SDS)

WDR11-AWDR11A0001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT I

Page 2: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 2/5

ResponsePrecautionaryStatements

StoragePrecautionaryStatementsDisposalPrecautionaryStatements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Glycerin 8.79% CH2OHCH

(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Ethylene glycol 7% HOCH2CH2OH

(2)-230 Existing 107-21-1

Ammonia 0.3% (1)-391 Existing 7664-41-7Triethanolamine 0.3% N(CH2CH2

OH)3(2)-308 Existing 102-71-6

Thiodiglycol 9.5% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Impurities and/orStabilizing Additives whichContribute to the

Section 4 - FIRST AID MEASURESInhalation

Skin Contact

Eye Contact

Ingestion

If skin irritation or rash occurs, get medical adviceand attention.Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do.Continue rinsing.When the ocular stimulation lasts, Seek medicaltreatment and advice.Rinse mouth. Do NOT induce vomiting.

No information available

Remove person to fresh air and keep comfortablefor breathing.Get medical advice and attention if you feel unwell.

Immediately rinse skin with water.Get medical advice and attention if you feel unwell.

Wash with plenty of soap and water.

IF SWALLOWED: Rinse mouth. Do NOT inducevomiting.(P301+P330+P331)IF ON SKIN: Gently wash with plenty of soap andwater.(P302+P350)Store locked up.(P405)

Dispose of contents and container in accordancewith local, regional and national regulations (to bespecified).(P501)

mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

IF exposed or concerned: Call a POISONCENTER/doctor/...(P308+P311)

IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, ifpresent and easy to do. Continuerinsing.(P305+P351+P338)If eye irritation persists: Get medical advice andattention.(P337+P313)

Page 3: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 3/5

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Section 6 - ACCIDENTAL RELEASE MEASURESEnvironmentalPrecautions

Methods and Equipmentfor Containment andCleaning up

Prevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixturesSpecific HygineMeasures

Storage PrecautionaryStatements

Technical Measures

Material Used inPackaging/Containers

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

Eye Protection

Packaging materials and containers are notlegislated, but use sturdy and closed-typecontainers.

Good general ventilation should be sufficient tocontrol airborne levels.Wear eye protection.

Protection glasses (ordinary glasses, ordinaryglasses with side shields, and goggles).

Wash hand thoroughly after handling.

The storage facility should be provided withnecessary lighting, lighting equipment, andventilator to store and handle dangerous goods.Refer to "Section 10 - STABILITY ANDREACTIVITY".Have containers keep away from direct sunlightand heat.Keep away from heat.Store locked up.

Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and use necessarypersonal protective equipment as described in"Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION".Wash hand thoroughly after handling.

Avoid swallowing.Protect from high temperature and direct sunlight.Refer to "Section 10 - STABILITY ANDREACTIVITY".

Pay attention not to cause the influence on theenvironment by discharging into rivers.This product is water pollutant and should beprevented from contaminating soil or from enteringsewage and drainage systems and bodies of water.After removal, flush contaminated area thoroughlywith water.

Vacuum or sweep up material and place in adisposal container.Absorb spill with inert material (e.g., dry sand orearth), then place in a chemical waste container.Prevent flowing into drain, sewage, basement, andclosed area.

Get medical advice and attention if you feel unwell.

Dry chemicals, CO2, water spray or regular foam.

Page 4: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 4/5

Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAppearance Physical State

FormColour

OdourOdour thresholdpHMelting Point/FreezingPointInitial Boiling Point andBoiling RangesFlash PointEvaporation RateFlammability (solid, gas)Flammability or ExplosiveLimits

Lower Limit

Upper LimitVapour PressureVapour DensitySpecific Gravity (Density)Partition Coefficient : n-Octanol/WaterAuto-IgnitionDecompositionTemperatureViscosityKinematic viscosity

Section 10 - STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of HazardousReactionConditions to AvoidImcompatible Substancesor MixturesHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute ToxicitySkin Corrosion/IrritationSerious eye damage/eyeirritationRespiratory or SkinSensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicitySpecific target organtoxicity (single exposure)Specific target organtoxicity (repeatedexposure)Aspiration Hazard

Section 12 - ECOLOGICAL INFORMATION

No data availableNo data availableNo data available

No data available

No data available

No data available

No information availableNo data availableNo data available

No data available

No data available

No data available

No data availableNo data availableNo data available

No data availableNo data available

No data availableNo data availableNo data available

No data availableNo data available

No data available

no data availableNo data availableNo data availableNo data available

No data availableNo data available

blackslight odorNo data availableNo data availableNo data available

No data available

liquidliquid (viscous liquid)

Page 5: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 5/5

Hazard to the aquaticenvironment (acuteHazard to the aquaticenvironment (long-termhazard)Hazard to the ozone layer

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Emergency ResponseGuide Number

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

Not applicable

Not applicable

Not applicable

No information availableThis information is furnished without warrantyexpress or implied.This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

Not applicableNot applicable

Not applicable

Not applicable

Not applicable

Not applicable

No data available

No data available

For disposal, conform with the standards providedby related laws and local public bodies.Commission a waste disposal company, or a localpublic body who are licensed by local or regionalgovernment, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

No data available

Page 6: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 2/5

ResponsePrecautionaryStatements

StoragePrecautionaryStatementsDisposalPrecautionaryStatements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Glycerin 8.79% CH2OHCH

(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Ethylene glycol 7% HOCH2CH2OH

(2)-230 Existing 107-21-1

Ammonia 0.3% (1)-391 Existing 7664-41-7Triethanolamine 0.3% N(CH2CH2

OH)3(2)-308 Existing 102-71-6

Thiodiglycol 9.5% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Impurities and/orStabilizing Additives whichContribute to the

Section 4 - FIRST AID MEASURESInhalation

Skin Contact

Eye Contact

Ingestion

If skin irritation or rash occurs, get medical adviceand attention.Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do.Continue rinsing.When the ocular stimulation lasts, Seek medicaltreatment and advice.Rinse mouth. Do NOT induce vomiting.

No information available

Remove person to fresh air and keep comfortablefor breathing.Get medical advice and attention if you feel unwell.

Immediately rinse skin with water.Get medical advice and attention if you feel unwell.

Wash with plenty of soap and water.

IF SWALLOWED: Rinse mouth. Do NOT inducevomiting.(P301+P330+P331)IF ON SKIN: Gently wash with plenty of soap andwater.(P302+P350)Store locked up.(P405)

Dispose of contents and container in accordancewith local, regional and national regulations (to bespecified).(P501)

mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

IF exposed or concerned: Call a POISONCENTER/doctor/...(P308+P311)

IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, ifpresent and easy to do. Continuerinsing.(P305+P351+P338)If eye irritation persists: Get medical advice andattention.(P337+P313)

Page 7: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 3/5

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Section 6 - ACCIDENTAL RELEASE MEASURESEnvironmentalPrecautions

Methods and Equipmentfor Containment andCleaning up

Prevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixturesSpecific HygineMeasures

Storage PrecautionaryStatements

Technical Measures

Material Used inPackaging/Containers

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

Eye Protection

Packaging materials and containers are notlegislated, but use sturdy and closed-typecontainers.

Good general ventilation should be sufficient tocontrol airborne levels.Wear eye protection.

Protection glasses (ordinary glasses, ordinaryglasses with side shields, and goggles).

Wash hand thoroughly after handling.

The storage facility should be provided withnecessary lighting, lighting equipment, andventilator to store and handle dangerous goods.Refer to "Section 10 - STABILITY ANDREACTIVITY".Have containers keep away from direct sunlightand heat.Keep away from heat.Store locked up.

Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and use necessarypersonal protective equipment as described in"Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION".Wash hand thoroughly after handling.

Avoid swallowing.Protect from high temperature and direct sunlight.Refer to "Section 10 - STABILITY ANDREACTIVITY".

Pay attention not to cause the influence on theenvironment by discharging into rivers.This product is water pollutant and should beprevented from contaminating soil or from enteringsewage and drainage systems and bodies of water.After removal, flush contaminated area thoroughlywith water.

Vacuum or sweep up material and place in adisposal container.Absorb spill with inert material (e.g., dry sand orearth), then place in a chemical waste container.Prevent flowing into drain, sewage, basement, andclosed area.

Get medical advice and attention if you feel unwell.

Dry chemicals, CO2, water spray or regular foam.

Page 8: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 4/5

Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAppearance Physical State

FormColour

OdourOdour thresholdpHMelting Point/FreezingPointInitial Boiling Point andBoiling RangesFlash PointEvaporation RateFlammability (solid, gas)Flammability or ExplosiveLimits

Lower Limit

Upper LimitVapour PressureVapour DensitySpecific Gravity (Density)Partition Coefficient : n-Octanol/WaterAuto-IgnitionDecompositionTemperatureViscosityKinematic viscosity

Section 10 - STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of HazardousReactionConditions to AvoidImcompatible Substancesor MixturesHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute ToxicitySkin Corrosion/IrritationSerious eye damage/eyeirritationRespiratory or SkinSensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicitySpecific target organtoxicity (single exposure)Specific target organtoxicity (repeatedexposure)Aspiration Hazard

Section 12 - ECOLOGICAL INFORMATION

No data availableNo data availableNo data available

No data available

No data available

No data available

No information availableNo data availableNo data available

No data available

No data available

No data available

No data availableNo data availableNo data available

No data availableNo data available

No data availableNo data availableNo data available

No data availableNo data available

No data available

no data availableNo data availableNo data availableNo data available

No data availableNo data available

blackslight odorNo data availableNo data availableNo data available

No data available

liquidliquid (viscous liquid)

Page 9: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 5/5

Hazard to the aquaticenvironment (acuteHazard to the aquaticenvironment (long-termhazard)Hazard to the ozone layer

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Emergency ResponseGuide Number

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

Not applicable

Not applicable

Not applicable

No information availableThis information is furnished without warrantyexpress or implied.This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

Not applicableNot applicable

Not applicable

Not applicable

Not applicable

Not applicable

No data available

No data available

For disposal, conform with the standards providedby related laws and local public bodies.Commission a waste disposal company, or a localpublic body who are licensed by local or regionalgovernment, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

No data available

Page 10: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR14-B, PENTEL CO., LTD., 3, 2017/07/24, 1/6

Preparation Date  2013/04/20Revision Date 2017/07/24

Section 1 - CHEMICALS AND COMPANY IDENTIFICATIONChemical IdentifierProduct CodeCompany NameAddressCompany ContactPhone NumberFax NumberMail AddressEmergency PhoneNumberRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Health Hazards

GHS Label Elements

Symbols

Signal WordHazard Statements

PrecautionaryStatementsPreventionPrecautionaryStatements

Wear protective gloves.(P280)Wash hand thoroughly after handling.(P264)Wash eye thoroughly after handling.(P264)

H318 Causes serious eye damageH332 Harmful if inhaledH361 Suspected of damaging fertility or theunborn childH371 May cause damage to blood,kidney,centralnervous systemH373 May cause damage to liver,kidney throughprolonged or repeated exposure

Avoid breathing mist, vapours and spray.(P261)

Reproductive toxicity Category 2Specific target organ toxicity (single exposure)Category 2(blood,kidney,central nervous system)Specific target organ toxicity (repeated exposure)Category 2(liver,kidney)Other hazards than mentioned above are Notapplicable or Classification not possible.

