ONTARIO GUIDELINES

FOR

CLASSIFICATION

OF

PESTICIDE PRODUCTS

sB965.0581984

PESTICIDES ADVISORY COMMITTE=E

November-, 1984

The HonourableAndrew S. Brandt

Ministry/ Ministerof the Dr. Allan E. Dyer

.. Environment Deputy Minister

"I

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TABLE OF CONTENTS

Page

Introduction ...................................................... 1

Definition ........................................................ 1

Classification Procedure .......................................... 1

Schedules Described ............................................... 2

Schedules 1 and 5 ............................................... 23Schedule 2 .................................................... 3

Schedule 3 ...................................................... 3Schedule 4 and 6 ................................................ 4

Guidelines for Oral, Dermal and InhalationToxicity Evaluation .............................................. 5

Classification Criteria for Control ProductsClassified "Restricted" Under the Pest Control

Products Act ..................................................... 6

Review of Previously Classified Active Ingredientsand/or Previously Classified Pesticide Products .................. 6

Packaging Guidelines ..............................................7 & 8

Information Required for Pesticides ContainingNew or Previously Unclassified ActiveIngredients (see also Appendix I) ................................9 & 10

Information Required for Classification of newPesticide Products Containing PreviouslyClassified Active Ingredients (see also Appendix V... .... o ...... 11

Information Required for Classification ofFertilizer-Pesticide Products ContainingPreviously Classified Active PesticideIngredients* (see also Appendix V., .... o .................. 11

Additional Information, .......... o.o ..... o .......... ... ooo ... ... 12

Classification of IBT* Supported Compounds, ........... o ........ ... 12

Appendix I .......................................................13 - 31

Appendix II ......................................................32 & 33

135 St. Clair Ave. W. 135 quest, avenue St. Clair

Suite 100 Bureau 100Toronto, Ontario Toronto, Ontario

MW 1P5 MW 1P5

416/965-7048 416/965-7048

ONTARIO GUIDELINES FOR

CiASSIFICAT310N OF PESTICIDES PF40UJ .TS

INT )DUCTION

under the authority of the Pesticides Act, Revised Statutes ofOntario, 1980 and Regulation 751 administered by the Ministry of theEnvironment, all pesticide products sold in the Province of Ontariomust be classified and assigned a schedule, and subsequent marketing ofeach product must be in accordance with the regulations relating to the

classification. Six schedules exist and are described herein.

A function of the Pesticides Advisory Ccmmittee is to classifyeach product. The resulting classification, when published in the

Ontario Gazette, becomes an amendment to the regulations under thePesticides Act.

DEFINITION

Pesticides are defined in the Pesticides Act and include

products registered under the federal Pest Control Products Act, andfertilizer-pesticide products registered under the federal Fertilizer

Act. The Ontario classification takes into consideration the

marketable formulation when considering toxicity, but the active

ingredient when considering persistence and movement potential of

parent compounds and/or their metabolites. Specific use patternsrelating to environmental impact or to the humaneness of pest animalcontrol are also considered.

CLASSIFICATION PR')CEDURE

All applications for classification must be to the

Chairman, Ontario Pesticides Advisory Committee, Ministry of the

Environment, Suite 100, 135 St. Clair Avenue West, Toronto, OntarioM4V 1P5.

Information required for classification purposes is described onpages 9-11.

-2-

SQHEMUIFS DESCRIBED

Schedules 1 and 5

Schedule 1 pesticides are restricted and can only be used underthe authority of a specific use permit. Schedule 5 pesticides arelimited to application on agricultural land. Sales of both Schedule 1and Schedule 5 pesticides are permitted only through wholesale vendorsand holders of Class 1 retail vendor licences. A record must be keptof each sale.

The criteria for defining Schedule 1 include:

1) pesticides that pose a serious hazard to public healthand/or the natural environment.

2) Toxicity ratings as described in Column 1 of Table 1 onpage 5.

3) pesticides that are persistent and/or give rise topersistent metabolites that produce undesirable side effectson nontarget organisms either by acute or chronic toxicity.

4) pesticides which through their mode of action may inflictunnecessary suffering to pest vertebrate animals.

Criterion for defining Schedule 5

pesticides normally in Schedule 1 but which are essentialfor the protection of agricultural crops and for whichsuitable substitutes do not exist.

-3-

schedule 2

Pesticides and/or pesticide formulations in this group arerestricted to agriculturalists, licensed exterminators and registered

custom sprayers. Sales are permitted through wholesale vendors andholders of Class 1 and Class 2 retail vendor licences. Sales records

must be kept.

The criteria for defining Schedule 2 include:

1) pesticides that could pose a hazard but are consideredsuitable for use by the experienced professional applicatorsif used according to recanmended procedure.

2) Toxicity ratings as described in Column 2 of Table 1 on

page 5.

3) organic pesticides that do not present problems of long termpersistence or accumulation in biological tissues, and thoseinorganic pesticides that may present a degree of hazard tothe environment.

Schedule 3

Pesticides and/or pesticide formulations in Schedule 3 may bemade available for domestic purposes as the hazards accompanying theiruse are considered minimal. Sale of Schedule 3 pesticide products is

restricted to wholesale vendors and holders of Class 1, Class 2 orClass 3 retail vendor licences. Sales records are not required.

The criteria for defining Schedule 3 include:

1) pesticides or dispersants should pose minimal hazards to theenvironment or to public health if used according torecommended procedure.

2) toxicity ratings as described in Column 3 of Table 1 onpag e 5.

3) organic pesticides that are short-lived and do not produceeither persistent or toxic metabolites.

4) those inorganic pesticides that present a minimal environ-mental hazard.

5) product residues should not pose a problem when 'empty'containers are disposed of in municipal garbage.

-4-

Schedule 4 and 6

Schedule 4

Pesticides and/or pesticide formulations in this group are thosethat can safely be handled by any type of outlet and would be available

for sale in food handling establishments. Wholesalers are required to

have at the lease a limited wholesale vendor licence but no vending

licence is required at the retail level.

the criteria for defining this group include:

1) pesticide formulations that can be considered relativelyinnocuous to humans. This includes compounds that arecurrently available for non-pesticide uses, or are used asinsect or animal repellents classified as "Domestic" underthe federal Pest Gontrol Products Act, or are pesticidesformulated in very low concentrations.

