Occurrence of Apatite Associated With Magnetite in an Ophiolite Complex (Othrys), Greece
-
Upload
jorge-pirela -
Category
Documents
-
view
220 -
download
1
Transcript of Occurrence of Apatite Associated With Magnetite in an Ophiolite Complex (Othrys), Greece
-
7/30/2019 Occurrence of Apatite Associated With Magnetite in an Ophiolite Complex (Othrys), Greece
1/8
American Mineralogist, Volume 86, pages 11431150, 2001
0003-004X/01/00101143$05.00 1143
INTRODUCTION
Segregations of apatite in association with Fe-Ti oxides
occur in a variety of geological settings. Nelsonites are rare
igneous rocks composed largely of apatite and Fe-Ti oxides
(magnetite, ilmenite, or rutile) that occur in association with
anorthosite suite rocks (Philpotts 1967, 1981; Watson and Green
1981; Kolker 1982; Herz and Force, 1987; Force 1991; Ashwal
1993; Owens and Dymek 1992; Darling and Florence 1995;
Duchesne 1999). Nelsonite is thought by some to originate as
an immiscible liquid separated from parent magmas of
ferrodioritic composition (Philpotts 1967, 1981; Kolker 1982).
Another kind of association of magnetite and apatite, withoutsignificant ilmenite or rutile, is found in alkaline or calc-alka-
line igneous rocks (McKeown and Klemic 1956; Philpotts 1967;
Darling and Florence 1995). The origin of apatite-magnetite
associations in these types of igneous rocks is not clear. Both a
magmatic (Park 1961; Henriquez and Martin 1978; Naslund et
al. 1998) and hydrothermal origin (Barton and Johnson 1996;
Murray and Oreskes 1997; Barton 1998) have been proposed
for the El Laco deposit, Chile. The characteristics of the Kiruna
deposit, in Northern Sweden, are not definitive regarding its
origin. On the basis of field, textural, mineralogical, and
geochemical data, an exhalative-sedimentary origin has been
proposed by Park (1975) for the Kiruna deposits. Recently, the
Kiruna deposit has been compared to the El Laco deposit in
the Chilean Andes (Nystrom and Henriquez 1994).
Low-Ti, Fe-oxide (Cu-U-Au-Ag REE) deposits, like the
giant Olympic Dam (Australia), Bayan Obo (China), and most
of the New York-New Jersey deposits, are characterized by
magnetite and/or hematite and most contain apatite with sig-
nificant amounts of REE. These deposits exhibit features con-
sistent with a hydrothermal origin (Hitzman et al. 1992; Foose
and McLelland 1995; Barton and Johnson 1996; Oreskes and
Hitzman 1997).Occurrences of apatite in ultramafic rocks are very rare
(Mitchell et al. 1943; Southwick 1968; Honnorez and Kirst
1975; Nickel et al. 1979; Hopkinson and Roberts 1995; Gjata
et al. 1995; Dick and Natland 1999). Recently, small concen-
trations of apatite associated with magnetite or silicates were
discovered along a shear zone in the Othrys (Ano Agoriani area)
ophiolite complex, Greece, at the tectonic contact between a
gabbroic rock and serpentinized lherzolite. This paper is prob-
ably the first report of an apatite-Fe oxide association in an
ophiolite complex, and we provide a description of the apatite-
magnetite occurrence, an account of its mineral chemistry, and
a discussion of its genesis.* E-mail: [email protected]
Occurrence of apatite associated with magnetite in an ophiolite complex (Othrys), Greece
IOANNIS MITSISAND MARIA ECONOMOU-ELIOPOULOS*
University of Athens, Department of Geology, Panepistimiopolis, Athens 15784
ABSTRACT
Small irregular to lens-like occurrences (maximum 0.5 1 m) of apatite associated with magne-
tite and silicates are present in the Agoriani area of the Othrys ophiolite complex, central Greece.
The Ano Agoriani area is dominated by peridotite (plagioclase lherzolite) of the mantle sequence,
intruded by irregular bodies, dikes, and veins of gabbro, as well as by dikes of pyroxenite and peg-
matitic gabbro.
Apatite occurs as large (up to 3 cm long) well-formed crystals associated with magnetite. The
aggregates consist predominantly of apatite, or massive magnetite with subordinate amounts of apa-
tite. Apatite may also be accompanied by silicate minerals, mainly chlorite and lesser amounts of
serpentine, tremolite, and Ni-silicates (nepouite, pimelite), and by Ni-sulfides (pentlandite, violarite,
heazlewoodite).
