PELA INC - TECHNICAL MEMORANDUM NO. 3 FOR REMEDIAL ... · Number TICs found: Contract: SAS No.: SDG...

PELA•:;&.-.. " • ' ' ' 48

I: TECHNICAL MEMORANDUM NO. 3

FOR REMEDIAL INVESTIGATION/FEASIBILITY STUDY

CITY DISPOSAL CORPORATION LANDFILL

(DUNN LANDFILL)

(PELA Reference No. 495201)

Appendix B.

Results of Analyses of Soil Samples and

Ground-Water Samples - Technical Report C

Volume I of II, Part 2 of 2

CA1889-CA1892, CA1907-CA1908

CA1910, CA2144-CA2148

CA2152-CA2153, CA2266, CA2282

February, 1990

P. E. LaMoreaux & Associates, Inc. —

ETC

SAMPLE DATA

00

IBSEMIVOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO,

Lab Name: ETCNJ

Lab Code: Case No.:

Contract

SA5 No.

Ma t P i x : (soil /wa t e p ) WATER

Sample wt/vol: 910.0 Cg/mL) ML

Level: (low/mod) LOUt

Moisture: not dec. dec.

Extract ion: (SepF/Cont /Sonc ) CONT

GPC Cleanup: CY/N) N pH:

SDG No.:

Lab Sample ID: CA1889C

Lab File ID: >G9052

Date Received:

Date Extracted: 10/12x89

Date Analyzed: 11/15/89

D i l u t i o n Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:Cug/L or ug/Kg) UG/L Q

108-95-2 ———1 1 l-4A-4-~-._95-57-8 ————541-73-1 ———106-46-7 ———100-51-6 ———95-50-1 ————95-48-7 ————108-60-1 ———106-44-5 ———A91 -f.A-7--~-67-72-1 ————98-95-3 ————78-59-1 ————88-75-5 ————105-67-9 ———65-85-0 ————111-91-1 ———

1 9FI-R9-1 ---_91-20-3 ————106-47-8 ———

59-50-7 ————91-57-6 ————77-47-4 ————

95-95-4 ————Q 1 CO ^Vl-7d-/-----88-74-4 ————131-11-3 ———208-96-8 ———606-20-2 ———

1----Phenol 1——— bis(2-Chloroethyl )ether ____ 1— — 2-Ch loropheno 1 1

—— -1 P4-Dich lorobenzene „,.,,__ I—— -Benzyl alcohol 1-- — 1 ,2-Dichlorobenzene , 1——— 2-Methvl phenol 1----bis(2-Chloroisopropyl)ether_j——— 4-Methyl phenol 1----N-Nitroso-d i-n-propy lamine _ 1——— Hexach loroethane , ,, „ ,,„,._..,_,. 1— --Nitrobenzene 1---- Isophorone 1----2-Nit rophenn 1 1----2 , 4-Dimethy Ipheno 1 1----Benzole acid 1----bis(2-Ch 1 o roe thoxy) me thane _ 1_ —— 2,4-Diehlorophanol....,, ... ... 1----Ir2 .4-Trich larohanzane 1__ — Naphthalene , ni 1- —— 4-Th loroani 1 ina , 1———— Havach larohutadiena __. ,. 1— __4-Ch loro-3-methyl phenol ____ 1__ — 9-r1«thylnaph thai ana 1----Hexach lorocyc 1 open tad iene __ 1———— 9,AJA-Trieh Inrophanol 1—— __9r4r5-Trieh Inrophanol 1__-_9-rh loronaphthalana t_-_-2-Ni t roan i 1 ine inp, M_ 1. —— -Dimathylphthalata 1----Acenaphthylana iiiiiiiiiimn 1——— -2 ,6-Din i t rota 1 uana ,_ 1

1

111111111111111111111111111111115511111111111111111111551155111111

1IIIIUIUIUIUtuIUIUIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU1

FORM I SU -1"654

1/87 Rev.

1 1CSEMIVOLATILE ORGAN ICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Matrix: (soiI/water) WATER


Leve 1: Clow/med) LOU

S Moisture: not dec. dec.

Extract ion: (SepF/Cont/Sonc) CONT

GPC Cleanup: (Y/N) N pH:

Contract:

SAS No.: SDQ No.:


Lab File ID: >G9052

Date Received: /

Date Extracted: 10/12/89


Dilution Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:Cug/L or ug/Kg) UG/L

99-09-2 ——————— 3-Nitroani 1 ine____________83-32-9-—-———-Acenaphthene______________51-28-5———————2,4-Dinitrophenol_________100-02-7——————4-Ni trophenol_____________132-64-9- ————— -Dibenzofuran______________121-14-2 —————— -2,4-Dini tro toluene________84-66-2———————Diethylphthalate__________7005-72-3———-—4-Chlorophenyl-phenylether_86-73-7———————Fluorene_________________100-01-6 —————— 4-Ni t roan i 1 ine____________534-52-1—---——4,6-Dinitro-2-methyIpheno1_86-30-6---------N-Nitrosodiphenylamine (1)_101-55-3-- —— —— 4-Bromopheny1-pheny1 ether__118-74-1--------Hexachlorobenzene_________87-86-5——---——Pentachlorophenol_________85-01-8—---—--Phenanthrone______________120-12-7—————--Anthracene________________84-74-2- ———— —— Di-n-butylphthalate________206-44-0- —————— Fluoranthene______________129-00-0- ——— - — Pyrene_____________________39-68-7——————--Butylbenzylphtha late_______91-94-1———-——3,3'-Dichlorobenzidine_____56-55-3--—-———Benzota)anthracene________218-01-9- — - ——— Chrysene_________________117-81-7——————bisC2-Ethylhexyl )phthalate_117-84-0 —————— Di-n-octylphthalate________205-99-2 —————— -BenzoCb)f luoranthene_______207-08-9————--Benzo(k)fluoranthene_______50-32-8-----——BenzoCa)pyrene____________193-39-5------—Indeno(l,2,3-cd)pyrene_____53-70-3————---Dibenz(a,h)anthracene______191-24-2-—-——-8enzo(g,h , i)perylene_______

(1) - Cannot be separated from Diphenylamine

FORM I SU -2

5511555511111111115555111111551111111111112211111111111111111111

Q

IUIUIUIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

1/87 Rev.

5 55

IFSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

ERA SAMPLE NO.

Lab Name:ETCNJ

Lab Code: Case No.:

Matrix: CsoiI/water)UATER

Sample wt/vol: 910.0 Cg/mL)ML

Level: C low/mod) LOW

\ Moisture: not dec._____ dec.___

Extraction: (SepF/Cont/Sonc) CONT

GPC Cleanup: CY/N) N oH:

iNumber TICs found:

Contract:

SAS No.: SDG No.:


Lab File ID: >G9052

Date Received:

Date Extracted:10/12/89


Dilution Factor: /

CONCENTRATION UNITS:Cug/L or ug/Kg)UG/L

CAS NUMBER

01. 141-78-602.03.04. 10574-37-5

COMPOUND NAME

Acetic ac id, ethyl esterACETONE DIMERUNKNOWN2- Pen tone, 2 , 3-d i me thy 1-

RT

5.166.427.865.24

EST. CONC

690772211

iQ I

BJ 1BJ 1BJ lJ 1

iiii

i

i

,

i

i

•

,

i;

111

_____ 1

FORM I Sv-TIC 1/87 Rev.

TOTAL ION CHROtlPTOCRPMFile >C9e52

1688808-

1488800-

1288888-

1808888-

808888-

688000-•

408888-

288008-•

35.0-500.0 MU.

.... «M. ....

a I?iII !et

4 '

I

1 jil 'i» JI ji

i<

»

!

i ]r .•i

. j • i - i - ) •

CR1889C ,QC7009Z,Li

80,8 , 1200 , 1600 , 20,08

I

E- .t •t •i

t "| _\ 1 !! 1 =i •*•, S i $ 2

' * *7 i: ? 1 1£=! f * |

1 1 1 ? ?^B' ' "aV ' '28' ' "a'a" ' "s'6' ' Ve" ' V4"

Data File: >G9052::U3Name:Misc: CA1889C ,QC70092,L:M6, 910,2

Id File: IG0130::PFTitle: IFB/BNA, PP/BNALast Calibration: 89111? 12:26

Operator ID: PT1575Quant Time: 891115 13:15Injected at: 891115 07:14

Quant Output File: ^G9052::AQ

BTL*1B

557

Operator ID: PT1575Output File: ^G9052::AQData F i l e : >G9052::U3Name:Misc: CA1889C ,QC70092,L:M6, 910,2

ID File: IG0130::PFTitle: IFB/BNA, PP/BNALast C a l i b r a t i o n : 891115 12:26

Compound

QUANT REPORT

Quant Rev: 7 Quant TimeInjected at

Di lut ion Factor

Page 1

891115 13:15991115 07:14

1.00000

BTL#1B

R.T. Scan* Area Cone Units

1)3)5)12)17)18)32)36)50)52)54)65)67)73)

*d4-l,4-Dichlorobenzene2-Fluorophenol CSURR)Phenol-05 CSURR)N-Nitrosodi-n-propylamine

*d8-Naphtha leneNitrobenzene-05 CSURR)

*dlQ-Acenaphthene2-Fluorobiphenyl CSURR)Fluorene2 ,4,6-Tr ibromopneno 1 CSURR)

*dlO-Phenanthrene*d!2-ChryseneTerphenyl-D14 CSURR)

*d!2-Perylene

10.7.

10.12.14.12.19.17.22.22.24.32.29.36.

6545123541358792292928293229

34318631742752842779770191 A9161014140812621605

230417294849423810^9Q^T

462180214393170195224983

OC 1 T

36304138009566089124039187

406974

40334031

5540405840

.00

.20

.16

.00

.72

.00

.37404-.86.00.00.11.00

UG/MLUG/MLUG/MLUGi'ML -UG/MLUG/MLUG/MLUG/MLi i(~ •'Ml

UG/MLUG/MLUG/MLUG/MLUG/ML

9087943794909899

9596999383

* Compound is ISTD[-40-

358

Fil* >G90S2 CR1889C .QC70092 ,U tM6 , 9 Sc*n 73Bpk fib 9999 . . SUB NRM 5.16 min.

43

8060-

4000-

0-2

42 ™/*•• \ v6^4*,75 ' 3'0 35 40 4'S S'e 55 60 65 70

FiU NBS49K flc*tic »cid, •thyl **t*rBpk Hb 9999

43

8000-

4000-

0-",

2927/ "2

' 1 ^61 7,0

. 1 f'5 30 35 40 4 5 50 5 5 60 65 ~ O

Fi 1* MB349K Prop*noic AC id , 2-m*th\»l-Bpk Ob 9999

43

^

4000-

2

£7 41"' "»9 •**. lV 38

.,(• ^1,' . . . . . , . . . . , , . . . . , . .55 60

47 \ / 71,1 .' , \ f. (

5 - 3 0 35 40 45 50 5? 60 £5 70

. 1 . :

-60

-ft75 30 35 90

Sc»n 757C .00 min .

/ ' /75 S0 85 9

-se

-0J

£c*n 7560.00 mm.

L73/ 88

/. i75 SO SS 9(

-01

Data File: >G9052::U3Name :Miac D a t a : CA1S39C .QC70092,L:M6, 910.2RT (.nun): 5.16Scan: 73ttrea: 694873? Rank: 1S e m i - q u a n t i t a t i v e Cone t u n c o r r e c t e d ) :Sem i-quant i tat i'-'e Cone f corrected ):

312.29 UG'ML686.74 uqxl

BTLftl'-

Calculated using Istd: d4-l,4-Dichioroben2ane |3 10.65 minutes

, 1. noetic a c i d , ethyl ester2. Propartoic acid,. 2-methyl-

38 C4H8028S C4HS02

Sample f i l e :Search speed: 2

Spect rum #:Ti 1 t i ng op t ion: S No. of ion r a n q e 5 ^e

1.

Prob. CAS # COM #

60* 141736 2197

ROOT

HBS49KnBS4«K

2321

DK

5068

; TILT00

CON

359

Fil» >C90S2 CR1S89C ,0070092 ,L :M6 , 9 Scan 135Bpk fib 9999 , SUB NRM 6,42 mm.

43

8009-

4000-

0-

41\

59

56

.. ...Ai73 1 0

.... . *9 s f.. .. \.20 ' 40 ' 60 ' 80 ' 100

-60

-40

•eFilt HBS49K £-P*ntanon*, 4-hvdroxy-4-nntth«.-'l- ^can 2351Bpk Ab 9999 0.00 rnin.

43

3000-

4000-

0-

27 , . * l\.;' >,.59

.. ..,'>,.!••a ~3 33 9S 10:

20 40 cB &0 100

-80

-*0

Fil» NBSJ9K Hydrop*roxid». 1 , 1-d i m* thy 1 e thy I Scan 347Bpk Rb 999? 0.60 min.

3380-

4000-

e-

J*41 57

N

.. . ,.,ll

-

73 39/

• 29 ' 40 ' 40 ' 30 ' 100

-30

-40

-a

Data File: >G9052::U3Name:Ihsc D a t a : CA1389C ,OC70Q92 ,L: M6 _, 910,2RT '.mm ) : 6 . 42Scan: 135Rrea: 779535 Rank: ^4Sem i-quan t i t a t i ve Cone C uncor rec ted ) : 35.04 UG--'MLSemi-quantitative Cone ( corrected >: 77.00 ug/1Calculated using Istd: d4-l,4-Dichlorobensene £ 10.65 minutes

1. 2-Pen tanone, 4-hydroxy-4-metny1-2. Hydroper oxide, 1 ,1-d ime thy 1ethy 1

116 C6H120290 C4H1002

Sample f i l e : iG9052 Spectrum ft:Search speed: 2 T i l t i n g option: S

135No. of ion ranges searched

1.

Frob.

"•020

CAS tt CON # FOOT

127422 1790I"? 3

NBS49KNBS49(-.:

DK #FLG TILT \ CON

4031

U

Til* >G90S2Bpk fib 999911000:

10000-

9000-

8000-

7000:

6000-

5000:

4000-

3000-

2000

1000-;0-

43

II

55

44 \

1, . . 1 1 , 1 140 ' $0 '

C01S89C ,QC70092,LiM6, 9 Sc*n £06SUB NRfl 7.86 min.

35y

y6\ v i/ V

60 ' 70 ' 30 ' 9*0 ' 100 ' 110

-U0

-190

^O

•60

!*•0

fO

•40

•30

i"-

Data F i l e : >G9052::U?Name '•Misc Data: CA1889C ,QC700q2,L:16, 910/2RT C m i n ) : 7.3^Scan: 206rtrea: 217791 Rank: 9S e m i - q u a n t i t a t i v e Cone (. uncor rec t ed ) : 9.79 UG-'IILSemi-quant i tat ive Cone C c o r r e c t e d ) : 21.51 -jg-''IC a l c u l a t e d u s i n g Istd: d4-l 4-Dich lorobenzene |i| 10.65 m i n u t e s

BTL#18

No PBF1 h i t s for t h i « scan.

361

FH» >C90S2Bpk flb 9999

C01889C ,QC70092,LiM6, 9 Scan 77SUB NRM 5.24 it in.

SS 83

. (.3 79

96 t

JI.20 30 40 sfl 60 70 90 90

Fil* NBS49KBpk flb 9999

2-P»nt»n», 2 ,3-dimethyl-

41 5,S 83

Scan 11940.00 nun.

1 i5 25 'i i TVi1

31 ^j

if i i ' l M45

U£*53

HtU62

4-t-p365 69

/ 74 7998N

20 38 40 50 60 30 98Til* NBS49KBpk flb 9999

0J

3-P*nt«n-2-on», 4-

5543

11770.00 mm.

25.>.

T */

29 39 --.' 31 ^1 . 1 . .'•' ,...!.,.

jic 53.? ."l

9353 65 67 79

..<< '.-"'. .' .N

,,20 30 40 50 60 70 80 90


Cvclopropan*, 1,1,2,2-t«tram*th^l-

55 S3

lean 122;& .30 nun

'; 1925/ x

27/ ^ 1 46

,1 '53

"•> 62 65 67 74i . !> .'. r"T. f

X1

20 40 SS 60 70 90 90

Data File: >G9Q52::U3Name :riisc Data: CA1889C ,QC70092 ,L: M6 , 910,2RT tmin): 5.24Scan: 77hrca: 112972 Rank: 10Semi-quant i tat ive Cone tuncorrec t ed 1" : ?.08 UG-'T1LSemi-quantitative Cone C corrected ): 11.16 ug/1Calculated using Istd: d4-1 ,4-D ich lorobenzene |3 10.61? mimjtes

I. 2-Pentene, 2 ,3-dime thy 1-'2 . 7-Penten-2-one, -*-methyl-7. Cyclopropane, 1,1,2,2-tetramethyl-

98 C7H1498 C6H10098 C7H14

Sample file: -G90?2 Spectrum #:Search speed: 2 T i l t i n g option: S No. of ion ranges searched: 46

1.

P-ob

60*

CAS if CON # POOT

14179^94466140 NBS49K

NBS49K

K

409778

DK

61itc;

TTLT

90°

COM

17 7070

177015

362

IBSEMIYOLATILE ORGANICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

M a t r i x : (soil/water) UJATER

Sample wt/vol: 920.0 <g/mL) ML

Level: Clow/mod) LOW

Si Moisture: not dec. dec.



Contract:

SAS No.: SDG No.:


Lab File ID: >G9053

Date Received:



Di lut ion Factor: 1


108-95-2 —————— Phenol___________________111-44-4——-——-bis(2-Chloroethyl)ether____93-57-8 ——————— 2-Chlorophenol____________541-73-1——--—-1,3-Dichlorobenzene________106-46-7-———---1,4-Dichlorobenzene________100-51-6 ———— ---Benzyl alcohol_____________95-5Q-l---------l,2-Dichlorobenzene________95-48-7———————2-Methyl phenol____________108-60-1----——bis(2-Chloroisopropyl)ether_106-44-5 ——————— 4-Methyl phenol_____________621-64-7--------N-Nitroso-d i-n-propylamine_67-72-1--———---Hexachloroethane__________98-95-3-—------Nitrobenzene______________78-59-1---------Isophorone________________88-75-5--—-----2-Nitrophenol_____________105-67-9- — — —— 2,4-Dimethyl phenol________65-85-0----- — --Benzoic ac id______________111-91-1 —— -- — -bis(2-Ch1oroethoxy)methane_120-83-2----—--2,4-Dichloropheno1_________120-82-l--------l,2,4-Trichlorobenzene_____91-20-3 ——————— Naphthalene_______________106-47-8--------4-Chloroanilme____________87-68-3---------Hexachlorobutadiene________59-50-7-----——4-Chloro-3-methylpheno1____91_57_6_--__—--2-MethylnaphthaIene________77_47_4--_—-___Hexachlorocyclopentadiene__88-06-2-------—2,4,6-Trichloropheno1______95_95_4__—-----2,4,5-Trichlorophenol______91-58-7---------2-ChloronaphthaIene________88-74-4---------2-Nit roan i1 me_____________131-ll-3--------Dimethylphthalate_________208-96-8--------Acenaphthylene____________6Q6-20-2--------2,6-Dmitroto luene________

111111111111111111111111111111115411111111111111111111541154111111

Q

IUIUIUIUIUIUIUIUIUIUIUIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

FORM I SU -1 1/87 Rev

' 1CSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

ERA SAMPLE NO

Lab Name: ETCNJ

Lab Code: Case No.:

Matrix: (soil/water) WATER

Sample wt/vol: 920.0 (g/mL) ML

Level: Clow/mod) LOW

X Moisture: not dec. dec.

Ex t rac t i on: C SepF/Con t/Sonc) CONT


Contract:

SAS No.: SDG No.:


Lab File ID: >G9053

Date Received:



Dilution Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg) UG/L

I 99-09-2 ——————— 3-Nit roan i line____________83-32-9 ——————— Acenaphthene______________51-28-5 ——————— 2,4-Dinitrophenol_________100-02-7——————4-Nitrophenol_____________132-64-9 —————— -Dibenzofuran______________121-14-2 —————— 2,4-Dinitrotoluene________84-66-2 ——————— Die thylphthe late__________7005-72-3—————4-Chlorophenyl-phenylether_86-73-7— —————— Fluorene ______________100-01-6- ———— --4-Nitroani1ine.____________534-52-1————-—4,6-Dinitro-2-methylphenol_86-30-6—————-—N-Nitrosodiphenylamine (1)_101-55-3—---——4-Bromophenyl-phenylether__118-74-l--------Hexachlorobenzene_________87-86-5 —————— -Pentach lorophenol_________85-01-8----—-—Phenanthrone______________120-12-7—— — —— Anthracene________________84-74-2 ——————— Di-n-butylphthe late________206-44-0 — — ——— Fluoranthene______________129-00-0-———--Pyrene_____________________85-68-7——-——-Butylbenzylphthalate_______91-94-1 ——————— 3,3 '-Dichlorobenzidine_____56-55-3---------Benzo(a)anthracene________218-01-9 ——————— Chrysene___________________117-81-7——————bis(2-Ethylhexyl )phthalate_117-84-0 —— ———— Di-n-octylphthalate________205-99-2—————--Benzo(b)fluoranthene_______207-08-9 —————— Benzo(k)f luoranthene_______50-32-8 ——————— BenzoCaJpyrene^.___________193-39-5 — --- — -IndenoCl ,2,3-cd)pyrene_____53~70-3---------Dibenz(a,h)anthracene______191-24-2---—---Benzo(g,h,i)perylene_______

5411545411111111115454111111541111111111112211111111111111111111

(1) - Cannot be separated from Diphenylerrune

FORM I SU -2

Q

IIUIUIUIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU

1/87 Rev,

364

IFSEMIUOLATILE ORGANICS ANALYSIS DATA SHEET


EPA SAMPLE NO.

Lab Name:ETCNJ . Contract:

Lab Code: Case No.: SAS No.:

Matrix: (soiI/water)WATER

Sample wt/vol: 920.0 (g/mL)ML

Level: (low/mad) LOU

% Moisture: not dec._____ dec.____


GPC Cleanup: (Y/N) N pH:___

Number TICs found: 3

SDG No.:


Lab File ID: >69053

Date Received: /o/



Dilution Factor: __/


CAS NUMBER

01. 141-78-602.03.

COMPOUND NAME

Acetic acid, ethyl esterACETONE DIMERUNKNOWN

1

RT

5.116.568.04

EST. CONC

4008914

Q

BOBJJ

FORM I SU-TIC 6651/87 Rev.

TOTAL ION CHROMflTOCRPMFile >C9063

1699999-

1499999-

1299999-

1999999-

000000-

699999-

499999-

299999-

'I '

35.0-E00.0 *»U. CR189BC ,0070892, Li

40,0 , 800 | 1200 | 1699 r 2089

I *i

!.&<z1 (

~ ?

si *\I ii f :i .£ >

« a*C Z

! ""^ 1 i

s 1 i > i l lh ! • fI ' l'2" ' 16" ' 20 ' "24 ' 20 ' 3'2 ' 36 ' ' "4f0" ' 44

Data File: >G9053::U3Name:Miac: CA1890C ,QC70092,L:M6, 920,2

Id File: IG013Q::PFTitle: IFB/BNA, PP/BNALast Calibration: 89111? 12:26


Quant Output File:

BTL#19

3)66

\

QUANT REPORT

Operator ID:Output File:Data File:Name:disc: CA1890C

PT1575"G9Q53::AQ>G9053::U3


Di lut ion Factor

,QC70092,L:M6, 920,2

Page 1

991115 13:22891115 08:10

1.00000

8TL*19

ID File: IG0130::PFTitle: IFB/BNA, PP/BNALast Calibration: 891115 12:26

Compound R.T. Scan* Area Cone Units

3)5)12)17)18)32)36)50)52)54)65)67)73)

*d4-l,4-Dichlorobenzene2-Fluorophenol CSURR)Phenol -05 CSURR)N-Nitrosodi-n-propylamine

*d8-NaphthaleneNitrobenzene-05 CSURR)

*dlQ-Acenaphthene2-Fluorobiphenyl CSURR)Fluorane2,4,6-Tr ibromophenol CSURR)

*dlO-Phenanthrene*dl2-ChryseneTerphenyl-014 CSURR)

*d!2-Perylene

10.7.10.12.14.12.20.18.22,22.24.32.29.36.

896436

69621320575556575858

346186320431533431801706921920

1019141312661610

24607932092143547437195498070250936179642262662

39380149915546098914729854

407071-te-40364034

5740405840

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UG/MLUG/MLUG/MLUCi'MLUG/MLUG/MLUG/MLUG/MLUflj'HL •UG/MLUG/MLUG/MLUG/MLUG/ML

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Data FiLe: >G9053::U5Name :Misc Data: CA1390C ,QC70092,L:M6, g20,2PT ' mm ) : 6 . 56Scan: 133Hrea: *664?7 Pank: 53*mi-quant i tat i '.,*e Cone '. uncorrected)-'Seni-quantitative Cone t corrected ):

41. 04 UG-'ML89.22 ug'l

BTLttl9

Calculated using Istd: d4-l,4-Dichlorobenzene @ 10.8° minutes

1. 2-Pentanone, 4-hydroxy-4-methyl-2. Hydrcperoxide, 1,1-d ime thylethyl

116 C6H120290 C4H1002

3*np le f i l e : nearch speed: '2

Spec t rum #:T i l t i n g op t ion : S


1.

Prob .

20

CAS *

1234227 '5 12

CON #

179017??

ROOT

NBS4PKNBS491-.

K

4334

DK

4031

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35

57

•"""'' 69 ?l

•I |'l 1" l't'1'l-T"! I | 1 1 , . , . . . , , . . . . , . .

86 99 100S X • X 1 * :.< ir

60 70 30 90 100 110

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Data File: G90?3: : U3Name :Misc Data: CA1S9QC ,QCPT (min ) : 3. 04Scan: 206Area: 1505?! Rank: 10Sem i -quant i t at ive Cone •' uncor rec ted ) : 6.?° UG-'MLSemi-quantitative Cone C corrected ): 13.90 ug •'' 1Calculated uting I =. t d : d4-l ,4-Dich lorobenzene g 10.89 minutes

1. Pentanoic acid, 2,2-dimethy1 -, ethenyl ester 156 C9H1602

S a n . p l e f i l e : > G 9 Q ? ? S p e c t r u m # :i e a r c h speed: 2 T i l t i n g o p t i o n : S

206Mo. of ion rang i ' e a r c I"' e C

P r o b . CrtS # COM # ROOT K DK ttFLG T I L T % CON

t i) -4497C050 6671 NSS4*K 76 4o 2 0 100 i 1

i70

IBSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET

EPA SAMPLE NO,

Lab Name: ETCNJ

Lab Code: Case No.:

Matrix: (soil/water) UATER


Leva 1: Clow/mad) LOU




Contract:

SAS No.: SDG No.:


Lab File ID: >G9061

Date Received: f


Date Analyzed: 11x15/89



108-95-2 —————— Phenol___________________111-44-4——————bis(2-Chloroethyl )ether____95-57-8 ——————— 2-Chlorophenol________'541-73-1 ————— — 1,3-Dich lorobenzene________106-46-7———————1,4-Dich lorobenzene________100-51-6 —— - — — Benzyl alcohol___________95-50-1———————1,2-Dichlorobenzene____'95-48-7———————2-Methyl phenol____________108-60-1—————--bis(2-Chloroisopropyl)ether_106-44-5 ——————— 4-Methyl phenol_____________621-64-7--------N-Nitroso-di-n-propylamine_67-72-1 —— ——— — Hexach lo roe thane__________98-95-3-- — - ——— Ni trobenzene______________78-59-1 ————— --- Isophorone________________88-75-5 ————— — -2-Nitrophenol_____________105-67-9 — ———— -2,4-Dimethyl phenol________65-85-0 —————— --Benzoic acid______________111-91-1 —————— bis(2-Chlproethoxy)methane_120-83-2—---——2,4-Dichlorophenol________120-82-1- ———— — 1,2,4-Tr ichlorobenzene_____91-20-3 ——————— Naphthalene_______________106-47-8-——----4-Chloroani1ine___________87-68-3-——--——Hexachlorobutadiane________59-50-7—-———-4-Chloro-3-methyIpheno1____91-57-6 ——————— 2-Methyl naphthalene________77-47-4—————---Hexachlorocyclopentadiene__88-06-2————-—2,4,6-Trichloropheno1______95-95-4----—---2,4,5-Trichlorophenol______91-58-7-—------2-Chloronaphthalene________88-74-4------ —— 2-Ni t roam 1 me____________131-11-3 —————— D i met hylph thai ate_________208-96-8----—--Acenaphthylene____________606-20-2 — — - —— 2,6-Dimtroto luene________I__ ______ ____ ____ _____I

101010101010101010101010101010105210101010101010101010521052101010

Q

IUIUIUIUIUIUIUIUIUIUIUIUtutuIUIUIUIUIUtuIUIUIUiUIUIUIUIUIUIUIUIUIU

71

FORM I SU -1 1/87 Rev.

1 1CSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:


Sample wt/vol: 960.0 (gXmL) ML

Level: (low/mod) LOW

\ Moisture: not dec. dec.

Extrect ion: (SepF/Cont/Sonc) CONT

6PC Cleanup: CY/N) N pH:

Contract:

SAS No.: SOG No.:


Lab File ID: >G9061

Date Received:





99-09-2 ——————— 3-Nitroanil ine____________83-32-9 —————— -Acenaphthene______________51-28-5 ——————— 2,4-Dinitrophenol_________1QTO-02-7——-———4-Nitrophenol_____________132-64-9——————Dibenzofuran______________121-14-2 —————— 2,4-Dinitro toluene_________84-66-2 ——————— Diethylphthalate__________7005-72-3 —————— 4-Chloropheny 1-pheny let her_86-73-7——————-Fluorene_________________100-01-6 ———— - — 4-Nitroanil ine____________534-52-1——--——4,6-Dinitro-2-methyIpheno1_86-30-6---------N-Nitrosod iphenylamine C1)_101-55-3--------4-Bromopheny1-phenylether__118-74-1- ———— — Hexach lorobenzene_________87-86-5 ——————— Pentach lorophenol_________85-01-8 —— -- ——— Phenenthrene______________120-12-7——————Anthracene________________84-74-2 ——————— Di-n-butylphthalate________206-44-0 ——— ——— Fluoranthene______________129-00-0———— —— Pyrene_____________________85-68-7———————Butylbenzylphthalate_______91-94-1--———--3,3'-Dichlorobenzidine_____56-55-3- — --- — -BenzoCa )anthracene_________218-01-9 ———— —— Chrysene_________________117-81-7——————bis(2-Ethylhexyl)phthalate_117-84-0————— — Di-n-octylphthalate________205-99-2 —————— Benzo(b )f luoranthene_______207-08-9 —————— -BenzoCk)f luoranthene._______50-32-8 —————— -BenzoCa )pyrene____________193-39-5----—--IndenoCl,2,3-cd>pyrene_____53-70-3 ————— ---Dibenz Ca,h)anthracene______191-24-2---- — --8enzo(g,h,i )perylene______

5210525210101010105252101010521010101010102110101010101010101010


FORM I SU -2

Q

IIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

1/87 Rev,672



EPA SAMPLE NO.

Lab Name:ETCNJ

Lab Code: Case No.:

Ma t r i x : (soil /wa t e r ) LJATER


Level: Clou/med) LOU

H Moisture: not dec._____ dec.___

Extract ion: CSepF/Cont/Sonc) CQNT

GPC Cleanup: (Y/N) N oH:

Number TICs found:

Cont ract:

SAS No.: SDG No . :


Lab Fi le ID: >G9061

Date Received: /



Dilution Factor: *

CONCENTRATION UNITS:(ug/L or ug/Kg)UG/L

CAS NUMBER

01. 141-78-602.03.04.

COMPOUND NAME

Acetic acid, ethyl esterACETONE DIMERUNKNOWNUNKNOWN

RT

5.046.437.838.88

EST. CONC

330911111

Q

BJBJBOBJ

FORM I Sv-TIC 1/87 Rev.673

TOTflL ION CHROMRT06RRMFUt >G9B61 35.e-Sae.B MU. ,.„ CR1B91C ,BC7B»9Z,LI

TIC408 ( 88.8 t 1288 ( 1608 , 28,88

laeaeaaj

908088-

888888-

788800-

608008-

500088-

480008-

300008-

288888;

100808-

1 f§ i

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[f

• f •

r| a af i l l!iri s1 ' ? i1 ii til

i 7 5 s^ 1 i T

4 ' 8" ' J'2 ' t'« 28 ' 24 ' 28 32 ' 36 48 44

Data File: >G9061::U3Name:Misc: CA1891C ,QC70092 ,t_:M6, 960,2

Id File: IG0130::PFTitle: IFB/BNA, PP/BNALast Calibration: 891119 12:26

Operator ID: PT1575Quant Time: 89111? 16:33Injected at: 89111? 19:46

Quant Output File: *G9061i:AQ

BTL*27

574

Operator ID: PT1575Output File: AG9061t:AQData Fila: >G9061::U3Nama:Misc: CA1891C ,QC70Q92,L:M6 , 960,2

ID File: IG0130::PFTit la: IFB/9NA, PP/BNALast Calibration: 89111? 12:26

QUANT REPdRT


Di lut ion Factor

Pege 1

891115 16:53891115 15:46

1.00000

BTL#27


1)3)5)12)17)18)32)36)49)52)54)65)67)73)

»d4-l,4-Dichlorobenzene 10.63 344 2404192-FluorophenoL (SURR) 7.44 187 180156Phenol-05 (SURR) 10.08 317 215251N-Nitrosodi-n-propylamine 12.34 428 39268

*d8-Naphthalene 14.41 530 502004Nitrobenzene-05 (SURR) 12.34 428 261574

•dlO-Acenaphthene 19.88 799 1756442-Fluorobiphenyl (SURR) 17.93 703 268640Diethyl phthalate 21.63 885 63952,4,'6-Tribromophenol (SURR) 22.30 918 22321

•dlO-Phenanthrene 24.31 1017 144641*d!2-Chrysene 32.32 1411 54223Terphanyl-014 (SURR) 29.33 1264 84573

»d!2-Perylene 36.32 1608 35508

40.0040.5336.1011 . .lift.

* Compound is ISTD

UG/MLUG/MLUG/ML-UC f tIL.

40.0037.8840.0036.29

1.3833.2840.0040.0056.2440.00

UG/MLUG/MLUG/MLUG/MLUS/'IILUG/MLUG/MLUG/MLUG/MLUG/ML

888994

94969899

9698989489

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!S/-*19

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-03

Data File: >G9061::U3Name :hisc Data: CA1891C .OC70092,L:M6, 960,2RT f m i n ) : 5.04Scan: o9Area: 7744492 Rank: 1S e m i - q u a n t i t a t i v e Cone (unconnected); i?9.84 UG-'ML,Semi-quan t i tat ive Cone <• c o r r e c t e d ): 333.01 ug/lC a l c u l a t e d using I s t d : d4-l,4-Dichlorobenzene ft 10.63 m i n u t e s

BTL#27

1. Acetic acid, ethyl ester 38 C4H802

Sample f i l e : .G9061 Spect rum ft:Search speed: 2 T i l t i n g o p t i o n : S No. of ion ranges searched

Prob. CAS # CON tt ROOT K DK ftFLG TILT % CON C_I R_I'J

1. c2* 141796 2197 N6S49K 27 ?1 1 0 68 IS 20 15

376

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76092, Lif16, 9 Sc*n 1376 .43 min .

73 1069 s 83 /

.... /../ . . .'... ., 1,20 40 ' 60 90 ' 1 30

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43_**'

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1 ! 1 1 | 1 1 1 Tl ' 1 1 1 | 1 i . t | i i . , ( i i 120 40 60 'g'e' ' ' IQ0

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Fil» NBS49K Hydrop»roxid», 1 . 1 -di m« thvl* thy I Scan 347Bpk fib 9999 3.30 mm.

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Data Filc: >G9061::U3Name:riisc Data: CH1891C , OC70G92 ,L: M6 , 960,2RT (mm ) : 6.4?Scan: 137Area: 102861C Rank: 2Se m i - q u a n t i t a t i v e Cone Ojncorrected): 47.g0 UG-MLSemi-quantitative Cone ( corrected ): '' 1 .47 ug-''lCalculated using Istd: d4-1,4-Dicnlorobenzene |S 10.63 minutes

BTL#2;

1 . 2-Pen t anone , 4-hydroxy-4-rne t hy 1 -2. Hydropero.-, ide , 1 ,1-d :methy lethy 1

116 C6H12Q290 C4H1002

Sample f i l e : -S°06l Spectrum #:••earch speed: 2 T i l t i n g option: 5 No. of ion ranges searched:

1.

Prab .

7020

CAS * CON ROOT Dh

123422 17«0 NBS49K 4? 40"='512 1"3J NBS-9K ?4 71

G TILT %

0

COM C I P_P.

3S ?114

'677

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65

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30 40 50

CP1891C ,QC70092,Ltt16, 9 Sc«n 206SUB NRM 7.33 mln.

65 r

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57

' V/'l i'i ' I ' l ' l ' i ' ' • ! "'"'' i i • ..• i . . . . ,- .

®6 99 100

( V60 70 30 90 100 110

-100

-SO

-60

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Til* NBS49K P#ntanoic acid, 2 ,2-dimethyl- , #fhenyl *st*r 2c»n 9601Bpk Ab 9999 0.00 min.

4310000-

8006-

6000-

4000-

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41

29r .i,,

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55\

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57X 69 7l

.. . f,/ ..86 H3/ 37 \1 / 1.

60 70 SO 90 100 110

-100

-SO

-60

-40

-20

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Data F i l e : -G90ftl::U3Name :Nisc Data: CA1391C .OC70G92,L=M6, 960,2PT ''mm): 7.3?Sc an: 206Area: 125146 Pan!,: 9bem i-quart t i tat ive Cone ' unco r rec t ed ) : 9.74 !JG-'ML5«m i-quan t i t a t we Cone ' corrected >: 11.13 ug.-'lC a l culated using I*td: d4-1 ,4-Dich 1 orobenzene {? 10.6? minutes

BTL#2:

I. Pentanoic acid., 2 ,2-dimethyI-, ethenyl ester 156 C9H1602

G9061 Spectrum tf:Ti 1t ing option: S

206No. of ion range* searched

<=rob . CAS fl CON # POOT K C'K frFLG TILT

-•: 4n9"'C050 6671 NBS49h 42 40 2 0

CON C_I P_IU

9 42 14

378

Fil* >G9061Bpk Ob 9999

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J 7

Cfil891C ,QC7009Z,L;t t6, 9 Scan £53SUB NRM 3.88 mm.

7143 ^

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J " £3 / 91 103 109 [• •• ' • ' • ' • '"• . . < • • • • • • ' . • H. .1. . . . ..r^" .. . - ' . r--' _ La,

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Fil* NBS49K HBpk fib 9999

: 29 41

•pt*n», 3,3,4-trinnthul- i.c»n0.00

57' 72 65 95 - 11? 127

i_ ....J. . .._, , —— ._.'. ./ —— ..... — . ———— >s.20 40 £0 30 100 120

Fil* NBS49K ButaBpk fib 9999

41

0 - F,,,,_F,T Jiv. - . H . . . . . , . . - . , . . . . , . . . , , . . . . , . . . • . • • • . i • • • • i . . . .

J357nin .

H?

noic acid, 2-prc-p*nyl *5t*r Jean 42950.00 mm.

4 3 7 1

y 72 89 109 101 113 123 f

20 40 £0 30 100 120

Flit NBS43KSpk fib 9999

41-1 ""•

l-Prop«n4, 1-chloro- ^csn ?430 .00 min .

f49 61 62 79 t

• 20 ' 40 ' o'e ' 30 ' IQO ' 12©

Data File: >G«061::U7Name :disc Data: CfllS^lC ,0070092 ,L:M6 , 960,2PT imin): 9.83Scan: 2^8Area: 121200 Rant : 10Serru-quan t 11 a t i -.-e Cone C unco r rec t ed ) : ?.l? UG--'MLSemi-quan t i 13 t i ve Cone ' corrected >: 10.73 ug--'lC a l c u l a t e d using I s t d: d4-l,4-Dichlorobenzene jS 10.6? minute*

BTL#2'

1. Heptane, 3 , ?• ,-t-t r i me t hy 1-2. Butanoic acid, 2-prcpenyl ester7. 1-Propene, 1-chloro-

142 C10H22128 C7H120276 C7-H5CI

le f i l e : ;-Gg06l Spec*: rum #:Search speed: 2 T i l t i n g option: S No . of ion ranges searched: 46

Prob. CAS ^ CON

11 * "? '3 O 2 16 r C *

ROOT

H6S49KMBS49K

K

7Q

DI-- TILT

00

COH P_ 11..'

1?i •-»

579

IBSEMIUOLATILE ORGANICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Ma t r i x: (soil/wet e r) UATER


Level: (low/med) LOW

K Moisture: not dec. dec.

Extract ion: (SepF/Cont/Sonc) CQNT


CAS NO. COMPOUND

IContract: I_______

SAS No.: SDG No.:


Lab File ID: >G9054

Date Received:




CONCENTRATION UNITS:Cug/L or ug/Kg) UG/L Q

108-95-2 ———111-44-4 ———95-57-8 ————541-73-1 ———106-46-7 ———100-51-6 ———95-50-1 ————95-48-7 ————108-60-1 ———106-44-5 ———621-64-7 ———67-72-1 ————98-95-3 ————78-59-1 ————88-75-5 ————105-67-9 ———65-85-0 ————111-91-1 ———

91-20-3 ————106-47-8 ———

59-50-7 ————91-57-6 ————77-47-4 ————

95-95-4 ————O 1 CQ 7 _

88-74-4 ——— -131-11-3 ———208-96-8 ———606-20-2 ———

——— Phenol——— bis(2-Chloroethyl ) ether ____——— 2-Ch loropheno 1 ...----1 f3-Dich lorobenzene

----Benzyl a Icoho 1 i n i i i m i i i „.——— 1 f2-Dich lorobenzene— --2-Methy Ipheno 1----bis (2-Ch loro i sop ropy 1 )ether----4-Methy 1 phono 1——— N-Ni t roso-di-n-p ropy lam ine _----Hexachloroethane——— Nitrobenzene---- Isophorone——— 2-Nitrophenol——— 2 ,4-Di me thy Ipheno 1_----Benzole acid- —— b is (2-Ch loroethoxy) me thane _——— 2 ,4-Dichlorophenol __——— 1 r 2 T4-Tr ich lorobenzene—— -Naphtha lene-_ — 4-Chloroan i 1 ine— _-He*aehlorabLJtadiene——— 4-Chloro-3-methyl phenol ____— --9 -Methyl naphtha lene——— Hexach lorocyc 1 open t ad i one __——— 9J4JA-Trich loropheno 1— --2,4,5-Trieh lorophenol— — 2-Ch loronaphtha lene- — -9-Nitrnani 1 ina _----D i me t hy 1 ph t ha 1 a t e .... ....— --Acenaph thy lene——— 2r6-Dinitrotoluene

11111111111111111111111111111111111111111111111111541111 111111111111111111111111111541111541111111111

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUtuIUIU1

FORM I SU -1

5301/87 Rev.

' 1CSEMI VOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO

Lab Name: ETCNJ

Lab Code: Case No.:



Level: (low/mod) LOUI

Contract:

SAS No . : SDG No . :



Date Received: t

% Moisture: not dec. dec.






CAS NO. COMPOUNDCONCENTRATION UNITS:Cug/L or ug/Kg ) UG/L

99-09-2 ———— -83-32-9 ———— •51-28-5 ———— -100-02-7 ——— -132-64-9 ——— -121-14-2 ——— -84-66-2 ———— -7005-72-3 —— -86-73-7 ———— •100-01-6 ——— -534-52-1 ——— -86-30-6 ———— -101-55-3 ——— -118-74-1 ——— -87-86-5 ———— -85-01-8 ———— -120-12-7 ——— -84-74-2 ———— •206-44-0 ——— -129-00-0 ——— -85-68-7 ———— -91-94-1 ———— -56-55-3 ———— -218-01-9 ——— -117-81-7 ——— -117-84-0 ——— •205-99-2 ——— •207-08-9 ——— -50-32-8 ———— -193-39-5 ——— -53-70-3 ———— -191-24-2 ——— -

----3-Nitroanil ine—— -Acenaphthane— --2.4-Dini t rophenol——— 4-Nitrophanol----Dibenzofuran- —— 2.4-Dinitrotoluene- — - D i e t h y l p h t h a l a t a-_-_4_Ch loropheny 1-pheny let her _----Fluorene. _ _ _ 4 _ N i t r o a n i 1 ine----4,6-Dinitro-2-methylpheno I _— --N-Nitrosodiphenylamine C 1) _—— -4-Bromopheny 1-pheny let her ___•---Hexachlorobenzene- —— Pen tachlo rophenol----Phenan throne. — -Anthracene-- — Di-n-butulohthalate----Fluoranthena----Pyrene .,.—— -Butylbenzylphthalate ......—— -3.3' -Dich lorobenz id me.---BenzoCalanthracene----Chrysene——— bis(2-Ethylhexyl )ph t h a i ate.- — D i - n - o c t y l p h t h a l a t e. — -RanzoCb ) f luoranthena. — -BenzoCk Jf luo ran thane———— BenzoCa )pyrana.---Indanod ; 5 , 3-ed ) pur ana.---nihanT(M,h 1 anthracana

1 J

5411545411111111115454111111541111111111112211111111111111111111

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUI UIUIUIUIUIUIUIU .iUIUIUIUIUIUIUIUIUIU1

(1) - Cannot be separated from Diphony lamine

FORM I SU -2 1/87 Rev

IFSEMIVOLATILE ORGAN ICS ANALYSIS DATA SHEET


ERA SAMPLE NO.

Lab Name:ETCNJ . Contract:

Lab Coda; Case No.: SAS No.:

Ma t r i x: (soil/wa tar)WATER



\ Moisture: not dec._____ dec.____



SDG No.:


Lab File ID: >G9Q54

Date Received: /Q/

Date Extracted:10X12/89


Dilution Factor: /

Number TICs found: 5" CONCENTRATION UNITS:(ug/L or ug/Kg)UG/L

CAS NUMBER

01. 141-78-602.03.04. 108-88-305.

COMPOUND NAME

Acet ic acid, ethyl esterACETONE DIMERUNKNOWNBenzene, methyl-UNKNOUN

.

RT

5.126.509.004.357.95

EST. CONC

46085251211

Q

BJBJBJJBJ

6diFORM I SV-TIC 1/87 Rev.

TOTAL ION CHROHATOGRflHTilt >6S

1400000-

1200000-

1000000-

000000-

688880-

408800-

200800-

054 36.8-508.8

400

S E8

1 jjjI S I :

" <"',('

1 , , 1I J i'2 '

MU. CR1892C ,aC7BB92,LlTIC

t 80,0 , 1200 , 1680 , 2000

( f f

I \ 1 t

.x . i f ' Eg

? I 7 ^ 511 1 i T16 20 ' 24 ' 28 ' 32 ' 36 ' 48 ' 44

Data Tile: >G9054::U3Name:Miac: CA1B92C ,QC70092,L:M6, 920,2

Id F i l e : IG0130::PFTitle: IFB/BNA, PP/"BNALast Calibration: 891119 12:26

Operator ID: PT1575Quant Time: 891119 17:28Injected at: 89111? 09:06

Quant Output File: AG9054::AQ

BTL*20

Operator ID: PT1575Output File: *G9054::AQData File: >G9054::U3Name:Misc: CA1892C ,QC7Q092,L:M6, 920,2


Compound

QUANT REPORT

Quant Rev: 7 Quant TimeIn jected'at

Di lut ion Factor

Page 1

891115 13:28891115 09:06

1.00000

BTL#20

R.T. Scan* Area Cone Unit*

1)3)5)12)17)18)32)36)50)52)54)65)67)73)

*d4-l,4-Dichlorob«nzene2-Fluorophenol CSURR)Phenol-05 CSURR)N-Nitrosodi-n-p ropy l a m i n a

*d8-NaphthaleneNi trobenzene-D5 CSURR)

»dlO-Acenaphthene2-F luo rob i phony 1 (SURR)Fluorene2, 4, '6-Tr tbromophenol (SURR)

*dlO-Phenanthrene*d!2-ChryseneTerphenyl-D14 (SURR)

*d!2-Perylene

10.7.10.12.14.12.20.18.22.22.24.32.29.36.

7754245057500209so4445464748

34118231542**+*o52842679670191 A7 1O

9151014140812611606

23944127844738548639375495825261972180192279524

47/0

37837145382613869605841494

406264-tt40384036

5440405640

.00

.89

.91

.00

.41

.00

.81*&r-.99.00.00.42.00

UG/MLUG/MLUG/MLUS^'ML —UG/MLUG/MLUG/MLUG/MLU8MILUG/MLUG/MLUG/MLUG/MLUG/ML

897996^o94959999R7OS9497989594

» Compound is ISTD

Fil* >G93S4Bpk fib 9999

seee-•

4900-,

0-25

38

3*0 38

Cai892C tQC70e9£.Ltn6, 9 'CAR 63$UB Nftrt

43

4?

.\

46 gi gg g^/ 50 55 58 / / \

. 1 f. . V. . t..f,.\.f \40 45 50 55 60 65 7

Fil* NBS49KBpk fib 9999

8090-

4000-•

8-

29

flc*ti.: acid, *thyl tittr

43

27/ «?,

25

tW-rr^T^30 35

Fil* N8S49K

•,i

61. /.1 I

40 45 50 55 60 65 7

7*1

,0

70/

0

Propanoic *cid, 2-m#thyl-Bpk Pb 9999

3000-.

4090-

0-

27

i25

43

41

'/' . i30 35

1

55 60, V \ /i l . .1 . .

7!•

40 45 50 55 60 65 70

5.12 min.

73/ 88

. i .

-S0•8

.La

75 80 85 98Sc»n 757

0.00 min.

73•'' V^ • ;

-80.-40

•675 30 35 90

Sc»n 7566 .00 min .

73/ 38

H30k.

^0

-a75 38 35 90

Data File: >G9054: : ij?Name:Misc Data: CA1392C .QC70092 ,L:M6, ^20,2RT (mm) : 5 . 12Scan: 63Area: 496417? .Rank: 1Semi-quantitative Cone ' uncor rec ted ): 217.58 UG-''MLSfttrii -quant i t at ive Cone r corrected ): 464. 71 ug'lCalculated using Istd: d4-l ,4-Dich lorobenzene I? 1C.77 minutes

1. Hicetic acid, ethyl esteri 2. Propanoic acid, 2-methy 1

88 C4H80288 C4H802

Sample f i l e : >G9054 Spect rum #:Search speed: 2 T i l t i n g option: S

67No. of ion ranges searched:

Prob . CAS # CON # ROOT

1. 141736-0312

21974793

NBS49KNBS49K

7221

OK

4668

TILT

00

COM C I P I'.

10006

20-i'3

20 16

Fil* >G90S4 CA1892C .QC70092 ,L iM6 , 9 Sc*n 131Bpk Pb 9999 , SUB MR 11 6. S3 mm.

43

8000-

4000-

0- ...1.1

59

J! 83, _i/... L ,

4'0 ' 90' / %\

120 ' 160 ' 200

-ee-40

F i l » NBS49K 2-P*nt»non*, 4-hvdroxy-4-m« thy 1- Sc*n 2351Bpk flb 9999 0.00 min.

43

8000-

4000-

0-N

5973 83 101 102

....ii.l . . ...!':... ...i . , . ..... '•", | . i . • • . | i • • ( • . r |

40 30FiU NBS49K Hvdroptrox id* t 1Bpk flb 9999

59

&000-

4000-

0-

43

27''N,

73

40 ' 30

, . I | . . [ i I I r | i , , , , , i | .

120 lo& £00

**-e

, I-dim»th'»i*th"l ?c»n 54"0 .00 min .

120 160 200

-80

-40

-0

Data Filc: =G90?4::U7Name :tlisc Data: CA1392C .QC70092 ,l_: M6 , 920,2PT -f mm) : 6.50Scan: 1?1Ar«a: 91796? Ran^ : 4Semi-quant i tat ive Cone ', unco rrec ted ): 79.32 UG-'MLSemi-quantitative Cone ( corrected .' J 85.4a u g - 1Calculated using I s t d : d4-l?4-Dich'iorob*nz*ne fl 10.^7 minutes

1 . '2-Pen t anone , 4-hydrcxy-4-me t hy 1 -2. Hydroperox ide , 1 , 1-d ime thy le t hy 1

116 C6H12Q290 C4H1002

Sample *•" ; 1 e : .•GOf|e;il Spectrum tt:>earch speed: 2 T i l t i n g o p t i o n t S

131•lo . of ion r a n q e s searched:

Prob. CAS

.23422

COM :

17-301"'?7

FOOT ttFLG TILT CON c i P4031

1-47 p

FU» >G90S4 C01892C ,QC70092 ,L :M6 , 9 Scan 2S4Bpk fib 9999 . , CUB NRM 9.00 min.

10800-

8880-

6808-

4000-

2808-

e-_

71

43

36*

X

'

t

JLU. , .-i-r . . . , . ,48

83/

105 2S3! X N.I,.,.., ..,f .. . .

--100

-ea•«0•-t0

-20

•(\80 ' 120 i£0' ' 200 ' 240 2>30

Fil» NBS49K Pentan*, 3-bromo- Scan 8114Bpk Rb 9999 0.00 nun.

110000-

.3000-

b000-

40C-0-•

2800-

43 7, ' r

29 .

. i

/ 1-1 00

i ..* ......

L

._ 107 150 152* / s _^f*ff

H30

•ee-10--20

~n40 ' SO ' 120 ' 1 lie ' 200 ' 240 ' 2S0

Data File: >G9054::U7Name :nisc Data: CA1S92C ,QC70Q92,L:M6, 920/2PT -f mm > : 9.00^f**r^! * *i»" <ta' 3 « ' • 4. **

Area: 264122 Rank: 9Semi-quantitativ'e Cone luncorrected): 11.76 UG-'T1LS e m i - q u a n t i t a t i v e Cone '. corrected ): 24.70 ug -' 1Calculated using Istd: d4-1,4-Dichlorobenzene @ 10.77 minutes

BTL«

1. °*ntane, 7-bromo-

Samp le f i l e : G90?-» Spec t rum #:Search ••.peed: 2 T i l t i n g option: S No . of i c n r a rig e s *. e a

=rob. CAS # CON

2? 1309105 A?4

ROOT OK #FLG TILT

387

Fii»Bpk

FlitBpk

Fil»Bpk

FiU

>C90S4flb 9999

jNBS49K

fib 9999

I-oV1 0

HBS49K*b 9999

1

flj

10

NBS49K

CP1892C ,QC70e92,L:M6, 9 2c*n 25SUB

3j

l'' 4^S

2*0 30 48Btnzvn* ,

15 26 27 32 3/*45/ **> s s i ^

t"i i-i i i't*ti-r-)-i i'1'l'l20 30 40

•)Rn 4.35 mm.91

50 51 rta 63^5 74 77 84 89v >.f. ...'l >. / > . >

S'0 60 78 30 90mtthy 1- Sc »n SS4

0.00 mm.91

50 51 £0 6365 74 77 S4 89"^.^ ^ ( f -^ / X ^

'' ' 'l ' 1 ' l 1 I' l ' l ' l 1 | I ' l ' l ' l | 1 I ' M l ' l ' n -50 60 70 83 93

1 ,3 ,S-Cyc lohsptatrien* ican 889

26 28 32 5*45">.i. .-' .,1 x

20 30 40

C'.'c lobu t«n« . •3-Bpk fib 9999

JU• 10

26 27 3

20 30 49

9.00 mm.91

50 51 60 63*574 7784 89. > rf. "^ . , i. f, ^ .' ^ > .• '-*SB 60 70 ' 30 ' 90

prop*nyl id*n«- ^c*n 8830.08 mm.

•si

58 51 63 *5 77 39~

. . , . . . . , 1 . . - , . . . . , . . i i j ..50 6© 70 88 ?0

Data File: >G9054::U7Name :Miac Data: CA1892C .QC70092 ,L:M6, 920,2RT •' mm V : 4.75Scan: 2?rtrea: 123244 Rank: 10S e m i - q u a n t i t a t i v e Cone (uncorrected"1: ^.?2 UG--''t1LSemi-quan t i t a t i ve Cone ( corrected ): 11.99 ug-'lCalculated using Istd: d4-1,4-Dichlorobensene I? 10.77 minute*

1. Benzene, methyl-2. 1,3 ,5-Cycloheptatri*ne7. Cyclobutene, 2-propenylidene-

92 C7H9$2 C7H892 C7H8

Sample f i l e : 'G9054 Spectrum #:Search speed: 2 T i l t i n g option: S No. of ion ranges searched: 46

Pr-ob.

•33*83*70*

CAS

103387

CON ROOT

NB'349KNBS49KNBS491-

K DK #FLG TILT CON

67 18 1000 10 0

338

Flit >C90S4 CP1892C ,OC79e92 ,L :M6 , 9 Scan 202Bpk Ob 9999 . SUB NRM 7.95 min.

,10000-

8090-

&0eo-4090-2090-

0-

43 85

39/

,1'30' " '40

57"/ -a ?1•' I ^9 "

..... MUfT....... ...!.-.50 60 70 80

se .39 !0oX "'v .-"' Ui

• M i ' i i'f'' i i < | I'i90 100 110

r

-100

-60

-60

-40

-20

-0

Fil» NBS49K P*ntanoic acid, £ ,2-dim*thy 1- , ethen^l *ster >c»n 9601Bpk fib 9999 0.03 mm.

10900-

80Q0-

6000-

4000-

2000-

O-

43

41

29 ^/

. \

^'S5

55 f 69 7|

. . 'ill'.. ,.llrX ,.36 U3/ ,;

36 40 50 60 70 SO 90 1G0 110

-100

-30

•60

-40

-20

-e

Data File: >G90?4::U?Name :Mi5c Data: CA1SQ2C ,QCxOG92,L:M6, ^20,2PT .(.mm) : 7.95Scan: 202nrea: 121*464 Rank: 11Sem i -quan t i t a t ive Cone f. uncorrected): 9.23 UG--T1LSem i -quan t i t a t i ve Cone C corrected 1 : 11.36 ug-' 1Calculated using 15. t d : d4- 1 ,4-Dich lorcbenzene il 10.77 minutes

BTL#20

1. Pentanoic acid, 2 ,2-dimethyl- , ethenyl ester 56 C9H1602

1 e f i l e : . iSearch speed: 2

Spec t rum ft:T i l t i n g option: S

202No. of ion ranges searched: 45

Prob. CrtS ft CON ft POOT V. DK ftFLG TILT S CON C_I R.I1.1

1. 41 4-.9"005Q 6671 NBS49K 76 46 2 0 100 '-2 17 12

339

IBSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

ERA SAMPLE NO,

Lab Nama: ETCNJ

Lab Coda: Casa No.:


Samp la wt/vol: 940.0 Cg/mL) ML

Level: (low/mad) LOW

% Moisture: not dac. dac.



Contract:

SAS No.: SDG No.:


Lab File ID: >G9078

Date Received:

Data Extracted: 10/11/89


Dilut ion Factor: 1


108-95-2——————Phenol___________________111111-44-4——————b is (2-Chloroe thy Dether____11199-57-8———————2-Chlorophenol____________111541-73-1 — ————— 1,3-Dichlorobenzene________111106-46-7——————1,4-Dichlorobenzene________111100-51-6 —————— Benzyl alcohol____________11195-50-1 ———— — — 1,2-Dichlorobanzena________11195-48-7———————2-Methyl phenol____________111108-60-1-——————bis(2-Chloroisopropyl)ether_l11106-44-5 —————— 4-Me thy! phenol____________111621-64-7--------N-Ni t roao-d i-n-propylamine_I 1167-72-1——— ——— -Hexachloroethana__________I 1198-95-3 ——————— Nitrobenzene______________I 1178-59-1 —— —— — -Isophorone________________11188-75-5 ——————— 2-Nitroph*nol_____________111105-67-9 —————— 2,4-Di methyl phenol________11165-85-0- ————— — Benzoic acid______________153111-91-1 —————— bis(2-Chloroethoxy)methane_111120-83-2 —————— 2,4-Dichloropheno1________111120-82-1 —————— 1,2,4-Tr ich lorobenzene_____11191-20-3 ——————— Naphthalene_______________HI106-47-8 ——— - —— 4-Chloroani 1 ina _____I 1197-68-3 ——— —— --Hexachlorobutad iene________I 1159-50-7———————4-Chloro-3-methylphenol____11191-57-6 ——————— 2-Methyl naphtha lane________I 1177-47-4———— ——— Haxach lorocyc 1 open tad iene__11188-06-2——— — —— 2,4,6-Tr ich loropheno 1______11195-95-4———————2,4,5-Tr ich loropheno 1______15391-58-7- ———— ---2-Chloronaph thai ana________11188-74-4———————2-Nit roan i line____________153131-11-3 —————— Dimethylphthalate_________1112 08-96-8-- — —— -Acenaph thy Iene____________111606-20-2 —— - — --2,6-Dini trotoluene_________111

Q

IU1UIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU

FORM I SU -1 1/87 9 Q.

• 1CSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:



Level: (low/mod) LOU


Extract ion: (SepFXContxSonc) CONT


Contract:

SAS No.:

I

SDG No.:


Lab File ID: >G9078

Date Received: ,$fe7/^f

Date Extracted: 10x11/89

Date Analyzed: 11x16/89

Dilut ion Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L OP ugXKg) UGXL

99-09-2 ——————— 3-Nitroani1 ine____________15383-32-9- ————— — Acenaphthene______________11151-28-5 ——————— 2,4-Dinitrophenol_________153180-02-7——————4-Nitrophenol_____________153132-64-9 —————— Dibenzofuran______________I 11121-14-2 —————— 2,4-Dinitro toluene________11184-66-2———————Diethylphthalate__________I 117005-72-3 ———— --4-Chlorophenyl-phenylether_11186-73-7———————Fluorene_________________111100-01-6 —————— 4-Nitroani 1 ine____________153534-52-1---————4,6-Dinitro-2-methylphenol_15386-30-6- — ——— — N-Nitrosod iphenylamina (1)_111101-55-3 —— — —— 4-Bromophenyl-phony let her__I 11118-74-1 — - —— — Hexachlorobenzene_________111g7-86-5-- — - —— -Pentach lorophenol_________15385-01-8 — -- —— --Phenan throne______________111120-12-7——————Anthracene________________111B4-74-2 ——————— Di-n-butylphthalate________I 11206-44-0 —————— Fluoranthene______________111129-00-0 ——————— Pyrene_____________________I 1185-68-7———————Butylbenzylphthalate_______! 1191-94-1 ——— ———— 3,3'-Dichlorobenzidine_____12156-55-3----- —— -BenzoCa )anthracene________I 11218-01-9 —————— Chrysene_________________I 11117-81-7——————bis(2-Ethylhexyl )ph thai ate_I 11117-84-0 —————— Di-n-octylphthalete________111205-99-2 ———— ---BenzoCb)f luoranthene_______111207-08-9—————--BenzoCk)f luoranthene_______11150-32-8---------Benzo(a )pyrene____________111193-39-5——————Indeno(l,2,3-cd)pyrene_____I 1153-70-3- — -- — — Dibenz(a,h )anthracene______111191-24-2--- — ---Benzo(g,h, i )perylene_______111

CD - Cannot be separated from 0 ipheny lam me

IIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU

FORM I SY -2 1X87 Rev

J91



ERA SAMPLE NO.

Lab Name:ETCNJ

Lab Code: Case No.:

Matrix: (soiI/water)UATER



\ Moisture: not dec._____ dec.___


GPC Cleanup: (Y/N) N oH:

Number TICs found: "7

Contract:

SAS No.: SDG No.:

Lab Sample ID: CA19Q7C

Lab File ID: >G9078

Date Received:



Dilution Factor: /


CAS NUMBER

01.02.03.04.05.06. 141-78-607. 141-79-7

COMPOUND NAME

UNKNOWNACETONE DIMERUNKNOWNUNKNOWNUNKNOWNAcetic acid, ethyl ester3-Pen ten-2-one, 4-methy 1-

RT

10.896.4115.3222.1011.844.935.15

EST. CONC

2301305181332712

Q

JBJ •JJJBJJ

FORM I SU-TIC 1/87-•ft*

TOTQL ION CWBQMflTQCBOMFlit > 69678

1868888-

1666888-

1480000;

1200008-

1 888880-

800088-

600088-

48888»•

200000-

a.