2) toxicity ratings as described in Column 4 of Table 1 on page

5. Products for which the LD50 values are less than

5000 mg/kg but greater than 2500 N/kg may be accepted ifadditional product toxicological data are presented.

3) pesticides that are of no known hazard to the environment orto domestic pets.

4) all products must carry a federally approved "Domestic"label.

5) maximum package content must not exceed 1 kilogram by weightor 1 litre by volume, and all containers must be physicallyinspected and approved by the Pesticides Advisory Committeeafter acceptance of the active ingredients as Schedule 4candidates. (See packaging guidelines, pages 7 & 8.)

Schedule 6

Pesticide products assigned to this group are identical to thosein Schedule 4 but there is no limit to package size and the productsmay also be designated for commercial use. Sale of Schedule 6

pesticide products may be sold by wholesale vendors, limited wholesalevendors and holders of Class 1, Class 2, or Class 3 retail vendorlicences.

-5-

GUIDBUNES FOR ORAL, DONAL AND DhtA MON =CITY EVALUATION

TABLE 1 Schedules Schedules Schedules Schedules1 and 5 2 3 4 and 6

Acute Oral LD50(single dose-mg/kg) 1) 0-50 50-500 500-5000 over 5000

(1)

Acute Dermal LD50single dose-mg/kg) 0-100 100-1000 1000 -10000 over 10000

Acute Inhalation LC50(continuous for 8hours - mg/L air) 0-2 0-20 20-200 over 200

(1) an of >= 2500 may be accepted for a schedule 4 or 6 candidate product ifindividual product toxicological data are provided.

Test Animals for toxicological data in order of preference:

(a) primates(b) dogs and cats(c) rodents(d) fish and birds

Classification will be based on lowest valid toxicity values. Other effectsconsidered - carcinogenesis, teratogenesis, mutagenesis and chronic toxicity.

-6-

CRITERIA FOR CLASSIFYING FERTILIZERS OONTAINING PESTICIO S

Fertilizers containing one pesticide active ingredient

Fertilizers containing only one pesticide active ingredient willbe classified according to the classification for that activeingredient.

Fertilizers containing more than one pesticide active ingredient

a) Except as described in (b) below, fertilizers containing twoor more pesticide active ingredients will not be acceptedfor normal classification and will be classified under

Schedule 1.

b) Fertilizers containing two or more herbicides that arecomplementary for the control of a similar group of weedswill be classified according to the total percentage of allactive ingredients present, e.g. 2,4-D, mecroprop, dicambafor broad leaf weed control in turf grass.

CLASSIFICATION CRITERIA FOR CONTROL PRODUCTS CLASSIFIEDwRESTRICTEEr UNDER THE PEST CCN ROL PF40DUCTS ALT

Where a pesticide product is submitted for classification underthe Pesticides Act, and contains an active ingredient or a mixture ofactive ingredients acceptable under Schedule 3 or 6 but carries afederal label exclusively "Restricted" under The PCP Act, that productwill be classified in a schedule no less restrictive than Schedule 2.The criteria for Schedules 1, 2 and 5 will be followed when classifyingall other exclusively "Restricted" control products.

REVIEW OF PREVIOUSLY CLASSIFIED ACTIVE INGREDIENTSAND/OR PREVIOUSLY CLASSIFIED PESTICIDE PRODUCTS

Active ingredients are reviewed from time to time as additionaltechnical data became available. Reclassification to a more restric-tive or a less restrictive schedule may result, or the compound mayremain in its original schedule. If, in the Committee's opinion, amore restrictive classification is deemed necessary, Registrants willbe invited to appear before the Committee for discussion and clarifica-tion.

Where a Registrant desires a product review for the purpose ofreclassification to a less restrictive category, a submission must beprovided in writing, accompanied by supportive documents.

-7-

PACKAGING GUIDELINES: SCHEDJIE 4 PESTICIDE PPODUCIS CNLY

1. INITIAL QUALIFICATION

All products must carry a federally approved "Domestic" label, andmust meet Schedule 4 active ingredient classification guidelines.

2. MAXIMUM CDNTENT

Maximum package content must not exceed 1 kilogram by weight or 1litre by volume, and all containers must be submitted to the PesticidesAdvisory Cc miittee for physical inspection and approval.

3. SHAKER OR SIFTER CAN DISPENSERS

All shaker-can dispensers used in packaging pesticide products musthave an approved device for reclosure. Formulators are invited to

discuss those approved devices with the Committee. In some cases, a

simple plastic cap, similar to that used on coffee cans, may besufficient.

4. PRESSURIZED DISPENSERS

Every pressurized spray dispenser used in packaging pesticideproducts must have a cap, locking device or seal, so as to preventaccidental activation during transit, storage and display.

5. FOLDING PAPER RWD CARTONS

Folding paper-board cartons may be approved when the product, if

formulated as a granule, impregnated fabric, pellet, powder, particu-late (e.g. rodent bait), solid, slow-release generator, tablet or

wettable powder, is packaged in an acceptable inner liner (e.g. plastic

or foil liner).

6. PLASTIC BAGS OR POUCHFS

Plastic bags or pouches used to package rodent baits must besufficiently strong to prevent accidental spillage during transit,

storage and display, and must be packaged in an outer display carton.Individual bags or pouches, or those which, in the opinion of theCommittee, could be easily torn, will not be approved.

7. GLASS BOTTLES

Glass bottles shall not be used for packaging Schedule 4 pesticidesif, in the opinion of the Committee, such containers can be easilyshattered or broken during transit, storage and display.

8. PAPER BAGS

No paper bags will be allowed in Schedule 4.

Cont1d..........

-8-

PACKAGING GUIDELINES (Cont'd.)

9. OTHER LIMITATIONS

Where, in the opinion of the Ccmnittee, a pesticide containercan be mistaken for a food or toy container, the product will not bepermitted in Schedule 4.

All labels must contain suitable guidance for the general publicand must not be misleading.

10. APPROVAL OF NON-CONFORMING CONTAINERS

The Committee may approve non-conforming containers that, in itsopinion, warrant special consideration due to the type of product ormethod of application of that product.

