Optimization of metallic magnetic calorimeters

with embedded 163Ho Loredana Gastaldo, Enss Christian, Fleischmann Andreas, Hassel Clemens, Hengstler Daniel, Hähnle Sebastian, Kempf Sebastian, Krantz Matthäus, Wegner Mathias Dorrer Holger, Düllmann Christoph, Eberhardt Klaus, Kieck Tom, Schneider Fabian, Wendt Klaus Köster Ulli Türler Andreas Marsh Bruce, Day Goodacre Tom, Johnston Karl, Rothe Sebastian, Stora Thierry, Veinhard Matthieu

163Ho and neutrino mass

n p p p n n

e-

e-

e-

e- n p p p n n n

e-

e-

p

eν

e-

e- e-

Atomic de-excitation: •X-ray emission •Auger electrons •Coster-Kronig transitions

A non- zero neutrino mass affects the de-excitation energy spectrum

Calorimetric measurement . . . . . . .

eν

C16366

*16366

e*163

6616367

DyDy

DyHo

E+→

+→ ν • τ1/2 ≅ 4570 years

• QEC = (2.555 ± 0.016) keV

(2*1011 atoms for 1 Bq)

M. Wang, G. Audi et al., Chinese Phys. C 36, 1603, (2012)

163Ho QEC-value

C16366

*16366

e*163

6616367

DyDy

DyHo

E+→

+→ ν • τ1/2 ≅ 4570 years

• QEC = (2.555 ± 0.016) keV

(2*1011 atoms for 1 Bq)

M. Wang, G. Audi et al., Chinese Phys. C 36, 1603, (2012)

Calorimetric measurements

Measurements of x-rays Gatti et al., 1997

ECHo, 2012

C16366

*16366

e*163

6616367

DyDy

DyHo

E+→

+→ ν • τ1/2 ≅ 4570 years

• QEC = (2.555 ± 0.016) keV

(2*1011 atoms for 1 Bq)

Penning Trap Mass Spectroscopy

Direct measurement of the mass difference of 163Ho and 163Dy as prerequisite to a determination of the electron neutrino mass S. Eliseev et al., Phys. Rev. Lett., in print (2015)

QEC = (2.833 ± 0.030stat ± 0.015syst) keV

M. Wang, G. Audi et al., Chinese Phys. C 36, 1603, (2012)

163Ho QEC-value

Calorimetric measurements

Measurements of x-rays Gatti et al., 1997

ECHo, 2012

C16366

*16366

e*163

6616367

DyDy

DyHo

E+→

+→ ν • τ1/2 ≅ 4570 years

• QEC = (2.555 ± 0.016) keV

(2*1011 atoms for 1 Bq)

Penning Trap Mass Spectroscopy

Direct measurement of the mass difference of 163Ho and 163Dy as prerequisite to a determination of the electron neutrino mass S. Eliseev et al., Phys. Rev. Lett., in print (2015)

QEC = (2.833 ± 0.030stat ± 0.015syst) keV

To reduce uncertainties in the analysis: QEC determination within 1 eV PENTATRAP (MPIK HD)

M. Wang, G. Audi et al., Chinese Phys. C 36, 1603, (2012)

163Ho QEC-value

Calorimetric measurements

Measurements of x-rays Gatti et al., 1997

ECHo, 2012

( )( )

( )( )

∑ Γ+−

Γ

−−−Α=

H2

H2HC

H

2H2

CEC

22

CECC

4

201

EE

BEQ

mEQ

dE

dWH

πϕν

MI MII

NI NII

OI OII

OI

QEC = 2.8 keV

163Ho QEC-value

Requirements for sub-eV sensitivity in ECHo

Statistics in the end point region • Nev > 1014 → A ≈ 1 MBq

Unresolved pile-up (fpu ~ a ⋅ τr) • fpu < 10-5 • τr < 1 µs a ~ 10 Bq • 105 pixels

Precision characterization of the endpoint region • ∆EFWHM < 3 eV

fpu = 10-5 ∆EFWHM = 3 eV

Statistics in the end point region • Nev > 1014 → A ≈ 1 MBq

Unresolved pile-up (fpu ~ a ⋅ τr) • fpu < 10-5 • τr < 1 µs a ~ 10 Bq • 105 pixels

Precision characterization of the endpoint region • ∆EFWHM < 3 eV

Low temperature

Metallic Magnetic Calorimeter

fpu = 10-5 ∆EFWHM = 3 eV

Requirements for sub-eV sensitivity in ECHo

∼ 1 %

Mea

sure

d en

ergy

E

[keV

]

