Network Business Unit Micro Batteries - ABCDEOur microbatteries have a stable operating voltage over...

CMOS ICQuartz Crystals

Micro BatteriesMaterials

Liquid Crystal DisplayCustom LCD Module

Micro Batteries

Micro BatteriesProduct Catalogue

NetworkComponentsBusiness Unit

October 2002

Precautions for Your Safety

2

SII Lithium-ion rechargeable batteries (MS, RB, HB, TS) contain flammable organic solvents. For yoursafety, please follow following prohibitions.

• Pay attention to mat or sheet for ESDBattery with tabs or battery on PCB may short circuit on the matfor ESD. As a result the voltage of cell drops down.

• Pay attention to soldering by tipsDo no touch the battery by solder chips, in case of solderinganother components after equipping battery.Basically, keep any high temperature process away from bat-tery.

• Pay attention to material of jig for pick and placeUse nonconductive material of jig for pick and place of batter-ies, for short-circuit protect. If short circuit of battery is occurred,the voltage of battery drops down quickly but raises gradually.

• Pay attention to washing and dryingSome detergent or high temperature drying cause deterio-rate of battery. If you need to wash batteries, consult us.

International Transportation and DisposalInternational Transportation

(Air Transport)Based on DGR (Dangerous Goods Regulations) of ICAO (Inter-national Civil Aviation Organization), IATA (International AirTransport Association) has determined transport regulations. Theregulation states that lithium batteries are considered not dan-gerous if they meet the following requirements;Each bare cell with a solid cathode must contain 1.0g or less oflithium or lithium alloy.They may be transported in rigid packaging with short-circuitprotection.The SII lithium-ion rechargeable batteries contain under 1.0gof lithium or lithium alloy per cell.(Marine Transport)IMO (International Marine Organization) has determined trans-port regulations based on IMDG (International Marine Danger-ous Goods). The judgement standard of dangerous goods isbased on DGR of ICAO. When the batteries are not regardedas dangerous goods, they should be transported in rigid pack-aging with short-circuit protection, according to IATA standards.

DOT (department of Transportation)Regulations for packaging and transportation of lithium batter-ies in the U.S.A. are determined by Code 49 CFR173 185 ofFederal Resister.The judgement standard of dangerous goods corresponds toDGR of ICAO. When the batteries are not regarded as danger-ous, any transportation method is acceptable if they are trans-ported in rigid packaging with short-circuit protection.We will stick “Caution label”on outside of the shipping packageto the U.S.A., please let us know if you need it.

DisposalRecent environmental protection concerns have increased glo-bally and waste and recycling are regulated in the world. Thecurrent regulations differ in each country, state and local mu-nicipality. Please consult local regulations and authorities forrecommended disposal of batteries. If you are in question ofapplication or safety of our batteries, please consult your localauthorities.

Do not jumble batteries

Example Example of insulation

Insulating tape

Short-circuiting

discharge discharge

Contacting between batteries cause short-circuiting such as above diagram.

• Do not charge by high current or high voltage.Doing so may generate gas inside the battery, resulting swell-ing, catching fire, heat generation or bursting.

• Do not heat, disassemble nor dispose of in fireDoing so damages the insulation materials and may causecatching fire, heat generation, leakage or bursting.

• Do not solder directly to the batteryIf soldering is performed directly to the battery, the batteryis heated up, consequently causes leakage, explosion orfire due to overheating from internal short-circuiting.

• Do not short.If the (+) and (-) come into contact with metal materials, short-circuiting occurs. As a result, catching fire, heat generation,leakage or bursting may occur.

• Keep batteries out of children’s reach.If leaked liquid is ingested or a battery is swallowed, consulta physician immediately.

• Do not reverse placement of (+) and (-)If the (+)and(-) side of the battery is reverse inserted, it may causea short-circuiting or over discharge of the battery on someequipment and it may induce overheating, explosion or fire.

• Do not discharge by forceIf the battery is discharged by direct connection to an externalpower supply etc., voltage of the battery will decline lower than0 volts (electrical reversal) and will cause the battery case toexpand, overheat, leak, explode or burn.

• In case of leakage or a strange-smell, keep away fromfire to prevent ignition of any leaked electrolyte.

• In case of disposal, insulate between (+) and (-) ofbattery by an insulatingJumbling batteries or with other metal materials cause short-circuiting. As a result, catching fire, heat generation, leak-age or bursting may occur.

• If leaked liquid gets in the eyes, wash them withclean water and consult a physician immediately.

• Do not use new and used batteries together. Donot use different types of batteries together.It may cause catching fire, heat generation, leakage or bursting.

• If you connect two or more batteries in series orparallel, please consult us in advance.

It may cause bursting or catching fire due unbalanced load orvoltage.

• Do not use nor leave the batteries in direct sun-light nor in high-temperature areas.It may cause catching fire, heat generation, leakage or bursting.

• Do not apply strong pressure to the batteries norhandle roughly.It may cause catching fire, heat generation, leakage or burst-ing.

• Avoid contact with water.It may cause heat generation.

• Keep batteries away from direct sunlight, high tem-perature and humidity.It may cause heat generation or performance deteriora-tion.

Warning!

For prevention the performance deterioration of battery

Caution!


3

SII capacitors (XC, XH) contain flammable organic solvents.For your safety, please follow followingprohibitions.

• Do not charge by high current or high voltage.Doing so may generate gas inside the capacitor, resultingswelling, catching fire, heat generation or bursting.

• Do not reverse placement of (+) and (-)SII capacitors have polarity. If the (+) and (-) side of thecapacitor is reverse inserted, it may cause a short-circuit-ing or over discharge of the capacitor on some equipmentand it may induce overheating, explosion or fire.

• Do not solder directly to the capacitorIf soldering is performed directly to the capacitor, the ca-pacitor is heated up, consequently cause leakage, explo-sion or fire due to overheating from internal short-circuiting.

• Keep capacitors out of children’s reach.If leaked liquid is ingested or a capacitor is swallowed,consult a physician immediately.


• Do not discharge by forceIf the capacitor is discharged by direct connection to an exter-nal power supply etc., voltage of the capacitor will decline lowerthan 0 volts (electrical reversal) and will cause the capacitorcase to expand, overheat, leak, explode or burn.

• Incase of leakage or a strange-smell, keep awayfrom fire to prevent ignition of any leaked electro-lyte.

Warning!


• Do not short.If the (+) and (-) come into contact with metal materials,short-circuiting occurs. As a result, catching fire, heat gen-eration, leakage or bursting may occur.

• Keep batteries out of children’s reach.If leaked liquid is ingested or a battery is swallowed, con-sult a physician immediately.

• If leaked liquid, alkaline, get in the eyes, do not rubthem, wash them with clean water and consult aphysician immediately.

• If leaked liquid, alkaline, stick upon wears, for pro-tecting irritation, wash them with clean water im-mediately.

Warning!

• Do not reverse placement of (+) and (-) • Do not solder directly to the battery • Do not use new and used batteries together. Do

not use different types of batteries together. • Do not charge. • Do not use nor leave the batteries in direct sun-

light nor in high-temperature areas. • Keep batteries away from direct sunlight, high tem-

perature and humidity. • Avoid letting battery contact with water. • Make sure to insert batteries without having (+) and

(-) come in contact with metal parts of equipment.

• Read the equipment instruction manual and pre-cautions carefully before use. Some usage or typesof equipment do not suit the specifications or per-formance of these batteries.

• Remove batteries from the equipment, if finish us-ing. Do not leave batteries connecting with equip-ment after using.

• In case of disposal, insulate between (+) and (-) ofbattery by an insulating

Caution!

• If leaked liquid gets in the eyes, wash them withclean water and consult a physician immediately.

• Do not use nor leave the capacitors in directsunlight nor in high-temperature areas.It may cause catching fire, heat generation, leakage orbursting.

• Do not use new and used capacitors together. Donot use different types of capacitors together.It may cause catching fire, heat generation, leakage or bursting.

• If you connect two or more capacitors in series orparallel, please consult us in advance.

It may cause bursting or catching fire due unbalanced load orvoltage.

• Keep capacitors away from direct sunlight, hightemperature and humidity.It may cause heat generation or performance deteriora-tion.

Caution!


For using SII Silver Oxide batteries, please follow following prohibitions.

4

GENERAL DESCRIPTIONSeiko Instruments Inc. has commercialized a highly reli-able silver oxide battery in response to quartz watches.Since then the company has expanded its microbatterybusiness. With rapid progress in LSI technologies, highlyadvanced microbatteries are now being strongly de-manded for sophisticated electronic instruments andequipment. The company continues its best efforts todevelop high performance microbatteries which meet anyusers’ needs and requirements.This brochure introduces silver oxide batteries, manga-nese silicon lithium-ion rechargeable batteries, titaniumsilicon lithium-ion rechargeable batteries, reflowable ca-pacitors, and reflowable lithium-ion rechargeable batter-ies.We would like to continuously develop higher perfor-mance micro battery and widen product lineup. Pleasefeel free to contact us.