Registrants are encouraged to discuss with the Catittee anypackaging improvements they may make in order to conform with theserequirements.

11. TRANSFER TO SCHEDULE 6

Domestic products containing only Schedule 4 active ingredients,but not meeting the packaging requirements, will be classified underSchedule 6.

-9-

INPOMMON REQUIRED FOR PESTICIDES OONMUNIM NEWOR PREVIOUSLY UNCLASSIFIED AL"11W II gee Appendix I)

A. General

1. Technical data sheet2. Seven copies of federally approved label3. Suitable method of analysis for residues of pesticide in

environmental and biological samples.

B. Use Precautions if not Described on Technical Data Sheet

1. Flammability2. Corrosiveness3. Storage stability4. Safety precautions for handling and application5. Decontamination and disposal6. anerngency procedure for accidental contamination

C. Container

1. Type and size of containers2. If classification in schedule 4 is requested, a sample of an

empty container complete with closures and labels must beprovided (see Schedule 4 packaging guidelines on pages 7 & 8).

D. Registration Information

1. Registration status (full or temporary)

2. P.C.P. classification (restricted, commercial or domestic)

3. Maximum Residue Limits

E. Toxicology

1. Technical material: acute oral, dermal, and inhalationtoxicity, subacute toxicity, teratogenicity, carcinogenicity,mutagenicity and other in vitro short term studies.Include the dose response slope from which the oral LD50 isderived.

2. Formulated material: acute oral, dermal and inhalationtoxicity.

F. Environmental and other Hazards

1. Information on persistence and movement of the pesticide insoil, water and air, and the metabolism of the compound inplants and animals.

Coat/.. .

-10-

G. Other Ingredients

1. The Committee reserves the right to request information or dataon carriers, solvents, inert materials, propellents, impurities

and other ingredients.

H. Source

1. Information prepared by: Name and address of manufacturerpreparing data and date of submission.

I. options

1. If a Report of New Registration (RNR) has been issued byAgriculture Canada, items listed in the RNR need not besubmitted by the registrant.

2. If registration is pending but close to completion, and theregistrant wishes to initiate the classification process,copies of the proposed label text may be submitted to befollowed upon registration by approved labels (See item A.2).

J. The Ccmnittee reserves the right to request additional data on-the toxicology of the active ingredient/s or other constituentsin the product.

-11-

II6KAMATION REQUIRED FOR CLASSIFICATION OF NEW PESTICIDE PFCCUC15ClON AINIM PREVIOUSLY CLASSIFIED ACTIVE II+X 2 MIENTS See Anpendlx I

A. Seven copies of federally approved label.

B. Registration status (full or temporary).

C. Type and size of containers.

D. If the product(s) is a candidate for Schedule 4 (Domestic classifi-cation with no controls) and the acute oral LD50 is greaterthan 2,500mg/kg but less than 5,00Ong/kg individual product toxico-logical data must be provided. These data should include theLD50 and the slope of the dose response curve from which it isderived. As an alternative, evidence of non-morbidity inexperimental animals given an oral dose of 500 mg/Kg may be

presented. Should this latter option, which is in the interests ofhumane treatment of test animals, be chosen, a test protocol isavailable from the offices of the Pesticides Advisory Committee.

E. Container approval is required for all Schedule 4 products. Anempty container complete with closure and label must be submitted.(See Schedule 4 packaging guidelines on pages 7 & 8.)

F. The Committee reserves the right to request additional data on thetoxicology of the active ingredient/s or other constituents in theproduct.

INFORMATION REQUIRED FOR CLASSIFICATION OF FERTILIZER-PESTICIDEPF4CZ S OONTA NIM PREVIOUSLY CLASSIFIED ACTIVE PESTICIDE INGREDIENTS*

See Appendix)

A. one copy of application for federal registration under theFertilizer Act.

B. Seven typewritten copies of federally approved label text.(Please do not send fertilizer bags.)

C. Fertilizer registration number.

D. Type and size of packaging.

E. The Cannittee reserves the right to request additional data on thetoxicology of the pesticide active ingredient/s or otherconstituents in the product.

-12-

ADDITIONAL INFORMATION

Section 6 of the Pesticides Act states:

"Unless exempt by the regulations, no personshall sell, offer to sell or transfer any pesti-cide unless the pesticide is classified by theregulations and except under and in accordancewith a licence that shall be for such class andin respect of each premises on, in or from whichthe pesticide is or will be sold, offered forsale or transferred. R.S.O. 1980, c,376, s.6."

It is in the Registrant's interest to submit all new products forclassification as early as possible following federal registration

under the P.C.P. Act. Failure to do so will delay the marketing of the

product in Ontario.

Additional information on classification can be obtained from theOntario Pesticides Advisory Ccmnittee, 9th Floor, 1 St. Clair AvenueWest, Toronto, (Postal address, Suite 100, 135 St. Clair Ave. WLM-st,

Toronto, MW 1P5,) telephone (416) 965-7048.

Enquiries concerning marketing and use, and requests for copies ofthe Pesticides Act, Revised Statutes of Ontario, 1980 and Regulation751 should be directed to the Ccnmercial and Agricultural ChemicalsSection, Ministry of the Environment, 7th Floor, 40 St. Clair AvenueWest, Toronto, Ontario, telephone 965-2401.

CLASSIFICATION OF IBT* SOPPOR ED 0MP0L )6

The suggested classification of active ingredients appears in theAppendix I (pages 13-31). Registrants are advised that certaincompounds having IBT involvement, and against which data gaps stillexist, may be classified in a more restrictive schedule than thatindicated. For further information please contact the Committee

Chairman.

*Industrial Biotest Laboratories

-13-

A P P E N D I X I

ONTARIO CLASSIFICATION OF PESTICIDE ACTIVE INGREDIENTS

Revised November 1984

S V 1MI-S

* Schedule 5 - Agriculturist Use Permit Exemption

+ Subject to Container Approval, otherwise Schedule 6

** With Fire Retardant

# Granular - Not for Broadcast Application

## Annt.ial Use Permit and Records of Location, Rates andAmounts Used

x Approved Animal Collar

xSR Approved Animal Collar. Slow Release Generator

xx Approved Resin Strip or Paraffin Block

M Manufacturing purposes only.