Photon energy E [keV]

∆E [e

V]

MMCs: 1d-array for soft x-rays (T=20 mK)

Rise Time: 90 ns Non-Linearity < 1% @6keV

∆EFWHM = 1.6 eV @ 6 keV

250 µm

Reduction un-resolved pile-up

Definition of the energy scale

Reduced smearing in the end point region

Successful production and test of the first prototype

MMCs: Microwave SQUID multiplexing

Sebastian Kempf, talk on Tuesday

Meander

Source

Sensor

• Absorber for calorimetric measurement ion implantation @ ISOLDE-CERN in 2009 on-line process • About 0.01 Bq per pixel • Operated over more than 4 years

First detector prototype for 163Ho

L. Gastaldo et al., Nucl. Inst. Meth. A, 711 (2013) 150

P. C.-O. Ranitzsch et al., http://arxiv.org/abs/1409.0071v1

Absorber

• Rise Time ~ 130 ns • ∆EFWHM = 7.6 eV @ 6 keV (2013) • Non-Linearity < 1% @ 6keV • Synchronized measurement of 2 pixels

MII

MI

NII

NI

144Pm

OI

First calorimetric measurement of the OI-line

EH bind. EH exp. ΓH lit. ΓH exp

MI 2.047 2.040 13.2 13.7

MII 1.845 1.836 6.0 7.2

NI 0.420 0.411 5.4 5.3

NII 0.340 0.333 5.3 8.0

OI 0.050 0.048 5.0 4.3 P. C.-O. Ranitzsch et al ., http://arxiv.org/abs/1409.0071v1) L. Gastaldo et al., Nucl. Inst. Meth. A, 711, 150-159 (2013)

QEC = (2.843 ± 0.009stat - 0.06syst) keV

Calorimetric spectrum

MII

MI

NII

NI

144Pm

OI

Detector design and fabrication: • Increase activity per pixel • Stems between absorber and sensor

Understanding of the 163Ho spectrum: • Investigate undefined structures

High purity 163Ho source: • Background reduction

144Pm

Where to improve

NI

Requirement : >106 Bq >1017 atoms (n,γ)-reaction on 162Er

- High cross-section

- Radioactive contaminants Excellent chemical separation

Available 163Ho source:

~ 1018 atoms

Only 166mHo

: (n,γ)-reaction on 162Er High purity 163Ho source

ECHo requirements: 166mHo/ 163Ho < 10-9

Offline mass separation: RISIKO, Mainz University ISOLDE-CERN

Energy /keV

Coun

ts/c

hann

el

• Offline implantation @ISOLDE-CERN using GPS and RILIS • Chemically purified 163Ho source • maXs-20: - sandwich sensor design - absorber connected to sensor through stems - 16 pixels

Detector chip for second 163Ho implantation 250µm

0.

5 m

m

New detectors ready for … Mounted on a cold arm of a dry cryostat

Mounted on a cold arm of a dry cryostat

NI

OI MI

NII MII

preliminary

… first results NEW ( about 2 days)

… first results

MI

MII

NI

NII

OI

OLD (more then 1 month )

NI

OI MI

NII MII

preliminary

• Activity per pixel A ~ 0.2 Bq • Baseline resolution ∆EFWHM ~ 5 eV • Symmetric detector response • No strong evidence of radioactive contamination in the source

NEW ( about 2 days)

• Activity per pixel A ~ 0.2 Bq • Baseline resolution ∆EFWHM ~ 5 eV • Symmetric detector response • No strong evidence of radioactive contamination in the source

NI

OI MI

NII MII

preliminary

… first results

MI

MII

NI

NII

OI

NEW ( about 2 days)

Characterisation of spectral shape

MII

MI

NII

NI

144Pm

OI

Estimate the effect of • Higher order excitation in 163Dy • 163Ho ion embedded in Au

A. Faessler et al. J. Phys. G 42 (2015) 015108

R. G. H. Robertson Phys. Rev. C 91, 035504 (2015)

A. Faessler et al. Phys. Rev. C 91, 045505 (2015)

A. Faessler et al. Phys. Rev. C 91, 064302 (2015)

Characterisation of spectral shape

MII

MI

NII

NI

144Pm

OI

Estimate the effect of • Higher order excitation in 163Dy • 163Ho ion embedded in Au