Safety Precautions for handling Battery and Capacitor ...... 2Lineup of Micro Batteries and Capacitors ................... 5MS Lithium-Ion Rechargeable Battery ................................ 6Battery Holder ................................................................... 11Reflowable RB lithium-Ion Rechargeable Battery ......... 12Pb-free reflowable HB lithium-Ion Rechargeable Battery ... 14TS Lithium-Ion Rechargeable Battery .............................. 16Reflowable XC Capacitor (2.5V Rated Voltage Type) ......... 18Reflowable XH Capacitor (3.3V High-Rated Voltage Type) ............ 20Pb-free reflowable XHxxH Capacitor (3.3V Rated Voltage type) .... 22Silver Oxide Battery .................................................. 24SII GROUP ENVIRONMENTAL POLICY .................. 26Check Sheet for Selecting Micro Battery ..................... 27

CONTENTS

FEATURES1. Superior leakage resistanceElectrolytic leakage may lower the contact withterminals of the electronic instruments which usemicrobatteries. This interrupts the stable operations. Spe-cial sealing materials and processing technologies areemployed in the manufacture of our batteries.

2. Large capacityIn order to extend the operating time of the machineryand equipment with-in the limited battery space, batter-ies need large capacity.Our microbatteries have large capacity. It is obtained byour original design technologies and by use of high pu-rity materials.

3. Stable operating voltageThe battery Voltage depends on the temperature and thedepth of discharge. Since the change of the voltage af-fects characteristics of machinery and equipment, theoperating voltage must be stable.Our microbatteries have a stable operating voltage overa wide temperature range and in a depth of discharge.

4. High reliabilityBatteries are required to have high performance in anyevent, that is, high reliability.Our microbatteries are manufactured under our highquality control.Only batteries with high quality are delivered to custom-ers.

5

Lineup of Micro Batteries and Capacitors

Features of Micro Battery and CapacitorMS Series : 3V Type. Obtains small size, large capacity and highly long cycle life. Also superior in Over-discharge

characteristics.RB Series : Reflowable rechargeable battery with wide charging voltage range (1.8V to 3.3V).HB Series : Pb-free reflowable rechargeable battery with wide charging voltage range (1.8V to 3.3V). <New Product>TS Series : 1.5V Type. Wide charging voltage range from 1.5V to 3.0V with high reliability.XC Series : Smallest and thinnest size in reflowable capacitor with a rated voltage of 2.5V.XH Series : Reflowable capacitor obtaining both high rated voltage of 3.3V and high energy density.XH xx H Series : Pb-free reflowable capacitor obtaining both high rated voltage of 3.3V and high energy density. <New Product>SR Series : Wide variation of products which obtain high reliability gained through our watch Production.

MS412F

2.1mm (2.0mm)

3.3V

3.0V

2.5V

2.3V

2.0V

1.5V

0.7V

0V

1.4mm

1.2mm

0.9mm

MS414MS414FRB414HB414

MS421S

MS614MS614FMS614SXC614

XC609

MS621MS621FTS 621XC621

MS920MS920STS 920

MS1220

MS

Series

TS

Series

XC

Series

XH

Series

HB

/RB

Series

XC414XH414XH414H

Hei

ght

SizeDiameter

Φ4.8mm Φ6.8mm Φ9.5mm Φ12.5mm

Standard Voltage Range

Fitting List by ApplicationsUsage

Backup use

GSM

PDC/CDMA

Telephone

Digital Camera

VCR Camera

Camera

TV/VTR

GPS

PDA

Personal Computer

FAX

PC Card

Long time backup

Short time backup

WatchPower Supply

Battery Type MainRecharge

-ableRecharge

-ableRecharge

-ableCapaci-

torCapaci-

tor

Application SR TS MS RB/HB XC XH Necessary Features

Long cycle life and Over-discharge

Long cycle life and Over-discharge

Long cycle life and largecapacity



Long cycle life

Long cycle life

Long cycle life

Long cycle life

Long cycle life

Large capacity

Large capacity

Large capacity and smallself-discharge, Over-discharge,stable.

Large capacity

Small and Large capacity

6

MS Lithium-Ion Rechargeable Battery <3V Type>

FEATURES• Large discharge capacity:

Large discharge capacity for high operational voltagerange of 2.0V to 3.3V.

• Long cycle-life:

Over 200 times cycle-life under the charge/dischargecondition at 2.0V to 3.3V (D.O.D 100%).

• Excellent over-discharge characteristics:

Continued stable capacity characteristics after the bat-tery is over-discharged down to 0.0V.

• Approved product by UL

Manganese Silicon Lithium-ion Battery (MS series) isapproved by UL(Underwriters Laboratories Inc.)

UL File MH 15628MS412F/MS414/MS614/MS614F/MS614S/MS621/MS621F/MS920/MS920S/ (MS421S)

APPLICATIONS• Back up power supply for memory or clock in various

electronic equipment e.g. cellular-phones, cordlessphones, PHS, pagers, memory-cards, FAX machines,personal computers, PDA, Video cameras, digital cam-eras, tuners, handy terminals etc.

• Combined use with solar cells.

• Main power source for small and slim portable equip-ment.

SPECIFICATIONS

Sll own developed MS(Manganese Silicon) Lithium-ion re-chargeable battery addresses the demand most effectively.The battery uses silicon oxide as anode and lithium manga-nese composite oxide as cathode. As a result, it offers twentytimes the capacity of conventionally available batteries, in ad-dition to longer cycle-life and highly stable over-dischargecharacteristics.

Gasket

<Cross Section>

Negativecap

Negativeelectrode

Separater

Positiveelectrode

positivecan

(24˚C, 3.3V to 2.0V / 3.1V to 2.0V(F, S type))

MS412FMS414MS414FMS421SMS614MS614FMS614SMS621MS621FMS920MS920SMS1220S

0.070.070.070.110.170.160.170.230.230.460.47

Type

333333333333

1.00.251.22.52.33.03.44.05.58.011.0

0.0100.0100.0050.0100.0250.0250.0250.0250.0250.0500.050

0.150.150.150.150.500.500.500.500.501.000.80

200200200100200200200200200200100

10001000100010001000100010001000100010001000

4.84.84.84.86.86.86.86.86.89.59.512.5

1.21.41.42.11.41.41.42.12.12.12.12.0

100100100160

50808050803535

NominalVoltage

(v)

NominalCapacity

(mAh)

StandardCharge/

DischargeCurrent(mAh)

InternalResistance

(Ω)*1

StandardChargeVoltage

(V)

MaximumDischarge/

Current(continuous)

(mA)*2

100%D.O.D

(Depth ofDischarge)

20%D.O.D

(Depth ofDischarge)

3.13.33.13.13.33.13.13.33.13.33.1

Size(mm)

Diameters Height

Weight(g)

Cycle Life (Times)*3

New

New

Developing

e-

Charge

Discharge

Cathode(Positive Electrode)

Anode(Negative Electrode)

Li+

Li+

Li+

Li+

Li+ Li+ Li+

Li+

Li+

Li+

Li+Li+

Li+ Li+ Li+

Li+

Li+

Li+

Li+

Li+

Li+

Li+

Li+

Li+

Li+

Li+

Li+

Power Source e-

Principle System of MS Lithium-Ion Rechargeable Battery

Li+

1. High Capacity

3. Overdischarge Characteristics

2. Long Cycle LifeMore than 200 times cycle life under D.O.D (Depth of Discharge) 100%

1 able to absorb a large quantity of Lithium ions. 2 stable during Absorption (charging) and Release (discharging) of the Lithium ions

Anode (negative electrode) Lithium silicon composite oxide developed by SII in our MS battery is :

*1 Internal resistance is measured using AC (Alternating Current) method.

*2 Maximum discharge current indicates the value of current for approximately 50% of nominal capacity.

*3 100% and 20% D.O.D are based on nominal capacity.

7

Discharge Characteristics at Various Charge Voltage

1.5

2.0

2.5

3.0

3.5

0.0 0.5 1.0 3.01.5 2.52.0

2.85V 3.1V

1.5

2.0

2.5

3.0

3.5

0.0 0.5 1.0 3.0 3.5 4.01.5 2.52.0

2.9V

3.1V

2.8V2.7V 2.75V 3.0V

2.70V 2.75V 2.80V 2.85V 2.9V3.1V

Capacity [mAh]

Capacity [mAh]

Capacity [mAh]

Capacity [mAh]

Capacity [mAh]

Capacity [mAh]

Capacity [mAh]

Capacity [mAh]

3.3V

1.5

2.0

2.5

3.0

3.5

0.0 0.4 0.8 1.2 1.6

ChargeDischarge : 25µA/cov=2.0V (CC) Charge

Discharge : 300kΩ/cov=2.0V (CR)

ChargeDischarge : 25µA/cov=2.0V (CC)

1.5

2.0

2.5

3.0

3.5

0.0 0.5 1.0 1.5 2.0 2.5 3.0

3.3V

3.1

3.2V3.0V

2.9V2.8V

1.5

2.0

2.5

3.0

3.5

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5

3.3V

3.1V

3.2V3.0V

2.9V2.8V

1.5

2.0

2.5

3.0

3.5

0 1 2 3 4 5 6

2.9V2.8V2.7V 3.0V

3.3V

2.85V

1.5

2.0

2.5

3.0

3.5

0 2 4 6 8 10

3.1V 3.3V3.0V2.9V2.8V 2.7V 2.8V

3.1-3.3V

2.9V 3.0V

1.5

2.0

2.5

3.0

3.5

0 2 4 6 8 10 12

MS412F MS421S

MS614 MS614S

MS621 MS621F

MS920 MS920S

Vol

tage

[V]