35.6-509.0

4^0

ft«U. CR1907C ,QC7B8«7,ttPTIC

*, 6^8 _ 1288 , 16,88 ( 20,80

S ?3. i B

^

i

ii13"

\ I*| I I TJ

« J•i

k

i i Ji •k—5T

b

1 <J! ••k

r i'2 '

| _

1 | I f

| '

1"|

f !

[ 1 15 I5 i i £•t 5 J ^el

U . . . . . . . . . . . . . . .J j : 1 1 *

f * H 1 .1 . I T ?

16 20 24 28 32 36 40 44

Data File: >G9078::U4Name:Hisc; CA1907C ,QC70087,L:M6,940,2


Operator ID: CA3875Quant Time: 891116 17:14Injected at: 891116 16:27

Quant Output File: AG9Q78::AQ

BTI_# 4

393

Operator ID: CA3875Output File: "G9078::AQData File: >G9078i:U4Name:Misc: CA1907C ,QC70087,L:M6,940,2


Compound

QUANT REPORT


Di lut ion Factor

Page 1

991116 17:14891116 16:27

1.00000

BTL# 4


1)3)5)12)17)18)32)36)50)52)54)65)67)73)

*d4-l,4-Dichlorobenzene2-Fluorophenol CSURR)Phenol-05 (SURR)N-Ni t rosodi -n-p ropy lam ine

•dS-Naphtha leneNitrobenzene-05 CSURR)

•dlO-Acenaphthene2-Fluorobiphenyl (SURR)Fluorene2,4, 6-Tr ibromophenol CSURR)

»dlO-Phenanthrene»dl2-ChryseneTerphenyl-D14 (SURR)

»d!2-PeryIene

10.7.10.12.14.12.19.17.22.22.24.32.29.36.

5843123137318298

2625242725

34318832042R*+^O529428797702917917

1015140912621605

259179390982474592K IT5QO

609744338588278999429951

5071733872203389138113798154720

40.75.74.

40.39.40.35.. o

76.40.40.64.40.

000275

00320019•t*-0100003900

UG/MLUG/MLUG/MLUGVMLUG/MLUG/MLUG/MLUG/ML

• US*1 1'lLUG/MLUG/MLUG/MLUG/MLUG/ML

9993911R

93939999

9598989399

* Compound is ISTD

334

FiU >C9878Bpk Rb 9999

CB1987CSUB NftH

.QC78087.Ltn6.948 Scan18.89

358• in.

43

1 3^28 ' 46

FiU NBS49KBpk Ob 9999

55 7l 85 ®fl

lii|'rtUfihi»piw*| i*|ihi i"66 60

99 115 130 143158

180 120 140

2-Butanol, 3-«»thyl-f act tat* Scan0.00

I4781• in.

43

] 15 28

e^rr^M'hiin'f'

i56 70 8fi 87

f . . , .-,( .,•,,. .'I'.-. . . iT^Cn . .60 86

us 130

100 128 148 '

FiU HBS49K 2H-Pyran-2-on* , t»tranydro-4-hydroxy-4-»»thyl ScanBpk Ab 9999 8.88

f.4615• in.

4,3

.1, , ,28 40

FiU NBS49KBpk flb 9999

^8 f 85^ 87

fl.|l'l1'IV...ti|U..,7l'.iiC..60 80

flcetic AC Id, *thyl

183 112 138/ ** f

T, f, ,, ,| 'in-l 1 1 1 1 1 1 1 1 1 VI 1 | 1 1 1

188 128 140

tst*r Scan0.86

I7S7

min.43

i 26 J? 61 70 86

•J..,77iiJi'..M,J* —— j — t-> —— ————————————20 40 •".".JJ-T-ft————T- 188 ' 128 ' 148 '

IData File: >G9078::U4Name:Misc Data: CA1907C ,QC70087,L:M6,940,2RT Cmin): 10.89Scan: 398Area: 2807412 Rank: 1Semi-quantitat ive Cone (uncorrected):Semi-quantitative Cone ( corrected ):

108.12230.05 ug/l

BTL* 4

Calculated us ing Istd: d4-l,4-Dichlorobenzene @ 10.98 minutes

1. 2-Butano I , 3-methyl-, acetate2 . 2H-Pyran-2-one , tet rahydro-4-hydroxy-4-methy1-3. Acetic acid, ethyl ester

130 C7H1402130 C6H100388 C4H802

Sample file: >G9078 Spectrum *:Search speed: 2 T i l t i n g o p t i o n : S


1.2.3.

Prob.

37*35»

CAS 4

5343964503480141786

CON * ROOT

730343152197

NBS49KNBS49KNBS49K

K

252220

DK #FLG TILT

507458

7510076

CON C_I R_

272731

141412

141214

595

Fil* >G9078 CR1987C ,0070007 ,L if16 ,940Bpk fib 9999 SUB NRH

43

8008-

4999-

0-

59+** 101.L..\

" ' ' ' 40 ' 60 ' 120 ' 160 ' 299 ' 248Fil» NBS49K 2-P»ntanon«, 4-hydroxy-4-n«thyl-Bpk fib 9999

43

8880--.

4999-

8-

31\

59

J "" 18J 102

' ' |l4lt " ' • ' 80" " • 'itt ' " " i60' • " '200 • " "240'

Fil* NBS49K Hydrop«roxid* , 1 , l-dinithyl«thylBpk Ob 9999

S9

8000-

4000-

43 |/ 1

31

>|J 89

' * 40 ' 88 ' 120 ' 160 ' 200 ' 240

Scan 1386.41 min.

289X

•00

-40

-A' 280Scan 28510.88 Bin.

'"280

•80.-48

•0

Scan 8478.08 «in.

•-80

-40

A'"280

Data File: >G9078::U4Name:Misc Data: CA19Q7C ,QC70087,I_: M6 ,940,2RT Cmin): 6.41Scan: 138Area: 1638142 Rank: 2Semi-quant i tat ive Cone (unconnected):Semi-quant i t a t i we Cone C corrected ):

63.09 UG/ML134.23 ug/1

BTL* 4

Calculated using Istd: d4-l,4-Dichlorobenzene @ 10.58 minutes

1. 2-Pentanone, 4-hydroxy-4-methyl-. 2. Hydroperoxide, 1,1-dimethylethyl

116 C6H120290 C4H1002

Sample F i l e : >G9078 Spectrum #:Search speed: 2 T i l t i n g option: S


1.2.

Prob.

7825

CAS * CON *

12342275912

17901733

ROOT

NBS49KNBS49K

K

4334

DK #FLG TILT

4031

7237

CON C_I R_

450

557

1412

396

Flit >C9Bpk Rb 9

11000-

10000-

9000-

9000:7000-

6000:5000:4000:

300*

2000:

9-

09

1

79 CA1907C .QC70007.Lin6.940 Scan99 SUB NRH 16.32

•43

'

71 87

I oa *«By 115 207 231 265

00 120 160 200 240

E76• in.

rll0

•100

40

«0

-70

40

€0

•40

•30

•20

•10

Data File: >G9078::U4Name:Hisc Data: CA1907C ,QC7Q087,L:M6,940,2RT (min): 15.32Scan: 576Area: 755457 Rank: 7Semi-quantitat we Cone Cuncorrected):S e m i - q u a n t i t a t i v e Cone ( corrected ):

24.18 UG/riL.51.44 ug/1

BTL* 4

Calculated using Istd: d9~Naphthalene g 14.37 minutes

No PBM hits for thia scan.

337

FtU >C9078Bpk fib 9999

43

1 I 2j 1 A\T 9eJ . , , ... . ..T ,.

40 80

CA1907C .QC70087.LiM6.940 Scan 909SUB HUM 22.10

9 / 130 *41 167 169 i?3 213^Sy ^ ^ / / ^ E ^

120 ' 160 200

File NBS49K S-OCTflNONE-N-HETHYL-N-FORMYLHYBRflZONE ScanBpk Rb 9999

43 73

1 ' " if •.L....U'....40 80

0.00113' 1S6

9 120 14l X

184

^1 (^ / - r"

• in.

jn

1S463• in.

r.120 ' 160 200

Fll* NBS49K Undtcan*, 4,6-dinttthyl- ScanBpk fib 9999

S7

1 4/3 f 71

44*,-»l 4 T-T-t940 ' 80

Fll» NBS49K Octan*Bpk flb 9999

57•j 43 ( 7\1 *9 ' \ f*3 ' .1 J 8

fJ J. ,,1 -J. .._! ...-^-40 80

0.00

3 U3 MI IS5 iQ4

^ . / if / <^120 ' 160 ' 280

, 3.6-dl»*thyl- Scan0.00

& 113 127 142

120 ' 160 ' 200

16603• In.

FI6880• in.

L

Data File: >G9078::U4Name:Misc Data: CA1907C ,QC70087,L:M6,940,2RT Cmin): 22.10Scan: 909Area: 996986 Rank: 9Semi-quanti tat ive Cone Cuncorracted):Semi-quant itative Cone ( corrected ):

37.84 UG/ML80.52 ug/1

Calculated using Istd: dlO-Phenanthrene @ 24.25 minutes

BTL* 4

1. 3-OCTANONE-N-METHYL-N-FORMYLHYDRAZONE2. Undecane, 4,6-dimethy1-3. Octane, 3,6-dimethyl-

184 C10H20N20184 C13H28142 C10H22

Sample f i l e : >G9078 Spectrum #:Search speed: 2 Tilting option: S


1.2.3.

Prob.

36»25»20*

CAS '•

617481941731282215869940

CON * ROOT

12427438712333

NBS49KNBS49KNBS49K

K

282733

DK #FLG TILT CON C_I R_IV

577156

799888

295054

1475

1?

16

658

Fil» >C9078 * CR1907C .QC70007 .L 1(16 ,940 Scan 405Bpk Ob 9999 SUB NRM 11.04 *in.

., 4310080-

8000-

6008-

4000-

2000-

0-•«.,

/' r. ,)' ' " ' 4'0" " ' " "60 " " " 80 " ' ' " 'l(

i I12 13i .** IS5Lx \ v0 \'iM'iffiMji'i't'ti'iiii |'ii mi?30 120 140

-100

•60

•60

•40

-20

-0

F'l» NBS49K l-P»nt»n-3-ol, 2-ntthyl- Scan 1385Bp» fib 9999 0.00 «m.

7110000-

8000-

6080-

4000-

2000-

0-

Vz?/ ^ 6\i .. l.i, l.i . l.t,

X"

®.5 100

... . ..,1.., ! ...... w..., ..w...,...

r

101X0 ' 1^0 ' 140

-100

•e0-60

-40

-20

-0

Data Fi le: >G9078::U4Name:disc Data: CA1907C ,QC70087,L:H6,940,2RT (min): 11.84Scan: 405Area: 397532 Rank: 10Semi-quantitative Cone Cuncorrected):Semi-quantitative Cone ( corrected ):

15.31 UG/HL32.57 ug/1

BTL# 4

Calculated using Istd: d4-l,4-Dichlorobenzene @ 10.58 minutes

l-Penten-3-ol, 2-methyl- 100 C6H120

Sample file: >G9078 Spectrum #:Search speed: 2 Tilting option: S


Prob. CAS * CON # ROOT K

1. 5* 2088075 4271 NBS49K 25

DK #FLG TILT S CON C_I R_l«J

35 2 0 20 50 7 14

699

FlU >G9078 ' CA1907C ,0078887 ,L iH6 ,940 Scan 66Bpk fib 9999 SUB NRH 4.93 »in.

43

8600-

4080- 79 08 364

L^l L S V .'" S'0 ' 100 ' 150 ' 200 ' 250 ' 300 ' 350 ' 40

-60

-46

•00

FiU NBS49K Acetic acid, tfhyl »«t»r Scan 767Bpk fib 9999 0.00 Min.

43

8000-

4008-

i / ?\ i. i

-ee-40

4''"50" "'" V00"'I"T150' """200 "'" 253 "'"'300' "'" 360 "'"400

Fil* NBS49K Propanoic acid, 2-«»thyl- Scan 756Bpfc Ob 9999 0.00 Kin.

43i /

6000-

4000-

0-

1 J 7 88

i, «.„„,, „,„.,„,„ ,,...„„.,,„..,,„,„„ ,60 100 150 200 250 300 350 40

•68

-48

•00

Data Ft 10: >G9078::U4Name:Miac Data: CA1907C ,QC70087,L:M6,940,2RT Cmin): 4.93Scan: 65Area: 327002 Rank: 12Semi-quant i tative Cone (uncorrected):Semi-quantitative Cone C corrected >:Calculated using Istd: d4-l,4-Dichlorobenzene @ 10.98 minutes

BTL* 4

12.59 DC/ML26.80 ug/1

1. Acetic acid, ethyl ester2. Propanoic acid, 2-metnyl-

88 C4H30288 C4H802

Sample file: >G9078 Spectrum #:Search speed: 2 Tilting option: 5

'65No. of ion ranges searched: 46

1.2.

Prob. CAS #

60* 14178652» 79312

CON #

21974798

ROOT

NBS49KNBS49K

K

2828

DK

5061

*FLG

12

TILT

00

\

7267

CON

1518

C_I

3020 14

4CG

Fil* >G9078Bpk fib 9999

43 ss

1

0-3 , , . , JA--H f . . . . . . . . . . . _-T_T . . . . . . . .

CR19B7C ,QC70e87 (LtM6,940 Scan 76SUB NRM 6.15

83^^ff

70 .99 219.-'. ..L \^

• In.

J,4« B0 120 160 2B0

FlU HBS49K 3-P*nttn-2-on» , 4-»«thyl- ScanBpk flb 9999

5543 /

1 29 ^

40

0.0083

79 .99,.r>il., , , I T T , , , , , . , . . . M . . i . . . . . . .80 120 160 200

FiU HBS49K Cyc loprop*n* , 1 , 1 ,2 ,2-t*tra«*thyl- ScanBpk flb 9999

55-. 4l 'K i0X|, ,! ,iM., ...IjU.mi.rl ^

40

FiU NBS49KBpk fib 9999

41 SSJ / /

ii|i* |Jit|i *npir-f 4" r' 40

0.0083

67 99

80 ' tae ' 160 ' 2002-Ptnt«n*. 2,3-di«»thyl- Scan

0.00

83

r f ^80 120 160 200

1177• in.

I1227• in.

L1194• in.

IData File: >G9078::U4Name:Misc Data: CA1907C ,QC70087,L:M6,940,2RT Cmin): 5.15Scan: 76Area: 149729 Rank: 13Semi-quantitative Cone Cuncorrected):Semi-quantitat we Cone ( corrected ):

5.77 UG/ML12.27 ug/1

BTL*

Calculated us ing Istd: d4-l,4-Dichlorobenzene @ 10.58 minutes

1. 3-Penten-2-one, 4-methyl-2. Cyclopropane, 1,1,2 ,2-tetramethy1-3. 2-Pentene, 2,3-dimethy 1-

98 C6H10098 C7H1498 C7H14

Sample file: >G9078 Spectrum #:Search speed: 2 T i l t i n g option: S


Prob. CAS * CON #

1. 72* 141797 61402. 70» 4127473 61493. 7Q» 10574375 9446

ROOT

NBS49KNBS49KNBS49K

K

614340

DK #FLG TILT \ CON C_l R_!'.'

315461

809293

3296

324242

401


ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Contract:

SAS No.:



Love 1: (1ow/med) LOU

K Moisture: not dec. dec.

Extract ion; (SepF/Cont/Sonc) CONT


SDG No.:


Lab File IQ: >G9055

Date Received: /*





I108-95-2 —————— Phenol___________________112111-44-4——————bis(2-Chloroethyl >ether____11295-57-8———————2-Chlorophenol____________112541-73-1——————1,3-Dichlorobenzene________112106-46-7——————1,4-Dichlorobenzene________112100-51-6 —————— Benzyl alcohol____________11295-50-1- —————— -1,2-Dichlorobenzene________11295-48-7———————2-Methyl phenol____________112108-60-1————-bis(2-Chloroisopropyl)ether_l12106-44-5 —————— 4-Methyl phenol____________I 12621-64-7—————--N-Nitroso-d i-n-propylamine_I 1267-72-1 — -- ——— -Hexechlo roe thane__________I 1298-95-3 ——————— Nitrobenzene______________11278-59-1 ———— ——— Isophorone________________I 1288-75-5 ——————— 2-Nitrophenol_____________112105-67-9 —————— 2,4-Di methyl phenol________11265-85-0 ——————— Benzoic acid______________159111-91-1 —————— bis(2-Chloroethoxy)me thane_I 12120-83-2 —————— 2,4-Dichlorophenol________112120-82-1——————1,2,4-Tr ich lorobenzene_____I 1291-20-3 ——————— Naphthalene_______________112106-47-8 —————— 4-Chloroani line___________11287-68-3 ——————— Hexach lorobut ad iene________I 1259-50-7———————4-Chloro-3-methyl phenol____I 1291-57-6———————2-Methyl naphtha Iene________11277-47-4————•——Hexach lorocyc 1 open tad iene__I 1288-06-2 ——————— 2,4,6-Tr ich loropheno 1______I 1295-95.4————— —— 2,4,5-Tr ich loropheno 1______15991-58-7———————2-Chloronaphthalene________11288-74-4———————2-Nitroani 1 ine____________159131-11-3 —————— Dimethylphthalate_________112208-96-8 — -- —— -Acenaph thy lane____________112606-20-2 — -- — — 2,6-Dinitro toluene________I 12

Q

IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

402FORM I SU -1 1/87 Rev.

Lab Name: ETCNJ

Lab Code: Casa No.:



Level: (low/med) LOLJ



6PC Cleanup: <Y/N) N pH:

Contract:

SAS No.: SDG No.:


Lab File ID: >G9Q55

Date Received:



Dilution Factor! 1


99-09-2 —————— •83-32-9 —————— -51-28-5 —————— -100-02-7 ————— -132-64-9 ————— -121-14-2 ————— -84-66-2 —————— •7005-72-3 ———— -86-73-7 —————— -100-01-6 ————— -534-52-1 ————— -86-30-6 —————— -m RR T

118-74-1 ————— -87-86-5 —————— •85-01-8 —————— -120-12-7 ————— -84-74-2 —————— •206-44-0 ————— -129-00-0 ————— -85-68-7 —————— -91-94-1 —————— -CA-KR-"?--------

218-01-9 ————— -117-81-7 ————— -117-84-0 ————— •205-99-2 ————— -207-08-9 ————— -50-32-8 —————— -193-39-5 ————— -53-70-3 —————— -191-24-2 ————— -

•-3-Nitroani 1 ins--Acenaphthene— 2 .4-Dini t rophenol•-4-Ni trophenol•-Dibenzof uran--2 .4-Dini tro toluene--Diethylphthalate „•-4-Ch loropheny 1-pheny let her _--Fluorene , . ,„.— 4-Ni troani 1 ine— 4,6-Dini t ro-2-me thy 1 phenol _--N-Ni trosodipheny lamina (1 )--4-Bromopheny 1-pheny lather __--Hexachlarobanzana— Pentach loraphanol'-Phenanthrana IIH— Anthracene--Di-n-butulohthalate--Fluoranthana , ,--Purene--Butulhanzulphthalata.-3.3 ' -Dich larobani id me--Ban7a(a)anthracena•-Chryaane--bisC2-Ethylhexyl )phthalate _•-Di-n-octylphthalate--Ban^of h)f luo ran thana.-Bansotk 1 f luo ran t hena.-Ban-roCalpyrana-- Indeno( 1 f2 . 3-ed )purane_-nih«n» (*;hl«nthp«eana.-RanTnrf]|h| i Iparylana

5912595912121212125959121212591212121212122412121212121212121212

1IUIUIUIUIUIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU1

CD - Cannot be separated from Diphanylamine


4C3



EPA SAMPLE NO..

Lab NameiETCNJ

Lab Code: Case No.:

Matrix: (soi I/water )UJATER


Level: ( low/med) LOLJ

X Moisture: not dec._____ dec.____



Number TIC» found: 5

Contract:

SAS No.: SDG No.:


Lab File ID: >G9055

Date Received: /



Di lut ion Factor: /


CAS NUMBER

01. 141-78-602.03.04.05. 108-88-3

COMPOUND NAME

Acetic acid, ethyl esterACETONE DIMERUNKNOUNUNKNOWNBenzene, methyl-

RT

5.176.457.868.894.34

EST. CONC

810150231915

Q

8JBJBOBJJ


TOTAL ION CHROMATOGRAHFlit >690S6

1600000-

1400000-

1200000-

1000000-

800000-

600000-

480000-

-200000-

J

4 '

36.0-500.0 MU. T. Cfti«9C ,6C76H2;r;TIC

t *i t t 80,0 ( 1280 t 1600 , 2000

f ~i 1

[

! SKl1

II

f

!>!

(\

«**

§ ffs&

j '

fe !

|i|irt ' \ I f i s

f '• i * "1i 1 f j *1 I T T S

8 12' ' l'6 20 ' 2'4 ' 2'0 ' 32 ' '&' ' V0' ' ' 44 •

Data File: >G9055::U3Name:Misc: CA1908C ,QC70092,L:M6, 850,2

Id File: IG0130::PFTitle: IFB/BNA, PPxBNALast Calibration: 891119 12:26

Operator ID: PT1575Quant Time: 891115 13:34Injected at: 89111? 10:01

Quant Output File:

BTL*2 1

405

Operator ID: PT1575Output File: "*G9059::AQData File: >G9055::U3Name:Miac: CA1908C ,QC70092,L:M6, 950,2

ID File: IG0130::PFTitle: IFBxBNA, PPXBNALast Calibration: 89111? 12:26

Compound

QUANT REPORT


Di lut ion Factor

Page 1

891115 13:34891115 10:01

1.00000

BTL#21

R.T. Scan* Aree Cone Units

1)3)5)12)17)18)32)36)50)52)54)65)67)73)

*d4-l,4-Dichlorobenzene2-Fluorophenol CSURR)Phenol-05 (SURR)N-Ni trosodi-n-propylamine

»d8-NaphthaleneNitrobenzene-05 CSURR)

*dlO-Acenaphthene2-Fluorob iphenyl CSURR)Fluorene2, 4, '6-Tr ibromopheno 1 CSURR)

*dlQ-Phenanthrene•d!2-ChryseneTerphenyl-D14 (SURR)

*d!2-Perylene

10.7.10.12.14.12.19.17.22.22.24.32.29.36.

6447113540358794312928303231

3461903204305314308007059209191017141212651609

24271735045844114945953490791296434163346306847

29696120831430468445023102

407873•&40434044

4740407040

.00

.09

.28

.00

.91

.00

.57*W-.61.00.00.74.00

UGXMLUGXMLUGXML-UCVMLUGXMLUGXMLUGXMLUGXMLUfr'MLUGXMLUGXMLUGXMLUGXMLUGXML

879193

94969999

9596989393

* Compound is ISTD

406

Fil* >G9055Bpk fib 9999

8080-

4060-

^

25~

38 4i

\..

CP1908C ,QC7d092,Lit16, 8 Scan 77SUB NRM 5.17 min.

43X

•

\SS 7l3 73

.,/.?..N."V/ \r/ T

.-63

•40

-Ct38 35 48 45 58 55 68 65 78 75 98 35' 98

Fil* NBS49KBpk Ob 9999

8880-•

4000-

flJ

29

A c e t i c acid, »thyl ester Scan 7570 .90 niin .

43

27 / 4s2

,2'5

I ' l l — — - ..i|.|.

V / / S8.1 1 x < ^

-80•-48

-Q38 35 40 45 56 55 68 65 70 75 30 S5 90

File NBS49K Propanoic acid, 2-*ethuI- Scan 756Bpk flb 9999

3808-

0 .00 <n in .43

J 27 414880-

a- i25"

2,9 36/ \\i t . . . I .30 35 40

1

73

47 6f )8 71 / 88i 1 ' . - f . ,i

-90•-40

-a45 50 55 60 65 70 75 S 9 85 90

Data F i l e t >G9Q55::U3Name :Misc Data: CA1908C .QC70092 ,L: (16 , 3?0,2RT (min): 5.17Scan: 77ftrea: 7902898 Rank: 1Semi -quan t i tat ive Cone (.uncorrec t ed ) : 745.10 UG-'TILSemi-quant i tat i ve Cone <'. corrected ): 812.00 ug'ICalculated using Istd: d4-1,4-Dichlorobenzene @ 10.64 minutes

1. Acetic acid, ethyl ester2. Propanoic acid, 2-methyl-

38 C4H3CI288 C4HS02

Sample f i l e : >G90?? Spectrum ft:Search speed: '2 T i l t i n g option: '3 No. of ion ranges searched:

Prob. CAS 4 CON # ROOT

1. 60* 141736 2197 NBS49K 27 5125* 7° 712 4^*3 fJES49K 20 69

tFLG TILT "B CON C_I P_I'J

15 30 1 ?0 690 64 13

407

Fil» >G9055Bpk fib 9999

3009-

4009-

.*•30

%

CA1908C ,QC70092,LiM6, 8 Scan 140SUB NRM t,.4E win.

43

It

59

S\,83 98 101 116

69 77 / \ / s./ / / > | X20 ' 40 ' 60 ' 30 ' 100

-30

-40

-0

Filt HBS49K 2-P»nt»non», 4-hydroxy-4-m«thwl- Scan 2851Bpk Rb 9999 ' 0.30 mm.

8000-

4000-

0-

31

43

59: "., 73 83 98 t0l 102

20 40 66 ' 30 i0'0

-80

-40

-0

Fil» HBS49K Hvdrop*roxid». 1 , l-dim»thvl*thvl Scan 847Bpk Rb 9999 0.00 mm.

3009-

4000-

0-

3115 27 f

..(. ,( ,..,.

59

43

1

55

. N.ll

73 89/ X

• 20 40 60 30 100

-80

-40

-0

Data File: >G9055: : U3

Misc Data: CA1908C ,QC70092 ,L: M6 , 850,2RT (mirO: 6.4?Scan: 1**0Area: 1475034 Rank: 2Sern i -quant i tat ive Cone (uncor rec ted ) : 64.41 UG/MLSemi -quant i tat we Cone ( corrected ): 151.56 ug/1C a l c u l a t e d u e i n g I s t d : d4-l ,4-Dich lorobenzene @ 10.64 minutes

BTL#21

t i.. 2-Pentanone, 4-hydroxy-4-methyl-2 . Hydr ope ro.» ide , 1,1-d ime thy Is thy 1

116 C6H120290 C4H1002

Sample f i l e : •G9Q55 S p e c t r u m *:Search speed: 2 T i l t i n g o p t i o n : S


1.

Prob .

70

CAS ••

127422""5912

CON #

1790177J

ROOT

NBS49KHBS49K

K

4374

DK

4071

TILT * CON C_I P_IU

0 74 6 42 14425

4G8

Fii« >G90SS CA1908C ,QC78092,HM6, 3 Scan 209Bpk flb 9999 . SUB NRM 7.86 min.

.10000-

8000-

6000-

4009-

2008-

43 85

|

'

L471

112 v. / .

50 180 158 280 258 308 350 400 450

-100

•eaH40

-48

-28

-8

Fil* NB349K P*nt»noic *c i d , 2 ,2-dim*thy 1 - , *th*nyl *st*r 5c*n 9601Bpk flb 9999 0.00 min.

_10000-

•3800-

6000-

4008-

2380-

0-

43

u

f35'

113 114

•58 108 150 200 250 380 350 400 45©

r

-100•H50

-60

-40

-20

-0

Data Fi le: ^G905?: : U?Name :Misc Data: CA1908C .QC70092 ,U M6 , 3?RT Cm in): 7.96Scan: 209ttrea: 219231 Rank: 9Sem i -quant i tat we Cone (uncor rec t cd ) :Semi -quant i tat we Cone t corrected ):

9. £9 UG/tIL22.5? ug - I

BTL#21

C a l c u l a t e d using I s td : d4- l ,4-Dichlorobenzene @ 10. 64 minutes

i, 1. Pentanoic acid, 2 ,2-d ime t hy 1- ,_ ethenyl ester 156 C9H16Q2

Sample f i l e : .G9Q5? Spectrum #:Search speed: '2 T i l t i n g option: S


Prob. CAS # CON # ROOT K DK

1. 52 44970050 6671 NBS49K 36 46

TILT \ CON C_I R_IU

2 0 V8 20 20 12

4G9

Fil# >G9055Bpk flb 9999

43i Y s-0J, M . I M I l| I li'l'lM'l ,lt'|Vl'l

20 40

CR1908C ,QC70092,LiM6, 8 Scan 260SUB NRM 8.89 mm.

71

c 33"63 / 91 103 112 113

H3

60 ' 80 ' 100 ' 120

Fil» N8S49K l-Prop#n«, 1-chloro-, r 2 ) - ScanBpk Rb 9999

41

3 15 27 I 49 6(

0 I'l'l r't I l*'i'i i I'l'l' 'l i tt'l'i P '20 40

3440.00 min.

763 61 ' 79

"M*''' ' ii I*'1 'h ii 1 1| 1 1 ii i ii i ii 1 1 ii i ii 1 1b0 80 100 120

•

Til* NBS49K Butanoic acid, 2-prop»nyl #stet* Scan 4295Bpk Rb 9999

41 43

1 27 ^-j I

3 ' s0J it... •Ul.i ,,

' 20 40

0.00 nin.71^

57 69 89 99 100 113 123.... 'v*:, i.. !*^ ""^rT^" ' "^60 ' 30 ' 100 ' 120

File HBS49K l-Prop*nt, 1-chloro- ScanBpk Rb 9999

41

i 18 27 49 66«J / f >. "^B^i't'in j • .ii'i't i i •!'!' M'i »^yi-i-,

• 20 40

-•

-0

343G.Oe mm.

61 79

60 ' 30 ' 100 ' 120-0

Data Fi1*: >G905?::U3Name:disc Data: CA1903C ,QC7Q092,L:M6, 8RT (min): 3.89Scan: 260Area: 183463 Rank: 10Semi-quant i tat ive Cone 'uncorrected):Semi-quantitative Cone C corrected ):

8.01 UG/riL19.85 ug.M

Ca lcu la ted us ing Istd: d4-l ,4-Dichlorobenzene @ 10.64 minutes

1. 1-Propene, 1-chloro-, CZ)-2. Butanoic acid, 2-propenyl ester?. 1-Propene, 1-chloro-

76 C3H?C1128 C7H120276 C7H6C1

Sample f i l e : >G905? Spectrum t:Search speed: 2 T i l t i n g option: S


Prob.

*

CAS

161363482051787

CON * ROOT

5092 MBS49KMBS49KN8S49K

K DK

797

534940

TILT

i0

-1

COM C_I =?_!'..

124864

12

410

Fil* >G905SBpk fib 9999

36

91/

39

CR1908C ,QC70092,LfM6, 8 Sc»n 36;UB NRM 4.34 min.

437

100 150 200 250 300 358 400F i l « NBS49KBpk Rb 9999

91/

65

1,3,S-Cycloh»pt»tri«n«

94

100 150 200 250 300 350

£c*n 339.09 mm.

400


B*nz*n», m e t h v l - SCAD 8840.00 min.

100 150 200 250 300 350 400'

F i l « NBS49KBpk fib 9999

loout*n* , 2-

2•' >-f **.

50 180 150 200 250 300 350

Scan 3830.60 mm.

400

D a t a F i l e : . > G 9 0 5 5 : : U?Name :Misc Data: CA1908C ,OC70092,L:M6, 850/2R T i rn i n '' : H . 7 4Bean: 56*rea: 144292 Rank: ilS e m i - q u a n t i t a t i v e Cone (uncorrected): 6.70 UG-''MLS e m i - q u a n t i t a t i v e Cone ( corrected ): 14.83 ug'lCalculated using I s t d t d4-1^4-Dichlorobenzene |3 10.64 minutes

1. I ,7 ,5-Cycioheptatriene'2. Benzene, methyl-7. Cyclobutene, 2-propenylidene-

92 C7H892 C7H392 C7H8

Sample f i l e : >G9055 Spectrum #:earch speed: 2 T i l t i n g option: S No. of ion ranges searched

Prob . CAS # CON # ROOT

54425210SS83

520978558-4758474

NBS49KNBS49K(IBS49K

6/7754

DK

181725

TILT

0 10 00 560 100

CON C_I P_IU

544745

411

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:



Leva 1 : C low/med ) LOU

Contract:

SAS No.: SDG No . :


Lab File ID: >G9064

Date Received:

% Moisture: not dec dec

Extraction: (SepF/Cont /Sonc ) CONT




Di lut ion Factor : 1


I108-95-2 —————— Phenol___________________154111-44-4——————bisC2-Chloroethyl)ether____11199-57-8———————2-Chlorophenol____________111541-73-1——————1,3-Dichlorobenzene_______111106-46-7—— —— — 1,4-Dich lorobenzene________111100-51-6 —————— Benzyl alcohol____________11195-50-1- ——— —— -1,2-Dich lorobenzene________I 1195-48-7———————2-Methyl phenol____________111108-60-1-——-——bis(2-Chloroisopropyl)ether_l11106-44-5 ——————— 4-Methyl phenol_____________197621-64-7--------N-Nit roso-d i-n-propylamine__t1167-72-1- — —— — -Hexach lo roe thane__________I 1198-95-3 ——————— Nitrobenzene______________I 1178-59-1———————Isophorone_______________I 1188-75-5 ——————— 2-Nitrophenol_____________111105-67-9 —————— 2,4-Dimethylphenol________11165-85-0 ——————— Benzoic acid______;_______1390111-91-1 —— ——— -bis<2-Chloroethoxy)methane_111120-83-2 — ————— 2,4-Dichlorophenol________111120-82-1 —————— 1,2,4-Trich lorobenzene_____11191-20-3———————Naphthalene_______________111106-47-8-- ———— -4-Chloroani 1 ina ________I 1187-68-3 ———————Hexach lorobutad iene________I 1159-50-7———————4-Chloro-3-methylphenol____11191-57-6 ——————— 2-Methyl naphtha Iene_______11177-47-4——————Hexach lorocycl open tad iene__11188-06-2 ————— --2,4,6-Trichlorophenol______11195-95-4———————2,4,5-Trichlorophenol______15391-58-7———————2-Chloronaphthalene________111B8-74-4———————2-Nitroani 1 me____________153131-11-3 —————— Dimethylphthalate_________111208-96-8- — - — — Ace naph thy Iene_____________I 11606-20-2 — -- — — 2,6-Dinitrotoluene________111_______________________ ________I__

Q

IUIUIUIUIUIUIUIUIIUIUIUIUIUIUIIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU

FORM I SU -1 1/87

1 1CSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:





Extract ion: CSepF/Cont/Sonc) CONT


Cont ract:

SAS No.: SDG No.:


Lab File ID: >G9064

Date Received: /P///A





99-09-2 ——————— 3-Nitroani line____________15383-32-9 ————— — Acenaphthene______________11151-28-5 ——————— 2,4-Dinitrophenol_________153100-02-7——————4-Nitrophenol_____________153132-64-9 —— ——— -Dibenzofuran______________111121-14-2 —————— 2,4-Dinitrotoluene________11184-66-2 ——————— Diethylphthalate__________1117005-72-3———--4-Chlorophenyl-phenylether__I1186-73-7———————Fluorene_________________111100-01-6 ——————— 4-Nitroani 1 ine_____________153534-52-1 —————— 4,6-Dinitro-2-methylphenol_15386-30-6 —— ————— N-Ni t rosod ipheny lamine (1)__ I 11101-55-3 — ————— 4-Bromophenyl-phenylether__I 11118-74-1 —— - —— -Hexachlorobenzene_________11187-86-5 ——— ———— Pentach lorophenol_________15385-01-8 —— ——— — Phenanthrene______________111120-12-7——————Anthracene________________11184-74-2 ——————— Di-n-butylphthalate________111206-44-0 ———— —— Fluoranthene______________111129-00-0 —————— Pvrene ________________11185-68-7——————-Butylbenzylphthalate_______t1191-94-1 ——————— 3,3'-Dichlorobenzidine_____12156-55-3 —————— -8enzo(«)anthr«cene________111218-01-9 —————— Chrysene_________________111117-81-7—————--bisC2-Ethylhexyl)phthalate_111117-84-0 —————— Di-n-octylph thai ate________111205-99-2 —————— BenzoCb)f luoranthene_______111207-08-9 —— - — — Benzo(k) f luoranthene_______I1150-32-8 —— - — ---Benzo (a)pyrene____________111193-39-5--—————Indeno(l,2,3-cd)pyrene_____11153-70-3 — -- — — -D i benz (a, h) anthracene______I 11191-24-2- — - — --Benzo(g,h, i )perylene_______111


FORM I SU -2

IUIUIUIUIUIUIUtuIUtuIUIUIUIUIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

1/87 Rev.

413



ERA SAMPLE NO.

Lab Name:ETCNJ

Lab Code: Case No.:

Matrix: CsoiI/water)UATER

Sample wt/vol: 950.0 Cg/mDML


K Moisture: not dec._____ dec.___


GPC Cleanups CY/N) N pH:___

*r _ .1Number TICs found:

Contract:

SAS No.: SDG No.:


Lab File ID: >G9Q64

Date Received: /fl//



Di lut ion Factor: I


CAS NUMBER

01. 97-61-002.03.04. 4536-23-605. 107-92-606. 142-62-107.08.09. 98-89-510. 79-09-411. 79-31-212.13.14.15.1-6-: — 719 09 4 ———17. 111-14-818.19. 98-89-520. 501-52-021. 79-31-222. 108-94-123. 98-89-524. 108-10-125. 4536-23-6

11 COMPOUND NAME

IPentanoic acid, 2-methyl-1 UNKNOWN1 UNKNOWNIHexanoic acid, 2-methyl-IButanoic acidIHexanoic acid1 UNKNOWN1 UNKNOWNICyc lohexanecarboxylic acidIPropanoic acidIPropanoic acid, 2-methyl-1 UNKNOWN1 UNKNOWN1 UNKNOWN(ACETONE DIMERIPi-opanoic eeid ———————————— 11 Heptane ic acid1 UNKNOWN1 Cyc lohexanecarboxylic acid1 Benzenepropano ic acidIPropanoic acid, 2-methyl-ICyc lohexanonaICyc lohexanecarboxyl ic acid1 2- Pent an one , 4- me thy 1-IHexano ic acid, 2-methyl-111111

RT

11.259.2516.4012.698.90

11.6910.8011.3714.126.676.859.508.077.977.07e TlJ , . L

13.2011.8213.8517.667.017.89

14.183.74

12.31

EST. CQNC

4025220210201816141201312121088—i•6565878643944

11 Q

IJIJIJIJIJIJIJIJIJIJIJIJIJIJIBJ

-W- (IJ |lIJIJIJIJIJIJIJIJ1111

i_AI

/


TOTAL ION CMROHATOCRAMFil* >69864 35.0-580,8 *ftu.

zeeeeea-

leaaeofr

40,0 , 690 t 1200

C02144C ,QC7009Z ,Ltf

1608 2999

i2 16 ga ' 24 ' a'e ' 3*2 s6 40 44

Data File: >G9Q64::U3Name:Misc: CA2144C ,QC70092,L:M6,950,2




BTL*30

1 T,4 i b

QUANT REPORT Page

Operator IDOutput FileData File:Name:Misc: CA2144C

PT1575AG9064::AQ>G9064::U3

Quant 7 Quant TimeInjected at

Di lut ion Factor

,QC70092,L:M6,950,2

891116 12:12991115 17:58

1.00000

BTL*30

ID File: IG0130::PFTitle: IFB/BNA, PP/BNALest Calibration: 891116 12:11

1)2)2)2)2)2)3)5)6 )6 )

12)14)14)15)15)17)18)20)26)27)32)36)5 0 )52)54)65)67)73)

Compound R.T. Scan* Ar«a Cone Units

»d4-l,4-Dichlorobenzene 10.70 350 191857N-Nitrosodimethylamine 3.70 6 2368N-Nitroaodimethylamine 3.84 13 2774N-Nit rosod imethy lamine 3.98 20 4363N-Nitrosodimethylamine 4.16 29 2405N-Nitrosodimethylamine 4.53 47 29672-Fluorophenol (SURR) 7.60 198 218437Phenol-05 CSURR) 10.33 332 251594Phenol 10.25 328 4116Pheno 1 10 . 35 333 115954N-Nitrosodi-n-propylamine 12.41 434 327722-Methylphenol 12.29 428 71362-Me thy! phenol 12.41 434 1621234-Methylphenol 12.29 428 71364-Methylphenol 12.41 434 162123

»d8-Nephthalene 14.46 535 429069Nitrobenzene-05 CSURR) 12.41 434 214912Isophorone 13.32 479 6081Benzoic acid 14.89 556 214561Naphthalene 14.18 521 85574»dlQ-Acenaphthene 19.88 801 1328322-Fluorobiphenyl (SURR) 17.95 706 202511Fluorene 22.30 920 25912,4,6-Tnbromophenol CSURR) 22.30 920 36460

»dlO-PhenanthrBne 24.30 1018 129544*d!2-Chrysene 32.31 1412 54664Terphenyl-D14 (SURR) 29.32 1265 73787

«d!2-Perylene 36.32 1609 31172

* Compound is ISTD

40.00 UG/ML.946 UGj*rlL1.11 US^tlL1.?4 UC'fML.961 UC.'Ml

•i.19 UBi'MIr62.60 UG/ML55.01 UG/hL

. ™ 0«* Uo^ nL.25.45 UG/ML-12.00 UC.fML

2. 07 US^'tlL56.U.2 US^I'IL-g.09 USVML46.06 UG/ML40.00 UGXML36.34 UG/ML

?.9g UO-MIL*40.00 UG/ML36.64 UG/ML

69.78 UG/ML40.00 UG/ML40.00 UG/ML48.31 UG/ML40.00 UG/ML

911001001001001007994958539879096989391

*93829999909497999386

4 I 6

TOTQL ION CHROMPTOCRQHFile >69227 35.0-500.0

400 600 1200

C02144C ,

1600

36 40

Data File: >G9227: :U3Name:Misc: CA2144C ,QC70092,L:M6,950,20,10D

Id File: IG0134::USTitle: IFB/BNA, PP/BNALast Calibration: 891130 10:32

Op-arator ID: CA3875Quant Time: 891130 10:34Injected at: 891130 09:49

Quant Output File

BTL#25

417

QUANT REPORT

Operator ID:Output File:Data File:

Quant Rev: 7CA3875

>G9227::U3Name:Misc: CA2144C ,QC70092,L:M6,950,20,10D

ID File: IG0134::USTitle: IFB/BNA, PP/BNALast Calibration: 891130 10:32

Compound R.T. Scant

Quant TimeInjected at

Di lut ion Factor

Page 1-

891130 10:34.891130 09:49

1. 00000

BTL#25

Area Cone Units

1)2)2)2)3)5 )6)12)14)15)17)18)26127)32)36)52)54)65 J67)73)

*d4-l,4-DichlorobenzeneN- Nit rosod ime thylamineN-Ni t rosod ime thy lam ineN- Nit rosod ime thylamine2-Fluorophenol (SURR)Phenol-05 (SURR)PhenolN-Nitrosodi-n-propylamine2-Methy Ipheno 14-Methy Ipheno 1

*d8~NaphthaleneNitrobenzene- D5 CSURR)Benzoic acidNaphtha lene

*dlQ-Acenaphthene2-Flubrobiphenyl cSURR)2,4,6-Tr ibromophenol CSURR)

*dlO-Phenanthrene*d!2-ChryseneTerphenyl-D14 CSURR)

»d!2-Perylene

9333699

111111131113121917212?312835

.97

.20

.66

.75

.80

.53

.57

.66

.64

.64

.74

.66

.76

.94

.15

.24

.57

.54

.47

.52

.43

350174044194?28330433432432535433536496801707920

1017140712621602

1825503146299134112897832369162804168242272422736977126890325131478715991530^064846

13^46868558947763498

40.1.1.1.9.8.4.1.8.6.40.4.18.1.40.s •

6.40.40.5 .40.

003831493297374370940098425700170200005800

UG/MLUG/MLUG/MLUG/MLUG/MLUG 'MLUG/MLUG/MLUG/MLUG/MLUG/MLUG 'MLUG/HL *"UG 'MLUG/MLUG 'MLUG/MLUG/MLUG/MLUG 'MLUG/ML

8910010010079971004190999495979099999796979796

* Compound is ISTDIt-**

418

REFERENCE STRHPARD SPECTRUMFiU >DBMS TARGETBpk Ab 9999

leeee--

0-39

1 II40 60 60

REFERENCE SPECTRA Scan 881NRM NOM 881 .00 nin.

94

66s*

s^ -100

•

•0?'e ee 98 180 iie 1 0

SAMPLE SPECTRUM (BPCKCROUND SUBTRACTED)Flit >C9B64Bpk Ab 58699

j40000-

•

•

39 50 61 63ill ^f \40 60 68

CA2144C ,QC70092,LlH6,950SUB

94

66^ 76 ?9 93lL.,i /. X N

101

78 88 98 108 lie'

Scan 33318.36 ain.

hi 88*

*

.a120

SAMPLE SPECTRUM (UNALTERED)FIU >69864Bpk Ab 116680

68.

188800-•

^ '^ 45 65

..ililll.l.. ....... In.

f

66^

48' ' ' 'S0 ' 60 70

CA2144C

<" 86|. N

80

,QC70092,LiM6f950

9407 f^ iei

" f . 1 /90 100 118

Scan 33310.36 «in.

122X

hi 00•

-a120

Data File: >G9064::U3 Quant Output File: ^G9064::AQName:Misc: CA2144C ,QC70092,L:M6,950,2 BTL#30Quant Time: 891116 12:12 Quant ID File: IG0130::PFInjected at: 891115 17:58 Last Calibration: 991116 12:11

Compound No: 6Compound Name: PhenolScan Number: 333Retention Time: 10.35 min.Quant Ion: 94.0Area: 115954Concentration: 25.45 UG/MLq-value: 85

419

REFERENCE STANDARD SPECTRUMFil* >ES936Bpk Ab 9999

10000-

B-

39f40

TARGET REFERENCE SPECTRA Sc«n 907NRH ENH MOM 12.14 kin.

107

44r «1 ,r h-" 188 -180

-a68 80 100 120 ' '

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)Fil* >6SBpk Ab 7

5000ft-

0644692

I

39 51..i..i.. ih40

CA21SUB82

>4

63 7*

44C ,QC70e92,LiM6,950 Sea12.41

107f *

*\ 9f^ y 1 US

60 80 100 120

ft

Zr

434• in.

-160

-0

SAMPLE SPECTRUM (UNALTERED)Fil* >G9064 CA2144C ,QC70092 ,LiM6 ,950 Scan 434Bpk Ab 76264 12.41 Bin.

82

60000-

cu

54 1/ 74

" " . 1 1 1 1 II i . J*l 1 1 In ..,/*... . . . 1 . . 1 1 1 1 .

40 60 80

107f* 121

87 9^ 1*1 II /S f1 1 .1 i 1 ' II i . r ,l|

hia0i•A

100 ' 128

Data File: >G9064::U3Name:Misc: CA2144C ,QC70092,L:M6,950,2Quant Time: 891116 12:12injected at: 991115 17:58

Compound No: 15Compound Name: 4-MethyIpheno1Scan Number: 434Retent ion Time: 12.41 min.Quant Ion: 107.0Area: 162123Concentration: 46.06 UG/MLq-value: 98


BTL#30Quant ID File: IGQ13Q::PF

Last Calibration: 891116 12:11

420

REFERENCE STANDARD SPECTRUMFii* >J1646Bpk Ab 9999

10000-

•

8_

TARGET REFERENCE SPECTRA Sc»n 389SUB NRtl NOH 9.99 min.

18577 / 122

VT-T-l48

-100

•

-a80 ' 120 ' 168 ' 200 ' 240

SPECTRUM (BACKGROUND SUBTRACTEDFlit >G9227 CA2144C ,QC70092,LBpk Ab 18824 SUB

13620000-

- 54 68J7 105 122

-j_ j«I. _.u JL.U.... . ... j. . L a

f

L

40 88 120 160 230

J«6,95e Sc*n 53613.76 Ain.

264\

-100

•

-A240

SPECTRUM (UNALTERED)F:l« >G9P;:.- Ab 1

208001

0-

227 C8924

1

„ „? ««.«

n.i.. iftJ.. ...ill. .i.Hi.ii.... . .. 1.1. . L .U

A2144C ,QC7e092,LiM6,9S0 Scan13.76

36/

219 2<?L / >1 1 1 1 1 1 1 . , - 1 1 1 1 1 1 1 ....... 1 ., . , . , . 1 . . . 1 . . . 1

40. 80 120 160 200 240

536Bin .

-130

•«

Data File: >G9227::U3 Quant Output File: ^G9227::AQName :Miser CA2144C ,QC7Q092,L:M6,950,20,1QD BTL#25Quant Time: 891130 10:34 Quant ID File: 1G0134::USInjected at: 891130 09:49 Last Ca l i b r a t i o n : 891130 10:32

Compound No: 26Compound Name: Benzole acidScan Number: 536Retention Time: 13.76 min.Quant Ion: 122. 0Area: 32513Concentration: 18.42 UG-T1Lq-value: 97

421

Fil* >£906 »Bpk fib 9999

8000-

4000-

9_

39s\

, ,~ i i i-i • • • i40

Filt. NBS49KBpk Ab 9999

8000-•

4000-

B-T-T

C02144C ,QC70992,L:M6,950 Sc»n 377SUB HRM 11 .25 m in.

74

43/ 55 56

X / AQ^s /'" i,1.. .. ...,!•,.. .,. . ,'.,.!

87/ 101 102 117

S* / \ ,.-' -v

,,. . • I. . V x-

-60

-40•-M

60 ' s'e ' 100F'*ntanoic »c id , 2-m*thy 1 - Scan 2S59

G.00 ffiin.74/

4327 39 / ss „

j, \... . , 1i • • ' ' i •

43

Fil» NBS49KBplc Bb 9999

•SQ00-

.4000-

9: i • • •

-•" •>&69.1 .. ...tr. .1 ..... ,'i i

97S6 X 162, ...>r

-60•-40.u1 | i . . 1 | ' ' . . I . . . . | ' ' . . | 1 P . . | • r . , | , , .

66 £0 10u

H#x»noic acid, i-m«thyl- Sc»n 46360 .06 nun .

74

^43

i40

55 5^^ /' . —V .' 691 . 1,1 , f 1

M-fgi37

35 xx 1 6 1

\|, \

.•40

-A. .. | . . . . , . . , . | . . . . j . ( . . . . j ... ( ...

66 33 100

Data Fi le : .^99064: : U?Name :Misc Data: CA2144C .QC7Q092 ,i_: M6 ,950 ,2RT tmin): 11.2?Scan: J~>7

3955349 Rani-.: 1i -quan t 11 a t i ve Cone tuncorrected): 19.09 UG/'ML

BTL#70

Semi-quantitative Cone '. corrected J : 40 . 19 ug • 1Calculated using Istd : d-4-l,4-Oichlorobenzene gl 10.70 minute*

1. Pentanoic a c i d , 2-methyl-2. He x a n o i c acid, 2-me t h y1-

116 C6H12Q2170 C7H1402

Sample file: .-G9Q64 Spectrum #:Se-=i rch speed: 2 T i l t i n g option: S ' No . of ion ranges searched: 46

1.

Prob CON POQT

NBS49KN3S49K

DK ttFLG TILT

2 0

COH C I P_I'.

55 1"10 16

22

Fil* >G9064 C02Bpk flb 9999 . SUB H

s

1 43

3 3b \ B3

144C ,QC7e092,L:M6,9S0 Sc4nRM 9. 25

69 74 85 ^57 10t 19<.. >:. S . >s.i.. >..

20 ' 40 60 ' 80 ' 100

Fil* NBS49K l-Prop*ne,Bpk Ob 9999

5

1 16 2^ *3 46

2-flgoro- Sc»n8 .00

9

20 40 60 ee 100Fil* NBS49K Hud r 42 in*, 1,Bpk flb 9999

42 601 28^ 30] 18 1 f 46

PJ '. . ...,il l . . . ...,, l| r'. ...

2-dimethMl- Sc an0.00

61

20 40 68 30 Iy0

Fil* NBS49K H'.'dr4Zin*. 1,Bpk flb 9999

60-i 42j 28 30 /1 —*. ^ i 46

279min .

•

121min.

^

116mn .

l-dim-fthyl- -c in 1 150.00 mm.

\^ L1 1 I 1 j . . . . . . . . . I . . - ! . . . 1 . . . . r .... ( . . . . . . . . r .... r

• 20 40 68 80 180

Data F i l e : >G°064: :U7t-lame :Misc Data: CA2U4C .OC7Q092 ,L:M6,950/2RT (mini: 9.25Scan: 279Wrea: 2490615 Rank: 2Semi-quant i tat ive Cone f uncor rected ) : 12,02 UG-'MLSemi-quan t i t at i ve Cone <. corrected ): 25.31 ug'lCalculated using Istd: d4-l,4-Dichlorobensene (3 10.70 minutes

1. 1-Propene, 2-fluoro-2. Hydrazine, 1,2-dimethyl-3. Hydrazine, 1,, 1-d i me t hy 1 -

60 C3H5F60 C2H8N260 C2H8N2

Sample f i l e : /G9Q64 Spectrum #:Search speed: 2 T i l t i n g option; S

279No. of ion ranges search-ad

1.

Prob. CAS

52* 113460:•"'9* t=:-tn77!

CON *

2 0 0-420022 0 0 1

ROOT

NBS49-;NBS4°KN9S49K

V

27-i i;

20

OK

697274

ttFLG

•~i3o

TILT

0Q0

*B

17?ioocc

COM

167350

c_i2012— •

P_ I ( '

171217

423

F i l m >G9864Bpk flb 9999

91

1 39 SI *B

g-J, , , ,rtr •,) v i • | " "i"|-|"f" , , . . . , . . , , . , . , , , . , . , , , . , , , ,

CR2144C ,QC7eQ92,LlM6,950 -c»nSUB HRM 16.40

13693 118 / 13d

40 30 120 160 200Fil* NBS49K ThiocyanicBpk flb 9999

91

3 39 51 6S

1 ""-I •' '£ J „ . t J....r.f. -,--,— ,—,1

630min.

-*

*cid, ph«nwlm* thyl «st«r Sc*n 8318e.ee mm.

f93 121 149 is0 t

40 80 128 160 200

F i l * NBS49K Btnz*n*ac*tBpk fib 9999

91

3 39 51 6,5

0 } ,>,', ,.'•, ,4,--, , ' : . , , . . , . , , , , . . . , . , . , . , , , .

ic acid, ph*nylmsfht>l ester Scan 20.00

108 US 167 130 203 226

40 30 120 160 200

Fii* NBS49K E*n2Bpk flb 9999

51

1 39 si 654... >....../ ...,i! .. ........

3474iiin .

'-e

ena , ibromomath^l i- Scinl2E25e.oe mm,

t93 170 173 t

. - , ... ( ... p . . . . . . . | ... t ... | . . . . . . ( . . . ( .

• 40 SO 120 166 260

Data F i l e : >G9Q64::U3

i « ,- ! " ' **•* ' "M1"114^l~ GC7T) Q39 l : M6 3^ fl '"•l — '_. u- '3 . c • '_ rn .L i ^4 •-+W * -J^ ^ uu* «>. T L « * i L O j , . T u f ^.

R T *. m i n i : 1 & . 4 0Sc an: o? 0Area: 2379650 Rank: 7Seen i -quan \ i t a t i ',-e Cone ' uncor rec t ed ) : 1 05 . 56 UG /f1LSem i -quan t 11 a t i ve Cone ' corrected ? : 222.23 ug/' 1Calculated using I « t d : dS-Naph tha 1 ene 13 14.46 minutes

1. Thiocyanic acia, pheny 1 me thy 1 ester2. Bensensacetic a c i d , p h e n y 1 me t hy1 ester3. Benzene, <bromomethy1)-

14« C3H7HS226 C15H14Q2170 C7H7Br

Samp 1 e Ml*: .> GQ 06-* Spec t rum #:Search speedi 2 T i l t i n g option: S


Prob

43

CAS * CON

30123^11021o?1 0 L 7 0

3450

ROOT

NBS49KNBS49KHBS4°K

K DK #FLG TILT

575643

COM C_I P_l>.

2139

^

171 7 1°

16

4 2 4

Fil* >C9664 CR2144Bpk flb 9999 t SUB NRC1

C ,OC70092.LiM6,950 :c*n 44312.69 tnin.

?4

8/ 97 101 US 130 :

20 ' 40 60 30 ' 100 120

File NBi49K Hex»noic 4Cld,Bpk Pb 9999

" 41 43 q_,

E-n»»thyl- C-Cin 46860.00 min.

"4

87 ;

20 40 60 30 100 120Fil* NBS49K Urea, m*th»Bpk Pb 9999

30

; 1(5 41 44 53

0- , i'|'i | . , ;'!' ', , ,"T7i'!-. ., ,•,'!•! i , , . i . . . . . . . , , ___,-,-. . . , . , , , , , . . . . _

>\- Scan 2'?50.00 mm.

'4 ,

^- L20 43 60 30 100 120

FU* NB349K Butanoic acid,Bpk Rb 9999

i 2; 4>] IS ^ « 69

gj.. .;•'... .,ll ,,. .1. ...1, ...il , . "> 1

2-inffthyl- Sc*n 1E216.00 min.

'4

87/ 99 102 103 :

40 60 30

Data File: .'••G':'0o4: : U3Name :Mi3c Data: CA2144C ,OC700-32 ,L:M6,950,2RT ', mm ; : 12 .69Sc an: 443Area: 2201987 Rank: 4Semi-quant11ative Cone (uncorrected ): 99.79 UG/MLSern i-quan t i tat ive Cone f. corrected ): 209.15 ug-'lCalculated using Istd: dS-Naph tha lene |il 14.46 minutes

BTL030

1.. Hexanoic acid, 2-methyl-2. Urea , me thy 1-1'. Butanoic acid, 2-methyl-

150 C7H1402?4 C2H6M20

102 C?H1002

e f i l e : ••G9Qb<4 Spectrum *:Search speed: 2 T i l t i n g option: S

448No. of ion ranges iearched: 46

P r c - b . CAS IF CON # ROOT K DM #FLG TILT % COH C_I P_IU

1 .K-5S? 0?11 o ? 7 0

4332MBS49KNBS49K

2177

. **72

50 11in

7117

4 2 5

i F i l * MI 9 1364Bpk flb 9999

10000-

3000-

6000-

4000-

2000-

0J'\|

3'0'

39x

(0

T i l * NBS49KBpk flb 9999

_10000-

$000-

6000-

4000-

2000- ,

7

1 . 1 - i

42

,1.. i . . . . i• 30 40

CA2144CSUB NRM

60

47 55

' ' • (

"

' * ' 8.98 rnin..

73

t . . 1's'0' ' '60 7

x-.

,

0

Butanoic ac id

60""*

37 SS75 --x /i *•«. •'

80 90 100

-100

-30

-60

-JO

-20

-0

Scan 7510 .00 mm .

[-100

1 73

4-6i

50 60 70

-80

-60 !

-40

74 87 38 -20

f "> ' _c,30 90 100

Data F i l e ; >G9064: :U?Ma me :M:sc Oats: CA2144C ,QC7QG92 ,t_:M6 ,950 ,2RT (.mm): 3.90scan: 262rtrea: 19?4Q'=7 Panl- : 6Semi-quant i tat : v« Cone f. un corrected):Sem i -quart t i t a t i ve Cone t corrected J:

9 . 37 UG 'ML19.6? ug- 1

3TL#30

Calculate d using Istd: d4- 1 ,4-Dich lorobenzen* @ 10. 70 minutes

B'jtanoir acid 88 C4H302

Sa.-np 1 e f i l e :iea r cr speed :

i9 064 Spec t rum tt :T i l t i n g option: S

i 6 _No.. Q f i or ranges searched:

Prob. GAS -T COM tt ROOT K DK #FLG TILT % CON C_l P_!

F 2 * 107T=121 2009 NBS4°K 36 ^i 2 0 67 19 2 0 1

426

Fil* >G9064Bpk Qb 9999

8060-.

4800-«

0- , . , . . . . i ..

41N..1,

CR2144C ,QC70092.L(I16.950 Scan 399

I I I ,40

Fil« NBS49KBpk Hb 9999

3000-

4000-

0-

a/ 4x. i ... .1.

SUB60

/

——— tur., ,

NRM 11.69 min.

Ln7J

_

1 ,. . .,,60

-•*•

H*x*noic

60

43/

i|440

Fil* HBS49KBpk fib 9999

3000-•

4000-

0--

27 41V

,. •',... . .40

'55/

.... ..hi..

73-_

i, . i . , . . | i i , .60P*ntanoic

60

43

i i .f-r-,.. . ...i'i...

74 87 97 99,** f -. J

!'• • r i ' i ' . ' n i i i , i M f " i i i i . i i . i i -

.-40.-.a

80 100 120»cid Jean 2349

0.00 min .

;-4 8; -? 101 ^^i" . . i . N . . / /i . i ( . i • . ( i i i i j i • , i ! , . . , , ,

-60

-40

-e30 100 12&

acid £c*n 15430.00 min.

73

i .. . . . . . . . . . . ,60

\_74 1 02

87 101 _,-x . . . . - " ' , /<-'. . , . . - . , . . . . , . . . ! - . . . , .

1*0•-40

-0£.y 10d 120

D a t a F i l e : ' • G9064 : :U?f iame :Mi-; Data: "A2144C .OC?0092,L:M6,950,2D~ f ro in ) : 11 . 69Scan: 399Area: 17373Q? Rank: 7?em i -qu-an t ; t a t i ',•« Cone (uncorrected):Sem i -quan t i t a t i '-,'e Cone t corrected .' :

3.6? UG'ML19.16 uq.-'l

Calculated using I s t d : d4-l,^-Dichlorobenzene @ i 0 . 70 minutes-

1. He-anoic acid2. P e n t a n o i c acid

116 C6H12Q2102 C5H1002

e f i l e : XG9064 Spectrum ft:•arch speed: 2 T i l t i n g option: 5

?99No. of ion ranges searched: -46

P r o b . CAS ft CON ft ROOT

^3 142621 20?6 MBS49K? 2 10 Q r:- '2 -4 2 C 2 2 h IBS49 K

DK

52

T I L T S

Q 10 00 *6

CON C_I P_K'

5 55 14•; o •'. P ] O

427

h-cn

CO

_j r.in • <s> ofi £ •"" © G) O ^& O IS O O ® &^i-rf -. ... <T. <n IS. -p q> ^ ro fjl -« •-"

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a \-S~

^ w^Tf- E

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iritft

^

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^_^ - ————— - ————— —— ——— ——— - .. ...

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Off>(K^ [i i i i |'i i i n i HI | i i i i 1 i li i | HI i[ i i i i [ i i . i | r i n [i . i i | . i n-

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D 1- -IN O u O --i•? C O 1CD n "tfj .- -•- ••-- 11r .i 1 C O ii "

h» O -n c C Xin - ft o o *-•

O (J in

^-T 't 4) C'-0 TO r- I-- cjiO -< CO rt " C17 C-l • '7- *' *-' ^ffi vE -=1 — ) iD iD MI

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(i fl • • h i P C L. O_ 4- - -i *n fl 4-'• n) •! 3 ~1 <DLL TJ -* CT IT —

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Fil* >G9064Bpk flb 9999

CP2144C ,QC70092,L:M6,9S0 Scan 518SUB HRM 14.12 ffi in.

4173

10!

20 40 60 se 100 0Fll* NBS49KBpk Pb 9999

Cycloh«x»n*ctrboxy1ic AC id Scan 426e .00 mm

0J

41

20' I ' l l M l ' i ' l i ' 1 ' l l ' l "

68

40 69 30 100

IFJ.

Fil# NBS49K 1 ,3 ,2-fliox»borol*n», 2-*thy 1-4 ,5-dim*thy 1- Scan 4247b_.L, AW rtAAA * Ct CtOt . : —Bpk flb 9999

1130.00 (i,in.