The apatite-magnetite association from the Agoriani area differs from nelsonite hosted by an-
orthosite suites with respect to: (1) the host rock type (ophiolites); (2) the highly variable proportion
between apatite-magnetite; (3) the large size (up to 3 cm) of the apatite crystals; (4) the lack of
fluorine (
-
7/30/2019 Occurrence of Apatite Associated With Magnetite in an Ophiolite Complex (Othrys), Greece
2/8
MITSIS AND ECONOMOU-ELIOPOULOS: APATITE-MAGNETITE ROCK1144
CHARACTERISTICFEATURESOFTHEOTHRYSCOMPLEX
The Mesozoic Othrys ophiolite complex consists of a stack
of thrust sheets in which overlapping stratigraphic successions,
consisting mainly of harzburgites, lherzolites, gabbros, mafic
dikes, and pillow lavas, have been recognized (Hynes 1972;
Nisbet 1974; Menzies 1974; Konstantopoulou and Rassios
1993). The presence of both lherzolite and harzburgite in the
mantle sequence of the complex, and the variable geochemical
affinities of the lavas, provide evidence for development of the
complex during more than one oceanic stage, involving MORB
and supra-subduction zone (SSZ) features that may be inter-
preted as related to a back-arc basin (Hynes 1972; Nisbet 1974;
Smith et al. 1975; Sovatsoglou-Skounakis 1982; Paraskevo-
poulos and Economou 1986; Economou-Eliopoulos and
Paraskevopulos 1997).
Two tectonically separate chromite deposits, Eretria and
Domokos, have been exploited for refractory-grade chromite
resources (about 3 million tons). Small bodies of sulfide min-
erals (pyrrhotite, chalcopyrite, and minor pentlandite), are also
found at the Eretria mine, whereas magnetite occurs at the pe-riphery of a few podiform bodies (Economou and Naldrett
1984). Both high-temperature deformation (characterized by
mylonite zones and mineral foliations) and low-temperature
brittle deformation have been superimposed onto primary
mantle fabrics, and onto magmatic textures of rocks and ores
(Konstantopoulou and Rassios 1993).
DESCRIPTIONOFTHEAPATITE-MAGNETITEOCCURRENCE
The Ano Agoriani area (8 km west of Domokos), in the
western part of the Othrys complex, is dominated by plagio-
clase lherzolite (Fig. 1) consisting of forsterite, enstatite, diop-
side, and plagioclase, with minor spinel. Irregularly shapedbodies of gabbro and gabbroic dikes or veins intrude the pla-
gioclase lherzolite of the mantle sequence. Pyroxenite and gab-
bro pegmatitic dikes containing 220 cm pyroxene crystals also
cut lherzolite (Nisbet 1974; Menzies 1974). Apart from the
gabbro units of the magmatic sequence, numerous small gab-
broic bodies are found within the serpentinized lherzolite. An
abundance of gabbroic pods and dikes within plagioclase
lherzolite is considered to be characteristic of sections near the
petrological Moho (Menzies 1973, 1974; Nicolas 1989). These
gabbroic bodies are composed mainly of randonly oriented
skeletal plagioclase in a matrix of clinopyroxene (diopside-
augite). Small amounts of chlorite and spinel are also present.
These gabbroic bodies appear undeformed in contrast to the
ductile-brittle deformation along thrust surfaces at the tectonic
contact between gabbroic rocks and serpentinized lherzolite.
Variable proportions of apatite in association with magne-
tite were discovered in the Ano Agoriani area along a shear
zone, at the contact between lherzolite and a relatively large
(50 250 m), fine-grained body of gabbro (Fig. 1).
METHODSOFINVESTIGATION
The apatite-magnetite association from the Ano Agoriani
area was investigated as follows. X-ray powder diffraction pat-
terns (XRD) of apatite were obtained with a Siemens D5005
X-ray diffractometer at the University of Athens. Major- and
trace-element compositions, including rare earth elements
(REE) were determined on bulk mineral separates by a combi-
nation of instrumental neutron activation analysis (INAA), and
colorimetric methods at the XRAL Laboratories, Ontario,
Canada. Thin sections were investigated by optical microscopy
and scanning electron microscopy. Mineral compositions were
determined by electron microprobe analysis at the University
of Athens, Department of Geology, using a CambridgeMicroscan-5 instrument and a JEOL JSM 5600 scanning elec-
tron microscope, both equipped with automated energy disper-
sive analysis system, LINK 2000 and ISIS 300 OXFORD,
respectively. The H2O content of apatite was determined by
the Penfield method (Mitchell et al. 1943). Thermogravimetric
(TG) analysis of apatite was performed with a Perkin Elmer
TGS-2 thermal analyzer using a 5.0 deg/m in heating and ni-
trogen atmosphere, in the temperature range 80950 C.
MINERALOGY
Small, irregular to lens-shaped (maximum 0.5 m 1 m)
apatite-magnetite occurrences are composed of large euhedral
apatite crystals, ranging from a few millimeters to 3 cm in
length, in a magnetite matrix (Fig. 2). The color of apatite is
whitish, and it occurs mainly within massive magnetite or,
where associated with silicates (magnetite), it occurs either
as undeformed or fragmented to rounded crystals. Proportions
of apatite to magnetite are highly variable (Fig. 2). Inclusions
of magnetite within apatite, and Ni-sulfides (mainly pentland-
ite) dispersed throughout both apatite and magnetite are com-
mon, suggesting that all these minerals crystallized at the same
time.