Vol

tage

[V]

Vol

tage

[V]

Vol

tage

[V]

Vol

tage

[V]

Vol

tage

[V]

Vol

tage

[V]

Vol

tage

[V]


: max 0.025mA/72hr (CC/CV) : RL=2kΩ/96hr (CV)

: max.0.3mA/72hr (CC/CV)



ChargeDischarge : 100kΩ/cov=2.0V (CR)

: RL=300Ω/72hr (CV)






8


CHARACTERISTICSMS621

Storage Period at 60°C [days]

100

1000

10000

0 20 40 60 80 100

Depth of Discharge [%]

Cycle Life-Depth of Discharge

Cyc

le N

umbe

r [T

ime]

Cap

acity

[mA

h]

Cycle ConditionCharge : 100µA/cov=3.3V(C.C)Discharge : 100µA/cov=2.0V(C.C), normal capacity Measurement

Capacity MeasurementCharge : 0.3mA/3.3V/72Hr(C.C, C.V)Discharge : 25µA/cov=2.0V(C.C)

Cycle LifeCycle life is number of cycles when discharge capacity becomes60% of normal capacity after certain charge/discharge cycles under abovecondition.

Normal CapacityNominal Capacity(4mAh) x Depth of discharge/100

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

0 5 10 15 20 25

Storage Period at 80°C [days]

Over Discharge Period [month]

Room Temperature Storage Period [month]

High Temperature Storage Characteristics(80°C)

Over Discharge Characteristics

Cap

acity

[mA

h]C

apac

ity R

eten

tion

Rat

io [%

]O

pen

Circ

uit V

olta

ge [V

]

Temperature [°C]

Inte

rnal

Res

ista

nce

[Ω]

ChargeDischarge : 25µA/cov=2.0V(CC)

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

0 20 40 60 80 100

High Temperature Storage Characteristics(60°C)

0

20

40

60

80

100

0 1 2 3

Over Discharge Condition Discharge continuously with constant resistance of 18kohm for certain periodMeasure capacity after over Discharge (Set initial second cycle as 100%) Charge : 0.3mA/3.3V/72hr(CC/CV) Discharge : 25µA/cov=2.0V(CC)

0

20

40

60

80

100

0 20 40 10060 80

Storage Period at 60°C 3.3V [days]

Temperature [°C]

Over-Charge (Floating-Charge) Characteristics

Cap

acity

Ret

entio

n R

atio

[%]

Cap

acity

[mA

h]

Charge battery continuously for certain days under the condition of 60 deg.-C, 3.3V, 2kohm. then conduct 2 cycles of charge/discharge. the comparison in capacity with initial 2nd charge/discharge cycle Charge : 0.3mA/3.3V/72hr(CC/CV) Discharge : 25µA/cov=2.0V(CC)

0

1

2

3

4

0 1 2 6543

Self Discharge Characteristics

0

1

2

3

4

5

−20 −10 −20 −1040 503020100 60

Temperature Characteristics (Capacity)

Charge : 0.3mA/3.0V/72hr (CC/CV)Discharge : 25µA/cov=2.0V(CC)

Charge : 0.3mA/3.0V/72hr (CC/CV)Discharge : 25µA/cov=2.0V(CC)

0

100

50

200

150

300

250

400

350

500

450

30 40 5020100 60

Temperature Characteristics (Internal Resistance (Ri ac) )

Alternating Current method1kHz/1mA

Maximum

Average

: 0.3mA/3.3V/72hr(CC/CV)

Charge : 0.3mA/3.3V/72hr(CC/CV)Discharge : 25µA/cov=2.0V(CC)

9


Standard Charging Circuit Settings List for Using MS Rechargeable Battery with Constant

Voltage and Constant Resistance.Charging Voltage : 3.3V Max.

Charging current limiting resistance : R

D1 : Diode(Item of smaller VF, IR is recommendable)

D2 : Using a schottky type of smaller VF will lead

better performance

Circuit Example in the case of using 3V for Power Supply.

Circuit Example in the case of using 5V for Power Supply.

(1) with using voltage regulator IC

(3) with using charge/discharge control IC (4) with using devided resistance for valtage

(2) with using Zener diode

CHARGING CIRCUIT

Load

MS

CLOCKCMOSetc.

D2RD1

3.3V Max.

PowerSupply

Vc

MS412F

MS414

MS421S

MS614, 614F, 614S

MS621, 621F

MS920

MS920S

2.7 to 3.3

2.7 to 3.3

2.7 to 3.3

2.7 to 3.3

2.7 to 3.3

2.7 to 3.3

2.7 to 3.3

0.08max.

0.08max.

0.08max.

0.30max.

0.30max.

0.60max.

0.40max.

0.15

0.15

0.15

0.5

0.5

1.0

0.5

2

2

2

10

10

20

10

Type

ChargingVoltageRange (V)

RecommendableChargingCurrent (mA)At Battery Voltageof 3.0V Ic

At the Battery Voltage of 3.0V

IU

At the Battery Voltage of 0V

IL

Maximum Charging Current (mA) As for the minimum limit resistance R,please use the value which satisfies the following two formula;1)In the case a battery voltage is 3.0V: R> (Vc-3.0-Vf) / IU2)In the case a battery voltage is 0V: R> (Vc-Vf) / ILAlso for the recommendable limit resistance, please use Ic instead ofIU in the formula 1).

MS

D2R

D1

3.0V to 3.5V

3.3V Max.

Load

MS614F

D2 Vf=0.1VR

D1

3.3V

Vf=0.2V

3.1V

Load3.0-2.0V<3.0mAh>

Over 330Ω

MS

Load

D R

IC

5V 3.3V Max.

D1

D2 D3

3.3V Max.

ZD

R

MS

5V Load

IC

3.3V Max.

D

5V

MS

RLoad

D2D1R1

R2 3.3V Max.

5V

MSLoad

10


DIMENSIONS OF STANDARD TAB-WELD FOR MANGANESE SILICON LITHIUM-ION BATTERY

MS414, 412F FL26N / FL26E MS414, 412F IL21N / IL21E

0.5±

0.2

0.5±

0.2

0.10

±0.0

21.

0

1.0

1.8m

ax.

(9.2)

1.3±0.1

1.60±0.3

1.2±0.1

2.2±0.5

2.2±0.5

ø4.8+0–0.2

0.5±

0.2

0.10

±0.0

2

1.20

±0.1

0.5±

0.2

1.5

1.8m

ax.

1.3±0.1

1.60

1.65

2.2±0.5

(Solder Plating Area)

ø4.

80+

0–0

.2

MS614, 614F, 614S FL28N / FL28E MS614, 614F, 614S FL29N / FL29E

ø6.

8max

.

1.8±0.5

0.5±

0.2

1.0±

0.3

2.0±

0.3

1.8max.

0.10

±0.0

2

2.1±0.4

2.5+0.3–0.5


ø6.

8max

.

1.5±0.5

0.5±

0.2

1.0±

0.3

2.0±

0.3

85°±2°

0.10

±0.0

2

1.6±0.4

2.5+0.3–0.5

1.8max.

MS614, 614F, 614S IL38N / IL38E MS614, 614F, 614S LL32N / LL32E

1.8±0.5

0.5±

0.2

1.0±

0.3

2.0±

0.3

1.8±0.5

1.8max.

ø6.

8max

.

0.10

±0.0

2

2.1±0.4

2.5+0.3–0.5

2.5+0–0.6

2.9±0.3

1.8±0.5

2.1±0.3

1.8m

ax.

1.5

max

.

ø6.

8max

2.0±

0.3

0.10

±0.0

2

0.5±

0.2

2.9±

0.3

1.8±

0.5

2.50

90°±4°

MS614, 614F, 614S VI02N / VI02E

4.0±

0.1

1.4±

0.1

0.15±0.0290° ±2°

4.0±0.2

1.0±0.5

7.5+0.3–0.4

ø6.

8+

0–0

.1

MS621, 621F FL11N / FL11E

ø6.

8max

.

2.1±0.2

1.7±0.5

0.5max.

2.8m

ax.

(2.1

)

0.5±

0.2

0.5±

0.2

1.5±

0.3

2.5±0.3

0.15

±0.0

2

11

BATTERY HOLDER

<Applicable Batteries>MS414, MS412F, MS414F<Features>• Thin: 1.89mm Height after mounting• Easy for Automatic mounting: Able to insert battery vertically• Embossed Tape Package

With Standing Voltage

Contact Resistance

Insulation Resistance

Operational Temperature Range

DC500V/minute

StandardItem

-40°C ~ +85°C

Less than 100mΩ

More than 100MΩ

Using precision technology the holder realizes less-space and high reliability and obtains high mount-ing functionality.

MS414, MS412F, MS414F

8

4.9

3.7

1.2

1.894.891.2

1.8

5.8

7.4 9

7.6

Area for which patternsare prohibited.(Negative electrode patterns are permited.)

