OTC 6602 - Often Overlooked Data From Offshore Subsea Survey

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    OTC 66

    Often Overlooked Data Available From a Typical

    Offshore Subsea Survey

    M.W. Mateer, ARCO Oil Gas Co.

    This paperweePresentedtthe?srdAnnualo~ i nHouston,ex=,May6-9,191

    Thi s paper waa sel ect ed f or preaent eti on by t he OTC Program Committee f ol lowing r eview of informat ion cont ained i n an abstr act submit ted by t he aut ho s). Content s of t he psper ,

    aa p resented, hava no t been rev iewed by the Of fsho re Technology Conference and a re sub jact to co rrac tlon by the au thor a ). The mater ial , aa p resan ted , does not naceeaar il y ref lect

    any pos it ion o f the Offshore Technology Conference or i ts o ff ic ers. Psrmlas lon to copy 1s res tr ic ted to an aba trac t o f not mo re than 300 words . I ll us trat ions may no t be cop ied. The abs trac t

    should contain conapicuoua acknow ledgment of where and by whom the papar ia p resented.

    ABSTRACT

    Regul ar subsea i nspect i on of off shore

    structures to assess the conditi on of cathodi c

    protect ion systems is a way of 1i fe in the Gul f

    of Mex ico.

    In an effort to col lect more useful

    data, new i nspect i on procedures were

    i mpl emented i nto the ARCO Oi 1 and Gas Sout hem

    O stri c t plat form inspect ions to see i f i t was

    possi bl e to routi nel y cal cul ate the current

    output of anodes using the anode resistance

    method i n NACE RP-01-76.

    By t ri al and err or , a

    potent i al sampl i ng techni que was di scovered

    which al l ows the col l ection of the kind of

    potent i al data needed to cal cul ate anode

    current wth an accuracy simlar to that

    possibl e w th di rect measurement w th a gauss

    meter. The speed at which this data can be

    taken makes thi s survey techni que no more

    costl y than a normal potenti al survey whi l e

    provi di ng much more useful data.

    Keywords:

    cathodi c protect i on, anode,

    potent i al survey.

    I NTRODUCTI ON

    A typi cal underwater potenti al survey

    consi sts of measuring the potential of the

    structure agai nst a standard reference

    electrode ( usual l y Ag/AgCl ) in order to

    i nsure the vi abi 1ity of the cathodic protection

    system

    Although a great deal of data can be

    obtained, i t i s usual l y necessary to 1imt the

    scope of the potential survey to keep the time

    and cost reasonabl e.

    When pl anni ng for the

    ARCO Southern O strict 1989 pl atform surveys, a

    11l ustrat i ons at end of paper.

    compl ete rethi nki ng of our pl atform survey

    requi rements was done to try and take the best

    advantage of the changes caused by the new MMS

    pl atf orm survey requi rements.

    As par t of thi s rethi nki ng, the i dea of

    using potent i al measurements to survey anode

    current output was di scussed w th the survey

    contractor.

    I t was fel t that a usabl e

    corre 1at ion coul d be found between anode

    potent i al and anode current output usi ng the

    cal cul ati on method recommended i n NACE RP-O -

    76. This was cons idered to be an easy

    addit i on to our survey that could be

    accompl i shed w thout an i ncrease i n effort.

    The mai n unknown factor was the proper l ocati on

    of the potential survey poi nts needed to gi ve

    the proper anode and cathode potent iaIs for the

    cal cul ati on.

    Ideas on how to obtai n the needed

    data were devel oped and added to the survey

    procedures pr i or to the star t of work. I n

    order to have a standard against whi ch to

    compare the resul ts, an underwater gauss meter

    was obtai ned for taki ng anode current

    measurements di rect l y from the anode supports.

    Ouri ng the surveys, di rect current measurements

    and anode potent i al s were taken on 57 anodes on

    13 di ff erent pl atf orms.

    ANOOE CURRENT CALCULATIONS

    In theory, the output of an anode can

    be found by using the equati on:

    I = E/ R

    (1)

    where I i s the cur rent , E i s the potent i al

    di ff erence between the anode and cathode and R

    is the ci rcui t resi stance. Since the current

    density i s much hi gher at the anode than the

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    z

    OFTEN OVERLOOKED OATA AVAI LABLE FROM A

    cathode and the resistance in the stee1 is

    negl igi bl e, the ci rcuit resistance can be

    cons i dered to be the anode to el ectrol yte

    resi stance.

