Northwest Cyantoxin Results 7-11-19€¦ · 2019-07-11  · Colorado Radiochemistry IN00035 New...

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LABORATORY REPORT This report may not be reproduced, except in full, without written approval from EEA. If you have any questions concerning this report, please do not hesitate to call us at (800) 332-4345 or (574) 233-4777. Page 1 of 14 =: :: eu ro fi ns I Eaton Analytical

Transcript of Northwest Cyantoxin Results 7-11-19€¦ · 2019-07-11  · Colorado Radiochemistry IN00035 New...

  • LABORATORY REPORT

    This report may not be reproduced, except in full, without written approval from EEA.

    If you have any questions concerning this report, please do not hesitate to call us at (800) 332-4345 or (574) 233-4777.

    Page 1 of 14

    =::: e u ro fi n s I Eaton Analytical

  •  

    Revision date:  03/14/2019  

    STATE CERTIFICATION LIST

    State Certification State Certification Alabama 40700 Missouri 880 Alaska IN00035 Montana CERT0026 Arizona AZ0432 Nebraska NE-OS-05-04

    Arkansas IN00035 Nevada IN00035 California 2920 New Hampshire* 2124 Colorado IN00035 New Jersey* IN598

    Colorado Radiochemistry IN00035 New Mexico IN00035 Connecticut PH-0132 New York* 11398 Delaware IN035 North Carolina 18700 Florida* E87775 North Dakota R-035 Georgia 929 Ohio 87775 Hawaii IN035 Oklahoma D9508 Idaho IN00035 Oregon (Primary AB)* 4074

    Illinois* 200001 Pennsylvania* 68-00466 Illinois Microbiology 17767 Puerto Rico IN00035

    Illinois Radiochemistry IN00035 Rhode Island LAO00343 Indiana Chemistry C-71-01 South Carolina 95005

    Indiana Microbiology M-76-07 South Dakota IN00035 Iowa 098 Tennessee TN02973

    Kansas* E-10233 Texas* T104704187-18-12 Kentucky 90056 Texas/TCEQ TX207

    Louisiana* LA014 Utah* IN00035 Maine IN00035 Vermont VT-8775

    Maryland 209 Virginia* 460275 Massachusetts M-IN035 Washington C837

    Michigan 9926 West Virginia 9927 C Minnesota* 018-999-338 Wisconsin 999766900 Mississippi IN035 Wyoming IN035

    EPA IN00035 *NELAP/TNI Recognized Accreditation Bodies

    Page 2 of 14

    ~:: eu rofi ns I Eaton Analytical

  • Laboratory Report

    Client:

    Attn:

    Report:

    Priority:

    Status:

    PWS ID:

    Hillsborough County Board of County Commissioners

    Ed Watson

    332 N. Falkenburd Rd.

    458552

    FL6290388

    Standard Written

    Final

    Tampa, FL 33619

    Sample Event Code:

    PWS Facility ID:

    Sampling Point ID:

    00002

    0388002

    SE3

    Lab ID Code: IN00035

    110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345

    EEA ID #

    Client ID Method CollectedDate / Time

    CollectedBy:

    ReceivedDate / Time

    4353985 19070027-02 545 07/11/19 13:45 Client 07/16/19 10:15

    4353986 19070027-02 546 07/11/19 13:45 Client 07/16/19 10:15

    Sample Information

    Report Summary

    Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.

    We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.

    Note: This report may not be reproduced, except in full, without written approval from EEA.

    Client Name:

    Report #:

    Hillsborough County Board of County Commissioners

    458552

    Authorized Signature Title Date

    07/26/2019

    Page 1 of 2

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    =:~ eurofins I Eaton Analytical

    I I

    Analytical Services Manager

  • Client Name: Report #: 458552Hillsborough County Board of County Commissioners

    Sampling Point ID: PWS ID: FL62903880388002

    UCMR Result Summary

    AnalyteID #

    Analyte Method MRL† Result Units PreparationDate

    AnalyzedDate

    EEAID #

    3311 Anatoxin-a 545 0.0300 < 0.0300 ug/L 07/17/19 13:51 07/17/19 23:44 4353985

    3302 Cylindrospermopsin 545 0.0900 < 0.0900 ug/L 07/17/19 13:51 07/17/19 23:44 4353985

    3301 Total Microcystins & Nodularins 546 0.300 < 0.300 ug/L 07/19/19 13:30 07/22/19 08:57 4353986

    CVTM Percent CV 546 N/A 1.90 % 07/19/19 13:30 07/22/19 08:57 4353986

    † EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.

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    Page 4 of 14

    II I

    ~

  • Lab Definitions

    Continuing Calibration Check Standard (CCC) / Continuing Calibration Verification (CCV) / Initial Calibration Verification Standard (ICV) / Initial Performance Check (IPC) - is a standard containing one or more of the target analytes that is prepared from the same standards used to calibrate the instrument. This standard is used to verify the calibration curve at the beginning of each analytical sequence, and may also be analyzed throughout and at the end of the sequence. The concentration of continuing standards may be varied, when prescribed by the reference method, so that the range of the calibration curve is verified on a regular basis. CCL, CCM, and CCH are the CCC standards at low, mid, and high concentration levels, respectively.

    Internal Standards (IS) - are pure compounds with properties similar to the analytes of interest, which are added to field samples or extracts, calibration standards, and quality control standards at a known concentration. They are used to measure the relative responses of the analytes of interest and surrogates in the sample, calibration standard or quality control standard.

    Laboratory Duplicate (LD) - is a field sample aliquot taken from the same sample container in the laboratory and analyzed separately using identical procedures. Analysis of laboratory duplicates provides a measure of the precision of the laboratory procedures.

    Laboratory Fortified Blank (LFB) / Laboratory Control Sample (LCS) - is an aliquot of reagent water to which known concentrations of the analytes of interest are added. The LFB is analyzed exactly the same as the field samples. LFBs are used to determine whether the method is in control. FBL, FBM, and FBH are the LFB samples at low, mid, and high concentration levels, respectively.

    Laboratory Method Blank (LMB) / Laboratory Reagent Blank (LRB) - is a sample of reagent water included in the sample batch analyzed in the same way as the associated field samples. The LMB is used to determine if method analytes or other background contamination have been introduced during the preparation or analytical procedure. The LMB is analyzed exactly the same as the field samples.

    Laboratory Trip Blank (LTB) / Field Reagent Blank (FRB) - is a sample of laboratory reagent water placed in a sample container in the laboratory and treated as a field sample, including storage, preservation, and all analytical procedures. The FRB/LTB container follows the collection bottles to and from the collection site, but the FRB/LTB is not opened at any time during the trip. The FRB/LTB is primarily a travel blank used to verify that the samples were not contaminated during shipment.