DangerH315 Causes skin irritation

03-5695-7210

ink

(X)LRN5,LRN5H,LSN5H,XLRNT5,(X)LR7, LR10-B

Acute toxicity (Inhalation: dust and mist) Category4Skin corrosion/irritation Category 2Serious eye damage/eye irritation Category 1

Safety Data Sheet (SDS)

WDR14-BWDR14B0001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT [email protected]

BL107,BL110,BL117,BL17,BL27,BL57,BL60,BL80.BL77-B

BLN115,BLN15,BLN25,BLN75-B

Page 11: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR14-B, PENTEL CO., LTD., 3, 2017/07/24, 2/6

ResponsePrecautionaryStatements

StoragePrecautionaryStatementsDisposalPrecautionaryStatements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Glycerin 8.79% CH2OHCH

(OH)CH2OH

(2)-242 Existing 56-81-5

Etlylene glycol 9.72% HOCH2CH2OH

(2)-230 Existing 107-21-1

Diethylene glycol 7.3% HOCH2CH2OCH2CH2OH

(2)-415 Existing 111-46-6

Impurities and/orStabilizing Additives whichContribute to the

Section 4 - FIRST AID MEASURESInhalation

Skin Contact

Eye Contact

Ingestion

Section 5 - FIRE FIGHTING MEASURES

Rinse mouth. Do NOT induce vomiting.Get medical advice and attention if you feel unwell.

Remove person to fresh air and keep comfortablefor breathing.Get medical advice and attention if you feel unwell.

Wash with plenty of soap and water.If skin irritation or rash occurs, get medical adviceand attention.Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do.Continue rinsing.When the ocular stimulation lasts, Seek medicaltreatment and advice.

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

No information available

IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, ifpresent and easy to do. Continuerinsing.(P305+P351+P338)If eye irritation persists: Get medical advice andattention.(P337+P313)IF SWALLOWED: Rinse mouth. Do NOT inducevomiting.(P301+P330+P331)Store locked up.(P405)

Dispose of contents and container in accordancewith local, regional and national regulations (to bespecified).(P501)

Mixture

IF ON SKIN: Wash with plenty of soap andwater.(P302+P352)

If skin irritation or rash occurs, get medical adviceand attention.(P333+P313)IF INHALED: Remove to fresh air and keep at restin a position comfortable forbreathing.(P304+P340)

Page 12: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR14-B, PENTEL CO., LTD., 3, 2017/07/24, 3/6

Extinguishing Media

Section 6 - ACCIDENTAL RELEASE MEASURESPersonal Precautions,Protective Equipment andEmergency Procedures

EnvironmentalPrecautions

Methods and Equipmentfor Containment andCleaning up

Prevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Precautions for SafeHandling

Prevents Handling ofIncompatibleSubstances orMixturesSpecific HygieneMeasures

Storage PrecautionaryStatements

Conditions for SafeStorage

Material Used inPackaging/Containers

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

Hand Protection

Packaging materials and containers are notlegislated, but use sturdy and closed-typecontainers.

Good general ventilation should be sufficient tocontrol airborne levels.Wear protective gloves.

Wash hand thoroughly after handling.

The storage facility should be provided withnecessary lighting, lighting equipment, andventilator to store and handle dangerous goods.Refer to "Section 10 - STABILITY ANDREACTIVITY".Have containers keep away from direct sunlightand heat.Keep away from heat.Store locked up.

Wash hand thoroughly after handling.

Avoid breathing mist, vapours and spray.Avoid contact with eyes.Avoid swallowing.Protect from high temperature and direct sunlight.Refer to "Section 10 - STABILITY ANDREACTIVITY".

After removal, flush contaminated area thoroughlywith water.

Vacuum or sweep up material and place in adisposal container.Absorb spill with inert material (e.g., dry sand orearth), then place in a chemical waste container.Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and use necessarypersonal protective equipment as described in"Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION".

Dry chemicals, CO2, water spray or regular foam.

Wear appropriate personal protective equipment(Refer to "Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION") and avoid inhalationor contact with eyes and skin.Pay attention not to cause the influence on theenvironment by discharging into rivers.This product is water pollutant and should beprevented from contaminating soil or from enteringsewage and drainage systems and bodies of water.

Page 13: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR14-B, PENTEL CO., LTD., 3, 2017/07/24, 4/6

Eye Protection

Skin and BodyProtection

Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAppearance Physical State

FormColour

OdourOdour thresholdpHMelting Point/FreezingPointInitial Boiling Point andBoiling RangesFlash PointEvaporation RateFlammability (solid, gas)Flammability or ExplosiveLimits

Lower Limit

Upper LimitVapour PressureVapour DensitySpecific Gravity (Density)Partition Coefficient : n-Octanol/WaterAuto-IgnitionDecompositionTemperatureViscosityKinematic viscosity

Section 10 - STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of HazardousReactionConditions to AvoidIncompatible Substancesor MixturesHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute ToxicitySkin Corrosion/IrritationSerious eye damage/eyeirritationRespiratory or SkinSensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicitySpecific target organtoxicity (single exposure)

No data available

No data availableNo data availableNo data availableNo data available

No data availableNo data available

No data available

No information availableNo data availableNo data available

No data available

No data availableNo data available

No data availableNo data availableNo data available

No data availableNo data availableNo data availableNo data availableNo data available

No data available

No data available

No data available

No data availableNo data availableNo data availableNo data available

liquidliquid (viscous liquid)redslight odorNo data availableNo data available

Wear eye protection.Protection glasses (ordinary glasses, ordinaryglasses with side shields, and goggles).Use personal protective clothing and faceprotection as required.

Page 14: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR14-B, PENTEL CO., LTD., 3, 2017/07/24, 5/6

Specific target organtoxicity (repeatedexposure)Aspiration Hazard

Section 12 - ECOLOGICAL INFORMATIONHazardous to the aquaticenvironment (acute)Hazardous to the aquaticenvironment (long-term)Hazardous to the ozonelayer

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Emergency ResponseGuide Number

Not applicable

Not applicable

Not applicable

Not applicable

Not applicable

Not applicable

Not applicableNot applicable

When commissioning the disposal to a disposalcompany, notify the danger and toxicity thoroughlyto the company.Do not release waste liquid containing the productand used water for cleansing into rivers, etc., or donot discharge the concerned wastes intact forreclamation.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.In case of disposal of empty containers, removethe content thoroughly.

Not applicable

Not applicable

No data available

No data available

No data available

No data available

For disposal, conform with the standards providedby related laws and local public bodies.Commission a waste disposal company, or a localpublic body who are licensed by local or regionalgovernment, to dispose of the material.

No data available

Page 15: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR14-B, PENTEL CO., LTD., 3, 2017/07/24, 6/6

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

No information availableThis information is furnished without warrantyexpress or implied.This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

Page 16: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-C, PENTEL CO., LTD., 1, 2014/08/12, 1/5

Preparation Date  2014/08/12Revision Date 2016/01/12

Section 1 - CHEMICALS AND COMPANY IDENTIFICATIONChemical IdentifierProduct CodeCompany NameAddressCompany ContactPhone NumberFax NumberMail AddressEmergency PhoneNumberRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Health Hazards

GHS Label Elements

Symbols

Signal WordHazard Statements

PrecautionaryStatementsPreventionPrecautionaryStatements

[email protected]

Safety Data Sheet (SDS)

WDR20-CWDR20C0001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT I

048-928-6668

ink

BLN15/23/25/55/75/77/105,BL17/20/27/30/57/60/77/80/107/110,LRN5/7,LR7/10,LRNT5-C

Serious eye damage/eye irritation Category 2BSpecific target organ toxicity (single exposure)Category 1(respiratoryapparatus,heart,kidney,central nervous system)Specific target organ toxicity (repeated exposure)Category 1(respiratory apparatus,heart,centralnervous system)Other hazards than mentioned above are Notapplicable or No data available.