28/

.ill.. .43

. ..,..,

5745 (

.•<. ....III..71 ^73

. . . . . , . , . ( .

84

,L99 12S

">. 1 , ..7i.

40 6@ 88 1 0 120Fil* HBS49KBpk ftb 9999

j IS

20

2-But»n*-l ,4-d:4min« , N ,N44

4223 ^ 68

S,e ,' 30, ...MI.L .J.I... >,l

40 ' 6'0 ' 36

-dim* thyl-

97i, f'

' 100

5 c*n0.00

114/

129

2:610min .

LData File: >G9064::U3Ma me :fine D a t a : CA214^*C .QC70092 ,L: M6 ,950 ,2PT . m m ) : 14.12Sc an: ?13ftrea: 12So41^ Rank: 11Sem i -quant i tat i ve Cone f. uncorrected):Semi-quan tit a t ive Cone ' corrected ) :

58. 04 UG-'-H122.19 uq •'!

C a l c u l a t e d ueing !«td: d8-Naphthalene § 14.46 minutes

i . C;.'c 1 one * anec ar boxy 1 i c acid2. 1 , 7 ,2-Dioxaboro lane ., 2-ethyl-4,5-dimethyl-T. 2-Eutene-l ,4-diamine, N,N'-dimethy1-

123 C7H120212S CeHl?B02114 C6H14N2

1 e r i i e : - G1' 064 Spec t rum # :a r c h ?p.eed : 2 T i l t i n g option: S No. of ior ranges searched

CA

'A "* 7 « .j -iO . .' O *4-4

CON

.22*66 11 e

FOOT

riBS49kMBS49-',MBS49!-

r':

Q ™

2424

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2.9' UG -T1L6.30 ug "1

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1 . He vario i c ac id2. Hydrazine, 1 ,2-d i me t hy 1 -

116 C6H12Q260 C2H8N2

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40?hlo. of ion ranges searched

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1-42621 2C7o NBS*»9K 43 4^ 22C7o2002

0 *0ij 10 0

CON C.

20 1712

438

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41

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42730 .00 mm .

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Data Fi le: - "G9064: : U3

Miac Data: CA2144C ,QC'0092,L:M6,950,2PT r m i n J : 17.35Scan: ? 0 5Anea: ol!6g4 Rank: 27Semi-quantitative Cone (unconnected1*! 2^.60 UQ 'MLa err, i -quan t i t a t i ve Cone f connected ) : 58.10 ug -' 1C a l c u l a t e d uiing !-td: d8-Naphthalene (f 1*+, «46 n-, mutes

BTLft30

1. C y c l o h e x a n e c a r b o x y 1 ic ac id2 . 7 -Hexenc i c a c i d , methy l e a t e n? . 3 - D en teno ic a c i d , ? - m e t h y l - , methy l e s t e n .

128 C7H1202128 C7H1202128 C7H1202

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ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Matrix: (eoiI/water) WATER


Level: (low/med) LOLJ

Contract!

SAS No . :

Moiature: not dec. dec.

Extraction: (SepF/Cont/Sonc ) CONT


SDG No . :

Lab Sample IDi CA2145C

Lab File ID: >G9065

Date Received: /*

Date Extracted! 10/12/89

Dete Analyzed: 11/15/89


CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg ) UG/L

108-95-2 ——— -111-44-4 ————95-57-8 ————541-73-1 ————106-46-7 ————100-51-6 ————95-50-1 ————95-48-7 —————108-60-1 ————106-44-5 ————621-64-7 ————67-72-1 ————98-95-3 ————78-59-1 ————88-75-5 ————105-67-9 ————65-85-0 ————111-91-1 ————120-83-2 ————

91-20-3 —————106-47-8 ————87-68-3 —————KO en •?91-57-6 —————77-47-4 —————

95-95-4 —————91-58-7 —————88-74-4 —————131-11-3 ————208-96-8 ————606-20-2— * ——

1—— Phenol 111—— bia(2-Chloroethyl)ether ____ 111—— 2-Chlorophanol , 111—— 1 .3-Dichlorobenzena 1 11—— 1 P4-Oiehlorohanzena _._ 1 11—— Benzyl a leoho !.„,,„ Ill- — 1 ,2-Dich lorobanzena .„„.,„., Ill—— 2-Methylphenol . 1 11---b i» (2-Ch loroiaopropy 1 )ether_l 11—— 4-Methylphanol ... , 111—— N-Ni t roao-d i-n-propy lamine __ 1 11—— Hexaehlopoathane , ,, , 111—— Nitrahanzana mmmim 111—— -Isopharona . , ._._ Ill—— 2-Nitraphenol 111—— 2 ,4-DimethylphenaI.. ...,„! 11— --Banzai e acid , „ 157—— b is (2-Chlproethoxy)me thane _ 1 11—— 2 r4-Dich lorophano 1 ,, 111— .-1 .2 .4-Tr ichlorobenzane 1 11—— Naphthalana 111—— 4-Chloro«ni line . ,, 111—— .Haxaehlorahutadiana „„...„.„„„ .,, 1 1 1- — 4-Chloro-3-methylphenol_ ___ 1 11—— 2-Mathylnaphthalana _ ., 1 11—— Hexach lorocycl open tad lene __ 1 11- —— 2 x 4; A-Tr i eh Inrophano 1 1 11—— 2r4r5-Triehlorophenol 157

—— 2-Nitrnani 1 ine m_ , 157—— Oimathylphthalata _ , „ 111—— Acanaphthylana , „ 1 11— •-2,6-Qinitrotn luana m \ 1 1

1

1IUIUIUIUIUIUtuIUIUIUIUIUIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU1

FORM I SU -1 1/87

' 1CSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO,

Lab Name: ETCNJ

Lab Coda: Case No.:

M a t r i x : (soil/water) UATER


Level: Clow/mad) LOW

Cont ract:

SAS No.:

II_____

SDG No.:


Lab File ID: >G9065

Date Received: /


Extract ion: (SepF/Con t/Sonc ) CONT




D i l u t i o n Factor: 1


99-09-2 ——————— 3-Ni t roan i line____________83-32-9 —————— — Acenaphthene______________51-28-5 —————— -2,4-Dinitrophenol_________100-02-7——————4-Nitrophenol_____________132-64-9 ————— --Dibenzofuran______________121-14-2---———-2,4-Dinitrotoluene________84-66-2 ——————— Diethylphthalate__________7005-72-3--——--4-Chlorophenyl-phenylether_86-73-7---------Fluorone_________________100-01-6 — — —— -4-Nitroanil me____________534-52-1 — — - —— 4,6-Dini tro-2-methyIpheno1_86-30-6---------N-Nit rosod iphenylamina C1)_101-55-3——————4-Sromophenyl-phenylather__118-74-1--------Hexachlorobenzene_________87-86-5- — ------Pentachloropheno 1_________85-01-8- ———— —— Phenanthrana______________120-12-7—— — —— Anthracene________________84-74-2 ——————— Di-n-butylphthalate________206-44-0-———-—Fluoranthane______________129-00-0- — - ——— Pyrene___________________85-68-7———-----Butylbenzylphthalata_______91-94-1- ——— - —— 3,3'-Dichlorobenzid ine_____56-55-3 — --- —— -BanzoCaJanthracene.,________218-01-9 — -- ——— Chrysene_________________117-81-7——————bis(2-Ethylhexyl)phthalate_117-84-0——————Di-n-octy Iphthalate________205-99-2--------Benzo(b)fluoranthene_______207-08-9—-- ——— BenzoCtOf luoranthene_______50- 32-8-- —————— BenzoCa)pyrane____________193-39-5-—————IndenoC1,2,3-cd)pyrone_____53-70-3——----—D i benz(a,h)anthracene______191-24-2----—--Benzo(g,h,i)perylene_______

5711575711111111115757111111571111.111111112311111111111111111111

CD - Cannot be separated from D ipheny lamina

FORM I SU -2

IIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU

1/87 Rev.

447



ERA SAMPLE NO.

ILab Name:ETCNJ

Lab Coda I Case No.:

Matrix: Caoi1/watar)WATER


Lava 1: (1ow/med) LOU




Number TICs found: £

Contract:

SAS No.: SDG No.:


Lab File ID: >G9065

Date Received: /





CAS NUMBER

01. 141-78-602.03. 127-18-404.05. 108-88-306.

COMPOUND NAME

Acetic acid, ethyl esterACETONE DIMEREthane, tetrechloro-UNKNQUNBenzene, me thy 1-UNKNOUN

RT

5.056.455.508.934.388.36

EST. CONC

2608256471312

Q

BJBJJBJJJ


TOTAL ION CHROHRTOCRfmFile >C906S

100000*

900000-

000000-

700000-

600000-

S00000-

400000-

399999-

9AaaAAiCWWV]

10000*

1i

4 '

36

Hi

0-600.0 MU.TIC

40,0 ( 80,0 ,

.

,

£2

1

f a,• ^ .

|J ;i '4

1iriL

1 :

s

! :

M«Mj «<^ -

11

i-!*

•« :

j

CHZ146C ,QC70092,Lill

12,00 , 1686 , 20,00

II

ii

i 2 *E 5 E i>u I 1 fii i f f•f M f

8 ' l'2 ' 16 29 ' 24 ' 28 ' 32 ' 36 40 44

Data File: >G9065::U3Name:tlisc: CA2145C ,QC70092,L:M6,880,2

Id File: IG0130::PFTitle: IFB/BNA, PP/BNALast Calibration: 891116 12=11

Operator ID: PT1575Quant Time: 891116 12:2?Injected at: 89111? 18:54

Quant Output File: G9065::AQ

BTL*31

449

\

Operator ID: PT1575Output Fila: 'SG9065::AQData File: >G9065::U3Name:Misc: CA2145C ,QC70092,L:M6,880,2


Compound

QUANT REPORT


Di lut ion Factor

Page 1

891116 12:25891115 18:54

1.00000

BTL*31


1)5)12)17)18)32)36)54)65)67)73)

»d4-l ,4-Dich lorobenzenePhenol-05 (SURR)N-Ni trosodi-n-p ropy lam ine

•dS-NaphthaleneNitrobenzene-05

*dlO-Acenaphthene2-Fluorobiphenyl

*dlO-Phenan throne»d!2-ChryseneTerphenyl-014

»dl2-Perylene

(SURR)

(SURR)

CSURR)

10.10.12.14.12.19.17.24.32.29.36.

6609374437919632333433

346318430532430.801705

101814121265160?

2430581325942431510921277351169355283022121470461004998529259

40.2,

-«T40.39.40.40.40.40.38.40.

0029*6-0039001600008100

UG/MLUG/MLUC'MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

8696389495989996999389

* Compound is ISTD

450

Fil# >C906SBpk flb 9999

CR2145C ,QC7Q092,LiHb,3SO 3c*n 70SUB NRM 5.06 mm.

43

8090-

4000-

0-

37

N 1

y5 gS 61 68 / S7 99

•99

-40

!A' 39 ' 49 ' 50 " 60 ' 70 ' 80 ' ?'0 ' 100

Filt NBS49KBpk flb 9999

flc»tic acid, *thyl »it»r Scan 7570.00 mm.

43

8000-

4000-

0-H- 4.

29 4S 70 as/ 61 ° S.3

-30

-40

30 40 50 60 ?0 30 90 100Ftl» NBS49KBpk Pb 9999

Prc-panoic acid,, 2-m»thvl- ican 75rj0 .00 min .

43

3000-

4000-

J

27

i i3(

. >i.|.. ..-,.... r .... j• JO 40

4,5 55 r3 37 3S.r. >. *e .i........ j ..... ... | .... j .... ( .... ( .... | .... ( .... j .... j .... |50 60 70 80 90 10

-eo-40

-00

Data F i l e : >G9065::U3Name :Misc Data: CA2145C ,0070092,L:M6,88G,2RT (mm): 5.05Scan: 70Area: 2713533 Rank: 1Semi -quan t i t a t i-.'e Cone '. unco rrec ted ) :S e m i - q u a n t i t a t i v e Cone C c o r r e c t e d ):

114.57 UG/T1L2 6 0 . 3 0 ug 1

STL#71

C a l c u l a t e d u s i n g I s t d : d4-l ,4-Dichlorobenzene |S 10.66 m i n u t e s

1. A c e t i c a c i d , e t h y l esterv> 2 . P r o p a n o i c acid., 2-methyl-

33 C4HS0233 C-+H802

Sample f i l e : >G9065 S p e c t r u m #:Search «.peed: 2 T i l t i n g o p t i o n : S

70Mo. of ion range* searched

1.

Prob. CAS « CON # ROOT

60* 141786 21'37 NBS49

TILT CON

MBS4''K 23 50 1HBS49K Cl 68 2

0 "1 15 ?C 15O o ^ - * ^ ^ 1 ?

451

Fll* >C906S C02145C .QC70092 ,L |R6 ,330 Sc*n 139Bpk Ob 9999 . SUB NRM 6.4E nin.

8000-

4000-

0-

43

37

59

S3 69 71 101V \ J O - S /

2'0 ' 48 ' 60 ' 80 ' 100*

<e-40

-e

Fil* NBS49K 2-P*nt*nont, 4-hydroxy-4-i**thy 1 - *c*n 2851Bpfe flb 9999 0.06 mm.

8000-

4006-

43

i.i I.. ..I.

59

S3 69 33 95 101 102\ M | \ ',. / x //

20 43 60 SO 100

•€0

-0

Fil» NBS49K Hwdrop«ro>; ld» , 1 . 1 -dim«th'yl*thy 1 Sc»n 947Bpk Ab 9999 0.dd min.

59-1

8000-

0-/S ^ ^

• 20 40

53 -3 89. \..ii, '-'3 '9o'0 ' 80 ' 100

-30

-40

-9

Data File: >G9065:=U3Name :Misc Data: CW2145C ,QC70092,L:M6,880,2PT ( mm ) : 6 . 41?Scan: 139Area: 357240 Pank: 4Semi-quantitative Cone (uncorrected): 39.9? UG'MLSemi-quantitat\ve Cone t corrected ): 31.70 ugx1Calculated using Istd: d4-l,4-Dichlorobenzene (J 10.66 minutes

1. 2-Pentanone, 4-hydroxy-4-methy1-2. Hydroperoxide, 1,1-dimethylethyl

116 CoH120290 C4H1002

Sample f i l e : >G°06? Spectrum *:Search speed: 2 T i l t i n g option: S

139No. of ion ranaes searched

1.

Prob.

7020

CAS

123422

CON tt POOT

17901773

NBS49KNBS491'

K DK

344071

TILT % CON C_I P_IU

42e;

1412

452

\

Fil* >G906S CP2145C ,QC70092 ,U iM6 ,380 Sc*n 92Bpk fib 9999 SUB NRM 5.50 mm.

166-

8900-

4800-"

fl_

129

47 y37 ( /9 65 62 1 117^W 1 jf / \ \ \

i IL . J. .: . . l.i . 1.1.1. N . .

133

S' 156\

. .1 ^

'

. ,1 .

•-60.-40

^' 20 ' 4*0 ' 60 60 100 ' 120 ' 140 ' 160 '

FiU NB349K Eth»n», t»trachloro- *e»n 11115Bpk Ab 9999 0.09 nin.

8900--

4900-"

£-

166

129

942J ^5 47 59 32 / l\7

x- / (t / l \ | \• p • i ' i • i ' i • r ' i • i ' i • i ' i20 40 60 80 100 120

133./•

V

-69•-46'

H .1 ..ta 3i"I 1 • 1 • 1 ' i -140 160

Fil» HBS49K Pvrimidin#» 5-f luoro-2 ,4-dichloro- Scan 11553Bpk fib 9999 0.00 mm.

let

S000--

4300-

'

131

,.24 31 44 53 ' fl6 106X. 1 / s . "; / , rr'N: .. I ..... .1.1,. it ..i. ll . J. .... ;' ..* .

133/

, , .1.

'•ee•-40

-O. i . , . , . , . , , . , . , . r , . , . , . , . , . i . ,•20 40 60 30 100 120 14Q 160

Data File: >G9065::U3Name :disc Data: CA214?C ,QC?Q092,L:M6,880,2F'T i mm ) : ? . 50Scan: 92Arsa: (?815?3 Rank: ?Semi-quant: i t a t i^>e Cone funcorrected) :Semi -quan t i t a t i ve Cone f. corrected ,':

24.50 L"J,-'ML5"?.63 ug,'l

Calculated using Istd: d4-1,4-Dichlorobenzene @ 10.66 minutes

1. Ethene, t e *rachloro-2. Pyrirrudine, ?-f luoro-2 ,4-d ich lo ro-

164 C2C14166 C4HCL2FM2

Samp 1e f i l e : •G°065 Spec t rum tt:;esrch ipe*d: 2 T i l t i n g option: S Mo, of ion ranges searcheC: 46

Pr ob .

1.

CttS tt CON # ROOT

2213o NBS49K

OK *FLG TILT S CON C_! P_I"

^ 020*

1? o4 a?CT r ]_T

453

Til* >G906SBpk fib 9999

H 4I

CH2145C ,QC70092,L:ri6,S80 >c*n 261SUB HRM 8.93 *in.

43 _J-1

\ (i/' iti f y ir u-t L20 40 60 30 100 120

F l l * NBS49K 1Bpk flb 9999

41--H,

: 15 27o" f -n i'l

-Prop»n«, 1-chloro-, i E J - Sc*n 34E0 ,08 min .

76 _8 t

20 ' 40 60 ' 80 ' 10e 120Fil* NBS49K 1Bpk flb 9999

41

: is 27a . :'' ,.(' ..nil

-Prop#n#, 1-chloro-, i2)- ic»n 3440.00 mm.

76 t4? ^,0 61 ' 79 f

20 40 ~* 30 iee 120F i l » rlB'J4*K B u t aBpk fib 9999

no i>: ac id , 2-prop*nwl ** t*r ^ c »n 42i?S3 .00 mm .43 ri

57 £Q 39 9« ;@0 11"? l"*8 i. r. "^. , ^ -^^ f -..1«

- 20 ' 40 ' c-0 ' SO ' 100 ' 120

Data F i l e : x G906? : : U7Name :Hiic Dat a : CA2145C , Q C " 7 O G ^ 2 , !_:M6 ,380 ,2PT uriin :> : 3 . 97Scan: 261H - r e a : ^ ° 1 8 e> Par^ : e-'ierr, i -quan t i *•. a t i '.-e Cone " ' ' j n c o r r e c t e d 1 * :'iern i -quan t i t a t i ve Cone ' c o r r e c t e d !' : 47.10 -jg -•' 1C a l c u l a t e d us ing I s t d : c4 - l ,4 -D ich lo robenzene iT 1 G . 6 6 r mute 5

20 . 72 L'G-'?1L

BTL#?1

1-Propsri*. 1-chloro-, C E ) -i-Prcp*ne, 1-chlcro-, ', Z 1 -B u * a r o i c a c i d . 2-propenyl ester

^6 C?H5C1123 C7H12Q2

-s'.'p . e r : i •» :a r c n s p e «-^ i

Spec t r urn ^:T i l t i n g o p t i o n

261No . o f i on ran. s e a r c

P r G b . CAS 'i COM it ROOT K OK ftFLG TILT '3 COM C_I P_!M

1. 30* i c 17 6'? -2 3 * i ^ 17 c- 3 -*;:

4 5 4

Fil* >C906SBpk flb 9999

3 398J i... d.

40FiU NB349KBpk Pb 9999

| 26 39

ej.,rr>.-^ti'.40

F i l » NES49KBpk Rb 9999

: 39: 26 ,a-, ,rr>i-i^ifcf40

Fi 1* HB*4?KBpk Bb 9999

CR2145C ,QC70092,Ltt16,380- SeaSUB HRM 4.39

•?1

6,5 194 29i^.^.Jy^M ,,,,,,,,,,,,,,,<,,,,,,;,,,,,,,,,,,/,30 120 160 200 240 230

1 ,3,5-Cyc lohtptfctr i»n« I c *n0.00

91/

^ 1 «| r!1- "

80 120 160 200 240 230E*nz»n* i m e t h M l - Scan

0.0091

.e06 .?4^^^ —————————————————————————————————

90 120 160 200 240 2S0Cu>: lcbut*n» , 2-prop*nyl i d«n*- ;c»n

0..0091

i 37nm .

-

i.339nm .

-0

864ft in .

p

",

833run .

65 |

46• • i • • i i240 230

D a t a F i le : V G 9 0 6 ? : : U 7Name:I l i a c Oat a : CA214?C ,QC700°2 ,L: Mo ,830 ,2OT ' mm ' : 4.73Scan: 37MTea: 173-*87 Rani- : 7S*TI i -'iu<=n t i t a t i '.'e Cone 'unconnected): ? . 87 UG 'MLb*rr!; -quan t i t a t i ve Cone ' connected J : 13.26 ug 1C a lculated using ! «. t d : d4-l,^*-C|ichlGrobenzene |ij 10.06 minute*

1 , i . 7 ,^-Cycloheptatr lene2. Benzene, rnethyl-7 . Cy c 1 o b u t e n e , 2-propenyl idene-

92 C~"H392 C7H8

: . a * -p le ^ i l e : - G 9 0 6 5 S p e c t r u m ^ :• a r ; h ipeed: 2 T i l t i n g o p t i o n : S He. of" ion range* s e a r c h e d

P r G b . CftS tt COM it ROOT K OK ^FLQ ^ILT

c -*-2 ? 2 S -i "Q f IBS49 K 67 1310333? 3-»"? MBS^'9K "7 1"0 ° ^3 * ? 3-74 t^R'E 491 4* 30

COM C_! P_I'J

P.!j 1 :] ;. i r,"?

0 " 8 71 -4 0 3 0r, ! ri r, s -is

4 5 5

Fil» >G906SBpk Ab 9999

£6, /

3 39 44 621 ' * . 1 /9J, , i 1 , i , 1 I'l'l . i |'Vl',i| ) 1 |

40 60

Fll« NB-49K CyBpk fib 9999

56/

1 „ 4i 42

04 i'i'i . 1 1 ii|l('i 1 1 i'i'i' 'i 1 1-7'40 68

Fil» NBS49K 1 ,3-Cyc lop*ntaBpk flb 9999

56H 41 ,'

i ^'0j i. i40 60

CA2145C ,QC70092,LtM6.830 Scan 233SUB NRfl 8.36 mm.

34 112 hV2 ^ 35 99 " ^ fn - i ' - M . - J c r . . . . . ? . . . . . . - ' / - . . , . . ! . ^

30 100 120

c loh*x»n« Sc4n0.00

54

i? " 35•p.ir,.,, .,.,.,. cT,, , , , , , , . , , « . . ! . . .

30 100 120

ntdion*, 4 ,4-di»*thyl- Scan0.00

126" '34 -517 i 12 ,,:' •> / -" I.

30 100 120

Fil* N8S49K t ,3-Cvc lop»nt an#aion* , 4 ,S-dim» thvl- "cmEpk Sb 9999 3.00

559rtitn .

^

3'? 14min .

MS

33*3itiin . |

4167 9S in

, . . . . ,120

2 .UM6 ,330 ,2

Data Fi le: >G906?: : U3Ma me :Cisc Data: C*2l45C ,QC^PT (mm ) : 8 . 76Scan : 27?nrea: 12"012 Rank : 9Ser.i i -quan t i t a t i v e Cone 'unccrrected): ? . 7? D'J ML3 e TI i - q u a n t i t a t i ve Cone t corrected ) : 12.16 u g ICalculated using I z t d : d4-l ,4-Dich lorobenzene |3] 10.66 minutes

BTL#71

1. Cyc1ohexane2. 1 , 7-Cyc lopen t aned :cne , 4 ,4-dimethyi-7 . i , 7-Cyc lopentanedione, 4,^-dimethyl-

3*4 C6H12126 C"7H1002126 C""HI 002

amp!e t i l * :a r - h speed :

?9 0 6 5 Spec t rum ft:T i l t i n g o p t i o n : S

277Mo. of ion * e a r c t - e d

rob . CftS t CON y POOT K DK tfFLG TILT «< COr; C_I P_I

I v O i , ' t - ' U i

7rG2* iJ r l 1-^2?70 42

c: •!

0 ""0C "n;. i >:; o

456

TOTQL IQM CHRQHOTQGROHFil» >G9

1000000:

900000:300000-

700009:

500000;

40oo0e-30000*

10000

196

4

35

(

.0-600.0 %AU. Cfli£145C ,QCS792I,LiTIC

400 ( 80C t 1200 , 16,00

|1C L

.

^T

<

'i a3i.. 1i

1I g? i |l *5 ii ik

i 1 | | j

i ———— -i • i ' I * I ' I • i • i • i • I • I ' I ' I ' i • r ' I • I ' I ' r •t 12 16 20 24 28 32 36 40

Data File: >G9196::U6 Quant Output File

Mi*c: CA2145C ,QC87921,L:M4, 910,2

Id File: IG0134::UST i t l e : IFB/BNft, PP/BNALast Calibration: 891127 16:01

BTL# 4

Operator ID:Quant Time: 891128 19:23Injected at: 891128 18:38

457

QUANT REPORT

Operator ID:Output File:Data File:Name:tlisc: CA2145C

CA3875"•G9196: :AQ>G9196::U6

Quant Rev: 7 Uuant T i rneInjected at

Di lut ion Factor

,QC87921,l_:M4, 910,2

Page 1

891128 19:23.891128 18:38

1.00000

BTL# 4

ID File: IGQ134::USTitle: IFB/BNA, PP/BNALast Calibration: 391127 16:01

Compound R.T. Area Cone Uni ts

1)12)17)18)32 J36)54)65)67)73)

*d4-l ,4-DichlorobenzeneN-Ni trosodi-n-propylamine

»d8-Naphtha leneNi trobenzene-D5

•dlO-Acenaphthene2-Fluorobiphenyl

*dlO-Ph*nenthrene*d!2-ChryseneTerpheny 1-D14

*d!2-Perylene

CSURR)

C SL'RR )

(SURR)

10111311191"23312835

.15

.93

.as

.3746.79.77.82.74

356441542441809715

1026141812731613

24997037*27446846257*31169134231 -'912139757SJ3513390436727

40.

40.39.40.36.40.4U .62.4U .

00

0005003400007400

UG/MLUfa "1LUG/MLUG-'HLUG/MLUS. 'MLUG/MLUG/HLUG/riLUG-'ML

883894929699979?9395

* Compound is ISTD

458

IBSEMI VOLATILE ORGAN I CS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Nama: ETCNJ

Lab Code: Casa No.:

Matrix: (soil/water) LJATER



H Moisture: not dec. dec.



CAS NO. COMPOUND

Contract: I_________

SAS No.: SDG No.:


Lab File ID: >G9066

Date Received: /#////?7


Data Analyzed: 11/15/89

Dilution Factor: 1

CONCENTRATION UNITS:Cug/L or ug/Kg) UG/L Q

108-95-2 ———111-44-4 ———95-57-8 ————541-73-1 ———106-46-7 ———100-51-6 ———95-50-1 ————95-48-7 ————108-60-1 ———106-44-5 ———621-64-7 ———67-72-1 ————98-95-3 ————78-59-1 ————88-75-5 ————105-67-9 ———65-85-0 ————111-91-1 ———

91-20-3 ————106-47-8 —— -

59-50-7 ————91-57-6 ————77-47-4 ————

9 1 GQ "7

88-74-4 ————131-11-3 ———208-96-8 ———606-20-2 ———

1——— Phenol 1——— bis(2-Chloroethyl let her ____ 1—— -2-Chlorophenol 1——— 1 , 3-Dich lorobanzene 1-- — 1 r4-Dich lorobenzene 1——— Benzyl alcohol 1——— 1.2-Dichlorobenzene 1——— 2-Methyl phenol 1——— bis(2-Chloroisopropyl)ether_l----4-Me thy Ipheno 1 1----N-Ni t roao-di-n-p ropy lamina _ 1——— Hexachloroethane 1„ — -Nitrobenzene 1---- Isophorone 1——— 2-Ni t rophenol 1——— 2 ,4-Di methyl phenol 1—— -Banzai c ac id 1——— bis(2-Chloroethoxy)methane _ 1——— -2,4-Diehlorophanol „„ ,, .,. 1- —— 1,2 ,4-Tr iehlorobanzene 1- —— Naphthalene 1—— --4-Th larnani 1 ine 1———— Mutvaeh 1 n rob LJ tad i ena 1—— -4-Ch loro-3-me thy Ipheno 1 ____ 1..--9-MMfhyl naphtha lane 1-- — Hexach lorocyc 1 open tad iene __ 1——— _O A A_Tr . nh Inrnphano 1 1——— 7,4,5-Tr ichlorophanol 1-___9_rh Inrnnaph thai ena 1----2-Ni t poan i 1 ina .._,_ mi 1-_ —— Dimathylphthalate 1----Acenapht hy lane . 1——— 2.6-Dinitrotoluane 1

1

111111111111111111111111111111115611111111111111111111561156111111

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUtuIUIUIUIUIUIUIUIUIUIUIU1UIUIUIUIUtutui 4


1 1CSEMIVOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO,

Lab Name: ETCNJ

Lab Code:

Cont ract:

Case No.:


Sample uit/vol: 900.0 Cg/mL) ML

Level: (low/med) LOUt




SAS No.: SDG No.:


Lab File ID: >G9066

Date Received: ff11 f





99-09-2 ——————— 3-Nitroani 1 ine____________83-32-9--———---Acenaphthene______________51-28-5 —————— -2 ,4-Dini trophenol_________100-02-7——————4-Ni trophenol_________'132-64-9 ————— --Dibenzofuran_________,____121-14-2 ————— -2,4-Dinitrotoluene________84-66-2 ——— - ——— Diethylphtnalate__________7005-72-3——————4-Chlorophenyl-phenylether_86-73-7---~-----Fluorene___________________100-01-6 — - —— --4-Ni t roam 1 me____________534-52-1-—————-4,6-Dinitro-2-methylphenol_86-30-6-—--——-N-Nitrosodiphenylamine CD__101-55-3--—----4-Bromophenyl-phenylether___118-74-1--------Hexachlorobenzene_________87-86-5---——--Pentachloropheno1_________85-01-8--————--Phenanthrene______________120-12-7----——-Anthracene________________84-74-2 — ---— --Di-n-butylphthai ate________206-44-0————--Fluoranthene______________129-00-0---—---Pyrene_____________________85-68-7--———--Butylbenzylphthalate_______91-94-1- — ------3l3'-Dichlorobenz idine_____56-55-3----——--Benzo(a)anthracene________218-01-9--*-—--Chrysene___________________117-81-7——————bis(2-Ethylhexyl )phthalate_117-84-0- —————— Di-n-octylphthe late________205-99-2—-—---Benzo(b)fluoranthene_______207-08-9———----Benzo(k)fluoranthene_______5Q-32-8---------Benzo(a)pyrene____________193-39-5 —— ————IndenoC 1,2 ,3-cd )pyrene_____53-70-3---*—---Oibenz(a,h)anthracene______191-24-2----—--Benzo(g,h,i)perylene_______

(1) - Cannot be separated from Diphenylamtne

FORM I SU -2

5611565611111111115656111111561111111111112211111111111111111111

Q

IIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU

1/87 Rev.

460



ERA SAMPLE NO.

Lab NametETCNJ

Lab Code: Case No.:

Ma t r i x: (soil/wa t e r)WATER


Level: tlow/mod) LOU




Number TICs found: £

Contract:

SAS No.: SDG No.:


Lab File ID: >G9066

Date Received: tot/'/





CAS NUMBER

01. 141-78-602.03.04. 96-48-005.

COMPOUND NAME

Acetic acid, ethyl esterACETONE DIMERUNKNOWNButyro lactoneUNKNOWN

RT

5.066.428.908.239.84

EST. CONC

26067382520

Q

BJBJBJJJ


TOTAL ION CHROMRTOGRAHFUt >C9966 36

11 09999-

1999999-

999999-

809909-

799999-

609999;

500000:

409900-:

309000;

20000*

199999-;

a"1•.

i i -

i

1,[T

0-609.0 UU. CR2146C ,QC70892,LihTIC

49,9 , 00,9 , 12,00 , 1600 , 2000

^

I I

1 F

IJ Ifir i3s

911

<

.:

:

\ -^ f -! fL i '! I

U i? J

!

i- iI «t

1

7

* i

!; Mi's ^

12 16 20 24 29 32 36 40 44

Data File: >G9066::U3Name:Misc: CA2146C ,QC70092,L:M6,900,2



Quant Output File: ~G9066::AQ

BTt_*32

462

Operator ID: PT1575Output File: 69066: :AQData Fila: >G9066: :U3Name:disc: CA2146C ,QC70092 ,L:M6 ,900 ,2

ID File: IG0130: :PFTitle: IFB/8NA, PP/BNALast Calibration: 891116 12:11

QUANT REPORT


Di lut ion Factor

Page 1

891116 12:30891115 19:49

l.QOOOO

BTL*32

Compound R.T. Scant Area Cone Units

1)3)5)12)17)18)27)32)36)54)65)67)73)

»d4-l,4-0ichlorobenzene 10.65 347 2399612-Fluorophenol CSURR) 7.44 189 6421Phenol-05 CSURR) 10.06 318 21163N-Nitroaodi-n-propylamine 12.36 431 39811

*dS-Naphthalene 14.43 533 492184Nitrobenzene-05 CSURR) 12.36 431 256345Naphthalene 14.80 551 5561

»dlO-Acenaphthene 19.88 801 1644092-Fluorobiphenyl CSURR) 17.95 706 267265

*dlO-Phenanthrene 24.31 1019 128347*dl2-Chrysene 32.32 1413 48013Terphenyl-014 CSURR) 29.33 1266 59325

»d!2-Perylene 36.32 1610 29832

40.001.473.70

ti.66-

UG/MLUG/MLUG/MLUC.'rlL

40.0037.79-.449

UG/MLUG/MLUQj'ML-

40.0039.0740.0040.0044.2240.00

* Compound is ISTD

UG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

907789

949483979797999391

Fil* >S9066 CB2146C ,QC70092 ,L |M6 ,900 Sc*n 72Bpk Rb 9999 , SUB NRH 5.06 min.

seee--4000-

.A-.

43

39\.1 . t • i

7055 61 \ 73 86 ge M?'\ / "} , X / N-..

40•-40.

. 1 . . . . . . . t . , i . . 1 . . , l . i . > . i . . ^i_a4*8 ' 6'0 ' 30 ' 106

Fil* HBS49K flc*tic acid, *thyl **t*r Sc*n 757Bpk fib 9999 0.00 min.

3000-•

4000-"

ft-

43

29

.1.

ji * ' *J 3801 , ^^ .1 ,7 N / /\ 1 . ,

-60*

-40

-640 60 S0 10e

Fil* MBS49K Pr.op»noic *cid. 2-m*thyl- ;c4n 756Bpk Pb 9999 3.00 min.

43

S000-

4000-

oJ , ——— , , , . • • , . . . . , . . . . , . -. ———— . , . . . . , . . . .-r

2739N^

i l l . , J ,

I-SO

SS 7,3 S369 •'

,1 . ,s- (. , 1,

-40

-fl40 60 30 100

Data FiIs: >G906d::U?Name :Misc Data: CR2146C .QC70092 ,L: fib ,900 ,2RT Cmin): 5.06Scan: 72Hrea: 2872860 Rani- : 1Semi-quant i tat :ve Cone '.'uncorrected)!Semi-quantitative Cone ( corrected

118.81 UG-'MLC64.01 uq 1

BTL*32

Calculated using Istd: d4-1 ,4-Dichlorobenzene |S 10.65 minute*

1. Acetic acid, ethyl ester2. Propanoic acid, 2-methyl-

33 C4H30238 C4HS02

Sample f i l e : *G9066 Spec t rum #:Search speed: 2 T i l t i n g option: S 'No. of ion ranges searched

Prob

60

CAS * CON

1417867Q? 12

219"74 93

ROOT

23•-*••>

OK S TILT

00

CON

1?

R IU

6JO17

464

Fil* >Q9066Bpk fib 9999

i 43

10000-

8000-

6000-

4000--

2000-.

8_ Jl

C02146C ,QC7e092,L:ri6,900 Sc*n 139SUB NRM 6.42 nln.

r

59/

40


4310000-

8*00-

6000-

4000--

2000-

J

/

ilj

c

J40

101

/3 1 x6 ' Xr \ ii lL

-100

-QO

-60

-40•-20.•fi

80 ' 120 ' 160 ' 200 ' 240 ' 280

2-Pentanan* , 4-hMdroxy-4-m*thv>l- Sc *n 28510 .00 mm .

r.

9'

10183 / 102

....... L. iv******

-

-30

0

-40•-20

-e80 129 160 200 ' 240 2S0

Data F i l e : >G9066: : U?Name :disc Data: Crt'2l46C .OC70092 ,L= M6 ,900 ,2PT < mm ) : o . 42Scan: 1?9nr ea : 73? 2*+ 9 Pan I : aSemi-quant i t a t i ve Core f unco r rec t ed J :Sem i -quan r. i * a *. i •-'* Cone C corrected ) '•

70.72 UG.-'M!67.73 ug "I

BTU#32

Calculated using I=.td: c4- 1 ,4-D ich lorobenzene 1»» 10.6? minutes

2-Pen t anone , «-h vd ro >-v-^-me t hy 1 - 116 C6H12Q2

3.-j n-.p 1 * f i l e : Gg 0 6 6 5p e c t r u rn tt:Search speed: 2 T i l t i n g o p t i o n : S

179Nc . • o f ion r .a e 5 5 « a r c e d

1.

=rob. CAS tt CON f ROOT

123*22 I"'"?

K OK ttFLG TILT "i CON C_I P_!U

*7 40 2 0 ^- - 42 l*t

465

FU* >G9066 CR2146C .QC70092 ,L tf16 ,900 Sc*n 261flpk fib 9999 . SUB NRM 8.90 min.

_10000-

8000-

6000-

4000-

2000-

ej

41X

.,

43

71

SS/ 63

. ....Illll....,20 40 60

.1.1.. II..I 1 ,SO

-

S3

S9

...r < ™ :/8'I'H'l'l'l , .','! |'|'. !'|'l 1 l'|-| 1 1-

100 120

-100

-60

-60

-40

-20

-0

Film NBS49K l-Prop#n#, 1-chloro- 3-ran 343Bpk fib 9999 O.OO min.

4110000-

6000-

6000-

4000-

2000-

O-

— •*

18 27,..(.. .,!.. .,l!

4; 51

• 20 40 60

76i

*1

s... ! . . . , , .;J(j

9

109 ' 120

-100

-30

-60

-40

-20

-e

Data File: >G9Q6&::U?Name :Misc Data: CA2146C .QC7Q092,L:M6,900,2PT "imin): 3 -'? 0Scan: 261Hrea: 412169 Rank: ?Sen-j i -q.jan t 11 a t i p.'e Cone •" un corrected'1:Semi-quantitati'.'e Cone '' corrected '':

17. 04 UG-'ML77.33 ij

BTL#52

Calculated using ! « t d J d 4-1.4-Dichloro benzene |? 10.6^ minutes

1 . i-Prop«n«, i-c 76 C7H5C1

San-ip 1 e f i 1 * : GQ Ct6 Spec t r um ^:earch speed: 2 T i l t i n g option: S

261No . of 10r r a n q e s searched:

1.

Prob. CnS * CON # ROOT \f DK OFLG TILT CON C_! P_!'.i

466

Fil« ,-119066Bpk fib 9999

42

8000-.

4000-.

Q J , , , , , , . . , , , , . , , . . . , . ,,

.till55,.. ;>

20 40

Fil» HES49KBpk At 9999

23•

S000-.

4000-'

0-1

42

24

Vl

'

.. . ,11

€5îi . . i

J • 1 r I p , , . p I r i , h . ( I 1

20 40

CR2146CSUB h4RM

56 86S "\

'.i. \60 80

Eu ty ro I ac ton*

56 '366S

1F , 1 1 ' , , 1 1 • , | P

60 i O

Ti l* NBS41?* Eutinoic AC i d . 4-.:Bpfc Ob 9999

42

ÔOOJ "*

4000- 14

pi'"''. .! .,. Jl«

. . i•30 40

C6

-•''

i 1

*'3 ' iI-'O

,QC7009£,Lif16,900 Scan 2288 .23 mm .

110 140f^ / N

-60.-40.

">Ln100 ' 120

i! •: an 6170.06 rti i n .

-

87

/'r 1 . 1 ' 1 | • 1 t 1 ( T 1 1 1 | J 1 . f , 1 1 J

-30

-

Ô

"K"

100 120

More.- Ccar .?? i l60.00 mm.

-60

37.-•'"

-40

-a100 120

. a ta F i l e : ôOeo : : U?

4 : CA21-6C . O C 7 0 0 9 2 .L: M-i , 9 0 0 .2

'r t r e ^ : 2727 i~ ^ a n l : t.Ssrn i -qu *r. t i t a f. i '-.-e C o - s c '. ur c o r r e i t ed J : 1 1 . 2o UG -'T1L'E-e n-; •. - q u -3 r t i tat i • -e Co n c ( c o r r e c t e d ) : 2 ? . 0 3 u g •- 1C a ! c u 1 a t * a us ing I ; t d : d4- l ,^-Dichlorobenzer ie (? 10.6? m i n u t e

E. u * <-, r- o 1 5 c t c n e3 u t a n o i c . a c i d , . - c K 1 o r c -

86 C4H6G2^

£.an,p I * f i l e : '• 066 Spec tr urn ^ :T i l t i n g o p t i o n : Mo . :> f i G r r a r' q e = s e a r c h e d :

CON 41= POOT i itFLC- T ; L T

211 6

. /• rj4 o 7

Fil* ;C9066Bpk fib 9999

' 1 i ' ''4

FiU NBS49KBpk Bb 9999

3 M 4

C02146C ,0070092, Lt 116,900 ScanSUB NRtl 9.34

5743 59 '/ , 69,1 / 127 I41 156 i97 IS*

II.. .,,,,1, M .. i. / Y ^r"'e' 80 ' 120 ' ' ' 160 ' 200

Ethan* , ixothiocvanato- ic »n0.00

59 /?

S ,~ 89

' 40 ' 30 ' 120 ' 1 40 ' 200

Fi 1* NBS49KBpk fib 9999

Ac*ti* id*, N ,N-dim*thwl- Scan6.00

44$7

I S5 ^ Sl8

307nin .

mm .

'-Q

701riin.

40 ' so ' lie ' i40 ' 200F i 1* NBi4?KBpt fib 9999

: 4«- , | ," P4 •

0 .60

•-• ^qgS 72 39

40 30 120 160 260

nin .

<i

Oat a F i l e : G9066: :U?

Misc Data: CA21*6C .QC7QQ92,L:M6,°00,2RT fm i n ) : 9.84Scan: ?Q7ftrca: 21^268 Rank: 7Semi-quantitative Cc nc funccrrected): 8.93 U'a-'MLSem i -quan t i t a t i ve Cone f. corrected J : 19.97 ug.-" 1C a l c u l a t e d using I s t d J d4-l,4-Dichlorobenzene j3) 10.6? minutes

3TL#32

i . E t wi a n e , i s o t h i •:• c y a n a t o -C. Acetamide, H ,M-d i me t hy 1-7 . Thio c va nic acid, ethyl ester

37 C7H5NS87 C4H9NO37 C3H5NS

1 e f i l e : 'j1-1 066 Spec t r urn # :h speed: 2 T i l t i n g option: S

30:No. of ion r-anqe* searched: 46

CAS '- CON « ROOT K DK ttFLG TILT '; COn

K 4C 8 S S -2 i '2 f I6S49 ' 3 4 "*2 2 0 66 27 17^-^gr -219 MBS4' ^ 43 43 2 0 124 74 16[:-,20Or ""217 '-lES-'^i 21 30 2 0 130 '1'3 :^

468

TQTQL IQN CHROHQTOfiRQMFU« >S9

uwte-

1380000-

400008-

300000-

700000-

600000-

T 00900-

400980^

ja0e0*

0-

197 3S. 0-S00.0 »mu. CWZ146C ,QC37921,l_iTIC •

400 880 1208 1680

g S!*X

5 S ^.•S v-, E

|| | I

? g | fl *

» li ;| 1 1 1 sE ci 2 f isSk • Ti " X ' •)

1 V 1

j _ JLJ ——• i • p - i • F • i - i • i • i • i • i • i • i - F • i • i • r • i • ! • [ • ! •

4 8 12 16 20 24 23 32 36 48

Data F i l e : >G9197: :U6 U.jant Output F i l e : '".-'•'197: :

flisc: CA2146C ,QC87921 ,L: M4, 92 U, 2

Id F i l e : I GO 134: :UST.Me: IFB/BNA, PP-'BNrtLast Ca l i b r a t i o n : 391127 16:01

Operator ID: CA:'-375Duant Time: 891123 20:16Injected at : 891128 19:31

BTL#

469

1QUANT REPORT

Operator ID:Output File:Data File:Name tMisc: CA2146C

CA3875^G9197::AQ>G9197::U6

Quant Rev: 7

,QC87921,UM4, 920,2

ID File: IG0134: : USTitle: IFB/BNA, PP/BNALast Calibration: 891127 16:01

T imeInjected at

Di lut ion Factor

Page 1

891128 20:16891128 19:31

l.OOUOQ

BTL* 5

Compound R.

1)12)17»18)32 )36)5A165)6;->73)

*d4-l ,4-Dich lorobenzene 10.N-Ni t rosod i-n-propy lamine 11 ••dS-Naphtha loneNitrobenzene-05*dlO-Acenaphthene2-Fluorob iphenyl

»dlO~Phenanthrene*d!2-Chrysene .Terphenyl-D14

»d!2-Perylene

13.( SL'RR ) 11.

19.CSU'VR) 17.

23.31.

CSURR) 28.35.

T.

14338933334375717870

Scan*

356439540439807714

1024141512711611

Area

2331213651241382024 "?216252522 > Li 192241379fci3915817449f 14

Cone

40•'

404U403640405840

.00*-*«-.00.64.00.96.00.00.86.00

Units

UG/ML•UU '1L"UG/MLU«'"1LUG/MLUK -1LUG/MLUG '"1LUG/MLUG-'ML

q9U^ i94V.'.999-j98°y93V-.

* Compound is ISTD <6P//-*»

470


ERA SAMPLE NO,

Lab Name: ETCNJ

Lab Code:

Cont ract:

Case No.:



Level: (low/med) LOU)


Extraction: (SepF/Cont/Sonc) SERF


SAS No.: SDG No.:


Lab F i l e ID: >G9071

Date Received: 10/12/89





108-95-2 —————— Phenol___________________111-44-4——————bis(2-Chloroethyl )ether____99-57-8 ——————— 2-Chlorophenol_______541-73-1---—---1,3-Dichlorobenzene________106-46-7—————1,4-Dichlorobenzene________100-51-6---- — --Benzyl alcohol____________95-50-1————————1 .2-Dichlorobenzene95-48-7———————2-Methyl phenol____________108-60-1-——---bisC2-Chloroisopropyl)ether_106-44-5--- —— --4-Methyl phenol_____________621-64-7--------N-Nitroso-di-n-propylamine_67-72-l---------Hexachloroethane__________98-95-3---------Nitrobenzene______________78-59-1---- — --- Isophorone________________88-75-5----—---2-Nitrophenol______________105-67-9----—--2,4-Dimethylpheno1_________65-85-0----- — --Benzoic ac id______________111-91-1——----bis(2-Chloroethoxy)methane_120-83-2——-----2,4-Dichlorophenol_________120-82-1------—1,2,4-Trichlorobenzene_____91-20-3-------—Naphthalene_______________106-47-8--------4-Chloroani1 me ________87-68-3---------Hexachlorobutad iene________59-50-7----—---4-Chloro-3-methylphenol____91-57-6—————--2-MethylnaphthaIene________77-47-4-——-----Hexachlorocyclopentadiene__88-06-2---------2,4J6-Trichloropheno1______95-95-4---------2,4,5-Trich loropheno1______91-58-7---------2-Chloronaphthalene________88-74-4---------2-Nit roani1ine __________131-11-3- ————— -Dimethylphthalate_____;____208-96-8--------AcenaphthyIene._____________606-2Q-2--------2,6-Dmitroto luene_________

111111111111111111II1111111111115611111111111111111111561156111111

Q

IIUIUIUIUIUIUtutuIUIUIUIUIUIUIUIUiUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU

471FORM I SU -1 1x87

• icSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:


Sample wt/vol: 890.0 Cg/mD ML

Leve1: (lou/med) LOW

SMoisture: not dec. dec.

Extract ion: CSepF/Cont/Sonc) SERF


Cont ract:

SAS No.: SDG No.:


Lab F i l e ID: >G9Q71




Dilution Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:<ug/L or ug/Kg) UG/L

99-09-2 ———————— 3-Nitroanil me_____________ 5683-32-9---------Acenaphthene______________ 1151-28-5----- — --2,4-Dmi t ropheno 1__________ 56lO'Q-02-7--————— 4-Ni trophenol______________ 56132-64-9--------Dibenzofuran______________ 11121-14-2--------2,4-Dmi troto luene_________ 1184-66-2 ——— -----Diethylphtha late___________ 117005-72-3-------4-Chlorophenyl-phenylether_ 1186-73-7-- — -----Fluorene___________________ 11100-01-6 —— -----4-Nitroanil me_____________ 56534-52-l--------4,6-Dmitro-2-methylphenol_ 5636-30-6---------N-Nitrosodiphenylamme (1)_ 11101-55-3--------4-Bromophenyl-phenyle ther__ 11118-74-1--------He xach lorobenzene__________ 1137-86-5---------Pentachloropheno 1__________ 5685-01-8---------Phenanthrene_______________ 1112Q-12-7--------Anthracene_________________ 1184-74-2---------Di-n-buty Iphtha late________ 11206-44-0--------Fluoranthene_______________ 11129-00-0 ———— —— Pyrene______________________ 1185-63-7---------Butylbenzylphtha late_______ 1191-94-l---------3,3'-Dichlorobenzid me_____ 2256-55-3--------- Be nzo C a ) anthracene_________ 11218-01-9--------Chrysene___________________ 11117-81-7--------bisC2-Ethylhexyl)phthalate_ 11117-34-0--------Di-n-octyIphtha late________ 29205-99-2--------Benzotb ) f luo ran thene_______ 1120 7-08-9--------Be nzo (k )f luo ran thene_______ 115 0-32-8---------Be nzo (a )pyrene_____________ 1t193-39-5--------IndenoC1,2,3-cd)pyrene_____ 1153-70-3---------Dibenz(a,h)anthracene______ 1119 1-2 4-2-------- Be nzo (g,h, i )pery lene_______ 11

- Cannot be separated from Diphenylamme

FORM I SU -2

Q

IUIU1UIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI UIUIUIIUIUIUIUIU!U

4721/87 Re-

IFSEMIUQLATILE ORGAN ICS ANALYSIS DATA SHEET


ERA SAMPLE NO.

Lab Name:ETCNJ

Lab Code: Case No.:

Ma t r i x: (soil/wa t e r)WATER

Sample wt/vol: 890.0 <g/mL)ML

Love 1: Clow/med) LOW

S Moisture: not dec. _____ dec , ___

Extract ion: (SepF/Cont/Sonc> SERF

GPC Cleanup: CY/N) N PH:

Number TICs found: a

Contract:

SAS No.: SDG No.:


Lab Fi l e ID: >G9071




Dilution Factor: I


CAS NUMBER

01.02.03.04. 541-05-905. 5429-56-106. 541-02-607.08.,

COMPOUND NAME

ALKENEACETONE DIMERUNKNOWNCyc lot r is i loxane, hexa methyl2-Propenoic acid, 2-CacetylaCyc lopentasi loxane, decamethUNKNOWNUNKNOWN

RT

5.526.544.206.195.8114. 024.2625.72

EST. CONC

50050302616201029

Q

JBJJJJJJJ

j_

TOTAL ION CHROnflTOGRPHFile >G9871 3S. 0-580. 8 Amu. CRZ147C ,QC70891,Li

TIC

1288088-

1100080-

1080080-

908080-

eeoeee-

700080-

608884

680004

400888-

300080-,

200900-

188808-

480 , 80,0 | 1290 ( 1600 | 2088

-

1 Iif£ 3 § ^.

l8

* 1

. 1

» i s 5- J « "^s I I t s1 SB N | 1 1 t5 1 i! 3 |

•co ! fr 'i

i- ' 1" 2 i?» . ]" i^ I ?»e

4 ' 8 ' 1*2 ' 16 20 ' 24 ' 28 ' 32 ' 36 ' 4'0 ' 44

Data File: >G9071::U7Name :Misc: CA2147C ,QC70091,L:N6, 890,2

Id F i l e : IG0130::PFTitle: IFB/BNA, PP/BNALast Calibration: 891116 12:11


Quant Output File: ^69071::AQ

BTL*37

474

QUANT REPORT Page

Operator 10:Output File:Da t a File:Name:Misc: CA2147C

PT1575~G9071::AQ>69071::U3


Di lut ion Factor

,QC7QD91,L:M6, 890,2

891116 12:578911.16 00:27

1.00000

BTL#37



3)5)12)17)18)32)36)52)54)62)65)67)72)72)72)73)74)74)74)

•d4-l,4-DichloPobenzene 10.67 349 2305152-Fluorophenol (SURR) 7.48 192 62491Phenol-05 (SURR) 10.08 320 40949N-NitPOSodi-n-pPOpylamine 12.36 432 41914

•d8-Naphthalene 14.41 533 519116NitPobenzene-D5 (SURR) 12.36 432 278418

•dlO-Acenaphthene 19.88 802 1514992-FluoPobiphenyl (SURR) 17.95 707 2901652,4,6-TpibPomophenol (SURR) 22.30 921 25416

•dlO-Phenanthpene 24.32 1020 164366Di-n-butyl phthalate 26.66 1135 15170

»d!2-Chpysene 32.31 1413 76382T«pphenyl-D14 (SURR) 29.34 1267 130693bi*(2-£thylhexyl)phthalate 32.31 1413 4578bis(2-Ethylhexyl)phthalate 32.97 1445 9393bis(2-EthylhexylJphthalate 33.05 1449 3318•d!2-Pepylene 36.32 1610 18547Di-n-octyl phthalate 34.10 1501 3975Di-n-octyl phthalate 34.23 1507 3010Di-n-octyl phthalate 34.82 1536 13533

* Compound is ISTD

4 0 . 0 014.91

7.45Ifr.??

UG/MLUG/MLUG/MLU6*'ML

40.0038.9240.0046.0342.6540.00• a.26

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUC/MW

40.0061.24

UG/MLUG/ML

•UG/ML1 ?g '"VML

40.00 UG/ML3i76 DC'ML

-2. BO UB-'-nL12.81 UG/ML-

9275943894979298969797999455469895929599

475

REFERENCE STANDARD SPECTRUMrtu >J7Bpk Ab 9

18860-

0-*

992 TARGET REFE999 SUB

l'0 ' 00 ' 120

RENCE SPECTRA Scan4RM NOM 35.16149^

16*0 ' 268 ' 248 ' 2^8

8179Din.

-188

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)Fill >C9671 CA2147CBpk Ab 4856 SUB

1494008-

0^1 ... | ... | ... | ... i . . . ! • • • i ... | .

57 83 I04\ 78 y j, 135

M ^ ^.S^/ .. / .167

40 80 126 168

t QC76i>91.LlM6.

287X

200

221f

240

8 Sc*n 153634.82 n in .

a/"8\

-186

" ' • a«- 'SAMPLE SPECTRUM (UNALTERED)Fil* >6967tBpk Ab 4850

4808-

- 43- -*•"

9- ft d

40''/WMT -MV80

CA2147C ,QC70091,LiM6f149

104/ 133

i r -. <- •

-*••

167 287 209

/ .V120 ' 16*0 ' 208 ' 248

8 Sc*n 153634.82 «in.

-180

265 2V ;

' 28 0

Data File: >G9071=:U3Name:Miac: CA2147C ,QC70091,L:M6, 890,2Quant Time: 891116 12:57Injected at: 691116 00:27

Quant Output File: "G9Q71::AQ

BTL*37Quant ID File: IG0130::PF


Compound No: 74Compound Name: Di-n-octyl phthalateScan Number: 1936Retention Time: 34.82 min.Quant Ion: 149.0Area: 13533Concentrat ion: 12.81 LJG/MLq-value: 99

4 7 6

FiU >G9871 CBpk flb 9999 SUB

55

J 43

ll' 79IL.,1 ............ .1 40 eb

FiU NBS49K 3-P#nt«n-2-eBpk Pb 9999

561 ' ( ' » rj a .. ji . . , . " 1FiU»P*

FiUpk

-^

40 ' 80

NBS49K 2-P«nt*n», 4,4flb 9999

55. 41 i -"

40 ' 80

NSS49K 2-P»nr*n«,Pb 999?

55

»J U. .ij.hi ..bii ... i1 ' • i • ' ' r" '""r'i " ' • i""148 30

S2147C ,QC70091,LiM6, 8 ic*n 96NRtl 5.52 min.

93

99 155 195 :

'l20 ' 'l60'

n» , 4-m«thyl- Sc*n H770 .00 min .

83

, , IT?,, „ , , , , , , ; , , , , , , ) .128 160

-dim#thyl- , (2) - Sc*n 11890.00 min.

83ff

?9 E\f^^ Lfl

120 ' i£e

0.09 min.93•* • l-

99 E, ,'rr, . ; . , , , . , . , , . , , , , ,=e120 160

Data Filer >G9071::U3Nama:disc Data: CA2147C' ,QC70091,L:M6, 890,2RT (min): 5.52Scan: 96ftrea: 11209312 Rank: 1Sem i -quant i tat we Cone (uncorrect ed ): 222.46 UG'''MLSemi-quantitative Cone ( corrected ): 499.91 ug/1Calculated using Istd: d4-l,4-Dichlorobenzene @ 10.67 minutes

BTL#37

. 7-Penten-2-one, 4-methyl-

. 2-Pentene, 4,4-d i me thy 1- , C2)-3. 2-Pent«ne, 4,4-dimethy 1-

98 C6H10098 C7H1498 C7H14



Prob.

81*eg*

CAS \

141797762670

CON # ROOT

614?6 14?

NBS49KNBS49KNBS49K

4479

OK *FLG TILT

2948 34

COM C_I P_IU

131918 20

23i o

477

\

Bpk Ab 999943

****-

0- r 4> ——

CA2147C .QC70091 ,LiM6, 3 Sc*n 146SUB HRM 6.54 min.

59j-" 101

83 / , 194 212 *" s...J......£ A . / .. ..' / X-

40

F i l » MBS49KBpk fib 9999

43

S000-

4000-

0-

51

1/1. ..,1 ..»' " ' 40' ' '

Fil* HB349KBpk flb 9999

8000-

4000-

0-

?

31

140

80 ' 120 ' i^0 ' 200 ' 240'

-89

-40

-0

2-P«nt»non#, 4-ht,'droxy-4-m*thy 1 - Sc»n 23510.00 m i n .

59

V :r'":".''i"' ", "i — i i i i i i i i . i i i . i i i i i ' i , i i i i i i i . i36 120 160 206 240

-S0

-40

-e

H«.»drop*roxid* , 1 . 1 -diiri»th'.' 1 »thu 1 Sc»n 34?0 .90 min .

59

rSS t j:0 te.0 £00 240

H30

-40

-0

1 ,L : M6 , 3 9 0 , C

Data F i le: ^G9Q7 i : :U?Name :Mi*c Da ta : CA21**7C .OC^PT i mm ) : b . ?4Scan: 146htrea: 1124036 Pant- : 25 * fn i -quan t i t a t i " e Cone f u n c o r r e c * . e d ) : 2 2 . 3 1 UG TILS e m i - q u a n t i t a t i ' - e Cone • c o r r e c t e d ): ? 0 . I? '-t-J ' 1C a l c u l a t e d using I s t d : d4- l ,4 -D ich lo robenz*ne j»j 10.6

1 . 2-per-1 anone . -*-Hyd r o.•,;.'-•*-me thy 1 -2 . Hy d r o p e r o A i d e , I , 1 - d i me t h y 1 * t h y 1

116 C6H1202•50 C-4H1002

'E a rn p 1 e f i l e ::>e a r oh speed :

GQ071 Spec t run-, #:: T i l t i n g o p t i o n : S

146hlo. of ion range •;• e a r c h e d :

Frob . CAS # CON # POO

123-.22 1^0

(-' DK ttFLG TILT % CON C_I P__I

UBS49K 43 4050

4 7 8

Fil» >C9071 C02147C ,QC73891Bpk Rb 9999 _ SUE NRM

11088-

10003-

9003-

£000-

7980-

6008-

53 00-

4008-

3808:

^003-1

i eee-

*

43

3-3

, 1 i l l

'

S3

^1 55 co .^ * _./ f **> >j 3 co 74

i . , i i , i . 1 1 . •;''. '" . ;x . -x• 40 SO 60 ~G SO

,LiM6, S Scan 314.23 min.

34 98

r'' . i ,

rH0

:100

™

**

J79

'**

-50

-40

-33

**

:i0^

90 ' 100

Data File: >G9071::U?Ma me :Ni*c D a t a : Cft214"C .QC70091,L :M6, 3 9 0 , 2PT (m in J : 4 . 2 0Scan : 71Mr*a: 66^19*4 Rank.: ?Sem i -quan t i t a t ive Cone < uncor rected t : 17.13 UG'-'MLSerni-quan t i ta t i vc Cone >, corrected ): 2Q.62 -jg-'lCalculated using !std: d4-l,4-Dichloroben2«ne !? 10. o7 minutes

BTL#?7

No PBH h i t s for t h i s scan.

479

riU >C997t CR2147C .QC78891 ,LiM6 , 8 Sc«n 129•pk Ab 9999 . SUB NRH 6.19 din.

.10099-

8009-

6000-

400*-

2800-

287

75 96 133 163 1914/s V /i l" ( \ t i

-^

1 f

.-188

-08

•68

-48

-28

40 80 120 160 200 248

Til* NBS49K Cyc loti-isi lox*n», h»x»»tthyl- Scan 22491•pk Ab 9999 0.88 win.

10000-

8009-

6080-

j 4090-

2809-

297

•

15 39 ?/6 ... V33 163 ,77 191

^. ?V .M. "V .. \ V f,222

i S48 ' 88 ' 128 : lie ' 230 ' 24C

-188

•88

•68

-48

-28

)

D«t* File: -»G9071: : U3Name:Miac Data: CA2147C ,QC70091,L:M6, 890,2RT (min): 6.19Scan: 129Area: 577995 Rank: 6Semi-quantitative Cone <unconnected ): 11.47 UG/MLSemi-quantitative Cone ( corrected >: 25.78 ug'lCalculated using Istd: d4-l,4-Oichlopobenzene @ 10.67 minutes

STL#37

1. Cyclotrisiloxane , hexamethyl- 222 C6H180?Si?

Sample file: -G9071 Spectrum *:Search speed: 2 T i l t i n g option: S


1.

Prob. CAS # CON # ROOT K OK

••3* 541059 23991 NBS49K 79 30

TILT \ CON C_I P_IU

0 -2 95 24 32 61

430

X

Fil* >6907tBpk f)b 9999

J ,20

FiU NBS49KBpk Ob 9999

(HrTT'i . rt4^'Vo '

FiU NBS49KBpk Ab 9999

J i

ii 1

20'


*.

CA2147C ,QC70091,Lin6, 8 Scan 110SUB NRM 6.81 min.

43****

.Lh

S3 87 J29

*5 [' *9 75 ' 100 111 113 ^.

40 60 80 100 120

l-Prop»n-2-ol , format* Cean

I608

0.08 min.43^ ,

19

*» l'

58^ ;48 ' 60 ' 30 ' 100 ' 120

Butanal , 3-methyl- Scan

1637

0.00 min.44

>9 V '^ S3/ ? i j*HI *""• r -t ... i nil ... .li . r*~

40 ' 60 ' 90 ' 106 ' 120

l-:;•0

£-Prop*noic acid, 2-(ac«tvlaninol - Scan 44860.00 min.

43

J j.B 28

•'••^y •"•'"• ——

87 .^* 59 68 73 f 10-1 11J^ 112 ll?