In some cases, apatite is accompanied only by silicate min-
erals, mainly chlorite that may be Ni-bearing, and lesser
amounts of serpentine, tremolite, Ni-silicates (nepouite,pimelite), and Ni-sulfides (pentlandite, violarite,
heazlewoodite). Moreover, chlorite is a common mineral along
cracks and around the periphery of most apatite crystals, either
associated with magnetite or silicates. Goethite is a common
alteration product of magnetite.
Most apatite grains contain abundant fluid inclusions. They
appear to be primary on a textural basis (Roedder 1984), and
consist of very small, two-phase inclusions, containing aque-
ous liquid (L > 50%) and a vapor phase (Fig. 3).
The investigation of apatite with the scanning electron mi-
croscope and the microprobe revealed no zoning, very low REE
contents (below the detection limit of the method), and inclu-
sions of monazite crystals (Fig. 4).
MINERALCOMPOSITIONS
The large size of the apatite and magnetite crystals allowed
for both bulk and electron microprobe analysis. The H2O con-
tent in apatite ranges from 1.1 to 1.9 wt% and Cl from 6300 to
7500 ppm, whereas F is less than 20 ppm (Table 1). The pres-
ence of many small fluid inclusions, containing aqueous fluids
as the main phase, indicates that bulk H2O contents do not re-
flect only the (OH) anions in the apatite. Nevertheless, the pre-
dominant anions are (OH) and Cl, corresponding to
chlor-hydroxyl-apatite, consistent with the XRD pattern.
The minor and trace element contents of apatite (Table 1)
-
7/30/2019 Occurrence of Apatite Associated With Magnetite in an Ophiolite Complex (Othrys), Greece
3/8
MITSIS AND ECONOMOU-ELIOPOULOS: APATITE-MAGNETITE ROCK 1145
are consistent with the presence of chlorite and Ni-silicates
along cracks in the apatite, and with the presence of magnetite
and Ni-sulfides (mainly pentlandite) inclusions. The rare-earth
element (REE) content in the Agoriani apatite is relatively high
(up to 1350 ppm REE). In addition, the apatite displays steeply
fractionated chondrite-normalized patterns (Fig. 5) with veryhigh La/Lu ratios (average 1570).
Magnetite is pure, with very little Al, Mg, Ni, and Ti. Bulk
samples, however, have high Ni because of the presence of Ni-
sulfide inclusions (Table 1). The REE content of the Ano
Agoriani magnetite is below the detection limit of the INAA
method (for example
-
7/30/2019 Occurrence of Apatite Associated With Magnetite in an Ophiolite Complex (Othrys), Greece
4/8
MITSIS AND ECONOMOU-ELIOPOULOS: APATITE-MAGNETITE ROCK1146
Alkaline or calc-alkaline rocks
The origin of apatite-magnetite associations in alkaline orcalc-alkaline igneous rocks is not clear. For example, the El
Laco deposit, Chile, situated on the flanks of an andesite-
rhyodacite volcano, consists of five massive magnetite-hema-
tite bodies surrounded by numerous dikes and veins of
intergrown magmatic pyroxene and apatite. Some researchers
favor a magmatic origin (Park 1961; Henriquez and Martin
1978; Hitzman et al. 1992; Naslund et al. 1998) and others a
hydrothermal origin (Barton and Johnson 1996; Barton, 1998).
The Kiruna deposit, Northern Sweden, constitutes the great-
est concentration of apatite-iron ore in the world. As with the
El Laco deposit, it is considered to be magmatic in origin by
some investigators (Frietsch 1978) but hydrothermal by others
FIGURE 2. Large and well-formed apatite crystals (white) in magnetite (black). In the right specimen, the lower area (gray) is chlorite and
serpentine. (Scale bar = 9 cm.)
FIGURE 3. Small two-phase liquid-rich inclusions in apatite. Transmitted light.
(Barton and Johnson 1996; Barton 1998). On the basis of field,
textural, and mineralogical data, Parak (1975) proposed thatthe Kiruna deposits were exhalative-sedimentary in origin. It
is remarkable that within banded ores, small monazite needles
occur as inclusions in individual apatite crystals (Parak 1975).
Recently, the features of Kiruna have been compared with
those of El Laco and it has been suggested that such magmatic
ores, occurring in rocks ranging from Proterozoic to Cenozoic,
are not unique (Nystrom and Henriquez 1994). For example,
the deposits of the Cerro de Mercado, Durango, Mexico, are
considered to have formed as a result of a variety of subaerial
volcanic processes. During the later stages of the cooling pro-
cess, a quartz latite dike intruded the deposit, while a volatile-
rich, iron-oxide-rich phase is suggested to have evolved from
-
7/30/2019 Occurrence of Apatite Associated With Magnetite in an Ophiolite Complex (Othrys), Greece
5/8
MITSIS AND ECONOMOU-ELIOPOULOS: APATITE-MAGNETITE ROCK 1147
tite-actinolite veins, breccias, and wall-rock replacement, and
an outer zone of disseminated sulfides. It was concluded that
high temperature, low initial water content, and shallow-level
emplacement by intermediate plutons are necessary for the
development of Kiruna-type deposits (Hildebrand 1986).
