Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis...

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Optimizing Nitrogen Removal in Advanced OWTS within the Greater Narragansett Bay Watershed NEIWPCC Research Webinar, June 22, 2016 Brittany Lancellotti, Graduate Student, Laboratory of Soil Ecology and Microbiology, University of Rhode Island Anna Meyer, Environmental Analyst, NEIWPCC

Transcript of Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis...

Page 1: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Optimizing Nitrogen Removal in

Advanced OWTS within the

Greater Narragansett Bay Watershed

NEIWPCC Research Webinar, June 22, 2016

Brittany Lancellotti, Graduate Student, Laboratory of Soil Ecology and Microbiology, University of Rhode Island

Anna Meyer, Environmental Analyst, NEIWPCC

Page 2: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

TODAY’S PRESENTER Brittany Lancellotti

Master’s Student, Biological and Environmental Science Laboratory of Soil Ecology and Microbiology, University of Rhode Island

Page 3: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Optimizing Nitrogen Removal in Advanced

OWTS Within the Greater

Narragansett Bay Watershed

Brittany Lancellotti

Laboratory of Soil Ecology

and Microbiology

University of Rhode Island

Page 4: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Special Thanks to…

The Amador Lab:

Jose Amador

George Loomis

Dave Kalen

Kevin Hoyt

Ed Avizinis

Robert Bercaw

Ingrid Felsl

Lauren Zeffer

Jennifer Cooper

Ashley Waggoner

Page 5: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Although the information in this presentation has been funded

wholly or in part by the United States Environmental Protection

agency under agreement CE96184201 to NEIWPCC, it has not

undergone the Agency’s publications review process and therefore,

may not necessarily reflect the views of the Agency and no official

endorsement should be inferred. The viewpoints expressed here do

not necessarily represent those of the Narragansett Bay Estuary

Program, NEIWPCC, or EPA, nor does mention of trade names,

commercial products, or causes constitute endorsement or

recommendation for use. Results discussed in this document are

preliminary and have not been reviewed by NEIWPCC or NBEP.

Page 6: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Overview

1. Project description

2. Evaluation of rapid field tests

3. Evaluation of Performance of Advanced

N removal OWTS in the Narragansett

Bay Watershed

4. Predictors of effluent total nitrogen

5. Conclusions

Page 7: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Nitrogen Loading and Coastal Ecosystems:

Rhode Island

Algal Bloom-

Narragansett Bay

Fish Kill-

Greenwich Bay

Conventional Systems:

0-30 % N Removal

NH4+

NO3-

Page 8: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Addressing Eutrophication

Advanced Nitrogen Removal OWTS

19 mg N/L Total Nitrogen Final

Effluent Standard

Page 9: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Advanced N Removal OWTS

Groundwater

Soil

Septic Tank Advanced Treatment

Train

NH4+

N2

NO3-

N2O

NH4+

NO3

-

Nitrification

50-75% TN Removal

NO3-

Page 10: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Advanced OWTS in Rhode Island: Considerations

Effluent N

concentrations not

monitored after

installation

Installation and

maintenance

may affect

system

performance

Uncertainty

surrounding

performance

N inputs to

coastal

systems could

be higher than

expected

Page 11: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Our Approach:

Monitor system

performance and

operational

parameters

Develop statistical

model for

performance

optimization

Adjust systems

accordingly

Measure changes in

response to

adjustments

Page 12: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Sampling Design

We sample a total of 42 systems each

month:

Orenco

Advantex

AX20®

BioMicrobics

FAST®

SeptiTech

17 Systems 11 Systems 14 Systems

http://www.orenco.com/sales/choos

e_asystem/index.cfm

http://www.biomicrobics.com/produc

ts/fast-wastewater-treatment-

systems/microfast/

http://www.septitech.com/staar-residential/

Page 13: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Site Locations: Greater Narragansett Bay

Watershed

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Methodology: Operational Parameters

Field Analysis Lab Analysis

Avg. Daily Forward Flow

Recirculation Ratio

Water Temperature

BOD5

Total Nitrogen

Alkalinity

DO

NH4+

NO3-

pH

Page 15: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Overview

1. Project description

2. Evaluation of rapid field tests

3. Evaluation of Performance of Advanced

N removal OWTS in the Narragansett

Bay Watershed

4. Predictors of effluent total nitrogen

5. Conclusions

Page 16: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Evaluation of Rapid Field Tests

Used by O&M service providers to evaluate system

performance

Provide quick results on-site

Do they provide accurate results?

Page 17: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Evaluation of Rapid Field Tests: Methods

Rapid Field

Tests

Standard

Laboratory

Methods

?

Page 18: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Standard Values

0 10 20 30 40 50 60 70

Rapid

Test V

alu

es

0

10

20

30

40

50

60

70NH4

+

Laboratory Values

Ra

pid

Fie

ld T

est

Va

lue

s

How is Accuracy Defined?

0 1 2 3 4 5 6 7 8 9 10

0

1

2

3

4

5

6

7

8

9

10

Laboratory Values

Ra

pid

Fie

ld T

est

Va

lue

s

Slope= 1

Intercept= 0 Slope= 1?

Intercept= 0?

Page 19: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Rapid Field Test Methods

Alkalinity

Ammoniu

m

Dissolved

Oxygen

Nitrate

pH

pH ✔

Page 20: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Rapid Field Test Methods : Used in the

Laboratory

Alkalinity

Ammoniu

m

Nitrate

pH ✔ ✔

✔ ✔ Field

Conditions Accuracy

Page 21: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Field Conditions and Error

Varying light

conditions in the field

complicate visual

comparisons to color

charts.