-14-

ACA Acaricides and IM Insecticides

s®. 4+ar

OODE OOMMCId OR CHEMICAL NAME (BRAND) 908.1 SCH.2 9CH.3 9CH.6

ABT I temephos (Abate) (Abate) II all

ACP I acephate (Orthene)I

I >40%I

=<40%

ADCI

aldicarb (Temik)

ALDI

aldrinall*

all

ALM I d-trans allethrinI

I I >10%I

=<10%

ALPI

aluminum phosphide (Phostoxin)I all*

AMC I aminocarb (Matacil)I

>12%*I

=<12%I

BAYI

propoxur (Baygon)

BAY I propoxur Approved Ant Trap

BAYI

propoxur

BDC I bendiocarb (Fican)

BDC Ibendiocarb Approved Ant Trap

BNSI

borax

BOAI

boric acid

BPCI

dienochlor (Pentac)

BRpI

branophos (Nexion)

BTB I Bacillus thuringiensis (Dipel)

BZE benzene

1

CAB ( carbaryl

CABI

carbaryl

CADI

carbon disulfide

CAFI

carbofuran

CFVI

chlorfenvinphos

CINI

crotoxyphos

CLDI

chlordane

COAI

coal tar acids

COOI

coal tar oils

cou coumaphos

(Sevin)

(Furadan )

(Birlane)

(Ciodrin)

(Oo-Ral )

I

>20%I

=<20%I

I I

I I

>80% I =<80% I =<10% I

xSR

I I I

=< 1%

I I

>70%I

=00%

I

>70%I

=<70%

allI

I

allI

allI

all

I I

I I>80% I

=<80%I

=<8%

I

I

allI

>10%*i

=<10%#

>20%*I

=<20% I

I >20% I =<20%

>50%I

=<50%

xSR

all

I all>0.5% I =<O.5%

-15-

ACA Acaricides and INS IrLsecticides (Omit.)SCH.4+oc

CODE a" m oR Qua NAME (BRAND) 908.1 SCH.2 9CH.3 SCHA

I I I I

I I I I I

COY1

terbufos (Counter)1

>2.5%* =<2.5% I1

CPNI

chloropicrin1

> 20%1

=< 20% 11

CPT1

carbophenothion (Trithion)1

> 60%* 1 =< 60% 11

CTC I carbon tetrachloride I I all

mm J cypermethrin (Rip-cord) > 15% =<15%

DCFI

dicofol (Kelthane) I

1

> 4% 1 =< 4%1

DDT I DDTI

allI I i

DEL1

deltamethrin (Decis)1

all*

DEMI

demeton (Systox)I

all* II I

DFB1

diflubenzuron (Dimilin)I I I

>10%1

=<10%

DIA1

diazinon1 1

>20%1

=<20%1

=< 1%

DIA1

diazinon granular or dust1

I I

1

=< 2%

DIE1

dieldrin1

all1

I

1

DIM1

dimethoate (Cygon) I

1>40% 1=<40%

1

DIN1

dinocap (Dikar)1 1

>10%1

=<10%1

=< 1%

DIS1

disulfoton (Dy-Syston)1 > 5%*1

=< 5% 1

1

DIX1

dioxacarb 1 1 >20% 1 =<20% 1 =< 2%

DNC1

dinitrocresol sodium salt (Elgetol)1 1

>10%1

=<10%

DPAI

diphenylaonine (No-Scald)I I

all1

DUB I chlorpyrifos (Dursban) (Lorsban) 1 1 >25% 1 =<25% 1 =< 1%

DVP I dichlorvos and relatedI I I

I actives (Vapona) 1 1 >15% 1=<15% 1 xSR

DYF fonofos (Dyfonate) >10%* =<10%

EDB1

ethylene dibranide1 1

>20%1

<20%

EDC1

ethylene dichlorideI I I

all

END1

endrin1

all

ESF1

endosulfan (Thiodan)1 1

> 6%I

=< 6%

ETH ( ethion1 1

> 5%I

=< 5%

gro ethylene oxide1 1

all1

-16-

ACA Acaricides and INS Insecticides (Don't)

DDDE DOHlMN OR CHEKICAL NAME (BRAND) SM.l SC H.2 scH.3

I I I I

I I I

FEL ( fensulfothion (Dasanit)I

>15%* I =<15% I I

FBT I

FEMI

fenbutatin oxide

fenitrothion

(Vendex)

(Sumithion)I I >50% I =<50% I

FETI

fenthion (Baytex) I I > 5%I

=< 5% I

FEVI

fenvalerate (Belmark) I

I

allI

=< 8%

I I I IS. R.

Fom formetanate hydrochloride (Carzol) >50%* =<50%

GARI

tetrachlorvinphos (Gardona) (I

, all

GOO I azinphos-methyl (Guthion)I

>20%* I =<20%

GUM

HCN

HEP

natural gum resins

hydrogen cyanide

heptachlor

(HCN)

I

alli

all1

IOJ iodofenphos (Novanol N)I

all

ISR isophenphos (Amaze) >50%* =<50% _< 5%

KDC potassium dichromateI

>10%I

=<10%

LAR lead arsenate >20%*I

=<20%I

LIN lindane (Lindane) >75% =<75%S

_< 5%1

MAL I malathion >65%I

=<65%

MBR

MED

Imethyl bromide

I methidathion

( Dowf ume )

(Supracide)

all

>25%* =<25% I =<2.5%

MFN I menazon (Sayfos) >7.4$I =<7.4%

> 5%MET I methoxychlor (Marlate)