    This can be found by using a

    modi fi ed form of Ow ghts equati on: (for deep

    water)

    R = 0.0627(f /L)[ ln(2L/r ) - 1]

    (2)

    Where R is the anode res istance in ohms, L is

    t he l engt h of t he anode i n i nches, r i s t he

    radius of the anode in inches and ~ i s the

    r esi st i vi t y of t he wat er i n ohmcm To

    cal cul ate the output of an anode then, one must

    know the potent i a1 di ff erence between the anode

    and the structure, the resist ivi ty, and the

    length and radius of the anodes. To simpl i fy

    and i mprove data gatheri ng, the fo1l ow ng

    assumpti ons were made.

    1.

    Anodes were assumed to have the

    ori gi nal manufactured di mensions unl ess survey

    measurements showed a change had occurred.

    2.

    Structure potent i al s near the anodes i n

    the survey were cons i dered to be adequate for

    the cal cul ati on.

    3.

    Anodes potenti al s were taken i n several

    di fferent pl aces on the anode to eval uate the

    effects of geometry on potenti al .

    These assumpti ons simpl i fi ed the data gatheri ng

    and al l owed us to survey more anodes than woul d

    have been possi bl e otherwse. For our

    cal cul at ions the resist iv ity of the sea water

    was assumed to be 20 ohmcm

    The radi us was

    assumed to be:

    r = C12~

    (3)

    Where C is the circumerence of the anode cross

    sect i on.

    To i mprove the qual i ty of our

    cal cul ati ons, a correcti on was made to the

    measured anode potenti al to compensate for the

    IR

    drop caused by the mnimum two i nch (5.08

    cm separati on between the anode surface and

    the Ag/ AgCl reference.

    Thi s di st ance i s set by

    the const ruct ion of the reference cel l . To

    compensate, two di ff erent anode resistance

    cal cul ati ons were made, one usi ng the radi us

    val ue determned from equati on 3 (R) and one

    for a radius 2 inches (5.08 cm greater . (R+2)

    The di ff erence between the two was considered

    to be the resi stance of the el ectrol yte between

    the anode and the reference cel l . To correct

    the anode potenti al , f i rst the anode output was

    cal cul ated using the measured anode potenti al ,

    Then the calculated current is used to f i nd the

    IR

    drop between the anode and the reference by

    the equati on;

    IR

    drop = Current x [(R+2)-R] (4)

    Thi s

    IR

    drop i s then added back to the

    measured anode potenti al and the current

    cal cul ati on repeated w th the corrected

    potent i al .

    TYPICAL OFFSHORE SUBSEA SURVEY

    OTC 6602

    EXPERIMENTAL

    Thi rteen pl atforms were surveyed for

    anode performance as one part of our regul ar

    pl atf orm surveys.

    Al l pl atforms were

    convent i onal 4, 6 and 8 pi l e designs set i n 30

    to 90 feet of water i n OCS water s in the Gul f

    of Mexico.

    Platform ages var ied from 5 to 12

    years.

    Al l anodes were trapezoi ds i n cross

    sect ion measur ing 8x 8 x 8. A few typical

    anodes on each pl atform were measured for

    actual di mensi ons. Our procedure was to

    measure the potenti al of each anode three

    t imes, once in the mddle on the side facing

    away from the pl atform and once at each end.

    Structure potenti al s were taken on the l egs as

    near as possi bl e to the surveyed anodes. Many

    of the surveyed anodes were al so cl eaned and

    photographed so that we coul d correl ate

    appearance to anode potenti al and current

    output .

    Each surveyed anode was measured for

    current output w th the gauss meter four times.

    Each anode standoff was measured tw ce, once

    w th the meter fl i pped each way, to compensate

    for any effect of the earths magnet ic f i el d.

    The average of the two readi ngs for each

    standoff was taken as the correct value. The

    current val ues for each standoff were then

    added to get the total current for the anode.

    Someti mes the marine l i fe on the stand off was

    too thi ck to al l ow the sensing cl i p to f i t

    over the standoff .

