Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process...

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Nitrogen Fertilizer Manufacturing Out of Thin Air ….. Almost Out of Thin Air ….. Almost Presented by: Jim Schellhorn, Director of EHS Jim Schellhorn, Director of EHS Terra Industries Inc. NAEHSS August 2009

Transcript of Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process...

Page 1: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

Nitrogen Fertilizer ManufacturingOut of Thin Air ….. AlmostOut of Thin Air ….. Almost

Presented by:

Jim Schellhorn, Director of EHSJim Schellhorn, Director of EHSTerra Industries Inc.

NAEHSS

August 2009

Page 2: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

Terra Industries IncTerra Industries Inc.Verdigris, OK

2August 2009

Page 3: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

Terra Industries IncTerra Industries Inc.Verdigris, OKTerra Industries Inc.

Yazoo City, MS

3August 2009

Page 4: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

The Ammonia Process

Ammonia is the building block for all nitrogen fertilizer

One Nitrogen atom is bonded to three Hydrogen atomsatoms

The feedstocks necessary to make ammonia are very simple – natural gas and air

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y p g

Page 5: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

Natural gas CH4

NHN

NH3ammonia

AirN2O CO2O2

CO2carbon dioxide

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Page 6: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

The Ammonia Process

The ammonia process is not so simple – it involves high pressure, high temperature, seven different g p , g p ,catalytic reactions ….. (Control Room)

And a great deal of complicated equipment and instrumentation

(Ammonia Plant)

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Page 7: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

The Ammonium Nitrate Process

First you need to make nitric acid

(Absorber)

(Converter)(Converter)

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NH3 N2ONH3 N2ON2

NON2

N2NO HNO3

nitric acid

O2H2O

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water

Page 9: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

The Ammonium Nitrate Process

Then you react nitric acid with ammonia in a neutralizer

(AN Neutralizer)

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(AN Neutralizer)

Page 10: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

NHNH3ammonia

NH NONH4NO3

HNO3

Ammonium nitrate

3nitric acid

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Page 11: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

The Urea Manufacturing Process

Urea is made by reacting ammonia and carbon dioxide from the ammonia process under high p gtemperature and pressure

(Urea Synthesis Section)

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(Urea Synthesis Section)

Page 12: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

NHNH CONH

NH3NH2CONH2

UUreaCO22

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Page 13: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

The UAN Manufacturing Process

Both urea and ammonium nitrate are first manufactured as solutions (78% - 87% strength) ( g )

Mixed to make UAN

28% - 32% N(UAN Plant)

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Page 14: Nitrogen Fertilizer Manufacturing Out of Thin Air ... · The Solid Fertilizer Manufacturing Process Both urea and ammonium nitrate can also be concentrated and dried under controlled

The Solid Fertilizer Manufacturing Process

Both urea and ammonium nitrate can also be concentrated and dried under controlled conditions to make granular urea or prilled ammonium nitrate

(AN Prill Plant)

(Urea Granulation Plant)

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( )

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Contact Information

Jim SchellhornJim SchellhornDirector of Environmental, Health & SafetyTerra Industries Inc.6606 East 540 RoadClaremore, OK 74019(918) [email protected]

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QUESTIONS?QUESTIONS?

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