40 60 80 100 120

|

Data File: >G9071::U3Name:Miac Data: CA2147C ,OC70091,UM6, 390,2PT Cmin^: 5.81Scan: 110ftrea: 356100 Rank: 8Semi-quantitative Cone (unconnected): 7.07 UG'MLSemi-quantitative Cone ( connected ): 15.88 ug'lCa leu la ted us ing Istds d4-l,4-Dichlorobenzene [3 10. 67 minutes

BTL#3:

1. I-Propen-2-o 1 t formate•£. Butanal . 3-methyl-3. 2-P-*openoic acid, 2-''aQety lamino )-

86 C4H60236 C5H10012? C5H7NO?

Sample f i l e : >G9071 Spectrum *:.Secn*;h speed: 2 T i l t i n g option; S

110No. of ion ranges saarcned

P'-ob. CAS * CON ^ ROOT K

17* 72973000 1732 MBS49K 7027* 590363 1778 NBS49K 2o25* 5^*29561 7290 HBS49K 24

Or #FLG TILT

39 2 073 7 068 3 C

CON C_I R_!U

97100

5873

Q

1010

431

Fil» >C907l CR2147CBpk fib 9999 . SUB NRM

73

8009-

4000- 4B 122 193 223f . l/os / l/4 ^ X

40 ' 80 ' 120 ' 160 ' 200

251X

240

J9t,LiM6, 8 Sc»n 51414.02 nln.

2f7 355

T w "l,4 A. i ,••, T i280 320

.**-0

Fil» NBS49K Cyclop*r,twilox»n», d»ca*» thyl- Sc *n 40472Bpk Bb 9999 0.00 mm.

73

8000-«

4000-

0-45 191207

*0 " ' ' 80 ' ' 'l2o' ' 'l60' ' 200'Fll* NBS49K 7H-Dib*nzoCc ,a]c»r-tBpk Qb 9999

j 3800-

4000-

0-t

y3 y J? 133 /* I?7 221iTtV^..«r.,t i \ .-" \0- 30 120 160 206

251X

240*ZQl«

239

240

267 3«/ ^

L / _ !_' 'as'o' f '320'

-60

-40

-0

•;c*n 29*290.00 min,

26?

t

iU6*' 280' ' 320

e-40

-0

Data File: >G9071::U?Mame:hisc Oats: CA2147C ,QC70091,L:M6, 890,2RT (min): 14.02Scan: 514firea: 274^39 Rank: 10Semi-quant i tat i'..'e Cone >. uncorrec ted ) ' 8.37 UG'MLSemi-quantitative Cone C corrected ): 19.84 ug-'lCalculated using Istd: dS-Naphthalene @ 1^.41 minutes

yc lopen t as i loxane , decamethyl-H-Dibenso Cc ,g]carbazole

770 C267 C20H17M

Sample f i l e : >G°071 Spectrum #:Search speed: 2 T i l t i n g option: S

514 -No. of ion ranges searched

Prob. CAS tf CON * ROOT

39 5^1026 4328115* 1"4?92 75320

r.124

DK

71

frFLG

13

TILTio

\12549

CON

2c p. 13

432

Fil» >G907l CA2147C ,QC7009t ,LlM6 , d Sc*n 34Bpk fib 9999 SUB NRM 4.26 Bin.

43

8009-

4000-

0- 4

72\ 75 97

...,UL I./.. £

US/ 2SS

40 ' 90 ' 120 ' 160 ' 200 240

-90

-40

-0

Ftl» NBS49K 2-8ut*nont Sc Ml 257Bpk Pb 9999 0.00 mm.

43

eooo-4000-

0-

9«

' )r -

72X 74

„.., I/'

40 SO UO Uo ' 200 240

-80••40

-9

Fil» HBJ49K Prop»n», 2-m»thy|- 2c»n 37Bpk at 9999 0.00 mln.

43

3000-

4000-

0-1

27 H-, ,( 4 58 y......>-~

H90

-40

440 ' 80 ' 120 ' 160 ' 200 ' 240

Data File: >G9071::U3Name:Misc Data: CA2147C .OC70091,L:M6, 390,2PT (m:n ^: 4.26Scan: 34Mrea: 214?1'2 Pant : 12S*m i -quan t i ta t i •.'* Cone •'. uncor r ec t ed ) !Semi-quantitative Cone ( corrected >:

4.2? US''ML9.56 ug.-'l

BTL*37

Calculated using Istd: d4-i,4-Dichlorobenaene @ 10.67 minutes

2-3'j t an onePropane, 2-ms t h y1-

72 C4H80= 8 C-^HIO

anr.p 1 e f i l e : ; 'a r c h speed: 2

Spec t rum tt:T i l t i n g option: S

3*+Mo. of ion rangei searched

Prob. C*S # COH ROOT OK

-4-? 3 MBS4-5K 26 -*3248 '!8S49f. 2-5 40

'LG TILT "a CON C_I P_!'

0 38 73

433

fiU >69071Bpk flb 9999

10000-

6000-

4000-

200e-0-

1

45 ?! !33y / \

CA2147C ,QC70091,Lin6» 8 Sc«n 1089SUB HRM 25.72 min.

56x

327

2531 ?S /X 2,05 1 26r 311

..-. »j.uLiL..L j. It i v. L

s*'

4

I 399

,r >\

asf

-100

-80

-60

-20

50 100 150 200 250 300 350 400

FiU HBS49K 8-METHVL-13, 14-DIOXO-SH, 13H , l4H-HflPHTHO (1 ' ,2' Sc *n 36763Bpk fib 9999 8.00 min.

10000-

8000-

600.0-

J -1000-

. 2000-

0-

77 1363 / l* /

327

312

-56 f5 tq5 201 \ 284i

N/. V i 1 1329

50 100 ' 1EQ ' 200 ' 250 ' 3^0 ' 350 ' 400

-100

-30

-68 •

-40

-20

-0

Data F i l e : >G9071::U3Name:Mime Data: Crt214?c .OC70091,L:M6, 890,2RT <nun>: 2? . 72Scan: 1089Arsa: 153062 Panl : 1?Semi-quantitative Cone (uncorrected ): 12.94 UG'MLSemi-quant i tat i"e Cone f corrected ): 29.03 ug-'lCalculated using Istd: dlQ-Phenanthrene W 24.72 minutes

BTL*?:

?-METhYL-l?,l4-DIO:Oj-SH,13H.14H-NAPHTHOtl' ,2' :5,6)PY 327 C21H17NO?PANO ( 2 , ? -B) QUINOLI ME

f i l e : G'?L'71 Spec t run-, ^:apesd: 2 T i l t i n g option: S

1089'Mo. of ion ranges searched: 48

Prob. CAS # CON 4p ROOT

li* 7*050316 124 NBS49K

K OK #FLG TILT . % CON C_I P_IU

25 142 7 0 ' SO . 64 2 1?

434

TQTQL ION CHROMOTQCRflMFile >G9198 35.0-508.0

400. . . i . . . i . .1200000^

1100000:

1000000:

900000-

880000:

700000:

60000*

500000:

490000-

300000:

200000: [ s i?s

rCS2147C ,QC87921,Li

800 1200 160*. T ... . . i . . . J . . . i ; . . i .

iiI

4 8 12 16 28 24 28 32 36 40

Data Fi le: >G919B::U6Name:Muc: CA2147C ,QC37921 ,L: M4, 390,2

Id F i le : IG0134::UST i t l e : IFB/BNfl, PP-'BNALast C a l i b r a t i o n : 891129 09:10

Opera to r ID: CA3875Quant T ime: 391129 0 9 : 2 3I n jec ted at : 891128 2 0 : 2 4

Quant Output F i le : ^G9198: :AQ

4 8 5

QUANT REPORT

Operator ID: CA3875Output File: ~G9198::AQData F i l e : >G9198::U6Name:flisc: CA2147C ,QC87921 ,L: M4,

Quant Rev: 7

890,2



Di lut ion Factor

Page 1

891129 09:28.891128 20:24

1.00000

BTL# 6

Compound R.T. Scantt Area Cone Units

1)3)5)12)17)13)32 )36)52 !54)65'67)77 i

*d4-l,4-Dichlorobenzene2-Fluoropheno 1Phenol-05N-Nitrosodi-n-propy

•dS-NaphthaleneNi t robenzene-D5 (

»dlO-Acenaphthene2-Fluorobiphenyl2,4,6-Tribromopheno

*dlQ-Phenanthrene•dl'J-ChrysenaTerphenyl-D14

»d!2-Perylene

(SUM?)CSURR)

1 am i ne

SURR )

CSUHR)

1 C SURR )

I SURR)

10.6 .9.

11.13.11.19.17.21.23.31.28.35.

14926585893532417272727571'

356198332440540440807713925

1023141612701612

235390689539213624443779824596918215424205711757

243 5910858718590757164

401.

403740361140405640

.00

.78892

.00

.83

.00

.37

.81

.00

.00

.17

.00

UG/MLUG 'MLUG'-'ML' "- 'MlUG/MLUG "MLUGVMLUG 'MLUG-TILUG 'MLUG/MLUG 'MLUG/ML

928198

. 33949?989 •?9497979396

* Compound is I3TD

436


ERA SAMPLE NO.

Lab Name: ETCNJ Cont ract:

Lab Code: Case No.: SAS No.: SDG No.:

Matr ix: Csoi1/water) WATER Lab Sample ID: CA2148C

Sample wt/vol: 900.0 Cg/mL) ML Lab Fi l e ID: >G9072

Level: tlow/mod) LOW Date Received: 10/12/89

Mo isture: not dec dec






CAS NO. COMPOUNDCONCENTRATION UNITS:Cug/L or. ug/Kg) UG/L

i n o Q c ilUb-Vv-^----111-44-4- ——QK C "5 O

541-73-1 — —106-46-7 ———100-51-6----95-50-1-- ——O C .•. Q "?

1 no £ n 1 _.106-44-5 ----621-64-7 ———67-72-1- —— -98-95-3 —— --78-59-1-----88-75-5 ————105-67-9 — —65-85-0 —— --111-91 1- --120-83-2 —— -120-82-1 ———91-20-3-----106-47-8----87-68-3 ——— -59 50 791-57-6-----77-^7-4 ——— -88-06-2 -----95-95-4- —— -g 1 c;o 7 _ _ _ _83-74-4 ———— -1 3 1 _ 1 1_ 3___-208-96-8----606-20-2----

----Phenol----bis(2-Chloroethyl )e ther ____----2-Chlorophenol----1 r3-Dichlorobenzene----1 .4-Dichlorobenzene----Benzyl alcohol----1 .2-Dichlorobenzene----2-Methvlohenol----bisC2-Chloroisopropyl)ether_----4-Methvlphenol----N-Nitroso-d i-n-propy lamine __----Hexach loroethane----Ni trobenzene---- Isophorone-___2-Nitrophenol----2 ,4-Dimethylphenol----Bcnzoic acid-___b 1sl2-Chloroe thoxy) me thane __-___2 f4— Dichlorophenol----1.2.4-Trichlorobenrene----Naphthalene____4_Chloroani 1 me----Hexach lorobutadiene*___4_Ch laro-3-methKjlphenol----2-Meth'jlnaDhthalene----Hexach lorocyc lopentad lene __----2 .4 . 6-Tr ichlorophenol----2 .4 .6-Trichlorophenol----2-Ch loronaphthalena----2-NitPOaniline- _ _ _ n i m s t h y l p h t h a l a t e „----Acenaphth^lene----9;n-nin i trotolijene

1 t10 1 J11 U11 U11 U11 U11 U11 U2111 U25011 U !11 U l11 U11 U I11 U I11 U i50 J11 U i11 U11 U t1811 U :11 U11 U i11 U :11 U i11 U :56 U I11 U :56 U 111 U i11 U 111 U 1

1HO/


• icSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET

Lab Name: ETCNJ . Contract:

ERA SAMPLE NO.

Lab Code: Case No.' SAS No.: SDG No.:

Matrix: CsoiI/water> WATER


Level: Uow/med) LOW

Moisture: not dec dec




Lab File ID: >G9072






99-09-2 ————— —— 3-Nitroani 1 me___________83-32-9-——-——-Acenaphthene____________51-28-5————---2,4-DinitrophenoI________100-02-7---——--4-Nitropheno1_____________132-64-9-——---Dibenzofuran____________121-14-2 — -- —— -2,4-Dmi trotoluene________84-66-2————----Diethylphthalate_________7005-72-3—————4-Chlorophenyl-phenylether.86-73-7---------Fluorene__________________100-01-6- — -----4-Ni t roam 1 me____________534-52-1—----—4,6-Dimtro-2-methyIpheno1.86-30-6---- — ---N-Nitrosodiphenylamme (1).101-55-3--------4-Bromopheny1-phenylether_118-74-l--------Hexachlorobenzene_________87-86-5---------Pentachloropheno1________85-01-8—-------Phenanthrene____________120-12-7——————Anthracene______________84-74-2---------Di-n-butylphthalate______206-44-0-—-—--Fluoranthone______________129-00-0- — - — --Pyrene___________________85-68-7--——---Butylbenzylphthalate_____91-94-1- — ------3,3'-D;chlorobenzid me___56-55-3---------8enzo(a)anthracene_______218-01-9----—--Chrysene_________________117-81-7——————bis(2-Ethylhexyl )phthalate.117-84-0——--—Di-n-octyIphthalate______205-99-2—------BenzotbJfluoranthene_____207-08-9----—--Benzo(k)fluoranthene______50-32-8- —— - — --Benzola)pyrene__________193-39-5--------IndenoC1,2,3-cdJpyrene___53-70-?---------Dibenz(a,h)anthracene____191-24-2--------BenzoCg,h,i)perylene______

I156111156156111111.111111,111156156,111

I 11111.156111.111111111I 11111122111.111111111.til111

.111

.111

.111

.111I

tlJ - Cannot be separated from Diphenylamme

FORM I SU -2

Q

IIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUtuIU

1/37 Rev.

438

IFSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET


ERA SAMPLE NO.

Lab Name:ETCNJ

Lab Code: Case No.:

Matrix: (soi1/water)WATER


Level: Clow/med) LOW

S Moisture: not dec._____ dec.___

Extract ion: tSepF/Cont/Sonc) SEPF

GFC Cleanup: (Y/N) N PH:

. /Number TICs found:

Cont ract :

SAS No.: SDG No.:


Lab File ID: >G9Q72




D i l u t i o n Factor: ___/


CAS

01.02.03.04.05.06.07.08.09.10.11.12.13.14.15.16.17.ie.19.20.21.22.23.24.25.26.

NUMBER

928-94-9108-88-395.47-6100-41-4

541-02-6541-05-9

873-94-9

108-10-133467-74-2

54H-97-6622-45-7611-14-3620-14-4

59i-34-42050-24-0103-82-2

I1 COMPOUND NAME

IALKENE12-Hexen-l-ol , (Z>-IBenzene, methyl-1 Benzene, 1,2-dimethyl-IBenzene, ethyl-1 UNKNOWN1 Cyc lopentasi loxane , decame t h1 Cyc l o t r i s i loxane, hexa methyl[UNKNOWNICyclohexanone, 3,3,5-trimethIHCETONE DIMER1 UNKNOWN12-Pentanone, 4- me thy I -13-Hexen-l-ol, propanoate, tZ1 UNKNOWN[UNKNOWN1 UNKNOWN1 Cyc lohexasi loxane, dodecametIhcetic acid, cyclohexyl este1 Benzene, 1 -ethyl -2- me thy 1-1 Benzene, l-ethyl-3-methyl-1 UNKNOWN1 UNKNOWNIPropanoic acid, 1-methylprop1 Benzene , l,3-diethyl-5-methyIB^nzeneacetic acid11111

RT

5.617.974.657.387.0917. 1414. 106. 264. 24

11 .446 .6919.303.94

13.5525 . 7719.9427.4617.3611.509.6110.368.05

21.536.9313.7316. 02

EST. CQNC

19015013011055270220181717171108669782754844333832020

11 Q. |..-..

IJ1 JIJIJ1 JIJIJ1 J1 J1 JI8Jt J1 JtJ1 J1 J[J1 J1 JIJ1 JIJ1 J1 JI J1 Jt1111


439

TOTAL ION CHROHOTOCROHFlit >tt9«72 35.0-500.0 &»u. .

T I C1200

CR2148C ,QC7B091 ,Li

16.00 . 2000

4seooee-

3600000-

3200000-

2000000-

2400000-

2000000-

1600000-

1200000-

000000-

400000- & 5.1 T 62i 7

' 4 ' l'2 ' 1*6 ' 20 ' 24 20 32 36 48 44

Data F i le : >G9072:: U3Name:Misc: CA2148C ,QC70091,L:M6, 900,2

Id File: IGQ130::PFTitle: IFB/BNA, PPxBNALast Calibration: 691116 12:11


Quant Output File: 69072: 0

BTL#38

49U

QUANT REPORT

QuantOperator ID: PT1575Output File: ^G9072::AQData File: >G9072::U3Name :Misc: CA2148C ,QC70091,L:M6, 900,2

ID File: IG0130: : PFTitle: IFB/BNA, PP/BNALast Calibration: 891116 12:11

7 Quant TimeInjected at

Di lut ion Factor

891116 13:07891116 01:24

1.00 QUO

BTL#38

1)2)3)5)6)12)14)14)15)15)16 J17)18)20)22)26)27)27)28332)36 >37)39)50)52)

65)67J73)

Compound

*d4-l ,4-Dich lorobenzeneN-Nitrosodimethylamine2-Fluorophenol (SURR)Phenol-05 (SURR)PhenolN-Nitrosodi-n-propylamine2-Methylphenol2-Methylphenol4- Me thylphenol4-Met hy Ipheno Ibis(2-Chloroisopropyl Jet her»d8-NaphthaleneNi t robenzene-D5 (SURR)Isophorone2 , 4- Dime thy Ipheno 1Benzo ic acidNaph tha 1 oneNaphtha lene4-Chloroani 1 me

*dlQ-Acenaphthene2-Fluorobiphenyl (SURR)2-ChloronaphthaleneDimethyl phthalateF luorene2 ,4,6-Tr ibromopheno 1 (SURR )*dlO-PhenanthreneDi-n-butyl ph tha late*d!2-ChryseneTerphenyl-D14 (SURR)*d!2-Pery lene

R.

10.4.7.10.10.12.11.12.11.12.11.14.12.13.13.14.13.14.14.19.18.18.19.22.22.24.27.32.29.36.

T.

7165911822428330

300149425383387553539402

3039393646363836

Scan*

34750

210321323431402425402425362532431485500527496534534799705

919919

10161168140812621604

Area

1080837184299844114930113904321514783225773147832257732986

543511283582609325878193375734

11U64815113105683M3i;i124472206748427668619153598

24154323711119514251

Cone

40.

50.44.4.

9.14UW

113.O .40.37.O .

-tr22.

8." Z .40.73.-t-r

— *T165.40.

40.92.40.

00r /796144

46

f (

87

0086•tt-

70

09

0006

•84-

0600

000400

Units

UG/MLUQv'MLUG/MLUG/MLUG/MLUuVPIL-UG/ML

yrj r-ML

UG/MLUS' lieUG/MLUG/ML

UG/MLUG/ML

UG/ML•US'M'IL 'UG/MLUG/MLUGVMLUfr'HLUO.'MLUG/MLUG/ML

UG/MLUG/MLUG/ML

q93

luu87VI94

78

65yy100949474959190

70

98

66¥495

52

9391

* Compound is ISTD

491

REFERENCE STPHDflRD SPECTRUMFiU >LBMS TAR6ET REFERENCE SPECTRflBpk flb 9999 NRM NOM

94leeee-

•o_

39 65 66-" -- -i n40 ' 60 ' 80 ' 100 ' 120 ' 140 ' 160

SCAR 801881 .00 min.

-100•

-a' 180 ' 20*0 '

SflHPLE SPECTRUM (BACKGROUND SUBTRACTED)FiU >69Bpk Ab 5

4080-

07281S

c94

42 66 7i ""1

C02148C ,QC7e091,LiH6, 9SUB

19/

132 lv9 l

/ \40 60 BO 100 120 148 ' 160 ' 180

Scan10.22

94 210\ X1 zeV '

323kin.

-100

-0

SAMPLE SPECTRUM (UNALTERED)F1U >G9072 CA2148C ,QC70091 ,L iM6 , 9 Sc*n 323Bpk Ab 6211 16.22 Bin.

99 2»7

4008-_

0J

94<2 71 -^.

,jBl..d*iiiiL.iiJliL bl(h ,11

f

119 133 147 163 177 191,. . / L f .(. L L k

40 60 80 100 120 140 160 180 280

-100.••0

Data File: >G9072::U3Name :Misc: CA2148C ,QC70091,L:M6, 900,2Quant Time: 891116 13:07Injected at: 991116 01:24

Compound No: 6Compound Name: PhenolScan Number: 723Retention Time: 10.22 min.Quant Ion: 94.0Area: 11390Concentration: 4.44 UG/MLq-value: 94

Quant Output File:



492

REFERENCE STANDARD SPECTRUMFiU >E6936 TARGET REFERENCE SPECTRABpk Rb 9999 SUB

10810000-

•

,e-

77 79SI 7Z^f' \l 1ii Ik i

40 80 120

HRM NON

160 ' 200

Scan 86211.67 »in.

-180

•

,-fl

' 240 ' 288

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)FiU >G9072Bpk Ab 7162

•4080-

8- -prT-r

39a48

CA2148C ,QC7009l.LlM6, 9

9177 '

A.80108/

SUB

134

H,,(128

18' 218N j

Scan 40211.83 ain.

268/

hi 88

A168 ' 209 ' 240 ' 288

SAMPLE SPECTRUM (UNALTERED)FiU >G9872Bpk Ab 9926

10080-

39

fTk40

tea

- F fvjU^U*i • i i i80 120

CA2148C

Tr '"' ' 160 n

,QC78091

191 yA -,C2^0

,LiM6, 9

r23S249

' 240

Scan 40211.83 nin.

281s

h

hi0e

' 280

Data File: >G9072::(J3 Quant Output File: 69072: 0Name:Misc: CA2148C ,QC70091,L:M6, 900,2 BTLi38Quant Time: 891116 13:07 Quant ID File: IG013Q::PFInjected at: 891116 01:24 Last Calibration: 891116 12:11

Compound No: 14Compound Name: 2-MethyIpheno1Scan Number: 402Retent ion Time: 11.83 min.Quant Ion: 107.0Area: 14783Concentration: 9.46 US/ML-value: 78

493

REFERENCE STANDARD SPECTRUMFiU >EE936Bpk Rb 9999

10000- j_

0-

44

1

/

i||40

7J^ 79

if' ' ' 80 '

TARGET REFERENCE SPECTRANRM ENH NOM

107/ 100

120 ' 160 ' 200

Scan 96712.14 «in.

-108

,

-0' 240 ' 288

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)Flit >G9072Bpk Ab 81184

50000- _, 77 -9

o li dL t* *• #40 ' 80

CA2148CSUB

107

1' 119 178r" / \

'-•'tie 1 1" 1!*. 1 1

,QC70091,L

195209/ /

' ' 200 " '

iM6, 9 Scan 42512.38 «in.

-188'

253/ .

240 ' 288

SAMPLE SPECTRUM (UNALTERED)FiU >G9072Bpk Ab 81184

50000- ,. 77 „** * *% *k L,

49 ' 80

CA2148C

187

r * l?? 17<120 ' 168

,QC7089t

191 207

'"J200 '

,Lin6, 9 Scan 42512.30 *in.

-180

281 '249 \T ;i-y . 'I"- r. .''I'ff240 280

Data File: >G9072: : 1)3Name:Misc: CA2148C ,QC70091,L:M6, 900,2Quant Time: 891116 17:07Injected at: 891116 01:24

Compound No: 19Compound Name: 4-MethyIpheno1Scan Number: 425Retention Time: 12.30 min.Quant Ion: 107.0Area: 225773Concentration: 113.87 UG/ML-value: 99




494

RCrCRENCe_STANBARP SPECTRUMFile >J1646 TARGET REFERENCE SPECTRA Scan 3898pk Ab 9999 SUB NRM NOM 9.99 nln.

-,-, 1?5 12218808-

0~

/51/ r -180

•840' ' ' 80 ' 120 ' 160 ' 288 ' 248 ' 28*0 ' 32*0

SAMPLE SPECTRUM (BACKCRQUNP SUBTRflCTEP)FIU >G9872Bpk Ab 4467

4000-61

J,e-T-r-r48

CA2148CSUB

11973 '?S -

Jl__.1 1*8 193 _„

-** \ 2871 L . . . . \ /

90 ' 1^8 ' 168 ' 288 '

,OC78891,LiM6,

251\

'zi8

267 281

.<./,' \f* '

9 Scan 52714.38 Min.

32S3"/ k

-188

'$£9SAMPLE SPECTRUM (UNALTEREP)FIU >69072 CA2148C .QC78091 ,L iM6 , 9 Scan 527Bpk Ab 6779 14.38 »in.

73.

4000--

51

JliL-K,

f 1M ilf

1 . . , ! , ,48 88 I!

207 2B, 267 355

1. rVTi . \ (f *?.\[0 ' 168 ' 288 ' 248 ' 288 ' 32*8

-108

•

-0

Data File: >G9072: : U3Name:Misc: CA2148C ,0070091 6, 900,2

Quant Output File: ~G9Q72::AQ

BTLt38Quant Time: 891116 13:07Injected at: 891116 01:24

Compound No: 26Compound Name: Benzoic acidScan Number: 927R e t e n t i o n Time: 14.38 min.Quant Ion: 105. 0Area: 18337Concentration: 22.70 UG/ML

91

Quant ID File: IG0130::PFLast Calibration: 891116 12:11

495

REFERENCE STflHDflRD SPECTRUMfilm >IiBHSBpk Ob 9999

18808-

0-61

, f ,4'e '

TARCET REFERENCE SPECTRR Sc«n 3730NRH NON 373e.ee min.

128

64*

129

80 128 Ue 208 24*0 28"0 32*0

-100

'•9

SRHPLE SPECTRUM (BACKGROUND SUBTRACTED)FiU >69Bpk Rb S

40088-

0724784

I

51 y 102_.../.X.. j...i0- . , . — , , , . — ,— .—40 80 120

CR2148C ,QC7ee91,LlM6, 9 ScanSUB M.S3

20

146 223 „ 282"x x 234 265 y

1 *M ' W ' 24e' ' '2*V ' 'sie' ' '

534• in.

-100

•e

SflMPLE SPECTRUM tUNPLTERED)FiU >C9072Bpk fib 64784

™40008-

- 51 73i • , jk.H.

40 ' 88

C02148C

128

102^ j

U31'^ ™

120 ' lie ' 200

.QC78091 ,LiM6,

24 267 *,81

240 ' 288 '

9 Sc»n 53414.53 »in.

3f3\

-180•

320

Data File: >G9072::U3 Quant Output File: "-G9072::AQName:Misc: CA2148C ,QC?0091,L:M6, 900,2 BTL#38.Quant Time: 891116 13:07 Quant ID File: IG0130:=PFInjected at: 891116 01:24 Last Calibration: 891116 12:11

Compound No: 27Compound Name: NaphthaleneScan Number: 934Retent ion Time: 14.53 min.Quant Ion: 128.0Area: 110648Concentration: 8.09 UG/MLq-value: 90

496

1FiU > 69072Bpk Rb 9999

CA2148C .QC70091 ,Lin6, 9 Scan 97SUB HRM 5.61 Min.

? 83 '

J LjS0

FiU NBS49KBpk Rb 9999

/

1100 150 2003-P«nt»n-2-on« ,

434

259 300 350 4094-»»thvl- Scan

L1177

0.00 mid.55 83

1 ^* 1 Inl iiUL

SOFiU HBS49KBpk Ob 9999

99:

Jr— F.100 ISO 204 259 369 350 400

2-Ptnttn*, 4 ,4-dim«thy 1- Scan 12060.00 min.

55 «•*. / e3

J uSO

Fil* NB349KBpk flb 9999

t

V^ic0 leo 260 250 300 ' 350 490

-

'-9

2-P#nttn», 4,4-din#thH-, (Zl» Scan 11890.00 min.

55 83

50 100 150 200 259 300 350 400

-

Data File: >G9072::U3Name:Misc Data: CA2148C .QC70091,L:M6, 900,2RT (mm): 5.61Scan: 97Area: 19061368 Rank: 1Semi-quant i tat we Cone (uncorrected ): 34.86 UG-^MLSemi-quantitative Cone ( corrected ): 138.57 ugxlCalculated using Istd: d4-l,4-Dichlorobenzene @ 10.75 minutes

BTL#38

1, 3-Penten-2-one, 4-methyl-V_>2 . 2-Pentene, 4,4-d i.me thy 1-

7. 2-Pentene^ 4,4-dimethyI-, (Z>-

f i l e : >G9072 Spectrum tt:speed: 2 Tilting option: S

98 C6H10098 C7H1498 C7H14


Prob. CAS

1. 31* 1417972. 52» 262729347. 52* 762670

CON * ROOT

6140 NBS49K6145 NBS4QK6143 NBS49K

K

58793Q

OK

745157

#F!_G

09o

TILT

000

s7590SI

COM

131319

C_I

452H20

71

19

497

Fit* >C9072Bpk fib 9999

J *ik.Ji'40FiU HBS49KBpk Rb 9999

1 27 *~*

0ijT 4*\-tt40

Fil* NBS49KBpk Ab 9999

U7 '"jjJJ(j l.lilL |...M

'4'0

File NBS49KBpk Ab 9999

55

elcJ ,• 40

CP2148C ,QC7Q091-.Lin6. 9 Sc*nSUB NRM 7.97

57

82 oeX. 9^ 106 124 206

00 ' 120 ' 160 ' 200

2-H»x»n-l-ol , (Z ) - Scan0.00

57

" 82v. 98 100

80 ' 120 ' 16*0 ' 2^0

Cycloh*x*nol Scan0.00

57

32> 130

b j..,,H .....I-, -| - j - ,--,

30 120 160 200

Cyc loh»xanon» Ccan0.00

6Z^ 83 ^ 99

30 ' 120 ' 16*0 ' 200

213itin .

[

,399Tiin .

:

i«1384mtn.

I.153nin .

\

Data File: >G9Q72::U3Name:Misc Data: CA2143C ,QC70091,L:M6, 900,2RT Cmin): 7.97Scan: 21?Area: 14973416 Rank: 2Semi-quantitative Cone (uncorrect ed ) ' 66.66 UG'-'MLSemi-quantitative Cone ( corrected ): 148.13 ug/1Calculated us ing Istd: d4-l,4-Dichlorobenzene |9 10.73 minutes

BTL*?8

I. 2-Hexen-l-ol, rz»-CyclohexanolC',-c lohexanone**

100 C6H120100 C6H12098 C6H1QO

Sample f i l e : >G9072 Spectrum #:Search speed: 2 T i l t i n g option: S


Prob.

59*58

CAS -.

923-34*103970103Q41

CON ft

^3705866Q429

ROOT

HE549KNBS49K

K

505758

DK ftFLG TILT

48 1 03? I 0TQ rt '~>.•O *- -

CON

777767

c,i27 TO

T'T

498

Fil* >C9072 C02148C ,QC?Epk flb 9999 SUB MRM

91

J 3* 51 65 74

3091, LiM6, 9 5.:*4.65

J?115 128

t^L —— <* .20 40 60 30 100 120

Til* NBS49K B«nz»n», Bitthyl-Bpk flb 9999

91

3 2 15 27 *9 SI 65 77

Scan0.00

93 94

20 40 60 80 100 120Fil* NBS49K 1 ,3,S-Cycloh*pt«tri»n*Bpk flb 9999

91

! 28 39 5 ! 65 ??

0: i . , . , . . . i | . i 4,.' , inl|'n.-i 1'i'in . , rinll'i | .'inf.., , i-in'j . , . . , . . . . , . . , , . , , . . , . , ,

Scan0.00

93 94

20 40 60 80 100 120Fil* HBS49K Cyclobut«n», 2-prop*nul id*Bpk Pb 9999

91

3 27 39 51 « 77

•> 50Kin .

I884nin .

«889• in .

n*- Sc*n 8S30 .00 min .

93 C.-" La1 1 1 1 . .. .p .... r ......... ........... ..,,.... F ........ p .,...-,..,...

20 40 60 30 100 120

Data File: >G9072::U3Name:Misc Data: CA2148C .QC70091,UM6, 900,2RT (rr;in) : 4.6?Scan: ?0Area: 12770470 Rank: 3Semi-quantitative Cone •uncorrected): ?6.67Semi-quantitative Cone ( corrected 1: 125.94 ug--'lCalculated using Istd: d4-l ,4-Dich lorobenzene (3 10.7? minute*

BTL*78

I. Benzene, methyl-1,7 ,5-CycloheptaCyc lobutene., 2-propenylidene-

f

\ > > 1 j? ,5 -Cyc lohepta t r iene92 C7H892 C7H392 C^HS

Sample f i l e : G9072 Spectrum #:Search speed: 2 T i l t i n g option: S

50Nc. of ion ranges searched:

Prob. CAS * CON ft

97* 103883 8475^ 5 4252 947953* 520*7355 3474

ROOT K

N8S49K 75MBS49K 45MBS49K 44

DK #FLG TILT

1540

6864100

CON C_I P_I'J

•441318

687 A96?

499

FilBpk

Bpk

FilBpk

FilBpk

• >G9072 Cflflb 9999 SUB '.

] 39 51 65 77

23 40 60 30

• NBS49K B*nztn« , 1 ,flb 9999 «

] 39 51 ts 77

' 20 ' ' 40 ' ' 60 ' ' ' 30 '

• NBS49K E*nz*n*fflb 9999 t

3 15 39 51 65 77

£0 40 6@ 80

• HBS49K B*nz*n«, 1 ,flb 9*99

•3

~\

£9 ' 40 ' 60 ' 3b '

2148C .QC70091 ,L:M6, 9 Sc *n 184NRM 7.38 min.>1

196 "' 127 141 1S4 :

190 ' 120' ' 140 ' 160 ' 130

2-dinitthyl- ;.c*n 13160 .00 mm .

-1

106 tf icr r

'l0'0' ' 'lie' ' 'l40' ' 'l60' ' 'l30

•th^l- $c»n 1S100 .@0 mm .

1,~

...i r j>100 ' 120 ' 140 ' 160 ' 180

3-difli*thul- lc*n 131 10 .OQ mm .

1

107 E

100 ' 12S ' 140 ' 160 ' 130

Data File: >G9072::U7Name :r i i ic D a t a : CA2148C . O C ^ O Q ?PT f nun i : 7. 735 c a n : 184- i rea: ill"S7 tr6 R a n k : 4Bern i -q-j-an t i : a t ive Cone ' unco r r sc t ed J : 49 . 76 'JG.--ML=-er:: -quart t i t -3 t i i.>e Cone ( c o r r e c t e d ) : 11 0 . 59 uq.1 ' 1C a l c u l a t e d us i ng I a t d : d4- l ,^-Dichlorobenzen» |it ID.77 m inu te :

• n z e -i e .: n z e n e ,n z e n e ,

f i l e :speed :

Prob.

94*

1 , 2-d i meethyl-1 , 7-d i me

M390722 T

CAS ft

10041*+108737

thyl-

thyl-

Spectrum ft:i i t i n g option: S

CON ft ROOT

11010 MBS49K11006 MB349K1100" NBS-i°k

106106106

134No . of ion ranges

K DK ftFLG TILT

7'5 13 1 067 21 1 06 4 2 3 0 0

S

6832

CSHIOCSHIOCSHIO

=• e a r c h e

COM

Q

d:

£_I

63CO

500

u. V V'.i ii i- ni in v

• • it! iv '.«J (3 i—T r; ...t • TlT — 4 ' -4 IB O u'J i/i I' U i "D ;i Z O

|[i 3"^ ft fl- »fc >1> '-J "~i 1 - fl' *0 (•• - vfl 3 — 3 3 <P 0) i'i 3 •-»•

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9 3c*n 51314.10 min .

355 b323 ^tww^320 360

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Data File: -G9G72::U7Ma me :r i i - c Oa*a: CA21**SC ,QC70Q°1 ,L:M6 , °0RT ''minj: 14.10Scan: 517MT e.a: 2602737 Pant-. :3emi-quan t i t a t i v e Cone -uncorrected):Sem i -quan t i t at i '.-e Cone '. corrected ) :C a l c u l a t e d using I s t d : d'3-Naph tha 1 ene

°7.62 UG.'Tli216.97 ug'I1-4 . 49 rr i nu t

BTL#78

1 . C ; c 1 o p e n t- a i i 1 o.-, -a n e . d e c a m e t h y 1 -2 . l?H-uiber.zo La , i Icarbazole7. 7H-0ibenzoCc ,g1c arbasole

770 C10H300?Si?267 C20H17N267 C20H17N

Sample f i l e : , G9072 Spectrum $ '•e a r •:• h speed: 2 T i l t i n g option: S

517No. of i o r range* searched

Pnb

1?*

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9675

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207 r

133 I?? 191103 / 147 \ /i / v- svVr-H- A- -T T-rTY -i1-]- -rr- -v

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Data File: >G9Q72::U?Name :Misc Data: CA2143C ,QC70Q?i ,!_: H6 , 900,2PT tm i n ) : 6.26Scan: 12*Area: IS72642 Rank: SSerr: i-quant i tat i ve Cone t unco r rec t ed ) : 3.16 UG.-'MLSerr, i -qu an t i t « t i ve Cone ( corrected ): 13.13 ug'lCalcula t e d using Istd: d4-l,4-Dich!oroben2cne @ 10.73 minutes

Cyc 1 o t r i s i 1 oxane , hexarnet hy 1 - A ui 1 * n T c . "o n i- •-''-/. s -

f i l e : /G9Q72 Spectrum #:peed: 2 T i l t i n g option: S

129No. of ion r a n a e 5 s e -s r c r e d

Prob. CAS tt CON *F ROOT K

3-4 541059 28991 HBS49h 93

DK ^FLG TILT % CON

16 i Q 31 9

504

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Cfl214SC .OC70091 ,LiM6, 9 3c»r, 30SUB NRM 4.24 mm.

js ?e 193 -2SQ''' ^ "/ x^-. .J. . f

"'P1'"' 1 . . . , . . . , . . . , . . . , . . . , . - .-r . . . . . . . r • ,-r30 120 1&0 200 340

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99

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Data F i l e : >G9Q72::U7Name :Misc Data: Cfr21**3C .QC70091 ,L:M6 , 900,2RT (mm J : 4.24Scan: 70Area: 1746913 Rani- : 9Semi-quan t 11 a t i ve Cone njncor r ec t *d J : ".73 UG-'MLSem i -quan t i t a t i ve Cone i. corrected ) : 17.23 ug ' 1Calculated using Istd: d4-1 ,4-Dich lorobenzene !3 10.7? minutes

BTL#?8

. E t h a r o n e . 1 - '- 2 - rne t h y I c y c 1 o p r o p y 1 ) - 93 C6H1QO

e f i l e :Sea f"ch .speed :

'£9072 Spectrum % :T i l t i n g option: S No. of ion ranges searched

D r o t . CA3 # CON # ROOT K DK tfFLG TILT

11 * 9 ? 0 ? 6 7 c 1 ? t f 4SS 4* \'

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Data File: >Q9Q72: :U3Name :Miac Data: CA2i^SC ,QCroPT (mm): 6.69Scan: 150Area: 1631957 Pant' : 11Semi-quantitative Cone ( uncor r ec t ed ) : 7,49 UG.-'MLSemi-quantitati'.'« Cone ( corrected > - 16.64 ug-'lCalculated using Istd: d4-l ,4-Dich lorobenzene I? 10. 7? minutes

No PBH hit*, for t h i s scan.

b07

Fil* >C9072 Cfl2l48C ,0070091Bpk flb 9999 CUB NRM

281•«•..

j 45 ?f3 103 V33 163 1 9 3207 249

48


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: 44- .-^

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80 120 160 200 240 2S

LiM6, 9 S-:»n 76319 .30 win .

361 h285 331 ^1 E

«' ' '320' ' '368

3,6-BlS(N-LIMETHYLflriIHOJ-9-ETHYLCflRBfiZCiLE ic*n .514720.00 min.

281

117 141 166 193 222 250 J82 t

, , , ....Tv-t'' >', , n- n-', ' t ' , J . fT, . . . . . ,E«90 120 168 208 240 230 320 360

BENZENE, l-PHENYL-4-(2-CVflHO-2-PHENYLETHENYL> Scan 314840.00 mm.

281

-^ 113126 :!2 ij7 £03 ^ \J** $. .1 .1, r. .'. r' . .--"" r^ j*7 , „ jt • lMf tfl

S0 120 ' U0 200 ' 240 ' 280 ' 320 ' 360

Flof phi nan , ? ,S-did*hyaro-3-m* thoxj/-! 7-

281

70 96 147 I60 188 226 238

m»thyl- Sc»n 314760.00 min.

^ '•'-a. i - r p • i • T • i • i • : • i • i • I • > • i • s • i

30 120 160 208 249 2S0 320 360

Data F i l e : >G9072::U?Name :Misc Data: CA2148C .OC7Q091 .L:M6 , 900^2RT f mm > : 19.30Scan: 763Area: 17^2722 Rank: 12Semi-quant, i tat i'.,»e Cone iuncor rec t sd j : 51.4q UQ.-'MLSem i -quan t i * a t i ve Cone ( corrected ) : 114 . 43 ug. •' ICalculat-d using Istd: d3-Naphthalcne @ 14.49 minutes

BTL#?8

1. 7,6-BIS- N-DlnETH'VLAr-;lNO:'-9-ETHYLCARBAZQLE 281 C13H23N32. BENZENE, i-PHENYL-4-i2-CYANO-2-PHENYLETHENYL) 281 C21H15N7. Mor p h i n a n , 7,3-did eh yd ro-3-me t h o xy-i 7-me t h y1-6-me t h y 231 C19 H2 3 NO

1 e n e - ,


768No. of ion ranqes searched: 4&

Prob. CftS COM tt

27* t?~'10704? 7778Q

2 f * 13 16 Q o •+ - 7? Q 0

ROOT

HBS49KNES49K

DK #FLG TILT

11913214 i

1001 0 0100

CON

394244

10c3 17

b08

Fil* >C9072Bpk flb 9999

: 39

' '3'0' ' ' V0F i l * HBS49KBpk Ob 9999

. 291 ' 39

gjft ,., , ,. j|l|30 40

F i l * NBS49K OxiBpk fib 9999 t

gj .. ^1 1,30 40

FU* NBS49KBpk fib 9999

.

3 27 394 --' ""v04^ ——— i^

90 40

C02148C .QC70091 ,LiM6, 9 Scan 15SUB MRM 3.94 (Bin.

43r ,

^3 '51 / 69 72 83 8S 10e 112 1

r-i-rtA-11- !' rr -T^ • ' •>>•''' >'• ~ j50 60 70 80 90 100 1 IS2-P*ntanon* , 4-m»thyl- Scan 1363

0.00 mm.*3 ce

.S3 . 67 3E - *f^iei t

50 60 70 80 90 100 110ran*, £-m*thv/l-2- £ 1 -methy I* thy i ) - Scan 1371

0.00 min./3 58

/ *~52 66 ''.. ss iae t

, . ,'..i,l ., ,'' ! r" ,'' L50 60 70 80 90 100 110

l-Prop*n-£-ol , acetat* Scan lo2E0 .00 mm .

(3

5,8 7Z SS 100 101 :/-——— ^. . - , . . . . , . . . . r . . . . . . . . . r . , . , , . . . . r .

50 60 7@ 30 90 1C0 110 i

Data File: >G9072::U7Name :fUsc Data: CA2143C ,QC70 09 1 ,L : f16 , 900/2RT Cm in): 7.94Scan: 1?Mrea: 8-40790 Pant : 165emi -quar t i t a t ive Cone ' unco r r ec t ed ) : 7. 4 UG-'MLS«mi-quan *•_ i t a t i ve Cone f corrected ): 8.71 ug--'lC a l c u l a t e d using Istd: d4- i ,4-D ich 1 orobenzene (j) 10.77 minutes

3TL#?8

2-Per t anone , 4-methvl-Cx i rane , 2-methy1-2-C1-methy 1ethy1 )-l-Prop»n-2-ol, acetate

100 C6H120100 C6H120100 C5H802

Bar-pi* £ile: -G9Q72 Spectrum #:Search speed: 2 T i l t i n g option: S No. of ion ranqes searched: 45

F-ob.

-1*"C*T 7*

CAS *

108 1017222107?

103225

CON

176*17701766

FOOT

BS49

NBS49

J> J•?

706942

TILT

0 .' y0 1000 1 0 0

6612

14

bG9

FiU >S9072Bpk fib 9999

57

40 ' 60FiU NBS49K 3-H»Bpk fib 9999

57

: 29' S- 41

8 * .1.1. 1 1.. ..,,..wihif, ,, i , ,.. 11, pu.,40 60

F i l e MBS49K Cyc loprop*n«Bpk fit) 9999

671 39 41 """

40 ' 60

Flit NB349K CyclopropaneBpk fib 9999

67

1'V "eJl,,.. JJi, ,.ll, ......i • 1 • r • i j• 40 63

CB2146C ,QC70091,Utn&, 9 ScanSUB NRM 13,55

82'/ 99 113 128 138 194

80 ' 100 ' 'l20 ' 140 ' 160 ' 130<«n-l-ol, prop»no»tt, (ZJ- Sc»n

8.80

8231 37-*-^TI' i i i i i i i • i ' i > i i i • i i i i i

80 130 128 140 160 180

486min.

H3

5667mm .

» , 1 ,2-dim*thyl-3-n>*th}.>lffne- , c is- Scan 4710.00 min.

*i. jiz «•* E• ?'?rc7T7' . • j — i • . • i • i • i • i • ! ^80 108 123 140 168 180

, 1 ,2-diai#thyl-3-m*th(;l*n»- , tran 2c«n0.00

81 ^2 34

i • i • r • i • i • i • i • i • i • F • i • i30 100 120 140 160 180

460tiin .

Data F i l e : >G9Q72::U?Name :nisc Data: CA214SC .QC70091,L:M6, 900,2RT (.mm': 17.??Scan: 486rtrea: 738491 Rani-- : 17Serni-quan t i tat i^.-e Cone ( uncor r ec t ed ) : 29.93 UG-'T1L_Ssrri-qijantitati'.'e Cone t corrected ): 6? . 77 ug •' ICalc'jlated using Ia*d: d9-Naph tha lene |B 14.49 minutes

BTL#33

i. 7-4exen-l-ol, propanoate, fZ)-2 . Cyc lopr opane , 1 ,2-d i rue t hy I -7-m« thy 1 ene- , c is-~ . Cyclopropane. l,2-dirriethyl-7-rnethylene-. trans-

156 C9H160232 C6H1032 C6H10

S-arnple f i l a : >G9Q72 Spectrum #:earch speed: 2 Tilting option: S


Prob .

4841*

CAS # CON # ROOT K DK

•orfl 74&0 NBS49K 54 4l

TIL CON C I P I

e

b l O

Fil# >C9072Bplr fib 9999

11000-;

10000-j

9000-j

8080-;

7908-j

6008-j

500*j

4999-

3999-_

£000-;

1000-j 4S

0-

CA214SCSUB NRM

327

253

195

25.77 Bin.

:i0e

H"0

485

339

*9

|-30

-10

100 150 260 2S0 300 356 409

Data File: >G9072::U3Name :Misc Data: CA214SC ,QC7Q091,L:M6, 900,2PT fmin): 26.77Scan: 1085Ares: 75"'131 Rank : ISSemi-quantitative Cone tuncorrected): 47.3? L'S 'T1LSemi-quant i tat ive Cone '•. corrected ): 97.3° ug-'lCalculated using Istd: dlO-Phenanthrene (3 24.36 minutes

Mo PBM hits for t h i s scan.

511

o~

TJro"z

T-

-.-t

U'

-no"1

,-*•IT.-•IH

i*oft3•

n u"i u~i T u") i-i .1 ~1 O0< it 1i -> O ^ •• if &

n • • — IK ^ - o »T i*r i i • • • • = !

T^ "^ TO? •-*.-r Ql |> - .1- —o» 3 3 o xj •• ui *Q. •* •' '-1 O

- .- 4.. oC .-r f 1 I— 1 Iin fli CM to O f- G~>« rt- rt> |-J tJ '-O•^ ^. . ^, -jj | — . ,_~,

•n ; " t t *-Jii ii co to

-. n -in i i r~i.-» O O C CQ. "1 ' i Ql . ' .•!•- n o 3 O

j i

»-* u -r..on D i-^ .n>i o n ij oTJ -50 l-ir T -i(i *» -i r~3 O •»ft .-* O IS1 ill .-r O*<-* a. •»^r CL-. - . oa> •• •• o3 Oiff -•

f-Jr=i

CO '_•!t j l_i l>

• 0- J•jl 0 1 Ja-

c r-3 tu (Ti

3 — :i

wnT) *•

" <-j w *. 01 c. -j 01 - n o * - *O O I S ) O O O 1 ^ O * £ i £ i O ^

^. ^».- . t . . . . l . . i . l . . . . l . i j . l . . . . i . . . . i . . . . l . . . . l . . i . l . . . . l lii'D

0\

-

."

•3

'"^

-

<3-«

_

r.>*--^s

Iv-

m^

<jttf~

"— ;S5P-^-. «n -0("

^._

i '

t " §>r-"-- LO.

«^' — - „

'""" ^ f£ c.— O

D

" • 01* ^ *^1(4 3*

- I? «•u>

-_

O-JO®^^r

l\* ••^- (0 3tn *•

1

^. i i^>f.

3

A ^- |.j u> JL -}i <). -g ft- • ! • » - • - **• ~io o . ^

roHr

FiU >C9072Bpk fib 9999

110001

10000-j

9909-]

5000-j

709C-:

6000-

5000-j

4000-;

3008-j

2000-:

10007

0-

73"

•U5*

CS214SC .QC70091 ,LiM€., 9 lean 1168SUB NRM 27.46 min.

rllB135

VL..I jL,jL.

/

197

185

U jjf

32<5 47*267 \ 417 ••

251 / ^ 371 401 / \/ •' S ' . I *

... ^11 .. . i.i. X. ..V L . i•.•'• '.•T''f*J'V'y-'."-Tf-p-| 'f • * r'l'-'1 i- -i""f i-v i • | i i • • | • i • ' i • • •100 150 200 250 308 350 406 450

•133

^?0

:H30

:70

J«0

^0

140

J-30

:20i•:e

<

Data File: :• G9Q72: : U?Name :riisc Data: CA2143C ,QC70091 ,L: Ho , *QQ,2RT (. mm) : 27.46Scan: 1168Area: *7°°Q8 Pant : 22Semi-quantitative Cone 'unconnected): 7?.?T UG -'MLSemi-quantitative Cone i. cornected ): 74.59 ug.-'lC a l c u l a t e d using Istd: dlO-Phenanthnene @ 24.56 minutes

BTL#73

No PBM hits for this scan.

b13

Fil» >C9Bpk flb 9

80*8-

4808-

9-

Filf. NBSBpk flb 9

8000-

4000-

e-

Filt MBSBpk flb 9

3000-

4000-

0-

072 C02148C .QC70091 ,L lM6 , 9 Sc*n999 . SUB NRM 17.36

73

-341325 '' 429

45 ,,^ 147 "3 223 __, 267 y j 397 V",...,. 'A:. (... \..\. ..71/:. .\[ \ \5ft 100 150 200 250 388 3S& 405

49K 2-CHLORO-4-I.4-METHOXYPHEHYLJ-6- (4-NITROPHENYL lean 3999 0.00

341 '

28 ' S/* 3? 12? 13'3 19>0 ^16 2S2*"\ /6 3^4

jl.. .. ,.. >, . .\.;X . ^ ;' . . . L . . .w L . U . -^*

'50' ' 100 ' ' 'l50' ' ' 200' ' ' 250 ' ' 300 ' ' 350 ' ' '460

49K C';c Ioh#x4£i loxan* , dod«c*ffi*thv 1- 2c»n 4999 C.Ofl

73

i' 429325 .

4S 117 1/? l91 207 267 \ 3971 . , / . I N ^ / L I N . t•50 100 150 200 250 300 356 400

673nin .

-46

-0

3121

-80

-40

-0

4S1Snin .

•ee-40

-0

|

Data FiIs: >G9072::U?Name i'Use Data: Cft2l43C ,QC7>3 09 1 , L : M6 , 900,2RT (min): 17.3&Scan: o"7?Hrea: 5^6ol7 Rank: 27Serrt i -quan t i t a t i ve Cone (uncorrected): 21.67 UG-''MLSemi-quant i tat i 1J« Cone ( corrected ): 48.07 ug.'lCalculated using Istd: d8-Naphthalene @ 14.49 minutes

BTL#38

1. 2-CHLOPO-4-'.4-METHOXYPHENYL)-6-(4-NITROPHENYL)PYRlMI 341 C17H12C1M307D I HE

2. Cyc 1 ohexa* i 1 o <ane , dodecarnethyl- 444 Ci2H?606Si6

Sarr,pl- f i l e : >G9072 Spectrum #:search speed: 2 T i l t i n g option: S

67?No. of ion ranges searched: 4"

1.

Prob

2?*o

CAS % CON # ROOT DK #FLG TILT CON C_I R_I'J

>?677^67 424392-, 540976 46642

NBS49KNBS49K

10684

514

FiU >C9e7£Bpk Rb 9999

43rr8 _lU....Jh.•* 1 I' l'l'l"40

Fil# HBS49KBpk fib 9999

^ 6;

0-Vrf rr^40

FlU HBS49KBpk fit 9999

6"41

JjlULjk,40

Fi 1* NBi49KBpk flb ?999

41_, .- 67

i 1 "e^^MkA•40

C0214SC .QC70091 ,L:M6, 9 ScanSUB NRM 11 .50

r 82

^ f 99 U6 145 177 193206 235250 281frUiU * fr .<. , i , ;\ . ,-rr>, . , /, , ••<. , ,, . , .< , , ^ , .- , M

80 120 160 200 240 230

Rcvt ic acid, c^clohtxyl **t»r '.c»n0.00

82* /i

100

80 ' 120 ' 160 ' 200 ' 240 ' 280

4-Hex*n-l-ol , (2)- Scan0.00

*

82f 100,W^LW ——————————

80 120 160 200 240 230

3-H*x*n-l-ol , 12)- Scan0.00

-- 32/ 100vf. J /

30 120 160 200 240 280

386nin .

"

'-9

£722n in .

'-G

1386nin.

I485

run .

^

Data F i l e : >G9Q72::U3Name :Misc Data: CA2148C .QC7Q091 ,L:M6, 900,2PT Cm in): 11.50Sc an: 336Area: 731269 Rank: 24Semi-quant i tat i -./e Cone (unconnected ) :Semi-quan t11 a t i we Cone ( connected ):

1.70 LJG'ML3.77 UG---1

Calculated us ing Istd : d4-1.4-Dichlonobenzene |3 10.73 minutes

1. Ac-21 ic ac id , eye lohexy 1 ester2. 4-Hexen-l-ol, (Z > -3 . 7-Hexen-l-ol ., (Z) -

142 C8H140:100 C6H12Q100 C6H120

Sample f i l e : >G9072 Spectnum #:Search speed: 2 T i l t i n g option: S

386No. of ion nanges searched

Prob.

'633*30*

CAS :

622457923916923961

CON ROOT

NBS49KNBS49KNBS49K

K

71452?

DK #FLG ~ILT % CON C_I =_

2047 12

File >C9072Bpk Ab 9999

3 39 51 65 77

V0 ' 80

File NBS49K BenzeBpk Ob 9999

; 39 51 65 77*""*- / / '

40 80

C02148C .OC7Q091 ,L:M6, 9 3c»n 293SUB NRM 9.61 fflin.

105

1 20V ^ 149 177 192 211 :

129 160 200

ne , 1 -e thy 1-2-methy 1- »c an 3 2?0.00 m i n

120 7

v1 ^ - - 1 2 1 • :'l20' ' 'l60' ' '200

File NBS49K Benzene, 1-e thyl-4-methy 1 - Scan 3296Bpk fib 9999 e.00 min.

105-t f' 1-H 120 h1 ^9 C1 &C 77 ^1 ' _^ 101 r137 51 O » ' < -i ( ffff 1 £1 L

40 80

File NBS49K BenzeBpk flb 9999

3 39 51 65 77pd...,T ...,,.,.1,. .....;: .....

' ' ^ p - l ' - ' l• 40 30

120 ' 160 ' '208

ne, l-sthvl-3-methyl- Scan 3297G.00 niin.

105

120 F9i ^ 1 2 1 :. - , .1 J . . • , • • . 1 . . , . , . , I 1

120 160 200

Data Fi le: >G9D72: : U7Name :Misc Data: CA2149C , OC70 0^ 1 , L : Mb , 900,2RT (mm ) : 9.61Scan: 293Area: 379932 Rank: 2?Semi-quant i t a t i v e Cone (unconnected):Semi-quant i tat i ve Cone C corrected ):

1.69 IJG^ML3. 76 ug--'!

Calculated using Istd: d4- i ,4-Dich lorobenzene t? 10.73 minutes

1. Benzene, 1-e thy 1 -2-me t hy 1 -2. Benzene, l-ethyl-4-methyl-3. Benzene, l-ethyl-3-methyl-

120 C'3H12120 C9H12120 C9H12



1.

Prob

97*7*

CAS CON

611143 1766°622963 13o72620144 17671

ROOT

NBS49KNBS49KNBS49K

K

353431

DK

016

*FLG

001

TILT

n00

%

oo^697

CON

111

c_i•7-71~?o- j.•70

P_I'J

q-

9"1

°0

516

F i l » >G9072Bpk flb 9999

CA2148C ,QC70091,Lt)16, 9SUB NRM 10.36

105

330min.

0-

39 51 65 91120

13S 164 165 194 211

40 80 120 160 200F i l t NBS49KBpk flb 9999

B»nz»n», l-*thyi-3-in»thyl-

40 80 l20

0.003297m i n .

39""•

51.1 65

./M.Ml i

"••*t 1/

-rilUi — ,

91/^j, —— _

120^- 121—


B*nzsn*, l-*thyl-4-m*thvl-105

43 120 160

3c*n0.00

39

rt-i .irtn-i

51 65 77 91

t.-rfUfa-.tm/ .. .•••'( ...."'lil —— -;L

120^- 121

200

Fil* NBS49KBpk Pb 9999

39 51

40 90 20 168

6. 003293nun,

200

D a t a F i le : >G9072: :U3Name :Misc Data: CA214SC ,QC70091,L:M6, 900,RT (nun) ; 10.76Scan: 7?0Area: 345713 Rank: 26Semi-quantitativs Cone funcorrected):Semi-quantitative Cone C corrected ):Calculated us:ng Istd: d 4-1; 4-Die h lorobenzsne |i 10.77 minutes

1.54 UG.-'ML7.42 ug./l

1. Benzene , 1-ethy1-7-methy1-2. Benzene, 1-e thy 1-4-me t hy1 -7. Benzene , 1-e t hy 1-2-me t. hy 1-

120 C9H12120 C9H12120 C9H12

Samp 1e f i l eSearch speed

G9Q72 Spectrum #:: T i l t i n g o p t i o n : S


Prob. CAS ft CON

1. 94* 620144 13671

7. 97* 611143 13669

ROOT

NBS49KHBS49KNBS49K

K OK

121010

TILT \

100100

CON C_I P_IU

91111

686464

97g

r -1 i-jb i 7

Fil» >G9072 C02143C .QC70091 ,L iM6 . 9 Sc»n 217Bpk Ab 9999 . , SUB NRM 8.05 mm.

11000-

10000-

9000-

soeo-

6000-;

5003-;

4000-j

£003^

1000:

0-

f*

55

3?

^ 'W

112N

97 US jw. 179 192/ x 133 148 v x

4:«i ' 60 ' 30 1 00 ' 1 20 ' 1 40 ' 1 60 ' 1 30

rllO

:,oe

I-.30

™•€0

140

•20

-10

-0

Data Fi le: >G9072: : U3Name :Misc Data: CA2148C ,QC70091 .L: M6 , 900,2PT (rnin) : 3.0?Scan: 217Area : 743126 Rank : 27Semi -quant i tat ive Cone ( uncorrec ted ) :Serrii-quan t i t at i ve Cone C corrected ):

1.53 UG-'ML3.39 ug'l

BTUI7-

i - .Calcu. lated using Istd: d4-l;4-Dichlorobenacne |3 10. 73 minutes

No PBfl h i t s for th is scan.

b i s

Til* >G9Bpk Bb 9

11000-

10000-

9000;

7000;

6000;

5000;

4000;

3900;

2300;

1000;

0-

072999

45X

lull.s'e

CA2148CSUB NRM

73

267\

20?12? 1?4 !; V'

L ...ll..|i].i .1 i ,1 I if. i \ i »100 150 200 250

.QC70091 ,LiM6, 9 Scan21.53

435

287 325 255 j, .L. t t t. 1

300 350 400

877min .

pile

J-100

°

!*•«B

e"9-30

•20

-10

Data File: >G9072::U3Name :Misc Data: CH2143C -QC70091 ,L:M6 , =00,1RT i . m i n ) : 21.5?Scan: 877Mrea; 2Qbi349 Rank: 29S e r n i - q u a n t i t a t i v e Csnc Cuncorrected): 17,14 UG-'"MLS e m i - q u a n t i t a t i v e Cone f corrected ): 33.08 ug.'lCalculated using Istd: dlO-Phenanthrene (3 24.36 minutes

BTL#38

No PBM h i t s for t h i s scan.

519

Fil* >G9072 CP2148C .QC70091 ,L iM6 , 9 Scan 162Bpk Ab 9999 . SUB NRM 6.93 mm.

10000-

8000-

6090-

4000-

2000-

0-

57

41

j,lJiU ,*~i

75 191 US 133 148 163 191 ...( 8-6 ,' / / / / ' \ 2D

i. ... J. . i .1. f . t . ./ ' \ L1 | i i l"*n •I""!' | i i 1 | l-r r | i i-'i T , , . i i . . | i , . , i . . , T ,40 90 120 160 200

--100

-60

-60

-40

-20

-C

Fil* NBS49K Prop*noic acid, 1 -m» thy Ipropy 1 *sf*r Scan 4706Bpk Ob 9999 0-00 mm.

10000-

8000-

6000-

4000-

2000-

0-

57

29

\

/

^ 7 Bfi 1?1 US 13° 131i : o o •* yj -* -*.. J,P ,L .A ... t t. / . -40 80 120 160 200

_-100

-60

-60

-40

-20

-0

Data F i l e : >G9072:: U3Name :Misc Data: CA2143C ,QC7Q091,L:M6, 900,2RT (.mm,' : 6 . 93Scan: 162•Area: 277776 Rank: 30Semi-quant i t a t i v e Cone (unconnected) :Semi-quantitative Cone C corrected ):

1.22 UG/ML2.71 ug/'l

BTLK33

C a l c u l a t e d u s i n g I s t d : d4-1,4-Dichlorobenzene @ 10.73 m i n u t e s

1. Propanoic a c i d , 1 - m e t h y I p r o p y 1 ester 130 C7H1402

Sample f i l e : ^G9072 Spectrum #:Search speed: 2 T i l t i n g o p t i o n : S


Prob. CAS * CON # ROOT K DK #FLG TILT \ CON C_I R_K'

1. 33 591344 10265 NBS49K 53 26 1 0 68 4 57 21

520

Fil* >G9072Bpk Ab 9999

CP2148C ,QC70091,Ltn6, 9 Scan 495SUB NRM 13.73 min..133

_i 55*-s: 37 1 |

i% ' "~iJJd .uk0"*t i 1 1 TTl'FF146

Fil* NBS49KBpk ftb 9999

'/ 38 M9 /7 / /

j

(-jf |hurl'l"]H'HH IIL1 9'0 ' J20

t149 179 209 249 265 C

,h-~.. ' . / /**.£*160 ' 200 ' 240 ' 2^0

B*ni*n», 1 ,3-di*thyl-5-m*thyl- Scan 79660 .00 min .

1191?3-j ' ! h: si/

0 , , , , ,-,


77 «

M ,1 ,4-,-r4-, I'll ,vt,S0 120

149 E^ F0160 ' 2^ 240 ' 230

B*nz*n*, di*thyl»*thyl- Scan 79430.00 mm.