    Matrix Spike Duplicate Sample (MSD) / Laboratory Fortified Sample Matrix Duplicate (LFSMD) - is a sample aliquot taken from the same field sample source as the Matrix Spike Sample to which known quantities of the analytes of interest are added in the laboratory. The MSD is analyzed exactly the same as the field samples. Analysis of the MSD provides a measure of the precision of the laboratory procedures in a specific matrix. SDL, SDM, and SDH / LFSMDL, LFSMDM, and LFSMDH are the MSD or LFSMD at low, mid, and high concentration levels, respectively.

    Matrix Spike Sample (MS) / Laboratory Fortified Sample Matrix (LFSM) - is a sample aliquot taken from field sample source to which known quantities of the analytes of interest are added in the laboratory. The MS is analyzed exactly the same as the field samples. The purpose is to demonstrate recovery of the analytes from a sample matrix to determine if the specific matrix contributes bias to the analytical results. MSL, MSM, and MSH / LFSML, LFSMM, and LFSMH are the MS or LFSM at low, mid, and high concentration levels, respectively.

    Quality Control Standard (QCS) / Second Source Calibration Verification (SSCV) - is a solution containing known concentrations of the analytes of interest prepared from a source different from the source of the calibration standards. The solution is obtained from a second manufacturer or lot if the lot can be demonstrated by the manufacturer as prepared independently from other lots. The QCS sample is analyzed using the same procedures as field samples. The QCS is used as a check on the calibration standards used in the method on a routine basis.

    Reporting Limit Check (RLC) / Initial Calibration Check Standard (ICCS) - is a procedural standard that is analyzed each day to evaluate instrument performance at or below the minimum reporting limit (MRL).

    Surrogate Standard (SS) / Surrogate Analyte (SUR) - is a pure compound with properties similar to the analytes of interest, which is highly unlikely to be found in any field sample, that is added to the field samples, calibration standards, blanks and quality control standards before sample preparation. The SS is used to evaluate the efficiency of the sample preparation process.

    Page 1 of 1

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  • Laboratory Report

    Client:

    Attn:

    Report:

    Priority:

    Status:

    PWS ID:

    Hillsborough County Board of County Commissioners

    Ed Watson

    332 N. Falkenburd Rd.

    458552

    FL6290388

    Standard Written

    Final

    Tampa, FL 33619

    110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345

    EEA ID #

    Client ID Method CollectedDate / Time

    CollectedBy:

    ReceivedDate / Time

    4353984 19070027-02 544 07/11/19 13:45 Client 07/16/19 10:15

    Sample Information

    Report Summary

    Method 544 analysis will be performed only if the associated Screening Microcystin by EPA 546 sample result is >=0.3 ug/L.

    We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.

    Note: This report may not be reproduced, except in full, without written approval from EEA.

    Authorized Signature Title Date

    07/26/2019

    Page 1 of 1

    Page 6 of 14

    =:~ eurofins I Eaton Analytical

    Analytical Services Manager

  • Page 7 of 14

    ::,..__ ~ t/)

    .j/_ 3&9 795 Subcontracted Chain of Custody L./'5f5S-Z.... ,------- - ------ - ---,

    --- II I I II I 111111111111111 Hillsborough County Florida

    Environmental Laboratory Customer: Northwest Hillsborough CWS

    Public Utilities

    Sample ID: Customer:

    19070027-01-1 Northwest Hillsborough CWS

    Address: 17316 N Dale Mabry Hwy

    Collector: Grayson, Justin

    19070027-01-2 Northwest Hillsborough CWS

    Address: 17316 N Dale Mabry Hwy

    Collector: Grayson, Justin

    19070027-01-3 Northwest Hillsborough CWS

    Address: 17316 N Dale Mabry Hwy

    Collector: Grayson, Justin

    19070027-01-4 Northwest Hillsborough CWS

    Address: 17316 N Dale Mabry Hwy

    Collector: Grayson, Justin

    19070027-01-5 Northwest Hillsborough CWS

    Address: 17316 N Dale Mabry Hwy

    Collector: Grayson, Justin

    PWS#

    6290388

    9456 E Columbus Dr Tampa, FL 33619

    Certification Number: E44104

    Phone No. (813) 272-5977 x 43635

    Site:

    lPWTP-002

    Collection Date/Time:

    Start: 7/11/2019 9:40:00 AM

    End: 7/11/2019 9:40:00 AM

    Tille: Environmental Specialist I

    6290388 lPWTP- Stan: 7/11/2019 9:40:00 AM 002 End: 7/11/2019 9:40:00 AM

    Tille: Environmental Specialist I

    6290388 lPWTP- Start: 7/11/2019 9:40:00 AM 002 End: 7/11/2019 9:40:00 AM

    TIiie: Environmental Specialist I

    6290366 LPWTP- Stan: 7/11/2019 9:40:00 AM 002 End: 7/11/2019 9:40:00 AM

    Tille: Environmental Specialist I

    6290388 lPWTP- Stan: 7/11/2019 9:40:00 AM 002

    End: 7/1 1/2019 9:40:00 AM

    Tille: Environmental Specialist I

    Work Order: 19070027

    Scheduled Sample NW UCMR4-CYN Set Name:

    Subcontracted Vendor: Eurofins Eaton Analytical ,..

    Project: NW - UCMR4-CYN

    Contact: Stanley, John (Chief Environmental Scientist)

    Phone: (813) 272-5977 x 43635

    Profile#

    Sample Information Sample Type:

    Drinking Water

    (Grab)

    Drinking Water

    (Grab)

    Drinking Water

    (Grab)

    Drinking Waler

    (Grab)

    Drinking Waler

    (Grab)

    Container Type:

    Glass 250 ml Amber

    Glass 250 ml Amber

    Glass 250 ml Amber

    Glass 125 mL Amber

    Glass 125 ml Amber

    Preservative: Analysis Method:

    Trizma + 2CI acelamide 544 - Microcystins Subcontracted +AA+ EDTA UCMR List

    Trizma + 2CI acetamide +AA+EDTA

    Trizma + 2CI acetamide +AA+EDTA

    AA + bisulfate

    Na2S203

    545 - Cylindrospermin and Anatoxin Subcontracted

    546 - Total Microcystins Subcontracted

    Analytes:

    Q.