DangerH320 Causes eye irritationH370 Causes damage to respiratoryapparatus,heart,kidney,central nervous systemH372 Causes damage to respiratoryapparatus,heart,central nervous system throughprolonged or repeated exposure

Do not breathe mist, vapours and spray.(P260)

Wash hand thoroughly after handling.(P264)Wash eye thoroughly after handling.(P264)Do not eat, drink or smoke when using thisproduct.(P270)

Page 17: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-C, PENTEL CO., LTD., 1, 2014/08/12, 2/5

ResponsePrecautionaryStatements

StoragePrecautionaryStatementsDisposalPrecautionaryStatements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Ethylene glycol 12.6% HOCH2CH

2OH(2)-230 Existing 107-21-1

Glycerin 8.7% CH2OHCH(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Thiodiglycol 9.4% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Impurities and/orStabilizing Additives whichContribute to the

Section 4 - FIRST AID MEASURESInhalationSkin ContactEye Contact

Ingestion

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Section 6 - ACCIDENTAL RELEASE MEASURESEnvironmentalPrecautions

Methods and Equipmentfor Containment andCleaning up

IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, ifpresent and easy to do. Continuerinsing.(P305+P351+P338)IF exposed or concerned: Call a POISONCENTER/doctor/...(P308+P311)Get medical advice and attention if you feelunwell.(P314)Specific treatment.(P321)If eye irritation persists: Get medical advice andattention.(P337+P313)Store locked up.(P405)

Dispose of contents and container in accordancewith local, regional and national regulations (to bespecified).(P501)

mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

No information available

Call a doctor if you feel unwell.Wash with soap and water.Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do.Continue rinsing.When the ocular stimulation lasts, Seek medicaltreatment and advice.Rinse mouth. Do NOT induce vomiting.

Dry chemicals, CO2, water spray or regular foam.

Pay attention not to cause the influence on theenvironment by discharging into rivers.This product is water pollutant and should beprevented from contaminating soil or from enteringsewage and drainage systems and bodies of water.Vacuum or sweep up material and place in adisposal container.

Page 18: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-C, PENTEL CO., LTD., 1, 2014/08/12, 3/5

Prevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixtures

Storage PrecautionaryStatements

Technical Measures

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

RespiratoryProtectionHand ProtectionEye ProtectionSkin and BodyProtection

Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAppearance Physical State

FormColour

OdourOdour thresholdpHMelting Point/FreezingPointInitial Boiling Point andBoiling RangesFlash PointEvaporation RateFlammability (solid, gas)Flammability or ExplosiveLimits

Lower Limit

Upper LimitVapour PressureVapour DensitySpecific Gravity (Density)

Absorb spill with inert material (e.g., dry sand orearth), then place in a chemical waste container.After removal, flush contaminated area thoroughlywith water.Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and use necessarypersonal protective equipment as described in"Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION".Wash hand thoroughly after handling.

Avoid swallowing.Avoid contact with eyes.Protect from high temperature and direct sunlight.Refer to "Section 10 - STABILITY ANDREACTIVITY".

Refer to "Section 10 - STABILITY ANDREACTIVITY".Have containers keep away from direct sunlightand heat.Keep away from heat.

Good general ventilation should be sufficient tocontrol airborne levels.Use personal respiratory equipment as required.

Use personal gloves as required.Use personal eye protection as required.Use personal protective clothing and faceprotection as required.

liquidliquid (viscous liquid)blueodorlessNo data availableNo data availableNo data available

No data available

no data availableNo data availableNo data availableNo data available

No data availableNo data availableNo data availableNo data available

Page 19: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-C, PENTEL CO., LTD., 1, 2014/08/12, 4/5

Partition Coefficient : n-Octanol/WaterAuto-IgnitionDecompositionTemperatureViscosityKinematic viscosity

Section 10 - STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of HazardousReactionConditions to AvoidImcompatible Substancesor MixturesHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute ToxicitySkin Corrosion/IrritationSerious eye damage/eyeirritationRespiratory or SkinSensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicitySpecific target organtoxicity (single exposure)Specific target organtoxicity (repeatedexposure)Aspiration Hazard

Section 12 - ECOLOGICAL INFORMATIONHazard to the aquaticenvironment (acuteHazard to the aquaticenvironment (long-termhazard)Hazard to the ozone layer

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaMarine Pollutant

No data available

No data availableNo data available

No data availableNo data available

No data availableNo data availableNo data available

No data availableNo data available

No data available

No information availableNo data availableNo data available

No data available

No data availableNo data availableNo data availableNo data available

No data available

No data available

No data available

No data available

No data available

Disposal should be in accordance with applicableregulations and standards by the respective localgovernments.Commission a waste disposal company, or a localpublic body who are licensed by local or regionalgovernment, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

Not applicable

Page 20: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-C, PENTEL CO., LTD., 1, 2014/08/12, 5/5

Transport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Emergency ResponseGuide Number

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

Not applicable

Not applicable

Not applicable

Not applicable

Not applicableNot applicable

Not applicable

Not applicable

No information availableThis information is furnished without warrantyexpress or implied.This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

Page 21: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-D, PENTEL CO., LTD., 1, 2014/08/12, 1/5

Preparation Date  2014/08/12Revision Date 2016/01/12

Section 1 - CHEMICALS AND COMPANY IDENTIFICATIONChemical IdentifierProduct CodeCompany NameAddressCompany ContactPhone NumberFax NumberMail AddressEmergency PhoneNumberRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Health Hazards

GHS Label Elements

Symbols

Signal WordHazard Statements

PrecautionaryStatementsPreventionPrecautionaryStatements

H370 Causes damage to respiratoryapparatus,heart,kidney,central nervous systemH372 Causes damage to respiratoryapparatus,heart,central nervous system throughprolonged or repeated exposure

Do not breathe mist, vapours and spray.(P260)

Wash hand thoroughly after handling.(P264)Wash eye thoroughly after handling.(P264)Do not eat, drink or smoke when using thisproduct.(P270)

Serious eye damage/eye irritation Category 2BSpecific target organ toxicity (single exposure)Category 1(respiratoryapparatus,heart,kidney,central nervous system)Specific target organ toxicity (repeated exposure)Category 1(respiratory apparatus,heart,centralnervous system)Other hazards than mentioned above are Notapplicable or No data available.

DangerH320 Causes eye irritation

[email protected]

ink

BLN75,BLN77,BL17,BL27,BL57,BL60,BL77,BL80,BL107,LR7,LRN5-D

Safety Data Sheet (SDS)

WDR20-DWDR20D0001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT I

Page 22: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-D, PENTEL CO., LTD., 1, 2014/08/12, 2/5

ResponsePrecautionaryStatements

StoragePrecautionaryStatementsDisposalPrecautionaryStatements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Ethylene glycol 12.6% HOCH2CH

2OH(2)-230 Existing 107-21-1

Glycerin 8.6% CH2OHCH(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Thiodiglycol 9.4% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Impurities and/orStabilizing Additives whichContribute to the

Section 4 - FIRST AID MEASURESInhalationSkin ContactEye Contact

Ingestion

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Section 6 - ACCIDENTAL RELEASE MEASURESEnvironmentalPrecautions

Methods and Equipmentfor Containment andCleaning up

Vacuum or sweep up material and place in adisposal container.

No information available

Call a doctor if you feel unwell.Wash with soap and water.Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do.Continue rinsing.When the ocular stimulation lasts, Seek medicaltreatment and advice.Rinse mouth. Do NOT induce vomiting.

Dry chemicals, CO2, water spray or regular foam.

Pay attention not to cause the influence on theenvironment by discharging into rivers.This product is water pollutant and should beprevented from contaminating soil or from enteringsewage and drainage systems and bodies of water.

Dispose of contents and container in accordancewith local, regional and national regulations (to bespecified).(P501)

mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, ifpresent and easy to do. Continuerinsing.(P305+P351+P338)IF exposed or concerned: Call a POISONCENTER/doctor/...(P308+P311)Get medical advice and attention if you feelunwell.(P314)Specific treatment.(P321)If eye irritation persists: Get medical advice andattention.(P337+P313)Store locked up.(P405)

Page 23: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-D, PENTEL CO., LTD., 1, 2014/08/12, 3/5

Prevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixtures

Storage PrecautionaryStatements

Technical Measures

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

RespiratoryProtectionHand ProtectionEye ProtectionSkin and BodyProtection

Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAppearance Physical State

FormColour

OdourOdour thresholdpHMelting Point/FreezingPointInitial Boiling Point andBoiling RangesFlash PointEvaporation RateFlammability (solid, gas)Flammability or ExplosiveLimits

Lower Limit

Upper LimitVapour PressureVapour DensitySpecific Gravity (Density)

No data available

No data availableNo data availableNo data availableNo data available

No data availableNo data available

No data available

no data availableNo data availableNo data available

Use personal protective clothing and faceprotection as required.

liquidliquid (viscous liquid)greenodorlessNo data available

Have containers keep away from direct sunlightand heat.Keep away from heat.

Good general ventilation should be sufficient tocontrol airborne levels.Use personal respiratory equipment as required.

Use personal gloves as required.Use personal eye protection as required.

Wash hand thoroughly after handling.

Avoid swallowing.Avoid contact with eyes.Protect from high temperature and direct sunlight.Refer to "Section 10 - STABILITY ANDREACTIVITY".

Refer to "Section 10 - STABILITY ANDREACTIVITY".

Absorb spill with inert material (e.g., dry sand orearth), then place in a chemical waste container.After removal, flush contaminated area thoroughlywith water.Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and use necessarypersonal protective equipment as described in"Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION".

Page 24: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-D, PENTEL CO., LTD., 1, 2014/08/12, 4/5

Partition Coefficient : n-Octanol/WaterAuto-IgnitionDecompositionTemperatureViscosityKinematic viscosity

Section 10 - STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of HazardousReactionConditions to AvoidImcompatible Substancesor MixturesHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute ToxicitySkin Corrosion/IrritationSerious eye damage/eyeirritationRespiratory or SkinSensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicitySpecific target organtoxicity (single exposure)Specific target organtoxicity (repeatedexposure)Aspiration Hazard

Section 12 - ECOLOGICAL INFORMATIONHazard to the aquaticenvironment (acuteHazard to the aquaticenvironment (long-termhazard)Hazard to the ozone layer

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaMarine Pollutant

Commission a waste disposal company, or a localpublic body who are licensed by local or regionalgovernment, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

Not applicable

No data available

No data available

No data available

No data available

No data available

Disposal should be in accordance with applicableregulations and standards by the respective localgovernments.