MEv Imevinphos alpha isomer (Phosdrin) I all*

I

MGK I n-octyl bicyclohepteneI

dicarboximide ( MCF0 > 5%

MHB I methiocarb (Mesurol) I >3% =< 3%

MISI

methyl isothiocyanate (Vorlex) I >50% I =<50%

MIT I(Mitin FF) all

MML methcmyl (Lannate) I >30%* =<30% I =< 3%

scH.4+w

scH.6

1 =<10%

5%

5%

-17-

ACA Acaricides and INS Insecticides

OME 03*M OR CHMICAL NW (BRAND) SCH.l SCH.2 SCH.3

scH.4+orSCH.6

I

MOI Imineral oil (Dormant Oil) I I , I all

mom I methamidophos (Monitor) I >15%* I =<15% I =<0.5%

MOR I (Morestan) I I I all

MPR ( methoprene (Altosid) I I all

my metam sodiun (Vapam) all

NAL I naled (Dibrtm) I I >50% I=<50% I =<10%

NEO I tetramethrin I I I >10% I =<10%

NIA I nicotine I I > 4% I =< 4% I

ODM I oxydemeton-methyl (Metasystox) I I >10% I =<10%

oMI I propargite (Omite) I I I all

oxA oxamyl (Vydate) =>10%* <10% =< 3%

PBU I piperonyl butoxide (Synergist) I I I ` all

PCP I pentachlorophenol , I >20% I =<20% I =<0.1%

PDB I paradichlorobenzene (Moth-Killer) I I I I all

PPL I permethrin (Ambush) ( I I all

PHGI d-phenothrin ` I I I all

PHR I phorate (Thimet) I >15%* I =<15%

PHS I phosalone (zolone) I I >25% I =<25%

PIR I pirimicarb I I >20% ` =<20%

PLT I cyhexatin (Plictran) I I >50% I=<50% I

PRT I phosmet (Imidan) I I >50% I =<50%

PTH I parathion I all*

PYR I pyrethrins I I I > 1% ' =< 1%

PYR I pyrethrins metered aerosol commercial > 2% =< 2%

REz I resmethrin I I >10% I =<10%

RON I ronnel I I , > 5% I =< 5%

ROT I rotenone I I > 5% I =< 5% I =< 2%

RUE ` crufa ate (Ruelene) I I , all

-18-

ACA Acaricides and INS Insecticides (Can't)

CODE COMMON OR CHEMICAL NAME (BR&ND)

SFDI

sulfoxide synergist I

SFLI

sodium fluoride I

SFTI

sulfotepI

SIO I silicon dioxideI

SNPI

dimetilan (Snip) [I

[ I

SOAI

soap-insecticidal I

SUL I sulphur I

SUS sulphide sulphur (Lime sulphur)

TEDI

tetradifon (Tedion)I

THAI

isobormyl thiocyanacetateI

TnX I toxaphene (Hog-Mange Cure)I

TRII

trichlorfon (Dylox)I

TRN z-9-tricosene

WAX famphur (Warbex) I

SCH. 4+vrr

SCH.1 SCH.2 SCM.3 SCHA

I I

I I I all

>15%I

=05%I I

>10%* I =<10%

II

Iall

1285mg pert I

130.5 cm I

I I I

all

I I I all

all

I

I

I

I

>

all

2%

I

I =< 2%

allI

I I

I

I all

all

I I

FUN Fungicides

AAL

ASP

AUR

allyl alcohol

asphalt solids

auramine

(AA Soil Drench) I

(Pruning Paint)

(Benlate)

I

(Cady)

I

(Tersan)

(Gallex)

BML I benomyl

BNS I borax

CAPI

captan

CDDI

cadmium chloride

CTSI

cadimum sebacate

CNBI

chloroneb

CPNI

chloropicrin

CRG m-cresol

all

all

>20% =<20%

>50%

>70% 1 =<70%

all

all

=<10%

all

=<50%

-19-

FuN Fung is ides (OW O

00M OOMMON OR CHMOCAL NAME (BRAND) s®.1 SCH.2

SM.4iorSCH.3 sCH.6

CUB I

CUs

CUY

CUZ

copper as tribasic copper

sulphate

I copper sulphate

I copper oxychloride

copper as cupric hydroxide

I

I > 0%

I

I

I

I

all

all

all I

=<30% I

C YC cycloheximide (Acti-Dione) >0. 75% I=<0.75%

DAZ

DCH

dazcmet (Mylone)

dichlone (Phygon)

> 35% I =<35% I

allDEX fenaminosulf (Lesan) I > 10% I =<10%

DFT

DI K

captafol ( Di folatan)

dichloran (Botran)

I I all I

all I

DIN dinocap (Dikar) > 10% I =<10%

DNC dinitrocresol (Elg itol ) > 10% I =<10% I

DOD dodine (Cyprex) I all I

DOM

DPA

dodemorph-acetate (Meltatox)

diphenylamine (No-scald)

h d b

l I all I

DSE onsy rocarchlorinated C3

(DD., Telone, Vidden) >50% 1 =<50%

DYR anilazine (Dyrene) f >50% =<50% =< 5%_

ETR

ET Y

I ethirimol (Milgo)

I ethoxyguin

I I

II

>10% I =<10%

FEH I fentin hydroxide (Du-TLr) I all I I I

FER I ferbam I I I all

FOLI folpet (Phaltan) I I I > 5% =< 5%

FOR I formaldehyde I I ( all I

-20-

FUN F1Eaicide's (Om I t )

SCH.4+or

ODDE COMMON OR CMUCAL NAME (BRAID) SCR.1 9CH.2 SCH.3 SCH.6

I i I I i

GLY I glyodin (Cyprex) I I I all i

IPD I iprodione (Rovral) ( I iall

KCR potassium chromate >15% i =<15%

MAG I malachite green I i >10% i=<10% I

MAN i maneb (Manzate) all

MBD I carbendazim-phosphate (Lignasan) I i I all

MBR I methyl bromide (DcF -fume) I all I I

MCC I mercuric chloride Ii all I i

MCz I mancozebi I

Iall I

MOI I mineral oil I I i I all

MOR I (Morestan) all i

MSC I mercurous chloride ( I alli i

MTA i metalaxyl (Ridomil) I i all I i

MTM I metam sodium (Vapam) all I

MTR i metiram (Polyram) all -

NAB I nabam I I all i

i

OXT I oxytetracycline

hydrochloride (Terramycin R) all*

PF I paraformaldehyde i I all (

i

PMA Iphenyl mercuric acetate (PMAS) I I all I i

POI I pine oil all

PTX oxycarboxin (Arrest) > 5% =< 5% i

QTZ quintozene i I I all I

-21-

KN Fungicides (oon't)SOi. 4+or

CODE COMMN OR CHBMICAL NAME (BRAND) Sm.1 9CH.2 SM.3 ---SCH.6

I I I I I

I I I I I

STNI

streptomycin (Agri-Mycin)I I I all I

SULI

sulphur I I I I all

SUSI

sulphide sulphur (lime sulphur) I I

I

all

J i I I

TETI

chlorothalonil (Daconil) I

I I

allI

THII

thiram I

I

>50% I=<50%I

TPMI

thiophanate-methyl (Easout) I I

I

>50% I=<50%

TRBI

etridiazole (Truban) I

I I

>40%I

=<40%

TRRI

triforine (Rmginex) II

I I

all

TZL thiabendazole (Mertect) Iall

VIT I carbathiin (Vitavax)I I

Iall

_ I I I I

XAYI

2,4-xylenol (Gallex) I II

allI

I I I

I I I I

ZINI

zinebI I I

> 5%I

=< 5%

ZIRI

ziram I I

I

allI

J I I I

-22-

WPS Wood Preservatives

SCH.44or

0" OOMMON OR CHEMICAL NAME (HBRAM)

