Laser Frequency Jitter Tolerance and Linewidth Requirement ...
New states and peaks we found 29/06/2011 JLong. StateV’ I(Br + )/I(HBr + ) Linewidth (cm -1 )...
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New states and peaks we found 29/06/2011 JLong
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Transcript of New states and peaks we found 29/06/2011 JLong. StateV’ I(Br + )/I(HBr + ) Linewidth (cm -1 )...
New states and peaks we found
29/06/2011 JLong
State V’ I(Br+)/I(HBr+)Linewidth
(cm-1)Lifetime (ps)
f33 0 3 1.45% 0.57116 9.27936
f32 0 2 0.93% 0.53024 9.99547
V1 m-1? 0 137.89% 0.62 8.548387g3-(0+) 0 0 11.76% 0.6684 7.929384
D1 0 1 1.379% 1.028 5.155642V1 m+1 0 - - -
f32 1 2 2.529% 0.67611 7.838961
f31 0 1 0 0.68177 7.773883
V1 m+2 0 - - -F1 0 2 0.177% 0.44789 11.83326V1 m+3 0 159.779% 1.0208 5.192006V1 m+4 0 1036.579% 4.4003 1.204463E1 0 0 20.390% 0.81644 6.491598
i33 0 3 0 0.45073 11.7587
V1 m+5 0 670.276% 4.0551 1.306996
i32 0 2 23.371% 0.48073 11.0249
V1 m+6 0 710.875% 1.4956 3.543728
f31 1 1 - - -
F1 1 2 15.765% 1.3442 3.942866V1 m+7 0 377.028% 4.4102 1.20176H1 0 0 85.463% 1.3976 3.792215V1 m+8 0 614.082% 1.4837 3.572151E1 1 0 J’=05:266.268%163.661% 2.45.1483 2.314411.058539
g3-(0+) 2? 0 5.327% 0.48877 10.84355V1 m+9 0 1601.728% 3.42 1.549708
i32 1 2 6.469% 0.42539 12.45916
i31 0 1 - - -
V1 m+10 0 470.812% 0.85622 6.189998I1 0 2 0.420% 0.52114 10.17001
V1 m+11 0 - - -
New peaks of O branch
New peaks of O branch
New Rydberg states
i33(1-0) or g3-(0+) ??
New state
New Peaks
F1New peaks
New Ion pair state
Helgi
250x103
200
150
100
50
0
Rel
ativ
e In
ten
sity
/a.
u.
75.35x10375.3075.2575.2075.15
Wavenumber /cm-1
0123456
Q
V1m-1) ?
H79
Br+
79Br
+
H+
75.35x103
75.30
75.25
75.20
75.15
Wav
enu
mb
er
/cm
-1
6543210
J'
Bv =2.6876 ± 0.271 Dv =-0.0096669 ± 0.00641 Te =76667 ± 2.01
V1m-1)
150
100
50
0
-50
x10
3
77.977.877.777.677.577.4x10
3
i3 Q
P
R
S
O
S
E1
QF
1 S23456V
1
(m+3) Q
O
S
V1
(m+5) Q
V1
(m+6) Q
S
O
i3 Q
V1
(m+4) Q
P
F1 ???
S(2)?S(3)?S(4)?
Q(0)
Q(1)
Q(2)Q(3)Q(4)
Q(2)Q(3)
Q(4)Q(5)Q(6)
Q(7)
Q(8)Q(9)Q(10)
P(2)P(3)
P(4)P(5)P(6)P(7)
0123456789
77.8x103
77.7
77.6
77.5
En
erg
y /c
m-1
86420
J'
B =4.1311 ± 0.0768 D =-0.00027806 ± 0.000875 T =79143 ± 1.2
V1
(m+4)
100
50
0
-50
x10
3
78.9578.9078.8578.8078.7578.70x10
3
i3 Q
P
R
SOSE1
QF
1 S23456V
1
(m+3) QO
S
V1
(m+5) Q
V1
(m+6) Q
S
O
i3 Q
V1
(m+4) Q
PF
1 ???
S(2)?S(3)?S(4)?
Q(0)
Q(1)
Q(2)Q(3)Q(4)
Q(2)Q(3)
Q(4)Q(5)Q(6)
Q(7)
Q(8)Q(9)Q(10)
P(2)P(3)
P(4)P(5)P(6)P(7)
012345678901234567
78.90x103
78.85
78.80
78.75
78.70
En
erg
y /c
m-1
76543210
J'
B =3.6078 ± 0.0853 D =-0.0032002 ± 0.00153 T =80256 ± 0.837
V1
(m+6)
200
150
100
50
0
-50
x10
3
79.0579.0078.9578.90x10
3
i3 Q
P
R
S
O
S
E1
QF
1 S23456
V1
(m+3) Q
O
S
V1
(m+5) Q
V1
(m+6) Q
S
O
i3 Q
V1
(m+4) Q
P
F1 ???
S(2)?S(3)?S(4)?
Q(0)
Q(1)
Q(2)Q(3)Q(4)
Q(2)Q(3)
Q(4)Q(5)Q(6)
Q(7)Q(8)Q(9)Q(10)
P(2)P(3)
P(4)P(5)P(6)P(7)
0123456789 01234567
New peaks
2.5
2.0
1.5
1.0
0.5
0.0
x10
6
77.0076.9576.9076.8576.8076.75x10
3
O
P
D1 Q
R
S
OPR
S
f3 Q
OP
f3 Q
R
S S
R
F1 Q
P
???