    • 19070027-02-1 Northwest Hillsborough CWS

    Address: 12950 Fawnridge Blvd

    6290388 NWPWF- Stan: 7111/2019 1 :45:00 PM Drinking Waler 002 End: 7/11/2019 1 :45:00 PM (Grab)

    Glass 250 ml Amber Trizma + 2CI acetamide 544 - Microcyslins Subcontracted +AA+ EDTA UCMR Lisi

    o . ~cc A';/.J\ Collector: Grayson, Justin TIiie: Environmental Specialist I

    19070027 -02-2 Northwest Hillsborough CWS 6290388 NWPWF- Start:

    Address: 12950 Fawnridge Blvd 002 End:

    Collector: Grayson, Justin TIiie: Environmental Specialist I

    9070027-02-3 _.Northwest Hillsborough CWS

    Address: 12950 Fawnridge Blvd

    6290388 NWPWF- Start: 002 End:

    Collector: Grayson, Justin TIiie: Environmental Specialist I

    Report Generated: 07/11 /2019 02:50 PM

    RP.nnrt Version-:~ 5 2 8 1 Last RevisP.d 5/1~/2019 3 :20 :52 PM

    7/11/2019 1 :45:00 PM Drinking Water

    7111/2019 1 :45:00 PM (Grab)

    7111/20191 :45:00 PM Drinking Water

    7111/2019 1:45:00 PM (Grab)

    Glass 250 ml Amber

    Glass 250 ml Amber

    Trizma + 2CI acelamide +AA+EDTA

    Trizma + 2CI acetamide +AA+ EDTA

    I:;~

  • Page 8 of 14

    Subcontracted Chain of Custody ,---_------------------, ,------~-----------

    (~') ~

    Hillsborough County rlorida Public Utilities

    Environmental Laboratory

    9456 E Columbus Dr Tampa, FL 33619

    Certification Number: E44104

    Phone No. (813) 272-5977 x 43635

    1111111111111111111111 Work Order: 19070027

    Scheduled Sample NW UCMR4-CYN Set Name:

    Subcontracted Vendor: Eurofins Eaton Analytical ~

    Sample Information

    Customer: Northwest Hillsborough CWS

    Project: NW - UCMR4-CYN

    Contact: Stanley, John (Chief Environmental Scientist)

    Phone: (813) 272-5977 x 43635

    Profile#

    Sample ID: Customer: PWS# Site: Collection Daterrime: Sample Type: Container Type: Preservative: Analysis Method: Analytes: 'Res;aucR chlti t1"1L 4.bttnf 9070027-02-4 Northwest Hillsborough CWS 6290388 NWPWF- Start:

    Address: 12950 Fawnridge Blvd 002 End:

    Collector: Grayson, Justin Title: Environmental Specialist I

    19070027-02-5 Northwest Hillsborough CWS 6290388 NWPWF- Start:

    Address: 12950 Fawnridge Blvd 002

    End:

    Collector: Grayson, Juslin Title: Environmental Specialist I

    :,~y ~~ Date/Time. t - I I -1 q 111S7.. (

    Rehnqu:shed By: Oatotrirne

    Relinquished By· Datemme.

    R eport Generated: 07/11/2019 02:50 PM

    R1rnnrt Version".\.S.28.1 L;:isl Revisen S/131201 !l 3 :20:S2 PM

    7/11/2019 1 :45:00 PM Drinking Water Glass 125 ml Amber

    7/11/2019 1 :45:00 PM (Grab)

    7/11/20191:45:00 PM Drinking Water Glass 125 ml Amber

    7/11/20191:45:00 PM (Grab)

    Accepled By; OatefTime:

    AccepledBy OalefTime

    Accepted By DalefTlme·

    AA + bisulfate

    Na2S203

    545 • Cylindrospermin and Anatoxin Subcontracted

    () , t.(dC

    ,C}f'S 546 • Total Microcystins Subcontracted G) • '{ • C.

    L/ :7:,5 ; OJ N Notes

    Page 2 of 2

  • Eurofins Eaton AnalyticalRun Log

    Run ID: 262038 Method: 545

    Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix

    CCL 4354676 CY 071719M545a-CY.mdb07/17/2019 17:38RW

    QCS 4354675 CY 071719M545a-CY.mdb07/17/2019 17:53RW

    LRB 4355044 CY 071719M545a-CY.mdb07/17/2019 18:07RW

    CCM 4354677 CY 071719M545a-CY.mdb07/17/2019 21:18RW

    FS 4353985 19070027-02 CY 071719M545a-CY.mdb07/17/2019 23:44DW

    CCH 4354678 CY 071719M545a-CY.mdb07/17/2019 23:59RW

    0.00

    Page 1 of 2 EEA Run ID 262038 / EEA Report # 458552

    Page 9 of 14

    =::: e u rofi n s I Eaton Analytical

  • QC Summary Report

    EEAID #

    RPDUnitsTargetAmountClient IDMethodAnalyteSampleType

    DilFactor

    RPDLimit

    RecoveryLimits

    % Recovery

    ResultFlag

    MRL Extracted Analyzed

    False

    IS-L-phenylalanine-d5 545 N/ACCL 21674 ug/L 1.0 4354676--- ------50 - 1509921941 07/02/2019 12:30 07/17/2019 17:38False

    IS-Uracil-d4 545 N/ACCL 8146 ug/L 1.0 4354676--- ------50 - 1501047851 07/02/2019 12:30 07/17/2019 17:38False

    Anatoxin-a 545 0.0300CCL 0.028633 ug/L 1.0 4354676--- ------50 - 150950.03 07/02/2019 12:30 07/17/2019 17:38False

    Cylindrospermopsin 545 0.0900CCL 0.09572 ug/L 1.0 4354676--- ------50 - 1501060.09 07/02/2019 12:30 07/17/2019 17:38True

    IS-L-phenylalanine-d5 545 N/AQCS 20356 ug/L 1.0 4354675--- ------50 - 1509321941 07/02/2019 12:30 07/17/2019 17:53True

    IS-Uracil-d4 545 N/AQCS 8400 ug/L 1.0 4354675--- ------50 - 1501077851 07/02/2019 12:30 07/17/2019 17:53True

    Anatoxin-a 545 0.0300QCS 0.586247 ug/L 1.0 4354675--- ------70 - 1301170.5 07/02/2019 12:30 07/17/2019 17:53True

    Cylindrospermopsin 545 0.0900QCS 1.31115 ug/L 1.0 4354675--- ------70 - 130871.5 07/02/2019 12:30 07/17/2019 17:53False

    IS-L-phenylalanine-d5 545 N/ALRB 19431 ug/L 1.0 4355044--- ------50 - 1508921941 07/17/2019 13:51 07/17/2019 18:07False

    IS-Uracil-d4 545 N/ALRB 8093 ug/L 1.0 4355044--- ------50 - 1501037851 07/17/2019 13:51 07/17/2019 18:07False