Mafic-ultramafic rocks
Layered mafic intrusions. Apatite-enriched layers have
been reported in the Upper Zone of the Bushveld complex.
Textural and compositional relations suggest that the periodic
development of an immiscible Fe-Ti-Ca-P liquid in the top-most 1000 m of the Upper Zone (Von Gruenwaldt 1994). The
development of the mineralized zones at the base of distinct
geochemical cycles suggests the formation of the immiscible
Fe-Ti oxide and apatite by magma mixing processes (Von
Gruenewaldt 1994).Also, in the Bushveld complex, with the
exception of its abundant fluorite, the Vergenoeg deposit is re-
lated to granites containing fayalite, fluorite, apatite, ilmenite,
and magnetite, and is similar to massive iron deposits as Kiruna
and Cerro Mercado (Borrok at al. 1998). Furthemore, based on
isotope and fluid inclusion data on fluorite from the Vergenoeg
deposit which contain abundant aqueous inclusions, Borrok et
al. (1998) concluded that this mineralization formed from hy-
drothermal fluids of magmatic origin.Ultramafic chlorite rocks. Well-documented occurrences
of fluor-hydroxyl-apatite have been found in Georgia and Mary-
land of the U.S.A., associated with chlorite-talc schists located
in the peripheral parts of small ultramafic bodies (Mitchell et
al. 1943; Southwick 1968; Herz and Valentine 1970). More
specifically, a small body of ultramafic chlorite rock contain-
ing unusually large quantities of rutile, magnetite, apatite, and
ilmenite is present in Harford County, Maryland. The central
part of the ultramafic body is mostly massive to schistose soap-
stone and serpentinite, whereas its southwest margin contains
lenses of strongly deformed uralitized gabbro and pyroxenite.
Mitchell et al. (1943) and Southwick (1968) concluded that
FIGURE 4. Small crystals of monazite included within apatite.
Backscattered and secondary electron micrograph. (Scale bar = 5 m.)
FIGURE 5. Chondrite-normalized REE-patterns for apatites. Datafrom Table 1, chondritic values after Taylor and McLennan (1985).
the parent magma (Lyons 1988).
In NW Canada, magnetite-apatite-actinolite rocks are asso-
ciated with plutons that intrude andesites of an early Protero-
zoic continental magmatic arc. These plutons exhibit wide
alteration halos comprising an inner zone of nearly complete
wall-rock albitization, an intermediate zone of magnetite-apa-
TABLE 1. Average (n = 3) chemical composition of apatite and mag-
netite from the Agoriani area, Othrysapati te associated with: magnet ite associated
Mineral silicates & silicates magnetite with apatitesamples magneti te
AP-PEG 6-MG2 7-A 7-5Mt 7-Mt(593)
wt%CaO 53 50 54.2 0.32 0.98P2O5 39.2 38.5 43.1
-
7/30/2019 Occurrence of Apatite Associated With Magnetite in an Ophiolite Complex (Othrys), Greece
6/8
MITSIS AND ECONOMOU-ELIOPOULOS: APATITE-MAGNETITE ROCK1148
the hydroxyl-apatite in these rocks was initially normal fluor-
apatite, and that exchange of (OH) for F-anions took place dur-
ing low-grade metamorphism and associated black-wall
metasomatism in the presence of excess water.
Within serpentinized peridotite near Nullagine, Western
Australia, Ni mineralization associated with lesser amounts of
magnetite, apatite, and chlorite occurs along shear zones, and
has been attributed to hydrothermal and/or metasomatic activ-ity (Nickel et al. 1979).
Ophiolite complexes. Apatite has been reported in Fe-Ti
oxide-rich gabbro localized along shear zones in the Lizard
complex, U.K. (Hopkinson and Roberts 1995), and in core
samples from hole 735b at the Atlantis II Fracture zone, South-
west Indian Ridge (Dick and Natland 1999). In layer 3, Fe-Ti
oxide-rich gabbro of the Lizard ophiolite, ilmenite and magne-
tite (in a ratio of 12:1) poikilitically enclose zircon and apatite.
The origin of this association is attributed to the migration and
impregnation of evolved Fe, Ti-rich melts in deformed areas
(including shear zones) of gabbro (Hopkinson and Roberts
1995). Subordinate quantities of apatite are found in veins com-
posed mainly of zoisite, actinolite, and euhedral chlorite, which
are related to hydrothermal brecciation in and adjacent to shear
zone.