ALD ' aldrin

ANH Ianthracene oil (Carbolineum)

BNA j borax anhydrous

(sod. tetraborate)

BNS I borax

BR) L bis-(tri-n-butyltin) oxide

CLD I chlordane

CCA I coal tar acidsCPN I chloropicrinCRC I cromic acidCRT I creosoteCUN I copper napthenate

CUD I copper oxide

CUS i copper sulphate

CUQ I copper-8-quinolinolate

DCA I dichlofluanid (Cuprinol)

DNP dinitrophenol

SCH.1 SCH.2 SCH.3

all

l

SCH.6

all

I >70% I =00%

>10% =<10%

>50% =<50% I

>20% 1 =<20%

all

all

IRN I iron from iron napthenate I

PCP I pentachlorophenol

PML

PMO

Iphenyl mercuric lactate

phenyl. mercuric oleate

SMM

TCP

ZNN

sodium metaborate octahydrate

tetrachlorophenol

zinc napthenate

I

I

>10% I

>10%

>

=<

=<

3% 1

all

all

10% I

10%

=< 3%

=< 1%

=< 1%

I

I

>20% I

allall

=< 20% ` =<0.1%

1 >50% I =<50%

>20% I =<20%

I > 3% 1 =< 3%

-23-

VPC Vertebrate Pest Omtrol Products (excluding mdenticides)

ODDS OOMMON OR CHEMICAL NAME (BRAND)

AMP l 4-amino pyridine (Avitrol)

ANR1

anticmycin fish toxicant

AOH1

ammonia vertebrate repellent

AZA I (ornitrol) bird chemosterilant

BAS1

niclosamide (Bayluscide)

BON1

bone oil animal repellent

CAS1

capsaicin animal repellent

FET fenthion bird repellent

MNK methyl nonyl ketone dog and cat

MUS

repellent

mustard oil

NIA l nicotine animal repellent

NPH1

naphthalene animal repellent

oAL1

oil of lemon grass

PDB l paradichlorobenzene animal

PMB

repellent

polymerized butenes

ROT l rotenone fish toxicant

SOA1

soap repellent

STR 1 strychnine as alkaloid or

l sulphate

TFM

THI

lampreycidethiram animal repellent

SCH.1 SCH.2 SCH.3

I

all##

allI

I

allI

all

1

all

I

all

I

i

I

all

> 4% 1 =< 4% 1

all1 1

>50% 1 =<50% 1

SCH.4+or

SCH.6

all

all

all

all

all

all

-24-

ROD Rcdenticides

ODDS ODMF M OR CHEMICAL NAME (BRAND)

I

ALP

ALS

SCH.4for

9CH.1 9CH.2 9CHA BCHA

I

I I I

1

aluminum phosphide (Phostoxin)I

all* I

I I

1

alphachloraloseI

I allI I

I I I

BRF

BRM

I I I I

I brodifacoum (Talon) 1 >0.005 =<0.005 1

brcxnad iolone ( Branone )

CHP I chlorophacinone (Rozol)

CPD1

3 chloro-1,2 propanediol

1

(Epibloc)

CPN chloropicrin

DPC1

diphacinone (Ramik)

EGO1

ergocalciferol (Sorexa)

FUM1

fumarin

HCN ( hydrogen cyanide (HCN)

MBR1

methyl bromide (Dow-fume)

PIN1

pindone

RSp red squill

SOE Igaseous oxides of sulphur

SC)1

sulfaquinoxaline

STR1

strychnine as alkaloid or

1

sulphate

SUF sodium monofluoroacetate (1080)

_ I1

WAR1

warfarin

ZNP1

zinc phosphide

> 5% 1 =< 5% 1 =<0.5% 1 =<0.05%

I I I

> 5%1

=< 5% 1 =<0.5% 1 =<0.05%

>20% 1 =<20%1 1

1

> 1%1

=< 1%1 =<0.01%

>10%1

=<10%1

=< 1%I

=<0.1%

1

>40%1

=<40%1

=<14%

>5% 1 =< 5% 1 =<0.5% 1 =<0.05%

all

> 5% _< 5% 1 =<0.5% 1 =<0.05%

>0.5% 1 =<0.5% 1

all I

I I 1

> 5% 1 =< 5% 1 =<0.5% 1 =<0.05%

>10%I

<10%1

-25-

HER Herbicides

sm.44or

CODE COMMON OR CHEMICAL NAME (BRAND)

AAL

ACA

ACL

ALA

ALL

AMA

AMI

AMS

A.SM

ATR

AVG

AZP

allyl alcohol (AA Soil Drench)

acifluorfen

acroleinalachlor

allidochlor

ammonium methyl arsonates

amitrole

ammonium sulfamate

asulam

atrazine

difensoquat

aziprotryn

(Blazer)

SCH A SCH.2 scH.3 scH.6

all

all

(Lasso)

(Randox) I all

(Asulox F)

(Avenge)

(Balan)

(Carbyne)

(Sencor)

(Hyvar)

(Bladex)(Blagal)

(Benazolin)

(Betasan)

all

all

I

>10% I =<10%

all I

I=<15%

I

=<70%I

all

(Torch. Pardner) I

L JI I I I

BAL

BAR

BAX

BBU

BDX

BEN

BET

BNP

BN5

BRY

BTL

BZN

BZP

bent luralin

ba rban

metribuzin

bromacil

cyanazine

benazolin

bensulide

borax pentahydrate

borax

bromoxynil

desmedipham

bentazon

benzoylprop-ethyl

all

all

>15%

>70%

all

(Basagran) I I >80%

(Endaven)I I

all

i I

I =<15% I

I I

I allI

> 7%I

=< 7%

I II

>50%I

=<50%

i I

>70%I

=00%

-26-

HER Herbicides (o0 lt)