    Anatoxin-a 545 0.0300LRB 0.002141 ug/L 1.0 4355044--- ------------ < 07/17/2019 13:51 07/17/2019 18:07False

    Cylindrospermopsin 545 0.0900LRB 0.0 ug/L 1.0 4355044--- ------------ < 07/17/2019 13:51 07/17/2019 18:07True

    IS-L-phenylalanine-d5 545 N/ACCM 22141 ug/L 1.0 4354677--- ------50 - 15010121941 07/02/2019 12:30 07/17/2019 21:18True

    IS-Uracil-d4 545 N/ACCM 7934 ug/L 1.0 4354677--- ------50 - 1501017851 07/02/2019 12:30 07/17/2019 21:18True

    Anatoxin-a 545 0.0300CCM 0.473143 ug/L 1.0 4354677--- ------70 - 130950.5 07/02/2019 12:30 07/17/2019 21:18True

    Cylindrospermopsin 545 0.0900CCM 1.23156 ug/L 1.0 4354677--- ------70 - 130821.5 07/02/2019 12:30 07/17/2019 21:18False

    IS-L-phenylalanine-d5 545 N/AFS 20220 ug/L 1.0 435398519070027-02 ------50 - 1509221941 07/17/2019 13:51 07/17/2019 23:44False

    IS-Uracil-d4 545 N/AFS 9673 ug/L 1.0 435398519070027-02 ------50 - 1501237851 07/17/2019 13:51 07/17/2019 23:44False

    Anatoxin-a 545 0.0300FS 0.0300 ug/L 1.0 435398519070027-02 ------------ < 07/17/2019 13:51 07/17/2019 23:44False

    Cylindrospermopsin 545 0.0900FS 0.0900 ug/L 1.0 435398519070027-02 ------------ < 07/17/2019 13:51 07/17/2019 23:44True

    IS-L-phenylalanine-d5 545 N/ACCH 21574 ug/L 1.0 4354678--- ------50 - 1509821941 07/02/2019 12:30 07/17/2019 23:59True

    IS-Uracil-d4 545 N/ACCH 8389 ug/L 1.0 4354678--- ------50 - 1501077851 07/02/2019 12:30 07/17/2019 23:59True

    Anatoxin-a 545 0.0300CCH 1.961 ug/L 1.0 4354678--- ------70 - 130982.0 07/02/2019 12:30 07/17/2019 23:59True

    Cylindrospermopsin 545 0.0900CCH 5.37284 ug/L 1.0 4354678--- ------70 - 130906.0 07/02/2019 12:30 07/17/2019 23:59

    Page 2 of 2 EEA Run ID 262038 / EEA Report # 458552

    Page 10 of 14

    D

    D

    .___.ODD□□ DDDDDDDD

    DODD□

  • Eurofins Eaton AnalyticalRun Log

    Run ID: 262209 Method: 546

    Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix

    FS 4353986 19070027-02 FH 07/22/2019 08:57DW

    LRB 4358071 FH 07/22/2019 08:57RW

    LRB 4358072 FH 07/22/2019 08:57RW

    LFB 4358073 FH 07/22/2019 08:57RW

    LFB 4358074 FH 07/22/2019 08:57RW

    CCL 4358075 FH 07/22/2019 08:57RW

    QCS 4358076 FH 07/22/2019 08:57RW

    FS 4353986 19070027-02 FH 07/22/2019 08:57DW

    LRB 4358071 FH 07/22/2019 08:57RW

    LRB 4358072 FH 07/22/2019 08:57RW

    0.00

    Page 1 of 2 EEA Run ID 262209 / EEA Report # 458552

    Page 11 of 14

    =::: e u rofi n s I Eaton Analytical

  • QC Summary Report

    EEAID #

    RPDUnitsTargetAmountClient IDMethodAnalyteSampleType

    DilFactor

    RPDLimit

    RecoveryLimits

    % Recovery

    ResultFlag

    MRL Extracted Analyzed

    True

    Total Microcystins & Nodularins 546 0.300FS 0.300 ug/L 1.0 435398619070027-02 ------------ < 07/19/2019 13:30 07/22/2019 08:57True

    Percent CV 546 N/AFS 2 % 1.0 435398619070027-02 ------------ 07/19/2019 13:30 07/22/2019 08:57False

    Total Microcystins & Nodularins 546 0.300LRB 0.0 ug/L 1.0 4358071--- ------------ < 07/19/2019 13:30 07/22/2019 08:57False

    Percent CV 546 N/ALRB 1.6 % 1.0 4358071--- ------------ 07/19/2019 13:30 07/22/2019 08:57True

    Total Microcystins & Nodularins 546 0.300LRB 0.0 ug/L 1.0 4358072--- ------------ < 07/19/2019 13:30 07/22/2019 08:57True

    Percent CV 546 N/ALRB 1.699999 % 1.0 4358072--- ------------ 07/19/2019 13:30 07/22/2019 08:57False

    Total Microcystins & Nodularins 546 0.300LFB 0.538 ug/L 1.0 4358073--- ------60 - 1401080.5 07/19/2019 13:30 07/22/2019 08:57True

    Total Microcystins & Nodularins 546 0.300LFB 0.562 ug/L 1.0 4358074--- ------60 - 1401120.5 07/19/2019 13:30 07/22/2019 08:57False

    Total Microcystins & Nodularins 546 0.300CCL 0.239999 ug/L 1.0 4358075--- ------50 - 150800.3 --- 07/22/2019 08:57True

    Total Microcystins & Nodularins 546 0.300QCS 0.678 ug/L 1.0 4358076--- ------70 - 1301130.6 --- 07/22/2019 08:57

    Page 2 of 2 EEA Run ID 262209 / EEA Report # 458552

    Page 12 of 14

    1~~rnrnrnt ~ D

    D

    =O==ll==O==ll==ll=]D[ =

    ll=====ll=ll==l~l=l~~l=□[ =

    ....______.____ODD□□--□-

  • Sample Type Key

    Type (Abbr.) Sample Type Type (Abbr.) Sample Type

    CCH Continuing Calibration High

    CCL Continuing Calibration Low

    CCM Continuing Calibration Mid

    FS Field Sample

    LFB Laboratory Fortified Blank

    LRB Laboratory Reagent Blank

    QCS Quality Control Sample

    1.00

    Page 13 of 14

  • END OF REPORT

    Page 14 of 14

  • LABORATORY REPORT

    This report may not be reproduced, except in full, without written approval from EEA.

    If you have any questions concerning this report, please do not hesitate to call us at (800) 332-4345 or (574) 233-4777.