In rocks collected from the Atlantis II Fracture zone, South-
west Indian Ridge, Dick and Natland (1999) described large
euhedral crystals of apatite contained in ilmenite-magnetite
patches. These Fe-Ti oxides (which locally include Fe-Cu-Ni
sulfides) are abundant in the most-deformed (sheared and brec-
ciated) gabbro and least-abundant in the least-deformed rocks.
In most cases, the oxides occur as an undeformed coarse ma-
trix in shear zones, postdating the major phase of deformation.
However, in a few cases, the oxides predate the deformation.
Small patches of late felsic material contain mainly amphib-ole, ilmenite, and magnetite, with minor amounts of sulfides,
quartz, apatite, and zircon, suggesting that the Fe-Ti oxides
precipitated from highly evolved melts and/or late-magmatic
hydrous fluids.
In the Puka ophiolite massif, Albania, occurrences of dis-
seminated apatite in Fe-Ti oxide rich gabbro also have been
reported but no interpretation was offered (Gjata et al. 1995).
Low-Ti oxide-apatite
A distinct class of mineral deposit has been recognized re-
cently that are characterized by low-Ti Fe ores containing vari-
able amounts of Cu, U, Au, and REE, like the deposits of
Missouri and Kiruna of Sweden, the giant Olympic Dam ofAustralia, the giant Bayan Obo of China, the Humboldt of Ne-
vada, the New York and New Jersey (Oreskes and Einaudi 1990;
Hitzman et al. 1992; Foose and McLelland 1995). All these
deposits are characterized by magnetite and/or hematite ores
with low Ti content (
-
7/30/2019 Occurrence of Apatite Associated With Magnetite in an Ophiolite Complex (Othrys), Greece
7/8
MITSIS AND ECONOMOU-ELIOPOULOS: APATITE-MAGNETITE ROCK 1149
tite crystals within pillow lavas, which have been strongly af-
fected by hydrothermal alteration (Economou-Eliopoulos,
unpub. data), may indicate that the apatite was initially F-rich
and that a gradual exchange of (OH) for F has occurred. How-
ever, the large size (up to 3 cm) of the apatite crystals and their
spatial association with shear zonesseems to be consistent with
its deposition into preexisting lithologies rather than being the
product of a replacement process. The dominance of (OH) ions
in the studied apatite, and the presence of abundant primary,
liquid-rich, two-phase fluid inclusions (Fig. 3) suggests that
apatite formed in the presence of an aqueous fluid phase.
Deposition of apatite and the associated minerals are re-
lated to the circulation of an oceanic hydrothermal system, prob-ably a Cl-rich brine, as is exemplified by the presence of
Cl-apatite. The presence of inclusions of magnetite within apa-
tite and the association of sulfides with both apatite and mag-
netite suggest that these minerals share a common origin. As
far as the origin of the association of massive magnetite with
sulfides of both Cyprus and Fe-Cu-Ni-Co type in ophiolite com-
plexes elsewhere, it has been suggested that they too have pre-
cipitated from circulating hydrothermal systems. Interaction
of the hydrothermal system with the host rocks produces a re-
duced, slightly acidic, saline solution, which can be assumed
to rise preferentially along a zone of high permeability. Physi-
cochemical changes (temperature, redox, pH conditions) within
the hydrothermal system at near-surface or at lower stratigraphiclevels like that of the gabbros, cause precipitation of sulfide-
oxide mineralization (Economou and Naldrett 1984; Foose et
al. 1985; Scott et al. 1990; Eliopoulos et al. 1998).
Recently, on the basis of fluid inclusion data, replacement
textures, extensive zones of wall-rock Fe metasomatism,
geochemical data (isotopic, major- and trace- element compo-
sitions) and the presence of Cl-apatite, the hydrothermal origin
has been suggested for another class of low-Ti iron-oxide de-
posits (Cu-U-Au-REE), like those deposits in Missouri, Kiruna
in Sweden, Olympic Dam in Australia, the Bayan Obo in China,
and Humboldt in Nevada (Oreskes and Einaudi 1990; Hitzman
et al. 1992; Foose and McLelland 1995; Barton and Johnson
1996; Barton 1998). With respect to the source of the P for
these low Ti iron-oxide deposits, Barton and Johnson (1996)
proposed an evaporitic-source model.