No data available

No data available

No data availableNo data availableNo data availableNo data available

No data available

No data availableNo data available

No data available

No information availableNo data available

No data availableNo data available

No data availableNo data available

No data availableNo data available

No data available

Page 25: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-D, PENTEL CO., LTD., 1, 2014/08/12, 5/5

Transport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Emergency ResponseGuide Number

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

No information availableThis information is furnished without warrantyexpress or implied.This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

Not applicable

Not applicable

Not applicableNot applicable

Not applicable

Not applicable

Not applicable

Not applicable

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

Page 26: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-V, PENTEL CO., LTD., 1, 2014/08/12, 1/5

Preparation Date  2014/08/12Revision Date 2016/01/12

Section 1 - CHEMICALS AND COMPANY IDENTIFICATIONChemical IdentifierProduct CodeCompany NameAddressCompany ContactPhone NumberFax NumberMail AddressEmergency PhoneNumberRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Health Hazards

GHS Label Elements

Symbols

Signal WordHazard Statements

PrecautionaryStatementsPreventionPrecautionaryStatements

Safety Data Sheet (SDS)

WDR20-VWDR20V0001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT [email protected]

ink

BLN15,BLN25,BLN75,BLN77,BL17,BL27,BL57,BL60,BL77,BL80,BL107,LRN7,LR7,LR10-V

Serious eye damage/eye irritation Category 2BSpecific target organ toxicity (single exposure)Category 1(respiratoryapparatus,heart,kidney,central nervous system)Specific target organ toxicity (repeated exposure)Category 1(respiratory apparatus,heart,centralnervous system)Other hazards than mentioned above are Notapplicable or No data available.

DangerH320 Causes eye irritationH370 Causes damage to respiratoryapparatus,heart,kidney,central nervous systemH372 Causes damage to respiratoryapparatus,heart,central nervous system throughprolonged or repeated exposure

Do not breathe mist, vapours and spray.(P260)

Wash hand thoroughly after handling.(P264)Wash eye thoroughly after handling.(P264)Do not eat, drink or smoke when using thisproduct.(P270)

Page 27: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-V, PENTEL CO., LTD., 1, 2014/08/12, 2/5

ResponsePrecautionaryStatements

StoragePrecautionaryStatementsDisposalPrecautionaryStatements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Ethylene glycol 12.6% HOCH2CH

2OH(2)-230 Existing 107-21-1

Glycerin 8.6% CH2OHCH(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Thiodiglycol 9.4% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Impurities and/orStabilizing Additives whichContribute to the

Section 4 - FIRST AID MEASURESInhalationSkin ContactEye Contact

Ingestion

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Section 6 - ACCIDENTAL RELEASE MEASURESEnvironmentalPrecautions

Methods and Equipmentfor Containment andCleaning up

IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, ifpresent and easy to do. Continuerinsing.(P305+P351+P338)IF exposed or concerned: Call a POISONCENTER/doctor/...(P308+P311)Get medical advice and attention if you feelunwell.(P314)Specific treatment.(P321)If eye irritation persists: Get medical advice andattention.(P337+P313)Store locked up.(P405)

Dispose of contents and container in accordancewith local, regional and national regulations (to bespecified).(P501)

mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

No information available

Call a doctor if you feel unwell.Wash with soap and water.Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do.Continue rinsing.When the ocular stimulation lasts, Seek medicaltreatment and advice.Rinse mouth. Do NOT induce vomiting.

Dry chemicals, CO2, water spray or regular foam.

Pay attention not to cause the influence on theenvironment by discharging into rivers.This product is water pollutant and should beprevented from contaminating soil or from enteringsewage and drainage systems and bodies of water.Vacuum or sweep up material and place in adisposal container.

Page 28: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-V, PENTEL CO., LTD., 1, 2014/08/12, 3/5

Prevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixtures

Storage PrecautionaryStatements

Technical Measures

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

RespiratoryProtectionHand ProtectionEye ProtectionSkin and BodyProtection

Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAppearance Physical State

FormColour

OdourOdour thresholdpHMelting Point/FreezingPointInitial Boiling Point andBoiling RangesFlash PointEvaporation RateFlammability (solid, gas)Flammability or ExplosiveLimits

Lower Limit

Upper LimitVapour PressureVapour DensitySpecific Gravity (Density)

Absorb spill with inert material (e.g., dry sand orearth), then place in a chemical waste container.After removal, flush contaminated area thoroughlywith water.Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and use necessarypersonal protective equipment as described in"Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION".Wash hand thoroughly after handling.

Avoid swallowing.Avoid contact with eyes.Protect from high temperature and direct sunlight.Refer to "Section 10 - STABILITY ANDREACTIVITY".

Refer to "Section 10 - STABILITY ANDREACTIVITY".Have containers keep away from direct sunlightand heat.Keep away from heat.

Good general ventilation should be sufficient tocontrol airborne levels.Use personal respiratory equipment as required.

Use personal gloves as required.Use personal eye protection as required.Use personal protective clothing and faceprotection as required.

liquidliquid (viscous liquid)purpleodorlessNo data availableNo data availableNo data available

No data available

no data availableNo data availableNo data availableNo data available

No data availableNo data availableNo data availableNo data available

Page 29: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-V, PENTEL CO., LTD., 1, 2014/08/12, 4/5

Partition Coefficient : n-Octanol/WaterAuto-IgnitionDecompositionTemperatureViscosityKinematic viscosity

Section 10 - STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of HazardousReactionConditions to AvoidImcompatible Substancesor MixturesHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute ToxicitySkin Corrosion/IrritationSerious eye damage/eyeirritationRespiratory or SkinSensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicitySpecific target organtoxicity (single exposure)Specific target organtoxicity (repeatedexposure)Aspiration Hazard

Section 12 - ECOLOGICAL INFORMATIONHazard to the aquaticenvironment (acuteHazard to the aquaticenvironment (long-termhazard)Hazard to the ozone layer

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaMarine Pollutant

No data available

No data availableNo data available

No data availableNo data available

No data availableNo data availableNo data available

No data availableNo data available

No data available

No information availableNo data availableNo data available

No data available

No data availableNo data availableNo data availableNo data available

No data available

No data available

No data available

No data available

No data available

Disposal should be in accordance with applicableregulations and standards by the respective localgovernments.Commission a waste disposal company, or a localpublic body who are licensed by local or regionalgovernment, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

Not applicable

Page 30: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR20-V, PENTEL CO., LTD., 1, 2014/08/12, 5/5

Transport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Emergency ResponseGuide Number

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

Not applicable

Not applicable

Not applicable

Not applicable

Not applicable

This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

Not applicable

Not applicable

Not applicable

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

No information availableThis information is furnished without warrantyexpress or implied.

Page 31: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2012/1/13, 1/4

Preparation Date  2012/01/13Revision Date 2016/01/22

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct NameProduct CodeCompany NameAddressCompany ContactPhone NumberEmergency PhoneNumberFax NumberMail AddressRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Glycerin 11.5% CH2OHCH

(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Ethylene glycol 5% HOCH2CH2OH

(2)-230 Existing 107-21-1

Thiodiethylene glycol 9% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Triethanolamine 0.7% N(CH2CH2OH)3

(2)-308 Existing 102-71-6

Impurities and/or Stabilizing Additives No information availablewhich Contribute to the Classification

Section 4 - FIRST AID MEASURESInhalation

Skin Contact

Eye Contact

Ingestion

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Rinse a mouth. Don't make vomit by force.Get medical advice and attention if you feel un

Carbon dioxide, dry chemicals, water sprinklingeneral foam extinguishing agents

If breathing is difficult, move affected persothe open air. Keep him or her at rest to alloweasier breathing.Get medical advice and attention if you feel un

Wash with soap and plenty of water.If skin irritation or rash occurs: Get medicaadvice and attention.Wash eyes carefully for several minutes withwater. Take off contact lenses if easily removand continue to wash eyes afterwards.When the ocular stimulation lasts, Seek medicatreatment and advice.

[email protected]

LR7-F,BL77-F,BL107FF-F

No classification standards applicable

mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

048-928-6668048-928-6668

048-928-9190

Safety Data Sheet (SDS)

WDR21-FWDR21F0001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT I

Page 32: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2012/1/13, 2/4

Section 6 - ACCIDENTAL RELEASE MEASURESPersonal Precautions,Protective Equipment andEmergency ProceduresEnvironmentalPrecautions

Decontamination/Absorption/Sweeping/Vacuming/Neutralization

Methods and Equipmentfor Containment andCleaning upPrevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Local and GeneralVentilation

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixtures

Storage PrecautionaryStatements

Technical Measures

ImcompatibleSubstances orMixturesStorage Conditions

Material Used inPackaging/Containers

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

RespiratoryProtectionEye Protection

Specific Hygine Measures

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

A general proper ventilation is enough to controlconcentration in air.No information available

Use an adequate personal eye protector.Goggles (ordinary glass type, ordinary glass typewith side shields, and goggle type)Wash hands thoroughly after handling.

The storage facility should be privided withnecessary lighting, lighting equipment, andventilator to store and handle dangerous goods.Refer to "10. STABILITY AND REACTIVITY"

Have containers keep away from direct sunlightand heat.Keep away from heat.Store locked up.Packaging materials and containers are notlegislated, but use sturdy and closed-typecontainers.

Provide local ventilations and a full ventilationsystem as described in "8. EXPOSURECONTROLS AND PERSONAL PROTECTION."Avoid the contact with eyes.

Wash hands thoroughly after handling.Avoid swallowingAvoid high temperature and direct sunlight.Refer to "10. STABILITY AND REACTIVITY"

Collect the material into a disposal container bysucking up or sweeping up.

Absorb spills with inert materials (such as dry sandor soil) and collect them into chemical-wastedisposal container.Cleansing the contaminated area thoroughly withwater after removal.

Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and Use necessarypersonal protective equipment as described in "8.EXPOSURE CONTROLS AND PERSONAL

No information available

Pay attention not to cause the influence on theenvironment by discharging into rivers.This product is water pollutant. Prevent soilcontamination, or the product from flowing into thedrain systems.

Page 33: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2012/1/13, 3/4

Appearance Physical StateColourOdourpH

Initial Boiling Point andBoiling RangesFlash PointAuto-Ignition

Section 10 - STABILITY AND REACTIVITYStability

Possibility of HazardousReactionConditions to AvoidHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute Toxicity

Section 12 - ECOLOGICAL INFORMATIONEnvironmentalHazards

Ecotoxicity

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaUN No.Marine PollutantRegulatoryInformation by AirUN No.

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaUN No.Marine PollutantRegulatoryInformation by AirUN No.

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

Not applicableNot applicable

Not applicable

No information availableThis information is furnished without warrantyexpress or implied.

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

Not applicableNot applicable

Not applicableNot applicable

Not applicable

Not applicable

No information available

For disposal, conform with the standards providedby related laws and local public bodies.Commission the authorized waste disposalcompany, or a local public body who conducts thedisposal, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

Not applicable

The material is stable under storage and handlingconditions comprised with the regulations.No data available

No data availableNo data available

No information available

No information available

orangeslight odorNo data availableNo information available

no data availableNo information available

liquid (viscous liquid)

Page 34: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2012/1/13, 4/4

This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

Page 35: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2013/11/21, 1/4

Preparation Date  2013/11/21Revision Date 2016/01/22

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct NameProduct CodeCompany NameAddressCompany ContactPhone NumberEmergency PhoneNumberFax NumberMail AddressRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Glycerin 11.5% CH2OHCH

(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Ethylene glycol 5% HOCH2CH2OH

(2)-230 Existing 107-21-1

Thiodiethylene glycol 9% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Triethanolamine 0.7% N(CH2CH2OH)3

(2)-308 Existing 102-71-6

Impurities and/or Stabilizing Additives No information availablewhich Contribute to the Classification

Section 4 - FIRST AID MEASURESInhalation

Skin Contact

Eye Contact

Ingestion

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Rinse a mouth. Don't make vomit by force.Get medical advice and attention if you feel un

Carbon dioxide, dry chemicals, water sprinklingeneral foam extinguishing agents

If breathing is difficult, move affected persothe open air. Keep him or her at rest to alloweasier breathing.Get medical advice and attention if you feel un

Wash with soap and plenty of water.If skin irritation or rash occurs: Get medicaadvice and attention.Wash eyes carefully for several minutes withwater. Take off contact lenses if easily removand continue to wash eyes afterwards.When the ocular stimulation lasts, Seek medicatreatment and advice.

[email protected]

LR7-P,BL77-P,BL107FP-P

No classification standards applicable

mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

048-928-6668048-928-6668

048-928-9190

Safety Data Sheet (SDS)

WDR21-PWDR21P0001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT I

Page 36: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2013/11/21, 2/4

Section 6 - ACCIDENTAL RELEASE MEASURESPersonal Precautions,Protective Equipment andEmergency ProceduresEnvironmentalPrecautions

Decontamination/Absorption/Sweeping/Vacuming/Neutralization

Methods and Equipmentfor Containment andCleaning upPrevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Local and GeneralVentilation

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixtures

Storage PrecautionaryStatements

Technical Measures

ImcompatibleSubstances orMixturesStorage Conditions

Material Used inPackaging/Containers

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

RespiratoryProtectionEye Protection

Specific Hygine Measures

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

A general proper ventilation is enough to controlconcentration in air.No information available

Use an adequate personal eye protector.Goggles (ordinary glass type, ordinary glass typewith side shields, and goggle type)Wash hands thoroughly after handling.

The storage facility should be privided withnecessary lighting, lighting equipment, andventilator to store and handle dangerous goods.Refer to "10. STABILITY AND REACTIVITY"

Have containers keep away from direct sunlightand heat.Keep away from heat.Store locked up.Packaging materials and containers are notlegislated, but use sturdy and closed-typecontainers.

Provide local ventilations and a full ventilationsystem as described in "8. EXPOSURECONTROLS AND PERSONAL PROTECTION."Avoid the contact with eyes.

Wash hands thoroughly after handling.Avoid swallowingAvoid high temperature and direct sunlight.Refer to "10. STABILITY AND REACTIVITY"

Collect the material into a disposal container bysucking up or sweeping up.

Absorb spills with inert materials (such as dry sandor soil) and collect them into chemical-wastedisposal container.Cleansing the contaminated area thoroughly withwater after removal.

Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and Use necessarypersonal protective equipment as described in "8.EXPOSURE CONTROLS AND PERSONAL

No information available

Pay attention not to cause the influence on theenvironment by discharging into rivers.This product is water pollutant. Prevent soilcontamination, or the product from flowing into thedrain systems.

Page 37: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2013/11/21, 3/4

Appearance Physical StateColourOdourpH

Initial Boiling Point andBoiling RangesFlash PointAuto-Ignition

Section 10 - STABILITY AND REACTIVITYStability

Possibility of HazardousReactionConditions to AvoidHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute Toxicity

Section 12 - ECOLOGICAL INFORMATIONEnvironmentalHazards

Ecotoxicity

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaUN No.Marine PollutantRegulatoryInformation by AirUN No.

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaUN No.Marine PollutantRegulatoryInformation by AirUN No.

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

Not applicableNot applicable

Not applicable

No information availableThis information is furnished without warrantyexpress or implied.

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

Not applicableNot applicable

Not applicableNot applicable

Not applicable

Not applicable

No information available

For disposal, conform with the standards providedby related laws and local public bodies.Commission the authorized waste disposalcompany, or a local public body who conducts thedisposal, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

Not applicable

The material is stable under storage and handlingconditions comprised with the regulations.No data available

No data availableNo data available

No information available

No information available

pinkslight odorNo data availableNo information available

no data availableNo information available

liquid (viscous liquid)

Page 38: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2013/11/21, 4/4

This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

Page 39: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2012/1/13, 1/4

Preparation Date  2012/01/13Revision Date 2016/01/22

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct NameProduct CodeCompany NameAddressCompany ContactPhone NumberEmergency PhoneNumberFax NumberMail AddressRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Glycerin 11.5% CH2OHCH

(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Ethylene glycol 5% HOCH2CH2OH

(2)-230 Existing 107-21-1

Thiodiethylene glycol 9% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Triethanolamine 0.7% N(CH2CH2OH)3

(2)-308 Existing 102-71-6

Impurities and/or Stabilizing Additives No information availablewhich Contribute to the Classification

Section 4 - FIRST AID MEASURESInhalation

Skin Contact

Eye Contact

Ingestion

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

048-928-6668048-928-6668

048-928-9190

Safety Data Sheet (SDS)

WDR21-SWDR21S0001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT I

[email protected]

LR7-S,BL77-S,BL77FS-S

No classification standards applicable

mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

If breathing is difficult, move affected person tothe open air. Keep him or her at rest to alloweasier breathing.Get medical advice and attention if you feel unwell.

Wash with soap and plenty of water.If skin irritation or rash occurs: Get medicaladvice and attention.Wash eyes carefully for several minutes withwater. Take off contact lenses if easily removed,and continue to wash eyes afterwards.When the ocular stimulation lasts, Seek medicaltreatment and advice.Rinse a mouth. Don't make vomit by force.Get medical advice and attention if you feel unwell.

Carbon dioxide, dry chemicals, water sprinkling, andgeneral foam extinguishing agents

Page 40: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2012/1/13, 2/4

Section 6 - ACCIDENTAL RELEASE MEASURESPersonal Precautions,Protective Equipment andEmergency ProceduresEnvironmentalPrecautions

Decontamination/Absorption/Sweeping/Vacuming/Neutralization

Methods and Equipmentfor Containment andCleaning upPrevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Local and GeneralVentilation

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixtures

Storage PrecautionaryStatements

Technical Measures

ImcompatibleSubstances orMixturesStorage Conditions

Material Used inPackaging/Containers

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

RespiratoryProtectionEye Protection

Specific Hygine Measures

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

No information available

Pay attention not to cause the influence on theenvironment by discharging into rivers.This product is water pollutant. Prevent soilcontamination, or the product from flowing into thedrain systems.Collect the material into a disposal container bysucking up or sweeping up.

Absorb spills with inert materials (such as dry sandor soil) and collect them into chemical-wastedisposal container.Cleansing the contaminated area thoroughly withwater after removal.

Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and Use necessarypersonal protective equipment as described in "8.EXPOSURE CONTROLS AND PERSONALProvide local ventilations and a full ventilationsystem as described in "8. EXPOSURECONTROLS AND PERSONAL PROTECTION."Avoid the contact with eyes.

Wash hands thoroughly after handling.Avoid swallowingAvoid high temperature and direct sunlight.Refer to "10. STABILITY AND REACTIVITY"

The storage facility should be privided withnecessary lighting, lighting equipment, andventilator to store and handle dangerous goods.Refer to "10. STABILITY AND REACTIVITY"

Have containers keep away from direct sunlightand heat.Keep away from heat.Store locked up.Packaging materials and containers are notlegislated, but use sturdy and closed-typecontainers.

A general proper ventilation is enough to controlconcentration in air.No information available

Use an adequate personal eye protector.Goggles (ordinary glass type, ordinary glass typewith side shields, and goggle type)Wash hands thoroughly after handling.

Page 41: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2012/1/13, 3/4

Appearance Physical StateColourOdourpH

Initial Boiling Point andBoiling RangesFlash PointAuto-Ignition

Section 10 - STABILITY AND REACTIVITYStability

Possibility of HazardousReactionConditions to AvoidHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute Toxicity

Section 12 - ECOLOGICAL INFORMATIONEnvironmentalHazards

Ecotoxicity

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaUN No.Marine PollutantRegulatoryInformation by AirUN No.