    Page 1 of 14

    =::: e u ro fi n s I Eaton Analytical

  •  

    Revision date:  03/14/2019  

    STATE CERTIFICATION LIST

    State Certification State Certification Alabama 40700 Missouri 880 Alaska IN00035 Montana CERT0026 Arizona AZ0432 Nebraska NE-OS-05-04

    Arkansas IN00035 Nevada IN00035 California 2920 New Hampshire* 2124 Colorado IN00035 New Jersey* IN598

    Colorado Radiochemistry IN00035 New Mexico IN00035 Connecticut PH-0132 New York* 11398 Delaware IN035 North Carolina 18700 Florida* E87775 North Dakota R-035 Georgia 929 Ohio 87775 Hawaii IN035 Oklahoma D9508 Idaho IN00035 Oregon (Primary AB)* 4074

    Illinois* 200001 Pennsylvania* 68-00466 Illinois Microbiology 17767 Puerto Rico IN00035

    Illinois Radiochemistry IN00035 Rhode Island LAO00343 Indiana Chemistry C-71-01 South Carolina 95005

    Indiana Microbiology M-76-07 South Dakota IN00035 Iowa 098 Tennessee TN02973

    Kansas* E-10233 Texas* T104704187-18-12 Kentucky 90056 Texas/TCEQ TX207

    Louisiana* LA014 Utah* IN00035 Maine IN00035 Vermont VT-8775

    Maryland 209 Virginia* 460275 Massachusetts M-IN035 Washington C837

    Michigan 9926 West Virginia 9927 C Minnesota* 018-999-338 Wisconsin 999766900 Mississippi IN035 Wyoming IN035

    EPA IN00035 *NELAP/TNI Recognized Accreditation Bodies

    Page 2 of 14

    ~:: eu rofi ns I Eaton Analytical

  • Laboratory Report

    Client:

    Attn:

    Report:

    Priority:

    Status:

    PWS ID:

    Hillsborough County Board of County Commissioners

    Ed Watson

    332 N. Falkenburd Rd.

    458551

    FL6290388

    Standard Written

    Final

    Tampa, FL 33619

    Sample Event Code:

    PWS Facility ID:

    Sampling Point ID:

    00001

    0388001

    SE3

    Lab ID Code: IN00035

    110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345

    EEA ID #

    Client ID Method CollectedDate / Time

    CollectedBy:

    ReceivedDate / Time

    4353966 19070027-01 545 07/11/19 09:40 Client 07/16/19 10:15

    4353967 19070027-01 546 07/11/19 09:40 Client 07/16/19 10:15

    Sample Information

    Report Summary

    Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.

    We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.

    Note: This report may not be reproduced, except in full, without written approval from EEA.

    Client Name:

    Report #:

    Hillsborough County Board of County Commissioners

    458551

    Authorized Signature Title Date

    09/10/2019

    Page 1 of 2

    Page 3 of 14

    =:~ eurofins I Eaton Analytical

    I I

    Analytical Services Manager

  • Client Name: Report #: 458551Hillsborough County Board of County Commissioners

    Sampling Point ID: PWS ID: FL62903880388001

    UCMR Result Summary

    AnalyteID #

    Analyte Method MRL† Result Units PreparationDate

    AnalyzedDate

    EEAID #

    3311 Anatoxin-a 545 0.0300 < 0.0300 ug/L 07/17/19 13:51 07/17/19 23:30 4353966

    3302 Cylindrospermopsin 545 0.0900 < 0.0900 ug/L 07/17/19 13:51 07/17/19 23:30 4353966

    3301 Total Microcystins & Nodularins 546 0.300 < 0.300 ug/L 07/19/19 13:30 07/22/19 08:57 4353967

    CVTM Percent CV 546 N/A 1.80 % 07/19/19 13:30 07/22/19 08:57 4353967

    † EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.

    Page 2 of 2

    Page 4 of 14

    II I

    ~

  • Lab Definitions

    Continuing Calibration Check Standard (CCC) / Continuing Calibration Verification (CCV) / Initial Calibration Verification Standard (ICV) / Initial Performance Check (IPC) - is a standard containing one or more of the target analytes that is prepared from the same standards used to calibrate the instrument. This standard is used to verify the calibration curve at the beginning of each analytical sequence, and may also be analyzed throughout and at the end of the sequence. The concentration of continuing standards may be varied, when prescribed by the reference method, so that the range of the calibration curve is verified on a regular basis. CCL, CCM, and CCH are the CCC standards at low, mid, and high concentration levels, respectively.

    Internal Standards (IS) - are pure compounds with properties similar to the analytes of interest, which are added to field samples or extracts, calibration standards, and quality control standards at a known concentration. They are used to measure the relative responses of the analytes of interest and surrogates in the sample, calibration standard or quality control standard.

    Laboratory Duplicate (LD) - is a field sample aliquot taken from the same sample container in the laboratory and analyzed separately using identical procedures. Analysis of laboratory duplicates provides a measure of the precision of the laboratory procedures.

    Laboratory Fortified Blank (LFB) / Laboratory Control Sample (LCS) - is an aliquot of reagent water to which known concentrations of the analytes of interest are added. The LFB is analyzed exactly the same as the field samples. LFBs are used to determine whether the method is in control. FBL, FBM, and FBH are the LFB samples at low, mid, and high concentration levels, respectively.

    Laboratory Method Blank (LMB) / Laboratory Reagent Blank (LRB) - is a sample of reagent water included in the sample batch analyzed in the same way as the associated field samples. The LMB is used to determine if method analytes or other background contamination have been introduced during the preparation or analytical procedure. The LMB is analyzed exactly the same as the field samples.

    Laboratory Trip Blank (LTB) / Field Reagent Blank (FRB) - is a sample of laboratory reagent water placed in a sample container in the laboratory and treated as a field sample, including storage, preservation, and all analytical procedures. The FRB/LTB container follows the collection bottles to and from the collection site, but the FRB/LTB is not opened at any time during the trip. The FRB/LTB is primarily a travel blank used to verify that the samples were not contaminated during shipment.

    Matrix Spike Duplicate Sample (MSD) / Laboratory Fortified Sample Matrix Duplicate (LFSMD) - is a sample aliquot taken from the same field sample source as the Matrix Spike Sample to which known quantities of the analytes of interest are added in the laboratory. The MSD is analyzed exactly the same as the field samples. Analysis of the MSD provides a measure of the precision of the laboratory procedures in a specific matrix. SDL, SDM, and SDH / LFSMDL, LFSMDM, and LFSMDH are the MSD or LFSMD at low, mid, and high concentration levels, respectively.