Page 22: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Accurate Rapid Field Test Methods

Nitrate pH ✔ ✔ Ammonium ✔ Ammonium

Nitrate

COD

Page 23: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Overview

1. Project description

2. Evaluation of rapid field tests

3. Evaluation of Performance of Advanced

N removal OWTS in the Narragansett

Bay Watershed

4. Predictors of effluent total nitrogen

5. Conclusions

Page 24: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Evaluation of N Removal in Advanced

OWTS

Final effluent total nitrogen concentrations

Collected from March 2015 to May 2016

Standard laboratory values reported

Orenco

Advantex

AX20®

BioMicrobics

FAST®

SeptiTech

17 Systems 4 Systems 14 Systems

Page 25: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

90th Percentile

Advantex FAST SeptiTech

System Type

0.5 1.0 1.5 2.0 2.5 3.0 3.5

TN

mg

N/L

0

20

40

60

80

100

120

Advantex FAST SeptiTech10th Percentile

Median

Out of range

values

75th Percentile

25th Percentile

Distribution of TN Concentrations:

March 2015 - May 2016

90th Percentile

Page 26: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Advantex Systems: Distribution of TN Concentrations:

March 2015 - May 2016

71% of

systems

meet the

19 mg N/L

TN

standard.

Individual AX Systems

0 1 2 3 4 5 6 7 8 9 101112131415161718

TN

(m

g N

/L)

0

20

40

60

80

100

Page 27: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

FAST Systems: Distribution of TN Concentrations:

March 2015 - May 2016

57% of

systems

meet the

19 mg N/L

TN

standard.

Individual FAST Systems

0 2 4 6 8 10 12 14

TN

(m

g N

/L)

0

20

40

60

80

100

120

Page 28: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

SeptiTech Systems: Distribution of TN Concentrations:

March 2015 - May 2016

50% of

systems

meet the

19 mg N/L

TN

standard.

Individual SeptiTech Systems

0 1 2 3 4

TN

(m

g N

/L)

0

10

20

30

40

50

60

Page 29: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Individual SeptiTech Systems

1 2 3 4 5 6 7

TN

(m

g N

/L)

0

20

40

60

80

100

120

14 % of systems

meet the

19 mg N/L TN

standard.

March 2015 - December 2015 January 2016 - May 2016

Individual SeptiTech Systems: Not turned on for Denitrification

1 2 3 4 5 6 7

TN

(m

g N

/L)

0

20

40

60

80

100

120

Individual SeptiTech Systems

14 % of systems

meet the

19 mg N/L TN

standard.

Page 30: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Median TN Concentration:

Narragansett vs. Barnstable County Systems

System Type

AX FAST SeptiTech

TN

(m

g N

/L)

0

5

10

15

20

25

30

Our Study

Barnstable County

Includes

systems not

turned on for

denitrification

mode

Page 31: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Percentage of Systems in Compliance:

Narragansett vs. Cape Cod

System Type

AX FAST SeptiTech

% S

yste

ms in

Com

plia

nce

0

20

40

60

80

100

Our Study

Barnstable County

Includes

systems not

turned on for

denitrification

mode

Page 32: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

+ Differences in Regulations

4 maintenance visits required per year

Effluent sampling required

19 mg N/L TN standard

Online management database Tracks maintenance visits

Tracks effluent constituent levels

Alerts when effluent does not meet standards

2 maintenance visits

required per year

Focus on mechanical

function

Do not include effluent

sampling

19 mg N/L TN standard

Barnstable County,

Massachusetts Rhode Island

Page 33: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Overview

1. Project overview

2. Evaluation of rapid field tests

3. Performance of Advanced N removal

OWTS in the Narragansett Bay

Watershed

4. Predictors of effluent total nitrogen

5. Conclusions

Monitor system

performance and

operational

parameters

Develop statistical

model for

performance

optimization

Adjust systems

accordingly

Measure changes in

response to

adjustments

Page 34: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Which Parameters Best Predict Effluent Total

Nitrogen Concentration?

Ammonium

Nitrate

Alkalinity

pH

DO

Sample Temperature

Average Forward Flow

Recirculation Ratio

BOD

Total Nitrogen

How well do these

parameters

correlate with TN?

Which parameters

can serve as

indicators for

effluent TN?

Page 35: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Significant Predictors of

Total Nitrogen

Orenco

Advantex

AX20®

BioMicrobics

FAST®

SeptiTech

System Type

Ammonium

Ammonium Nitrate BOD

pH

Nitrate

Nitrate Average

Forward Flow

Page 36: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Best Predictors of Total Nitrogen

Total Nitrogen Ammonium Nitrate BOD

pH

Nitrification &

Denitrification

Optimal

pH= 6-8

Total Nitrogen

Page 37: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

In conclusion…

• Accurate rapid field tests are available.

• Differences in regulatory requirements for

monitoring influences management and may

affect performance.

• Ammonium, nitrate, BOD, pH, and average

forward flow are significant predictors of TN.

Page 38: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

Where are we now?

• Continuing to collect and analyze final effluent wastewater

samples

• Additional sampling in August

• Evaluating underperforming systems and working with

service providers to make adjustments to improve N

removal

Page 39: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

We are hopeful!

Monitored Massachusetts systems are performing better, but with the same level of management, RI systems can perform to standard.

One town in RI is considering requiring effluent sampling during O&M visits.

Page 40: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

CONTACT

Brittany Lancellotti

Master’s Student

Laboratory of Soil Ecology and Microbiology, University of Rhode Island

[email protected]

Anna Meyer

Environmental Analyst

NEIWPCC

[email protected]

Page 41: Nitrogen Removal in advanced OWTS within the Narragansett Bay … · 2018. 2. 15. · George Loomis Dave Kalen Kevin Hoyt Ed Avizinis Robert Bercaw Ingrid Felsl Lauren Zeffer Jennifer

QUESTIONS