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaUN No.Marine PollutantRegulatoryInformation by AirUN No.

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

liquid (viscous liquid)skyblueslight odorNo data availableNo information available

no data availableNo information available

The material is stable under storage and handlingconditions comprised with the regulations.No data available

No data availableNo data available

No information available

No information available

No information available

For disposal, conform with the standards providedby related laws and local public bodies.Commission the authorized waste disposalcompany, or a local public body who conducts thedisposal, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

Not applicableNot applicableNot applicable

Not applicableNot applicable

Not applicable

Not applicableNot applicableNot applicable

Not applicable

No information availableThis information is furnished without warrantyexpress or implied.

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

Page 42: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-F, PENTEL CO., LTD., 1, 2012/1/13, 4/4

This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

Page 43: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-CA, PENTEL CO., LTD., 1, 2016/07/21, 1/5

Preparation Date  2016/07/21

Section 1 - CHEMICALS AND COMPANY IDENTIFICATIONChemical IdentifierProduct CodeCompany NameAddressCompany ContactPhone NumberFax NumberMail AddressEmergency PhoneNumberRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Health Hazards

GHS Label Elements

Symbols

Signal WordHazard Statements

PrecautionaryStatementsPreventionPrecautionaryStatements

Wash hand thoroughly after handling.(P264)Wash eye thoroughly after handling.(P264)Do not eat, drink or smoke when using thisproduct.(P270)

H320 Causes eye irritationH332 Harmful if inhaledH371 May cause damage to respiratoryapparatus,heart,kidney,central nervous systemH373 May cause damage to respiratoryapparatus,heart,central nervous system throughprolonged or repeated exposure

Do not breathe mist, vapours and spray.(P260)

Avoid breathing mist, vapours and spray.(P261)

Acute toxicity - inhalation (mist) Category 4Serious eye damage/eye irritation Category 2BSpecific target organ toxicity (single exposure)Category 2(respiratoryapparatus,heart,kidney,central nervous system)Specific target organ toxicity (repeated exposure)Category 2(respiratory apparatus,heart,centralnervous system)Other hazards than mentioned above are Notapplicable or Classification not possible.

Warning

[email protected]

ink

BL77-CAX,BL77-CABR,LR7-CAX,LR7CABRPAF

Safety Data Sheet (SDS)

WDR21-CAWDR21CA001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT I

Page 44: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-CA, PENTEL CO., LTD., 1, 2016/07/21, 2/5

ResponsePrecautionaryStatements

StoragePrecautionaryStatementsDisposalPrecautionaryStatements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Glycerin 11.5% CH2OHCH

(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Ethylene glycol 5% HOCH2CH2OH

(2)-230 Existing 107-21-1

Thiodiethylene glycol 9% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Triethanolamine 0.7% N(CH2CH2OH)3

(2)-308 Existing 102-71-6

Impurities and/orStabilizing Additives whichContribute to the

Section 4 - FIRST AID MEASURESInhalation

Skin Contact

Eye Contact

Ingestion

Get medical advice and attention if you feel unwell.

Rinse mouth. Do NOT induce vomiting.

No information available

If breathing is difficult, move affected person tothe open air. Keep him or her at rest to alloweasier breathing.

Get medical advice and attention if you feel unwell.

Wash with plenty of soap and water.If skin irritation or rash occurs, get medical adviceand attention.Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do.Continue rinsing.

Mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

IF exposed or concerned: Call a POISONCENTER/doctor/...(P308+P311)Call a doctor if you feel unwell.(P312)Get medical advice and attention if you feelunwell.(P314)If eye irritation persists: Get medical advice andattention.(P337+P313)Store locked up.(P405)

Dispose of contents and container in accordancewith local, regional and national regulations (to bespecified).(P501)

Use only outdoors or in a well-ventilatedarea.(P271)IF INHALED: Remove to fresh air and keep at restin a position comfortable forbreathing.(P304+P340)IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, ifpresent and easy to do. Continuerinsing.(P305+P351+P338)

Page 45: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-CA, PENTEL CO., LTD., 1, 2016/07/21, 3/5

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Protection of Fire Figther

Section 6 - ACCIDENTAL RELEASE MEASURESEnvironmentalPrecautions

Methods and Equipmentfor Containment andCleaning upPrevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixturesSpecific HygineMeasures

Storage PrecautionaryStatements

Technical Measures

Material Used inPackaging/Containers

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

RespiratoryProtectionHand ProtectionEye ProtectionSkin and BodyProtection

Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAppearance Physical State

Use personal eye protection as required.Use personal protective clothing and faceprotection as required.

liquid

Keep away from heat.Store locked up.Packaging materials and containers are notlegislated, but use sturdy and closed-typecontainers.

Good general ventilation should be sufficient tocontrol airborne levels.Use personal respiratory equipment as required.

Use personal gloves as required.

Wash hand thoroughly after handling.Avoid swallowing.Protect from high temperature and direct sunlight.Refer to "Section 10 - STABILITY ANDREACTIVITY".

Wash hand thoroughly after handling.

Have containers keep away from direct sunlightand heat.

This product is water pollutant and should beprevented from contaminating soil or from enteringsewage and drainage systems and bodies of water.After removal, flush contaminated area thoroughlywith water.

Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and use necessarypersonal protective equipment as described in"Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION".Avoid contact with eyes.

Get medical advice and attention if you feel unwell.

Small fires: Dry chemical, CO2, water spray orregular foam.In fire fighting, wear respiratory protection andchemical protective clothing.

Pay attention not to cause the influence on theenvironment by discharging into rivers.

Page 46: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-CA, PENTEL CO., LTD., 1, 2016/07/21, 4/5

FormColour

OdourOdour thresholdpHMelting Point/FreezingPointInitial Boiling Point andBoiling RangesFlash PointEvaporation RateFlammability (solid, gas)Flammability or ExplosiveLimits

Lower Limit

Upper LimitVapour PressureVapour DensitySpecific Gravity (Density)Partition Coefficient : n-Octanol/WaterAuto-IgnitionDecompositionTemperatureViscosityKinematic viscosity

Section 10 - STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of HazardousReactionConditions to AvoidImcompatible Substancesor MixturesHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute ToxicitySkin Corrosion/IrritationSerious eye damage/eyeirritationRespiratory or SkinSensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicitySpecific target organtoxicity (single exposure)Specific target organtoxicity (repeatedexposure)Aspiration Hazard

Section 12 - ECOLOGICAL INFORMATIONHazardous to the aquaticenvironment (acute)Hazardous to the aquaticenvironment (long-term)

No data available

No data available

No data available

No data available

No data available

No data availableNo data available

No data available

No data availableNo data availableNo data available

No data availableNo data available

No data availableNo data available

No data available

No information available

No data available

No data availableNo data available

No data availableNo data available

No data available

No data availableNo data available

No data availableNo data availableNo data availableNo data available

No data availableNo data availableNo data available

No data available

No data availableNo data available

liquid (viscous liquid)Blue Blackslight odor

Page 47: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-CA, PENTEL CO., LTD., 1, 2016/07/21, 5/5

Hazardous to the ozonelayer

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Emergency ResponseGuide Number

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

Not applicable

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

This information is furnished without warrantyexpress or implied.This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

No information available

Not applicable

Not applicable

Not applicable

Not applicableNot applicable

Not applicable

Disposal should be in accordance with applicableregulations and standards by the respective localgovernments.Commission a waste disposal company, or a localpublic body who are licensed by local or regionalgovernment, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

Not applicableNot applicable

No data available

Page 48: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-E, PENTEL CO., LTD., 1, 2016/07/21, 1/5

Preparation Date  2016/07/21

Section 1 - CHEMICALS AND COMPANY IDENTIFICATIONChemical IdentifierProduct CodeCompany NameAddressCompany ContactPhone NumberFax NumberMail AddressEmergency PhoneNumberRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Health Hazards

GHS Label Elements

Symbols

Signal WordHazard Statements

PrecautionaryStatementsPreventionPrecautionaryStatements

H373 May cause damage to respiratoryapparatus,heart,central nervous system throughprolonged or repeated exposure

Do not breathe mist, vapours and spray.(P260)

Avoid breathing mist, vapours and spray.(P261)Wash hand thoroughly after handling.(P264)Wash eye thoroughly after handling.(P264)Do not eat, drink or smoke when using thisproduct.(P270)

Specific target organ toxicity (repeated exposure)Category 2(respiratory apparatus,heart,centralnervous system)Other hazards than mentioned above are Notapplicable or Classification not possible.

WarningH320 Causes eye irritationH332 Harmful if inhaledH371 May cause damage to respiratoryapparatus,heart,kidney,central nervous system

03-5695-7210

ink

BL77-EX,BL77-EBR,LR7-EX,LR7EBRPAF

Acute toxicity - inhalation (mist) Category 4Serious eye damage/eye irritation Category 2BSpecific target organ toxicity (single exposure)Category 2(respiratoryapparatus,heart,kidney,central nervous system)

Safety Data Sheet (SDS)

WDR21-EWDR21E0001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT [email protected]

Page 49: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-E, PENTEL CO., LTD., 1, 2016/07/21, 2/5

ResponsePrecautionaryStatements

StoragePrecautionaryStatementsDisposalPrecautionaryStatements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Glycerin 11.5% CH2OHCH

(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Ethylene glycol 5% HOCH2CH2OH

(2)-230 Existing 107-21-1

Thiodiethylene glycol 9% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Triethanolamine 0.7% N(CH2CH2OH)3

(2)-308 Existing 102-71-6

Impurities and/orStabilizing Additives whichContribute to the

Section 4 - FIRST AID MEASURESInhalation

Skin Contact

Eye Contact

Get medical advice and attention if you feel unwell.