    In

    these cases the di ver

    removed the growth w th a chi ppi ng hamner. In

    cases where fl uctuati ng or unstabl e

    measurements were seen, repeated readi ngs were

    taken unti l a stabl e number was achi eved.

    RESULTS AND DI SCUSSI ON

    Anode Potenti al Survey

    A total of 57 anodes on 13 di f ferent

    pl atforms were measured for current output and

    potent i al .

    Typical l y three or four anodes on

    each structure were sel ected for test ing. The

    potenti al s and vi sual examnati ons showed a

    w de var iat ion in anode performance. Figure 1

    shows the di stributi on of anodes by thei r

    measured potenti al .

    Over 65% of the anodes

    surveyed had potenti al s more posi ti ve than -

    1.00 volts vs an Ag/AgCl reference. The l owest

    potenti al anode had a measured potenti al of -

    0.951 volts vs Ag/AgCl. The mean potent ial of

    the anodes was -0.991 volts . This was

    surprising si nce the expected potential of the

    anodes was -1.05 to - 1. 13 vol t s. Thi s i s ver y

    di scouragi ng and l eads us to bel i eve that the

    number of poorl y performng anodes i n servi ce

    is greater than we had previously bel ieved. In

    spi te of this , structure potent ial s were

    uni formy good.

    Evi dentl y the hi gh potenti al

    anodes were produci ng more than thei r share of

    the CP current.

    As seen below thi s did turn

    out to be the case.

    The appearance of the anodes varied i n

    l ine w th the measured potent ial . Those w th

    384

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    OTC 6602

    MATEER 3

    the most negati ve potent i al s rough and pi tted

    whi l e the more posit i ve anodes have a much

    smoother appearance.

    Figures 2 & 3 show this

    di ff erence i n appearance. None of the anodes

    surveyed had so much meta 1 l oss as to change

    thei r overal 1 shape.

    The presence of mari ne

    growth on the anodes did not appear to effect

    thei r potenti al .

    A potential di f ference of 10

    to 15 m 11ivol ts was consistentl y observed

    between the center and end potent i a1 readi ngs.

    Thi s i s to be expected due to the higher

    current dens i ty at the ends compared to the

    center.

    Anode Current Measurements

    Measured current outputs for the anodes

    ranged f ran 0.2 amps to 2.75 amps.

    Surprisingl y, the current for each standoff was

    never equa1 and somet i rm?swas very di f ferent.

    In some cases 75

    of the current was found to

    travel through one standoff. A visual

    i nspecti on of these anodes found some

    separation of the alumnum from the core at the

    l ow current end. Perhaps some extra resi stance

    from a poor steel / al umnum bond i s responsibl e

    for reduci ng the current. The most probabl e

    cause for the core separation is poor casting

    qual i ty.

    For a given structure, a strong

    rel ati on exi sted between the potent i al ,

    appearance and measured output of the anodes.

    The anodes w th the most negati ve potent i al s

    i nvari abl y had the hi ghest current output and

    the most corroded appearance. The expected

    1i fet i mes of the anodes al so varied

    accordi ngl y.

    Measured Versus Predi cted Current

    After the survey was compl eted and the

    data reported, the predi cted currents were

    cal cul ated and compared to the measured val ues.

    The overal 1 correlati on between the measured

    and predicted currents was not as good as

    hoped. Table 1 contains the data from al l

    anodes surveyed.

    The compari son between

    measured and predi cted anode output i s shown i n

    Fi gure 4.

    The 1i ne represent i ng the l east

    squares f i t of the measured current data is

    very close to the prediction but the data

    scatter is large.

    The probable cause of thi s

    scatter is the lack of cathode potential

    readi ngs close enough to the surveyed anodes.

    Most of the structure potenti al s were taken on

    the l egs, whi l e the anodes were l ocated

    primari l y on the cross members. Our

    expect.ati on that l eg potenti al s wouI d be

    adequate for cal cul ati ng anode output was not

    supported for most of the anodes.

    anode currents for thi s pl atform i s much better

    than for al 1 the anodes surveyed. The slope of

    the least squares f i t 1ine for the measured

    currents i s 28. 25 amps/vol t (0. 0354 ohms)

    compared to the 27. 85 amps/vol t (0.0359 ohms)

    derived frcm Dw ghts equati on. The curve f i t

    of the measured data to the prediction is also

    very good for thi s plat form The accuracy of

    the calculation appears to be as good as the

    expected accuracy obtai ned from using the gauss

    meter.