133_j

: 27 41«: .-; »-r.....V-1; [ ,i, , Jfri-t"(i

40

Fil* NBS49KBpk Bb 9999

"j

H 5l

0J , !1T-• 40

119 ,'77 ^1 i'^ / i,H-. ,*., .It, ,4. n^.nili80 120

h

i 50 Lt vr; ...,,,.....,,..,,.,,..., c«160 200 240 290

3 (2H) -B*nzofuranon*, 6-m*thyl- Scan 78723.00 min.

119 H-/63 9°bJ y

• llfr,*>,Jt,, 'I.. •[,.«.

83 120

~~* -

150 :K la160 200 240 290

Data File: >G9072::U3Name :Misc Data: CH2148C ,QC70091,L:M6, 900,RT (min): 13.73Scan: 495rtrea: 243335 Rank: 315 e m i - q u a n t i t a t i v e Cone (.unconnected):Semi-quantitative Cone t connected ):C a l c u l a t e d u s ing Is td : d3-Naphthalene @

9.13 UG/ML20.29 ug/114.49 m i n u t e s

BTL#38

1. Benzene,. l , 3 - d i e t h y l - 5 - m e t h y l -2. Benzene, diethy 1 methy1-3. 3(2H)-Benzofuranone, 6-me thy 1-

143 C11H16143 C11H16143 C9H8Q2

Sample f i l e : >G9072 S p e c t r u m #:Search speed: 2 T i l t i n g o p t i o n : S

495No. of ion nanqes searched: 46

Pnob. CAS

1 . 9 3 * 20502402. 91* 255501343. 35-* 20395414

CON # ROOT

190461904213*98

NBS49 KNBS49KNBS49K

K

908045

DK ftFLG TILT

202363

759147

CON C_I R_IU

2931og

575014

9 69412

521

Fil*Bpk

Fil*Bpk

FillBpk

>G9072fib 9999

8 ' 'i 'eVNBS49K

fib 9999

] 39 65

C02148C .QC70091 ,L:t1$, 9 Scan 607SUB NRM 16.02 mm.

91

136 F107 / 177192 268 232 356 t

12V ' 'U0 ' 200' ' 240' ' 280 ' 320'Btnitn»»c*tic acid Scan 5534

0.80 mm.

136 F105 / 138 t

1 '40' ' 80 ' 120' ' i6Y ' '200 ' 240' ' 'zeV ' '32VNBS49K

«b 9999

3 39 65tfJ -f-f -*l-j 4-H

B«nz»n*, (•thoxynethvl) - Scan0.00

»1

lf7 ^s 137

40 80 120 160 200 240 280 320Fill NBS49KBpk fib 9999

<

! 39 65*- - •*-•— -i — •

5606nin.

B*nz«n«, ( iodomtthyl ) - Scan 217940.00 mm.

)1t-

127 218 219 E

'•40 ' 30 ' 1^0 ' 160 ' 200 ' 240 ' 238 ' 320

Data File: >G9072::U3Name :nisc Data: CA2143C ,QC7Q091?L:M6; 900,2RT (mtn): 16.02Scan : 607Area: 240358 Rank: 32Semi-quantitative Cone Cuncor rec t <ed ) : 9.03 UG-TILSemi-quantitative Cone C corrected ): 20.08 ug-'lCalculated using Istd: d8-Naph tha lene (3 14.49 minutes

BTL#38

1.. Benzsneacetic acid2. Benzene, '. e thoxyme thy 1 ) -3. Benzene, C iodomethy1)-

136 C3H802136 C9H120218 C7H7I


607Mo. of ion ranges searched: 46

1.

Prob .

73*52*42

CAS

103322

62 GO? 3

CON =

1661434943447

ROOT

NBS49KNBS4-5KNBS49K

K

302333

DK

627446

ILT

000

94100100

CON C_I R_IU

1955 1420 1217 13

522

TOTOL IQN CHQQHQTOCBOMFill >C9888 3S.e-Se8.e MU . CBZ14BC ,BC7B«l,LiF

3680008-

3200088-

2808080-

2488808-

2888888-.

1680008--

1280888-

800800-

400000-

8-

480 ( 868 t 12,88 , 1688 ( 2888

fa

2

1

?B g ^ ? Ej- 5 § a n1 i - -* 1 :' i 1 -jjj;jj|!!J|j j

4 ' 8 ' 1*2 ' 16 ' 28 ' 24 ' 28 ' 32 ' 36 ' 48 ' 44

Data File: >G9088::SSName:Misc: CA214BC ,0070091 :116, 900,2



Quant Output File: ^G9Q88::AQ

BTL*14

QUANT REPORT Page

Operator ID:Output Fi1«:Data File:Name :Miac: CA2148C ,QC70091,L:M6, 900,2

CA3875-G9088::AQ>G9088::SS

Quant Rev: 7 Quant Time:In jected at:

Oi lut ion Factor:

891117 02:53891117 01:46

1.00000

BTL#14

ID File: 160131: • PFTitle: IFB/BNA, PP/BNALast Calibration: 891116 16:06

1)2)3)5)6)12)

15)15)17)18)20)22)26)27)27)27)28)32)36)37)39)50)52)

65)67)73)


*d4-l,4-Dichlorobenzene 10.58 344 179032N-Nitrosodime thy lamina 4.40 41 573472-Fluorophenol (SURR) 7.73 204 143462Phenol-05 (SURR) 10.09 320 91557Phenol 10.13 322 10584N-Nitrosodi-n-propylamina 12.29 428 469182-Methylphenol 11.74 401 147032-Methylphenol 12.21 424 2369104-Methylphenol 11.74 401 147034-Methylphenol 12.21 424 236910

*d8-Naphthalene 14.36 529 548187Nitrobenzene-05 (SURR) 12.29 428 301544Isophorone 13.42 483 806602,4-0imethylphenol 13.74 499 5034Benzoic acid 14.34 528 17918Naphtha lane 13.48 486 9135Naphtha lane 13.68 496 2987Naphthalene 14.40 531 1169264-Chloroani1ine 14.40 531 15751

*dlO-Acenaphthane 19.79 795 960142-Fluorobiphenyl (SURR) 17.87 701 3075322-Chloronaphthalene 18.80 747 8530Dimethyl phthe late 19.19 766 2287Fluorene 22.25 916 46872,4,6-Tribromophenol (SURR) 22.23 915 66860

*dlO-Phenanthrene 24.21 1012 162424*d!2-Chrysene 32.21 1404 23270Terphenyl-D14 (SURR) 29.23 1258 109939

*d!2-Perylene 36.23 1601 2610

* Compound is ISTD

40.00 UG/MLUS 'IIL

40.9020.882.62

•id.26

UG/MLUG/MLUG/ML-•UC.'MU

4.65 UG/ML-•4J&41L

T*?

59.1040.0038.950.34-

UG/ML"UG/ML

-5rr US/ML10.28

-Uf-319 UC.'MU8.55 UG/ML-

40.00 UG/ML73.13 UG/ML

.JM7 US .'ML• 1.66 US/'ML

201.22 UG/ML40.00 UG/ML40.00 UG/ML179.52 UG/ML40.00 UG/ML

901009491100387791649994937492902474897384994466939598989388

524

IBSEMI VOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Ma t P i x: (soil/wa t e p) WATER


Level: Cloui/med) LOW


Extract ion: (SepF/Cont/Sonc> CONT

6PC Cleanup: (Y/N) N pH:

Cont pact:

SAS No.: SDG No.:


Lab File ID: >G9067

Date Received: felU




CAS NO. COMPOUNDCONCENTRATION UNITS:Cug/L OP ug/Kg) UG/L

108-95-2——————Pheno 1__________________111-44-4——————bisC2-ChloPoethyl )ethep___95-57-8 ——————— 2-Chlopophenol___________541-73-1 —————— 1,3-DichlopQbenzene_______106-46-7——— ——— 1,4-DichloPobenzene_______100-51-6--————Benzyl alcohol___________95-50-1 ——— - ——— 1,2-Dichlorobenzene_______95-48-7———————2-Methylphenol___________108-60-1——-——-bis(2-ChIOPOisoppopy1)ethep,106-44-5 —————— 4-Methylphenol___________621-64-7——— ——— N-Ni t poso-d i-n-ppopy lamine_67-72-l---------HexachIOPOethane_________98-95-3 ————— —— Nit pobenzene_____________78-59-1 ——— ———— Isophopone_______________98-75-5 ——————— 2-NitPophenol____________105-67-9 —————— 2,4-Di methyl phenol________65-85-0 ——— - —— -Benzoic ecid_____________111-91-1 ——— ——— bis(2-Chlopoethoxy)methane_120-83-2—————2,4-DichlopophenoI________120-82-1- —— — --1,2,4-TpichloPobenzene____91-20-3 ——————— Naphthalene______________106-47-8- ——— — -4-Chlopoeni 1 ine______;____87-68-3 ——————— Hexachlopobutadiene_______59-50-7———————4-ChloPO-3-methyl phenol___91-57-6 ——————— 2-Methyl naphthalene_______77-47-4————— —— Hexach lopocyc 1 open tad iene_88-06-2———————2,4,6-Tpichlopophenol_____95-95-4- ————— --2,4,5-Tp ich loropheno 1______91-58-7- ——— ——— 2-Ch loronaph thai one_______88-74-4—- — - — -2-Ni tpoani 1 ine____________131-11-3 —————— Dimethytphthe late________208-96-8--————Acenaphthylene___________606-20-2---——-r2,6-Dinitpotoluene________

I.111.111111111.111111.111.111111111111111.111.111111.111.157111.111111111.111111111.111.111111.157.111157111.111111

I1UIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

FORM I SU -1525

1/87 Rev.

' 1CSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO

Lab Name: ETCNJ

Lab Code: Case No.:

M a t r i x : (soil/water) WATER


Level: (low/med) LOUI




CAS NO. COMPOUND

IContract: I

SAS No.: SDG No.:



Date Received: /0




CONCENTRATION UNITS:(ug/L or ug/Kg) UG/L Q

99-09-2 ———— -83-32-9 ———— -51-29-5 ———— -10'0-02-7 ——— -132-64-9 ——— -121-14-2 ——— -84-66-2 ———— •7005-72-3 —— -86-73-7 ———— -100-01-6 ——— •K^/i C 1 17 jA-52-1----86-30-6 -----101-55-3 ———118-74-1 —— -87-86-5 — ——85-01-8 — ——120-12-7 - ——84-74-2 — ——206-44-0 - ——129-00-0 - ——85-68-7 ————91-94-1 ————56-55-3 — ——218-01-9 ———117 Q 1 "911 /-B 1-7 —— — —117-84-0 —— -205-99-2 ———207-08-9 ——— •50-32-8 ————193-39-5 —— -53-70-3 ————1 Q 1 1 Jt 1IT 1-24-*----

—— -3-Ni t roani 1 ine ... _- —— Acenaphthene— — 2 r4-Din 1 1 rapheno 1. —— 4-Ni t raphenal. —— Oibenzafuran----2,4-Dinitroto luene—— -Diethylphthalate----4-Ch loropheny 1-pheny let her _----Fluorene ,,„_ — -4-Ni t roani line- —— 4,6-Dini t ro-2-methy Ipheno 1 _----N-Nitrosodiphenylamine Cl ) _. —— 4-Bromopheny 1-pheny 1 ether __----Hexaeh 1 Q robe nz ana— --Psntachlnrophenol----Phenanthrena_ — -Anthracana ,..._, _ __. —— Di-n-hutylphthalate----Fluo ran thane__-_pyrene_ —— Buty Ihenzy Iphtha late._ ,„, . ,,_.— — 3 j.3 '-Dichlorobanzidine_ —— Banzofalanthracene----Chryaene——— bis(2-Ethylhexyl )phthalate _— —— Di-n-octylphthalata———— Ran7a(h )f 1 no ran thane _gii— — Ranrnfklf 1 uo pan thane__ —— Ben?a(a)pyrana _. — -Indenod ,2,3-cdJpyrene..—— -rHh.nTf^hl anthracene_ ——— B*«»nf ;h ; i )p«rylana

5711575711111111115757111111571111111111112311111111111111111111

1IUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUtuIU1


FORM I SU -2 1/87

IFSEtl IUOLATILE ORGAN ICS ANALYSIS DATA SHEET


ERA SAMPLE NO.

Lab Name:ETCNJ

Lab Code: Case No.:

Ma t r i x: (soil/wa tar)UATER

Sample wt/vol: 870.0 Cg/mDML

Level: <low/med) LOU

3* Moisture: not dec._____ dec.___


GPC Cleanup: (Y/N) N pH;

Number TICs found: ^

Contract '•

SAS No.: SDG No.:


Lab File ID: >G9067

Date Received: t»t/tff




CONCENTRATION UNITS:tug/L or ug/Kg)UG/L

CAS NUMBER

01. 141-78-602.03.

COMPOUND NAME

Acetic acid, ethyl esterACETONE DIMERUNKNOUIN

RT

5.076.428.90

EST. CONC

3606646

Q

BJBJ 'BJ

-VW

FORM I SU-TIC 1/87 Rev

TOTAL ION CHRONflTOCRBMFil* >G9067

1688800-

1400000-

1200000-

1000000-

800000-

600*0*

48888*

200008-

r

36.0-500.8 *DU. CR215ZC ,0078892, LiPTIC

1ii•t

, . . 4*

i frS 1

1 Iri i s! «?'<

i

1 A

rf'i

1 , 888 1380 , 1608 , 2088

¥

r ^ fi 1 i3 !I :

t ^ !

a1 £1* 'S ' • *

- 1 'I ! s *'! j- i I 1*i IS fJ l h- 2 M

I « I «? T' 8 12 ' 16 28 ' 24 ' 26 ' 32 ' 36 ' 40 ' 44


Id F i l e : IG0130J:PFTitle: IFB/BNA, PP/BNALast Calibration: 891116 12:11



BTL*33

S28

QUANT REPORT

Operator ID:Output File:Da t a File:Name:Miac: CA2152C

PT1575-G9067::AQ>G9067::U3

Quant Raw: 7 Quant TimeInjected at

Dilut ion Factor

,QC70092,L:M6,870,2

Page J

891116 12:36891115 20:44

1.00000

BTL*33



1)3)5)12)/17)18)32)36)50)52)54)A9 1O A '65)67)DO i

73)

»d4- 1,4-D ichlorobenzana2-Fluorophenol (SURR)Phenol-05 CSURR)N-Ni t rosodi -n-p ropy lamina


•dlO-Acenaphthene2-Fluorobiphenyl CSURR)Fluorane2,4,'6-Tr ibromophenol (SURR)

•dlO-PhenanthreneOi-n-butyl ph thai ate*d!2-ChryseneTerphonyl-014 (SURR)Butyl benzyl phthalate•d!2-Perylene

10.7.10.12.14.12.19.17.22.22.24.

32.29.31.36.

6445093542358996333332633234

33

3471903204315334318027079229221020113414141267

1611

24574935745844569543629530356281474187309298793

42786150911241465366104175291747111

40.79.76.

40.38.40.38.• '1

58.40.

40.57.

40.

009808

00510034**-0700

0004

00

UG/MLUG/MLUG/ML

UG/MLUG/MLUG/MLUG/MLU6>'r1LUG/MLUG/MLUfr'ML •UG/MLUG/ML

UG/ML

889091

94959898

9697979993

- 7289

* Compound is ISTD 1-JO-

b29

FiU >G9067Bpk flb 9999

eeee-•

4080-

0~n-25

CR2152CCUB MRM

43/

4f39 ••

\ i/'5/8^ "'30 35 40 45 50 5*5 60

FiU NBS49KBpk Ob 9«99

3000-.

4000-

0-i ,»** ( '25

29

f lc* t ic ac id , *thi.

43

2?/ 42

/ i x1

M | l i n | M i i |\i

(

,QC70092,Li(16.870 Scan 73

70>1 69 /

65 70

I **t»r

i **6* .•. 1. i . . . . . , , , , , , ... , , ,

30 35 40 45 56 55 60i

. i . | . i . . j . r

65 70

FiU NBS49K Propanoic acid. 2-m»ths>l-Bpk Rb 9999

.9000-

43/

. 27 414000-

•1

A

' « 33/ %

• i' . .M ,30 35 40

1

55 647 \ yi / \ /1 1 . . 1 i45 56 55 60

071f"

65 7S

5.07 min.

7 6\ f•60•-40

-fl75 80 85 90

Scan 7570.00 min.

73 88/ /

-60

-40

-A• , I 1 ! 1 1 1 1 , '

75 83 35 ?@

Scan 7560.Q0 min.

73y

/. i

^50•-to-a. , . , . . , . . . . , . - . . , -

75 30 85 90

Data File: :G9067::U7Name :Misc Data: CA2152C .QC70Q92 ,'_: M6 ,87Q ,2RT f mm ) : ? . 073can : 77Krea: 7668292 Rank: 1Sem i -quart t i t a t i ve Cone !-uncor r ec t ed ) : 1?6.09 UG--''MLSemi-quant i tat i ve Cone ( corrected ): 753.30 ug/'lC a l c u l a t e d using Istd: d4-l,4-Dich lor obenzene ji[ 10.64 minute

1. Acetic a c i d , ethyl ester2. Prcpanoic acid, 2-me thy 1-

38 C4HSQ298 CaH8C2

San,pie f i l e : 'G9Q67 Spectrum tt:Search speed: 2 T i l t i n g option: S No. of ion ranges searched

CAS tt CON 4t ROOT K DK #FLG TILT S CON

141^36 2197 NBS49K 23 ?0 1 0 ^2 I1?7° 7 12 -4 3 MBS49K 2S 61 2 0 67 13

530

Fil« >G9067 C021S2C ,G!C70092,LiM6 ,3?0 Sc»n 139Bpk Rb 9999 , SUB NRM 6.42 mm.

43.

8009-

4000-

0 - , , , , , , . , , , . . . . , , . , , . , . , . , . . , , , , . , , , , , , . , , , , . , . , , . , , - .

38y

r 1 ll . I

' \59 L8e

55 83 ?8 101 H6 -40v 67 79 ,- s. / % -X. / ,• .• •• --

1 • - i ' . 1 , . 1 ' . . . r • . . , h . . 1 , 1 '. . ——A

20 40 60 30 100

Fil» NBS49K 2-P*nt*non», 4-hydroxy-*-** thvl- Sc*n 2351Bpk Ab 9999- 0.00 min.

8000-4000-

6-

43

3127 /'if i i.

-6059

56 ' ^ 73 8^3 98 101 102-40

III / •"'* f V' 1 "" "

20 40 60 30 100Fil* NBS49K HMdrop*roxid*, 1 . 1 -dimtthvl *th\»I ;,:ir. §47Bpk Ob 9999 0.00 mm.

8000-,

4000-

6-

43 ' U31

VS ZJ / 1.^ .. . .1 . . i . l i

LES 73 39 h*°.. \.n. / \ L

• 20 40 60 30 100

Data Fi le: >G9067: :U3Name :Misc Data: CA21S2C .CC^0092 ,L: M6 ,370 ,,2FT f. rn in '} : 6 . 42Scan: 1?9Area: 670018 Pank: 6Sent i - quant i tat ive Cone 'uncorrected'1 :Sern i -quan t 11 at i • *e Cone ( corrected ) :

23.? I UC-/ML65.5? uq.'l

Calculated using Istd: d4- 1 , 4-0 i ch 1 o robenzene |il 10.64 minute

1 . 2-Pentanone . 4-hydroxy-4-methyl-2. Hyd roperoxide, 1,1-dimethylethyl

116 C6H12G290 C4H1002

Sarr.p le f i l e : '• G9Q67" Spectrum^:Search speed: 2 T i l t i n g o p t i o n : S

139Mo. of ion ranges sear-hed:

1.

Prob.

7020

CAS # CON # ROOT DK #FLG TILT

123422 1790 NBS49K 43 40 2 075912 1^33 HSS49K 34 31 i 0

oTP

CON c_i P_;

S31

\

FiU > 69067Bpk fib 9999

8000-

4000-

0-20

FiU NBS49KBpk ab 9999

8000-

4000-18

i - i ' •28

FiU HBS49KBpk Pb 9999

3000-

4800-

0-

15

•28

CP2152C ,QC78892.L:H6,870 Scan 261SUB NRM 8.90 min.

7

36

43

55 631. ..1, I.I. III,. ..1.,.!,.

.»-•

40 ' 60

i

.1,,88

83

^ 103 117

188 ' 120 ' 148

-80

-48

-8

l-Prop»n», 1-chloro- Sc»n 3430 .0Q min .

41

27

(. ..-I'll

7

49 61X X'

'. j 1 1 1 t'i - . ; 1 1 1 1 i 1 1 P . i j ,• i40 68

P»ntan* ,

43 r

if

55 70

,. .. .1 .....'>; ,40 t'0

6

se

79

iee ' 128 140

-30

-48

-e

3-bromo- Scmrt 81140.08 mm.

1 i•

83 95 107 158

..X ./ / '?' \.80 100 ' 128 ' 148

-60

-40

-3

Data File: >G9067:: U7Name :Misc Data: CA2152C .QC70092,L:M6,370,2RT (min): 8.90Scan: 261Area: 4*8969 Rank: 7Semi-quantitative Cone Ojncor r ec ted 1 :Semi-quantitative Cone ( corrected ):

19.95 UG.-''ML45.37 ug/'l

BTUfc??

Calculated using ! =. t d : d4-1.4-Dichlorobenzene |S 10.64 minutes

i. 1-Propene, 1-chloro-'2 . Pentane, 7-b r omo-

76 C3H5C1C5HllBr

Sample f i l e : ^-G'51367 Spectrum #:Search speed: 2 T i l t i n g option: 3


Prob. CAS #

5^02161309105

COM «

50Q1

ROOT

NBS49K

K

4635

DK

4741

#FLG

21

TILT

ofl

s507'

CON

7150

c i R

17

S32

ETC

STANDARDS DATA

6BSEMIUQLATILE ORGAN I CS INITIAL CALIBRATION DATA

Lab NameJETCNJ . Contract:

Lab Code: Case No.: SAS No.: 50G No.:

Instrument ID:GC/MS G Calibration DateCs) 11/08/89 11/08/89

Min RRF for SPCCC#) - 0.050 Max SRSD for CCCC«) - 30. OS

I LAB FILE ID:IRRF80 ->G8976I

RRF20 *>G8977RRF12Q->G8975

RRF50 ->G8948RRF160->G8974

11 COMPOUND

1 Phono 1Ibis(2-Chloroethyl iether ___12-Chloropheno 11 1 ,3-Dichlorobenzene

\. y!l,4-Dichlorobenzene(Benzyl a Icohol1 1 ,2-Dichlorobenzene12-MethylphenolIbis(2-Chloroisopropyl )ether14-Methylpheno 1IN-Nitroso-di-n-propyiamine_1 He xachlo roe thane1 Ni t robenzene1 Isophorone12-Ni t ropheno 112 r4-Dimeth<ulphenol1 Benzo ic ac id

11

*1t1*11111*111*11

t b is (2-Ch loroe thoxy )methane__l12.4-Dichlorophenol »1 1,2 ,4-Tr ichlorobenzene1 Naphtha lene14- Ch loroan i I me1 Hexach lorobutadiene

\~S 1 4-Ch loro-3-me thy Ipheno 112-MethylnaphthaleneIHexachlorocyclopentad iene _12 ,4,6-Trichlorophenol12 ,4,5-Trichlorophenoll2-Chloronaphthalene_1 2-Ni t roan i 1 ine1 Dime thy Iphtha late1 Acenaphthylene12 ,6-Dinitrotoluene1 3-N i t roan i 1 i ne1 Acenapht hene1 2 t4-Din i t ropheno 11 4-Ni t ropheno 11

111**1**11I1111**i1

RRF20

1.1341.000.954

1.1371.047.577

1.101.692.206.944.769.420.427.805.222.378

0.000.502.316.425

1.085.415.288.261.571.589.411.486

1.517.389

1.6522.162.298.271

1.425.057.055

1RRF50 1

.9031

.7891

.7401

.9291

.846 1

.4921

.8821

.5671

.1861

.7001

.5771

.3651

.4141

.7541

.2261

.3381

.0711

.476 1

.3081

.3951

.9801

.3821

.2651

.2521

.5081

.6011

.3941

.52011 . 476 1.4231

1 . 48 8 12.0571.3211.3151

1.3251.1421.0981

1

1RRF80 1

.8751

.6891

.6491

.8321

.7541

.4671

.7841

.5261

.1751

.6591

.5081

.3221

.4101

.7071

.2141

.3321

.0921

.4441

.2901,3731.9131.3501.2511.2381.4721.6401.381 1.5161

1.3551.4081

1.37611.9191.3021.2821

1.2221. 125 1.0821

1

1RRF 12 01

.6441

.5421

.5041

.6761

.6601

.4321

.6981

.4281

. 1291

.4831

.4331

.2701

.3751

.6811

.206 1

.3231

. 106 1,4061.276 1.3531.8261.3281.2271.2261.4451.6041.3741.4821

1.3011.3881

1.30211.7501.3031.2841

1.1621. 1471.0941

1

1RRF160I

.5991

.5561

.4711

.6761

.6641

.4981

.7091

.4541

.1401

.5791

.5221

.2651

.3861

.6131

.2131

.3161

.1351,4191.2681.3271.8151,3371.2051.2471.4411.5351.3781.4571

1. 1831.3901

1.28511.6731.2871.2661

1.Q86I.1611.1051

t

__ 1RRF 1

.8311

.7151

.6641

.8501

.7941

.4931

.8351

.5331

.1671

.673!

.5621

.3281

.4021

.7121

.2161

.3371

.1011

.449 1

.2921

.3751

.9241

.3621

.2471

.2451

.4871

.5941

.3871

.49211.3671.4001

1.421 I1.9121.3021.2841

1.2441.1261.0871

1

RSD

26.26.29.22.20.10.19.19.19.25.22.20.5.10.3.7.

26.8.7.10.12.9.13.5.11.6.3.5.9.3.10.10.4.6.10.32.22.

B

1*457

996375403L.

21719 1fl-i t291*5*a449*31719 1717101717*44^•«

1FORM YI S"J -1 1/87 Rev.

34

6CSErilUOLATILE QRGANICS INITIAL CALIBRATION DATA

Lab Name:ETCNJ Contract:

Lab Code: Case No.: SAS No.: SOG No.:

Instrument ID:GC/MS G

Min RRF for SPCCC*) - 0.050

Calibration DateCs) 11/08/89 11/08/89

Max KRSD for CCCC») - 30.

ILAB FILE ID: RRF20 ->G8977 RRF50 ->G8948IRRF80 ->G8976 RRF120->G8975 RRF160->G8974111 COMPOUND

IDibenzofuran12,4-DinitrotolueneIDiethulphthalate1 4-Ch loropheny 1-pheny let her_IFluorana n_

\Lj>l4-Nitroani 1 ina!4,6-Dinitro-2-methylphenol_IN-Nitrosodiphenylamine C 1 )_«I 4-Bromopheny 1-pheny lether _1 He xachloro benzeneIPentachlerophenol *IPhenanthrene1 AnthraceneIDi-n-butylphthalate1 Fluoranthene ., *IP'jrenaIButvlbenz-jlphthalate ,l3,3'-DichlorobenzidineIBanzoCa)anthracaneI ChrysanetbisC2-Ethylhexyl )phthalate_IDi-n-octulphthalate *1 Benzo(b) fluoranthene,_IBenzoCk)fluoranthene

\-S\ BenzoCa )pyrene *1 IndenoC 1 ,2 ,3-cd )pyrene ____IDibenz (a ,h) anthracenelBenzoCq,h;i)perylene.INitrobenzene-d512-Flunrnbiphenyl1 Terpheny l-dl4IPhenol-d51 2-Fluoropheno 112 ,4,6-Tribromophanal1

RRF20......1.798.356

1.414.689

1.401.193.097.727.368.433

* 0.0001.4921.4471.391

» .996.973.804.265

1.4161.436.866

1.2161.7001.426

» 1.2401.997.648.717

.519X.6851.0651.057.838.180

RRF50

1.712.364

1.165.598

1.315.261.166.778.373.404.133

1.4191.4101.4121.0391.005.904.399

1.4261.4201.1471.9391.5911.2701.1902.588.909.930

.5311.5761.057.908.697.174

RRF80

1.615.338

1.043.569

1.208.231.158.704.368.398.134

1.3521.3681.322.945.902.885.362

1.3551.3051.1202.1111.4831.4051.2162.310.819.791

.5041.4941.064.822.617.186

RRF120

1.494.337

1.030.534

1 . 168.245.175.674.343.378.163

1.2891.2991.395.988.969.872.389

1.3431.3201 . 1 752.0801.3921.2881.1792.743.988.966

.4911.3451.011.714.581.168

1 __RRF160I RRF

1.4911 1.622.3671 .352.9771 1.126.4791 .574

1.1061 1.239.2711 .240.1871 .157.5711 .691.3211 .355.3551 .393.1791 .152

1.2621 1.3631.2291 1.3511.4141 1.3871.0041 .994.9861 .967.3601 .865.3861 .360

1.3731 1.3331.2901 1.3541.1901 1. 1001.7951 1.8281.3201 1.4971.0741 1.2931.090 1 1. 1832.8041 2.4881.0151 .3761.0021 .861

.4681 .5021.2151 1.463.9871 1.037.6941 .839.5681 .660.2021 .182

1

SRSD

8.34.015.513.69.512.722.311. 1«6.37.415 . u«6.96.52.73.4-4. 04. 3

15.22.75. 112. 119. 9«10.210.84. e«13.416.913.8

4.912 . ;*3.4

17.816.97.2

CD Cannot be separated from DiphenylamineFORM 01 SU -2 1/87 Rev

535

TOTQL ION CHBOMOTQCRflMFil* >C897? 3S.8-S0e.0

400TIC

1200

BHH STD 20PPH

1600 2800

12 16 28 24 28 32 36 40 44

Data File: >G8977::U6Name :Misc: SNA STD 20PPM

Id File: IG0127::USTitle: IFB/8NA, PP/BNALast Calibration: 891104 17:41



8TL#99

1)36

QUANT REPORT Page

Operator ID:Output File*.Da t a File:Name:Misc: BNA STD

CA3875G8977::AQ>G8977:: U6

20 PPM


Di lut ion Factor

891108 20:15891108 19:27

1.00000

BTL#99



1)3)4)5)6)7)8)

/ B)8)9)9)9)10)10)10)11)12)12)13)14)14)15)15)16)16)

'">18)19)19)19)20)21)22)23)24)25)26)27)27)28)28)29)

*d4-l, 4-Dich lorobenzene2-Fluoropheno 1 CSURR)bis(2-Chloroethyl ) etherPhenol-05 CSURR)Phenol2-Chloropheno 11, 3 -Dich lorobenzene1 ,3-Dichlorobenzene1 ,3-Dich lorobenzene1,4-Dichlorobenzene1 , 4-Dich lorobenzene1, 4-Dich lorobenzene1,2-Dich lorobenzene1,2-Dich lorobenzene1,2-Dich lorobenzeneBenzyl alcoho IN-Nitrosod i-n-p ropy lam ineN-Nitrosodi-n-propylamineHexachloroethane.2-Methy Ipheno 12-Methylphenol4-Methy Ipheno 14-Methy Ipheno 1bis(2-Chloroisopropyl)etherb is (2- Ch loro isopropy 1 )etherbisC2-Chloroisopropyl )ether

»d8-NaphthaleneNitrobenzene-05 CSURR)Ni t robenzeneNi t robenzeneNi t robenzeneIsophorone2-Ni t rophenol2 ,4-Di methyl phenolb isC2-Chloroethoxy )me thane1,2, 4- Trich lorobenzene2, 4-Dich lorophenolBenzoic acidNaphthaleneNaphtha lene4-Ch loroan i 1 ine4-Ch loroan i I ineH e xachlorobutadiene

11.7.10.10.10,10.10.11.11.10.11.11.10.11.11.11.12.12.12,12.12.12.12.12.12.12.14.12.12.12.13.13.13.14.14.14.14.14.14.14.14.15.15.

09795848526096136396136396136368597955166116611822558979188361618118443158645893932562

343181318313315319337345370337345370337345370372417427415396418396418397399415530427397429467467477495508526515518515532532548566

1577346611178854833808941375253896498261286840896498261286840896498261286840455286062514022331415456674465545667446516276821810668

3535539172632362754804443

142262391616682488826751555580933702438

191736253127343950961

40.23.25.27.29.27.24.22.23.26.24.25.27.25.26.28.34.7.23.30.41.22.31.17.8.

11.40.19.8.19.1.

22.19.23.22.20.21.4.

0042136131092737511913375943732142961006037606267131005653901751218317485628

.27121.7.

22.19.

29837353

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

8988939188918785859695959796958467389675686*9Q

100100ICO9..916?-1 -

**'9"**99085959?939290676198

537

Operator ID:Output F i l a :Data File:Name:Mi so: SNA STD

CA3875~G8977::AQ>G8977::U6

20 PPM

QUANT REPORT


Di lut ion Factor

Page 2

891108 20:15891108 19:27

1.00000

BTL#99

ID File: IG0127::UST i t l e : IFB/BNA, PP/BNALast C a l i b r a t i o n : 891104 17:41

Compound R.T. Scan# Area Cone Units

30)31)32)33)34)34)35)'35)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)51)51),52 )53 )54)55)56)56)57)58)59)60)60)61)61)62)63)63)64)64)

2-Methylnaphthalenep-Chloro-m-cresol

*dlO-AcenaphtheneHexach lorocyc 1 open tad iene2,4,6-Trichlorophenol2,4,6-Trichlorophenol2,4,5-Trichlorophenol2,4,5-Trich loropheno 12-Fluorobi phenyl CSURR)2-Chloronaphthalene2-Ni troani 1 ineD i me't hyl phthalateAcenaphthy Iene2,6-Dinitroto luene3-Ni troani 1 ineAcenaph thene2,4-DinitrophenolDibenzof uran2,4-Dinitrotoluene4-Ni t ropheno 14-Ni t roan i 1 ineDiethyl phthalateFluorene4-Chlorophenyl phenyl ether4-Ch loropheny 1 phenyl ether2,4,6-Tr ibromophenol CSURR)1 ,2-Dipheny Ihydraz ine

*dlO-Phenan throne4,6-Dinitro-o-cresolN-NitrosodiphenylamineN-Nitrosodiphenylamine4-Bromopheny I phenyl etherHexach lorobenzenePen tach loropheno 1PhenanthrenePhenanthreneAnthraceneAnthraceneDi-n-butyl phthalateFluorantheneFluorant henePyrenePyrene

17.16.20.17.18.18.18.18.18.18.19.19.19.19.20.20.20.20.21.21.22.22.21.21.22.22.22.24.22.22.22.23.23.24.24.24.24.24.27.28.29.28.29.

08943688122212223857068785993444669515072110988412785979391251579150859985990847094709

6386317996776896946896947027117357757747817988038148288388348908858798728869189091017899886905957974

1003102010271020102711301198122911981229

1008814612314359642290295083485929508348591209641089112796411858115521321422194341023124080

12908425572396513830101487100568

2197494431293996167153245746750095572928173331402993M

11435211087011435211087010657776304745467630474546

232040211922161922201622221715217201510102119.

2015164091

2022214201920191514141313

.23

.20

.00

.86

.16

.64

.62

.63

.12

.93

.60

.39

.53

.90

.37

.11

.03

.47

.99

.77

.50

.37

.62932.97.71.73. 00.95.80.07.85.71.34.45.83.50.88.58.77.43.99.66


8297999895979697999586979971100971009882709792978885947597787697889596999898979898989797

b38

Operator ID: CA3875Output File: ^G8977::AQData File: >G8977::U6Name:Miaci SNA STD 20PPM

ID File: IG0127::USTitle: IFB/BNA, PP/BNALaat Calibration: 891104 17:41

Compound

QUANT REPORT


Di lut ion Factor

Page 3

891108 20:15891108 19:27

1.00000

BTL#99


69)66)67)68)69)69)70)70)71)72)73)74)75)75)75)76)76)76)77)77)77)78)78)79)80)

»d!2-ChryaeneBenzidineTerphenyl-D14 (SURR)Butyl benzyl phthalateBenzo(a)anthraceneBenzo(a)anthraceneChryseneChrysene3,3'-Dichlorobenzidinebis(2-Ethylhexyl )phthalate«d!2-PeryleneDi-ri-octyl phthalateBenzo(b)f luorantheneBenzo (b)f luorantheneBenzo(b)f luorantheneBenzo (k ) f luorantheneBenzo (k ) f luorantheneBenzo (k)f luorantheneBenzo (a )pyreneBenzo (a )pyreneBenzo(a)pyreneIndenod ,2 ,3-c ,d)pyreneIndenoC Il2,3-c,d)pyreneD ib en zo (a |h) anthraceneBenzoCghi )perylene

32282931323232323233363535353635353635353639403940

.83

.99

.81

.55

.77

.89

.77

.89

.87

.50

.84

.27

.86

.92

.70

.86

.92

.70

.86

.92

.70

.83

.62

.93

.62

1413122412641350141014161410141614151446161015331562156516031562156516031562156516031757179617621796

56083627129855225593970640271397064027174332428928870175562454420578179022454420578179022454420578179022883010351936010351

40.58.23.17.19.19.19.20.11.13.40.12.22.18.16.28.23.20.27.23.20.13.5.12.13.

00428091517998270891000518601849897888373395016954

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

98100949310010010010086958397918789959092938991100100100100

* Compound is ISTD

c~oa r -IT- 3 zp3 C—. ft 0• 3 TO *» ft

a - -»3

ft ft ~

OD <D O« vfl 1>»-• M WI— »•* CDO O NJCD CD Nil

»O O

•« a. *--*r* W 3— -n n •

OD

-> \ ci «»» mo -4" Zf O»-• » MO v \J ~3 .. *-•• T) ••

TICa> \ t/)

*.»-•M

m<o*.OD

C(K

DCft3

O**•ac

w * ai w

n

(sum)

OD>O*-00

DO £3-Ir

QUANT REPORT Pag*

Operator ID:Output Fi!•>Data Fila:Namatrii»c: SNA STD

CA3875*G8948i:AQ>G8948HU6

II

Quant Rev: 7 Quant TimeInjaetad at

Di lut ion Factor

8911Q8 16:30891108 19:42

1.00000.

BTL* 2

ID Fila: IG0127::USTit la: IFB/BNA, PP/SNA-Last Calibration: 891104 17:41


1)2)2)3)4)5)6)7)8)8)8)9)9)9)10)10)10)11)12)12)13)14)14)15)15)16)16)16)17)18)19)19)19)20)20)21)22)23)24)25)26)27)27)

*d4-l , 4-Dich lorobanzanaN-Ni trosodim* thy laminaN-Ni t rosodi ma thy lamina2-Fluorophenol CSURR)b i»C2-Ch loroethy 1 ) etherPhenol -05 CSURR)Phenol2-Ch loropheno 11 ,3-Dichlorobenzen*1 ,3-Dich lorobenzane1 ,3-Oichlorobanzan*1 , 4-Dich lorobenzane1 ,4-Oichlorobanzane1,4-Dichlorobanzane1 ,2-Dich lorobenzane1,2-0 ichlorobenzene1,2-0 ichlorobanzaneBenzyl a IcoholN-Nitrosodi-n-propy laminaN-Ni t rosod i-n-p ropy laminaHexachloroethane2-Methy Ipheno 12-Methy Ipheno 14-Methy Ipheno 14-Methylphenolbis<2-Chloroisopropy \ ) etherbis(2-Chloro isopropyl )etherb is C2-Ch lor o isopropyl )ether"d8-NaphthaleneNitrobenzene-05 (SURR)Ni t robenzeneNi trobenzan*Ni t robenzeneIsophoroneIsophorone2-Ni t rophenol2, 4-Di me thy Ipheno 1bis(2-Chloroethoxy) me thane1,2,4-Trichlorobenzane2 f 4*0 ich loropheno 1Benzo ic acidNaphtha leneNaphtha lene

11.084.194.767.80

10.5910.4910.5310.5910.9511.1211.6310.9511.1211.6310.9511.1211.6311.6912.6012.8112.5212.1712.6212.1712.6212.1512.2212.5214.8612.8112.1712.8513.6213.6214.5813.8014.1914.4514.7814.5814.8214.5814.92

343432182319314316319337345370337345370337345370373418428414397419397419396399414529428397430468468515477496509525515527515532

241341219081M2203

2101542379662738122724622232212801562551932660252801562551932660252801562551932660251484011740444489311011817098121112117098121112156209211633510545192729984413187023360912770

4261704237

127398190669268763223181174149399807643

553354

40.00 UG/ML64.10 UG/ML.645 UG/ML

48.65 UG/ML49.56 UG/ML59.25 UG/ML58.36 UG/ML52.52 UG/ML49.58 UG'ML45.16 UG/ML47.08 UG/ML53.49 UG/ML48.72 UG/ML50.79 UG/ML56.36 UG/ML51.33 UG/ML53.51 UG/ML60.10 UG/ML64.59 UG/ML16.66 UG/ML50.17 UG/ML61.57 UG/ML76.02 UG/ML46.62 UG/ML57.56 UG/ML38.96 UG/ML14,67 UG/ML24,33 UG/ML40.00 UG/I1L50.01 UG/ML27.20 UG/ML48.18 UG/ML2.63 UG/ML52.75 UG/ML.524 UG/ML

48.90 UG/ML53.18 UG/ML52.47 UG/ML47.58 UG/ML52.63 UG/ML39.68 UG/ML.664 UG/ML

48.07 UG/ML

9010010082819285908886889795979896988476389274876598100100100939159785997847992909696969089

b41

QUANT REPORT Paga

Oparator IDs CA3879Output Fila:Data Fila:Nama:Miact SNA STO

Quant Rav: 7

>G8948i:U6

II

Quant Tima:Injactad at:

Dilution Factor:

8911068911Q8

1

8TL* 2

16:3015:4200000

ID Fila: IGQ127MUSTitlai IFB/8NA, PP/BNALast Calibration: 891104 17:41

Compound R.T. Scan* Araa Cone Units

28)28)28)29)30)30)31)32)3)34)34)39)39)36)37)37)37)38)39)40)41)42)42)43)44)49)46)47)48)49)50)50)51)51)52)53)54)55)56)56)57)58)59)

4-Chloroani 1 ina4-Chloroani 1 ina4-Chloroani 1 inaHaxachlorobutadiana2-Mathylnaph thai ana2-Mathylnaph thai anap-Chloro-m-crasol

*dlO-AcanaphthanaHaxachlorocyclopantadiana2, 4, 6-Tr ichlorophanol2 ,4,6-Tr ichlorophanol2, 4, 9-Tr ichlorophanol2, 4, 9-Tr ichlorophanol2-Fluorobi phanyl CSURR)2-Chloronaph thai ana2-Chloronaph thai ana2-Chloronaph thai ana2-Nitroani 1 inaDi ma thy I phthalataAcanaphthy lana2,6-Oinitroto luana3-Nit roani 1 ina3-Nitroani 1 inaAcanaphthana2,4-Oini trophanolDibanzofuran2,4-Oinitrotoluana4-Nitrophanol4-Nitroani 1 inaDiathyl phthalataFluoranaFluorana4-Ch lorophanyl phanyl athar4-Ch lorophanyl phanyl athar2 ,4,6-Tr ibromophanol CSURR)1,2-Diphanylhydrazina

•dlO-Phananthrana4,6-Oinitro-o-cra»olN-Ni trosodi phanyl am inaN-Ni trosodi phanyl am ina4-Bromophanyl phanyl atharHaxachlorobanzanaPentachlorophanol

14.9814.9215.2919.5917.0817,3816.9420.3317.8518.1218.2218.1218.2218.3818.1218.2218.5619.0919.8619.8220.0120.3920.9220.4320.6620.9221.1921.0722.2922.1021.9822.7721.8222.1022.7522.9724.7722.3922.1022.9123.9923.8924.46

5155325485656386536317986766896946896947026896947117357797737827998278038148278388348928898799188718899179081016899889909996973

1001

2539730882199601499012872965974

142574173023

- 129881891081124428910811244234086989114301

3191499159632191944478269330681365620

28650830686370222788212124956417 .25195928444324366544

129423376953041561735453595912955168760809888754028769

.614 UG/ML17.70 UG/ML52.29 UG/ML44.94 UG/ML51.76 UG/ML1.08 UG/ML48.86 UG/ML40.00 UG/ML55.73 UG/ML45.87 UG/ML60.60 UG/ML39.77 UG/ML52.55 UG/ML51.73 UG/ML1.42 UG/ML.686 UG/ML

50,89 UG/ML49.09 UG/ML50.49 UG/ML93.99 UG/ML48.07 UG/ML44.73 UG/ML3.69 UG/ML49.07 UG/ML43.88 UG/ML48.72 UG/ML40.89 UG/ML47.91 UG/ML35.99 UG/ML44.03 UG/ML46.09 UG/ML.394 UG/ML2.30 UG/ML45.56 UG/ML37.97 UG/ML43.93 UG/ML40.00 UG/ML42.32 UG/ML4.12 UG/ML53.66 UG/ML58.01 UG/ML50.63 UG/ML36.87 UG/ML

b42

63706298827396999899979897995762968697989910010099100948762899699898684948098767596909698

Oparator IDi CA3875Output Fila: AG8940::AQData Filai >G894«MU6Nama:Miaci BNA STD II

ID Fila: IG0127MUSTit la: IFB/BNA, PP/BNA-Laat Calibration: 891104 17:41

Compound

QUANT REPORT

Quant Rav: 7 Quant Tim*iInjactad at:

Oi lut ion Faetori

Paga 3

891108 16:30891108 15:42

1.00000

BTL# 2

R.T. Scan* Araa Cone Units

60)60)61)61)62)63)63)64)64)65)66)67)68)69)69)70)70)71)72)73)74)75)75)75)76)76)76)77)77)77)78)78)79)80)

PhananthranaPhananthranaAnthraeanaAnthracanaDi-n-butyl phthalataFluoranthanaFluoranthanaPyranaPyrana•d!2-ChryaanaBanzidinaTarphany 1-014 CSURR)Butyl banzyl phthalataBanzo(a)anthracanaBanzo(a)anthraeanaChryaanaChryaana3,3 '-Diehlorobanzidinab la (2-Ethylhaxy I) phthalata*d!2-ParylanaDi-n-octyl phthalataBanzo(b)f luoranthanaBanzo(b)f luoranthanaBanzo(b)f luoranthanaBanzo(k)f luoranthanaBanzo(k)f luoranthanaBanzo(k)f luoranthanaBanzo(a)pyranaBanzo ( a )pyranaBanzoCa)pyrana1 ndano C 1 ,2 ,3-e ,d Jpyrana1 ndano ( 1 ,2 ,3-c ,d )pyranaOibanzo(a,h)anthracanaBanzoCghi )parylana

24.24.24.24.27.28.29.28.29.32.28.29.31.32.32.32.32.32.33.36.35.35.35.36.35.35.36.35.35.36.39.40.39.40.

83978397044308430880957751758875888449822384916684916684916681618961

1019102610191026112811961228119612281411122212621348140914151409141514131445160915311561156416011561156416011561156416011756179517601795

307821305841307821305841306399225446218023225446218023721297111M95331814671285431280441285431280443596710345445846111119911747278368173911747278368173911747278368173148332533165207653316

48.48.48.48.39.38.37.36.35.40.51.59.50.49.48.50.50.41.46.40.48.51.41.38.66.53.49.65.52.48.45.16.44.43.

61307442555528492900510929119230117007000389428065208322067621254490

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML .UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

98979796979898979799100939810010010010086999199908891949194929093100100100100

* Compound la ISTD

\

Ai>'>!<JiU a

TOTAL ION CHUOHOTOCIIOMrue

1400000-

1200000-

1000000-

3S.8-«90.9 TIC•NH STD

1200 . U.00 20.00

Data Fil«: >G8976::U6Nam«:Misc: BNA STD 80PPM

Id Fil«: IG0127::USTitle: IFB/BNft, PP^BNALast Calibration: 891104 17:41


Quant Output Filet "G8976::AQ

BTL*98

544

QUANT REPORT Page

Operator ID:Output File:Date File:Name:Misc: SNA STD

C A3 8 75^G8976::AQ>G8976::U6

80PPM


Di lut ion Factor

891108 19:18891108 18:30

1.00000

BTL*98



1)2)3)4)5)6)7)8)8)8)9)9)9)10)10)10)11)12)12)13)14)14)15)15)16)16)16)17)18)19)19)19)20)20)21)22)23)24)25)25)26)27)27)

*d4-l, 4-Dich lorobenzeneN-Nitrosodi me thy lamina2-Fluorophenol CSURR)bis(2-Chloroethyl ) etherPhenol-05 CSURR)Pheno 12-Chlorophenol1,3-Dichlorobenzene1 ,3-Dich lorobenzene1,3-Dichlorobenzene1 , 4-Dich lorobenzenel,4-'Dich lorobenzene1 , 4-Dich lorobenzene1 ,2-Dich lorobenzene1 ,2-Dich lorobenzene1,2-DichlorobenzeneBenzyl alcoholN-Nitrosodi-n-propylamineN-Nitrosodi-n-propylamineHexachloroethane2-Methylphenol2-Methy Ipheno 14-Methylphenol4- Me thy Ipheno 1bisC2-Chloroisopropyl)etherbisC2-Chloroisopropyl )ether .bisC2-Chloroisopropyl)ether

*d8-NaphthaleneNitrobenzene-05 CSURR)Ni t robenzeneNi t robenzeneNit robenzeneIsophoroneIsophorone2-Ni t rophenol2 ,4-Di me thy Ipheno 1bisC2-Chloroethoxy)methane1,2, 4- Trich lorobenzene2 ,4-Dichlorophenol2,4-DichlorophenolBenzoic acidNaphtha leneNaphtha lene

11.4.7.10.10.10.10.10.11.11.10.11.11.10.11.11.11.12.12.12.12.12.12.12.12.12.12.14.12.12.12.13.13.14.13.14.14.14.14.15.14.14.14.

09148262525662991566991566991566726484552166216619255589842188656563842249816130896196

3453

184322317319322340348373340348373340348373376421431417400422400422399402417532431400433471471519480499512528518552532518535

196008236268M24185527023932219534319625450232616829551730737532616829551730737532616829551730737518325819912254946126074206257258257206257258257687282412339818361181363719161197295825155055109744877

154436240078320620269487209554219466143M9327

659524

408568698590737164667669728073769190257091114698658203340754176479.

7483787179•

821

71

.00

.12

.94

.30

.85

.52

.73

.07

.39

.98

.67

.47

.26

.79

.19

.13

.39

.99

.11

.73

.45

.51

.24

.70

.65

.59

.98

.00

.91

.60

.34

.00

.13755.17.79.33.89.24830.14.01.68


891008576938585898789989798999899857638947488669810010010094915880539780829490949694

9089

b45

QUANT REPORT Page 2

Operator ID:Output FiIs:Data File:Name:Mi so: BNA STD

CA387538976::AQ>G8976::U6

80PPH


Di lut ion Factor

891108 19:18891108 19:30

1.00000

BTL#98


Compound R.T. Scant Area Cone Units

<-/

28)28)28)29)29)30)30)

-31)32)33)34)34)35)35)36)37)37)37)38)39)40)41)42)42)43)44)45)45)46)47)48)49)50)50)51)51)52)53)54)55)56)56)57)

4-Chloroan i 1 ine4-Ch loroani 1 ine4-Chloroan i 1 ineHexachlorobu tad ieneHexachlorobu tad iene2-Methyl naphthalene2-Methylnaphthalenep-Ch loro-m-cresol*dlO-Acenaph thaneHexach lorocyc 1 open tad iene2,4,6-Tr ichlorophenol2,4,"6-Trich loropheno 12,4,5-Tr ichlorophenol2,4,5-Tr ich loropheno 12-Fluorobiphenyl (SURR)2-Ch loronaph the lane2-Chloronaphtha Iene2-Ch loronaphtha Iene2-Nit roani 1 ineDimethyl phthalateAcenaphthy Iene2,6-Dinitroto luene3-Nit roani 1 ine3-Ni t roani 1 ineAcenaphthene2,4-Dini t ropheno 1DibenzofuranDibenzof uran2,4-Dinitroto luene4-Ni t rophenol4-Ni t roan i I ineDiethyl phthalateFluoreneFluorene4-Ch iorophenyl phenyl ether4-Chlorophenyl phenyl ether2,4,6-Tr ibromophenol (SURR)1 ,2-Dipheny Ihydraz ine

*dlO-Phenanthrene4,6-Dinitro-o-cresolN-NitrosodiphenylamineN-Nitrosodiphenylamine4-Bromopheny 1 phenyl ether

14.14.15.15.15.17.17.16.20.17.18.18.18.18.18.18.18.18.19.19.19.20.20.20.20.20.20.21.21.21.22.22.21.22.21.22.22.22.24.22.22.22.23.

61962812631140953586132313234113235806888402379645679602180826149979851279587840125258

518535551543568641655633800678691696691696705691696713737777775784801830805816830833841836894888881920874887920910

1018901887907959

315586423252676

2610181149341219

7106171832136703174897104201141027104201141027408366111014016

37060111144337621352458182507771206373

33412334189441588230492508224776312528506733026828427894

15557250863367386128155404711570918032094322

2676.

67761

73409471966183782.

7469747972645726173.

6064506367.3

696467406467791

956.18.55979.96.92.60.68.00.98.08.21.63.41.44.24811.80.47.62.99.41.08.30.43.88.55384.75.15.34.05.68582.52.32.85.16.00.51.76.64.48


61726198998177969998979797979756619584979983100100981009983986694949985978296839768759490

b46

QUANT REPORT

Operator 10: CA3875Output File: *G8976::AQData File: >G8976::U6Name:Miac: SNA STD 80PPM

ID File: 1G0127::USTitle: IFB/BNA, PP/BNALaat Calibration: 891104 17:41

Compound


Di lut ion Factor

Page 3

891108 19:18891108 18:3*0

1.00000

BTL*98


58)59)60)60)61)61)

, 62)W63)

63)64)64)65)66)67)68)69)69)70)70)71)72)73)74)75)75)75)76)76)76)77)77)77)78)78)79)80)

HexachlorobenzenePentach loropheno 1PhenanthrenePhenanthreneAnthraceneAnthraceneDi-n- butyl phthalateFluorantheneFluoranthenePyrenePyrene

*dl2-Chry»eneBenz id ineTerphenyl-D14 CSURR)Butyl benzyl phthalateBenzo (a )anthraceneBenzo (a )an thraceneChryseneChrysene3,3'-DichlorobenzidinebisC2-Ethylhexyl ) phthalate

*d!2-PeryleneDi-n-octyl phthalateBenzoCb)fluorantheneBenzo (b)fluor an theneBenzoCb)fluorantheneBenzo (k )fluor an theneBenzo(k)f luo ran theneBenzo (k)fluor an theneBenzo (a)pyreneBenzo(a)pyreneBenzo (a )pyreneIndeno(l,2,3-c,d)pyreneIndeno(lj2,3-c,d)pyreneDibenzo(a,h) en thraceneBenzoCghi )perylene

23.24.24.25.24.25.27.28.29.28.29.32.28.29.31.32.32.32.32.32.33.36.35.35.35.36.35.35.36.35.35.36.39.40.39.40.

935086018601084609460983998055798979898550842786946986946986946983629162

976100410221029102210291131 .11991230119912301414122512651351141214171412141714151447161115341563156716041563156716041563156716041758179717621797

10190534357346533350549346533350549338785242152231223242152231223468852898299742B29591270931223471270931223473391710502125676108421761487212962420761487212962420761487212962420118598406424207640642

79.59.74.74.74.75.59.56.53.53.50.40.322.95.78.74.71.76.73.60.71.40.83.77.73.63.99.94.81.97.92.79.64.22.64.59.

826310963016220754086800981179709151665095006838304339144726127254121276

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

989897979696969797979896100949410010010010085948798908990939293929092100100100100

* Compound is ISTD

547

TOTQL ION CHRQHQTOCROMFUt >G69?S 35.0-580.0 a*u. T1C

BNH snr I20PPH400 808 1200 1600 2000. 1 ... i ... i ... t ... i . . . r . . . i . . . ( . . . i

12 16 20 4 20 32 36 40 44

Data File: >G8975::U6Name:Misc: BNA STD 120PPM

Id File: IG0127::USTitle: IFB/BNA, PP/BNALast Calibration: 891104 17:41


Quant Output File: 'M38975::AQ

BTL*97

b48

QUANT REPORT Page

Operator ID: CA3875Output File: AGB975::AQData File: >G8975::U6Name:Misc: BNA STD 120PPM


Compound


Di lut ion Factor

391108 18:46891108 17:34

1.00000

BTL#97


1)2)3)4)5)6)7)

' 8)8)8)9)9)9)10)10)10)11)12)12)12)13)14)14)15)15)16 )16)16)17)18)19)19)19)20)21)22)23)24)25)25)26)27)27)

*d4-l ,4-Dich lorobenzeneN-Ni t rosod i me thy lamine2-Fluorophenol CSURR)bis (2-Ch loroethyl ) etherPhenol-05 (SURR)Pheno 12-Ch loropheno 11 ,3-0 ich lorobenzene1, 3-D ich lorobenzene1,3-Dich lorobenzene1 ,4-Dich lorobenzene1 ,4-Dich lorobenzene1 ,4-Dich lorobenzene1 ,2-D ich lorobenzene1 ,2-Dich lorobenzene1,2-Dich lorobenzeneBenzyl alcoho 1N- Ni t rosod i-n-pr op y lamineN-Nitrosodi-n-propylamineN-Nitrosod i-n-p ropy lamineHexach lo roe thane2-Methylpheno 12-Methy Iphenol4-Methylpheno 14-Methylphenolb is (2-Ch loroisopropyl )etherbis (2-Ch loroisopropyl)etherbis(2-Chloroisopropyl)ether*d8-NaphthaleneNitrobenzene-05 (SURR)NitrobenzeneNit robenzeneNi t robenzeneIsophorone2-Ni t rophenol2,4-Dimethylpheno 1b is (2-Ch 1 o roe thoxy) me thane1,2, 4- Tr ich lorobenzene2 ,4-Dich loropheno 12, 4-Oich loropheno 1Benzoic acidNaphtha leneNaphtha lone

11.4.7.10.10.10.10.10.11.11.10.11.11.10.11.11.11.12.12.12.12.12.12.12.12.12.12.12.14.12.12.12.13.13.13.14.14.14.14.15.15.14.14.

08198363555961981467981467981467755567855522692269182655898522917169852650836432016497

3434

183321317319320338346372338346372338346372376415421430415399422399422397401415530430399433472471479499511527518551536518534

219709313557M382919357221470903424198332290445650434848459782445650434848459782445650434848459782284651

210029538473449178103282124318246282124318246851094483557718356539525211228611400884197867287732202513453694337933780392950163222

113597M12651884032

40100978111199858684899391969896101126.

1162989111125849564344340

111591045

114107122107102113

1142197

.00

.78

.38

.72

.94

.81

.88

.63

.53

.38

.46

.19

.42

.47

.09

.59

.64856.34.94.14.59.88.49.31.79.13.94.00.05.76.79.17.33.15.10.35.16.01.23.90.39.34


881009278968489888689989598999699849174389576896899100100100949255837398849589959799

9289

b49

QUANT REPORT Page 2

Operator 10: CA38 75Output File: ~G8975::AQOata File: >G8975::U6Name:Misc: SNA STD 120PPM


Compound


Oi lut ion Factor

891108 18:46891108 17:34

1.00000

BTL*97

R.T. Scant Area Cone Units

28)28)28)29)29)30)30)

-31)32)33)34)34)35)35)36)37)37)37)38)39)39)40)41)42)42),43 )'44)45)45)46)47)48)49)50)50)51)51)52)53)54)55)56)56)

4-Chloroani 1 ine4-Ch loroan i 1 ine4-Ch loroan i 1 ineHexach lorobu tad ieneHexach lorobu tad iene2-Methyl naphtha Iene2-Methyl naphtha lanep-Chloro-m-cresol

*dlO-Acenaph thaneHexach lorocycl open t ad iene2,4,6-Trich loropheno 12 ,4,'6-Tr ichlorophenol2,4,5-Trichlorophenol2, 4, 5-Tr ichlorophenol2-F luo rob i phenyl CSURR)2-Ch loronaphtha Iene2-Ch loronaphtha Iene2-Ch loronaphtha Iene2-Ni t roan i 1 ineDimethyl ph the lateDimethyl phthalateAcenaphthylene2,6-Dinitrotoluene3-Ni t roam 1 ine3-Ni t roani 1 ineAcenaph t hene2,4-DinitrophenolDibenzof uranDibenzof uran2,4-Dinitrotoluene4-Ni t ropheno 14-Ni t roan i 1 ineDiethyl phthalateFluoreneFluorene4-Chlorophenyl phenyl ether4-Ch lorophenyl phenyl ether2,4,6-Tr ibromophenol CSURR)1,2-DiphenyIhydrazine

*dlO-Ph en an throne4,6-Dinitro-o-creaolN-Nitrosod i phony lam meN-Nitrosodiphenylamine

14.14.15.15.15.17.17.16.20.17.18.18.18.18.18.18.18.18.19.19.19.19.20.20.20.20.20.20.20.21.21.22.22.21.22.21.22.22.22.24.22.22.22.

64972911641039963488142414244114245908899785043895446969951807301599788511786078421154

518534550541567639653632798677690695690695703690695712736776780774783800828803815815828839834894887879918872885918909

1016900885906

43811152983508904036

24258847627710092241436135516245621151947195841151947195841546686

155157187

528835157915529403

29017114521233361155638523

472590595722087

6072031368383840199523418896474726411111460217023682295220391305436871422003263766

1351071

921082

104401341041349011610531

10799105.

109109967

103108.

10290110809398.5978796401079

111

.34

.38

.69

.53

.19

.77

.30

.87

.00

.56

.56

.77

.66

.85

.92

.16

.46

.67

.30

.93580.44.19.86.14.34.76351.02.64.55.07.46.13850.15.55.76.26.00.52.30.49


66716199998280979999969696969958609686989498931001009810058958673959297829682957497697794

550

QUANT REPORT Page

Operator ID: CA3875Output File: 38975: :AQData File: >G8975::U6Name:Miac: BNA STD 120PPM


Compound


Di lut ion Factor

891108 18:46991108 17:34

1.00000

BTL*97


57)58)59)60)60)61)61)62)63)63)64)64)65)66)66)67)68)69)69)69)70)70)70)71)72)

1/73)74)75)75)75)76)76)76)77)77)77)78)78)79)79)80)

4-Bromopheny 1 phenyl etherHexachlorobenzenePentach lorophenolPhenanthrenaPhenanthreneAnthraceneAnthraceneDi-n-buty 1 ph tha lateFluorantheneFluorenthenePyrenePyre'ne•d!2-ChryseneBenzidineBenzidineTerphenyl-D14 (SURR)Butyl benzyl phthalateBenzo (a )anthraceneBenzo (a) anthraceneSenzoCa ) anthraceneChryseneChryseneChrysene3,3'-Dichlorobenzidinebis(2-Ethylhexyl ) phthalate

»d!2-PeryleneDi-n-octyl ph tha lateBenzo (b ) f luor ant heneBenzo (b)f luor an thaneBenzo(b)fluorantheneBenzo (k ) f luor ant honeBenzo (k) f luor an thaneBenzo (k)f luorantheneBenzo(a)pyreneBenzo(a)pyreneBenzoCa)pyreneIndenod,2)3-c>d)pyreneIndenoCl ,2,3-c,d)pyreneDibenzo(a,h) anthraceneDibenzoCa,h)anthraceneBenzo (ghi )perylene

23.23.24.24.25.24.25.27.28.29.28.29.32.28.29.29.31.32.32.32.32.32.32.32.33.36.35.35.39.36.35.35.36.35.35.36.39.40.39.40.40.

5892498600860008461146118399808055779197779197855083258694698694698694698764936464

957974100210201027102010271129119712291197122914121223126312631349140914161419140914161419141314451609153115611565160215611565160215611565160217581796176117961796

1343561480696373950463050889850463050889854645038703337936638703337936655535477312078

1684661452132236962199624Q27

223696219962402764851195755367142290831532761419131298691532761419131298691532761419131298693021641063521087773513

106352

127.113.108.105.106.106.107.93.87.86.83.81.40.449.19.

135.116.111.109.2.

113.111.2.97.113.40.123.108.100.92.139.129.118.136.126.116.115.40.115.

3.109.