Area for which patternsare prohibited.(Positve electrode patterns are permited.)

<Specifications>

• Hatched parts are solder plated. (N type: Pb 10% Sn 90%) (E type: Sn 100%)• The E type is plated by Pb-free solder. We are going to discontinue N type soon.• For any optional terminal shapes, please consult with us.• Unit of dimensions: mm

BH0414

MS621, 621F IL36N / IL36E

ø6.

8

1.7

0.5±

0.2

2.5±0.4

0.5±

0.2

1.8

1.0

0.15

2.0

2.2m

ax.

2.7m

ax.

2.5±0.4

MS621, 621F VN31N / VN31E

MS920 FL27N / FL27E

ø9.

5max

. 0.5±

0.2

0.5±

0.2

2.0±

0.3

2.7m

ax.

0.15

±0.0

2

2.1±0.5

(3.3)

(2.2

)

12.8+0–1.0

MS920 IL37N / IL37E

ø9.

5max

.0.5±

0.2

1.0±

0.3

1.0±

0.3

0.5±

0.2

1.7±0.3

1.8±0.5

2.0±

0.3

2.7m

ax.

0.15

±0.0

5

2.5±0.42.5±0.4

12

Reflowable RB Lithium-Ion Rechargeable Battery

Charge-Discharge Characteristics

RB Lithium-Ion rechargeable battery allows reflow sol-dering for automatic mounting, by adopting highly heat-resistant material and precise sealing technology. RBSeries features high capacity and long cycle life withpossible charging voltage range from 1.8V to 3.3V, whichis most suitable for backup use of real time clock andSRAM etc.

FEATURES• Reflowable : Superior heat resistance without deterioration of battery performance due to

reflow soldering.• Wide Range of charging voltage : Wide range voltage

(1.8V to 3.3V) allows to be used forvarious applications

• High Capacity : Ten times higher than capacitor in 0.3mAh typ.

(charge:3V cut off 1.2V)• Long cycle life : More than 1,000 times charge/discharge cycle (10% D.O.D)• Excellent over discharge characteristics

APPLICATIONSPower supply back up use for Cellular phone, Wirelessphone, PHS, Digital still Camera, PDA, MD player.

SPECIFICATIONS

CHARACTERISTICS

3.0 4.8 1.4

0.3 (3.0-1.2)1000 ( 10% D.O.D )

100 ( 100% D.O.D )0.2 (2.5-1.2)

0.14 (3.0-2.0)

0.070.005RB414

TypeDiameter

(mm)Cycle Life

(Time)

Standard ChargeDischarge Current

(mA)

Nominal Voltage

(V)

Height(mm)

Weight(g)

Nominal Capacity(Voltage Range)

(mAh)

3.5

0.0 0.1 0.2 0.3 0.4 0.5

3.0

2.5

2.0

1.5

1.0

0.5

0.0

Capacity [mAh] Capacity [mAh]

Vol

tage

[V]

Vol

tage

[V]

Capacity [mAh]

Vol

tage

[V]

3.5

0.00 0.05 0.150.10 0.20 0.25 0.30 0.35

3.0

2.5

2.0

1.5

1.0

0.5

0.0

3.5

0.00 0.05 0.150.10 0.20 0.25 0.30 0.35

3.0

2.5

2.0

1.5

1.0

0.5

0.0

Charge : 3.3V/max.25µA/48hr/RT(CC/CV)Discharge : 5µA/cov=0.0V

1. 3.3V 2. 3.0V 3. 2.5V



13

CHARACTERISTICS

REFLOW SOLDERING CONDITION

RB414 II06N / II06E

DIMENSIONS OF STANDARD TAB-WELD FOR REFLOWABLE RB BATTERY

* Hatched parts are solder plated. (N type : Pb 10% Sn 90%) (E type : Sn 100%)* The E type is plated by Pb-free solder. We are going to discontinue N type soon.* For any optional terminal shapes, please consult with us.* Unit of dimensions : mm

1.0

2.0

3.0

4.0

0.15 0.200.100.050.00

initial

After 60°C x 100 storage days

Capacity [mAh]

Vo

lta

ge

[V

]

Charge-Discharge Cycke Characteristics(100% D.O.D) High Temperature Strage Characteristics (60°C)

0.00

0.05

0.10

0.15

0.20

0 20 40 60 80 120 140 160 180 200100

Ca

pa

city

[m

Ah

]

Cycle Number (times)

5µA Discharge/25µA,30hr Charge

20µA Discharge/500µA,5hr Charge

0

50

100

150

200

250

0 50 100 150 200 250 300

Tem

pera

ture

on

the

cell

surf

ace

(°C

)

Time (Seconds)

Pre heat region

above 200°CReflow region

0 10 20 30 40 60 7050

Time above 200 °C (Seconds)

240 °C Peak Temperature: under 5sec.

200

210

220

230

240

250

Pea

k T

empe

ratu

re (

°C)

Reflow Soldering Temperature Profile Example Recommended Reflow Condition

The times of repeated reflow soldering must be two times or less.The Temperature must be measured at top of the cell.

RB414 IV01N / IV01ERB414 IV02N / IV02E

0.5±0.5

7.1±0.2

1.8±0.2

1.1±0.1

4.35

Recommendable P.C.Board layout(Scale=4 : 1, Tolerance=±0.05)

1.5 1.57.4

3.5

2.5

0.5±0.2

1.1±0.5

0.6±0.1

1.1±0.1

1.5±

0.2

1.67

±0.0

5

0.1±

0.03

0.2±

0.1

1±0.

2

(Side Solder Plating Area)



(Ben

ding

Poi

nt)

3 0 –0

.05

2 0 –0

.05

1.42

0 –0.1

0.2

+0

0

4.8

0 –0.2

φ

(Solder Plating Area) Recommendable P.C.Board layout

Example of battery mounting

45°

1.0±0.1

2.4±0.2

5.9

4.1

2.4

2.7

5.9

2.71.7 2.4

1.0±0.5

2.9±0.2

2.9±

0.2

1.24

1.24

1.67

±0.1

0.1±

0.02

0.8±

0.5

3.5±

0.1

2.4±

0.2 (S

olde

r P

latin

gA

rea)


1.41

0 –0.1

0.2

+0.

1 0

2.6

4.8M

AX

φ

45°

3.5±0.1

1.0±0.1

1.0±

0.02

0.8±

0.5

2.4±0.2

2.4±

0.2

2.4±

0.2

2.4±0.2

1.24

1.24

1.67

±0.1

1±0.

51.

41 0 –0

.1

0.2

+0

0

2.6

4.8M

AX

φ

2.7

4.1

2.4

2.4

1.7

2.7

5.4

(Sol

der

Pla

ting

Are

a)

(Sol

der

Pla

ting

Are

a)

Recommendable P.C.Board layout


14

Pb-free ReflowableHB Lithium-Ion Rechargeable Battery NEW

For protecting the global environment, SII developedLithium-ion rechargeable battery which allows Pb-freereflow soldering (automatic mounting by Pb-free solder)HB414 is the Pb-free reflowable Lithium-ion recharge-able battery, by adopting highly heat resistant materialand precise sealing technology.HB series features high capacity and long cycle life withpossible charging voltage range from 1.8V to 3.3V, whichis most suitable for backup use of real time clock andSRAM etc.

FEATURES• Pb-free reflowable Superior heat resistance (260°C peak) allows reflow

soldering by Pb-free solder.• Wide Range of charging voltage : Wide range voltage

(1.8V to 3.3V) allows to be used forvarious applications

• High Capacity : Ten times higher than capacitor in 0.3mAh typ.

(charge:3V cut off 1.2V)• Long cycle life : More than 1,000 times charge/discharge cycle (10% D.O.D)• Excellent over discharge characteristics

APPLICATIONSPower supply back up use for Cellular phone, Wirelessphone, PHS, Digital still Camera, PDA, MD player.

SPECIFICATIONS


3.0 4.8 1.4

0.3 (3.0-1.2)1000 ( 10% D.O.D )

100 ( 100% D.O.D )0.2 (2.5-1.2)

0.14 (3.0-2.0)

0.070.005HB414

TypeDiameter

(mm)Cycle Life

(Time)

Standard ChargeDischarge Current

(mA)

Nominal Voltage

(V)

Height(mm)

Weight(g)

Nominal Capacity(Voltage Range)

(mAh)

0

50

100

150

200

250

0 50 100 300150 250200

Time above 200°C

Recommended Reflow Condition

Peak Temperature

Max.260°C

Model

Applicable (within 5 seconds)

HB414 XH414H

Time (seconds)

Reflow soldering profile (for reference only)

Tem

pera

ture

(°C

)

220

230

240

250

260

270

0 10 20 60 7030 5040

Time above 200°C (seconds)


Pea

k te

mpe

ratu

re (

°C)

The peak temperature is within five seconds.