The Agoriani apatite mineralization is similar to the latter
class of deposits in terms of the association of apatite with low-
Ti Fe-oxides (magnetite), the presence of REE-bearing miner-
als (monazite) that are considered to be of hydrothermal origin,
and abundant aqueous fluid inclusions within apatite. Although
the above distinct class of deposits and the Agoriani apatite-
magnetite association both appear to be hydrothermal in ori-
gin, the source for the P is different in each. Apart from apatite
that is a common accessory phase in all mafic ophiolitic rocks,
high whole-rock concentrations of P2O5 and abundant apatitehave been reported in some mafic ophiolitic rocks (Hynes 1972;
Gjata et al. 1995; Tables 1 and 2). In addition, amphibolite dikes
cross-cutting the Zidani, Greece, serpentinized peridotite, are
characterized by high contents of Ti (2.9 wt% TiO2) and P (up
to 0.71 wt% P2O5,) and contain ilmenite and apatite. A salient
feature of the latter dikes is the highest P content in the less-
altered samples (2 wt% H2O), whereas strongly deformed, al-
tered, vermiculite-bearing samples (11.7 wt% H2O) exhibit low
(0.1 wt%) P2O5 contents (Karkanas et al. 1996). Such a de-
crease in P content in the deformed, highly altered dikes from
the Zidani area, combined with the presence of small crystals
of apatite with replacement features, within strongly altered
pillow lavas (Economou-Eliopoulos, unpub. data) suggests thatP might be mobile and enriched in hydrothermal systems re-
lated to ophiolites.
Therefore, the composition of the apatite (chlor-hydroxyl-
apatite) and the presence of abundant, primary, two-phase, aque-
ous fluid inclusions (Fig. 4), coupled with the composition of
the associated magnetite and sulfides, may indicate formation
of apatite under hydrothermal conditions.
ACKNOWLEDGMENTS
We thank K. Barlas and E. Michaelides, University of Athens, Departmentof Geology, who performed the electron microprobe analyses. Anna Ewing-Rassios, IGME Kozani (Greece) is also thanked for reading this manuscript.Many thanks are expressed to the Editor Robert F. Dymek and Associate Editor
TABLE 2. Chacteristics of the apatite-magnetite mineralization in the Agoriani area (Othrys) and other Fe-Ti-oxide-apatite occurrences
Apatite FluidHost rock Apatite occurrence Fe-Ti oxides composition REE in apatite inclusions Origin
in apatite
anorthosites Ti-bearing high content,Nelsonite (il-ap rock) il, ru, Ti-mt F-apatite flat to positive slope rare cumulates and/or
of the REE-patterns immiscible liquidrich in Ti, P +/ Zr
monazite inclusionsalkaline/ negative to positive rare tocalc-alkaline low-Ti F,Cl-apatite slope of the abundant
mt (il, ru) REE-patterns
mafic/ peripheral parts and/or hydrothermal and/orultramafic along shear zones il, ru,mt F-(OH)-apatite n.d. n.d. metasomatic activity
ophiolites highly evolved meltsFe-Ti oxide-rich gabbro and/or il, mt n.d. n.d. n.d. and/or late-magmatic
along shear zones hydrous fluids
Agoriani, shear zones along margins pure mt Cl-(OH)-apatite inclusions of abundantOthrys of gabroic bodies with lherzolite monazite two-phase hydrothermal
liquid-rich
Notes: il = ilmenite, ru = rutile, mt = magnetite, n.d. = no available data.
-
7/30/2019 Occurrence of Apatite Associated With Magnetite in an Ophiolite Complex (Othrys), Greece
8/8
MITSIS AND ECONOMOU-ELIOPOULOS: APATITE-MAGNETITE ROCK1150
Brent E. Owens, and reviewers Robert S. Darling, SUNY College at Cortland,Allan Kolker and Eric Force, U.S Geological Survey, Reston, Howard Naslund,SUNY at Binghamton, for their suggestions and constructive criticism of ear-lier drafts of the manuscript.
REFERENCESCITED
Ashwal, L.D. (1993) Anorthosites, 422 p. Springer-Verlag.Barton, D.M. (1998) Evaluation of possible roles of non-magmatic brines in igne-
ous-related hydrothermal systems, especially Fe(-Cu-Au-REE) deposits. Ab-
stracts GSA Annual Meeting, Toronto, Ontario, p. A127.Barton, M.D. and Johnon, D.A. (1996). Evaporitic-source model for igneous-re-
lated Fe oxide (REE-Cu-Au-U) mineralization. Geology, 24, 259262.Borrok, D.M., Kelser, S.E., Boer, R.H., and Essene, E.J. (1998). The Vergenoeg
magnetite-fluorite deposit, South Africa: support for a hydrothermal model formassive iron oxide deposits. Economic Geology, 93, 564586.
Darling, R.S. and Florence, F.P. (1995) Apatite light rare earth element chemistry ofthe Port Leyden nelsonite, Adirondack Highlands, New York. Implications forthe origin of nelsonite in anorthosite suite rocks. Economic Geology, 90, 964968.
Dick, H.J.B. and Natland, J. (1999) Proc. ODP Initial Reports 176: College Station,Texas, Ocean Drilling Program.
Duchesne, J.C. (1999) Fe-Ti deposits in Rogaland anorthosites (South Norway):geochemical characteristics and problems of interpretation. Mineralium De-posita, 34, 182198.
Dymek, R.F. and Owens, B.E. (1996). Petrogenetic relationships among FTP-rocksof the anorthosite suite (nelsonites, OAGNs, jotunites, and oxide ores) as re-
vealed by REE characteristics of separated apatites. Geological Society ofAmerica, Abstracts with Program, 28, p. 288.