ODDS OOMMON OR CHE24ICALL NAME (BRAND)

SCH.4+or

SCH.1 SCH.2 s®.3 SCHA

CBU I chlorbranuron

CHAI

chloramben (Amiben)

CHLI

chlorthal dimethyl (Dacthal)

CIPI

chlorpropham (CIPC)

CLX I chloroxuron ( 1'enoran )

all

CPNI

chloropicrin >20% =<20%

CSLI

chlorsulfuron (Glean)

CUM I copper sulphate (Bluestone)

CUT cutrine

DAL I dalapon (Dowpon, Basfapon)

DAZI

dazanet (Mylone)

DCR I dichlobenil

DICI

dicamba (Banvel)

DIGI

dichlorprop amine (2,4-DP)

DIHI

dichlorprop IV esters

DIH I dichlorprop HV esters all

DIPI

diphenamid (Snide)

DIQ I diquat (Reglone)

DNA I dinitramine (Cobex) all

DNB I dinoseb (Sinox)

DPBI

2,4-DB butyl ester (Enbutox)

DPP ( dichlofop-methyl (Hoe-Grass)

EXJR I diuron (Karmex)

DXA )

DXR ]-I 2,4-D acids, amines and saltsI

all(N

DX.S ] I i

DXEI

2,4-D H.V. estersI

all I

all

> 7%

all

> 6%

7%

6%

=<10%

_< 6%

-27-

HER Herbicides (Omit)

SCH.44ar

ODDE ODr!! M OR CHEMICAL NA14E (BRAID) 9®.1 SCH.2 SCH.3 SCH.6

DXF ] II

DXG]I

2,4-D L.V. esters

ENTI

endothal

EPTI

eptam (EPIC)

ERBI

erbon

FESI

ferrous sulphate

FLAI

flamprop-methyl

FLZI

fluazifop-butyl

FNCI

chlorfenac

FNPI

fenoprop salts and mines

FNPI

fenoprop H.V. esters

FNPI

fenoprop L.V. esters

(Silvex) I all

all I

I I J

all I

all

all

I

all##I

i

I I all##II

I 1

i I t

GPSI

glyphosate (Roundup) I I

I

>50%I

=<50%

I I 1 I

I I I

HCYI

hydrogen cyanamideI I

allI I

_ I l I i I

I I I I I

IoxI

ioxynil (Zbtril)I I

>14%I

=<14%

I I I I I

I I 1

KRB

KRE

propyzamide

fosamine ammonium

(Kerb)

(Krenite)

allI I

allI

I I I I

I I

LUN I linuron (Lorox) I

I I I i I

-28-

Hm Herbicides (don't.)

9CH.4+or

00M OOMPM OR CHMICAL NAME (BIi ID) 9®.2 9CH.6

iI I

MAB] I MCPA amines and salts I all(M)I I all I

MAS) I I I

MAEI

[MCPA H.V. esters I all II I

MAEI

[MCPA L.V. esters I all(M) I all I I

MBRI

methyl bromide I allI I

MBS I MCPB salts (Tropotox)I I

Iall

I

ME)cI

mecoprop salts (Qompitox) I I I > 6%I

=< 6%

I = 50MISI

methyl isothiocyanate (Vorlex) II

>50% < %

MOHI

mineral oil-herbicidal I ( I I

all

MOL I monolinuron (Afesin) I I Iall

MONI

monuronI I

>15% ( =<15%

MOOI

monuron - TCA I

I

allI I

MSMI

monosodium methane arsonate I I I

allI

MTBI

metobranuron (Patoran)I

I all I

I

MTLI

metolachlor (Dual) II

allI

MTM metam-sod ium (Vapan) I I all I

I I I I I_

I I I I I

NAPI

naptalam (Alanap) II

Iall

I

I I I I i

Ii I I I

PAOI

paraquat (Gramoxone) I

I> 3%

I

=< 3% I

PCpI

pentachlorophenolI

all I

I I

PEBI

pebulate (Tillam) I I I all I

PIc Ipicloram amines or salts (Tbrdon) I I all##I I

PMP I phenmedipham (Betanal) II I

allI

-29-

HER herbicides

SCH.4-for

ODDS COMMM OR CHEMICAL NAIL (BRAW) 9®.1 SCH.2 SCH A SCH A

PRF I propham

PRLI

propanil (Stampede)

all

PRMI

prcmetone I >15%

PROI

prometryne (Gesagard) I I >15%

PRP propachlor (Ramrod) I

I

PYZ pyrazon (Pyramin) I

i 1 l I I

i I I I

ROEI

cycloate (Ro-Neet) I

I

all

i

SCL Isodium chlorate mixtures

SODI

sethoxydim (Poast)

SID I siduron (Tupersan)

SLNI

solan

SMMI

sodium metaborate octahydrate

SMTI

sodium metaborate tetrahydrate

SMZI

simazine

SPCI

sodium pentachlorophenate

SUAI

sulfallate (Vegadex)

Sur I butylate (Satan)

all I all**

allI

> 7%

all

I>50% I =<50%

I>50%

I=<50%

>15% I =<15%

I

TRA I trichlorobenzoic acid (TBA) all

TBTI

terbutryn ) I

I

all

T1BZI

terbuthylazine] (Topoguard) I I all

TCSI

trichloroacetic acid (TCA)I I

all

TEBI

tebuthiuron (Spike) II

>15% I =<15%

TERI terbacil (Sinbar) I I all

TRF I trifluralin (Treflan) II

I all

-30-

HER Herbicides (OWt )