<Reflow Soldering Conditions>

15

CHARACTERISTICS

HB414 II06E

DIMENSIONS OF STANDARD TAB-WELD FOR REFLOWABLE HB BATTERY

* Hatched parts are solder plated. (E type : Sn 100%)* The E type is plated by Pb-free solder.* For any optional terminal shapes, please consult with us.* Unit of dimensions : mm

HB414 IV01EHB414 IV02E

0.5±0.5

7.1±0.2

1.8±0.2

1.1±0.1

4.35


1.5 1.57.4

3.5

2.5

0.5±0.2

1.1±0.5

0.6±0.1

1.1±0.1

1.5±

0.2

1.67

±0.0

5

0.1±

0.03

0.2±

0.1

1±0.

2




(Ben

ding

Poi

nt)

3 0 –0

.05

2 0 –0

.05

1.42

0 –0.1

0.2

+0

0

4.8

0 –0.2

φ



45°

1.0±0.1

2.4±0.2

5.9

4.1

2.4

2.7

5.9

2.71.7 2.4

1.0±0.5

2.9±0.2

2.9±

0.2

1.24

1.24

1.67

±0.1

0.1±

0.02

0.8±

0.5

3.5±

0.1

2.4±

0.2 (S

olde

r P

latin

gA

rea)


1.41

0 –0.1

0.2

+0.

1 0

2.6

4.8M

AX

φ

45°

3.5±0.1

1.0±0.1

1.0±

0.02

0.8±

0.5

2.4±0.2

2.4±

0.2

2.4±

0.2

2.4±0.2

1.24

1.24

1.67

±0.1

1±0.

51.

41 0 –0

.1

0.2

+0

0

2.6

4.8M

AX

φ

2.7

4.1

2.4

2.4

1.7

2.7

5.4

(Sol

der

Pla

ting

Are

a)

(Sol

der

Pla

ting

Are

a)



1.5

2.0

2.5

3.0

3.5

0.00 0.05 0.200.10 0.15

Capacity [mAh]

Charge-Discharge Characteristics

Vol

tage

[V]

1.0

2.0

3.0

4.0

0.00 0.05 0.200.10 0.15

Capacity [mAh]

High Temperature Storage Characteristics (60°C)

Vol

tage

[V]

Charge : 3.3V/max.25µA/30hr (CC/CV)Discharge : 5µA/cov=2.0V (CC)

2nd Discharge Curves

after 100days

initial

0.00

0.05

0.10

0.15

0.20

0 20 40 10060 80

Cycle Number [times]

Charge-Discharge Cycle Characteristics

Cap

acity

[mA

h]

0.00

0.05

0.10

0.15

0 10 10020 30 40 50 60 70 80 90

Cycle Number [times]

Over Discharge Cycle Characteristics

Cap

acity

[mA

h]5µA Discharge/25µA, 30hr Charge

20µA Discharge/500µA, 5hr Charge

5µA Discharge/25µA 30hr Charge

20µA Discharge/500µA 5hr Charge

16

TS Lithium-Ion Rechargeable Battery <1.5V Type>

SPECIFICATIONS

*1: at 2.3V charge *2: 100% and 20% are based on nominal capacity *3. *4: D.O.D indicates depth of discharge

TS(Titanium Silicon) Lithium-lon battery is 1.5V type re-chargeable battery features large capacity, wide charg-ing voltage range, long cycle-life and excellent reliabilitywith using titanium composite oxide as cathode andoriginally developed Litium silicon oxide as anode.

FEATURES• Large discharge capacity:

TS obtains 15 times larger capacity to same size ca-pacitor.

• Long cycle-life:Realizes more than 1000 charge/discharge cycles at20% of discharge depth.

• Excellent over-discharge characteristics:TS maintains continuous stable characteristics afterover-discharge to 0V.

• Wide charging voltage range:TS has excellent charge-efficiency even at the chargevoltage of 1.5V.Any setting is available from 1.5V to 3.0V.

• Outstanding leakage resistance:SII’s long experienced sealing technology through sil-ver oxide battery manufacturing for timepiece achievedthe excellent leakage resistance.

APPLICATIONS• Power supply for backing up memory or clock in cellular phone, PHS, pagers etc.

• Combined use with solar cells (watch, calculator, blinking road-marker etc.)• Main power source for small portable equipment.

TS621

CHARACTERISTICS

For Charging Circuit DesignIf the battery is charged by excessive voltage or current, it makesthe battery deteriorate and may cause leakage, excessive heat,explosion or fire. Please set the circuit parameter not to exceedthe regulated charging voltage and charging current written inthe right column. Please consult us if you need to use differentcharging condition from the right column.

In case of under 1.6VIn case of 1.6 to 3.0V

0.2mA3mATS621

6mATS920 0.4mA

Charge Voltage When battery voltage

reaches 0.7V( )

< Maximum Charging Current >

epyTlanimoN

egatloV)v(

lanimoNyticapaC1*)hAm(

dradnatS/egrahCegrahcsiD

tnerruC)Am(

mumixaMegrahcsiD

tnerruC)suounitnoc(

)Am(

2*)semiT(efiLelcyC )mm(eziSthgieW

)g(%0013*D.O.D

%024*D.O.D

retemaiD thgieH

126ST 5.1 5.2 510.0 5.0 002revo 0001revo 8.6 1.2 22.0

029ST 5.1 0.5 030.0 2.1 002revo 0001revo 5.9 1.2 54.0

0.0

0.0

Charge/discharge characteristics

Capacity [mAh]

Vo

lta

ge

[V

]

0.5

1.0

1.5

2.0

2.5

0.5 1.0 1.5 2.0 3.02.5

Charge : 2.3V/8.2KΩ/36hr (CV/CR)Discharge : 100KΩ/cov=0.7V (CR)

Charge

Discharge

0.0

1.4

Charge voltage dependence of discharge capacity

Charge Voltage [V]

Dis

cha

rge

Ca

pa

city

[m

Ah

]

Ch

arg

e T

ime

[h

r]

0.5

1.5

1.0

2.0

2.5

3.0

0

20

60

40

80

100

120

1.6 1.8 2.0 2.2 2.4 2.82.6 3.0

Charge : 0.1mA/coc=0.01mA (CC/CV)Discharge : 50µA/cov=0.7Vı (CC)

Charge period

Discharge capacity

17

TS621

TS920

0.0

0

Over charge (Floating charge) characteristics

Discharge Capacity [mAh]

Vol

tage

[V

]

0.5

1.0

1.5

2.0

2.5

0.5 1 1.5 2 32.5


Initial

after 60°C,3.0V -impressed, 200days

0.0

1

Charge/discharge cycle characteristics

Cycle Number [time]

Cap

acity

[m

Ah]

0.5

1.5

1.0

2.0

2.5

3.0

10 100 1000 1000

Charge : 0.1mA/2.3V/36hr (CC/CV)Discharge : 50µA (CC)

100%Depth of Discharge

50% D.O.D

20% D.O.D

5% D.O.D

Continued

0.0

0.0

Over discharge characteristics


Vol

tage

[V

]

0.5

1.0

1.5

2.0

2.5

0.5 1.0 1.5 2.0 3.52.5 3.0


after over discharge (10KΩ-200days)

Initial

0.0

0.0

Storage characteristics

Discharge Capacity [V]

Vol

tage

[V

]

0.5

1.0

1.5

2.0

2.5

0.5 1.0 1.5 2.0 3.52.5 3.0


after 200days storage in 60°C

Initial

0.0

0.0

Over discharge cycle characteristics


Vol

tage

[V

]

0.5

1.0

1.5

2.0

2.5

0.5 1.0 1.5 2.0 3.52.5 3.0


50th Cycle

20th Cycle

Initial

0.0

0.0

Temperature characteristics


Vol

tage

[V

]

0.5

1.0

1.5

2.0

2.5

0.5 1.0 1.5 2.0 3.52.5 3.0


-20°C 25°C 60°C

0.0

0

Charge/discharge characteristics

Capacity [mAh]

Vol

tage

[V

]

0.5

1.0

1.5

2.0

2.5

1 2 3 4 65

Charge :2.3V/3.9KΩ/36hr (CV/CR)Discharge :100KΩ/cov=0.7V (CR)

0

1

2

3

4

5

6

7

0

20

40

60

80

100

120

Temperature Characteristics

-20

Temperature [°C]

Ca

pa

city

[m

Ah

]

Inte

rna

l R

esi

sta

nce

[Ω

]

0 20 40 60

Charge : 2.3V/3.9kΩ/36hr (25°C) (CC, CV)Discharge : 100kΩ/cov=0.7V (CR)Internal Resistance :1kHz/1mA (AC)

Capacity

Internal Resistance

18

Reflowable XC Capacitor < 2.5V Rated Voltage Type >

Using chemically-stable large surface area activated car-bon as electrode, this new type of capacitor features high-capacitance, low-impedance, high-rated voltage, andlong-term reliability through unique sealing technology.Moreover, using original heat resistant materials and celldesign, the capacitor allows reflow soldering in responseto the demand of automatic mounting.

FEATURES• Able to conduct reflow soldering• Large-capacitance

Higher-capacitance of 0.3F is available for size621(φ6.8 2.1mm), compared to conventional elec-tric double layer capacitors.

• Low-impedance & Excellent charge-discharge rate.Impedance is less than that of conventional capaci-tors, and it realizes quick charge, discharge.

• High-rated voltage2.5V rated operating voltage allows for flexible design.