Structures present also in new data

High purity 163Ho source has been produced

163Ho ions have been successfully implanted in offline process @ISOLDE-CERN

Conclusions and outlook

NI

OI MI

NII MII

preliminary

Prove scalability with medium large experiment ECHo-1K

• A ∼ 1000 Bq High purity 163Ho source (produced at reactor) • ∆EFWHM < 5 eV • τr< 1 µs • multiplexed arrays microwave SQUID multiplexing

• 1 year measuring time 1010 counts = Neutrino mass sensitivity mν < 10 eV Just approved Research Unit FOR 2202/1 „Neutrino Mass Determination by Electron Capture in Holmium-163 – ECHo“

ECHo-1M towards sub-eV sensitivity

Conclusions and outlook

Thank you! Department of Nuclear Physics, Comenius University, Bratislava, Slovakia Fedor Simkovic Department of Physics, Indian Institute of Technology Roorkee, India Moumita Maiti Goethe Universität Frankfurt am Main Udo Kebschull, Panagiotis Neroutsos Institute for Nuclear Chemistry, Johannes Gutenberg University Mainz Christoph E. Düllmann, Klaus Eberhardt, Holger Dorrer, Fabian Schneider Institute of Nuclear Research of the Hungarian Academy of Sciences Zoltán Szúcs Institute of Nuclear and Particle Physics, TU Dresden, Germany Kai Zuber Institute for Physics, Humboldt-Universität zu Berlin Alejandro Saenz Institute for Physics, Johannes Gutenberg-Universität Klaus Wendt, Sven Junck, Tom Kieck Institute for Theoretical and Experimental Physics Moscow, Russia Mikhail Krivoruchenko Institute for Theoretical Physics, University of Tübingen, Germany Amand Fäßler Institut Laue-Langevin, Grenoble, France Ulli Köster Kirchhoff-Institute for Physics, Heidelberg University, Germany Christian Enss, Loredana Gastaldo, Andreas Fleischmann, Clemens Hassel, Sebastian Kempf, Mathias Wegner Max-Planck Institute for Nuclear Physics Heidelberg, Germany Klaus Blaum, Andreas Dörr, Sergey Eliseev, Mikhail Goncharov, Yuri N. Novikov, Alexander Rischka, Rima Schüssler Petersburg Nuclear Physics Institute, Russia Yuri Novikov, Pavel Filianin Physics Institute, University of Tübingen, Germany Josef Jochum, Stephan Scholl Saha Institute of Nuclear Physics, Kolkata, India Susanta Lahiri

∆N

/N

6 10-13 above QEC-1eV

5 10-9 above QEC-20eV

163Ho and neutrino mass: sub-eV sensitivity

MI MII

NI NII

OI OII

OI

Statistics in the end point region • Nev > 1014 → A ≈ 1 MBq

QEC = 2.8 keV

163Ho and neutrino mass: sub-eV sensitivity

Statistics in the end point region • Nev > 1014 → A ≈ 1 MBq

Unresolved pile-up (fpu ~ a ⋅ τr) • fpu < 10-5 • τr < 1 µs a ~ 10 Bq • 105 pixels

3

2

1

0

1

3

2

1

0

1

3

2

1

0

1

∆t = 0.5 µs τr = 0.1 µs τr = 5 µs

163Ho and neutrino mass: sub-eV sensitivity

Statistics in the end point region • Nev > 1014 → A ≈ 1 MBq

Unresolved pile-up (fpu ~ a ⋅ τr) • fpu < 10-5 • τr < 1 µs a ~ 10 Bq • 105 pixels

Precision characterization of the endpoint region • ∆EFWHM < 2 eV

fpu = 10-5 ∆EFWHM = 3 eV

• Rise Time ~ 130 ns • ∆EFWHM = 7.6 eV @ 6 keV (2013) ∆EFWHM = 2.4 eV @ 0 keV (2014) • Non-Linearity < 1% @ 6keV

Calorimetric spectrum

IN OUT

Microwave SQUID Multiplexer for the Readout of Metallic Magnetic Calorimeters S.Kempf et al., J. Low. Temp. Phys. 175 (2014) 850-860

• Single HEMT amplifier and 2 coaxes to read out 100 - 1000 detectors

No events

Event in 3

MMCs: Microwave SQUID multiplexing

9.1

mm

15.5 mm

Elbow coupler MMC rf-SQUID

MMCs: Microwave SQUID multiplexing

Microwave SQUID Multiplexer for the Readout of Metallic Magnetic Calorimeters S.Kempf et al., J. Low. Temp. Phys. 175 (2014) 850-860