Clow CO!l4ON OR CHEMICAL NAME (BRAND) SCH.1 SCH.2

SCH.4+or

- SCHA SCH.6

TRL I triallate (Avadex BW) I allI I

TXB I

TXE I

2,4,5-T amine

2,4,5-T H.V. esters

I

I all

I

I

I

I

all## I

I

TXF 12,4,5-T L.V. esters I I all##I

I I I I I

VER I vernolate (Vernam) I I I all I

VPR I hexazinone (Velpar) I I all I I

WAT water soluble dyes I + I I

I I I I I_mixtures of

I 2,4-D l

mecoprop ] amines

dichlorprop] and salts > 6% 1 =< 6%

plus dicamba I I I > 3% 1 =< 3%

IRP (Insect Repellents)

I I I I

BPG (butoxypolypropylene glycol (Crag) I I

I I

all

CAS I capasaicinI I

II

all

CIT1

oil of citronella I I I Iall

DMP I dimethyl phthalate I (I

I all

DTU I N,N-diethyl-m-toluamide (Deet)I

I+

I all

EHX I ethyl hexanediol I I I Iall

LAV oil of lavender I I ( Iall

M(,B I 2,3,4,5-bis (2-butylene)

tetrahydro-2-furfural (MGK II) all

MGD I di-n-propyl isosinchomeronate

(MGK 326) all

Wli I 2-hydroxyethyl N-octyl sulfide

(MGK 874) all

-31-

MISCELLANEOUS OOMPOUNDS

SCH.4+or

(X)DE OOM MION OR CHEMICAL NAME (BRAND)

ACA I acetic acidANC

I

ancymidol

AYCI

cittowet

BZAI

benzoic acid

kinoprene

maleic hydrazide

mefluidide

metaldehyde

nepthalene acetic acid

CCCI

chlormequat (Cycocel)

CFMI

chlorflurecol (Maintain)

COCI

coconut diethanolamide

CPA 4-chlorophenoxy acetic acid

sm.1 SCH.2

I I

(PGR)I

(ALIT)

(ADJ)I1

all(PGR)I >90% I =<90%

DAM daminozide (B-Nine-Alar) (PGR)11

allDFA

1

dimethyl alkyl (AW)I1

allETA

I

1, 2-ethaned iol ( ALIT) I

SCH.3 SCH.6

> 6% 1=< 6%

all1

=<10%I

>25% 1 =<25%

1

all

=<10% =< 1%

all

ETVI

ethephon ( Ethrel ) ( PGR)1 1 1 >40% 1=<40%

FAA]I

I

FAB]I

fatty alcohols (PGR)II I

all

IBA indole-butyric acid (PGR)II

>10% I =<10% =< 1%

KPR

MAH

MFD

MH Y

NAA

W)N

OPE

PAE

PVP

TMM

TC)F

(A-Rest )

(Enstar)(MH.30)

(Embark)

(Slug Bait)

nonylphenoxypolyethoxyethanol

octylphenoxypolyethoxy

ethanol ester

primary alcohol ethoxylate

polyvinyl polymer adjuvant

trimethylmonyl polyethoxy

ethanol

tall oil fatty acids

I I

( IGR)1I

(PGR) I

(PGR)1 all(MOL)

( PGR )1

(ALU)I I all

(ALU )1

(ALU)II

(ALIT )1

I I

(ALIT)1I

(ALU) II

all1

>30% ( =< 30%

allI

E. & O. E. , (Errors and Cinissions Excepted)

APPENDIX II

-32-

Obsolete Active Ingredients Previously Scheduled

CODE COMMON NAME PRODUCT TYPE

ACR acrylonitrile INS

ANY antimonyl potassium tartrate INS

AZK terbutol (Azak) HER

AZO azobenzene INS

BBE benzyl benzoate IRP

BHC benzene hexachloride INS

BRL binapacryl (Morocide) FUN

BTD benzothiazyl disulfide FUN

CAC cacodylic acid HER

CAR calcium arsenate INS

CBZ chlorobenzilate ACA

CDU cadmium succinate FUN

CFB see FUN ACA

CHD chlordecone INS

CHR chloranil FUN

CRA cresylic acid INS

CUC copper from copper oxychloride sulfate (COCS) FUN

CUR copper from copper salts of rosin and fattyacids FUN

DCP dibrcmochloropropane (DBCP) NEM

DES disul sodium HER

DIF dichlofenthion NEM,/INS

DMA disodium methyl arsonate HER

DMX dimefox INS

DNC dinitrocresol HER

DNP dinitrophenol HER

EMC ethylmercuric chloride FUN

EMS ethyl-mercury p--toluene sulfonanilide FUN

FEN fenuron HER

FUN chlorphenamide (Fundal) ACA

(SDP phosacetim ((bphacide) ROD

HMC hydroxymercurichlorophenol FUN

HMN hydroxymercurinitrophenol FUN

KCT potassium cyanate HER

LEP leptophos INS

LER lethane INS

MBM manganous benzothiozyl mercaptide FUN

MDD manganous bis dimethyl dithiocarbamate FUN

MMA methylmercuric acetate FUN

MMB methyl mercuric benzoate FUN

MMD methyl mercuric dicyandiamide FUN

MMH ozine methyl mercury FUN

MMO methyl mercury pentachlorophenolate FUN

MMP methyl mercury 2,3-dihydroxy propyl mercaptide FUN

MMT methyl mercury propionate FUN

-33-

obsolete Active Ingredients Previously Scheduled

CODE

NEBNOBN YC

CANOUTOVX

PACPBTPLAPMFPMTP'I'G

RYA

SAFSARSTCSTT

TANTCHTDETECTEPTESTHSIUKTRCVACZICZPSZRN

00M ON NAME

neburonnorbrcmidetartiary octyl mercaptanoil of sassafrasoutfoxovex

phenyl amino cadmium dilactatepiperonylnitralin (Planavin)phenyl mercury formanidephenyl mercury triethanol ammonium lactateparathion methyl

ryaniasodium fluoaluminatesodium arsenitesodium tetrachlorophenatestrychnine nitrate

karbutilate (Tandex)2,4,5-TrichlorophenolTDEtechnazeneTEPPtetradisolthallium sulphateniclofentrichlornate(Vacor )zinc dimethyl dithiocarbamatezinc petroleum sulfonatezectran

PRODUCT TYPE

HERRODARPARPHERINS

FLAY

ACAHERFUNFUN

INS

INS

INSHER/INS

FUNROD

HERWPSINSINS

INSINS

ROD

HERINSROD

ARPFUN

INS

SEi

90')0`)1i198'1