    These resul ts confi rmed our beli ef that

    the poor correl ati on for the other pl atforms

    surveyed was due to i naccurate cathode

    potent ial data. Future surveys w 11 include

    the potent i al of the members supporti ng the

    anodes so that accurate cathode potenti al s can

    be used i n the cal culati on.

    ONCLUSI ON

    Dw ghts equati ons can be used to

    cal cul ate accurate anode current output from

    structure potent i al survey data usi ng the

    method gi ven i n NACE RP-01-76, section 5,

    appendix 4. The qual i ty of data required for

    accurate calculations is wel 1 w thin the reach

    of a typfcal structure potenti al survey,

    provided the fol l ow ng steps are taken:

    *

    Anode potent i als shoul d be taken in the

    mddle of the anode rather than the ends.

    *

    The measured anode potenti al shoul d be

    corrected for IR drop before the current is

    calcul ated.

    *

    Cathode potent ial s shoul d be taken on

    the member support i ng the anode.

    *

    The geometry of at least some of the

    anodes shoul d be measured. Ori gi nal di mensi ons

    may be used i f the anode shape is found not to

    have changed substanti al l y since i nstal l ati on.

    A visua1 i nspection of the anodes was

    suff Ici ent i n most cases.

    2. The measured potent i al s of t he anodes

    i n thi s survey var i ed wdel y. Less than hal f

    of the anodes surveyed met or exceeded the

    potent i al expected for the a110YS used. Ei ther

    the qual ity control for anode manufacture is

    not as good as expected or the long term

    performance of these anodes i s not wel 1 known.

    3. Al 1 anodes sur veyed had unequa1

    currents i n the two standoffs w th some anodes

    havi ng 75% of thei r current i n one support.