    Matrix Spike Sample (MS) / Laboratory Fortified Sample Matrix (LFSM) - is a sample aliquot taken from field sample source to which known quantities of the analytes of interest are added in the laboratory. The MS is analyzed exactly the same as the field samples. The purpose is to demonstrate recovery of the analytes from a sample matrix to determine if the specific matrix contributes bias to the analytical results. MSL, MSM, and MSH / LFSML, LFSMM, and LFSMH are the MS or LFSM at low, mid, and high concentration levels, respectively.

    Quality Control Standard (QCS) / Second Source Calibration Verification (SSCV) - is a solution containing known concentrations of the analytes of interest prepared from a source different from the source of the calibration standards. The solution is obtained from a second manufacturer or lot if the lot can be demonstrated by the manufacturer as prepared independently from other lots. The QCS sample is analyzed using the same procedures as field samples. The QCS is used as a check on the calibration standards used in the method on a routine basis.

    Reporting Limit Check (RLC) / Initial Calibration Check Standard (ICCS) - is a procedural standard that is analyzed each day to evaluate instrument performance at or below the minimum reporting limit (MRL).

    Surrogate Standard (SS) / Surrogate Analyte (SUR) - is a pure compound with properties similar to the analytes of interest, which is highly unlikely to be found in any field sample, that is added to the field samples, calibration standards, blanks and quality control standards before sample preparation. The SS is used to evaluate the efficiency of the sample preparation process.

    Page 1 of 1

    Page 5 of 14

  • Laboratory Report

    Client:

    Attn:

    Report:

    Priority:

    Status:

    PWS ID:

    Hillsborough County Board of County Commissioners

    Ed Watson

    332 N. Falkenburd Rd.

    458551

    FL6290388

    Standard Written

    Final

    Tampa, FL 33619

    110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345

    EEA ID #

    Client ID Method CollectedDate / Time

    CollectedBy:

    ReceivedDate / Time

    4353965 19070027-01 544 07/11/19 09:40 Client 07/16/19 10:15

    Sample Information

    Report Summary

    Method 544 analysis will be performed only if the associated Screening Microcystin by EPA 546 sample result is >=0.3 ug/L.

    We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.

    Note: This report may not be reproduced, except in full, without written approval from EEA.

    Authorized Signature Title Date

    09/10/2019

    Page 1 of 1

    Page 6 of 14

    =:~ eurofins I Eaton Analytical

    Analytical Services Manager

  • Page 7 of 14

    Subcontracted C hain of Custody

    -di 3& 179g

    --------------

    7 I IJ I I 111111111111 fl I IJI Cosmme, Nom,w;;;;~~/_ Environmental Labo

    ratory

    ~ p .

    Work Order: 19070027 roiecr NW

    · UCMR4-CYN

    Hillsborough County

    9456 E Columbus Dr Tampa, FL 33619

    Sl!)TipletD·

    •o7nor Address

    ~Oi-002

    ,ddress

    • 9010021-0·

    Address

    Collector

    19070U2 NI• ·1

    Address

    Collector

    1.90711027 •0l-5

    Address

    Collector

    '9070027 -02-1

    Address

    Collector

    19070027-02·2

    Address

    Collector

    Public Ut1l1ti€S

    Customer

    ...Northwest Hillst:>orough CWS

    1'7';! 16 N Dale '-,11abry Hwy

    Graysor., Jusun

    Northwest H1llsb0rough CWS

    17316 N Dale Mabry Hwy

    Grayson Justin

    Nortn,vest H1llsbocough CWS

    17316 N Dale Mabry Hwy

    Grayson, Just in

    Northwest H11lsbo:ovgt. C\i\'S

    17316 N Dale Mabry HIN}

    Grayson, Justm

    Northwest Hillsborough CWS

    17316 N Dale Mat>ry Hwy

    Grayson. J1.,1sti11

    Nortnwest Hillsborough cws

    12950 t=awnndge Blvd

    Grayson. Justin

    Northwest Hillsborough CWS

    12950 Fawnridge Blvd

    Grayson, Justin

    Certification Number: E44104

    Phone No. (813) 272-5977 x 43635

    PWS~ Site Collection Date/Time:

    6290388 LPWTP· Start: 7 111/2019 9 40'0

    0 AM

    002 End: 7 /1 i/2019 9·40 00 AM

    Title Enwonmenta, Soec1al1s1 I

    5290388 LPWrP-Slart· 7/ 11/2019 9:40 0

    0 AM

    002 End 7/11/2019 9·40 00 AM

    Title E~·.-ironmental Specialist I

    6290388 LPWTP-Start· 7/ 11/2019 9 40 0

    0 AM

    002 End 7/1112019 9 40 00 AM

    Title C.nv,ronme-,tal Specialtst I

    --529n~as LPWTP S

    tan 711112019 9 40 00 AM

    002 End 7/11/2019 9 40 00 AM

    Title Er.wonmental Spec1ahst I

    6290388 LPWTP-Stan: 7/ 11/2019 9 40 0

    0 AM

    002 End 7/11/2019 9 40:00 AM

    Title Environmenta1 Specialist I

    6290388 NWPWF-SIan 7/11/2019 1 45

    00 PM

    002 End 7/11i2019 1 45·00 PM

    nue Environmenlal Specialist I

    6290368 NWPWF-Start 7111/2019 1.45 00 P

    M

    002 End· 7/11/2019 1 45·00 PM

    Tille Environmental Spec1ailsl I

    6290386 NWPWF-Stan: 7/11/2019 1 -15 00

    PM

    002 End· 111112019 1 45·oo PM

    Contact Stanley Joh

    Scheduled Sample NW UCMR4 ·CYN

    Scienti ' n (Chief Environment

    h~~ ~

    Phone (B13) 272-5977 X 43635

    Subcontracted Vendor Eurofins Eaton Analy

    t'c I P

    I bLC I a

    rofile #

    Sample Information ~------

    Sample Type . Container Type

    Drinking Waler Glass 250 ml Amber

    (Grab)

    Dn~k1ng Water Glass 250 ml Amber

    (Grab)

    Dnnk1n9 Water Glass 250 ml Amber

    (Grab)

    Dnskmg Water Glass 125 ml Ambe1

    (Grab)

    Octnk,ng Water Glass 125 ml Amber

    (Grab)

    Dnr.ktng Water Gfess 250 mL Ambe,

    (Grab)

    Drinking Water Glass 250 ml Amber

    (Grab)

    Drinking Water Glass 250 ml Ambei

    (Grab)

    Preservauve. Analysis Method

    Tnzma • 2CJ acetam,de

    +AA+ EDTA 544 . M1crocysuns Subcon

    lrac•ed

    UCMR List ·

    L/7,rj Tnzma • 2CI acetam1de +AA .. EDTA

    -Tnzma + 2CI acetam1de

    •AA• EDTA

    AA ~ b1sulfate -

    ~t Cyhndrosperm1n and Anatox,n u ontracted

    =i -3539(tl(I Na2S203 546 -To1a1 M1crocysuns Subcontracted

    lJ~S30(;7 Tnzma • 2Ci aceJamlde

    •AA• EDTA ~C4,;RM~~:cysnns Subcontracted

    -

    rrizma • 2CI ace1am1de

    •AA+ EDTl\

    rrizma • 2CI acetamide

    +AA+ EDTA

    Anal)l?es.