9385609483211177972328630006556243001500708005662300659486309154559176000048927436

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

88979898979796969797989797100100939410010010010010010064979fl99898g8*«?'I92«19091100100100100100

Compound i s ISTD

551

TOTQl ION CHBQHOTQCSQMFile >68974 35.0-500.0 MU. BUA STB U8PPH

1600 2000

40 44

Data File: >G8974::U6Name:Misc: SNA STD 160PPM

Id File: IG0127::UST i t l e : IFB/BNA, PP/BNALast Calibration: 891104 17:41


Quant Output File:

BTL*96

S52

QUANT REPORT Page X

Qparator ID: CA3875Output File: "G8974::AQData File: >G8974::U6Name:Misc: SNA STD 160PPM

ID File: IG0127::USTitle: IFB/BNA, PP/BNALaat Calibration: 891104 17:41

Compound


Di lut ion Factor

891108 17:25891108 16:3>

1.00000

BTL#96

R.T. Scan* Apaa Cone Units

1)2)3)4)5)6)7)

' 8)8)8)9)9)9)10)10)10)11)12)12)12)12)13)14)14)15)15)16 )16)16)17)18)19)19)20)20)20)21)21)21)22)22)23)24)

*d4-l,4-DichlorobenzeneN-Ni t rosod i me thy lamine2-Fluoropheno 1 CSURR)bis(2-Chloroethyl ) etherPhenol-05 CSURR)Phenol2-Ch Icropheno 11,3-0 ich lorobenzene1 ,3-0 ich lorobenzene1 ,3-0 ich lorobenzene1 ,4-Dich lorobenzene1 ,4-'D ich lorobonzene1 ,4-0 ich lorobenzene1,2-Dichlorobenzene1,2-0 ich lorobenzene1,2-0 ich lorobenzeneBenzyl a IcoholN-NitPOSodi-n-propylamineN-Ni t rosod i-n-p ropy lamineN-NitPosodi-n-ppopylamineN-Ni tpoaodi-n-p popy lamineHexach lor oe thane2-Methylphenol2-Methylphenol4-Methylpheno 14-Methylpheno Ib is (2-Ch loro isop ropyl ) etherbis (2-Ch lor oisopropyl Jet herbis (2-Ch loroisopropyl)ether

*d8-NaphtheleneNitpobenzene-05 (SURR)Ni t robenzeneNitrobenzeneIsophoroneIsophoroneIsophorone2-Ni tpophenol2-Ni tpophenol2-Ni trophenol2,4-Dimethylpheno 1 .2 ,4-Di methyl phenolbis (2-Ch loroethoxy) me thane1,2,4-Tpichlorobenzene

11.4.7.10.10.10.10.10.11.11.10.11.11.10.11.11.11.12.12.12.12.12.12.12.12.12.12.12.12.14.12.12.12.13.13.13.13.13.13.13.14.14.14.

0823836657616398146798 "1467981467775577778755227122711824558987249363739571859530285281

34$9

186325321323324341349375341349375341349375380418429429434418402426402426400403418533434403437471476487475482487455503515529

2065533498854692964597165730254952513889385588385485675853805588385485675853805588385485675853804114132654

431266M144743886082186493753774781683753774781681152714882070910381010713475296821588094301919346961212719192

32501828432091

481998638900498445

40119126111144123106115113121124122130131128137194

1187623811615720111915293395740141721434

137174

1471.

159147126

.00

.61

.94

.86

.89

.95

.93

.55

.43

.04

.66

.37

.58

.35

.93

.59

.69

.15

.01

.76

.42

.40

.94

.19

.58

.33

.34

.53

.42

.00

.16

.61

.86

.43

.22

.80

.18

.96

.29692.47.96.05


901008988968185878689979696979797838076693894779070991001001009492618896979755845691948995

553

QUANT REPORT Page

Operator ID: CA3875Output File: 68974::AQData' File: >G8974: :U6Name:Misc: SNA STD 160PPM


Compound


Di lut ion Factor

891108 17:25891108 16:37

1 . 0 0 0 0 0

BTL*96


24)25)25)26)26)27)27)

W28)28)28)29)29)30)30)31)32)33)34)34)35)35)36)37)37)37)

V^J8)

39)40)41)42)42)42)43)43)44)45)45)46)47)47)47)48)

1 ,2 ,4-Tr ich lorobenzene2,4-Dichlorophenol2, 4-Dichlo ropheno 1Benzoic acidBenzoic acidNaphtha leneNaphthalene4-Chloroani 1 ine4-Ch loroan i 1 ine4-Ch loroani 1 ineHexach lorobutadieneHexachlorobutadiene2 -Methyl naphtha lene2- Methyl naphthalenep-Chloro-m-cresol

*dlO- AcenaphtheneHexachlorocyclopentadiene2,4,6-TrichIorophenol2 ,4,6-Trichlo ropheno 12,4,5-Trichlorophenol2,4,5-Trichlorophenol2-Fluorobiphenyl (SURR)2-Ch lor onaphtha lene2-Ch loronaphthalene2-Chloronaphtha lene2-Ni t roani 1 ineDimethyl phthalataDimethyl phthalateAcenaphthylene2,6-Dinitrotoluene3-Nit roani 1 ine3-Ni t roan i 1 ine3-Ni t roani 1 ineAcenaphtheneAcenaphthene2 ,4-Din it ropheno 1Dibenzof uranD ibenzof uran2,4-Dinitrotoluene4-Ni t ropheno 14-Ni t ropheno 14-Ni t ropheno 14-Ni t roani 1 ine

15.14.15.14.15.14.14.14.14.15.15.15.17.17.16.20.17.18.18.18.18.18.18.18.18.19.19.20.19.20.20.20.20.20.20.20.20.20.21.20.20.21.22.

50663077176697669732116411399634861527152743152759109000860641 .719847877171982241981234

563522553527547522537522537554544570642656635801679693699693699707693699715740779784777787804819832807827819819832844804832839899

2671408648

451329501205374M17734

12416045953

1610935134545204

31278767139414589375892161904346352244478296200244478296200787088245959045

7692852522868323763749

1083316185747172323280813730

7033452402

1044433615

9653602373692523291567874175346

1461

34241

1127

146147

11111433

1524015814017012214712741

131132139.

13913712019

128.

159.

13513167

163118

675.48.62.73.76.83'.93.71.26.46.85.23.48.12.79.00.81.82.61.09.92.65.19.54.09.79.41628.48.65.90.97.63.74440.60508.75.61.08.02.55.07


939790969389896070619699817998999796979e>"69857589«*8"986*96e:10Clie100978"*1005<*959768467096

b54

QUANT REPORT Paga

Operator ID: CA3875Output File: *G8974::AQData File: >G8974::U6Name:Misc: SNA STD 160PPM


Compound


Di lut ion Factor

891108 17:25891108 16:37

1.00000

BTL*96


49)50)50)51)51)52)53)

U/54)55)56)56)56)57)58)59)60)60)61)61)62)62)63)63)64)64)

. 65)^-^ 66)

66)67)68)69)69)69)70)70)70)71)72)72)73)74)74)75)

Diethyl phtha lateFluoreneFluorene4-Ch loropheny 1 phenyl ether4-Ch loropheny 1 phenyl ether2,4,6-Tribromophenol CSURR)1 , 2-Di phenyl hydraz ine

*dlO-Phenanthrene4,6-Dinitro-o-cresolN-NitrosodiphenylamineN-NitrosodiphenylamineN-Ni't rosodi phenyl am ine4-Bromophenyl phenyl etherHexechlorobenzenePent ach loropheno 1Phenan threnePhenanthreneAnthraceneAnthraceneDi-n-butyl phtha lateOi-n-butyl phtha lateFluorantheneFluoranthenePyrenePyrene

*d!2-ChryseneBenz id ineBenz id ineTerphenyl-D14 CSURR)Butyl benzyl phtha lateBenzo(a)anthraceneBenzo Ca> anthraceneBenzo (a ) an three oneChryseneChryseneChrysene3,3'-Dichloroben2idineb i s C 2 - E t h y l h e x y l ) p h t h a l a t eb i s C 2 - E t h y l h e x y l ) p h t h a late

*d!2-PeryleneDi-n-octyl p h t h a lateDi-n-octyl phtha lateBenzoCb)fluoranthene

22222221222222242222222323232424252425262728292829322829293132323232323232333436343535

.14

.02

.81

.95

.14

.81

.61

.79

.48

.14

.57

.12

.58

.93

.50

.87

.01

.87

.01

.45

.09

.47

.10

.47

.10

.82

.97

.79

.79

.54

.78

.90

.98

.78

.90

.98

.84

.49

.38

.83

.38

.26

.87

889983922875889922912

101990688991093796097710051023103010231030110111321200123112001231141412251265126513511412141814221412141814221415144714911611149115341564

632751716164758718312

31033213100381363716556012409331677378195

2071212264235082118730M836009814190836009814190

270993632666501865275766501965275776121813943092

300557262001418166392705

9372418166392705

9372117586362303

2565612492565

439981323423

118123

16

1161411254015310126.

159142159138134138135.

1261191161121104055821176153151142

3155145

3129152

140.

142137

.16

.92

.31

.89

.76

.03

.58

.00

.10

.56

.04690.36.52.50.39.77.74.12367.69.19.99.83.75.00.68.22.53.26.38.16.39.06.62.48.19.89.08.00830.32.79


b

93988393859680977777947290959997979696989597989797981001009395

10010010010010010086996092949999

55

QUANT REPORT

Operator ID: CA3875Output File: ~G8974::AQData File: >G8974::U6Name:disc: BNA STD 160PPM

ID F i l e : IG0127::USTitle: IFB/BNA, PP/BNALast Calibration: 891104 17:41

Compound

Quant Rev: 7 Quant Time:In jected at:

Di lut ion Factor:

Page 4

891108 17:25891108 16:37

1.00000

BTL*96

* Compound is ISTD


75)75)76)76)76)76)77)77)77)77)78)78)79)79)80)

BenzoCbBenzoCbBenzoCkBenzoCkBenzoCkBenzoCkBenzo CaBenzoCaBenzoCaBenzoCaIndenoCIndenoCDibenzoDibenzo

) f luoranthene) f 1 uoranthene) f luoranthene) f luoranthene) f luoranthene) f luoranthene)pyrene)pyrene)pyrene)pyrenel,2,3-c,d)pyrenel,2,3-c,d)pyrene(a, n) anthraceneCa,h) anthracene

Benzo Cghi)perylene

353635353636353536363940394040

.95

.71

.87

.95

.71

.89

.87

.95

.71

.89

.90

.68

.94

.68

.68

156816051564156816051614156415681605161417621800176418001800

263090267026323423263090267026

3001323423263090267026

30016868892454722485746874

245472

112.113.176.143.146.

1.173.140.142.

1.156.56.158.4.

151.

087696951164168697617100793931

UG/MLUGxriLUG/MLUGxriLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUGxriLUGXML

89899292939591909193100100100100100

556

78SEMIUOLATILE CONTINUING CALIBRATION CHECK

Lab Nama:ETCNJ . Contract:68D9Q036

Lab Code:F2 Case No.:12895 SAS No.: SDG No.:

Instrument ID:GC/f1S G Calibration Date: 11/14/39 Time: 17C*

Lab File ID: >G9036 Init Calib. Datee(a): 11/08/89 11/08/89

Min RRF5Q fop SPCCt*) - 0.050 Max ?;RSD for CCCC»>

11 COMPOUND

IPhanolIbis(2-Chlopoethyl)ethep ___12-Chlorophenol ,_. ,1 1 ,3-Dich lopobanzena1 1 .4-Dich lorohanzena , ,IBanzul a Icoho 1 .1 1 .2-Dich lorobenzena12-Mathglphanol .,lbia(2-Chloro i sop ropy 1 ) ether1 4-Mathy Ipheno 1

11

*111»t1111

IN-NitPOso-d i-n-ppopy lamine_*! Haxach loroathane MI , 1INi t pobenzene1 laophorona12-Ni trophanol iini12 rA-Oimethylphana 1iBenzoic acid , ,„lb isl2-Ch lopoethoxy ) me thane_1 2 ,4- Die h lor op h an Q 11 1 ,2,4-Tp ich lorobanzana1 Naphtha lane imimfiml4-i"h loroani 1 ina MI1 Hex » eh 1 nrobu t ad tanat4-Ch loPo-3-mathylpheno I1 2 -n« thy In aphtha lane1 Hexach lorocyc 1 open tad lane _12,4,4-Tneh Inrophanoll2A,5-Trieh Icsrophanol ,„„„,,,„_1 9-Th loranaph thai ana19-Ni trn^ni 1 in*in ; m.thy lphth»latat An«naphthylana ,_, ,,12 jA-nini troto luana

t A,-»nj»phth«n« __ ___1 9 J A-Hini t rnphwno 1 _ _ , „1 4-N i t ropheno 11

11»111*111**1

*1

1111*

**1

1RRF I

.8311

.7151

.6641

.S'JOI

.7941

.493*1

.8351

.1671

.6731

.5621

.4021

.712!

.2161

.3371

.1011

.4491

.2921

.3751

.9241

. 362 1

.2471

.2451

.4871

.5941

.3871

.49211.3671.4001

1.42111.9121.3021.2341

1.2441. 126 1.0871

1

RRF50

.925

.363

.771

.966

.377

.539

.934

.635

. 1V4

.831

.616

.J36

.443,759.241

.U72

.465

.701

. 3341.022.416.242

.510

.634

.417

.4611.498.427

1.4822.114.326.329

1.300.160.119

!%D I

11. 3»20.6!16.2113.7!10. 5»19.4111.9119. Oi15. ol23.5!9.7*

* / « • •10.11

11.7*14.4129". 013.513.3*2.5 !

10.6114.71

2.**4.71

7.7*6.3!9.616.914.3 110.617.8116.1!

26 . 4$36.9*

1

FORtl UIl SO -1 1/37 Rev.

557

7CSEMIUQLATILE CONTINUING CALIBRATION CHECK

Lab Name:£TCNJ

Lab Code:F2

Instrument ID:GC/MS G

Lab1 File ID: >G9036

Case No.:12895

Contract:69D90036

SAS No.: SDG No.:

Calibration Date: 11/14x89 Time: 1703

Init Calib. Dates(s): 11X08/89 11/08/89

Min RRF50 for SPCCC#> - 0.050 Max *RSD for CCCC»)

11 COMPOUND

1 D i hanzof uran12 ,4-Dinitroto luene _IDiethulphthalate14-Ch loropheny 1-pheny lether_1 F I uorene1 4-Ni t roan t 1 met4,6-Dinitro-2-methylphenol_IN-Ni t rosodipheny lamine (1 )_1 4- Bromopheny 1-pheny 1 ether _ ,i Hexacn lornbanzana1 F>int ach lorophano 11 Phenanthrane.r--.-. ;.' acenaIDi-n-butylphthalata1 F Luoranthane ,1 Parana |1M| ,iB^fi-jlbanzylphthalate13,3' -Oichlorobenzidine.^___1 E. nzo(a JanthracenaIChrusaneIb ; ?l2-Ethylhexyl )phthalate_1 Di-n-actylphtha late ,_ „iB.-jnsotb J f lua ran then*1 Banzo (k ) f luoranthene1 B.r?n2Q(a)pypane IMI

1 Indeno(l,2,3-cd)pyrene_— __i D ;b*nz (a ,h ) anthracene1 Banzo Cg fhf i )parylene ,__

INi trohanzane-dS1 2-Fluorobipheny 1i Tarphany l-d!4iPhanol-dS1 9-FI Liopoph«no 112 , 4,6-Tr ibromophano 11

___ 1 1RRF IRRF50 1

1.6221 1.6541.352! .3831

1.1261 1.2321.5741 ,5781

1.2391 1.3131.2401 .2981.1571 .1981.6911 .7181.3551 .3291.3931 .3691.1521 .1661

1.3631 1.51611.3511 1.53111.3871 1.7251.9941 1.2321.9671 1.2081.8651 1.0171.3601 .4711

1.3831 1.50611.3541 l.,'38l1.1001 1.39811.3281 2.05511.4971 1.38911.2931 1.25811.1831 1.21912.4881 3.1061.8761 1. 1131.8311 1.1331

.5021 -554I1.4631 1.59711.0371 .9891,8391 .9961.6601 .7651.1821 .1791

1 1

i*D 1

2.018.719.41.31

5.9124.2126.013.9*7.316.319.4»11.3113.4124.4123. 9»24.9 117.6130.7;8.912.5!

27.1112. 4«7.212.7!3.1*

24.3127.1128.5!

10.2:9.214.6 i

18.7115.911.71

t

(1) Cannot be separated from Diphenylamine

FORM ui i su -2 1X87 Re

TOTPL ION CHROHATOCR0Hflit >69O« 35.9-580.8 w

1600000-1

1400000-

1200000-

1000080-

880000-

600000-

400000-

200880-

TIC1680 2000

44

Data File: G9036::U6Name:Hisc: BNH 5TD I I

Id File: IG017G::PFTitle: :FB-'9MA. PP^BNALast Cal itrsr:cn: 391114 09:31

Operator ID: =71575Quant Time: 3*1114 17:51Injected *t : :';'1114 17:0?

Quant Output File:

BTL# 2

b59

QUANT REPORT Page

Operator 10:Output File:Data File:Name:Misc: BNA STD

PT1575^G9036::AQ>G90J6::U6

II


Dilution Factor

891114 17:51891114 17:03

1.00000

BTL# 2

ID File: IG013Q: s PFTitle: IFB/BNA, PP/BNALast Calibration: 391114 09:31

Compound R.T. Scan* Cone Units

1)2)2)3)4)5)6 J

/ 7 )3)3)8)9)9)9)10)10)10.'11)12)1 -^ >17)i4J14 J15)15 )A 6 J16 Ji )13)19)I0.119 )20)20)21)22 )23)24)25 )25)26)•^ s J27?

•*d4-l,4-DichlorobenzeneN-Ni t rosod i me thy Lami neN-Nitrosodimethylamine2-FIuorophenol '. SURR)bi»C2-Chloroethvl ) etherPhenol -D5 ' (SURR)Pheno 12-Chloropheno I1,3-Dichlorobenzene1 ,3-Oichlorobenzenel,?-Dichlorobenzene1,4-Dichlorobenrenei ,4-Dichl a robenzene1,4-Dichlorobenzene1,2-Oichlorobenzene1, 2-Dichlorobenzene1 ,2-DichlorobenzeneSenzy 1 a 1 coho 1N-Nitrosodi-n-propylamineM-N 1 1 rosod i-^-propy laminaHexach loroe t h'ane2 -Me thy Ipheno 12-Methylphenol•+-Me thy ipheno 1•4-Methy Ipheno 1bist2-Chioroisopropyl )etherbia<.2-Chloroisopropyl )ether

*d3-NaphthaleneHi t robenzene-D5 '.SURR)Mi t robenzeneMi t robenzeneNi t robenzeneIsophoroneIsophorone2-Ni t rophenol2 , 4-0 i me thy Ipheno 1b islS-Chloroethoxy) me thane1 ,2 ,4-Trichloroben2«ne2 , 4-Qich lorophenol2,4-QichlorophenolSenzo ic ac idNaphtha leneNaphtha lene

10.3.™7*10.10.10.10.10.10.11.10.10.11.10.10.11.11.12.12.12.11.12.11.12.11.12.14.12.11.12.13.13.14.13.13.14.14.14.14.14.14.14.

65778140181014165369205369205369202322331079247924751044387944222217408105361735461750

345.79

185322313320721"39347372339347372339347372376422470•4 16

40i423401423399•416531430401433471471513480500512527513551532518534

2325412163236696

270305304720351614326706272351341267309344329792341267309844329792341267709944?29~7Q22 07° 4421-5575666617 o4772241462934132241462934136334643727

535L6337051517339329603616234 '

5076535136

1613922582593112372563572015G32064478603567

683472

40.42.

i. .53.61.63.69.59.52 .47.50.58.52.?6.54.49.52."5 .T"?

19.?2 .67.38.55.7*1

56.36.40.55 ."*"57 .3.

63.

005172312969647204252902680752506303609150230155715720002955

301411

.64555 .66.55.45.55 .

7762703521

.565110. 67

.6675? .26

UG/MLUG/MLUG-'MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG-'MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

a10103?*s9815i'~7-9c9:^T

C

3*91010-cc3c

9"Q

O

3

-

T

-

-

-

.

.

-

'-

1

_

_

-

':

--•:

gtr•3O

3•3

3

-."

"

bSO

Operator 10: PT1579Output File: ^G9Q36::AQData File: >G9036::U6Name:Misc: SNA STD II

ID File: IG0130::PFTitle: IFB/BNA, PP/8NALast Calibration: 391114 09:31

Compound

QUANT REPORT


Oi lut ion Factor

Page 2891114 17:51891114 17:03

1.00000

BTL* 2

R.T. Scantf Area Cone Units

282328292970"*0^132333474353576373-?373879*041

42-*24344

/'• e

46-*748950505151525?545556565758

!))

)))j))))))))i)i)3));<j•\)) .))))))j>i,i)))jj))

4-Ch loroan i 1 me4-Ch loroan i 1 ine4-Ch loroan 1 1 meHe xach lorobut ad t en eHe xach lorobut ad lene2-Methylnaphthalene2-Methylnaphthalenep-Chloro-m-cr^sol

»dlO-^cenapntheneHexachioroc vc lopentadiene2,4,6-T-;cniDrcphenol2,4,6-TrichlDrophenol2 ,4,5-Tr ich isrophenol2 , 4 1 $ - 7 r ; c n . o r 3 p h e n o 12-F luo rob i phenyl C SURR )2-Ch loronaoh t ha lene2-Chloronapr.tha lene2-Chloron.aontha lene2-Nitroanil:n«0 i me thy i :•!•• 1 n s la t ertcenapn t hy i *ne2 ,6 -Cm i * roto .'jene3-N 1 1 roan i 1 i ne3 - N i t r o a n : 1 i n «Acenaph t hsne2 ,4-Dinitropheno IDibenrof uran2 ,4-Dinitrotoluene-*-Ni t ropheno I4-N i t roan i I t neDiethy 1 phtha lateF luoreneF I uo rene**-Ch loropheny 1 phenyl ether4-Ch loropheny 1 phenyl ether2 ,4,Q-Tribromophenol '.SURR)1 ,2-Diphenylhydrazine

»dlO-Phenanthrene4 ,6-Dm i tro-o-cresolN - N i t rosod iphenylammeM-Ni trosodiphenylamine4-8 ro mo phenyl phenyl etherHexach lorobenrene

14.14.14.14.15.16.16 .16.19.17.17.17.17.; 717.17.1 713.13.19.19.19.19.20.19.20.20.20.20,21.21.21._ _ .21.21.22.22.24.21.21.22 .•T T

23.

175035DO

i?

6494523841687368/a9668781161453757924793no

4771637967533039653012309465061042

5185345515425686396546337986776906956906*5704690695711367777737933003273033153273399353923863799173729859179081015399385905*56372

3021368432780742164

1613413413916549

'1589011894121501209874110918598741109135373087101737306

35470010114235073950046377114779785321

30778837312391531906792820070573291599310737

31736399

1369664239935531718714946219133541679997697736221

2272.

39581

63404248534550481.

49635552647354990526592376354,25151624071347A344

t

,

5,

.

.

.,

.,

.

.

.

.

.

4..........

.

.

.

.5.........

'855625i32775412380067081782o73443>647579899134244799196356297027125340396900000276289570


•s**"•iol95QQ

327194*6°8°69696'' 7935662•3435°3993910010097100'3591SO9537

*•>32a 732•3C

T

'37

C'3

~ 7'35•3 1,

96

o

QUANT REPORT Pag*.

Operator ID: PT1575Output File:Data File:Name,:Misc: SNA STD

Quant Rev: 7

>G9036:


Di lut ion Factor

II

ID File: IG013Q::PFTitle: IFB/BNA, PP/BNALast Calibration: 391114 09:31

Compound

891114 17:51891114 17:03

1.00000

BTL# 2

R.T, Scan* Area Lone Units

59)60)60)61)61)62)

. S3)^63 >

64)64)65)66 )67)63)69)69)69)

. 70)70 )70)71)72)"73)74 j.75 )

k_ J'' •* *

76)"^6 )76 )77?77)77)•73)73)7'3 )79)90)30)

PentachlorophenolPhenan threnePhenanthrenaAnthraceneAnthraceneOi-n-butyl phthalateFluorantheneFluoranthenePyrenePyrene•»d!2-ChryseneBenzidineTerphenyl-014 (SURR)Butyl benzyl phthalateSenzo(a)anthraceneBenzo(a)anthraceneBenzo (a)anthraceneChryseneChryseneChrysene3 ,?'-Dichlorobenzidineh • s(2-Ethylhexyl )phthalate•al2-P«ryleneDi-n-octyl phthalateBenzo (.b)f luorantheneBenzo*. b) f luorantheneBenzo tb ) f luorantheneBenzo ». K ) f luorantheneBenzoik )f luorantheneBenzo '. k)f luorantheneSenzo(a)pyreneBenzo la JpyreneBenzoCa JpyreneIndenoCl,2,7-c,d)pyreneIndeno(l,2,3-c,d?pyreneDibenzo(a,h)anthraceneDibenzota ,h)anthraceneBenzo l gh i )pery 1 eneBenzo igh i )perylene

24.24.24.24.24.26.27.23.27.23.72.28.29.31.72.72 .32.32.32.72 .32.33.36.34.35.35.36.35.35.36.35.35.36.39.39.79.39.39 .39.

01395039506496599659325133102740482740483805323237431337-»313374313163722871637

100110191025101910251130119512261195122614091222126213491407141314171407141314171412144516061532155915621599155915621599155915621599174517801749178017451790

339423547463532573547463582574036172882552325332882552325889916740147122584126060136637172037

3175136637172037

7175?876817772432Q5421075114251012900012507314251012*000125073142510129000125073313574116131114158

3173313574116131

725252535362Kg5759574037745575243.

5450.

066240<*«•47

797364140?6

' 51*9~*226/

220675

.52

.37

.39

.01

.54

.43

.11

.94

.04

.38

.00

.25

.58

.00

.08

.01375.36.1113 13.16.03.00.32.39. 77.52.02.06.39.52. 16.60.97.61.26.12.30.*2

UG/MLUG/MLUG/MLUG/tlLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLJG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

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10101010101CQQ

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Compound ia ISTD

b62

7CSE'11 VOLATILE CONTINUING CALIBRATION CHECK

Lab NameiETCNJ . . Contract:68D9UU36

Lat. Code:F2 Case No.:12S95 SAS No.: SDG No.:

Instrument ID:GC/MS G Calibration Date: 11/15/39 Time: 05'I"..1

Lab File ID: >G9G50 In it Calib. Date»(s): 11/08/89 11/06/89

nin RRF50 for SPCCltf) - 0.050 Max %HSD for CCCt*) - XT

1COnPOUNO I

Dihenzofuran t2 r4-Din 1 1 ro t o luene „, 1Diethwlphtha late t4-Chlorophenyl-phenylether_lF 1 uorene 14-Ni t roan i 1 me 14 ; 6-Di n i tro-2-methylpheno l_lN-Nitrosodiphenylamine ( 1 )_»4-Bromopheny 1-phenylethe r __ 1Hexachlorobenzene 1Pentachlorophenol *Phenanthrene 1An t hracene 1Di-n-butylphthalate tFlijoranthene *Purene 1B-tylbenzylphthalate t3,3 ' -Dichlorobenzidi ne ____ 1Br?nzola)anthracene 1Chrusene 1b i s t2-Ethy Ihexyl Jphtha late_lDi -n-oc ty Iph tha 1 a t e ,_ *Ber.rolb)fluoranthene tBenzo(k)fluoranthene 1Bi-nzota)pyrene *Indenoll,2J3-cd Jpyrene ____ 1Oibenz(a fh)anthracene IBenzoCg fh ri)perylene, 1

Nitrobenzene-d5 12-Fluorobiphenyl 1Terpheny 1 -d!4 IPf.*nol-d5 12-Fluorophenol t2 , 4 , 6-Tr i h romopheno 1 1

1

RRF

1.622. 3 5 2

1. 126

1.239.240.157.691.355.3V3. 152

1.3631.3511.387.994.967.865.360

1.3831.3541.1001.S231.4971.2931.183

.876

.331

.c-021.4631.037.8/9.6^0. 182

RRF50

1.619.310

1.052.535

1.232.224.163.734.353.334. 122

1.5071.5401.5301.1001 . 0561.014.426

1.5121.4411 . 3 ' J 02.1631.3291.4981.2162.333.992

1. 053

.5501.6861. 109.V9'j.740.15?

1SD 1

.2112.116.616.S !.61

6.9 i3.816.3*.31

2.3119. 7»10.6!14.0110.4110. 6»9.2 :

17.2118. '2 19.3t6.41

20.01IS.?*11.2115. v i2.8*13.9 113.3119.5 :

.».««„ |

15.217.0:

18.3112. u;16.11

(1. Cannot be separated from Dipheny1 amine

FORM UlI SU -2

b63

TOTAL ION CHROHPTOCROHFll* >G90S0 35.0-500.0

TICBHfl STD II

40 44

Data File: >G9050::U3Narr.e:Miac: SNA STD II

Id File: IG0130::PFTitle: IFB/BNA, PP/BNALast C a l i b r a t i o n : 891114 09:31

Op«rator ID: PT1575Quant Time: 89111? 06:09Injected at: 891115 05:22

Quant Output File: ^£9050: '-

BTL* 2

bo4

Operator ID: PT1575Output File: 69050::Data File: >G9050::Name:Misc: BNA STD II

AQU3

QUANT REPORT

Quant Rev: 7 Quart t T i meIn jected at

Di lut ion Factor

Page 1-

891115 06:09.691115 05:22

1.00000

BTLtf 2

ID File: IGQ130::PFT i t l e : IFB/8NA, PP/BNALast Calibration: 891114 09:31

Compound R.T. Scanft Area Cone Units

11.

1111111i111II111i.2n•"i.-ii.-->t.• •>0•->n

12234567888999rj0o1r.

'2TT

4455666V*8999

0Cl12345eX

7

))))

• »)J)1)t)1)

)i)i>i)')i)!

)

1

)

i

)

1

)

1

)

1

)

I

)

1

>

1

*d 4- 1, 4- Dich lorobenzeneN-Ni t rosod ime t hy 1 am i neN-Ni trosodimethylamine2-Fluorophenol (S' :*R)bis(2-Chloroethyl) etherPhenol -05 (S'-^R)Pheno 12-Ch loropheno 11 , 3-D ich lorobenzene1,3-Dich lorobenzene1 ,3--Dichlorobenzene1,4-0 ich lorobenzene1,4- Dich lorobenzene1 ,4-Oich lorobenzene1/2-Dichlorobenzene1 , 2 -Dichlo robenzene1 , 2-DichlorobenzeneBenzyl alcoholN-Ni t rosod i-n-propylamineN-Ni t rosod i-n-propylamineHe -'ach loroethane2-Me thy Ipheno I2-Methy Ipheno 14-Me thy Ipheno 14-Me thy Ipheno 1b i s (2-Ch loroisop ropy!) etherbii(2-Chloroisopropyl )e'therbis( 2-Ch loroisopropyl )ether

•*d8-Naphtha leneNitrobenzen*-D5 t S'JPR )N i t robenzeneNi t robenzeneNi * robenzeneI sophoroneIsophorone2-Ni t ropheno 12 ,4- Dime thy Ipheno 1b is (2-Ch loroethoxy)methane1,2 , 4- Trich lorobenzene2 ,4-Dich lorophenolBenzo ic acidNaphtha leneN « n h t h j» 1 « n «

10.7 .3.j1

10.10.10.10.10.lu .11.1C.10.11.10.1U .11.11.12.12.12.11 .12.11.12.11.11.12.14.12.11.12.13.u.14.17.13.14 .

14.14.14.14.14.

65748040181014165369205369205369202820361077247724758110443677422020173879053615421550

34881118832572132372434235037534235037534235037537942443241940342640342640240541953443240343547347352148250251553052057?520577

256551165^314976

2371VO2785043 1 8 1 7 Q284403242166311742280002292041311 '4228000229204131174228C"J022*204118- .'681792114^ 1661268491886262539251386262^39256 2 '• 381953140212471741324463154028244*1913137

4 07'-"? 44113

131169204496237419224810171 '242*065T?6*

610430

4071?1

5i'6167665852474953525454495172651353628351695617364U"r-335.'2

5 -'

515*5"41?r. '76

C "*>

.00

.32

.08

.01

.69

.47

.76

.43

.36

.03

.05

.37

.43

.68

.85

.26

.38

.47

.96

.07

. 75

.31

.88

.48

.30

.60

.30

.66

.00

.93

.82

.68

.88

.54580.42.34.54. 52. 37. 25•r-5197

UG/MLUG "1LUG/MLUG. 'MLUG/MLUG MLUG/MLUG 'MLUG/MLUG 'MLUG/MLUG 'MLUG/MLUG-'MLUG/MLUG 'MLUG/MLUG 'MLUG/MLUG -'MLUG/MLUC- 'MLUG/MLUG 'MLUG/MLUG 'MLUG/MLUC- 'MLUG/MLUC- 'MLUG/MLUb MLUG/MLUG 'MLUG-'MLIJb 'MLUG/MLUC- MLUG''MLUC- "1LUG-'MLUt '"1LUG/ML

89iuo100818593859288873.9989698999799SO75"*. 'J79748766961001001 0 094g^577955QX76';' *'94'- ; i

05°694g.j

88565

QUANT REPORT Page

Operator ID: PT1575 Quant Rev:Output File: ~G9Q50: : AQDataNameMisc

ID FTit 1Last

28)28)28)29)30 i30)31 1' 32 )33)34)343

35)35 '36)37)37)3"1 )'-8)3^ '40)41 '42)42 i43)4-^45J46 '4"11)48 i49)5 U '50 )51 ''51 )?•;• •53)5 7 •5?)CT, !

'-5 )?e '56357)

Fi le: >G9050: : U3:: SNA STD II

ile: IG0130::PFe: IFB/BNA, PP/BNACalibration: 891114 09:31

Compound

4-Ch loroan i 1 ine4-Ch loroan i 1 me4-Ch loroan i 1 ineHexach lorobutadlene2-Methylnaphthalene2- Methyl naphtha lenep-Ch loro-m-creao 1

*dlO-AcenaphtheneHexachlorocyclopentadiene2,4,6-Trichlorophenol2,4,6-Trichlorophenol2,4,5-Trichlorophenol2,4,5-Trich lorophenol2-F luo rob i phenyl (£' :*R)2-Chloronaphthalene2-Chloronaphtha lene2-Chloronaphthalene2 - N i t r o a n i 1 i n eDimethyl phthalateAcenaphthylene2 ,6-Dinitrotoluene3-Nitroani 1 me3-NitroanilmeAcenaph t hene2 ,4-Dmitropheno 1Dibenzofuran2 ,4- Din itrotoluene4-N 1 1 r opheno 14-N i t roan i 1 meDiethy 1 phthalateF 1 u o r e n eF 1 u o r e n e4-Chlorophenyl phenyl ether4-Ch loropheny 1 phenyl ether2 ,4,6-Tr ibromophenol (SURR)1 ,2-Diphenylhydraz me1 ,2-Diphenylhydrazme1 , 2 - D i p h e n y 1 h y d r a z ine

*dlO-PhenanthreneA, 6- Dm i t ro-o-creso 1N - r 1 1 t rosod iphenylammeN-Nitrosodiphenylamne4-6ro mo phenyl phenyl ether

7I

Di lut

Quant Time'.n ject ed a t :i on Fac tor :

891115 06:09.891115 05:22

1.00000

BTL* 2

R.

14,14.14.15.16,16.16.IV.17.17.17.17.17.17.17.17.18.18.19.19.19.1' .20.19.20.20.20.20.21.21.21.O •"•4. »

21.21 .22.21.22.2?.24.2 1 .21.TV .23.

T.

15508219659451874367776777966977126144385691489721487062786852313966313913102892660710

Scantt

520537553571643657636B0168169369869369370769469871573978 U777736803831806818331842838895y90882921876c'39921876912960

1013*Q286U1J09960

Area

26998Uo66220499140 a 432785345037

• 12238714HJ59122648769037900876 '--0379008297-4082892 9 U 5

2768417-4842?6373335 :j 394727450V 164385

230l'0618355

285 > 95545°714'-: 5 53941418540921721320024364°432726*323267

27730634V.M51143142 3 -' '-• 99756

10p.'2150721

Cone

23643v54.

55404650514749511

5261505453635

525851536565545 LI.i-

4"44

-55

tt405844847

796.34.99.27.18vao.38.00.81.29.66.92.24.56.56547.14.39.57.55.38.34.53. 02.79.51. 01.28.77. 02.79468.20.52. 09"65.72.01.00.51.48. 34.27

Units

UG/MLUG/MLUG/MLUG-'MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG 'MLUG/MLUG/MLUG/MLUG-'MLUG/MLUG 'MLUG/MLUG T1LUG/MLUG 'MLUG/MLUG 'MLUG/MLUG 'MLUG/MLUG -1LUG/MLUG.'MLUG/MLUG-'MLUG/MLUG MLUG/MLUG 'MLUG/MLUG 'MLUG/MLUG '1LUG/MLUG MLUG/ML

q64756299817995999994969$96985761968~"97938?100100VV100*y8569949198349185974174439672749537

Operator ID: PT1575Output F i l e : '"G9050Data File: >G9050Name :Misc: SNA STD I I

QUANT REPORT

Quant Rev: 7AQU3

7 Quant TimeInjected at

Di lut ion Factor

Page 3

891115 06:09891115 05:22

1.00000

BTL# 2

ID File: IG013Q::PFT i t l e : IFB/BNA, PP/BNALast Calibration: 891114 09

Compound

31

R.T. Scan# Area Cone Units

58 i59)60?60)61'61)62)'63)67 >64)64)65)66)67)68 *69)69 i70)70 '71)72 '73)74 :75)75 i^5 )76 i76)76 i^7)7" i77)78'78 )7° •=30)8'.:

Hfixach lorobenzenePentach loropheno 1Phenan threnePhenan th reneAn t h raceneAn t h raceneDi-n-butyl ph t h a l a t eF luo ran t heneF 1 uoran thencPyrenePyre/ie

*d!2-ChryseneBenz i d i neTerphenyl-D14 f SvSR)Butyl benzyl phthalateBenzo(a JanthraceneBenzo l a )anthraceneCh ryseneCh r ysene3,3'-Dichlorobenzidinebis (2-Ethylhexyl )phthalate*d!2-Pery leneDi-n-octyl ph t h a l a t eBenzo I b ) f luorantheneBenzo Cb ) f luorantheneBenzo ( b ) f luorantheneBenzo Ck ) f luorantheneBenzotk ) f luorantheneBe tzo (k ) f luorantheneBenzoCa)pyreneBenzo ( a ipyreneBenzo < a ) pyr eneIndenol 1 ,2,3-c , d )pyreneIndenoCl ,2 , 3 - c , d JpyreneDibenzo (a , h )anthraceneBenzo'ghi JperyleneBe'~'ZQ (. gh i ) pe r y 1 ene

23.2 — .24.24 .24.2-.26.2"' .28.2 ~" .28.32 .28.2° .31.32.32.7 •"'

32.7 •">

33.36.34.3U .35.36.35.3*.36.35 .35.3o .39.3° -39.7g .39.

43023649364962965996593151320727392739370432313642173642173642171538231538

976100510221U281022U<28113?1199123011991230141?12261266135214111417141114171416144916101536156?15661 6 0 ?156?1566160?1K6?1566160?17491-35175?1^491785

5512617536

216234221074216234221 Li 7421965215732415156615 7S 2 4151566443171569462149567898-i69780747£-697BO 7472 7 • c 877928? :J .'6882109504625685^46151504625 6 y 5 74615150-625685746 1511075583^9 437661

1C''1- 5839974

46.53.52.53.52.5? .55.52.50.52.50.40.

326.51.56.52.49.54.52.5° .58.40 .51.42 .47.7 y, f

44.i1'1 .40.54.60 .40 .66 .L — .

68.18'::.70 .

592303206735427566696000321382308659043454009200324103612707924557748766U

UG/MLUG/MLUG/MLUG-'MLUG/MLUG 'MLUG/MLUS/MLUG/MLUG/MLUG/MLUG 'MLUG/MLUG-'MLUG/MLUG 'MLUG/MLUG MLUG/MLUG.'MLUG/MLUG 'MLUG/MLUG MLUG/MLUG MLUG/MLUG MLUG/MLU'-- MLUG/MLUG 'MLUG/MLUG MLUG/MLUG MLUG/ML

969898989797979798989791?100499

1 U 01001001008797S799^2909195*404'i ',Q2g *.

luoi IJ 0

1 0 !Jl U U1 0 0

Compound is

b67

7BSENIOOLATILE CONTINUING CALIBRATION CHECK

Lab Name:ETCNJ . Contract:68D9U036

Lab Code:F2 Case No.:12895 SAS No.: SDG No.:

Instrument ID:GC/MS G Calibration Date: 11/15/89 Time: 17u"

Lafc File ID: >G9063 I n i t Calib. Datesls): 11/08/89 11/08/89

Mm RRF50 for SPCCt#) - 0.050 Max \KSD for CCCC*J

COMPOUND

Pheno 1b i s (2 -Ch lo roe thy l Jet her _2 -Ch loropheno 11 T 3-D ich lorobenzene1 ,4-Dich lorobenzeneBenzol a lcohol1 ,2-Dich lorobenzene2-Fleth'jlpheno 1b i s (2-Ch loro isopropy 1 J e t h4-rie t hv Ipheno 1N-Ni t roso-d i-n-propylaminHexach loroethaneNi t robenzeneIsophorone2-Ni t rophenol2 f4-DimethylphenolB.-nzo ic ac id

11

*111*111

er 1t

"l1t*tt

b i s (2 -Ch lo roe thoxy Jrnet hane__l2 , - -D ich loropheno l *1 ,2 ,4-Tr ich 1 orobenzene __N A p h t h a 1 e n e4-Ch loroani 1 meHrr .• ach lo robu tad lene4-Ch loro-3- me thy Ipheno 1 _2-r tethv j lnapntha leneHexach lorocyc lopentad iene2 ,,<*,6-Tr ichlorophenol2 ,4,5-Tr ichlorophenol2-Ch loronaphthalen*2-Ni t roan i 1 meD ; me t h y 1 p h t h a 1 a t eA^enaph thy lene n im

2 jA-Din i f rn to luene"5 -N i t roAn i lme M I n i

Acenaph t hene9,4-r i in i t rophenol ,.„.,,„4 -M i t ropheno I

__ 1i1**

^ ••B

1

*

*$$1

RRF

.831

.VI 5

.664

.550

.794.493.835.533.167.673.562.3-^8.402.712.216.337.101. 449.292.375.924. 362.247.'1-45.487

.387

. 4921.367

.4001.4211.912

.302

1.244. 126.087

RRK50

.950.823. 761.952.922.497.945.579.173.734.569.377.454.710.236.751

. -68

.2*6

1. 007. ?84.250.213.481. 662.433.449

1.550.417

1.4152. 134

.290

. 2991.361. 116. 098

SD I

14.3*15.1!

14.7112 . 1 !16. 1*

. :••!13.21

8 . 5 i3 . 5 19.1!1.4*

15. C! I12.91

V '

9.5*4.2 :

41 .014.1 !

1.6*2 . 9 :9 . 0 16 . 0 11.2*

10. -*1 .31

11. 6#11.8*

8 . 9 :1 3 . 3 1

4 . 1' :. 4 1

11.6!4. 0 t5 . 4 !9.4*8 . \ 9

13.0*:

FORM ui i su -i 1/S7 Rev.

68

SE'IIUOLATILE CONTINUING CALIBRATION CHECK

Lab NametETCNJ . . Contract:68D90036

Lab Code:F2 Casa No.:12895 SAS No.: SDG No.:

Instrument ID:GC/f1S G Calibration Date: 11/15/89 Time: 17U2

Lab F i l e ID: >G9063 I n i t Calib. Datesls): 11/06/89 11/08/89

Min RRF5Q fop SPCCC#) - 0.050 Max *R30 for CCCC»i

1 11 COMPOUND 1

ID ibenzofuran 1I 2 r 4 - D m i t r o t o l u e n e 11 D ie thu lph tha la te 11 4-Ch lorophenyl-phenylether_l1 F 1 uorene 11 4-Ni t roan i 1 me 11 4,6-Din i tro-2-methylphenol_lIN-Ni t rosodiphenylamme 11 )_*1 4-Bromopheny 1-pheny le t her __ 1IHexachlorobenzene 11 Pe n t a c h 1 o r o p h e n o 1 *1 Phenan t hrene 1lAni-hracene 11 Di-n-buty Iphtha la te , ,, 1I F ' - j o ran thene *IPurene 1I B i . t y l b e n z y l p h t h a l a t e 11 3 ,3 ' -Dich lorobenz id me ____ 11 Br nzo la )an t hracene ,.,.,. 1iChrvsene ,„ , 1Ib • s (2~Ethy Ihexy 1 )phtha l a t e_ tID i - n -oc t y l ph tha la te *1 Be- nzo ( b i f l u o r a n t h e n e 1iBenzo tk l f l uo ran thene i n 1IBiTizo(a)pyrene *1 Indenol I ,2 ,3-cd )pyrene _____ 1I D . b e n T f * f h ) a n t h r a c e n e 1IRenzo (g ,h , i ) pe ry l ene i im-_ I

INi t robenzen«-d5 _„ 112-Fluorobiphenyl 11 Terpheny l-dl4 ,_._.,, 1lPh«nol-d5 t12-Fluorophanol „„ 112 7 4,6 -Tr ib romopheno l 11 1

___ 1RRF IF

1.622 1. 352 1

1.1261.5741

1 .2391. 2 4 0 1.1571.691 1. 3 5 5 1.393 1. 1521

1.363 11.35111.3371

.9941

.9671

.865 1

. 3 6 0 11 .38311. 35411.10011.S28 11.49711 .29311.18312.438 1

.8761

.Bail

1.46311.0371

. 8 3 9 1

.660 1

. 18211

1?P!-50 I

1.660 1. 3 3 2 1

1. 115 1.5641

1.2581. 2 4 3 1.1671. 761 I. 3 5 0 1.3351. 120 1

1.51111.481 11.61611. 12611. 08411.0181

. 429 11 .48311 . 4 3 3 11 . 3 5 3 12 .27911 .37QI1.527!1.263 12.91411.03UI1. 0791

.55111.66411. 1131

.953 1

.7271

.15711

1SD 1

2 . 3 15 . 9 !1. 011.8 I1.5 11.116.61

10.1*1.312.1!

21.4«10.9!

9 . 7 116.5113. 3»12.1:17.7119.1 i

7 . 3 15 . 8 :

2 3 . 0 124.7"-

8 . 0 118. li6.7»

17.1!

17.6 122 . 4 !

1

9 . ;• !13.8 1

7. 8 :13.711 0 . 1"13.6 1

3-0. :-"S

*"**tf

(I1 Cannot be separated from Diphenylamme

FORM UI I SU -2 I.'37 Re

569

TOTAL ION CHROMflTOCRAMFile >G9663 35.6-506.0 tmu. TIC

BNB STB II

r o 12 16 40

20.00

44

Data File: >G9Q63::U3Name:Miac: BNA STD II

Id File: IG0130::PFTitle: IFB/BNA, PPXBNALast Calibration: 891119 12:26



BTL# 2

570

QUANT REPORT Page

Operetor ID: PT1575Output File: ^G9063::AQData File: >G9063::U3Name:Miac: SNA STD II


Compound


Di lut ion Factor

891115 17:49891115 17:02

1.00000

BTL# 2

R.T. Scant Area Cone Units

1)2)2)3)4)5)6)7)8)8)8)9)9)9)10)10)10)11)12)12)13)14)14)15)15)16)16)16)17)IB)19)19)19)20)20)21)21)22)23)24)25)26)27)

»d4-l ,4- Dich lorobenzeneN-Ni trosod i me thy 1 em ineN-Nitrosodi me thy lamina2-FIuorophenol CSURR)bisC2-Ch loroethyl) etherPhenol-05 CSURR)Phenol2-Chlorophenol1,3-Dich lorobenzene1,3-Dich lorobenzene1 ,3-Dich lorobenzene1 ,4-Dich lorobenzene1 ,4-Dich lorobenzene1,4- Dich lorobenzene1,2-Di en lorobenzene1 ,2-Dich lorobenzene1 ,2-Dich lorobenzeneBenzyl alcoholN-Ni trosod i-n-p ropy lam ineN-Nitrosodi-n-propylamineHexech lo roe thane2-Methylpheno I2-Methylpheno 14-Methylphenol4-MethylphenolbisC2-Chloroisopropyl )et herbisC2-Chloroisopropyl)etherbis(2-Chloroisopropyl)ether

»d8~NaphthaleneNitrobenzene-05 CSURR)Ni t robenzeneNi t robenzeneNi t robenzeneIsophoronelaophorone2-Ni t ropheno I2-Ni t ropheno 12,4-DimethylphenolbisC2-Chloroethoxy)methane1,2, 4- Trich lorobenzene2,4-DichlorophenolBenzole acidNaphtha lene

10337101010101010111010111010111112121211121112111112141211121313141313131414141414

.65

.76

.80

.40

.18

.12

.16

.18

.53

.71

.22

.53

.71

.22

.53

.71

.22

.28

.20

.38

.10

.79

.24

.79

.24

.75

.81

.10

.44

.38

.79

.44

.22

.22

.17

.20

.40

.79

.05

.36

.17

.44

.17

34568

185322 .31932132233934837?339348373339348373376421430416401423401423399402416531430401433471471518470480499512527518531518

2765491803216466

2514862846633296023283252631803292553188123266273292553188123266273292553188123266271716441968185154313049420001625365920001625365959893268894186249267133949015778127970713993

43732544747800

145630216438288152237521182454366097903

40501

4947485350484748545254525051435013474962364644203140503054251

.00

.53

.81

.18

.41

.05

.55

.41

.99

.44

.60

.54

.81

.11

.29

.64

.88

.66

.94

.34

.72

.19

.38

.54

.34

.74

.09

.27

.00

.09

.89

.77

.74

.32.5252535048505060

.85

.15

.67

.68

.58

.87

.30.620


b /

8910010077819380888689919699969799978577399676876797100100100949454836298795485918496968788

1

uporator ID: PT1575Output Fila: AG9067::AQData Fila: >G9063::U3Name:nisc: SNA STD II


Compound

QUANT REPORT


Di lut ion Factor

Page 2

891115 17:49891115 17:02

1.00000

BTL* 2


27)28)28)28)29)29 )30)30)31)32)33)34)34)35)35)36)37)37)37)38)39)39)40)41 )42)42)43)44)45)46)47)48)49)50)50)51)51)52)53)54)55)56)56)

Naphtha lane4-Ch loroan i 1 ine4-Ch loroan i 1 ine4-Ch loroan i 1 ineHexachlorobutadieneHexachlorobutadiene2-Methyl naphthalene2-MethyInaphthalenep-Chloro-m-cresol

*dlO-'AcenaphtheneHexachlorocyc 1 open t ad i one2,4,6-Trichlorophenol2,4,6-Trichlorophenol2,4,5-Trich lorophenol2,4,5-Trichlorophenol2-F luo rob i phenyl CSURR)2-Chloronaphthalene2-Chloronaphthalene2-Chloronaphthalene2-Ni t roan i 1 ineDimethyl phthalateDimethyl phthalateAcenaphthylene2,6-Dinitrotoluene3-Ni t roan i 1 ine3-Ni t roan i 1 ineAcenaph thene2 ,4-Dini trophenolDibenzo f uran2,4-Dinitrotoluene4-Ni t rophano 14-Ni t roan i 1 ineDiethy 1 phtha lateFluoreneF luorene4-ChlorophenyI phenyl ether4-Ch loropheny 1 phenyl ether2,4,6-Tr ibromophenol CSURR)1,2-Diphenylhydrazine

*dlO-Phenanthrene4,6-Dinitro-o-cresolN-Nitrosodi phenyl am ineN-Nitrosodi phenyl am ine

14.14.14.14.14.15.16.16.16.19.17.17.17.17.17.17.17.17.18.18.19.19.19.19.19.20.19.20.20.20.20.21.21.21.22.21.21.22.22.24.21.21.22.

50175084661965945189436977697796697712634652385691489921487264807054334068311333956809

534518534551542568640654633799678691695691695704691695712737778781774783800828804815828840836893888880919873887918909

1017900887907

6202612717

81761236682

21501541622964375692

1345001542741277028352086490835208649032Q95396433060

29881780347272838

201441145355939576284921

26244822278320084639301896446786215015242511

23115149

108716303442679131334002787911041126832

48,

1751

t5250.

52404749514850491.

495052.

48545245055515358545351.25251514051451

.64590.75.39731.40.95978.61.00.60.65.42.33.05.36.43505.35.68.77390.85.10.46.48.20.49.27.53.36.27.02.04486.50.69.51.50.00.36.51.82


89597361969982769598999797979?9758*99580998?99-9

100100Q61009-9*59Q?

9?919891958298757595

b72

\

QUANT REPORT Page

Operator ID: PT1575Output File: AG9063::AQData File: >G9063::U3Name:Misc: SNA STD II

ID File: IG0130::PFT i t l e : IFB/BNA, PP/BNALast Calibration: 891115 12:26

Compound


Di lut ion Factor

891115 17:49891115 17:02

1.00000

BTL* 2


57)58)59)60)

. 60)^~6l )

61)62)63)63)64)64)65)66)67)68)69)69)70)70)71)72)73)

^74)75)75)75)76)76)76)77)77)77)78)78)79)80)80)

4-Bromopheny 1 phenyl etherHexachlorobenzenePentach loropheno 1PhenanthrenePhenanthreneAnthraceneAnthraceneDi-n-buty 1 phthalateFluorantheneFluoranthenePyrenePyrene

«d!2*ChryseneBenz id ineTerpheny 1-014 (SURR)Butyl benzyl phthalateBenzoCa)anthraceneBenzo (a) anthraceneChryseneChrysene3,3 '-Dichlorobenzidineb i s C 2 - E t h y l h e x y l ) p h t h a l e t e

*d!2-PeryleneDi-n-octyl phthalateBenzo (b)f luorantheneBenzo (b)f luorantheneBenzo Cb ) f luorantheneBenzo Ck)f luorantheneBenzo Ck)f luorantheneBenzo Ck ) f luorantheneBenzoCa )pyreneBenzo(a)pyreneBenzo (a )pyreneIndeno(l,2,3-c,d)pyreneIndeno(l,2,3-c,d)pyrene0 ibenzoC a ,h) anthraceneBenzo C g h i )peryleneBenzo (gh i )perylene

23.23.24.24.24.24.24.26.27.28.27.28.32.28.29.31.32.32.32.32.32.33.36.34.35.35.36.35.35.36.35.35.36.39.39.39.39.39.

1345043953395366996299623451351029402940380732823743183743183743181387211387

958974

10031020102710201027113211971228119712281411122312641350140914141409141414131447160715331560156316001560

.1563160015601563160017451781174917451781

583566419319956

2519492470082519492470082694631878031807811878031807815307414188741476753698396950409839695040284728973735046998436034966873553156034966873 .55315603496687355315127638472614512812763847261

49504850494948525149535140385050494751495051405251574745504256625151195113851

.51

.11

.97

.14

.16

.04

.08

.79

.21

.29

.32

.33

.00

.17

.37

.21

.05

.38

.45

.69

.39

.25

.00

.68

.81

.42

.49

.99

.96

.15

.65

.78

.93

.41

.04

.92

.34

.22

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

86969898989797969898979798

1009291

10010010010088999099898990929293909192

100100100100100

» Compound is I STD

b 73

Lab Name:ETCNJ

7BSEMIUOLATILE CONTINUING CALIBRATION CHECK

Cont rac t:


Instrument ID:GC/MS G Calibration Date: 11/16/89 Time: 1426

Lab File ID: >G9076 Init Calib. Dates(s): 11/08/89 11/08/89

Min RRF50 for SPCCt#) - 0.050 Max *RSD for CCCC») 30

11 COMPOUND!......»»..............1 Pheno 1Ibis(2-Chloroethyl Jethe1 2-Chloropheno 11 1 ,3-Dichlorobenzene1 1,4-DichlorobenzeneIBenzyl alcohol11 .2-Dichlorobenzene12-Methu IphenolIbis(2-Chloroisopropyl )14-Methylphenol

1!

.....(.*

r ____ 111*111

ether 11

IN-Nitroso-d i-n-propy lamine_#IHexachloroethane 11 Ni t robenzene1 Isophorone1 2-Ni t ropheno 112 r4-Dimethylphenol

11*1

1 11 b is 12-Ch loroet hoxy) met hane_l12,4-Dichlorophenol *1 1,2,4-Trichlorobenzene1 Naphtha Iene1 4-Ch Inroan i 1 meIHcxachlorobu tad ienel4-Chloro-3-methylpheno12-MethylnaphthaleneIHexachlorocyc lopentad it 2 ,4,6-Tr ich lorophenol12,4,5-Trichlorophenol1 ?-Ch loronaphthalene[2-Ni t roan i 1 ine1 Dim« thy Iph thai ate , _ ,. „1 Aeenaph thylene12,6-Dini trotoluene13-Nitroanilme MIII<I<III

lAcanaphthenc1 2 ,4-Din 1 1 ropheno 11 4-N i t ropheno 11

____ 111*

1 ___ *1

ene _ #*1t11111***1

RRF

.831,715.664.850.794.493.835.533.167.673.562.328.402.712.216.337

0.000.449.292.375.924.362.247.245.487.594.387.492

1.367.400

1.4211.912.302.284

1.244.126. 087

1 1IRRF50 1|......|»1 .90411 .82011 .74111 .9651t .91411 .45911 .95811 .70611 .2011t ,89611 .64511 .38411 .47311 .70611 .24211 .52311 0. 00011 .4361t .29011 .38111 .99811 .12711 .21411 .19111 .46411 .67011 .42811 .47711 1.62811 .40111 1.27511 2. 090 11 .26811 .1431t 1.33811 .13211 .0811t 1

1SD 1..... t8.8«14.6111.6113.6115. 1»6.91

14.8132.4119.9133.1114.8*16.9117.71

.9112. !•4.410.018.21.4»

1.618.11

65.0113. 4»21.9*4.9112. v#10.5*3.0

19.1. 4

10.29.311.147. S7.6»4.3*7.2tt

I

FORM UI I SU -1 1/87 Rev.

574

7CSEMIVOLATILE CONTINUING CALIBRATION CHECK

Lab NamerETCNJ . . Contract:


Instrument ID:GC/MS G Calibration Date: 11x16/89 Time: 1426

Lab File ID: >G9076 I n i t Calib. DatesCs): 11/08/89 11/08/89

Min RRF50 for SPCC(#) - 0.050 Max NRSD for CCCC*) - 30.UN

11 COMPOUND|...........................1 Dibenzof uranI2 t4-Dinitrotoluene1 D iethvlphthalate1 4-Ch lorophenyl-phenylether_1 Fluorene1 4-Ni t roan i 1 mel4,6-Dinitro-2-methylphenol_IN-Nitrosodiphenylamine 1 1 )__*I 4-Bromopheny 1-phenylet her _ _IHexachlorobenzeneIPentachlorophenol *1 Phenan threne1 An t hraceneIDi-n-butylphthalate1 Fluoran t hene *t PwreneiButylbenzylphtha late!3,3'-Dichlorobenzid ine ____1 Benzo(a )anthracene1 ChruseneIb is(2-Ethylhexyl )phthalate_IDi-n-oct-jlphthalate1 BenzoCb ) f luorantheneIBenzotk)fluorantnene1 Benzo (a)pyrene *1 Indeno t 1 ,2 ,3-cd Jpyrene ____1 Dihenz ta ,h Janthracene1 Be n T. o t g , h } i ) p a r y 1 a n e „ mmm|....».........«... ..........INit:rohenzene-d512-Ftuorob iphenyl1 Terphenvl-dl4IPhenol-d51 2-F 1 uorophano 117,4, 6-Tr ibromophenol__1

1RRF 1...... |1.6221.3521

1.1261.5741

1.2391.2401. 1571.691 1.3551.3931.1521

1.36311.35111.3871.9941.9671.8651.3601

1.38311.35411.1001

• 1.82811.49711.29311.18312.4881.8761.3811

.50211.463 11.0371.8391.660 1.1821

1

1RRF50 1...... |.1.5931.3011.9511.5141

1. 1801.2021.1981.7691.3441.3631.1891

1.50211.48911.66511.11711.09411.0271.2381

1.49311.38211.31912. 16211.50711.29411.22713.21011. 12911. 148 t

.56511.752 11.0531.980 1.7841.1381

1

1SD 1..... |

1.7114.7115.5110.414.8115.7126.4111.3*3.017.61

24. 0»10.2110.2120.1112. 3»13.1118.8133.818.012.11

20.0118. 3»

.71

. 1 !3.8»

29. 0129.0130.3 1

12.4119.811.51

16.8 118. ?l24. 01

1

( 1 ) Cannot be separated from Diphenylarrune

FORM UII SU -2 1/87 Rev.

S75

TOTflL ION CHROMftTOGRBM>C9076 35.0-500.0 MU .

TIC400 | 800 t 1200

BNH STD II

1600

40

2000

44

Data F i l e : >G9076::U4Name:Miac: BNft STD I I

Id File: IG0130::PFT i t l e : IFBXBNA, PP/BNALast Calibration: 391116 12:11



BTL# 2

QUANT REPORT Page

Operator ID: CA3875Output File: /VG9076::AQData File: >G9076::U4Name :Misc: BNA STD I I


Compound


Di lut ion Factor

891116 16: 13891116 14:26

l.OOOGQ

BTL# 2

R.T. Scan* Area Cone Uni ts

1)2)3)4)5)6)6)7)

> 8)8)8)9)9)9)10)10)10)11)12)12)13)14)14114)15 '15);16 ''l6 )16 )17)18)19)19)19)2020)21 )22)2"*; i24)25 )25.'27 i

*d4- 1 ,4-Dich lorobenzeneN-Ni trosod imethylamine2-Fluorophenol CSURR)bis(2-Chloroethyl) etherPhenol-05 CSURR)Pheno 1Pheno 12-Ch loropheno 11,3-0 ich lorobenzene1,3-Dich lorobenzene1, 3-D ich lorobenzene1 , 4- D ich lorobenzene1 ,4-Dich lorobenzene1 ,4-D ich lorobenzene1,2-0 ich lorobenzene1 ,2-D ich lorobenzene1 ,2-Dich lorobenzeneBenzy 1 a Icoho 1N-Mi t rosod i-n-propylamineN-Ni t rosod i-n-propylamineHe^ach loroethane2-Me thy Ipheno I2-Me thy Ipheno 12-Me t hy 1 pheno 14- Me thylpheno 14-Methylpheno 1b i ?• <2-Chloraisopropyl )etherb is (2-Chloro isopropyl Jet herbisC2-Chloro isopropyl )ether*d8-Naphtha leneNi t robenzene-D5 CSURR)N i trobenzeneN i t r obenzeneNitrobenzeneI sophoroneI sophorone2-Ni trophenol2 , 4- D i methyl pheno 1b is t 2-Ch loroethoxyJmethane1 t'2 ,4-Tr ich lorobenzene2 , 4-D i ch lorophenol2 , 4- C1 ich lorophenolNaph t ha lene

10.3.7.10.10.10.10.10.10.10.11.10.10.11.10.10.11.11.12.12.12.11.11.12.11.12.11.11.12.14.12.11.12.13.13.14.13.13.14.14.14.14.14.

61723816121620144967184967184967187919360518772477247379053936794219191735780331157817

3467

187324322324326323340349374340349374340349374404424432417374403426403426401404417532432404435473473521481502514528520551521

3384782250763315393463344145733826144211

313450408456386884405361403456386884405361408456386884405361194263M27278779909

1,623562436

2^889037891429339037891484917380235121073061551585923561143232919607

6444557193

221130294643444 1 74347755265138

273011788

405053495147.

4350485052495151485046561650.