(2001) Petrogenesis of apatite-rich rocks (nelsonites and OAGNS) as-sociated with massif anorthosites. Economic Geology, 96, 795813.
Economou-Eliopoulos, M. (1996) Platinum-group element distribution in chromiteores from ophiolite complexes: implications for their exploration. Ore GeologyReviews, 11, 363381.
Economou, M. and Naldrett, A.J. (1984) Sulfides associated with podiform bodiesof chromite at Tsangli, Eretria, Greece. Mineralium Deposita, 19, 289297.
Eliopoulos, D., Skounakis, S., and Economou-Eliopoulos, M. (1998) Geochemicalcharacteristics of sulfide mineralizations from the Pindos ophiolite complex.Bulletin of the Geological Society of Greece, XXXII, No 3, 179186.
Foose, M.P. and McLelland, J.M. (1995) Proterozoic low-Ti iron oxide deposits inNew York and New Jerrsey: relation to Fe-oxide (Cu-U-Au-REE) deposits andimplications. Geology, 23, 665668.
Foose, M.P., Economou, M., and Panayotou, A. (1985) Compositional and mineral-ogic constraints in the Limassol Forest portion of the Troodos ophiolite com-plex, Cyprus. Mineralium Deposita, 20, 234240.
Force, E.R. (1991) Geology of titanium-mineral deposits. Geological Society ofAmerica Special Paper 259, 112 p.
Frietsch, R. (1978) On the magmatic origin of iron ores of the Kiruna type. Eco-nomic Geology, 73, 478485.
Gjata, K., Shallo, M., Neziraj, A., Meshi A., and Xhomo, A. (1995) Geologicalsection in Western type ophiolites. Workshop on Albanian ophiolites and re-lated mineralization, IUGS/UNESCO Modelling Progmamme. Documents duBRGM 244, 121138.
Hemley, J.J., Cygan, G.L., Fein, J.B., Robinson, G.R., and D Angelo, W.M. (1992).Hydrothermal ore-forming processes in the light of studies in rock-bufferedsystems: 1. Iron-copper-zinc-lead-sulfide solubility relations. Economic Geol-ogy 87, 122.
Henriquez, F. and Martin, R.F. (1978) Crystal growth textures in magnetite flowsand feeder dykes, El Laco, Chile. Canadian Mineralogist, 16, 581589.
Herz, N. and Force, E.R. (1987) Geology and mineral deposits of the Roselanddistrict of Central Virginia. U.S. Geological Survey Professional Paper 1371,56 p.
Herz, N. and Valetine, L.B. (1970) Rutile in the Harford Country, Maryland, serpen-tine belt. U.S. Geological Survey Professional Paper 700-C, 4348.
Hildebrand, R.S. (1986) Kiruna-type deposits: their origin and relationship to inter-mediate subvolcanic plutons in the Great Bear magmatic zone, northwest Canada.Economic Geology, 81, 640659.
Hitzman, M.W., Oreskes, N., and Einaudi, M.T. (1992) Geological characteristicsand tectinic setting of Proterozoic iron oxide (Cu-U-Au-REE) deposits. Pre-cambrian Research, 58, 241287.
Honnorez, J. and Kirst, P. (1975) Petrology of rodingites from the equatorial Mid-Atlantic fracture zones and their geotectonic significance. Contributions toMineralogy and Petrology, 49, 233257.
Hopkinson, L. and Roberts, S. (1995) Ridge axis deformation and coeval melt mi-gration within layer 3 gabbros: evidence from the Lizard complex, U.K. Con-tributions to Mineralogy and Petrology 121, 126138.
Hynes, A.J. (1972) The geology of part of the western Othrys mountains, Greece.Ph.D. thesis, University of Cambridge.
Karkanas, P., Laskou, M., Economou-Eliopoulos, M., and Zhelyaskova-Panayotova,
M. (1996) Amphibolite dikes within the Zidani Asbestos mine, Northern Greece,
and their significance. Ofioliti, 21, 117123.Kolker, A. (1982) Mineralogy and geochemistry of Fe-Ti oxide and apatite (nelsonite)
deposits and evaluation of the liquid immiscibility hypothesis. Economic Geol-ogy, 77, 11461158.
Konstantopoulou, G. and Rassios, A. (1993) Application in the Othris Area. In :Advanced Tectonic and Geochemical Methods for Chrome Exploration inOphiolites. Contract MA2M-CT90-0035, Final Technical Report, 96102.
Lyons, I.J. (1988) Volcanogenic Iron Oxide deposits, Cerro de Mercado and Vicin-ity, Durango, Mexico. Economic Geology, 83, 18861906.
McKeown, F.A. and Klemic, H. (1956) Rare-earth-bearing apatite at Minevill, EssexCounty, New York. U.S. Geological Survey Bulletin, 1046-B, 923.