    3. '{•G

    f~ ~I-~

    Rt..,,~ c.n&;,.,._ AM,w

    /, 0 ~

    R.c.,s,d t.ccJ. Cit/,,,. I /IL

    o.c;, 'c R

  • Page 8 of 14

    Subcontracted Chain of Custody ----- - --------"7 i--------~----- - -----

    11111111 Ill lllll II I Ill Hillsborough county Public Utilities

    En vironmental Laboratory

    9456 E Columb us D r Tam pa, F L 3 3619

    Certific a tion Numb er : E44104

    Phone N o (81 3) 2 72-5977 x 43635

    Work Order: 19070027

    Scheduled Sample NW UCMR4-CYN Set Name

    Subcontracted Vendor Eurofins Eaton Ana lytica l

    Sample Information

    Customer Northwesl Hillsborough CWS

    Proiect

    Contact

    Phone

    Profile II

    NW - UCMR4-CYN

    Stanley, John (Chief Environmental Sc1enI1st)

    (813) 272-5977 X 43635

    PWS# Sile Collecuon DaterTime Sample Type Container Type Preservative Analysis Method A ly

    ,ner: na tes

    le ID Gus~ Samp e-.... nn-,oo ,.n,.,o,,.,c e ....... ..,., 1 1, .... n1n 1 , A c -nn

    cu. 11 n ...... l,,_..., ,,.,_.__ '"''~ ~ - --- · -

    19070027 -02-4

    Address

    Collector

    19070027 02-5

    6ddress

    i~1-z:· Re ll"IQ'.;~ .. c~ 81

    R'-- ,..,.,~ .. ~6,

    est Hillsborough CWS NorthW

    Fawnridge Blvd 12950

    Grayson, Juslin

    Northwest Hillsborough cws

    12950 Fawnndge Blvd

    ,on Justin ,--

    -✓--,, t

    6290~HH NWPWF-002

    Stan.

    End

    Title Environmental Spec1al1s1 I

    6290388 NWPWF-002

    Stan

    Fnd

    Title Environmental Specialist I

    Oaterm~

    t - I I - I Cf 11157__ 0.i(e,...,...,e

    Date.'ir:re

    R eport Generated 07111/201 9 0 2 :5 0 P M

    R1mor1 VP.rstnn 1 S ?A 1 I ;:iSI RP.visP.d S/13/?01 !l 3 ?O S? PM

    7/11/2019 1:45:00 PM

    7/11/2019 1 45:00 PM

    7/11/2019 14500 PM

    7/11/2019145.00 PM

    Acceplea By

    Accec,teo S\

    A.cc.er,le~ Bt

    Drinking Water

    (Grab)

    Drinking Water

    (Grab )

    Glass 125 ml Amber

    Glass 125 ml Amber

    O•·erT1ft'e

    :::>a·e ltn·e

    On:e f,,-.e

    AA • bisulfate

    Na2S203

    545 • Cylindrospermin and Anatox1n Subcontracted

    546 • Total Mrcrocyst,ns Subcontracted

    No:es

    Page 2 of

  • Eurofins Eaton AnalyticalRun Log

    Run ID: 262038 Method: 545

    Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix

    CCL 4354676 CY 071719M545a-CY.mdb07/17/2019 17:38RW

    QCS 4354675 CY 071719M545a-CY.mdb07/17/2019 17:53RW

    LRB 4355044 CY 071719M545a-CY.mdb07/17/2019 18:07RW

    CCM 4354677 CY 071719M545a-CY.mdb07/17/2019 21:18RW

    FS 4353966 19070027-01 CY 071719M545a-CY.mdb07/17/2019 23:30DW

    CCH 4354678 CY 071719M545a-CY.mdb07/17/2019 23:59RW

    0.00

    Page 1 of 2 EEA Run ID 262038 / EEA Report # 458551

    Page 9 of 14

    =::: e u rofi n s I Eaton Analytical

  • QC Summary Report

    EEAID #

    RPDUnitsTargetAmountClient IDMethodAnalyteSampleType

    DilFactor

    RPDLimit

    RecoveryLimits

    % Recovery

    ResultFlag

    MRL Extracted Analyzed

    False

    IS-L-phenylalanine-d5 545 N/ACCL 21674 ug/L 1.0 4354676--- ------50 - 1509921941 07/02/2019 12:30 07/17/2019 17:38False

    IS-Uracil-d4 545 N/ACCL 8146 ug/L 1.0 4354676--- ------50 - 1501047851 07/02/2019 12:30 07/17/2019 17:38False

    Anatoxin-a 545 0.0300CCL 0.028633 ug/L 1.0 4354676--- ------50 - 150950.03 07/02/2019 12:30 07/17/2019 17:38False

    Cylindrospermopsin 545 0.0900CCL 0.09572 ug/L 1.0 4354676--- ------50 - 1501060.09 07/02/2019 12:30 07/17/2019 17:38True

    IS-L-phenylalanine-d5 545 N/AQCS 20356 ug/L 1.0 4354675--- ------50 - 1509321941 07/02/2019 12:30 07/17/2019 17:53True

    IS-Uracil-d4 545 N/AQCS 8400 ug/L 1.0 4354675--- ------50 - 1501077851 07/02/2019 12:30 07/17/2019 17:53True

    Anatoxin-a 545 0.0300QCS 0.586247 ug/L 1.0 4354675--- ------70 - 1301170.5 07/02/2019 12:30 07/17/2019 17:53True

    Cylindrospermopsin 545 0.0900QCS 1.31115 ug/L 1.0 4354675--- ------70 - 130871.5 07/02/2019 12:30 07/17/2019 17:53False

    IS-L-phenylalanine-d5 545 N/ALRB 19431 ug/L 1.0 4355044--- ------50 - 1508921941 07/17/2019 13:51 07/17/2019 18:07False