QEC determination of 163Ho

Penning Trap mass spectrometry

Precise measurement of the 163Ho and 163Dy atomic mass

2222zc νννν ++= −+

Talk by Klaus Blaum yesterday

QEC determination of 163Ho

Penning Trap mass spectrometry

First experiments at TRIGA-TRAP (Uni-Mainz) in 2014 * • Development of efficient Ho ion source using laser ablation • Uncertainties on 163Dy and 163Ho mass reduced by a factor of 2 • Know-how to be applied in SHIPTRAP

Presently: SHIPTRAP (GSI) • QEC determination with smaller uncertainties • Define scale of the experiment

*Preparatory studies for a high-precision Penning trap measurement of the 163Ho electron capture Q-value F. Schneider et al., submitted to EPJ

Magnetic sector-field Mass Spect. 30 kV two stage acceleration

60° double focussing separator magnet

Mass resolution: 𝑚𝛥𝑚

= 500 - 1000

Suppression of neighboring masses > 105

• Optimized resonant laser ionization for Ho efficiency larger than 24%

• Successful tests using 165Ho

Mass separation @ RISIKO

• off-line mass separator

( )( )

( )( )

∑ Γ+−

Γ

−−−Α=

H2

H2HC

H

2H2

CEC

22

CECC

4

201

EE

BEQ

mEQ

dE

dWH

πϕν

163Ho and neutrino mass

MI MII

NI NII

QEC = 2.555 keV

OI OII

OI

( )( )

( )( )

∑ Γ+−

Γ

−−−Α=

H2

H2HC

H

2H2

CEC

22

CECC

4

201

EE

BEQ

mEQ

dE

dWH

πϕν

MI MII

NI NII

OI OII

OI

163Ho and neutrino mass

QEC = 2.8 keV

Detector chip for second 163Ho implantation • Offline implantation @ISOLDE-CERN using GPS and RILIS • Chemically purified 163Ho source • maXs-20: - sandwich sensor design - absorber connected to sensor through stems Optimization of photo-lithographic processes

1.5 µm 5 µm

5 µm

AZ NLOF2070

Background Background sources:

• Environmental radioactivity Material screening

• Cosmic rays Underground labs

• Induced secondary radiation by cosmic rays μ-Veto

• Radioactivity in the detector

Study of background sources through:

• Monte Carlo simulations • Dedicated experiments

Underground measurements in Modane

Screening facilities • Uni-Tübingen • Felsenkeller

Separation at CERN/ISOLDE December 2014 • Off-line process • 2 new chips to test! … each with 16 pixel detector arrays

Mass separation @ISOLDE-CERN

Chemically purified 163Ho source in ISOLDE GPS mass separtion systems

Material constants • W, x: Crystal field parameters

• A: Hyperfine coupling strength

Thermodynamical properties of Au:Ho

Gold (fcc)

4f-Electrons (Ho)

• Magnetic moment of Ho3+ • Crystal field • Zeeman effect • Hyperfine interaction

J = 8 B I = 7/2

B

• Investigation of solid state effects • Determination of the maximum activity per pixel

• Magnetization „High-T“ measurement (2K – 300K)

− easy − no influence from Hyperfine interaction Determine W = -0.112

x = -0.357 • Heat capacity

Determine A

Deriving material constants from measurements

Thermodynamical properties of Au:Ho

Heat capacity measurement of Au:Ho

• 165Ho implanted in MMC absorbers • Acceleration voltage 30 kV • 3 chips • Number of ions per chip :

2*1011 / 2*1012 / 2*1013

(1Bq / 10Bq / 100Bq)

163Ho 165Ho

J 8 8

I 7/2 7/2

HoCC+C

E

T

M

+∂∂

∝abssens

S ΔΦ

Define the maximum activity per pixel

Gold atoms in implanted volume (160*160*0.01 µm3): ~ 1013

1 Bq 10 Bq 100 Bq

Dilute alloy High concentrated Ho layer Thin Ho layer

Heat capacity measurement

Gold atoms in implanted volume (160*160*0.01 µm3): ~ 1013

1 Bq 10 Bq 100 Bq

Dilute alloy High concentrated Ho layer Thin Ho layer

Ready to be measured

Heat capacity measurement