• Long cycle life over 100,000times• Excellent long-term reliability

There is no characteristic deterioration due to over-charge and overdischarge.

• Charge/discharge circuit is very simple (constant volt-age charge)

APPLICATIONS• Back up for memory and clock function, in various electronic equipments, cellular phones, cameras, PDA, Faxmachines, VTR, TV, printer, pagers, etc.• Combined use with solar cells.• Auxiliary power supply for voltage drop of battery.

SPECIFICATIONS

*Operating Temperature Range: -25°C~+70°C

Type

Dimensions

XC4142.5

2.5

2.5

4.86.8

6.8

1.40.9

2.1

0.06 0.060.14

0.21

0.07

0.30

6025

25

XC609

2.5 0.166.8 1.40.18 25XC614

XC621

Rated OperatingVoltage

(V)

Electrical Characteristics (at Room Temperature)*

ElectrostaticCapacity

(F)

InternalResistance

(Ω)

Diameter(mm)

Height(mm)

Weight(g)

XC414

XC614

CHARACTERISTICS

0 10 20 30 40 50 60 70 80 90 1000.0

0.5

1.5

1.0

2.0

2.5

3.0

Vo

lta

ge

[V

]

Charge

Charge : 2.5V/25mA/0.5hr(CV, CC)Discharge : 100µA/cov=0.0V (CC)

Capacity [µAh]

Discharge

0.001

0.02

0.04

0.06

0.08

0.10

5000 10000 15000

Cycle [time]

Ca

pa

city

[F

]

Continued

Charge: 2.5V, 1.3kΩ, 9min. (Constant voltage, Constant resistance) Discharge: 1.3kΩ/COV=0V(Constant resistance)

0.00

0.02

0.04

0.06

0.08

0.10

- 25 25 70

Temperature [°C]

Charge: max. 2.5V, 25mADischarge: 0.02mA

Ca

pa

city

[F

]

Charge-Discharge Characteristics Charge-Discharge Cycle Characteristics Temperature Characteristics

0.0

0.5

1.0

1.5

2.0

2.5

3.0

0 20 40 60 80 100 120 140 160

Capacity (µAh)

Vol

tage

(V

)

0.000.020.040.060.080.100.120.140.160.180.20

0 5000 10000 15000 20000 25000 30000

Continued

Ca

pa

city

[F

]

Cycle [time]

Cycle Conditions Charge: 2.5V, 9min. Discharge: Short, 1min.Capacity Measuring Charge: 2.5V, max. 200µA, 5hr Discharge: 100µA, cov.=0V

0.000.020.040.060.080.100.120.140.160.180.20

-40 -30 -20 -10 0 10 20 30 40 50 60 70 80

Temperature [°C]

Charge: 2.5V, max. 200µA, hoursDischarge: 100µA, cov=0V

Ca

pa

city

[F

]

Charge-Discharge Characteristics Charge-Discharge Cycle Characteristics Temperature Characteristics

Charge: 2.5V, max. 200 A, 5hr, RTDischarge: 100 A, COV=0Vµ

µ

Charge

Discharge

19

XC609 II38N / II38E XC614 II21N / II21E XC621 II31N / II31E

DIMENSIONS OF STANDARD TAB-WELD FOR REFLOWABLE XC CAPACITOR

0.10

±0.0

3

ø6.

8+

0–0

.2

10.3MAX

1±0.5

0.7±0.1



0.8±0.2

(Side Solder Plating Area)(Side Solder Plating Area)1.4±0.1

0.6±0.5

2.3±0.2

1.5±

0.2

3±0.

1

4±0.

1

1.26

±0.2

0.1±

0.03

2±0.

2

REFLOW PROFILE SAMPLE

XC414 II06N / II06E

7.5MAX

2 0

-

0.05

0.2

+0.

1

01.

42 0

-

0.2

3 0

-

0.05

1.8±0.2

0.5±0.5

1.1±0.1

1.1±0.5

1.1±0.1

0.6±0.1

0.5±0.2

0.1±

0.03

1.67

±0.0

5

φ 4.

8 0

-

0.2



(Sol

der P

latin

g)

2.45

+0.

15

ø6.

8+

0–0

.2

2.15

0 –0.2

1.3±0.5

1±0.1


2±0.3

0.7±0.1

2.5±0.31.4±0.1



1.5±

0.2

3 -0

.05

0.15

±0.0

32±

0.2

4 -0.

05

(Solder Plating Area)0.6±0.5

00

0

11.9MAX

XC609

XC621

Note: Before assembly, please make sure the polarity( + / - ) of capacitor.

0.001 0.01 0.1 1 10

0.0

0.5

1.0

1.5

2.0

2.5

3.0

Charge Characteristics (Charge Voltage 2.5V)

47Ω

240Ω

470Ω

Vol

tage

(V)

Time(hour)

0.0

0.5

1.0

1.5

2.0

2.5

3.0V

olta

ge(V

)

0.01 0.1 1 10010 1000Time(hour)

Discharge Characteristics (constant resistance)1098876543210

0 2 4 6 8 10 12 14 16 18 20 22 24Time (hour)

Leak Current Characteristics(Charging at 2.5V)

Cu

rre

nt(µ

A)

1098

7

65

4

32

1

00 2 4 6 8 10 12 14 16 18 20 22 24

Time (hour)

Leak Current Characteristics(Charging at 2.5V)

Cur

rent

(µA

)

0.001 0.01 0.1 1 100.0

0.5

1.0

1.5

2.0

2.5

3.0

Charge Characteristics (Charge Voltage 2.5V)

47Ω

240Ω

470Ω

Vol

tage

(V)

Time(hour)

0.0

0.5

1.0

1.5

2.0

2.5

3.0

Vol

tage

(V)

0.001 0.01 0.1 1 10 100Time(hour)

Discharge Characteristics (constant resistance)

5.1kΩ 56kΩ 510kΩ

5.1kΩ 510kΩ56kΩ

0

50

100

150

200

250

0 50 100 150 200 250 300

Tem

pera

ture

on

the

cell

surf

ace

(°C

)

Time (Seconds)

Pre heat region



1.3±0.5

2±0.

20.

15±0

.02

1±0.2

1±0.1 0.7±0.1

0.8±0.1 1.4±0.1

2.1±0.2

1.5±

0.2

0.6±0.5

4 0 –0

.05

1.4 0 –0

.15

0.55

0 –0.2

6.8

0 –0.2

0.15

±0.0

2

1.79

+0.

15 0

3 0 –0

.05

φ

(9.9)

(solder Plating Area)

(side solderPlating Area)

(side solderPlating Area)

(solder Plating Area)


20

Reflowable XH Capacitor <3.3V High-rated Voltage Type>

CHARACTERISTICS

SPECIFICATIONS

Adopting high voltage-resistant material and new design,we realize the XH unit cell that is a high voltage-resistantreflowable capacitor rated to 3.3V.Using chemically-stable large surface area activatedcarbon as electrode and SII's original sealing andmanufacturing technology, the XH capacitor featureshigh-capacity, low-impedance and long-term reliability.The XH capacitor is most suitable for clock and memorybackup in various electronic equipments due to its wideoperating voltage.

FEATURES• High-rated voltage : Able to be used at wide range

voltage form 0V to 3.3V and be used for various appli-cations

• Reflowable• High Capacity : 0.07F with "414" size (diameter4.8 mm : hight 1.4mm)• Low Impedance : Quick Charge-Discharge Performance• Long Cycle Life : More than 10,000 times charge-discharge cycle• Able to make simple charging circuit (Constant-volt-

age charging)

APPLICATIONSPower supply back up use for Cellular phone, Wirelessphone, PHS, PDA, MD player

3.3 4.8 1.40.07 0.0670XH414

Type Nominal Voltage(V)

Electrostatic Capacity(F)

Electrical Characteristics(at Room Temperature)*

Internal Resistance(Ω)

Weight(g)Diameter

(mm)Height(mm)

Dimensions

*Recommended Operating Temperature Range: -25°C to +70°C

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

0

20

40

60

80

100

120

0 3000 6000 9000 12000 15000 18000

Cycle Number

Charge-Discharge Cycle Charge: 3.3V, 9min. Discharge: Short circuit for 1min.Capacity Measurement Charge: 3.3V / 5hr Discharge: 20µA, cov.=2V

Continued

Charge-Discharge Characteristics Charge-Discharge Cycle Characteristics

0.15 0.200.200.100.050.00

Vo

lta

ge

[V

]

Capacity [mAh]

Discharge: 20µACharge:50µA/3.3V 5hr, RT

21

CHARACTERISTICS


XH414 II06N / II06E

DIMENSIONS OF STANDARD TAB-WELD FOR REFLOWABLE XH CAPACITOR

0

20

40

60

80

100

120

0 50 100 150 200 250

Discharge Current(µA)

Charge: 3.3V 5hr.Discharge: at each current, cov.=2V

0

20

40

60

80

100

120

Temperature(°C)

Cap

acity

Ret

entio

n R

atio

(%)

Charge: 3.3V 5hrDischarge: 20µA, cov.=2V

Cap

acity

Ret

entio

n R

atio

(%)

Discharge Current Characteristics Temperature Characteristics

- 40 - 30 - 20 -10 0 10 20 30 40 50 60 70 80

0

50

100

150

200

250

0 50 100 150 200 250 300

Peak Temperature

Time (Seconds)

Pre heat region


Tem

pera

ture

on

the

cell

surf

ace

(°C

)

0 10 20 30 40 60 7050

Time above 200 °C (Seconds)

240 °C Peak Temperature: under 5sec.