    IS-Uracil-d4 545 N/ALRB 8093 ug/L 1.0 4355044--- ------50 - 1501037851 07/17/2019 13:51 07/17/2019 18:07False

    Anatoxin-a 545 0.0300LRB 0.002141 ug/L 1.0 4355044--- ------------ < 07/17/2019 13:51 07/17/2019 18:07False

    Cylindrospermopsin 545 0.0900LRB 0.0 ug/L 1.0 4355044--- ------------ < 07/17/2019 13:51 07/17/2019 18:07True

    IS-L-phenylalanine-d5 545 N/ACCM 22141 ug/L 1.0 4354677--- ------50 - 15010121941 07/02/2019 12:30 07/17/2019 21:18True

    IS-Uracil-d4 545 N/ACCM 7934 ug/L 1.0 4354677--- ------50 - 1501017851 07/02/2019 12:30 07/17/2019 21:18True

    Anatoxin-a 545 0.0300CCM 0.473143 ug/L 1.0 4354677--- ------70 - 130950.5 07/02/2019 12:30 07/17/2019 21:18True

    Cylindrospermopsin 545 0.0900CCM 1.23156 ug/L 1.0 4354677--- ------70 - 130821.5 07/02/2019 12:30 07/17/2019 21:18False

    IS-L-phenylalanine-d5 545 N/AFS 20951 ug/L 1.0 435396619070027-01 ------50 - 1509521941 07/17/2019 13:51 07/17/2019 23:30False

    IS-Uracil-d4 545 N/AFS 8789 ug/L 1.0 435396619070027-01 ------50 - 1501127851 07/17/2019 13:51 07/17/2019 23:30False

    Anatoxin-a 545 0.0300FS 0.0300 ug/L 1.0 435396619070027-01 ------------ < 07/17/2019 13:51 07/17/2019 23:30False

    Cylindrospermopsin 545 0.0900FS 0.0900 ug/L 1.0 435396619070027-01 ------------ < 07/17/2019 13:51 07/17/2019 23:30True

    IS-L-phenylalanine-d5 545 N/ACCH 21574 ug/L 1.0 4354678--- ------50 - 1509821941 07/02/2019 12:30 07/17/2019 23:59True

    IS-Uracil-d4 545 N/ACCH 8389 ug/L 1.0 4354678--- ------50 - 1501077851 07/02/2019 12:30 07/17/2019 23:59True

    Anatoxin-a 545 0.0300CCH 1.961 ug/L 1.0 4354678--- ------70 - 130982.0 07/02/2019 12:30 07/17/2019 23:59True

    Cylindrospermopsin 545 0.0900CCH 5.37284 ug/L 1.0 4354678--- ------70 - 130906.0 07/02/2019 12:30 07/17/2019 23:59

    Page 2 of 2 EEA Run ID 262038 / EEA Report # 458551

    Page 10 of 14

    D

    D

    .___.ODD□□ DDDDDDDD

    DODD□

  • Eurofins Eaton AnalyticalRun Log

    Run ID: 262209 Method: 546

    Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix

    FS 4353967 19070027-01 FH 07/22/2019 08:57DW

    LRB 4358071 FH 07/22/2019 08:57RW

    LRB 4358072 FH 07/22/2019 08:57RW

    LFB 4358073 FH 07/22/2019 08:57RW

    LFB 4358074 FH 07/22/2019 08:57RW

    CCL 4358075 FH 07/22/2019 08:57RW

    QCS 4358076 FH 07/22/2019 08:57RW

    FS 4353967 19070027-01 FH 07/22/2019 08:57DW

    LRB 4358071 FH 07/22/2019 08:57RW

    LRB 4358072 FH 07/22/2019 08:57RW

    0.00

    Page 1 of 2 EEA Run ID 262209 / EEA Report # 458551

    Page 11 of 14

    =::: e u rofi n s I Eaton Analytical

  • QC Summary Report

    EEAID #

    RPDUnitsTargetAmountClient IDMethodAnalyteSampleType

    DilFactor

    RPDLimit

    RecoveryLimits

    % Recovery

    ResultFlag

    MRL Extracted Analyzed

    True

    Total Microcystins & Nodularins 546 0.300FS 0.300 ug/L 1.0 435396719070027-01 ------------ < 07/19/2019 13:30 07/22/2019 08:57True

    Percent CV 546 N/AFS 2 % 1.0 435396719070027-01 ------------ 07/19/2019 13:30 07/22/2019 08:57False

    Total Microcystins & Nodularins 546 0.300LRB 0.0 ug/L 1.0 4358071--- ------------ < 07/19/2019 13:30 07/22/2019 08:57False

    Percent CV 546 N/ALRB 1.6 % 1.0 4358071--- ------------ 07/19/2019 13:30 07/22/2019 08:57True

    Total Microcystins & Nodularins 546 0.300LRB 0.0 ug/L 1.0 4358072--- ------------ < 07/19/2019 13:30 07/22/2019 08:57True

    Percent CV 546 N/ALRB 1.699999 % 1.0 4358072--- ------------ 07/19/2019 13:30 07/22/2019 08:57False

    Total Microcystins & Nodularins 546 0.300LFB 0.538 ug/L 1.0 4358073--- ------60 - 1401080.5 07/19/2019 13:30 07/22/2019 08:57True

    Total Microcystins & Nodularins 546 0.300LFB 0.562 ug/L 1.0 4358074--- ------60 - 1401120.5 07/19/2019 13:30 07/22/2019 08:57False

    Total Microcystins & Nodularins 546 0.300CCL 0.239999 ug/L 1.0 4358075--- ------50 - 150800.3 --- 07/22/2019 08:57True

    Total Microcystins & Nodularins 546 0.300QCS 0.678 ug/L 1.0 4358076--- ------70 - 1301130.6 --- 07/22/2019 08:57

    Page 2 of 2 EEA Run ID 262209 / EEA Report # 458551

    Page 12 of 14

    1~~rnrnrnt ~ D

    D

    =O==ll==O==ll==ll=]D[ =

    ll=====ll=ll==l~l=l~~l=□[ =

    ....______.____ODD□□--□-

  • Sample Type Key

    Type (Abbr.) Sample Type Type (Abbr.) Sample Type

    CCH Continuing Calibration High

    CCL Continuing Calibration Low

    CCM Continuing Calibration Mid

    FS Field Sample

    LFB Laboratory Fortified Blank

    LRB Laboratory Reagent Blank

    QCS Quality Control Sample

    1.00

    Page 13 of 14

  • END OF REPORT

    Page 14 of 14

    2019-07-11 NW- Fawn Ridge Cyanotoxins2019-07-11 NW- Lake Park Cyanotoxins