    The expected cause i s poor adhesion between the

    core and the al umnum

    Fortunatel y, one pl atform i n the survey

    was found to have very consistent cathode

    potenti als over the entire structure, i ncludi ng

    l egs, nodes and cross members. Because of

    thi s, we deci ded to survey every anode on this

    st ructure as a test of the cal cul at i on. Data

    f or t hi s pl at form i s gi ven i n Fi gure 5. The

    correl ati on between cal cul ated and measured

    385

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    TABLE 1

    SURVEY POTENTIAL ANO CURRENT OATA

    ANOOE

    ANOOE

    CORRECTEO CATHODE MEASUREO CALCULATE

    POTENTIAL

    POTENTI AL POTENTI AL CURRENT CURRENT

    IN VOLTS

    IN VOLTS

    IN VOLTS IN AMPS

    IN AMPS

    1

    2

    3

    4

    5

    6

    7

    8

    9

    10

    11

    12

    13

    14

    15

    16

    17

    18

    19

    20

    21

    22

    23

    24

    25

    26

    27

    28

    29

    30

    31

    32

    33

    34

    35

    36

    37

    38

    39

    40

    41

    42

    43

    44

    45

    46

    47

    48

    49

    50

    51

    52

    53

    54

    55

    56

    57

    -0.951

    -0.952

    -0.958

    -0.963

    -0.963

    -0.964

    -0.966

    -0.968

    -0.971

    -0.972

    -0.972

    -0.972

    -0.973

    -0.974

    -0.975

    -0,975

    -0.976

    -0.979

    -0.979

    -0.979

    -0.980

    -0.981

    -0.981

    -0.982

    -0.983

    -0.987

    -0.990

    -0.990

    -0.993

    -0.995

    -0.995

    -0.996

    -0.997

    -0.998

    -0.998

    -0.999

    -1.000

    -1.000

    -1.001

    -1.002

    -1 003

    -1.003

    -1.004

    -1.004

    -1.004

    -1.004

    -1.004

    -1.007

    -1.007

    -1.009

    -1.009

    -1.010

    -1.016

    -1.033

    -1.034

    -1.041

    -1.043

    -0.953

    -0.953

    -0.965

    -0.970

    -0.965

    -0.965

    -0.969

    -0.970

    -0.974

    -0.977

    -0.976

    -0.974

    -0.978

    -0.978

    -0.987

    -0.977

    -0.982

    -0.985

    -0.982

    -0.982

    -0.983

    -0.987

    -0.985

    -0.989

    -0.988

    -0.996

    -0.996

    -0.994

    -0.998

    -1.003

    -1.003

    -1.004

    -1.004

    -1.004

    -1.006

    -1.007

    -1.008

    -1.009

    -1.009

    -1.010

    -1.012

    -1.012

    -1.014

    -1.010

    -1.010

    -1.008

    -1.009

    -1.009

    -1.013

    -1.017

    -1.017

    -1.015

    -1.019

    -1.046

    -1.047

    -1.052

    -1.053

    -0.945

    -0.950

    -0.921

    -0.935

    -0.945

    -0.957

    -0.945

    -0.945

    -0.947

    -0.935

    -0.945

    -0.947

    -0.945

    -0.945

    -0.934

    -0.961

    -0.945

    -0.934

    -0.960

    -0.953

    -0.950

    -0.945

    -0.948

    -0.945

    -0.945

    -0,935

    -0.945

    -0.959

    -0.948

    -0.945

    -0.945

    -0.945

    -0.957

    -0.935

    -0.945

    -0.945

    -0.947

    -0.934

    -0.950

    -0.956

    -0.945

    -0.953

    -0.945

    -0.960

    -0.959

    -0.961

    -0.958

    -0.985

    -0.958

    -0.957

    -0.945

    -0.964

    -0.985

    -0.970

    -0,955

    -0.980

    -0.945

    0,525

    0.25

    1.4

    1.55

    0.47

    0.20

    0.54

    0.52

    0.70

    1.05

    0.80

    0.37

    1.05

    0.77

    2.60

    0.50

    1.18

    1.30

    0.53

    0.70

    0.62

    1.25

    0.80

    1.40

    1.13

    1.90

    1.20

    0.95

    1.10

    1.66

    1.62

    1.60

    1.40

    1.35

    1.75

    1.75

    1.75

    2,00

    1.65

    1.72

    1.80

    1.85

    2.20

    1.37

    1.20

    0.90

    1.00

    0.43

    1.25

    1.70

    1.77

    1.05

    0.55

    2.75

    2.75

    2.25

    2.20

    0.24

    0.09

    1.21

    0.98

    0.56

    0.22

    0.66

    0.71

    0.76

    1.17

    0.86

    0.74

    0.92

    0.91

    1.48

    0.46

    1.02

    1.42

    0.60

    0.82

    0.92

    1.17

    1.02

    1.21

    1.21

    1.70

    1 41

    0.99

    1.40

    1.61

    1.61

    1.63

    1.30

    1.93

    1.71

    1.73

    1.71

    2.10

    1.64

    1.51

    1.85

    1.64

    1.93

    1.41

    1.41

    1.32

    1.41

    0.67

    1.53

    1.67

    2.01

    1.42

    0.94

    2.12

    2.56

    1.99

    3.02

    386

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    NODE POTENTI L DISTRIBUTION

    %OF ANODES PER GROUP

    951-975 976- 1000

    1001- 1025 1026- 1050

    ANODE POTENTIAL -MILLIVOLTS )

    Fig. node potential distribution.

    Fig. 2GOOd anode.

    F ig . 3Bad anode .

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    388

    ANODE OUTPUT COMPARISON

    C LCUL TED VS ME SURED

    AMPS OF CURRENT

    3. 5

    I

    MESURED CURRENT

    +CALCULATED CURREN -

    DATA FROM ALL PLATFORMS SURVEYED

    Fi g. 4Anode ou tp ut compar ison- dat a fr om al l platf orms sur ve yed .

    ANODE OUTPUT COMPARISON

    C LCUL TED VS ME SURED

    AMPS OF CURRENT

    3. 5

    - .. - - . .. . _. _r_.

    MEASURED CURRENT

    + CALCULATf=D CURRENT

    DATA ON SINGLE PLATFORM

    Fig . 5Anode out pu t comper feo n-d eta on ei ngl e plat form.