200

210

220

230

240

250

Pea

k T

empe

ratu

re (

°C)

Reflow Soldering Temperature Profile Example Recommended Reflow Condition


XH414 IV01N / IV01EXH414 IV02N / IV02E

0.5±0.5

7.1±0.2

1.8±0.2

1.1±0.1

4.35


1.5 1.57.4

3.5

2.5

0.5±0.2

1.1±0.5

0.6±0.1

1.1±0.1

1.5±

0.2

1.67

±0.0

5

0.1±

0.03

0.2±

0.1

1±0.

2




(Ben

ding

Poi

nt)

3 0 –0

.05

2 0 –0

.05

1.42

0 –0.1

0.2

+0

0

4.8

0 –0.2

φ



45°

1.0±0.1

2.4±0.2

5.9

4.1

2.4

2.7

5.9

2.71.7 2.4

1.0±0.5

2.9±0.2

2.9±

0.2

1.24

1.24

1.67

±0.1

0.1±

0.02

0.8±

0.5

3.5±

0.1

2.4±

0.2 (S

olde

r P

latin

gA

rea)


1.41

0 –0.1

0.2

+0.

1 0

2.6

4.8M

AX

φ

45°

3.5±0.1

1.0±0.1

1.0±

0.02

0.8±

0.5

2.4±0.2

2.4±

0.2

2.4±

0.2

2.4±0.2

1.24

1.24

1.67

±0.1

1±0.

51.

41 0 –0

.1

0.2

+0

0

2.6

4.8M

AX

φ

2.7

4.1

2.4

2.4

1.7

2.7

5.4

(Sol

der

Pla

ting

Are

a)

(Sol

der

Pla

ting

Are

a)




22

Pb-free Reflowable CapacitorXH414H <3.3V High-rated Voltage Type> NEW


SPECIFICATIONS

For protecting the global environment, SII developed Ca-pacitor which allows Pb-free reflow soldering (automaticmounting by Pb-free solder)XH414H is the Pb-free reflowable Capacitor, by adoptinghighly heat resistant material and precise sealing technol-ogy.The XH414H Capacitor features high-capacity, low-imped-ance and long term reliability.It is most suitable for clock and memory backup in variouselectric equipments due to its wide operating voltage.

FEATURES• Pb-free reflowable

Superior heat resistance (260°C peak) allows reflowsoldering by Pb-free solder

• High-rated voltage : Able to be used at wide rangevoltage form 0V to 3.3V and be used for various appli-cations

• High Capacity : 0.07F with "414" size (diameter 4.8 mm : hight 1.4mm)• Low Impedance : Quick Charge-Discharge Performance• Long Cycle Life : More than 10,000 times charge-discharge cycle• Able to make simple charging circuit (Constant-volt-

age charging)

APPLICATIONSPower supply back up use for Cellular phone, Wirelessphone, PHS, PDA, MD player

3.3 4.8 1.40.07 0.0770XH414H

Type Nominal Voltage(V)

Electrostatic Capacity(F)

Electrical Characteristics(at Room Temperature)*

Internal Resistance(Ω)

Weight(g)Diameter

(mm)Height(mm)

Dimensions

*Recommended Operating Temperature Range: -25°C to +70°C

0

50

100

150

200

250

0 50 100 300150 250200

Time above 200°C


Peak Temperature

Max.260°C

Model

Applicable (within 5 seconds)

HB414 XH414H

Time (seconds)

Reflow soldering profile (for reference only)

Tem

pera

ture

(°C

)

220

230

240

250

260

270

0 10 20 60 7030 5040

Time above 200°C (seconds)


Pea

k te

mpe

ratu

re (

°C)

The peak temperature is within five seconds.


<Reflow Soldering Conditions>

23

CHARACTERISTICS

XH414H II06E

DIMENSIONS OF STANDARD TAB-WELD FOR REFLOWABLE XH414H CAPACITOR

XH414H IV01EXH414H IV02E

0.5±0.5

7.1±0.2

1.8±0.2

1.1±0.1

4.35


1.5 1.57.4

3.5

2.5

0.5±0.2

1.1±0.5

0.6±0.1

1.1±0.1

1.5±

0.2

1.67

±0.0

5

0.1±

0.03

0.2±

0.1

1±0.

2




(Ben

ding

Poi

nt)

3 0 –0

.05

2 0 –0

.05

1.42

0 –0.1

0.2

+0

0

4.8

0 –0.2

φ



45°

1.0±0.1

2.4±0.2

5.9

4.1

2.4

2.7

5.9

2.71.7 2.4

1.0±0.5

2.9±0.2

2.9±

0.2

1.24

1.24

1.67

±0.1

0.1±

0.02

0.8±

0.5

3.5±

0.1

2.4±

0.2 (S

olde

r P

latin

gA

rea)


1.41

0 –0.1

0.2

+0.

1 0

2.6

4.8M

AX

φ

45°

3.5±0.1

1.0±0.1

1.0±

0.02

0.8±

0.5

2.4±0.2

2.4±

0.2

2.4±

0.2

2.4±0.2

1.24

1.24

1.67

±0.1

1±0.

51.

41 0 –0

.1

0.2

+0

0

2.6

4.8M

AX

φ

2.7

4.1

2.4

2.4

1.7

2.7

5.4

(Sol

der

Pla

ting

Are

a)

(Sol

der

Pla

ting

Are

a)



* Hatched parts are solder plated. (E type : Sn 100%)* The E type is plated by Pb-free solder.* For any optional terminal shapes, please consult with us.* Unit of dimensions : mm

0.0

0.5

1.0

1.5

2.0

3.0

2.5

3.5

0 20 40 1008060

Capacity [µAh]

Charge-Discharge Characteristics High Temperature Storage Characteristics (70°C)

Vol

tage

[V]

0

20

40

60

80

100

120

0 10 20 30 5040

Storage Period [days]

Cap

acity

Ret

entio

n R

atio

[%]

Charge : 3.3V/50µA/5hr/RT (CC/CV)Discharge : 20µA/cov=0V (CC)

Charge : 3.3V/5hr (CV)Discharge : 20µA/cov=2V (CC)

0

20

40

60

100

80

120

−40 −30 −20 −10 0 10 20 8060 7040 5030 −40 −30 −20 −10 0 10 20 8060 7040 5030

Temperature [°C]

Temperature Characteristics (Discharge Capacity)

Cap

acity

Ret

entio

n R

atio

[%]

0

100

200

300

400

500

600

800

700

900

1000

Temperature [°C]

Temperature Characteristics (Internal impedance)R

i [Ω

]

Charge : 3.3V/5hr (CV)Discharge : 20µA/cov=2V (CC)

Charge : 3.3V/5hr (CV)Discharge : 20µA/cov=2V (CC)* Internal impedance (Ri) measured at 1kHz A.C.

24

Silver Oxide Battery High performance batteries acknowledgedin the quartz watch market

Silver oxide is used as cathode, zinc is used as anode,and sodium hydroxide solution or pottasium hydroxidesolution is used as electrolyte. These batteries with largecapacity and stable voltage characteristics are widelyapplied to products demanding high accuracy, likequartz watches.

FEATURES• Large capacity

Energy density per volume is about 2 times higher thanthat of alkaline-manganese batteries.

• Stable operating voltage Operating voltage is very stable until the end of dis-

charge.

• Excellent leakage resistance

Excellent leakage resistance is achieved by our spe-cial sealing materials and superior processing tech-nologies.

• Excellent pulse load characteristicsBatteries using pottasium hydroxide solution are mostsuitable for functions which consume relatively high cur-rent, such as an alarm-or-backlight-function incorpo-rated into digital quartz watches.

• A comprehensive variety of products

The diameter is from 4.8 mm to 11.6mm, the height isfrom 1.2mm to 3.6mm.

Users can select the most suitable battery for theirapplications.

APPLICATIONSWatches, Clocks, Calculators, Hearing aids, Digital clini-cal thermometers, Cameras, Electronic games, Cardradios, Remote controllers.

CROSS SECTION

SPECIFICATIONS

*C.C.V. : Closed Circuit Voltage Low Drain 2kΩ 7.8msec Pulse High Drain 200Ω 5sec.