617748615725344051'2352249

•5145514949

•

,00.99.86.77.38.61524.65.68.00.29.34.57.94.09.39.70.24.62.59.83498.05.39. 14.02.92.93.93.00.23.40. 11.36.69555.20.90.97.36. 00504641

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG.'MLUG/MLUG 'MLUG/MLUG-'MLUG/ML

8910080BO93

1UO10033873890969798979899837539956680'W879V31001UU1009392c/6855498798196879596'•''638

577

Operator ID: CA3875Output F i l e : ^G9Q76:: AQData F i l e : >G9076::U4Name:Misc: BNA STD II


Compound

QUANT REPORT


Di lut ion Factor

Page 2

891116 16:18 '891116 14:26

1.00000

BTL# 2


27)28)28)28)29)29)30)30)

\w/'31 )32)33)34)34)35)35)36)37)37)37)38)39)40)41)42)42)43)V/44)

^45)46)47)48)49)50)50)51)51)52)53)54)55)56)56)57)

Naphtha lone4-Chloroani I ine4-Ch loroan i 1 ine4-Ch loroan i 1 ineHexachlorobutad. teneHexachlorobutadiene2-Methylnaphthalene2-Methylnaphthalenep-Chloro-m-cresol

*dlO-Acen«phtheneHexachlorocyclopentadiene2,4,6-TrichlorophenoI2,4,6-Trichlorophenol2,4,5-Trichlorophenol2 ,4,5-Trichlorophenol2 -Fluor obi phenyl (SURR)2-Chloronaphthalene2-Chloronaphthalene2-Ch loronaphthalene2-Ni t roan 1 1 ineDimethyl phthalateAcenaphthylene2 ,6-Din i trotoluene3-Ni t roan i I ine3-N i t roan i 1 i neAcenaph thene2 ,4-Din i trophenolDibenzof uran2,4-Dinitrotoluene4-Ni t ropheno 14-NitroanilineDie thy 1 phtha lateF 1 u o r e n eFluorene4-Ch lorophenyl phenyl ether4-Ch lorophenyl phenyl ether2,4,6-Tr ibromophenol tSURR)1 ,2-Diphenylhydrazine

*dlO-Phenanthrene4,6-Dini tro-o-creso 1M-Mi troaodiphcnylamineN-Mitrosodiphenylamine4-Br omopheny 1 phenyl ether

14141415141516161619171717171717171718181919192020192020202022212122212122222421212223

.45

.15

.45

.80

.62

.13

.59

.38

.49

.83

.37

.63

.75

.63

.75

.92

.63

.75

.06

.59

.40

.32

.52

.42

.42

.93

.18

.42

.66

.64

.05

.62

.48

.27

.34

.62

.25

.07

.25

.89

.62

.03

.07

53552Q5356015435686406546357996786916976916977056916977127387787747843288283048168288408399088878809198738879189091016900887907958

9115244243

11583752012798

1955874234408726

174511215733180801115409128729115409128729472450121223726

4391391031853439395635987240239338M7553

36085335468429700811032175854587M256366 .31315429656587

13353237330367143165383409581371515891471099

49.

16,,

4248.

43405049554753521.

52484548462444956434541414246.2

454349405945049

.55604.50741612.78.16992.75.00.62.41.11.71.22.63.45446.55.14.07.98.28.75.69.16.93.00.36.02.72.63.91437.17.58.99.00.00.25.36.53. 14


38626961989383319697989697969793566192S3989389

ICO100°810095906531949790939195"9976*7491?83

b78

QUANT REPORT Page

Operator IDOutput FileData File:Name:Misc: BNA STD

CA3875~G9076:: AQ>G9076:: U4

I!


Di lut ion Factor

891116 16:18891116 14:26

1.00006

BTL* 2

ID File: IGQ130::PFT i t l e : IFB/BNA, PP/BNALast Calibration: 891116 12:11

Compound R.T. Scan# Area Cone Units

58)59)60)60)61)61)62)63)

.,63)^ 64)

64)65)67)68)69)69)70)70)71)72)73)74)75)75)75)76)76)

^— ' 76 )77)77)77)78)78)79)79)80)80)

HexachlorobenzenePentach lorophenolPhenan t hrenePhenanthreneAnthraceneAnthraceneDi-n-butyl phthalateFluoran theneFluoran thenePyrenePyrene*d!2-ChryseneTerphenyl-D14 (SURR)Butyl benzyl phthalateBenzo Ca )anthraceneBenzoCa)anthraceneChryseneChrysene3,3 '-Dichlorobenzidinebis<2-Ethylhexyl ) phthalate

»dl2-PeryleneDi-n-octyl phthalateBenzolb)f luorantheneBenzo (.b >f luorantheneBenzoCbJf luorantheneBenzo Ck)f luorantheneBe nzo <k ) f luorantheneBenzoCk ) f luorantheneBenzo Ca )pyreneBenzo la )pyreneBenzo Ca JpyreneIndenol 1,2 ,3-c,d)pyreneIndcnoC 1 ,2,3-c,d)pyreneDibenzoCa,h)anthraceneDibenzola,h)anthraceneBenzoCghi )peryleneBenzoCghi )perylene

23.23.24.24.24.24.26.27.28.27.28.32.29.31.32.32.32.32.32.32.36.34.35.35.36.35.35.36.35.35.36.39.39.39.39.39.39.

39983347334761915491542627042234223434992476293510293510293510057714770577

974100310201027102010271132119612271196122714101263135014081414140814141414144616061533155915621599155915621599155915621599174417791748177917441779

7509638996

310592307839310592307839344203230398226062230898226062685939025888089128031118534128031118534204321131024777712912690008772987330690U08772987330690008772987330619173168587674422408

19173168587

47.78.49.49.50.50.51.49.48.51.50.40.47.50.50.46.52.43.27.48.40.47.54.46.44.49.42.40.59.51.48.55.19.54.1.

143.53.

18817228712652595551430009463461122576760043709855373920682561097181967923

UG/MLUG/MLUG/MLUG/ML'UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

9893989797969597989897989490100100100luo8393909991899094939)939192

1UU1001001001UO100

Compound is ISTD

b79

70SEHIVOLATILE CONTINUING CALIBRATION CHECK

Lab Name:ETCNJ . . Contract:68D90036

Lab Cod«:F2 Case No.:12895 SAS No.: SDG No.:

Instrument ID:GC/MS G Calibration Date: 11/17.'39 Time: 2207

Lab F i l e 10: >G9104

Min RRF50 for SPCCCf)

Init Calib. Dates(s): 11/03x89 11/08/89

0.050 Max SRSD for CCCt»J -

11 COMPOUND

1 Dibenzof uranI2 f4-Dinitrotoluene1 Diethy Iphtha late1 4-Ch loropheny l-pheny lether—1 Fluarene1 4-Ni t roan i 1 mel4,6-Dinitro-2~methylphenol_IN-Nitrosodiphenyl«mme ( 1 )_*t 4-Bromopheny 1-pheny let her _1 Hexach lorobenzene, ,„_,,IPentachlorophenol,IPhenanthrene1 Anthracene._,IDi-n-butylphthalate(Fluoranthene _„_.1 P«jreneIButylh«nzylphthalate13 ,3 '-Oichlorobenzid me ____1 Benzo (a )an t hracena n nn MI ni

IChryaane1 b is C2-E thy Ihexyl )phthalate_IDi-n-octolphthalata *IBanzotblfluor an thane iniIBenza(k If lucaranthene __, In_1 Banzo (a Jpyrene ,,„_._ . *1 Indeno(l,2,3-cd )pyrene ____IDibenz(a ,h)anthracaneIB«nzotg,h,i)perylene

INitrohenzene-d512-Fluorohiphany !__ _I Tarpheny l-d!4 „._ ,._IPhanol-d512-Fluorophenol12,4,6-Tribromophenol , .. ,._..1

___ 1RRF 1

1.622!..^521

1.1261.5/41

1.2391.-401.1571.6911.3551.3931

• .15211.36311.35111.3871

• .9941.9671.8651., 01

1.38311.35411.10011.82811.49711.29311.18312.-i38l.8761.yali.*U2I

1.46311.U37I

.8391

.660 1

.18211

1RRF50 1

1.6551.4571

1.3841.5 -'01

1.2541.3031.2141.6671.2941.3331.1161

1.-J99I1.352!1.62011.06111.00911.0361.?-^5l

1.37111.24511.30312. 07711.26911.23511.127!2. 371.980!.8671

.4V7I1.34411. 155 1.8141.6*6 1.2041

1

SO

2.029.523.0

.61.2

26.236.23.4«17.115.323.7-4.7.1

16.86.6*4.319.89.7.9

8. 118.513.6"15.24. .44.7«

10.011.91.6

1. 18.1

11.43.0.7

11.9

Cannot be separated from Diphenylamme

FORM "JI I SU -2

er

580

TOTAL ION CHROMPTOCRflHFile >69184 35.8-588.0 au.

1899090-t

ze0o00-

TIC48,0 98,8 , 12,80

BHfl STD II

1600

*. ' * ' 12 40

Data File: >G91Q4::U3Name:hisc: SNA STO II

Id Fila: IG0132::PFTitle: IF8/BNA, PP/BNALast Calibration: 891117 19:36

Operator ID: CA3B75Quant Time: 891117 22:52Injected at: 891117 22:07

Quant Output File

BTL* 2

531

QUANT REPORT Page

Operator ID:Output Fila:Da t a File:Name:Misc: BNA STD

CA3875AG9i04t:AQ>G9104i:U3

II


Di lut ion Factor

891117 22:52891117 22:07

1.00000

BTL* 2

ID File: IG0132: :PFTitle: IFB/BNA, PP/BNALast Calibration: 891117 15

Compound

36


1)2)334)5)6)6)6)7)8)8)8)9)9)9)10)10)10)11)12)12)13)14)14)15?15)16)16)ID18)19)19)19)20)20)21)21)22)23)24)25 J25)26)

*d4-l,4-Dich lorobenzeneN-Nitrosodimethylamine2-Fluorophenol CSURR)bis(2-Chloroethyl) etherPhenol -05 CSURR)PhenolPhenolPhenol2-Ch lorophenol1 ,3-0 ich lorobenzene1 , 3-D ich lorobenzene1,3-QAch lorobenzene1 ,4-0 ich lorobenzene1 ,4-Dich lorobenzene1 ,4- D ich lorobenzene1,2-Oich lorobenzene1,2-Dich lorobenzene1 ,2-Dich lorobenzeneBenzyl a Icoho 1N-Nitrosodi-n-propylamineN-Nitrosod i-n-p ropy lamineHexachloroethane2-Methy Ipheno 12-Methy Ipheno 14-Me thy Ipheno 14- Me thy Ipheno 1bift(2-Chloroisopropyl )etherb is(2-Ch loro tsopropyl )ether

»d8-NaphthaleneNitrobenzene-05 (SURR)Ni t robenzeneNi t robenzeneNi t robenzeneIsophoroneleophorone2-Ni t ropheno 12-Ni t ropheno 12,4-Dimethylphenolb is(2-Ch loroethoxy )me thane1,2, 4- Tr ich lorobenzene2,4-Dichlorophenol2,4-DichlorophenolBenzoic acid

10.3.7.10.10.9.10.10.10.10.10.11.10.10.11.10.10.11.11.12.12.12.11.12.11.12.11.12.14.12.11.12.13.13.14.13.13.13.14.14.14.14.14.

60493113098513201348641748641748641725193305782578257205393578391919171735800233173255

3599

197336334322336339336353361387353361387353361387391437444430417440417440414430545445417447486486534485494516527542534566553

275107181732225440244279279884175882537847205

23419230981928377930923030981928377930923030981928377930923015575821425452485121831204225273179204225273179907463989755584934520316360626639717291

57646247869767

148514251074307298245*291941412069

133590

404946504724214948444850465047434711041104645603446632840432643245.24149424546

•69

.00

.67

.26

.06

.58

.96

.77

.21

.75

.66

.57

.57

.44

.20

.34

.72

.71

.63

.57

.94

.27

.13

.55

.93

.96

.77

.71

.01

.00

.61

.47

.10

.80

.51378.76.97.23.14.72.49495. 13

UG/MLUG-'MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG 'MLUG/MLUG/'flliUG/MLUG/MLUG/MLUG 'MLUG/MLU&< MLUG/MLU&.'MLUG/MLUC- 'MLUG/MLU& 'MLUG/MLUG 'MLUG/MLUG 'MLUG/MLUG. MLUG/MLU& 'MLUG/MLUG 'MLUG/MLUG 'MLUG/MLUG 'MLUG/MLUG/MLUG/MLUG "1LUG/ML

8910U81779210010010079888692989596939697827538•5 i768880g'd10010094V257-•'8589878<?483968295989996

552

QUANT REPORT Page 2

Operator ID: CA3875Output File:Data File:Name:Misc: BNA STD

Quant Rev: 7

>G9104: :U3


Di lut ion Factor

II

ID File: IGQ132::PFTitle: IFB/BNA, PP/BNALast Calibration: 891117 15:36

Compound

891117 22:52891117 22:07

1.00000

BTL* 2


27)27)28)28)28)29)29 )30)30)31)32)33)34)34)35)35)36)37)37)37)38)39)39)4Q)41 )42)42)42)43 )44)45)45)46)47)47)48)49.150)50)51)51)52)53)

NaphthaleneNaphtha lene4-Chloroani 1 ine4-Ch loroani 1 me4-Ch loroani 1 ineHexachlorobutadieneHexachlorobu tad iene2-Methylnaphthalene2-Methylnaphthalenep-Chloro-m-creaol

*dlQ-AcenaphtheneHexacji lorocyc 1 open tad iene2 ,4, 6-Tr i chlo rophenol2, 4, 6-Tr ich loropheno 12,4,5-Trichlorophenol2,4,5-Trich loropheno 12-F luo rob i phenyl (SURR)2-Ch loronaph the lene2-Ch loronaph thalene2-Ch loronaph the lene2-Ni t roan i 1 meDimethyl phthalateDimethyl phtha lateAcenaph thy lene2,6-Dinitrotoluene3-Ni troani 1 me3-Ni t roan i 1 ine3-Ni troani 1 meAcenaph thene2 ,4-Dm i t rophenolDibenzofuranDibenzofuran2 ,4-Dini tro toluene4-Ni t rophenol4-Ni t ropheno 14-Ni t roan i 1 meDiethyl phthalateFluoreneF luorene4-Ch loropheny 1 phenyl ether4-Ch loropheny 1 phenyl ether2, 4, 6-Tr ibromophenol iSURR)1,2-Diphenylhydrazme

14.14.14.14.14.14.15.16.16.16.19.17.17.17.17.17.17.17.17.18.18.19.19.19.19.19.20.20.19,20.20.20.20.19.20.21.21.21.22.21.21.22.22.

17451745826314618953843867776777936777076044523356912146952121467091688266492935642911

534548534548566557582654668650813692706711706711719706711726752793797788799816831843818831831843855816854910902394933887901933924

8695671715

3061863182025082057

1480593417916866

186395257926158989120836141181120836141181433422129334944

4016151409415087043374

64124410637510485320547922

383510241512560

5335401471952148389759766244629540428745649103

18392565701486590

491

49117.

4842.

47404847553945451.

444247.

45446014

4545.

4349242464545.2474?44

637.22.77.89.05673.43.69858.17.00.15.24.19.23.83.39.42544.16.90.83317.76.93.32.18.56.57.80230.03.78.35.63.24.88.35512.33.09.51.75

UG/MLUG- MLUG/MLUG-T1LUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG-J1LUG/MLUG-'MLUG/MLUG/MLUG/MLUG TILUG/MLUG 'MLUG/MLUG 'MLUG/MLUG.'MLUG/MLUG-'MLUG/MLUG 'MLUG/MLUG 1LUG/MLUG-'MLUG/MLUG-TILUG/MLUG-T1LUG/MLUG-T1LUG/MLUG TILUG/MLUG-'^ILUG/ML

88895963619799827697999997*697«»oyf- -4

6.*-8 •*?^ •»

s:i .1CJ*g.-V <

*••- <<9 5-. -it> 1V '

95c •90g-36'--i"*?

533

QUANT REPORT Page

Operator 10:Output File:Data File:Name:Misc: SNA STD

CA387569104::AQ>G9104f:U3

II


Di lut ion Factor

891117 22:52891117 22:07

1.00000

BTL* 2

ID File: IG0132::PFTitle: IFB/8NA, PP/BNALast Calibration: 891117 15:36


53)54)55)56)56)57)58)59)60)60)61)61)62)63)63)64)64)65)67)68)69)69)69)70)

^7QJ

71)72)73)74)75)75)75)76)76)76)77)77)77)78)78)79)79)

1 , 2-Dipheny Ihydraz ine*dlO-Phenanthrene4,6-Dinitro-o-cresolN-NitrosodiphenylamineN-Nitrosodiphenylamine4-Bromophenyl phenyl etherHexach lorobenzenePen tech lorophenolPhenanthrenePhenen threneAnthraceneAnthraceneDi-n-butyl phthalateFluorantheneFluoranthenePyrenaPyrene*d!2-ChryseneTerphenyl-D14 (SURR)Butyl benzyl phthalateBenzo(a)anthraceneBenzo (a) an three en aBenzo (a) anthraceneChrysenaChryseneChrysene3 ,3 '-Dich lorobenz id inebis(2-Ethylhexyl ) phthalate»d!2-PeryleneDi-n-octyl phthalateBe n zo (b ) f luorantheneBenzo Cb ) f luorantheneBenzo (b ) f luorantheneBenzo Ck )f luorantheneBenzo Ck)f luorantheneBenzoCk )f luorantheneBenzo(a)pyreneBenzoCa JpyreneBenzo (a JpyreneIndenoCl, 2, 3-c,d JpyreneIndenoCl,2,3-c,d)pyreneD ibenzo ( a ,h JanthraceneD ibenzo (a, h) anthracene

23242121222323242424242426272827283229313232323232323232363435353635353635353638393939

.08

.26

.94

.64

.06

.08

.41

.00

.34

.49

.34

.49

.60

.90

.53

.90

.53

.25

.27

.03

.21

.34

.40

.21

.34

.40

.32

.99

.22

.76

.26

.35

.08

.26

.35

.08

.26

.35

.08

.97

.66

.03

.66

9721030916901922972988101710341041103410411145120912401209124014231276136314211427143014211427143014261459161815461571157516111571157516111571157516111753178717561787

747973099388272518671

258535113320129045449595032485236955032485236956275904108953907784108953907781145291653841483421962221781712629

19622217817126295655618651071079184551112760109743100118112^6010974310011811276010974310011824316077065870542138

640423494446404547434544454245434051464440.

4743

382444045444339484742504944401240

•

.88

.00

.91

.59

.72

.79

.41

.01

.48

.33

.59

.36

.75

.02

.81

.53

.30

.00

.26

.23

.55

.45597.85.45641.91.85.00.98.62.42.62.35. 06.93.65.30.98.71.90.28989

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG-XILUG/MLUG-'MLUG/MLUG 'MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG 'MLUG/MLUG ;MLUG/MLUG 'MLUG/MLUG 'MLUG/MLUG/MLUG/MLUG 'MLUG/MLUG.'MLUG/MLUG-'MLUG/MLUG 'MLUG/MLUG/MLUG/ML

39977174958497989797969696979893989?948V100100100too100100869984Qg89s^9092

9293919192100100lUO100

534

Operator ID: CA3B75Output File: -G9l04i*fWData File: >Bfl04nU3Name:disc: BNA STD II

ID File: IGQ132::PFTitle! IF8/BNA, "'Last Calibration: 991117 15-36

QUANT REPORT

Quant Rev: 7 Quant Time:Injected at

Oi lut ion Factor

Page 4

891117 22:52891117 22:07

1.00000

BTL* 2


90) Benzo(ghi>perylene80) BenzotghiJperylene

» Compound is ISTD

38.97 175339.66 1787

24316077065

111.38 UG/ML 10035 .30 UG/rlL 100

b35

88SEMIVOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Name: ETGNJ . . Contract:

Lab Code: . Case No.: SAS No.: SDG No.:

Lab File ID (Standard): >G9036 Data Analyzed:

Instrument ID: GC/MS G Time Analyzed: 1703

1

111 12 HOUR STO

1 UPPER LIMIT

t LOWER LIMIT

I EPA SAMPLE1 NO.

OHQC70087C02ICA1907CR03JCA2139C041 -.05 I ^06107f08109!10111112113!141IS!14117118 119;20121!221

ISKDCB)AREA *

282541

565082

141270

255355288674254550

RT

10.65

10.7010.6410.62

IS2CNPT)AREA *

535163

1070326

267581

518146514242532142

RT

14.44

14.4914.4214.40

I S3 (ANT)AREA *

189412

373824

94706

175698172977187300

1•RT i

19.8X1

:

!1

19.93119.8^119.871

!• , 1

;1

1

1

l

1

I

I

i

151 (DCS) - .l,4-Dichlorobenzene-d4152 CNPT) - NaphthaIana-d8153 (ANT) - Acanaphthane-dlQ

UPPER LIMIT • + 100%of internal standard areLQUER LIMIT - - 50%of i n t e r n a l standard are

Column used to flag i n t e r n a l standard area values with an asterisk.

FQRM U I I I SU -1 1/87 Re

SE-IIUQLATILE INTERNAL STANDARD AREA SUMMARY



Lab File ID CStMXUrd): >G9036 Data Analyzed: \

Instrument ID: CC/MS 6 Time Analyzed: 1703

111 12 HOUR STD

1 UPPER LIMIT1 ............1 LOWER LIMIT

1 EPA SAMPLE1 NC.

OHQC70Q87C021CA19Q7CR

04!05!061 A07!oa i09:10111!12113!14115!16117118119 1201211221

IS4CPHN)AREA #

187149

374298

93575

160667158911167522

RT

24.30

......

24.3724.2824.30

IS5(CRY)AREA #

99167

198334

49594

..........754777767582871

RT

32.32

32.3732.2932.30

IS61PRYJMREA #

32054

1641LI3

41Q27..........

50574•5374364060

1RT :

36. .V-':

1

36.38136. 3C:36.311

II

* * . !

1

11

1

1

1

1

1

1

IS- CPHN) « Phenanthrene-dlOIS? (CRY) - N»phthalene-d8IS6 IPRY) - Perylene-dl2

UPPER LIMIT - + 100Sof internal standard are.:.LOWER LIMIT - - 5OSof internal standard a r e >

$ iJolumn used to flag internal standard area values with an asterisk,

page > of *"

FORM UII I SU -2 1/87

b37

8BSEMIUOLATILE INTERNAL STANDARD AREA SUMMARY



Lab File ID (Standard): >G9050 Data Analyzed: 11/19x89


111 12 HOUR STD

1 UPPER LIMIT

1 LOWER LIMIT

1 EPA SAMPLE1 NO.

01IQC70092C02ICA1889C03ICA1890C04ICA1892C05ICA19Q8C06ICA2141C07ICA2142C08ICA2143C09ICA2149C10ICA2151C11 ICA1891C121131141151161171181191201211221

IS1COCB)AREA *

256551

513102

128276

240559230417246079239441242717235102249428244556237764240162240419

RT

10.65

10.6210.6510.8910.7710.6410.7310.6510.6710.6610.7110.63

IS2CNPT)AREA #

471741

943482

235870

471802462180498070495825490791502344497082475863487364473507502004

RT

14.44

14.4014.4114.6914.5714.4014.5314.4114.4314.4514.4914.41

I S3 CANT)AREA *

141059

282118

70530

168640170195179642180192163346181473184494169610173464176429175644

RT

19.87

19.8719.8720.1320. 0219.8719.9719.8719.9019.9119,9319.88

151 (DCB) - l,4-Dichlorobenzene-d4152 CNPT) - Naphthalene-d8153 (ANT) - Acenaphthene-dlO

UPPER LIMITof internalLOUJER LIMITof interna1

- + IOCSstandard area- - 5QSstandard area

# Column used to flag internal standard area values with an asterisk

FORM V I I I SY -1 1/87 Rev

b38

' 8CSEMIvOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Name: ETCNJ . . Contract:


Lab File ID (Standard): >G9050 Data Analyzed: 11/15/89


1I1 12 HOUR STD

1 UPPER LIMIT

1 LOUER LIMIT

1 EPA SAMPLE1 NO.

01IQC70092C02ICA1889C03ICA1890C04ICA1892C051CA1908C06ICA2141C07ICA2142C08ICA2143C09ICA2149C10ICA2151C11ICA1891C12113114115116117118119 1201211221

1 54 C PHN)AREA *

114814

229629

57407

127020138009149915145382120831144621169279143921137686147269144641

RT

24.28

24.3024.2824.5624.4524.2824.4124.3024.3624.3224.3724.31

IS5CCRY)AREA #

44817

89634

22409

3414556608546096138643046456237912354998555766070454223

RT

32.31

32.2832.2932.5732.4632.3032.4132.3132.3432.3332.3732.32

IS6CPRY)AREA *

30368

60736

15184

1895839187298544149423102279215984132865351193827435508

RT

36.32

36.3136.2936.5836.4836.3136.4236.3236.3536.3436.3836.32

154 (PHN)155 (CRY)156 (PRY)

- Phenanthrene-dlQ» NaphthaIene-d8• Perylene-dl2

UPPER LIMIT - + 10OSof internal standard areaLOUER LIMIT - - 90Sof internal standard area

# Column used to flag internal standard area values with an asterisk.

page >* of

FORM U I I I SU -2 1/87 Rev

b39

8BSEMI VOLATILE INTERNAL STANDARD AREA SUMMARY



Lab File ID (Standard): >G9063 Data Analyzed: 11/15/W9


01020?040506070809101112131415161718192021

12 HOUR STD............UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO.

QC70091CCA2271CRCA2147CCA2148CCA2271C

IS1CDCB)AREA ft

276549

553098

138274

250442275372230515108083*129422*

RT......

10.65

......10.6910.6610.6710.7110.66

IS2CNPT)AREA ft

492671

985342

246335..........

524559529334519116543511496678

RT......14.44......

......

14.4714.4414.4114.4914.44

I S3 (ANT)AREA ft

154274

308543

77137

18671319281815149910563359580*

RT

19.89

19.9219.8919.8819.9419.90

i1

151 (DCb) » 1 ,4-DichIorobenzene-d4152 (NPT) - NaphthaIene-d8IS? CANTj - Acenaphthene-dlO

UPPER LIMIT - * 100Sof internal standard area.LOWER LIMIT - - 5 OSof internal standard area.

ft Column used to Mag internal standard area values w i t h an asterisk,

page ..]_.__ of

FORM UII I SU -1 1/87 Rev

b90

• 8CSEMIUOLATILE INTERNAL STANDARD AREA SUMMARY



Lab File ID (Standard): >G9Q63 Data Analyzed: 11/15/39


I11 12 HOUR STDI ------------1 UPPER LIMIT!--------»"--1 LOUER LIMIT|.. ..........1 EPA SAMPLE1 NO.1 ............

01IQC70091C02ICA2271CR03ICA2147C04ICA2148C05 ICA2271C06107108109110111112113114115116117118119120 I21 122 1

IS4(PHN)AREA *

133400..........

266800..........

66700..........

167193177060164366153598115409

RT

24.33

......24.3524.3224.3224.3624.33

1 55 (CRY)AREA 4

53074

106148

26537

8068680693763824323720846*

RT

32.34

_'......32.3532.3232.3132.3632.31

IS6CPRY)AREA *

35046

70092

17523

62052619351854714251*8751*

RT

36.32

36.3636.3336.3236.3636.32

IS4 iPHM ) - Phenanthrene-dlQ135 (CRY) - NaphthaIene-d8IS6 (PRY) - Perylene-dl2

UPPER LIMIT - * 100*of internal standard areaLOWER LIMIT - - 5 OSof internal standard area

# Column used to flag internal standard area values w i t h an asterisk.

page "* of y

FORM 01 I I SU -2 1/87 Rev

591

' SBSEMIUOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Name: ETCNJ . - Contract:



Instrument ID: EC/MS G Time Analyzed: 1702

01020304050607080910111213141516171819202122

12 HOUR STD

UPPER LIMIT

LOUJER LIMIT

EPA SAMPLENO.

CA2144CCA2145CCA2146CCA2152C

ISl(DCB)AREA *

276549

553098

138274

191857243058239961245749

RT

10.65

10.7010.6610.6510.64

IS2CNPT)AREA *

492671

985342

246335..........

429069510921492184530356

RT

14.44

14.4614.4414.4314.42

I S3 (ANT)AREA *

154274

308548

77137

132832169355164409187309

RT

19.89

19.8819.9119.8819.89

I SI CDCB) - 1,4-Dichlorobenzene-d4152 CNPT) - Naphthalene-dS153 (ANT) - Acenaphthene-dlO

UPPER LIMIT - + 100*of internal standard areaLOUER LIMIT - - 50%of internal standard area

ft Column used to flag internal standard area values w i t h an asterisk.

page _J_ of *"

FORM U I I I Sv1 -1 1/87 Rev

592

' ecSEMIUOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Name: ETCNJ . • Contract:




01020304050607080910111213141516171819202122

11I 12 HOUR STD

1 UPPER L I M I T

1 LOWER L I M I T

1 ERA SAMPLEI NO.

ICA2144CICA2145CICA2146CICA2152C1111t1111I11111111

IS4CPHN)AREA *

133400

266800

66700

129544121470129347150911

RT

24.33

24.3024.3224.3124.32

I S5 ( CRY )AREA #

53074

106148

26537

54664461004801365366

RT

32.34

32.3132.3332.3232.32

IS6CPRY)AREA *

35046

70092

17523

31172292592983247111

RT

36.32

36.3236.3336.3236.33

154 CPHN) - Phenanthrene-dlO155 (CRY) - Naphthalene-d8156 (PRY) - Perylene-dl2

UPPER LIMIT - + 10 OSof internal standard areaLOUER LIMIT - - 5OXof internal standard area

0 Column used to flag internal standard area values w i t h an asterisk,

page f of >

FORM Yin SU -2 1/87 Rev

593

'SBSEMI VOLATILE INTERNAL STANDARD AREA SUMMARY




Instrument ID: GC/tIS G Time Analyzed: 1426

01020304050607080910111213141*51617181^202122

............12 HOUR STD

UPPER LIMIT

LOWER LIMIT

ERA SAMPLENO.

CA2271CSCA2148C

IS1CDCB)AREA #

338478..........

676996

169239

286120179032

RT......10.61

......

......10.5910.58

IS2(NPT)AREA ft

730615

1461230

365307

..........588970548187

RT

14.39

......

......14.3714.36

I S3 (ANT)AREA ft

215733

431*66

107866

19232796014*

RT

19.83

19.8019.79

I SI iDCb) - l,4-Dichlorobenzene-d4IS2 tNPT) - Naphthalene-daIS? iANT) - Acenaphthene-dlQ

UPPER LIMIT - + 100%of internal standard area.LOUIER LIMIT - - 50Sof internal standard area.

# Column used to flag internal standard area values with an asterisk,

page I_ of V

FORM V I I I SU -1 1/87 Re-

•ecSEMI VOLATILE INTERNAL STANDARD AREA SUMMARY





11I""— ------1 12 HOUR STD1------------1 UPPER LIMIT|.. ..........1 LOUER LIMIT|. ...........1 EPA SAMPLE1 NO.I............

OHCA2271CS02ICA2148C03 1041051061071nsi09 110111 112113114115116117118119 1201211221

IS4CPHN)AREA ft

165383..........

330766

32692

177951162424

RT

24.25

24.2324.21

IS5CCRY)AREA #

63593

137186

34296

6628423270»

RT

32.26

32.2432.21

IS6CPRYJAREA ft

47777

95554

23389..........

621522610*

RT

36.24

36.2336.23

ISA CPHN) - Phenanthrene-dlO155 (CRY) - Naphthalene-d8156 IPRY) - Perylene-dl2

UPPER LIMIT = * 100Sof internal standard areaLOUER LIMIT - - 50Sof internal standard area

# Column used to flag internal standard area values w i t h an asterisk

page -X of X

FORM U I I I SY -2 1/87 Rev

fa

ETC

RAW QC DATA

MS Data File: >G8947::U6

Na-.e: .................... Operator: C«3875Mi.-sc: DFTPP

Date/Time: llxQB/89 15:16BTL# 1

Fli» >G8Bp- Qb 2

^flftflCl— i

23000-

i**63-24008-

20000-

;soo0-16900-

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6000-

4000-

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MS Data File: >G8?47::U6

Misc: DFTPPOperator: CA3875 Date/Time: 11/08x39 15:16

BTL# 1

Flit >66947 3S.0-4ti.a MU. DFTPPTIC

4ytftf"90-

448098-

499999-

353980-

320909-

24900*

599,e9:

169009;

120000-

SOOOfl^

H

200 , 400 | 690 ( 800 ( 1000

JLjL,..,6 ' 8 ' 10 ' 12 14

-199

-90

•80

!*-49

•39

•20

•19

599

MS Data File: >G9:J35::U6

Misc: OFTPPOperator: PT1575 Date/Time: 11/14/89 16:43

BTL# 1

FiU >C903SBpk Qb 34272

3600*-

3260*

28000--

24089-

20000-J.

16009-"

12900-_

80ee-—

400*•

A.

69

\

.

9>

L

77/

iJah Jm

196

'

127

L167 i

iii.Ail JJ

255

224

ill

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.s'0 199 ise 20e 2i«

DFTPP Sctn 139S.42 nin.

-110

442

27SX

323 368 46.3

i. 1. .L. ... ( f . \ f.

•180

-98

•90

-70

<«;^0i4o',•39•

f20;

-Ift|

4•.' . «j' .». ' . Y . •*••*• i» |i i ^i f ~399 358 40c

6CU

MS Data File: >G9035 : :U6

mac: OFTPP

>G9Q35139

File: >

m/z

36.9038.0039.0040.0043.9044.9049.0050.0051.0052.00

54.9055.9056.9057.9061.0062.0063.0064.0065.0068.9072.9074.0075.0076.0077.0077.9079.0079.90

\^S 81.0081.9583.0585-0585.9587.0587.9590.9591.9593.05

NA*

G9035 Scan *:

Int.

.4..

1...

14.54.2.•

1.4.

m m

t

<l2..

1.67.

,5.a.2.50.3.3.2.3.1.1.,,,,..

5.

277721558400196228549986762620295736102204674*54045303074997648033517699350431306754831021036674899449248855890337

m/z

94.0597.9598.95101.05102.95103,95104.95106.95108.05109.95110.95112.05116.05116.95117.95121.95122.95123.95124.95126.95127.95128.95129.95131.95133.95134.95135.95136.95140.05140.95142.05142.95144.05147.05147.95149.05151.15153.05

DFTPP

139 Retn. t ime:

Int.

.5053.9043.2832.121.627

1.2141.06813.6671.952

30.9294.771.528.791

9.112.724.942

1.377.677.671

49.0663.98321.5541.789.216.648

1.634.619.811.245

2.253.858.557.309

1.3512.36?.490.356.694

m/z

153.95154.95155.95156.95158.05159.95161.05165.05166.05166.95168.05170.85171.95173.05173.95175.05175.95177.05177.95178.95179.95180.95182.05183.95185.05186.05186.95188.05188.95190.95192.05193.05196.05197.95198.95199.95201.35

Int.

11

31

1

221

1113

31006

.616

.293

.759

.312

.365

.706

.977

.788

.770

.968

.695

.195

.388

.505

.878

.389

.569

.808

.236

.982

.104

.056

.228

.292

.608

.315

.096

.266

.724

.382

.753

.905

.172

.000

.495

.467

.601

5.42

m/z

202.95204.05204.95205.95207.05207.95208.95210.15210.85211/05214.95216.95217.85220.95222.95223.95224.95226.95227.95228.95230.95233.95234.95236.85242 . 05242.95243.95244.95246.00248.80253.00255.00256.00256.90258.00259.00264.90

Int.

.5342.5764.87319.7602.795.604.210.446.890.875.210

5.278.581

6.5241.11211.0122.5563.828.484.782.406.233.271.266.575.589

8.7861.0801.371.283.201

39.2545.780.481

2.063.306.759

i * ' * -»*• « f

BTL* 1

m/z

273.00274.00275.00276.00277.00273.10283.10296.00297.00303.00313.90315.00323.10324.00327.00328.00333.00334.00345.80351.90353.10353.90364.90365.80371.30372.10382.90402.00402.90421.05422.05423,05423.95440.95441.95442.95444. 05

&o • *»^

Int.

' 1.27;3.08418.1-'2.5011.2-.'.268. 1*5

4.231.511.423.26*.426

1.401.315

".37-5".266. 2i'".983.2**.371.2<*-H.400

1 . 5 3 H.266. lc;>.680.274.371. 41 i.303. 3 - :

2.393.57-1

5.85041.55V7.989. 7J 5

601

MS Data Ftle: >G9035::U6

Name: .................... Operator: PT1575tlisc: DFTPP

Date/Time: 11/14/89 16:43BTL* 1

Fil. >CS

260090-

£49999-

229eee-290000-

180000-

160000-

140000-

120009-

160099-

89900-

60000-

49000-

20990-

9-

036 3«.0-4W.9 WU. DFTPP

199 299 300 409 599 600

>

A_JU___M——— r-A*—— "' ' ' •""""•• '-" ——— "-

' 5*0 ' 6!9 ' ?'.9 ' 8^9 ' 9^9 ' 19

•100

•99

•09

•79

-60

0

i40

:30

-29

-10

U9

602

(IS Data File: >G9049::U3

-.C: DFTPPOperator: PT1575 Date/Time: 11/15/89 5:00

BTL# I

Filt >C9849BPL Ob 48144

44008-

48088-

36889

32999-;

28088-•

24003;

>eeee-_

16088-

12060-1-

8088-J

4080-

0-

69\

-

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77/

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198

127/

I .iiu.4fJ.Ai i.i

f

224

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£55

DFTPP Sc&n 1425.43 ftin.

442N

275X

1 1SC

323 365 403L .L ./ i ... 1 1 . N i

-ne

100

•90

•60

70

•60

•58

-40

•30

•20

-€'304 35 v 4t'*J

603

MS Data Fi le: >G9049: :U3

Miac: DFTPP

>G9049142

File: >

m/z

38.0039.0039,9043.9049.0050.0051.0052.0055.0055-9057.0057.9060.906 J . 9 063.0064. 0065.0068-9070.0073.0074.0075.0076 . 1 077. 0078.0079. 0079.9080.9032.0587.0584. 0585.0536.0587.0587.959C.95-92.059?. 0594.0594.95

NRM

G9049 Scan #:

Int.

.6754.235.404

1. 086.423

12.61247.2902.329.247

1.6543.385• .219.508.675

1.836.286.827

58.868.259.423

4.4547.4282.11543.7432.8072.9822.5083.677.762.790.212.638.981.451.164.839.750

5.356.406. 137

m/z

98.0599. 05100.05101.05102.95103.95105.05107.05108.05110.05111.05112.05116.05116.95118.05122.05123.05124.05125.05127.05128.05128.95129.95131.05131.95132.85134.05135.05135.95136.95139.95140.95142.05142.95144. 05147.05147.95149. 05151.05151.65

n^A^Jfctrtr*" P*T 1 R 7^• UwOla^Wi * r **«*•**/

DFTPP

142 Retn. ti

Int.

33

1

1

121

283

8

1

453

191

1

2

12

.482

. 064

.336

.928

.722

. 081

.934

. 034

.799

.186

.761

.503

.640

.462

.683

.785

.407

.623

.600

.416

.575

.891

.500

.319

.159

.149

.543

.542

.623

.613

.242

.314

.382

.441

. 162

.171

.352

. 404

. 344

.224

m/z

151.85152.95154.05155.05156.05157. 15157.95159.15160.05161.05161.95165.05166.05167.05168.05168.95170.05170.95173.05174.05175.05176.15177.05178.15179.05180.05181.05183.95185.05186.05187.05188. 15189.05191.05191.95193.15196.05193.05199.05200. 05

me •

Int.

11

1

31

1

321

1103

31006

.234

.755

.560

.059

.333

.421

.471

.279

.660

.051

.331

.767

.775

.849

.338

.366

.162

.239

.414

.964

.333

.615

.670

.209

.126

.048

.113

.184

.472

.709

.231

.356

.752

.331

.387

.954

.169

.000

.444

. 4114

Date

5.43

m/z

201.65203.05204. 15205.05206.05207.05208.05211.05214.95215.95217.05218. 05221.05223.05224.05225.05226.15227.05227.95229.05231.05233.95234.95237.05241.05241.95243.05244.05245. 05246.00247.00249.10255,10256.10257. 10258.10259. 10265.10273.10

/Time: 11/15/89BTL* 1

Int.

.560

.5782.7054.71620.4342.865.623.657.262.548

5.592.800

6. 1431.18311.0483.029.272

4.148.638

1.074.384.294.359.399.314.551.590

9.4581.2651.529,309.3U1

44.5206.350.546

2.254.478.929

1.417

m/z

274. 10275.10276.10277.10278,10285.00293.10295.00296.10297.10303.10304.10314.10315.10316.10321.00323.10324.10327.10334.10341.10346. 10352. 10353.10354.20365.10366. 10372.20383. 10402. 10403.20421.15422.15423.15424. 15441.15442. 15443. 15444 . 15

5:00

Int.

3 . 45 >21.3662.7651.410.26?.279. ? 1 9.179

5 . 1 •; 4.755.6l':t.164.26'"'.418.349.194

1.341.339. 3?1-*

1.056. 2 S .-S.379. 4'-' -..396. 44.-,

2. 090. iv.1

.971

.2V 4

.289

.5 :•:•:

.443

.3^43.263. 7> '-

8.27859. 3 r*.10.871

9 "• *

604


Name: ......Misc: DFTPP

Operator: PT1575 Date/Time: 11/15/89 5:001

Filt >G9

320000-

240000-

200000-

iteeee-

120000-

aeea*-

40000-

0-

849 35.0-468.0 MU . DFTPPTIC

100 200 3d0 400 Sat) 630

... ,,-;..,,-!-!-

_____-f -ft , •, yiriTiiT'T I • | i i i rT T . t t T f . "»7 r-. . . ) i i . r T . . . . •!

96

0

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^

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0

605

flS Data F i l e : >G9062::U3

Nome: .................... Operator: PT1575Mi3c: DFTPP

Date/Time: 11x15/89 16:41BTL# 1

F:l« >C9Bpv Ob 2

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MS Data File: >G90b2::U3

Misc: DFTPP . BTL# 1

Fil« >G9

288060-

Mdeee^

0-

So2 36.J-4S0

• • • T • • • • i ' • • '5.0

.fl MIU. DFTPPTIC

20L* 360 430 583 frtftf-tee

•^0

^68

-5?

-40

608


Name: .................... Operator: CA3875rtisc: DFTPP

Date/T ime: 11/16/89 14:06BTL# 1

File >G9Bplf Qb 2

30000-

28000-

26000-

24000-

22000-20000-

•18000-

16000-.

14000-.

12000-

10000-

8000-

6000-

4000-

2009-

O-

0767

6

U5

560

9

0

j

J

77/

, 1U^100

1.

.1

27

167\

.kLi. i i150

1,

.2

99i

2

224

1

...130 25

55/

t t9

DFTPP Scan5.46

442X

275

323 365 403

L . 1» . L i .. . U . N 1300 350 400

150min .

j-ne

J-iee

-99

•60!J-70•60:,;50•

40•-30

-23•- 1 A•

'•*

609

1S Data

Name I

Fi le: >G9CI75: :

lisc: OFTPP

>G9075150

File: >

m/z

37.37.39.39.41.43.44.49.9.

• 1 .52.55.57.60.61.62.65.68.70.73.74.74.76.77.78,79.~>9 .

-6U .81.82.84.85 .86.90.92.92.94.98.

0090009000909000900000900090909000900000009000000000909095959595959505950505

U4

NRM

G9075 Scan #:

Int.

.229

.8104.322.522.393.615.282.410

12.65346.3182.5661.4853.804'.494.657

1.878.821

57.469.264

1.4014. 4687.6252.53844. 1582.8892.9692,3123.408.921.737.668.991.462.821.838

5.063.334

3. 157

m/z

98.9599.95100.95 '103.05103.95104.95105.95106.95107.95109.95110.95112.05115.95116.95117.95121.85123.05123.95125.05126.95127.95128.95129.95130.95132.95133.85135.05135.95137. 05140.95142.05142.85145.95146.95147.95148.95151.15152.95

CA3875 Date/Tima : 1 1x1 A/flQBTL# 1

14:06 -

DFTPP

150 Retn.

Int.

2.872.3621.749.542

1.2071.168.386

11.8501.773

27.4833.960.466.761

7.695.570.761

1.436.779.598

44.5973.26119.3431.641.330.254.497

1.513.664.654

2.118.751.508.362

1.3352.0971.467.407.702

m/z

153.95154.95155.95156.95157.95158.95159.95160.95161.85164.85166.05166.95167.95169.05171.95173.05173.95174.95175.95177. 05178.95179.95180.95185.05185.95186.95187.95188.95191.95192.95196.05197.95198.95199.95201.35202.95203.95

t ime :

In

.1.1...,.

1.,..

4.1...,,

1.,,

3.2.,

1.11.3.,,,.

3.100.6....

2.

t .

574238586431445337692099285810640068659313389490706579567789129031998349040003309699946876150000561407598529344

5.46

m/z

204.95205.95206.95207.85211.05215.85216.85217.85220.95222.85223.95224.95226.05226.95227.95228.95230.85234.85236.85241.75243.05243.95244.95245.90247.00249.00255.00256.00257.00257.90259.00265.00265.90272.90274. 00275.00276.00

Int.

4.62819.8992.688.706.890.417

5.629.741

7.0721.42611.1472.983.323

4.343.699.928.455.323.278.574.668

9.5511.3001.728.407.480

43.4076.231.508

2.350.400.911.233

1.3493.390

21.4852.914

m/z

277. 00277.90284.90292.90296. I'JO297. 00303.10304.00314. 00315.00316.UO323.00324. 00327.00334.00335.00341. 00345.90352.00353.00354. 00364.90365.90371.00372.00372.90382.90402. 00403. 00420.95422.05422.95424. 05440.95441 .95442 . 954*43 .95

Int .

1.544.243.327.372

4.969.668.643.229.303.612.379

1.885.339.410

1. 116.278.337.400.615.403.612

2. 131.316.184. 998.257.320.393.591.431.433

3.960. V6

10. 18471.2*313.6961.224

1S Data Fi le: >G9G75 : :U4

Name: .................... Operator : CA3875Miac: DFTPP

Date/Time: 11/16/89 14:06BTL# 1

Filt >C9

300000-

288800-

260000-

240000-

220000-

180000-

160000-

140000-

120000-

100000-

80000-

60000-

48000-

075 36.0-450

........w...

5.0

.0 ABU.

200

F^ __ J' 6!0

TIC300

w1 ?.'e

!,f

*

400

U8.0

orTpp500 600

\ ——— A.. _. . { ,

' 9'.0 ' lO'

-100

•98

0

•70

*»

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-40

:30

•20

:ie

0

611

IBSEMIUQLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Cont pact:

SAS No.:

Matrix: (soi I/water) WATER

Sample wt/vol: 1000. Cg/mL) ML


SOG No . :

Lab Sample ID: QC70087C


Date Received: lo

Moisture: not dec. dec





Di lut ion Factor : 1


108-95-2 ——————— Phenol___________________110111-44-4——————bis(2-Chloroethyl )ether____11095-57-8 ——————— 2-Chlorophenol____________110541-73-1 —————— -1,3-Dichlorobenzene________I 10lOifr-46-7——————1,4-Oichlorobenzene________110100-51-6 —————— Benzyl alcohol____________11095-50-1 ——————— 1,2-Dichlorobenzene________11095-48-7———————2-Methyl phenol_________ IIP108-60-1——————bis(2-Chloroisopropyl)ether_l10106-44-5 —————— 4-Methyl phenol____________I 10621-64-7-- — - — -N-Nitroao-d i-n-propylamine_I 1067-72-1------- — Hexach lo roe thane__________I 1098-95-3---------Nitrobenzene______________I 1078-59-1-- ——— ---Isophorone________________I 1088-75-5——————— 2-Nitrophenol_____________I 10105-67-9 ————— --2,4-Di methyl phenol_________I 1065-85-0 ——————— Benzoic acid______________150111-91-1- —— ----bis(2-Chloroethoxy)methane_I 10120-83-2 —————— -2,4-Dichlorophenol_________110120-B2-1 —————— 1,2,4-Tr ich lorobenzene_____I 1091-20-3 ——————— Naphthalene_______________110106-47-8 —————— 4-Chloroani line___________I 1087-68-3———• — ---Hexach 1 orobut ad ione________I 1059-50-7———————4-Chloro-3-me thy I phenol____t 1091-57-6 ——————— 2-Methyl naphtha lone________I 1077_47_4- —— —— --Hexachlorocyc1 opentadlene__I 1088-Q6-2---------2,4,6-Trichlorophenol______I 1095_95-4___._.___2,4,5-Trichloropheno1______15091-58-7———————2-Chloronaphthalene________t 1088-74-4-- —————— 2-Nitroani 1 ine____________150131-11-3 —————— -Dimethylphthalate_________I 102 08-96-8--------Acenaph thy lene_____________I 106 06-2 0-2--------2 ,6-D in i tro toluene________I 10

____ I

Q

tuIUIDIUiuIUIUtuIUIU!UIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU

FORM I SU -1 1/87 Rev,6i2

1CSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO

Lab Name: ETCNJ

Lab Code: Case No.:

Contract

SAS No.


Sample wt/vol: 1000. (g/mL) ML

Level: (low/mad) LOW

X Moiature: not dec. dec.

Extrect ion: (SepF/Cont/Sonc> CONT


i SDG No.:


Lab File ID: >G9041

Date Received: /o///'/£$


Date Analyzed: 11/14x89


CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or 'ug/Kg) UG/L

I99-09-2———————3-Nitroaniline____________15083-32-9———————Acenaphthene______________I 1051*28-5 ——————— 2,4-Dinitrophenol__________15010(^02-7——————4-Nitrophenol_________ ISO132-64-9———————Dibenzofuran______________110121-14-2——————2,4-Dinitro toluene________11084-66-2 ——————— Die thy Iph the late__________1107005-72-3 —————— 4-Chlorophenyl-phenylether_I 1086-73-7———————Fluorene__________________I 10100-01-6———————4-Nitroani 1 ine____________150534-52-1 —————— 4,6-Dinitro-2-methylphenol_15086-30-6- ——— ----N-Ni trosodiphenylamine CD_110101-55-3 —————— -4-8romophenyl-phenylether__I 10118-74-1- —————— Hexachlorobenzene_________11087-86-5 ——————— Pentachlorophenol_________15085-01-8-- ————— -Phenanthrene______________110120-12-7———————Anthracene________________11084-74-2 ——————— Di-n-butylphthalate________110206-44-0——————Fluor an thene_____________110129-00-0——————Pyrene___________________11085-68-7———————Butylbenzylphthalate_______11091-94-1 ——————— 3,3'-Dichlorobenzidine_____12056-55-3---------Benzo(e)anthracene_—H_______11Q218-01-9———————Chryaene__________________I 10117-81-7———————bis<2-Ethylhexyl)phthalate_110117-84-0——————Di-n-octy Iph the late________133205-99-2 —————— Benzo(b)f luo ran thene_______110207-08-9——————BenzoCk ) f luor an thene______11050-32-8 ———— — --Benzo(a)pyrene___________110193-39-5 ————— --IndenoCl,2,3-cd)pyrene_____11053-70-3 ——————— Dibenz Ca,h)anthracene______I 10191-24-2 —————— Benzo(g,h,i )perylene_______110

__ ________ ......______ -—-i


FORM I SU -2

IIDIUIUIU*IUIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUItuIUIUIUIUIUI_

O I 0

1/87 Rev


TENTATIUELY IDENTIFIED COMPOUNDS

ERA SAMPLE NO.

Lab Name:ETCNJ

Lab Code: Case No.:

Ma t r i x: (soil/we t•r)UATER

Sample ut/vol: 1000. (g/mL)ML

Level: (low/med) LQU



GPC Cleanup: (Y/N) N pH;

. INumber TICs found: _

Contract:

SAS No.: SDG No.:


Lab Ftlo ID: >G9041

Date Received: t

Date Extracted:10x11/89


Dilution Factor: /


CAS NUMBER

01. 14l'-78-602. >03.04. 2233-00-3

COMPOUND NAME

Acetic ac id, ethyl esterACETONE DIMERUNKNOWN1-Propene, 3,3,3-trichloro-

RT

5.156.547.949.14

EST. CONC

2702302613

Q

J3JJ

FORM I SU-TIC Pcv

TOTAL ION CHROMATOGRAHFiU >C9

1800000-

1600000^

1409900-

1200000-

1000000-

doooe*

600000-

400880-

200806-

0-

041 35.0-500.0 *mu. QC78887C ,QC78«87,Li

400 ' 800 1200 , 1600 , 2000

IS S1

S &lS"1 II I I

5 % 1 ^5Mn H ii" f i t l l l l **4 • A 2 i i ? i s* ' 4 ^ IIIsi s I? 1»• , * a T

I I * ~ * 5 L i

, | i I I " ! 1 *,"4 ' 8 ' 12 ' 16 ' 20 ' 24 ' 20 ' 32 ' 36 ' 40 ' 44

Data FUe: >G9041: : U5Name :Misc: QC70087C ,QC7QQ87 ,L_: M6 ,1000 ,2

Id File: IG0130::PFT i t l e : IFB/BNA, PP/BNALast Calibration: 891115 08:47


Quant Output File: *G9041::AQ

BTLtt 7

6 i 5

QUANT REPORT Page

perator ID: PT1575 QuantOutput File: ~G9Q41::AQData File: >G9041::U5ame :isc: QC70087C ,QC70097,L: M6 , 1000 ,2

*D File:- IG0130: : PFitle: IFB/BNA, PP/BNA

i_ast Calibration: 991115 08:47

1)3)5)

17)18)

^J2 J

K n vU >52)54)62 )65)67)72)72)

72)72 )73 )74)74 '74'74

Compound

*d4-l , 4-Dich lorobenzene2-FluorophenolPheno 1-D5N-Ni trosodi-n-propylamin

»d8-NaphthaleneNitrobenzene-05 ' SURR)

•*dlO-Acenaphthene2-Fluorob ipheny 1Fluorene2,4,6-Tribromophenol

*dlO-PhenanthreneDi-n -butyl phtha late*dl2-CfrryseneTerpheny 1-014b is(2-Ethylhexyl ) phtha labis(2-Ethylhexyl)phthalabis' 2-Ethylhexyl ) phtha labis(2-Ethylhexyl ) phtha labis' 2-Ethylhexy 1 ) phtha la

»d!2-PeryleneDi-n-octyl phtha lateDi-n-octyl phtha lateOi-n-octyl phtha lateDi-n-octyl phthalate

tC15

f

(

Cttttt

SURR )SURR)

SURR)

SURR)

SURR)eee -ee

Rev:

R.

10./• ,10.1'14.12.19.13.22.22.24.OAiO .

32.29.32** <£ •

32.33.33.33.36.33.34.34.34.

T.

70531743494193003737377037392 v370212923892132889

7 Quant Time:In jec ted at :

Di lut ion Factor :

Scantt

34513931943053142979970491991910171132141112641405141114431449148716091487150015051535

Area

25535536397241823744713

518146300636175698

335048311160667^07 /754771236654092

160153241544132^02

50^74_ •' 0212 661021442234

391115 09:23391114 21:40' •

1.00000

BTLtf 7

Cone

40465-t±40414041

6140•

40661tIJ

• .

-tT40tf.

£16

.00

.49,31

.00

.'50

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.00•**2-.00.27. V?

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. 0-^.") 1. . J..1 T

.26

Units

UG''MI_UG-'MLUG/MLUS MLUG'MLUG-'TILUG/MLUG/MLUU'"" 1 'L.UG/MLUG/MLUVJJ ' it—UG/UL.UG/MLUG-' rlLj ./"* r futtU1— " I 4i-^ . «h ' -|| 1 f

'JTJ "-U (s •• 1 LUS. "MLUG/ML•j\3- riL! ll~ ''Ml*- •" ~

• gc.-'nuUG/HL^

q

3933•901 T

94969993379696T7

9794COv f 245-

5?38•3-39*9•3Q'93

Compound is ISTD

6 16

REFERENCE STflMDflRQ SPECTRUMFiU >J7992 TERCET REFERENCE SPECTRflBpk Ob 9999 ' SUB NRM NOM

14919800-

0-4

^

10 ' 88 ' 120 160 203

Scan 217935 . 16 nun .

•180

. , , , , i —— n-r-r-i —— '-9240 230

SflMPLE SPECTRUM tBflCKCROUND iUBTRflCTEDlFii« >G904i QC78087CBpk Rb 16757 SUB

149

10000-; 43 -- 3S 104j.3 b' / x 135

u a ' / x '

x"

167X"

i . ;.40 30 120 1=0

.QC700S7

297X

206

,L:M6,

247\

240

10 :c»n 153534.39 mm.

265 2!3/ X

-100

•

. i . i i i • .280

SflMPLE SPECTRUM CUNOLTERED)F l l * >C9041 OC700Q7CBpk flb 16816

149

13000- 35 1044,3 69 , , 13SjT A .L. ...?',.. ' ... /

^

167L0 , , . . , . . . , . . . , . . . | . . . . . . . | . . . , .

40 90 120 160

.QC78097

297\

200

,L:n6,

247\

240

10 tc»n 153534.89 irtin.

2932/s X,

-190

•

-a296

Data File: >G9041s:U5 Quant Output File: /VG9041::«QName :Misc! QC70087C ,QC70097 ,L:M6,1000,2Quant Time: 991115 09:2? Quant ID File: IG013Q::PFInjected at: 391114 21:40 Last C a l i b r a t i o n : 991115 08=

Compound No: 74Compound Name: Di-n-octyl p h t h a l a t eScan Number: 1535Retention Time: 34.39 mm.Quant Ion: 149.Qrtrea: 422?4Concentration: 16,26 UG/ML-^alue: 98

617

Ftl# >G9041 QC70887C ,0079987 ,L 1(16 , 19 Sc4n 72Bpk fib 9999 SUB NRH 5.15 *in.

.10000-8996-6090-4000-

2080-

0-

43'

,,.,S\:30 35 40

X"

70

49 S3 55 59 V ,/ 74 99\ \ r.' *T. ,/ .r4- f i M 1 1 1 1 1 h \\ ' 1 1 n 1 1 ' ' ' 1 1 ' 1 1 ' 1 1 1 ' » i » " M i * ' ' i45 50 55 60 65 70 75 80 85 9

_-100

•39

-60

-40

-20

•03

Fil« NBS49K fte#tic *cid, «thyl »it*r Scan 757Bpk Ob 9999 0.08 nin.

10080-

8000-

6090-

4000-

2000-

0-

43

29\

1, .V '... ... r ... . ( .30 35 40

x-

v 7, .1 r ,. . . . , .... i .... ( .... ( .... ( ......... r . ... ( .... j45 58 SB 60 65 70 75 80 85 91

_-100

-00

-60

-40

•20

-03

Data File: >G9041::U5Name:Misc Data: QC70087C ,QC70087,L:M6,1000,2RT (min): 5.15Scan: 72Area: 3265441 Rank: 1Semi-quantitative Cone Cuncorrected):Semi-quantitative Cone C corrected ):

132.70 UG/ML265.59 ug-1

BTL# '

Calculated us ing Istd: d4-l,4-Dichlorobensene (i 10.70 minutes

1. Acetic acid, ethyl ester 83 C4H802

Sample file: >G9041 Spectrum *:Search speed: 2 Tilting option: S


1.

Prob. CAS * CON * ROOT K OK #FLG TILT S CON C_I R_I'J

52» 141796 2197 NBS49K 27 51 1 0 68 16 20 15

618

FiU >C9041Bpk Ob 9999

,8000-

4000-'

m'"is,

QC70087C ,QC70007(Lin6.10 SCATi 140SUB NRM 6.54 mm.

*/'

h

59

5«\ |

73 93 98 101 116V / / \ \ \

,

-Q9

-40

20 49 66 80 100Fil» NBS49K 2-P«nt»non«, 4-hydroxy-4-*»thy 1- Sc4n 2851Bpk flb 9999 0.80 mm.

8000-

4000- 3127 /0-Wri-i i i T i | i i i »

20 4

43

AJ.

5955 f 73 83 98 ,„, i fl2X...II. ?/ / N7>

-60

-48

0 60 80 100

Fil* NBS49K Hvdrop»roxid» , 1 , l-di«f thyl»thy 1 Scan 847Bpk Pb 9999

seeo-j4000-

0 ...... . T .,. .T-.

3115 2? // ( \ \

0 .00 mm .59

43

k

'55 73 89

/ N

•-e0•40

-a

Data File: >G9041::U5Name:Misc Data: QC70087C ,OC70087,L:h6t 1000,2RT Cmin): 6.54Scan: 140Area: 2358274 Rank: 2Semi-quant 11 a t ive Cone ( uncor rec t ed ) : 116.15 UG-''MLSemi-quantitative Cone C corrected ): 232.30 ug-"lCalculated using Istd: d4-l,4»Dichlorobenzene |3 10.70 minutes

1. 2-P*ntanone, 4-hydroxy-4-methyl-2. Hydroperox ide, 1,1-dimethylethyl

116 C6H120290 C4H10Q2

Sample f i l e : >G9041 Spectrum *:Search speed: 2 . Tilting option: S


1.2.

Prob

7820

CAS ••

12342275912

CON *

17901733

ROOT

NBS49KNBS49K

K

4334

DK #FLG TILT

4031

7136

CON C_I P_IU

451

55 1412

619

Fill >«9841 QC78087C ,QC70a87,Lll"16,18 Sc*n 289Bptc Ab 9999 SUB NRM 7.94 min.

ueao-

18000-

90ee-

3000-

7088-

6880-

5088-

4800-

3080-

2888:

1080:

8-

39/

J

K s

» ,

X ''*7 71

1 , . . . 1 1 . 1 i . 1 . > . , . f

5/

97 99 188

i/ \/\ r it48 SO 60 70 80 98 180 110

;-UO

•108

•98

fO

:7«

•60

**

"*9

•38

•20

•IB

'-9

Data File: >69041::U5Name :Misc Data: QC70087C ,QC70087,L:M6,1000,2RT (mm): 7.94Scan: 209Area: 322759 Rank: 11Semi-quantitative Cone Cuncorrected): 17.12 UG/HLSemi-quantitative Cone C corrected ): 26.23 ug/1Calculated using Istd: d4-l,4-Dichlorobenzene @ 10.70 minutes

BTL* 7

No PBM hits for this scan.

620

Fil# >C9041 QC70997C .QC70097 ,L iM6 , 10 Scan 269Bpk flb 9999 SUB NRn 9.14 nin.

.10000-

8000-

6900-

4000-

2000-

0-

10»

83\

U4AM145

100 200 300 400

_-100

-30

-60

-40

-20

-0

Fil» NBS49K l-Prop«n», 3 ,3 ,3-tr ichloro- Scan 6992Bpk flb 9999 9.00 min.

19090-

9000-

6000-

4000-

2000-

0-

1

83

-1, 4- If f || .

09r

m, r*"100 ' 200 ' 300 ' 400 '

-100

-80

-60

-40

-20

-0

Data File: >G9041: : U5Name :Misc Data: QC70087C ,QC70Q87,!_: H6 , 1000 ,2RT (mm): 9.14Scan: 268Area: 160283 Rank: 12Semi-quantitative Cone ( uncorrec ted ) :Semi -quant i tat ive Cone C corrected ):

BTL# 7

6.51 UG/'ML13.03 ug/ L

Calculated us ing Istd: d4~l,4-Dichlorobenzene |i 10. 70 minutes

1. 1-Propene, 3 , 3 ,3-1richloro- 144 C3H3C1?

Sample file: >G9041 Spectrum *: 268Search speed: 2 Tilting option: S No. of ion ranges searched:

Prob. CAS « CON * ROOT K

1. 52» 2233003 11547 NBS49K 34

DK ttFLG TILT S CON C_I R__IU

79 2 0 79 19 20 14

621

IBSEMI VOLATILE ORGAN ICS ANALYSIS DATA SHEET

i Ir-Ln.

Lab Name: ETCNJ . .