Menzies, M. (1973) Mineralogy and partial melt textures within an ultramafic-ma-fic body, Greece. Contributions to Mineralogy and Petrology, 43, 273285.
Menzies, M.A. (1974) The petrogenesis of the Makrirakhi ultramafic complex. Ph.D.Thesis, University of Cambridge.
Mitchell, L., Faust, G.T., Hendricks, S.B., and Reynolds, D.S. (1943) The mineral-ogy and genesis of hydroxylapatite. American Mineralogist, 28,356371.
Murray, J.R. and Oreskes, N. (1997) Uses and limitations of cathdoluminescence inthe study of apatite paragenesis. Economoc Geology, 92, 368376.
Naslund, H.R., Dobbs, F.M., Henriquz, F.J., and Nystrom, J.O. (1998) Evidence foriron-oxide magmas at El Laco, Chile. Geological Society of America Abstractswith Programs, 30, 91.
Nickel, E.G., Hallberg, J.A., and Halligan, R. (1979) Unusual nickel mineralizationat Nullagine, Western Australia. Journal of Geological Society of Australia, 26,6171.
Nicolas, A. (1989) Structures of ophiolites and dynamics of oceanic lithosphere,397 p., Kluwer Academic Publishers, Dordrecht.
Nisbet, E.G. (1974) The geology of the Neraida area, Othrys mountains, Greece.Ph.D. thesis, University of Cambridge.
Nystrom, J.O. and Henriquez, F. (1994) Magmatic features of iron ores of the Kirunatype in Chile and Sweden: Ore textures and magnetite geochemistry. EconomicGeology 89, 820839.
Owens, B.E. and Dymek R.F. (1992) Fe-Ti-P rich rocks and massif anorthosite:Problems of interpretation illustrated from the Labrieville and St-Urbain plu-tons, Quebec. Canadian Mineralogist, 30, 163190.
Parak, T. (1975). Kiruna Iron Ores Are Not Intrusive-Magmatic Ores of the KirunaType. Economic Geology, 70, 12421258.
Paraskevopoulos, G. and Economou, M. (1986) Komatiite type ultramafic lavasfrom the Agrilia Formation, Othrys ophiolite complex. Ofioliti, 11, 293304.
Paraskevopoulos, G. and Economou-Eliopoulos M. (1997) Geochemistry and geo-tectonic setting of basaltic rocks from the Othrys ophiolite complex. AnnalesGeologiques des Pays Helleniques, 37, 611612.
Park, C.F. (1961) A magnetite flow in northern Chile. Economic Geology, 56, 431436.
Philpotts, A.R. (1967) Origin of certain iron-titanium oxide and apatite rocks. Eco-nomic Geology, 62, 303315.(1981) A model for the generation of massif-type anorthosites. Canadian
Mineralogist, 19, 233253.Roedder, E. (1984) Fluid inclusions. Review of Minerals, 12, 644 p.Scott, S.D., Chase, M.D., Hannington, P.J., Mcconachy, T.F., and Shea, G.T. (1990)
Sulfide deposits, tectonics and petrogenesis of Southern, Explores Ridge, NEPacific ocean. In Malpas, J. , Moores, E,M., Panayotou, A., and Xenophodos, C.(eds). Proceedings of the International Symposium on Ophiolites, OceanicCrustal Evolution, Nicosia, 719733.
Smith, A.G., Hynes, A.J., Menzies, M., Nisbet, E.G., Price. I.,Welland, M.J., andFerriere, J. (1975) The stratigraphy of the Othris mountains, Eastern CentralGreece: a deformed mesozoic continental margin sequence. Eclogae Geol. Helv.,68, 463481.
Southwick, D.L. (1968) Mineralogy of a rutile and apatite-bearing ultramafic chlo-rite rock, Harford county, Maryland. U.S. Geological Survey Prof. Paper 600C. p C38C44.
Sovatsoglou-Skounakis, E. (1982) Metallogeny of Cu-bearing pyrite related to ba-
sic rocks of the Othrys ophiolite complex. Ph. D. Thesis, Athens University,132 p.
Tashko, A., Laskou, M., Economou, M., and Economou G. (1998) On the origin ofTi-magnetite from the Puka ophiolitic massif, Albania. Bulletin of GeologicalSociety of Greece XXXII-3, 3946.
Taylor, S.R. and McLennan, S.M. (1985) The continental crust: its composition andevolution. Blackwell, Oxford.
Von Gruenewaldt, G. (1994). Ilmenite-apatite enrichment in the upper zone of theBushveld Complex: a major titanium-rock phosphate resource. InternationalGeology Reviews, 35, 9871000.
Watson, E.B. and Green, T.H. (1981) Apatite/liquid partition coefficients for therare earth elements and strontium. Earth and Planetary Science Letters, 56, 405421.
MANUSCRIPTRECEIVED DECEMBER 6, 2000MANUSCRIPTACCEPTED JUNE 22, 2001
MANUSCRIPT
HANDLED
BY
BRENT
OWENS