2
234523456
2345678
P(2)
P(3)
P(4)
P(5)
P(6)?/S(9)?
2 3 4 6 824
6
2 4 6 8
87
7
S(2) S(3) S(4) S(5)S(6) S(7)
S(8) S(9)?
S(10)O?
O? O?/P(6)?
???
R(2)R(3) R(4)
R(5)
R(6)
R8)S(5)
S(6) S(7) S(8)? S(9)?
P(2)P(3)
P(5)P(6)P(4)O(2)P(7)O(3)O(4)O(5)O(6)P(8)
Q(2)atomic line???
R(2)
R(3)/S(2)
R(4)
R(5)/S(3)/O(2)?
R(6)
R(7)?/S(4)/O(3)?
S(5)S(6)
R(8)
S(7)
P(5)
Q(2)P(2)P(3)P(4)S(8)
S(9)?S(10)?O(2)O(3)O(4)?P(6)?
P(7)?P(8)?P(9)?
R(2)R(3)/S(2)?R(4)R(5)/S(3)?
R(6)Q(2)Q(1)Q(3)Q(4)
Q(5)Q(6)Q(7)Q(8)
Q(9)
P(3)?/Q(10)
Q(11)?P(4)P(2)
R(7)S(4)
R(8)?R(9)?
R(7)
??????
???
R(2)
R(3)
R(5)
R(4)
R(6)S(3)S(4)S(5)S(6)
S(2)
S(7)P(6)?P(7)?P(8)?P(9)?
O(2): 76890.66925
O(3): 76856.62366
O(4 ): 76822.01947
O(5): 76786.86496
400
300
200
100
0
x103
80.1080.0580.0079.95
x103
Bv'=7.2379Dv'=-0.016Te=81353-0.5*
V1
(m+8)
H79
Br+
79Br
+???
80.386x103
80.384
80.382
80.380
80.378
80.376
80.374
80.372
Wa
ve
nu
mb
er
2h
v/c
m-1
76543210
J'
120
100
80
60
40
20
E
cm-1
Te=80386 ± 0.174 cm-1
Bv=8.0511 ± 0.0178 cm-1
Dv=0.00026382 ± 0.00032 cm-1
100
50
0
-50
x10
3
80.6580.6080.5580.5080.45x10
3
P
P
S
SS
S
OE1
Q
R
R
i3 Q
i3 QI1 Q
V1
(m+9) Q
g3
Q? i
3 ?
V1
(m+10) Q
Q(0)Q(1)Q(2)Q(3)Q(4)Q(5)Q(6)Q(7)?
Q(1)?Q(2)?
Q(3)?Q(4)?
Q(5)?
Q(6)?
P(1)?P(3)?P(5)?
P(6)?
P(7)?P(8)? O(0)?O(4)?O(5)?P(9)? O?O?O?
Q(0)Q(1)Q(2)Q(3)Q(4)Q(5)Q(6)Q(7)
Q(0)?
P(2)?
H79
Br+
79Br
+
81Br
+
H81
Br+
H+
40x103
30
20
10
Re
lati
ve
In
ten
sit
y
80.75x10380.7080.6580.6080.5580.5080.4580.40
Wavenumber 2hv/cm-1
Q
0123456
V'1
m+9)
H79
Br
79Br
80.60x103
80.55
80.50
80.45
En
erg
y /c
m-1
6543210
J'
B =4.3881 ± 0.367 D =0.017696 ± 0.0087 T =81951 ± 2.72
V1
m+9)
60
50
40
30
x10
3
80.7080.6580.6080.5580.5080.45x10
3
P
PS
S
S
SOE1
Q RRi
3 Qi
3 QI1 QV
1
(m+9) Qg
3
Q? i
3 ? V
1
(m+10) Q
Q(0)
Q(1)
Q(2)
Q(3)
Q(4)Q(5)
Q(6)
Q(7)?
Q(1)?
Q(2)?
Q(3)?Q(4)?
Q(5)?Q(6)?
P(1)?P(3)?
P(5)?
P(6)?
P(7)?P(8)?
O(0)?O(4)?O(5)?P(9)?O?O?O?
Q(0)
Q(1)
Q(2)Q(3)
Q(4)Q(5)Q(6)Q(7)
Q(0)?
P(2)?
H79
Br+
79Br
+
81Br
+H
81Br
+H
+
200
150
100
50
0
x10
3
81.381.281.181.0x10
3
P
P
S
SS
S
O
E1
Q
R
R
i3 Q
i3 Q
I1 Q
V1
(m+9) Q
g3
Q? i
3 ?
V1
(m+10) Q
Q(0)Q(1)Q(2)Q(3)Q(4)Q(5)Q(6)Q(7)?
Q(1)?Q(2)?Q(3)?Q(4)?Q(5)?
Q(6)?
P(1)?P(3)?P(5)?
P(6)?
P(7)?P(8)?O(0)?O(4)?O(5)?P(9)? O?O?O?
Q(0)Q(1)Q(2)Q(3)
Q(4)Q(5)Q(6)Q(7)
Q(0)?
P(2)?
H79
Br+
79Br
+
81Br
+
H81
Br+
H+