No information available

If breathing is difficult, move affected person tothe open air. Keep him or her at rest to alloweasier breathing.

Get medical advice and attention if you feel unwell.

Wash with plenty of soap and water.If skin irritation occurs: Get medical advice andattention.Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do.Continue rinsing.

If eye irritation persists: Get medical advice andattention.(P337+P313)Store locked up.(P405)

Dispose of contents and container in accordancewith local, regional and national regulations (to bespecified).(P501)

Mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

Use only outdoors or in a well-ventilatedarea.(P271)IF INHALED: Remove to fresh air and keep at restin a position comfortable forbreathing.(P304+P340)IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, ifpresent and easy to do. Continuerinsing.(P305+P351+P338)IF exposed or concerned: Call a POISONCENTER/doctor/...(P308+P311)Call a doctor if you feel unwell.(P312)Get medical advice and attention if you feelunwell.(P314)

Page 50: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-E, PENTEL CO., LTD., 1, 2016/07/21, 3/5

Ingestion

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Protection of Fire Figther

Section 6 - ACCIDENTAL RELEASE MEASURESEnvironmentalPrecautions

Methods and Equipmentfor Containment andCleaning upPrevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixturesSpecific HygineMeasures

Storage PrecautionaryStatements

Technical Measures

Material Used inPackaging/Containers

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

RespiratoryProtectionHand ProtectionEye Protection Wear eye protection.

Protection glasses (ordinary glasses, ordinaryglasses with side shields, and goggles).Use personal eye protection as required.

Keep away from heat.Store locked up.Packaging materials and containers are notlegislated, but use sturdy and closed-typecontainers.

Good general ventilation should be sufficient tocontrol airborne levels.Use personal respiratory equipment as required.

Use personal gloves as required.

Wash hand thoroughly after handling.Avoid swallowing.Protect from high temperature and direct sunlight.Refer to "Section 10 - STABILITY ANDREACTIVITY".

Wash hand thoroughly after handling.

Have containers keep away from direct sunlightand heat.

This product is water pollutant and should beprevented from contaminating soil or from enteringsewage and drainage systems and bodies of water.After removal, flush contaminated area thoroughlywith water.

Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and use necessarypersonal protective equipment as described in"Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION".Avoid contact with eyes.

Rinse mouth. Do NOT induce vomiting.Get medical advice and attention if you feel unwell.

Small fires: Dry chemical, CO2, water spray orregular foam.In fire fighting, wear respiratory protection andchemical protective clothing.

Pay attention not to cause the influence on theenvironment by discharging into rivers.

Page 51: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-E, PENTEL CO., LTD., 1, 2016/07/21, 4/5

Skin and BodyProtection

Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAppearance Physical State

FormColour

OdourOdour thresholdpHMelting Point/FreezingPointInitial Boiling Point andBoiling RangesFlash PointEvaporation RateFlammability (solid, gas)Flammability or ExplosiveLimits

Lower Limit

Upper LimitVapour PressureVapour DensitySpecific Gravity (Density)Partition Coefficient : n-Octanol/WaterAuto-IgnitionDecompositionTemperatureViscosityKinematic viscosity

Section 10 - STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of HazardousReactionConditions to AvoidImcompatible Substancesor MixturesHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute ToxicitySkin Corrosion/IrritationSerious eye damage/eyeirritationRespiratory or SkinSensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicitySpecific target organtoxicity (single exposure)Specific target organtoxicity (repeatedexposure)Aspiration Hazard

No data availableNo data availableNo data available

No data available

No data available

No data available

No information availableNo data availableNo data available

No data available

No data available

No data available

No data availableNo data availableNo data available

No data availableNo data available

No data availableNo data availableNo data available

No data availableNo data available

No data available

No data availableNo data availableNo data availableNo data available

No data availableNo data available

Brownslight odorNo data availableNo data availableNo data available

No data available

Use personal protective clothing and faceprotection as required.

liquidliquid (viscous liquid)

Page 52: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-E, PENTEL CO., LTD., 1, 2016/07/21, 5/5

Section 12 - ECOLOGICAL INFORMATIONHazardous to the aquaticenvironment (acute)Hazardous to the aquaticenvironment (long-term)Hazardous to the ozonelayer

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Emergency ResponseGuide Number

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

Not applicable

Not applicable

Not applicable

This information is furnished without warrantyexpress or implied.This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

No information available

Not applicableNot applicable

Not applicable

Not applicable

Not applicable

Not applicable

No data available

No data available

Disposal should be in accordance with applicableregulations and standards by the respective localgovernments.

When commissioning the disposal to a disposalcompany, notify the danger and toxicity thoroughlyto the company.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

No data available

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

Page 53: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-K, PENTEL CO., LTD., 1, 2016/07/21, 1/5

Preparation Date  2016/07/21

Section 1 - CHEMICALS AND COMPANY IDENTIFICATIONChemical IdentifierProduct CodeCompany NameAddressCompany ContactPhone NumberFax NumberMail AddressEmergency PhoneNumberRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Health Hazards

GHS Label Elements

Symbols

Signal WordHazard Statements

PrecautionaryStatementsPreventionPrecautionaryStatements

H373 May cause damage to respiratoryapparatus,heart,central nervous system throughprolonged or repeated exposure

Do not breathe mist, vapours and spray.(P260)

Avoid breathing mist, vapours and spray.(P261)Wash hand thoroughly after handling.(P264)Wash eye thoroughly after handling.(P264)Do not eat, drink or smoke when using thisproduct.(P270)

Specific target organ toxicity (repeated exposure)Category 2(respiratory apparatus,heart,centralnervous system)Other hazards than mentioned above are Notapplicable or Classification not possible.

WarningH320 Causes eye irritationH332 Harmful if inhaledH371 May cause damage to respiratoryapparatus,heart,kidney,central nervous system

03-5695-7210

ink

BL77-KX,BL77-KBR,LR7-KX,LR7KBRPAF

Acute toxicity - inhalation (mist) Category 4Serious eye damage/eye irritation Category 2BSpecific target organ toxicity (single exposure)Category 2(respiratoryapparatus,heart,kidney,central nervous system)

Safety Data Sheet (SDS)

WDR21-KWDR21K0001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT [email protected]

Page 54: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-K, PENTEL CO., LTD., 1, 2016/07/21, 2/5

ResponsePrecautionaryStatements

StoragePrecautionaryStatementsDisposalPrecautionaryStatements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Glycerin 11.5% CH2OHCH

(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Ethylene glycol 5% HOCH2CH2OH

(2)-230 Existing 107-21-1

Thiodiethylene glycol 9% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Triethanolamine 0.7% N(CH2CH2OH)3

(2)-308 Existing 102-71-6

Impurities and/orStabilizing Additives whichContribute to the

Section 4 - FIRST AID MEASURESInhalation

Skin Contact

Eye Contact

Get medical advice and attention if you feel unwell.

No information available

If breathing is difficult, move affected person tothe open air. Keep him or her at rest to alloweasier breathing.

Get medical advice and attention if you feel unwell.

Wash with plenty of soap and water.If skin irritation or rash occurs, get medical adviceand attention.Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do.Continue rinsing.

If eye irritation persists: Get medical advice andattention.(P337+P313)Store locked up.(P405)

Dispose of contents and container in accordancewith local, regional and national regulations (to bespecified).(P501)

Mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

Use only outdoors or in a well-ventilatedarea.(P271)IF INHALED: Remove to fresh air and keep at restin a position comfortable forbreathing.(P304+P340)IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, ifpresent and easy to do. Continuerinsing.(P305+P351+P338)IF exposed or concerned: Call a POISONCENTER/doctor/...(P308+P311)Call a doctor if you feel unwell.(P312)Get medical advice and attention if you feelunwell.(P314)

Page 55: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-K, PENTEL CO., LTD., 1, 2016/07/21, 3/5

Ingestion

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Protection of Fire Figther

Section 6 - ACCIDENTAL RELEASE MEASURESEnvironmentalPrecautions

Methods and Equipmentfor Containment andCleaning upPrevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixturesSpecific HygineMeasures

Storage PrecautionaryStatements

Technical Measures

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

RespiratoryProtectionHand ProtectionEye ProtectionSkin and BodyProtection

Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAppearance Physical State

FormColour

Use personal protective clothing and faceprotection as required.

liquidliquid (viscous liquid)Lime Green

Keep away from heat.Store locked up.

Good general ventilation should be sufficient tocontrol airborne levels.Use personal respiratory equipment as required.

Use personal gloves as required.Use personal eye protection as required.

Wash hand thoroughly after handling.Avoid swallowing.Protect from high temperature and direct sunlight.Refer to "Section 10 - STABILITY ANDREACTIVITY".

Wash hand thoroughly after handling.

Have containers keep away from direct sunlightand heat.

This product is water pollutant and should beprevented from contaminating soil or from enteringsewage and drainage systems and bodies of water.After removal, flush contaminated area thoroughlywith water.

Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and use necessarypersonal protective equipment as described in"Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION".Avoid contact with eyes.

Rinse mouth. Do NOT induce vomiting.Get medical advice and attention if you feel unwell.

Small fires: Dry chemical, CO2, water spray orregular foam.In fire fighting, wear respiratory protection andchemical protective clothing.

Pay attention not to cause the influence on theenvironment by discharging into rivers.