Lab Code: Case No.:



Level: (low/mod) LQU




Contract:

SAS No.: SDG No.:


Lab File ID: >G9Q68

Date Received: 10/t8/89




-_-*


108-95-2 —————— -Phenol_____________________lll-44-4--------bis(2-ChloroethylJether_____95-57-8 ——————— 2-Ch lorophenol____________54l-73-l--------l,3-Dichlorobenzene________106-46-7--------1,4-Dichlorobenzene________100-51-6 ——————— Benzyl a Icohol_____________95-50-l---------l,2-Dichlorobenzene________95-48-7————————2-Methylphenol_____________108-60-l--------bis(2-Chloroisopropyl)ether_106-44-5--------4-Methylpheno1_____________621-64-7--------N-Nit roso-d i-n-propylamine__67-72-l---------Hexachloroe thane___________98-95-?---------Nitrobenzene________________78-59-1---------I sophorone_________________88-75-5---------2-Nitrophenol______________105-67-9--------2,4-01methyl phenol_________65-85-0---------Benzoic acid______________lll-91-l--------bis(2-Ch1oroethoxy)me thane__12Q-83-2------~-2,4-Dichloropheno1__________12G-B2-l--------l,2,4-Tr ichlorobenzene_____91-20-3---------Naphthalene_______________106-47-8--------4-Chloroani1 me____________87-68-3---------Hexachlorobutadicne________59-50-7---------4-Chloro-3-methyIpheno1____91-57-6---------2-Methylnaphthalene________77-47-4---------Hexachlorocyclopentadlene___38-06-2---------2,4,6-Trichloropheno1______95-95-4---------2,4,5-Trichlorophenol______91-53-7---------2-Chloronaphthalene________83-74-4---------2-Nit roani 1ine_____________131-ll-3--------DimethyIphthalate__________2 OS-96-8--------Acenaphthylene_____________606-20-2--------2,6-DinitPOtoluene_________

101010101010101010101010101010105010101010101010101010501050101010

Q

FORM I Sv -1 1/87 Rev.

622

• 1CSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Cont ract:

SAS No.:





Extract ion: (SepF/Cont/Sonc) SERF


SDG No.:


Lab F i l e ID: >G9068/3

Date Received: lQ/t?/39



Dilut ion Factor : 1


I 1) - Cannot be separated from Dipheny1 amine

FORM I SU -2

Q

99-09-2 —— —83-32-9 ———— -51-28-5 ———— -10tJ-02-7 ——— -132-64-9 ———121-14-2 ——— -84-66-2 ———— •7005-72-3 —— -86-73-7 ——— --100-01-6 ——— -534-52-1 —— -86-30-6-- —— •101-55-3 ——— -118-74-1 —— --87-86-5 ———— -85-01-8 ———— -120-12-7 ——— •84-74-2 ———— -2Q6-44-0 ----129-00-0 —— -•85-68-7- ———91-94-1-----56-55-3-----218-01-9 ——— •1 1 "7 Q 1 "71/-D l-/----117-84-0 ———205-99-2 ———207-08-9 ———50-32-8- — —193-39-5 — —53-70-3- —— -191-24-2- ——

----3-Nitroanil ine----Acenaphthene----2 r4-Dmitrophenol----4-Nitrophenol----Dibenzofuran----2 ,4-Dinitrotoluene----Diethvlphthalate____4_Ch lorophenyl -pheny let hep _----Fluorene____4_Nitroani 1 me- — -4,6-Dmitro-2-methylpheno 1 _----N-Nitrosodi pheny lam me (1 ) __----4-Bro mo pheny 1 -pheny le the r----Hexachlorobenzene----Pentachlorophenol,----Phenanthrene----Anthracene , ,----Di-n-butylphthalate ,_„„„,„„„.„„----Fluoranthena----P-jrene----Butylhanzylphtnalata „_._----3t3'-Dichlorobenzid me,,...,,-___B»nTo(a Janthracene.,..,.,----Chrysene— --bisC2-Ethylhexyl )phthalate----Di-n-oc ty Iphtha late ,_._,.----BanzoChJf luo ran thane____Benzo(U)fluoranthene----BenTota )pyrena ,..,.,.,„,„„..,„„----Indeno(1.2.3-cd)D«jrene----Dihenzta .hJanthracene----Benzo (g ,h , i )perylene

11501101501501101101101101101501501101 101 101501101101101101 1011012G1101101101101 10110nonono110i

iIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU1

i/s



ERA SAMPLE NO.

Lab NameiETCNJ

Lab Code: Case No.:

Ma t P i x: (soil/wa tor)WATER

Sample wt/vol: 1000. Cg/mDML

Level: C low/meet) LOUi

S Moisture: not dec._____f dec.___

Extract ion: CSepF/Cont/Sonc) SEPF


Number TICs found: I

Cont ract:

SAS No.: SDG No.:


Lab File ID: >G9068

Date Received: 10/W/89



D i l u t i o n Factor: I


CAS NUMBER

01.

COMPOUND NAME

ACETONE DIMER

FORM I SV-TIC

RT

6.45

EST. CQNC

34

1/8

Q

J

7 Rev.

624

TOTAL ION CHROMflTOCROMFlit >69068

1200000-

1100800-

100000*

900000-

880088-

700000-

600000-

588880-

480000-

388000-

200000-

100000-

4

36.0-500.0 MU. OC 7 089 1C ,QC70991,LiTIC

1l

i•if

40,0 , 00,8 , 1209 , 16,88 , 2888

? ."

1 i1C

[

iE JSg i*

t §

ifI!

* .! ;i! ik

. ':'he>

' *& "5

i •}{" ? ,1 \ S

I J; I 1 I** * t £ f*| « I ?

8 ' 12 ' It 28 ' 24 ' 20 ' 3'2 ' 3*6 ' 40 ' 44

Data F i l e : >G906B::U?Name:Misc: QC70091C ,QC70091,L:H6,1000,2

Id File: IG013Q::PFTitle: IFB/BNA, PP/BNALast Calibration: 891116 12:11



BTL#34

625

Operator ID: PT1575Output File: 69068: 0Date File: >G9068::U3Name:Misc: QC70091C ,QC70091,L:M6,1000,2

ID File: IG0130::PFTitle: IFB/BNA, PP/BNALest Calibration: 891116 12:11

QUANT REPORT


Di lut ion Factor

Page J

891H6 12:41891115 21:40

1 . 0 0 0 0 0

BTL*34

Compound R.T . Seen* Area Cone Units

1)3)5)12)

32)36)49)50)52)54)62)65)67)73)

»d4-l,4-Dichlorobenzene 10.69 345 2504422-Fluorophenol CSURR) 7.46 186 248723Phenol-05 (SURR) 10.12 317 201201N-Nitrosodi-n-propy lamine 12.40 429 39007

«d8-Naphthalene 14.47 531 524559Nitrobenzene-05 CSURR) 12.40 429 261676

•dlO-Acenephthene 19.92 799 1867132-Fluorobiphenyl CSURR) 17.99 704 283085Diethyl phthelate 21.69 886 5555Fluorene 22.36 919 31132,4,6-Tribromophenol (SURR) 22.36 919 46698•dlO-Phenenthrene 24.35 1017 167193Di-n-butyl phthelete 26.66 1131 4153•d!2-Chrysene 32.35 1411 80686Terphenyl-014 CSURR) 29.37 1264 117155

»d!2-Perylene 36.36 1608 62052

* Compound is ISTD

40.0054.6133.70

40.0036.2040.0036.44-i.07

UG/MLUG/MLUG/MLUSi'ML-UG/MLUG/MLUG/MLUG/ML•US/ML

63.58 UG/ML40.00 UG/ML.•Iff UC'ML

40.00 UG/ML51.97 UG/ML40.00 UG/ML

897693

949598989384939896989386

626

F i l » >C9068 QC70091C .QC70091 ,L tM6 , 10 SCAH 136Bpk flb 9999 t SUB HRM 6. 45 min.

8009-

4000-

0-

43

41\

. .1. h

5956 ^ 73 10

.. . ...,Ni.l ... .* S / ,_ |,28 ' 40 ' 60 ' 80 ' 10'e

•69

-40

-0

F i l » NBS49K 2-P*ntinon* , 4-hydrox'/-4-fne th'.'l - t c an 2851Bpk flb 9999 6 .00 min .

8000-

4000-

43

27 *1-; 3 1"S. * '1.1 1. ... ),

59Sf " 6.a 73 33 ?s - 19:

...>,.! . .-•' -"' . f . > .. i'1 1 . , ( : , 1 1 | 1 1 . . | 1 1 . 1 | 1 1 , . 1 1 , | 1 . , 1 | > . . , | . , : . 1 •

20 40 60 SO 100

-SO

-40

Fil» NBS49K Hs>drop*roxid«, 1 . 1 -dim* thy I *thy 1 Scan 347Bpk flb 9999 13.00 mm.

59

&000-

4000-

.-'' i43

4127 i. \

IS S, V \..' \ . . . I . I ,

57 ;73 8 '3

,. . , . " l l ,• 20 ' 40 ' c.'0 ' 30 ' 100

•«0

-40

-0

Data File: >G9063::U7Name :nisc Data: QC7QO°1C .QC^OO'?! ,L:M6,1000 ,2PT 'min): 6.4?Scan: 176hrea: 1009371 Rank: iSeen i-quant i ta t ive Cone ', unc o r rec t ed ') ' 4 2 . 2 2 U ^ f l LSemi-quan t i t a t i ve Cone (. corrected :' : 84.4? ug 'ICalculated using I s t d : d4-1 ,4-D ich lorobenzene |I 10.o9 minute*

1. 2-Pentanone, 4-hydro•y-4-methyI-2. Hydroperoxide, 1 , i-dimethy1e thy1

116 C6H120290 C4H1002

Sample Mle: -GQ063 Spectrum ^:Search speed: 2 T i l t i n g o p t i o n : S

- OMo. of ion ranges searched: 46

Prob. HAS 0 COM ft POQT

127422-T, o i •-> r'BS 4° I

Ok ILT %

n "

CON C_I R_IU

6 42 141 ? 12

627

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:



Level: Uow/med) LOLJ




Cont ract:

SAS No.: • SDG No.:


Lab File ID: >G9051

Date Received:



Dilution Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or *ug/Kg) UG/L

i na-95-9-___111-44-4 —— -95-57-8 ————541-73-1 ———106-46-7 ———100-51-6 ———95-50-1 ————95-48-7 ————108-60-1 ———106-44-5 ———621-64-7 ———67-72-1 ————98-95-3 ————78-59-1 ————88-75-5 ————105-67-9 ———65-85-0 ————111-91-1 ———120-83-2 ———

91-20-3 ————106-47-8 ———Q*7_AQ_'3_____

59-50-7 ————91-57-6 ————77-47-4- ———

Q C OR Ay 7-y v-4-----o 1 _c;fl_'7__-._-88-74-4 ————131-11-3 ———208-96-8 ———606-20-2 ———

Dl*_«-t 1

----bis(2-Chloroethvl )ether— — 2-Ch lorophenol __ .----1.3-Dichlorobenzene——— 1 r4-Dichlorobenzene „— --Benzyl alcohol-- — 1.2-Diehlorobenzene—— -2-Methylphenn 1 _, _----bisC2-Chloroisopropyl)ether__----4-Met hy Ipheno 1 „„,——— N-Nitroso-d i-n-propy lamine _----Hexachloroethane----Ni trohenzenB_ — _ Isophorone----2-Ni t ropheno 1 __ .— --2 ,4-Di methyl phenol „„._„,....,„, . ,.----Banzoie acid----bis(2-Ch loroethoxy) me thane ______9 -Dichlorophanol----IjS^-Triehlornhenzene_ _ _ _ Naphtha lana-_-_4-Chloraani 1 i"«— --Hexachlorobutadiene- — -4-Chloro-3-methylpheno 1 ________9-M«thyl naphtha lane----Hexachlorocyc 1 open t ad i one __—— __9 JA JA-Triehloroph«nol___-•? r<i;5-Trieh loropheno 1--__9-rhlnrnnaphthalena m nn .„.„„„..----2-Nitroani 1 ine----Dimethwlphthalate- - - - Ac anaphthylana----SjA-Dinitrotoluene _IIM

11101101101101101101101101 10! 10110110no110110110150110110110110110no110no1101101501101501101101101

1IUIUIUtuIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU1

FORM I S"J -1

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Ma t r i x: (soil/wa tor) WATER


LeveI: C1ow/med) LOW


Extract ion: CSepF/Cont/Sonc) CONT


Cont ractI

SAS No.: SDG No . :



Date Received:



Di lu t ion Factor : 1

CAS NO. COMPOUNDCONCENTRATION UNITS:Cug/L or ug/Kg ) UG/L

99-09-2 ——————— -3-Nitroani 1 ine____________83-32-9----———Acenaphthene______________51-28-5- —— -----2,4-Dinit rophenol_________100-02-7--------4-Ni trophenol_______________132-64-9——-----Dibenzofuran______________121-14-2--- — ---2,4-Dmi trotoluene_________84-66-2 ——————— Diethylphthalate__________7005-72-3-------4-Chlorophenyl-phenylather_86-73-7—-------Fluorene__________________100-01-6--------4-Ni t roam 1 me____________534-52-1 — ------4,6-Din itro-2-methyIpheno1_86-30-6---------N-Nitrosodiphenylamine Cl)__101-55-3--------4-Bromophenyl-phenylether___118-74-1--------Hexachlorobenzene_________87-86-5---------Pentachlorophenol_________85-01-8---------Phenanthrone______________120-12-7——————-Anthracene________________84-74-2---------Di-n-butylphthalate________206-44-0--------Fluorantnene________________129-QO-0--------Pyrene___________________85-68-7---------Sutylbenzylphtha late_______91-94-l---------3,3'-Dichlorobenzid me_____56-55-3---------BenzoCa)anthracene__________218-01-9--------Chrysene___________________117-81-7--—----bis(2-Ethylhexyl)phthalate__117-84-0—------Di-n-octylphthalate________205-99-2--------Benzo(b)fluoranthene_______207-Q8-9--------Benzo(k)fluoranthene_______50-32-Q---------Benzo(a)pyrene____________193-39-5 —— ———— Indeno< 1,2 , 3-cd )pyrene______53-70-3---------DibenzCa,h)anthracene______191-24-2--------Benzo tg ,h ,i)perylene________

5010505010101010105050101010501010101010102010101010101010101010

( 1 ) - Cannot be separated from Diphenylamme

FORM I SU -2

!UIUIUIUtuIUIUIUtuIUIUIUIUIUIUIUIUIUIUIUIUtuIUIUIUIUIUIUIUIUIUIUI

1/87 Rev

629

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

Lab Name:ETCNJ

Lab Code: Case No.:

Matrix: (soi I/water )UJATER

Sample wt/vol: 1000. Cg/mDML




GPC Cleenup: (Y/N) N pH:___

i .Number TICs found: ty

Cont ract:

SAS No.: SDG No.:


Lab File ID: >G9051

Date Received:



Dilution Factor: _ /


CAS NUMBER

01. 141-78-602.03.04.

COMPOUND NAME

Acetic actd; ethyl esterACETONE DIMERUNKNOWNUNKNOWN

RT

5.106.448.907.84

.

EST. CONC

3901102014

Q

JJJJ

FORM I SU-TIC

TOTAL ION CHRONATOCRAMFii« >cg

1400600-

1200000-

1006600-

800000-

600006-

400008-

200666-•

cu9~

651 35.0-500.6 *»u. QC70092C ,QC70092,LiTIC

, 40» , 000 t 1200 , 1600 , 2006

I I

8 ^^ >•••

|T | » ^ g-

} J A i fi5 gJ ^B I 9 ,g- B • i tt

1 1^ S T Co ' '

'* i '' '• I 'f '! ; ." " .i i! !: I i

ik 5 -f ? £« 1 i" « 3

l^ II 7 T ?4 ' ' 8 12 ' 16 20 ' 24 "2'e ' 32 ' 36 ' 49 ' 44

Data File: >G9091::U3Name:Misc: QC70092C ,QC70092 ,(_: M6 ,1000 ,2

Id File: IG0130::PFTitle: IFB/BNA, PP/BNALast Calibration: 89111? 12:26



BTL*17

631

Operator ID: PT1575Output File: *G9051i:AQData File: >G9051::U3Name:Miac: QC7Q092C ,0070092,L:M6,1000,2


Compound

QUANT REPORT

Quant Rev: 7 Quant TimeIn jected at

Di lut ion Factor

Page 1

991115 13:07891115 06:18

1.00000

BTUU7


1)3)5)12)

32)36)50)52)54)65)67)73)

*d4-l ,4-Dichlorobenzene2-Fluorophenol CSURR)Phenol-05 CSURR)N-Nitrosodi-n-propylamine

»d8-NaphthaleneNitrobenzene-05 CSURR)

*dlO~Acenaphthene2-Fluorobiphenyl CSURR)Fluorene2,4,6-Tr ibromophenol CSURR)

*dlO-Phenanthrene»d!2-ChryseneTerphenyl-Dl4 CSURR)

»d!2-Perylene

10.7.10.12.14.12.19.17.22.22.24.32.29.36.

6243103340338794312930283231

346189320430532430801706921920

1019141212661610

24055930926640871634666471802229053168640229501

21Q232206127020341455566918958

406968-t*40354032

5040405840

.00

.53

.50

.00

.29

.00

.2944**.01.00.00.78.00

UG/MLUG/MLUG/MLUflj'MLUG/MLUG/MLUG/MLUG/MLUC-'MUUG/MLUG/MLUG/MLUG/MLUG/ML

888092

94959999flQ

9597989299

* Compound is ISTD

632

FiU >G905lBpk flb 9999

@@0$-

4000-

Z 5

QC70092C ,QC70092,1_:M6J1Q Scan 74SUB NPM 5.10 mm.

43

42•.. «•' /°;3 8^ee

•eo-40

•A30 35 40 4'S 50 55 ' 60 65 ' >'0 75 S0 85 90


S000-

4000-

©-5

29

ficttic icid, *thuV *st*r Icin 75?O .00 mm .

I?/ 42

' \ x

61 70 73jl ,' ,- • 33,i ( •: -f30 35 40 45 5 O 55 cO & 5 70 75 88 c, 5 V

-88•

-ea

FiU HBS49K Propanoic *cid. 2-m«trwl- Scan 756Bpk Qb 9999 O.OO mm.

Jsoeo-4090-

-0-1

t;7 •"' 29 33/ \

.1 , .',1.

43f _ I

I

1

7355 60 / 0047 ', i 7 1-' 38

. 1 ! .\ f. f\.

-80

-025 • 30 35 45

Data Fi 'G9051: : U7

r i isc O a t a : QC~1C092C .OC7Q092 ,L : M6 , 1000 ,2PT ' m m * : ? . iGScan : 74Mr ea : •*?4J<4£ 7 Rank : iSem i -qjan t i t at i vc Cone '. uncor rec t ed ) : i'5?.43 Ur-'MLSe (<~-. i - q u a n t i t a t i ve Cone '. corrected ) : 736.96 u g '' 1C a l c u l a t e d uiinq !=td: d4-l, 4- Oichloro benzene jTi 10.62 minutes

BTL*!1

'-ic e t i c s c i d , ethyl e .«• * e rFropanoic acid, 2-methyl-

33 C^H80298 C4H3Q2

Sarnp 1- f i l e :>earch speed: 2

Spectrum #:T i 1 t i n g op t ion: ^^o . of ion ranges searched

Prob .

i.

CAS * CON

21

OOT

21

OK

46c'5

TILT COM C_I P_

1617

633

\

F1U >C90S1 - QC70092C ,OC70092tLiH6 , 10 Scftn 140Bpk flb 9999 , SUB NRtl 6.44 min.

.10000-

9000-

6000-

4000-

2000-

0-

43

j

S9

j101/ 212 258

. / J. \' N1 40 ' 8*0 ' 120 ' l40 ' 200 ' 240

_-100

•ee0

-40

-20

-0

FiU NBS49K Hydrop»roxid* , 1 , 1-dihtthyUthyl Scan 647Bpk Ob 9999 0.00 min.

10000-

8000-

6000-M'4000-

2000-

0-

43/

31

•1 f1' JII 89..•Hi . f

• 40 ' 30 ' 120 ' 160 ' 200 ' 240

-100

-60

-40

-20

-0

Data File: ;G905i::U3Name:Mi3c Data: OC70C92C ,QC70092 ,!_: M6 ,1000 ,2RT Cmin): 6.44Scan: 140Area: 128819? Rank: 2Semi-quantitative Cone -.uncorrec t ed ' : 54.86 UG.'-'MLSemi-quantitative Cone C corrected ): 109.71 ug'lCalculated using I s t d J d4-1 ,4-Oichlorobenzene |B 10.62 minutes

BTL#1'

I. Hydroperox ide, 1 .1-d imethylethy1 90 C4H10G2

le f i l e : 'G'3051 Spectrum #:Search speed: 2 T i l t i n g option: '3

140No..of ion ranges searched:

Prob. CAS # CON # ROOT K OK #FLG TILT % CON C_I P_I"

25 75912 1773 NBS49K 3** 31 1 0 37 50 7 12

634

Fil* >G90St QC70092C , QC76092 ,L :H6 , 10 $c»n £61Bpk flb 9999 SUB NRM 8.90 min.

43 *l

3 i! «;s 1 331 / 1 ' 103

' 49 ' 80 ' 120 ' 160 ' 200FlU NBS49KBpk Pb 9999

l-Prop»n«, 1-chloro-j, (£J- Sc»n 3450 .00 min .

41

76 "49 X. "8 . ;

...../ ... ...f" ^' 40 ' 80 ' 120 ' 160 ' 200

FtU NBS49KBpk flb 9999

: 2?

l-Prop»n», l-ehloro- 2c*n 3433.00 min.

41

7t, f49 79 t

.../„. ...... •..,.i-' L>40 83 120 163 230

FlU NBS49KBpk Pb 9999

j 26

l-Prop*n#, 2-chloro- Cc *n 3460.00 min .

41

76 t61 "^ 79 f

0 .,¥,,r,-ri ! . . . ,• . . . , . . . , , , , , . , . , . , . , . , . j . . . , . . ~40 80 120 160 200

Data File: >G9051::U3Name :Misc Data: QC70092C ,QC7Q092,L:M6,1QOO,2RT (mm) : 8.90Scan: 261Area: 236161 Rank: 3Semi -quant i tat ive Cone f uncorrec ted J : 10.06 U'j.-'MLSem i -quan t i t a t ive Cone ( corrected ): 20.11 ug/'ICalculated using Istd: d4-1 ,4-Dich1orobenzene g 10.62 minutes

BTL#1!

1. 1-Propene, l-chloro-; C E)-2. i-Propene, 1-chloro-7. 1-Propene, 2-chloro-

76 C3H5CI-6 C7H5C176 C7H9C1

ample f i l e : >G9051 Spectrum #:r!rch ^pe*d: 2 T i l t i n g option: S

261Ho . of ion range*, searched: 46

Prob CAS # CON

''0216PC--03 2

? 0 g 1-? 0 9 1

ROOT K DK ttFLG TILT

NBS4-3K 4o

con

40 "53 17 17

635

FH» > 09051Bpk fib 9999

11000-

10000

?000

3000

7000

6000

5000

4000

?000-

1 -300-

0- 1

43

1, 50i

1, ...II. 1

'

i40

QC70092C ,QC70092,LlM6,10 Scan 209CUB NRM 7.84 mm.

35X

6? 71

,, 1 .. l/

s' ^Q 104 112 136

f. . ..,<../ /• i • • • • - • • i • - - • i • - - • i • • - - i • • , • - i •60 30 100 129

rl!0

-100

™

-ee

170

0

•50

-40

•30

lie

Data File: >G90?1::U3Name :Misc Data: aC70Q*2C .QC^O 092 ,L : M6 , 1000 ,2PT f mm. : "'.34Scan: 209Area: 1672?? Rank: '5Sem i-quan t i t a t we Cone ( uncor rec t ed ;> : 7.12 J'j'-'MLSem i -quan t i t a t i '.-e Cone ( corrected ) : 14.24 ug ' 1C a l c u l a t e d using Istd: a4-1 .4-Di ch lorobenzene |Ji 10.62 minutes

6TUU

Ho PBtl ' - t i ts , for t h i s scan.

636

ERA SAMPLE NO

Lab Name: ETCNJ

Lab Code: Case No.:




H Moisture: not dac. dec.



Contract:

SAS No.: SDG No.:

Lab Sample ID: CA1907CS


Date Received: {o/



D i l u t ion Factor: 1


108-95-2 ———— •111-44-4 ———— -95-*7-8 ————— -541 -77- 1----..106-46-7 ———— -100-51-6 ———— •99-90-1 ————— -95-48-7 ————— -108-60-1 ———— •106-44-5 ———— -621-64-7 ———— •67-72-1 ————— -98-95-3 ————— -78-59-1 ————— -88-75-5 ————— -105-67-9 ———— -65-85-0 ————— •111-91-1 ———— -120-83-2 ———— •

91-20-3 ————— •106-47-8-™*----87-68-3 ————— •99-90-7 ————— •91-57-6 ————— •77-47-4 ————— •

95-95-4 ————— •91-58-7 ————— -88-74-4 —————131-11-3 ————208-96-8 ———— -606-20-2 ————

•--Phenol•--bia(2-Chloroethyl Jet her ____---2-Ch lorophano 1' — 1 ,3-Diehlorah.anzane _MII---1,4-Dichlorohanzene•--Benzyl alcoho 1 ,,.__ ,—— Ir2-Dich lorobanzene- — 2-Methvlphenol— -bis(2-Chloroisopropyl)ether_---4-Methy Ipheno 1—— N-Ni t roso-di-n-p ropy lam ine _•--Hexach loroethane ..,...„,_.,— -Ni t robenzene— - Isophorone. — 2-Nitrophenol IMII.--2 ,4-Dimethylphenol ._—— Banzai c acid imi—— b ie<2-Ch lor oethoxy )me thane—— 2,4-Diehlornphanol—— Ij.2r4-Trieh larnhanzane—— Naphthalene ...,.--4-Chloroan i 1 ina __.„_.. — — Mavaeh larohut*d i ana— -4-Ch loro-3-methy Ipheno !_____—— 9-M» thy I naphtha \mnrn _—— Hexach lorocycl open t ad iene __—— 9 jAjA-Tr iehlorophanol---2r4.S-Trieh loroohenol—— 2-Chloronaphthalane _.--2-Nitroanilina—— Oimethylphthala t a _,.,_., _---Acanaphthy lana— -9 pA-ninitrntnlu«n«

140101601079101010101087101010101052101080101010160101010521052101010

11IU"1 * *IU1IUIUIUIUIU1IUtuIUIUIUIUIUIU1IUIUIU1IUIUIUIUIUIUtuIUIU1

FORM I SU -16371/87 Rev

1CSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Nama: ETCNJ -.

Lab Coda: Caaa No. :

Matrix: Caoi 1/watar ) WATER

Sampla wt/vol: 960.0 Cg/mLJ ML

Lava 1 : (1 ow/mad ) LOW

Contract:

SAS No.: SDG No.:

Lab Sampla 10: CA1907CS

Lab Fila ID: >G9077

Data Racaived:

tloiatura: not dac. dec.

Extract ion: (SapF/Cont/Sonc ) CONT

GPC Claanup: (Y/N) N pH:

Data Extractad: 10/11/89

Data Analyzed: 11/16/89

Di lution Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or 'ug/Kg) UG/L

99-09-2———————3-Nitroani1 ina____________83-32-9- —————— Acanaphthana_____________51'<-28-5———————2,4-0 in itrophanol_________lOfc-02-7———————4-Ni t rophano 1__________'132-64-9 —— — —— Dibanzofuran ______„_____121-14-2——————2,4-Dinitrotoluana________84-66-2———————Diathyiphthalata__________7005-72-3 —————— 4-Chlorophenyl-phanylethar_86-73-7———————Fluor ana_________________100-01-6 —————— 4-Nitroani 1 ina____________534-52-1 ————— — 4,6-0in i t ro-2-mathylpheno 1_86-30-6———————N-Ni troaodiphany lamina (1)_101-55-3—————--4-Bromophanyl-phanylathar__118-74-1 —————Haxachlorobanzana^._______87-86-5———-———Pantachlorophanol^________85-01-8-——————Phananthrana __________120-12-7——————Anthracana_______________84-74-2 ——————— Di-n-butylphthalata________206-44-0-——--—Fluoranthana__________129-00-0---———Porana _________85-68-7—---———Butylbanzylphthalata______91-94-1---——---3,3 '-Dichlorobanzidina_____56-55-3——————•-Banzo(a)anthracana_________218-01-9——————Chryaana_________________117-81-7——————bia(2-Ethylhaxyl)phthalata_117-84-0 —————— Di-n-octylphtnalata________205-99-2————-—Banzo(b) f luoranthana______207-08-9--——---Banzo(k)fluoranthana_______50-32-8—•——--—Banzo(a)pyrana_^________193-39-5——————Indano(l,2,3-cd)pyrana_____53-70-3--————-DibenzCa,h)anthracana______191-24-2 — --———Banzo(g,h,i)parylana.______

528752100107510101052521010101601010101081102110101010101010101010

(1) - Cannot ba separated from Diphanylamina

FORM I SU -2

U

IUIIUIUIUIUIUIUIUIUIIUIUIUIUtIUIUIUIUIUIUIUIUIUIUIUIU

1/87

TOTBL ION CHftOHATOCftRHrue >««77 35.e-5ee.ft

2600000-

2400000-

2200000-

2000000-

1800000-

1 60000*

1 400000-

1200000-

1000000-

800000-

600000-

400000-

200000-

1

J

•

•

ir

*H^

:.;K-'

Ii

E i

| I

I

i? ;§ ;'i !I

uu.

. *l

1!ik ,4

A

is

iiii*-

4 8 12 16

noi vn7r*^ Qf*7BBB7 i *ai^nfcTv i^ -A lVWVvWi f t W i rTIC000 , 1200 , 1600 , 20,00

1.i[!>[ i

I • »£i 1

i '3 * ^ iiiTJ. I \i ? ?

20 ' 24 ' 20 ' 32 ' 36 ' 49 ' 44

DataNama:

>G9077: :U4 Quant Output File: ^G9077::AQ

flisc: CA1907CS,QC70087,L:M6,960,2



BTL* 3

639

Operator IDt CA3875Output Fila: *G9077::AQData Fila: >G9077i:U4Same:1i»c: CA1907CSIQC70087,L:M6,960,2

ID Fila: IG0131::PFTit la: IFB/BNA, PP/BNAL.ast Calibration: 891116 16:06

Compound

QUANT REPORT

Quant Rav: 7 Quant TimatInjectad at:

Di lut ion Factor:

Paga 1

891116 16:23891116 19:70

l.OOOOQ

BTL* 3

R.T. Scant Araa Cone Unit*

1)3)5)6)6)7)9)'

W 9)10)12)12)17)18)24)31)32)36)43)46)47)y U >52)54)59)63)

*S 64)65)67)73)

*d4-ll4-Dichlorobenzane2-Fluoroph.no! (SURR)Phenol-05 (SURR)Phano 1Phanol2-Chlorophenol1 ,3-Dichlorobanzene1 ,4-Dichlorobenzene1 ,2-DichlorobenzeneN-Nitrosodi-n-p ropy laminaN-Nitrosodi-n-p ropy lamina

*d8-NaphthaleneNit r'obanzena-D5 (SURR)l,2,4*>Tr ich lorobenzanap-Chloro-m-crasol

*dlO-Acenaphthana2-Fluorobiphenyl (SURR)Acenaphthana2 , 4-Din it ro toluene4-Ni trophenolFluorene2,4,6-Tribromophenol (SURR)

*dlO-PhenanthrenePentach lorophanolFluoranthenePyrene

*dl2-Chry«aneTarphanyl-D14 (SURR)*dl2-Perylen«

10.7.10.10.10.10.10.10.10.12.12.14.12.14.16.19.17.19.20.20.22.22.24.23.

28.32.29.36.

6148141823166565651432383230518390936666272524985353232724

344190321323325322346346

419

529428525634797702802838838917916

10141001

1225140712611604

288384421058499893445519

414597OR nooz.250986

194291557636313993720192300862378172421193986143388266539723578

6503118729066636

1 99HT5ATTO y y1998337484412348149482

40.74.70.68.•

77.

38,

41,

40.41.38.78.40.37.41.35.48.

77.40.75.

39.40.62.40.

00537638•99-62-M-07

80

007228850059839228

I f W

610045•**-03006900

UG/MLUG/MLUG/MLUG/ML

UG/ML

UG/MLUS/I1LUG/MLUSi'MtUG/MLUG/tIL

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUS'-ttLUG/MLUG/MLUG/MLU6''MLUG/MLUG/MLUG/MLUG/ML

91919210010088

979776

949495959998979467O.798979890TO98989398

* Compound is ISTD

640


EPA SAMPLE NO.

Lab Name: ETCNJ

Lab Code : Case No.:


Sample wt/vol: 1000. (g/mL) ML


\Moisture: not dec. dec.

Extraction: (SepF/Cont/Sonc ) SEPF


Cont ract :

SAS No.: SDG No.:


Lab File ID: >G9073

Date Received: 1Q/M/89



Di lu t ion Factor: 1


108-95-2 —————— Phenol___________________111-44-4—------bis(2-Chloroethyl) ether____95-57-8 ———— ——— 2-Chlorophenol____________541-73-1--------1,3-Dichlorobenzene________106-46-7--------l,4-Dichlorobenzene________100-51-6 —— ——— -Benzyl alcohol____________95-50-l---------l,2-Dich torobenzene________95-48-7———————-2-Methyl phenol______________108-60-1----—--bis(2-Chloroisopropyl)ether_106-44-5 ——————— 4-Methyl phenol_____________621-64-7--------N-Nitroso-di-n-propy lam me__67-72-l---------Hexachloroethane__________98-95-3---------Nit robenzene________________78-59-1---------Isophorone_________________88-75-5---------2-Nitrophenol_____________105-67-9--------2,4-Dimethyl phenol_________65-85-0---------Benzoic acid______________lll-91-l--------bisl2-Ch1oroethoxy)me thane__120-83-2--------2,4-Dichlorophenol_________120-82-l--------l,2,4-Trichlorobenzene_____91-20-3---------Naphthalene_______________106-47-8--------4-Chloroani 1 me____________87-68-3—-------Hexachlorobutadlene________59-50-7----——--4-Chloro-3-methyIpheno1_____91-57-6—-------2-Methylnaphthalene_________77-47-4---------Hexachlorocyclopentadlene__88-06-2--——-—2,4,6-Tr ich loropheno1_______95-95-4--- - - - - - -2,4,5-Tr ichloropheno 1______91-58-7---------2-Chloronaphthalene________88-74-4---------2-Nit roani1 me_____________131-11-3---——--Dimethylphthalate__________208-96-8--------Acenaphthylene______________606-20-2--------2,6-Dmitroto luene__________

101010101010101010101010101010105010101010101010101010501050101010

Q

IUIUIUIUIUIUIUIUIUIUtuIUIUIUtutuIUIUIUIUIUIUIUIUIUIUIUIUIUI LII UIUIU

FORM I SU -1 1/87 Rev.641


EPA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case Mo,:



Leve1: Clow/med) LOW




Cont ract:

SAS No.: SDG No.:


Lab File ID: >G9073/i

Date Received: 10/i2/89 i



Dilut ion Fac tor: 1


99-09-2 ——————— 3-Nitroanil ine____________ 5083-32-9- — — ----Acenaphthene______________ 1051-28-5 ———————— 2,4-Dinitrophenol__________ 50100-02-7————— — 4-Ni t rophenol_____________ 50132-64-9---- — --Dibenzofuran_______________ 10121-14-2 —————— 2,4-Dmi trotoluene_________ 1084-66-2 ———— —— -Die thy Iphtha late__________ 107005-72-3 —————— 4-Chlorophenyl-phenylether__ 1086-73-7---------Fluorene__________________ 10100-01-6 ——— _-__4-Ni troani 1 ine_____________ ?0534-52-l--------4,6-Dinitro-2-methyIpheno1__ 5086-30-6----—---N-Nitrosodiphenylamine (1)__ 10101-55-3--------4-Bromophenyl-phenylether___ 10118-74-l--------Hexach lorobenzene_________ 1087-86-5---------Pentachloropheno 1__________ 5085-01-8---------Phenanthrene______________ 10120-12-7——————-Anthracene__________________ 1084-74-2 —————— -Di-n-buty Iphtha late._______ 10206-44-0----- — -Fluoranthene______________ 10129-00-0 —————— Pyrene___________________ 1085-68-7---------Buty Ibenzy Iphtha late_______ 1091-94-1---------3,3'-Dichlorobenzidine______ 2056-55-3---------Benzota )anthracene_________ 10218-01-9 —————— -Chrysene___________________ 10117-81-7- ————— -bis(2-Ethylhexyl )ph thai ate_ 10117-84-0--------Di-n-octyIphtha late________ 102Q5-99-2---- — --Benzo(b)f luoranthene________ 10207-08-9 —————— Benzotk )f luoranthene_______ 1050-32-8---------BenzoCa )pyrene____________ 10193-39-5 —— ----- Indenot 1,2 , 3-cd Jpyrene_____ 1053~7Q-3---~-----Dibenz(a,h)anthracene______ 10191-24-2--------Benzo(g,h,i )perylene_______ 10

Cl) - Cannot be separated from Dipheny1 am me

FORM I SU -2

Q

IUIUIUIUIUIUIUIUIUIUIUIUIU1UIUIUIUIUI UIUIUIUI U!UIUIUIUIUIUIUIUIU

1/87 Rev.

642

TOTAL ION CHROMQTOCROHFile >69073 3S.0-S00.0 *»u.

1408880-

1280060-

1000000-

980000-

688888-

400000-

200000-

TIC008 1 208

CRZZ71C ,QC70B91,Ll

1 600 2000

4 ' ' A ' 1 ' ^ ' '20' 32 '-3'6 ' 4'0 44


Id F i l e : IG0130: :PFTi t le : IFB/BNA, PPxBNALast Cal ibrat ion: 891116 12:11

Operator ID: PT1575Quant Time: 891116 13:14In jected at: 891116 02:22

Quant Output File: AG9073: :AQ

BTL#39

643

QUANT REPORT

Operator ID:Output File:Data File:Name :Misc: CA2271C

PT1575^G9073::AQ>G9073:: U3


Di lut ion Factor

,QC70091,L:M6,1000,2

891116 13:14891116 02:22

1.00000

BTL#39


Compound R.T. Scantt Area Cone Uni ts

1)3)5)17)18)32),36 )52 )54)65)67)73)

*d4-l ,4-Dich lorobenzene2-Fluoropheno 1Pheno 1-D5


»dlQ-Acenaphthene2-Fluorobiphenyl2,4,6-Tribromophenol

*dlO-Phenanthrene*dl2-ChryseneTerphenyl-D14*d!2-Perylene

CSURR)CSURR)

(SURR)CSURR)

CSURR)

10.7.10.14.12.19.17.22.24.32.29.36.

665211443890983533313332

348.1943215334328007069201017140812621604

1294222194277149749667822771859580M2406735617811540920846569308751

40.93.23.40.33.40.97.239.40.40.97.40.

002218002700086900007400

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

91SO899494

999498999396

* Compound is ISTD

644

IBSEMIYOLATILE ORGAN ICS ANALYSIS DATA" SHEET

EPA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Ma t r i x: (soil/wa t e r) UATER


Level : C low/mod) LOUI


Extract ion: (SepF/Cont/Sonc) SEPF


Cont ract:

SAS No.: SDG No.:


Lab File ID: >G9087




Dil u t i o n Factor : 1


10811195-54110610095-95-10810662167-98-78-88-1 0565-11112012091-10687-59-9 1-77-88-95-91-gg-131?nfi606

-95-2 —————— Phenol ___________________-44-4 —————— bis<2-Chloroethyl )ether ____57-8---------2-Chlorophenol _____________- 73 -1------.--1, 3-D ich lorobenzene ________-46-7--------l,4-Dich lorobenzene_ _______-51-6------ — Benzyl alcohol ____________50-1----- — --1,2-D i ch lorobenzene ________48-7 ———————— 2-Methyl phenol _____________-6fl-l--------bis(2-Chloroisopropyl )ether_-44-5 — - ———— 4-Methyl phenol _____________-6 4- 7- ------- N-Nitroso-d i-n-propy lamine __72-l---~-----Hexach loroe thane __________95-3----- — --Nitrobenzene ______________59-1--------- Isophorone ________________75-5---------2-Ni t ropheno 1 _____________-67-9--------2,4-Di methyl phenol _________85-Q------ — -Benzoic acid ______________-91-1--- — ---bis(2-Ch lo roe thoxy)me thane __-83-2--- —— --2,4-Dichloropheno 1 _________-82-l--------l,2,4-Trich lorobenzene _____20-3- ——— ----Naphthalene _______________-47-8--------4-Chloroani 1 me _____ • _____68-3-- — -----Hexach lorobu t ad lene ________50-7- —— -----4-Chloro-3-methylpheno 1 _____57-6----- ----2-Methyl naphthalene, _______47-4---------Hexach lorocyc lopentad lene __06-2---------2,4,6-Trichloropheno 1 ______95-4---------2,4,5-Trichloropheno 1 ______58-7---------2-Chloronaphtha lene ________74_4---------2-Ni t roan i 1 ine ________ „-11-3---- —— -Dimethylphthalate __________-96-9--------Acenaphthvjlene ________ „-20- 2 -------- 2 f 6-Din i tro to luene... ________

76101601070101010101033101010101050101074101010150101010501050101010

FORM I S"J -1 1/8

•1CSEMIUQLATILE ORGANICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Matrix: Csoil/water) WATER






Cont ract:

SAS No.: SDG No.:


Lab File ID: >G9087




Di lut i on Factor: 1


99-09-2---------3-Nitroani l me____________ 5083-32-9---------Acenaphthene______________ 8151-28-5---------2,4-Dmitropheno 1__________ 50100-02-7———————4-N it rophenol______________ 68132-64-9--------Dibenzofuran______________ 10121-14-2 ——— ——— 2,4-Dmitro toluene_________ 9584-66-2- ——————— Diethylphthalate___________ 107005-72-3--- - - - -4-Chlorophenyl-phenylet her__ 1086-73-7---------Fluorene___________________ 10100-01-6- - - - - - - -4 -Ni t roam 1 me_____________ 505 34-52-1------ --4,6-Dmi t ro-2-me thy 1 phenol_ 5086-30-6--- - - - - - -N-Ni t rosod i pheny lam me CD__ 10101-55-3--------4-8romophenyl-phenylet her__ 10118-74-l--------Hexach lorobenzene__________ 1087-86-5----- — --Pen tachlo rophenol___________ 15085-Ql-8---------Phenanthrene_______________ 10120-12-7—-- —— -Anthracene__________________ 1084-74-2 —— ------Di-n-butylphthalate________ 10206-44-0--------Fluoranthene________________ 10129-00-0 ——— - —— Pyrene___________________ 7885-68-7---------Butylbenzylphtha late________ 1091-94-l---------3,3'-Dichlorobenzid me_____ 2056-55-3---------BenzoCa )anthracene_________ 10218-01-9--------Chrysene___________________ 10117-81-7- —————— bist2-Ethylhexyl )phthalate_ 10117-84-0- -------Oi-n-octylph thai ate________ 10205-99-2--------Benzotb )f luoranthene________ 1020 7-08-9--------Be nzoCk if luoranthene_______ 1050-32-8---------Benzo(a )pyrene_____________ 10193-39-5------—Indeno(l,2,3-cdJpyrene______ 1053_70-3---------Dibenzta,h)anthracene______ 10191-24-2--------Benzo(g,h,i )perylene_______ 10

I 1 ) - Cannot be separated from Diphenylamine

FORM I SU -2

Q

1/87 Rev.

646

TOTQL IQH CHROMPTQCRQMFlit >S90e7 35.8-500.8 MU . CBa271CS.aC78B91.HH

1600000-

1400088-

1200000-

1000000-

808008-

600000-

400000--

200000-

't\i

•

I,

«

4

TIC, 468 | 800 ( 1209 | 1688 ( 2888

rl i ^ **

i3to ." !'i

1« - 1 - - g

I !1 e

»*-"! 1 I Is,^ i & * ? . - ¥V o 1 C* g1

^ if i1- S 2« 1 1 ll T T

8 "lP2 ' 16 20 ' 24" ' "z'e ' 32' ' 36 ' 48 ' ' 44

Data File: >G9Q87:: U3Name:Misc: CA2271CS,QC70091,I_: 116,1000,2

Id File: 160131::PFTitle: IFB/BNA, PPxBNALast Calibration: 891116 16:06



BTL#13

647

QUANT REPORT

Operator ID: CA3875Output File: ^G9087::AQData File: >G90S7::U3Name:Misc: CA2271CS,QC70091,L:M6,1000,2


Compound


Di lut ion Factor

Page 1

891117 01:38891117 00:50'

1.00000

BTL*13


1)3)5)6)6)7)

^ 8)9)10)12)12)17)18)24)OK 1ZV '31)

32)36)43)46)47)50)52)54)

W59)63)64)65)67)73)

*d4-l ,4-Dichlorobenzene2-Fluorophenol CSURR)Phenol-05 CSURR)Pheno 1Pheno 12-Ch loropheno 11,3-Dichlorobenzene1,4-Dichlorobenzene1,2-DichlorobenzeneN-Nitrosodi-n-propylamineN-Nitrosodi-n-propylamine

*d8-NaphtheleneNitrobenzene-05 (SURR)1,2 ,4-Tr ichlorobenzene2, 4-Dich loropheno 1p-Chloro-m-cresol

*dlO-Acenaphthene2-Fluorobiphenyl (SURR)Acenaphthene2 ,4-0 in i t r o t o l u e n e4-Ni t ropheno 1Fluorene2,4,6-Tribromophenol CSURR)

*dlO-Phenanthrene. PentachlorophenolFluoranthenePyrene

»d!2-ChryseneTerpheny 1-014 CSURR)

»d!2-Perylene

10.7.10.10.10.10.10.10.10.12.12.14.12.14.•t JT14.16.19.17.19.20.20.22.22.24.23.28.28.32.29.36.

593908121614636363133137312979488086906563242423965252242523

345188320322324323347 •347347421430531430527

63579870380384083991 ft~ ID918

1016100312271227141012631606

28612029234727746124425911772

42830622834722834722B34720215752514

5889703624372077704325

2177701923273268682610666879613197440264892177951636741889531889536628411902562152

40523937-t80** -9

^ 2

34^ •»^ 43-ti404337

774038404734

974075•• >*

- J U3B406840

.00

.16

.59

.78

.82T&?-.913.*

iC

.83Jo.00.58.06•rfri-.40.00.80.58.57.02

.49

.00

.88A -V

* V J

.84

.00

.23

.00

UG/MLUG/MLUG/MLUG/MLUC/MLUG/MLUGVMLUG/ML. 1M ~t-\\UU' i <i_UG/MLUS^'MLUG/MLUG/MLUG/MLUS^'MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUGj'ML —UG/MLUG/MLUG/ML* * *™ ' VrilUU' 1 ll_


908592

10010089869596723794949699989998989867PADO9697989897999392

* Compound is ISTD <£$>

648


EPA SAMPLE NO.

Lab Name: ETCNJ*»•"••

Lab Code: Case No.:

Contract

SAS No.

Ma t P i x : (soil /wa tap) UATER

Sample uit/vol: 960.0 Cg/mL) ML

Level: (low/mad) LOU

X Moisture: not dec. dec

Ext pact ion: (SepF/Cont/Sonc > CONT


SDG No.:

Lab Sample ID: CA1907CR

Lab File ID: >59043

Date Received: |»/*7/*f




CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L OP ug/Kg) UG/L

108-95-2 ———11-1-44-4 ———95- 7-8 ————541-73-1 ———106-46-7 ———100-51-6 ———95-50-1 ————95-48-7 ————108-60-1 ———106-44-5 ———621-64-7 ———67-72-1 ————98-95-3 ————78-59-1 ————88-75-5 ————105-67-9 ———65-85-0 ————111-91-1 ———

91-20-3 ————106-47-8 ———

91-57-6 ————77-47-4 ————Qfl_(lA-9-----95-95-4 ————91-58-7 ————88-74-4 ————131-11-3 ———208-96-8 ———606-20-2 ———

1——— Phenol 1— --bi»(2-Chlopoethyl )ethep ____ 1——— 2-Chlopophenol 1- —— 1 ,3-Dich lorobenzene 1—— -1 r4-DiehloPohenzane I—— -Benzyl alcoha 1 , 1——— 1 .2-Diehlarohenzene 1-- — 2-Methylphenal , . 1----bi»(2-Ch loro i sop ropy 1 )ether_!—— -4- Methyl phenol 1----N-Ni t poso-di-n-ppopylamine _ 1— — Haxachlopoethane . I——— Nitrobenzene 1---- Isophopone 1_ — -2-Nitraphanol M 1— --2f4-Dimathylphenol _ ,,.„„. , 1—— -Banzai c acid 1——— bi»(2-ChloPOethoxy) me thane _ 1—— -2 ,4-Oieh lorophanol I-. — -1 ,2 ,4-Tr ichlorobanzene ,,„„, 1——— Naphthalana 1— .--4-Chloroani 1 ine 1

——— 4- ChloPO-3-methyl phenol ____ 1

— --Hexach lorocyc 1 open tad iene __ 1*---2 ,4;A-Tr iehlorophenol 1-_ — 2f 4.5-Tr ichloropheno 1 1— --2-Ch toronaphthalene 1----2-Ni t roan i 1 ina 1- - - - 0 i me t h y 1 p h t h a 1 a t e .,„,, . ...„ , 1----Acenaphthylana 1-_ — 2 ro-Dini t rotoluane . , 1

1

130101401081101010101072101010101052101084101010130101010521052101010

11t u -IU1IUIUIUIUIU1IUIUIUIUIUIUIUIU1IUIUIU1IUIUIUIUIUIUIUIUIU1 f-

FORM i -i 1/87 Rev.

1CSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:

Contract:

SAS No.i


Sample ut/voli 960.0 (g/mL) ML




GPC Cleanup: <Y/N) N pH:

SDG No.:


Lab Ftle ID: >G9Q43

Date Received: /

CAS NO. COMPOUND



Dilution Factor: 1

CONCENTRATION UNITS:(ug/L or ug/Kg) UGxL Q

99-09-2 ——————— 3-Nitroaniline____________15283-32-9———————Acenaph thane______________18951-28-5———————2,4-Dinitrophenol_________15210(^-02-7——————4-Nitrophenol_____________197132-64-9———————Dibanzofuran______________110121-14-2——————2,4-Dinitrotoluene________16884-66-2———————Die thy Ipht ha late__________1107005-72-3——————4-Chlorophenyl-phenylether_11086-73-7———————Fluorene_________________110100-01-6——————4-Nitroaniline___________152534-52-1 —————— 4,6-Dini tro-2-methylphenol_15286-30-6 ——————— N-Nitrosodiphenylamina (1)_110101-55-3 ——————— 4-Bromophenyl-phenylether__1 10118-74-1—————-Hexachlorobenzene_________11087-86-5———————Pentachlorophenol_________18485-01-8———————Phenanthrene_____________110120-12-7———————Anthracene________________I 1084-74-2 ——————— Di-n-buty Ipht ha late________110206-44-0——————Fluoranthene_____________110129-00-0——————Pyrene__________________18385-68-7——————Butylbanzylphthalate______11091-94-1———————3,3'-Dichlorobanzidine_____12156-55-3——r-———B«nzo(a)anthrecene^______110218-01-9———————Chryeene_________________110117-81-7——————bi«(2-Ethylhexyl)phthalate_110117-84-0——————Di-n-octylphthalata_______110205-99-2——————Benzo(b)f luoranthane______110207-08-9 —————— Banzo(k)f luoran thane_______11050-32-8 —— ————— B«ngo(a)puran«_______1 10193-39-5——————Indeno(l,2,3-cd)pyrene_____11053-70-3 —————— --DibenzCa,h)anthracene______110191-24-2 —————— Benzo(g,h, i )perylene_______110_________________________________m_______I_CD - Cannot be separated from Diphanylamina

U

t *tuIIUIUIUIUIUIUIUIUIIUIUIUIU

IUIUIUIUIUIUIUIUIUIUIUIU

FORM I SU -2 1X87 Rev.

GSO

TOTPL ION CHROMOTOCRPHFil* >69943 35.0-500.9 MU . CR1907CR ,QC70087,Ui

i6eeeee-

1400000-

1200000"

1000000-

800000-

60000*

400000-

200000-

4«« , 908 : 1200 , 1600 , 20,00

13* r

a-. I -

•

Jl

•s.f ^

5

• i

| , ~ | i^| w S,? I tilI * 1 1 1 sf""-''!! ^ 1 j1 I6 1 5? 6,^ - «1 ( 4 it i "* 5

4 ' i 12 ' 16 ' 20 ' 24 ' 28 32 ' 36 ' 4'0 ' 44

Data File: >G9043::U5Name:Misc: CA1907CR ,QC7D087,L:M6, 960,2

Id File: IG0130::PFTitle: 1FB/BNA, PP/BNALast Calibration: 891115 08:47


Quant Output File: 'SG9Q43::AQ

BTL* 9

"-*'

651

Jperator ID: PT1575Output File: AG904fi.sAQ~)ata File: >G9043«MJ5Jame:ilisc: CA19Q7CR ,QC70087,L:M6, 960,2

0 File: IG013Q::PF' i t le : IFB/BNA, PP/BNA

Last Cal ibrat ion: 891115 08:47

Compound

QUANT REPORT

Quant Rev: 7 Quant TimeIn jected at

Di lut ion Factor

Page 1

391115 09:32891114 27:31

1.00000

BTL# 9

R.T. Scan* Area Lone Um ts

1)3)5)6)7)8)

10)12)12)17)13)22)24)3D32)36)43)46)47)4?)50)52)54)%9 )62)63)64)65)67)73)

*d4-l,4-Dichlorobenzene2-Fluorophenol CSURR)Phenol-05 CSURR)Phenol2-Chloropheno 11,3-Oichlorobenzene1, 4-Dichlorobenzene1,2-DichlorobenzeneN-Nitrosodi-n-propylamineN-Nitrosodi-n-propylamine

»d8-NaphthaleneNitrdbenzene-05 CSURR)2 , 4-Djmethy Ipheno 11,2,4-Trichlorobenzenep-Chloro-m-cresol

•dlO-Acenaphthene2-Fluorobiphenyl CSURR)Acenaphthene2,4-Dinitrotoluene4-Ni t ropheno 1Diethy 1 phtha lateFluorene2 ,4,6-Tr ibromophenol CSURR)

*dlQ-PhenanthrenePentachlorophenolDi-n-butyl phtha lateF luoran thenePyrene»dl2-Chrysen»Terphenyl-D14 CSURR)

*d!2-Perylen*

10.7.10.10.10.10.10.10.12.12.14.12.14.14.16.19.17,19.20.20.21.22.22.24.24.26.28 .28.32.29.36.

64491315196863AHO O1637423734345285929568606229292802625757293230

345190320321323347347347420430531430527527634793703803839835885918918

10161003113112271227141012641607

288674350003432400430073370978246584246584246534152722471725142423138982550

199968193680172977303296240340537962407470373270

49110153911267342018

i o i n K ~y17 1 U1? /

1910577767512142058743

40.63.60.64.66._•» i-38.Ju .

34.

40.44.. •'

40.63.40.43.42.32.46.-ir•

63.40.40.«" * .39.40.63.40.

0037184266f e

95' '35

0079* ,1-51420092344874•t «• *•^ u

420050rt r

trr-310023GO

UG/MLUG/MLUG/MLUG/MLUG/ML

UG/MLUU' 1 1LUG/MLUG'-MLUG/MLUG/ML' "** LJIWW' ^k— * .

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLyC/MtrUS' 'ML-UG/MLUG/MLUG/MLi "~ .'MlUU L-'JQ1 MLUG/MLUG/MLUG/MLUG/ML

89929333939595oc77763793377395939799"83769948595959990•3307•3307

*4

* Compound is ISTD as>

652

IBSEMIUQLATILE ORGANICS ANALYSIS DATA SHEET


ERA SAMPLE NO.

Lab Code: Case No.:

Ma t P i x: (soil/wa ten) WATER


Level: Clow/med) LOLJ


Extract ion: (SepF/Cont/Sonc) SERF


SAS No.: SDG No.:

Lab Sample 10: CA2271CR

Lab File ID: >G9070




Dilut ion Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:Cug/L or'ug/Kg) UG/L

108-95-2——————— Phenol___________________111-44-4——————bisC2-Chloroethyl )ether____95--57-S——————— 2-Chlorophenol____________541-73-1 —— — —— 1,3-Dichlorobenzene____'106-46-7---—-—1,4-Dichlorobenzene________100-51-6 —— --- — Benzyl alcohol____________95-50-1-—-———-1,2-Dichlorobenzene________95-48-7———————2-Methyl phenol____________108-60-1-----—-bis(2-Chloroisopropyl)ether_106-44-5 ——————— 4-Methyl phenol____________621-64-7------ — N-Nitroso-d i-n-propylamine_67-72-1—---——-Hexachloroethane__________98-95-3-----——-Nitrobenzene______________78-59-1---------Isophorone________________88-75-5——------2-Nitrophenol_____________105-67-9--- — ---2,4-Dimethylphenol_________65-85-0 ——— -----Benzoic ac id______;________lll-91-l--------bis(2-Chloroethoxy)me thane__120-83-2--------2,4-Dichlorophenol_________120-82-1--------1,2,4-Trichlorobenzene_____91-20-3 ——————— Naphthalene_______________106-47-8-- —— ---4-Chloroan i 1 me___________87-68-3--—-----Hexachlorobutadlane________59-50-7---——---4-Chloro-3-methylpheno1____91-57-6 ——— -----2-Methylnaphtha lene________77-47-4--———-—Hexachlorocyclopentadiene__88-06-2- — — ----2,4,6-Trichloropheno 1______95-95-4--- — ----2,4,5-Trich torophenol______91-58-7----—---2-Chloronaphthalene________88-74-4-------—2-Nitroani1ine____________131-11-3 ——————— Dimethylphthalate_________2 08-96-8---- ----Acenaphthylene^__________606-20-2--—----2,6-Dinitrotoluene_________

74101601063101010101072101010101050101063101010150101010501050101010

Q

U

IUIIUiuIUIUIU

IUIUIUtuIUIUIUIUIIUIUIUIIUIUIUIUIUIUIUIUIU

FORM I SU -1 Rev.

•1CSEMIUQLATILE ORGANICS ANALYSIS DATA SHEET

ERA SAMPLE NO

Lab Name: ETCNJ

Lab Code: Case No.:

Matrix: CsoilXwater) WATER

Sample wtxvol: 1000. CgXmL) ML

Level: ClowXmed) LOW


Extract ion: (SepFxContxSonc) SERF

GPC Cleanup: CYXN) N pH:

Cont ract:

SAS No,: SDG No.:


Lab File ID: >G9070

Date Received: 10x12x89

Date Extracted: 10x13x89

Date Analyzed: 11x15x89

Dilut ion Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:CugXL or ugXKg) UGXL

99-09-2---------3-Nitroani1ine____________83-32-9—----—-Acenaphthene______________51-28-5-----——-2,4-Dinitrophenol_________10-0-02-7——————4-Ni t rophenol_________•132-64-9—---—-Dibenzofuran______________121-14-2 —————— 2,4-Dini trotoluene_________84-66-2 — -------Diethylphthai ate__________7005-72-3-------4-Chlorophenyl-phenylether_86-73-7---------Fluorene__________________100-01-6--------4-N1troani1 me____________534-52-1---—---4,6-Dihitro-2-methylphenol_86-30-6---------N-Nitrosodiphenylamine Cl)__101-55-3--------4-Bromophenyl-phenylether__118-74-l--------Hexachlorobenzene_________87-86-5---------Pentachloropheno1_________85-01-8----——-Phenanthrone_______________120-12-7--------Anthracene________________84-74-2---- —— --Di-n-butylphthalate________206-44-0---—---Fluoranthene_______________129-QD-Q--------Pyrena__________________85-68-7---------Butylbenzylphthalate_______91-94-l---------3,3'-Oichlorobenzid ine_____56_55_3---------Benzo(a)anthracene_________218-01-9-—-—--Chrysene__________________117-81-7———————bisC2-Ethylhexyl Jph thai ate_117-84-0--------Di-n-octylphthalate________205-99-2---—---BenzotbJfluorantnone_______207-08-9--------Benzo(k)fluoranthene_______50-32-8---------Benzota >pyrene____________193-39-5--------Indeno(l,2,3-cd Jpyrene_____53_70-3---------DibenzCa,h Janthracene______191-24-2--------Benzo(g,h,iJperylene________

Cl) - Cannot be separated from Diphenylamine

FORM I SU -2

50705054106410101050501010101201010101073102010101010101010101010

Q

IUIIUIIUIIUIUIUIUtuIUIUIU(IUIUIUIUIIUIUIUIUIUIUIUIUIUIUIUIU

1X87 Rev.

654

TOTAL ION CHRQHATOCRAH

w

Tilt >69e?e 3S,e-5Ba.e *«u. „,„ CMZ/ICR ,ac7M*ifuiTIC

i2eeeee-iiaeaea-leeeaee-?eeeee-aeeeea-?aeeee-«eaeae-saeeae-4aeeaa-aaaeaa-aaaeaa-laaaee-

•.

\

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It

4

49,9 , aaa ( 1 200 , 1 6ae t 2aee

i f

ill I ffi 9 •

i, ;

i'-.

1

I 4

|

1 1

! i

i -x

f,, fi ^ ;*

i^ J !

L 1 ^ ?fe ! i s •1 i: •> 1 1

m r ! t8 12 ' 16 20 ' 24 ' 28 ' 32 ' 3*6 ' 49 ' 44

Data File: >G9070::U3Name:Misc: CA2271CR ,QC70091,L:M6,1000,2




BTI_#36

655

Operator ID: PT1575Output File: 69070::AQData File: >G9070::U3Name:Misc: CA2271CR ,QC70091,L:M6,1000,2


Compound

QUANT REPORT


Di lut ion Factor

Page 1

891116 12:92891115 23:31

1.00000

BTL*36


1)3)5)

W 6>7)8)9)10)12)12)17)18)24)31)32)36)43)46)47)49)50)

v '52)V 54)59)63)64)65)67)73)

*d4-l ,4-D ichlorobenzene2-Fluo ropheno 1 CSURR)Phenol-05 CSURR)Phenol2-Chloropheno 11 , 3-D ichlorobenzene1 ,4-D ichlorobenzene1,2-D ichlorobenzeneN-Ni t rosodi-n-pr opy lam ineN-Ni't rosodi-n-p ropy lam ine*d8-NaphthaleneNitrobenzene-05 CSURR)1,2, 4-Tr ichlorobenzenep-Ch loro-m-creso 1•dlO-Acenaphthene2-Fluorobiphenyl CSURR)Acenaphthene2,4-Dinitrotoluene4-Nit ropheno 1Diethyl phthalateFluorene2,4,6-Tribromophenol CSURR)

•dlO-Phenan thronePentach lo ropheno 1FluoranthenePyrene

*d!2-ChryseneTerphenyl-014 CSURR)

•d!2-Perylene

10.7.10.10.10.10.10.10.12.12.14.12.14.16.19.17.19.20.20.21.22.22.24.24.

28.32.29.36.

6645111520727272193744373654899697706264313132036161323433

3491913223243263523523524244335354335316388037088078438398899229221021100712321232141512681612

2753722715222334502416354151732006692006692006691419093714252933424571615982322377719281826306023071751225128136865370355175177060307641754611754618069311286361935

4054353679* J4J U31

36nJ

403331774032353227-t.

724058

36405040

.00

.21

.57

.96

.21

.61e m*

^

.20rf *+

• U.00.68.31.43.00.79.17.05.03

*tl-.74.00.07

.56

.00

.06

.00

UG/MLUG/MLUG/MLUG/MLUG/ML• * * -* *|wv " >wUG/MLi if* f|||UU-- • i*.UG/MLUC.'HtLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG I'ILUG/I'ILUG/MLUG/MLUG/ML


88799386969098997639949696989899988860949294979998979*9466

* Compound is ISTD

656

PELA INC - TECHNICAL MEMORANDUM NO. 3 FOR REMEDIAL ... · Number TICs found: Contract: SAS No.: SDG...

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Transcript of PELA INC - TECHNICAL MEMORANDUM NO. 3 FOR REMEDIAL ... · Number TICs found: Contract: SAS No.: SDG...