Page 56: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-K, PENTEL CO., LTD., 1, 2016/07/21, 4/5

OdourOdour thresholdpHMelting Point/FreezingPointInitial Boiling Point andBoiling RangesFlash PointEvaporation RateFlammability (solid, gas)Flammability or ExplosiveLimits

Lower Limit

Upper LimitVapour PressureVapour DensitySpecific Gravity (Density)Partition Coefficient : n-Octanol/WaterAuto-IgnitionDecompositionTemperatureViscosityKinematic viscosity

Section 10 - STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of HazardousReactionConditions to AvoidImcompatible Substancesor MixturesHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute ToxicitySkin Corrosion/IrritationSerious eye damage/eyeirritationRespiratory or SkinSensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicitySpecific target organtoxicity (single exposure)Specific target organtoxicity (repeatedexposure)Aspiration Hazard

Section 12 - ECOLOGICAL INFORMATIONHazardous to the aquaticenvironment (acute)Hazardous to the aquaticenvironment (long-term)Hazardous to the ozonelayer

No data available

No data available

No data available

No data available

No data available

No data available

No data available

No data availableNo data availableNo data availableNo data available

No data available

No data availableNo data available

No data available

No information availableNo data available

No data availableNo data available

No data availableNo data available

No data availableNo data available

No data available

No data availableNo data availableNo data availableNo data availableNo data available

No data availableNo data available

No data available

No data availableNo data availableNo data available

slight odorNo data available

Page 57: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-K, PENTEL CO., LTD., 1, 2016/07/21, 5/5

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Emergency ResponseGuide Number

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property This information is furnished without warranty

express or implied.This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

No information available

Not applicable

Not applicable

Not applicableNot applicable

Not applicable

Not applicable

Commission a waste disposal company, or a localpublic body who are licensed by local or regionalgovernment, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

Not applicable

Not applicableNot applicable

Not applicable

Disposal should be in accordance with applicableregulations and standards by the respective localgovernments.

Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.

Page 58: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-S3, PENTEL CO., LTD., 1, 2016/07/21, 1/5

Preparation Date  2016/07/21

Section 1 - CHEMICALS AND COMPANY IDENTIFICATIONChemical IdentifierProduct CodeCompany NameAddressCompany ContactPhone NumberFax NumberMail AddressEmergency PhoneNumberRecommended Useand Restriction onUse

Section 2 - HAZARDS IDENTIFICATIONGHS Classification

Health Hazards

GHS Label Elements

Symbols

Signal WordHazard Statements

PrecautionaryStatementsPreventionPrecautionaryStatements

H373 May cause damage to respiratoryapparatus,heart,central nervous system throughprolonged or repeated exposure

Do not breathe mist, vapours and spray.(P260)

Avoid breathing mist, vapours and spray.(P261)Wash hand thoroughly after handling.(P264)Wash eye thoroughly after handling.(P264)Do not eat, drink or smoke when using thisproduct.(P270)

Specific target organ toxicity (repeated exposure)Category 2(respiratory apparatus,heart,centralnervous system)Other hazards than mentioned above are Notapplicable or Classification not possible.

WarningH320 Causes eye irritationH332 Harmful if inhaledH371 May cause damage to respiratoryapparatus,heart,kidney,central nervous system

03-5695-7210

ink

BL77-S3X,BL77-S3BR,LR7-S3X,LR7S3BRPAF

Acute toxicity - inhalation (mist) Category 4Serious eye damage/eye irritation Category 2BSpecific target organ toxicity (single exposure)Category 2(respiratoryapparatus,heart,kidney,central nervous system)

Safety Data Sheet (SDS)

WDR21-S3WDR21S3001PENTEL CO., LTD.7-2,KOAMICHO,NIHONBASHI,CHUO-KU,TOKYOQUALITY ASSURANCE DEPARTMENT [email protected]

Page 59: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-S3, PENTEL CO., LTD., 1, 2016/07/21, 2/5

ResponsePrecautionaryStatements

StoragePrecautionaryStatementsDisposalPrecautionaryStatements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSDistinction of Substanceor Mixture

ENCS No. ISHL No.Glycerin 11.5% CH2OHCH

(OH)CH2OH

(2)-242,(7)-338

Existing 56-81-5

Ethylene glycol 5% HOCH2CH2OH

(2)-230 Existing 107-21-1

Thiodiethylene glycol 9% HOCH2CH2SCH2CH2OH

(2)-470 Existing 111-48-8

Triethanolamine 0.7% N(CH2CH2OH)3

(2)-308 Existing 102-71-6

Impurities and/orStabilizing Additives whichContribute to the

Section 4 - FIRST AID MEASURESInhalation

Skin Contact

Eye Contact

Get medical advice and attention if you feel unwell.

No information available

If breathing is difficult, move affected person tothe open air. Keep him or her at rest to alloweasier breathing.

Get medical advice and attention if you feel unwell.

Wash with plenty of soap and water.If skin irritation or rash occurs, get medical adviceand attention.Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do.Continue rinsing.

If eye irritation persists: Get medical advice andattention.(P337+P313)Store locked up.(P405)

Dispose of contents and container in accordancewith local, regional and national regulations (to bespecified).(P501)

Mixture

Chemical Name orGeneric Name

Concentration or ItsRanges

FormulaENCS No./ISHL No.

CAS RN

Use only outdoors or in a well-ventilatedarea.(P271)IF INHALED: Remove to fresh air and keep at restin a position comfortable forbreathing.(P304+P340)IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, ifpresent and easy to do. Continuerinsing.(P305+P351+P338)IF exposed or concerned: Call a POISONCENTER/doctor/...(P308+P311)Call a doctor if you feel unwell.(P312)Get medical advice and attention if you feelunwell.(P314)

Page 60: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-S3, PENTEL CO., LTD., 1, 2016/07/21, 3/5

Ingestion

Section 5 - FIRE FIGHTING MEASURESExtinguishing Media

Protection of Fire Figther

Section 6 - ACCIDENTAL RELEASE MEASURESEnvironmentalPrecautions

Methods and Equipmentfor Containment andCleaning upPrevention Measures forSecondary Accidents

Section 7 - HANDLING AND STORAGEHandling Technical Measures

Precautions for SafeHandling

Prevents Handling ofImcompatibleSubstances orMixturesSpecific HygineMeasures

Storage PrecautionaryStatements

Technical Measures

Material Used inPackaging/Containers

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering Controls

Personal ProtectiveEquipment

RespiratoryProtectionHand ProtectionEye ProtectionSkin and BodyProtection

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Use personal eye protection as required.Use personal protective clothing and faceprotection as required.

Keep away from heat.Store locked up.Packaging materials and containers are notlegislated, but use sturdy and closed-typecontainers.

Good general ventilation should be sufficient tocontrol airborne levels.Use personal respiratory equipment as required.

Use personal gloves as required.

Wash hand thoroughly after handling.Avoid swallowing.Protect from high temperature and direct sunlight.Refer to "Section 10 - STABILITY ANDREACTIVITY".

Wash hand thoroughly after handling.

Have containers keep away from direct sunlightand heat.

This product is water pollutant and should beprevented from contaminating soil or from enteringsewage and drainage systems and bodies of water.After removal, flush contaminated area thoroughlywith water.

Prevent flowing into drain, sewage, basement, andclosed area.Remove thoroughly since the smooth and slipperysurface will be formed on the floor.

Provide ventilation system and use necessarypersonal protective equipment as described in"Section 8 - EXPOSURE CONTROLS /PERSONAL PROTECTION".Avoid contact with eyes.

Rinse mouth. Do NOT induce vomiting.Get medical advice and attention if you feel unwell.

Small fires: Dry chemical, CO2, water spray orregular foam.In fire fighting, wear respiratory protection andchemical protective clothing.

Pay attention not to cause the influence on theenvironment by discharging into rivers.

Page 61: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-S3, PENTEL CO., LTD., 1, 2016/07/21, 4/5

Appearance Physical StateFormColour

OdourOdour thresholdpHMelting Point/FreezingPointInitial Boiling Point andBoiling RangesFlash PointEvaporation RateFlammability (solid, gas)Flammability or ExplosiveLimits

Lower Limit

Upper LimitVapour PressureVapour DensitySpecific Gravity (Density)Partition Coefficient : n-Octanol/WaterAuto-IgnitionDecompositionTemperatureViscosityKinematic viscosity

Section 10 - STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of HazardousReactionConditions to AvoidImcompatible Substancesor MixturesHazardous DecompositionProducts

Section 11 - TOXICOLOGICAL INFORMATIONAcute ToxicitySkin Corrosion/IrritationSerious eye damage/eyeirritationRespiratory or SkinSensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicitySpecific target organtoxicity (single exposure)Specific target organtoxicity (repeatedexposure)Aspiration Hazard

Section 12 - ECOLOGICAL INFORMATIONHazardous to the aquaticenvironment (acute)

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liquidliquid (viscous liquid)Turquoise Blueslight odor

Page 62: Pentel Stationery of Canada - Safety Data Sheet (SDS ...R).pdfWDR11-A, PENTEL CO., LTD., 4, 2014/10/29, 1/5 Preparation Date 2013/04/20 Revision Date 2016/01/12 Section 1 - CHEMICALS

WDR21-S3, PENTEL CO., LTD., 1, 2016/07/21, 5/5

Hazardous to the aquaticenvironment (long-term)Hazardous to the ozonelayer

Section 13 - DISPOSAL CONSIDERATIONSResidual Waste

Contaminated Containerand Packaging

Section 14 - TRANSPORT INFORMATIONInternational Regulations Regulatory

Information by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Regulations in Japan RegulatoryInformation by Roador RailRegulatoryInformation by SeaMarine PollutantTransport in bulkaccording toMARPOL73/78,Annex Ⅱ,andthe IBC codeRegulatoryInformation by Air

Emergency ResponseGuide Number

Section 15 - REGULATORY INFORMATION

Section 16 - OTHER INFORMATIONInformation ContactOther Property

Not applicable

This information is furnished without warrantyexpress or implied.This information is believed to be accurate to thebest knowledge of PENTEL Co., Ltd. but notassumes leagal responsibility for use of or relianceupon this information.

No information available

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Disposal should be in accordance with applicableregulations and standards by the respective localgovernments.Commission a waste disposal company, or a localpublic body who are licensed by local or regionalgovernment, to dispose of the material.Recycle containers after cleansing, or carry outthe disposal under the related laws and regulationsand the standards of the local governments.

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Regulatory information with regard to this product in your country or in your region should beexamined by your own responsibility.