Anode

Anode cap

Cathode can

Absorbent layer

Cathode

Gasket

Separator

.oNledoM

scitsiretcarahClacirtcelE)erutarepmeTmooRta(

snoisnemiDthgieW

)g(RACU.oN

).PYT(*.V.C.C egarotSssol

)XAM()Y/%(

lanimoNegatloV

)V(

lanimoNyticapaC

)hAm(

mumixaMniarD)Am(

retemaiD)mm(

thgieH)mm(

C˚42+)V(

C˚01–)V(

woLniarD

WS614RS

55.1

5.7

8.0

08.456.1 21.0 ––––

53.1 01.1

7

WS124RS 21 51.2 61.0 ––––

WS215RS 5.5

08.5

52.1 41.0 533

54.1

51.1

WS615RS 5.21 56.1 02.0 713 01.1

WS125RS 61 51.2 52.0 973

02.1

WS725RS 22 07.2 13.0 913

WS616RS 51

08.6

56.1 42.0 123

WS126RS 32 51.2 33.0 463

WS626RS 03 06.2 83.0 773

WS217RS 11

09.7

52.1 52.0 643

WS617RS 12 56.1 43.0 513

WS127RS 82 01.2 44.0 263

WS627RS 43 06.2 35.0 793

WS14RS 54 06.3 96.0 483

WS619RS 72

05.9

56.1 35.0 373

WS029RS 64 50.2 06.0 173

WS729RS 55 07.2 08.0 593

WS0211RS 35 06.11 50.2 49.0 183

hgiHniarD

W626RS

55.1

82

8

08.6 06.2 63.0 673

53.150.1

7

W127RS 62

09.7

01.2 14.0 163

W627RS 43 06.2 35.0 693

W14RS 54 06.3 96.0 293 51.1

W029RS 2401 05.9

50.2 65.0 073 01.1

W729RS35

07.2 77.0 993 50.1

W0211RS 51 06.11 50.2 49.0 193

04.1

02.1

25

Silver Oxide Battery

SR621SW

SR920SW

SR41W

SR920W

CHARACTERISTICS

Temp:24˚C1.6

1.4

1.2

1.0

0.8

0.6

1.6

1.4

1.2

1.0

0.8

0.6

100 200 300 400 500 600 700

1.6 24˚C

1.4

1.2

1.0

0.8

0.6

100 200 300

39kΩ Continuous(24˚C)

400 500

39kΩ 50kΩ

2kΩ 7.8msec(–10˚C)

–10˚C

1k 2k 5k 10k 20k

Load-discharge characteristics

Discharge time (hr)

Vol

tage

(V

)

Pulse-discharge characteristics

Discharge time (hr)

Vol

tage

(V

)

Load-temperature-voltage characteristics

Load (Ω)

Vol

tage

(V

)

Temp:24˚C1.6

1.4

1.2

1.0

0.8

0.6

1.6

1.4

1.2

1.0

0.8

0.6

1.6

1.4

1.2

1.0

0.8

0.6

100 200

10kΩ 20kΩ

300 400 500 100

20kΩ Continuous (24˚C)

200 300 400 500

2kΩ 7.8msec (–10˚C)

1k 10k

24˚C

100k

–10˚C


Discharge time (hr)

Vol

tage

(V

)


Discharge time (hr)

Vol

tage

(V

)


Load (Ω)

Vol

tage

(V

)

1.6

1.4

1.2

1.0

0.8

0.6

1.6

1.5

1.4

1.3

1.2

1.1

1.6

1.4

1.2

1.0

0.8

0.6

200 400 600

15kΩ Conitnuous (24°C)

100 200 300 400 500 1k800 1000

200Ω 5sec (24°C)

200Ω 5sec (–10°C)

100 200 500 2k 5k 10k 20k

24°C

–10°C


Discharge time (hr)

Vol

tage

(V

)


Discharge time (hr)

Vol

tage

(V

)


Load (Ω)

Vol

tage

(V

)

Temp:24°C

15kΩ 30kΩ

1.6

1.4

1.2

1.0

0.8

0.6

1.6

1.4

1.2

1.0

0.8

0.6

1.6

1.5

1.4

1.3

1.2

1.1

20kΩ Continuous (24˚C)

100 200 300 400 500 100 200 300 400 500

200Ω 5sec (24˚C)

200Ω 5sec (–10˚C)

1k100 200 500 2k 5k 10k 20k

24˚C

–10˚C

10kΩ 20kΩ


Discharge time (hr)

Vol

tage

(V

)


Discharge time (hr)

Vol

tage

(V

)


Load (Ω)

Vol

tage

(V

)

Temp:24˚C

26

Environmental Activities at Seiko Instruments Inc. BM Business Unit

SII Group Environmental Policy :

Environmental ConceptSII is concerned about every facet of the global environment and is aiming toward a world

where all living things can exist in harmony together. SII works for the protection of the

environment and its continual improvement in every corporate activity.

SII BM Business Unit is implementing following actions;(These actions are taken mainly at SII Micro Parts Ltd., the manufacturer of BM products)

1. Supply products and services that contribute to an environmental protection.

• Developing and supplying products that can endure the high-temperature reflow process, to promote the lead-

free manufacturing in the market.

• Conducting environmental assessment with every battery product being designed.

• Implemented a collection of used watch and rechargeable batteries, in cooperation with Battery Association of

Japan.

• Facilitating our products to meet ‘SII Green Plan Product Standards’ and targeting 30% of our products to acquire

‘SII Green Product Label’ by end of FY2004.

2. Promote Energy Saving

Saving energy in the manufacturing process;

Taking actions such as switching the source of air conditioning from electricity to gas, reducing CO2 emission

despite of increasing the production efficiency.

In FY2001 CO2 emission was reduced by 23.5%, compared to the volume in FY1990.

CO2

10076.5

FY1990 FY2001

3. Zero Emissions (‘No waste to emit’)

Reduce and Re-use;

Promoting to abolish any toxic or dangerous material, use environment-friendly substitutes and change packag-

ing to re-usable and recyclable material. In FY2001 the total waste disposal (including recycled) was reduced by

52.6%, compared to the volume in FY1997.

Total waste emitted

100

47.4 43

FY1997 FY2001 FY2005Recycling ;

Studying the best method to recycle each waste and converting to the method of more efficient, less faulty,

manufacturing. In FY2001 the total disposed waste was 10 tons, reduced by 86.3%, compared to the volume in

FY1997.

We are striving and taking actions continuously until we achieve ‘Zero Emissions’.

Final disposal of waste

73ton

FY1997 FY2001 End of FY2003

10ton 0ton

4. Green Purchase

Promoting “Green Purchase” action for manufacturing materials. To achieve this, we conduct “Suppliers Structure

Audit” and “Purchased Product Audit” and will extend this action to all materials we purchase.

5. Green Life

Promoting “Green Life” actions; such as cleaning-up campaign in the neighbor area, planting greenery, stop unnec-

essary car-idling campaign, and so on.

27

Check Sheet for Selecting Micro Battery

1. Your company name

2. Which application do you use?

3. Your expected backup period

4. Your requested delivery

5. Operation voltage of the device for backup

6. Consumption current at backup time

7. Setting value of charging voltage

8. Exist of a back current protection diode

9. Vf characteristics of the back current protection diode(at 10µA)

10. Resistance value of charging protection resistance

11. Limit of charging time

12. Necessary number of cycle

13. Other your requests

Please use check sheet below when you select our Micro Battery forselecting the best suited battery for your use.

Fax Sheet

Seiko Instruments Inc. BM Sales Sec. 043-211-8035 Battery Sales Person

hour / day / month

mm / yy

V to V

µA • µA

V

Yes • No

V

Ω

times

Name

Section

Phone

Fax

E-mail

Your contact information

SII Micro Parts Ltd. who manufactures the products described inthis catalog holds the ISO-9001 quality management systemcertificate and the ISO-14001 environmental management sys-tem certificate.

IMPORTANT1. The information herein is subject to change without notice.2. Neither reproduction nor duplication of this catalog in whole or part is allowed without the prior written

approval of Seiko Instruments Inc.3. The colors of the products reproduced herein may be different from the actual colors. Check color on

actual products before using the product.4. Circuits and respective application methods described herein are for reference only. Seiko Instruments

Inc. is not responsible for any and all infringement or damages to the rights of third parties (includingindustrial properties) caused by the use of circuits or application methods herein. Seiko Instruments Inc.shall not license any industrial properties owned by Seiko Instruments Inc. or any third party through thiscatalog.

5. When products described herein include Strategic Products (or Services) stipulated in the ForeignExchange and Trade Control Law, they shall not be exported without permission of governmentalauthorities.

6. The products described herein are designed for consumer equipment and cannot be used as part of anydevice or equipment which influences the human body or requires a significantly high reliability, such asphysical exercise equipment, medical equipment, disaster prevention equipment, gas related equipment,vehicles, aircraft and equipment mounted on vehicles.

No. CAB0210EJ0055-10/C

Released in Oct. 2002

Seiko Instruments Inc.Network Components Business Unit1-8, Nakase, Mihama-ku, Chiba-shi, Chiba 261-8507, JapanTelephone :+81-43-211-1205 Facsimile :+81-43-211-8035E-mail:[email protected] Instruments USA Inc.Electronic Components Div.2990 W. Lomita Blvd., Torrance, CA 90505, U.S.A.Telephone :+1-800-934-9334 Facsimile :+1-909-975-5699E-mail :[email protected]://www.seiko-usa-ecd.comSeiko Instruments GmbHSiemensstraße 9, D -63263 Neu-Isenburg, GermanyTelephone :+49-6102-297-0 Facsimile :+49-6102-297-320E-mail :[email protected]://www.seiko-instruments.deSeiko Instruments France S.A.R.L.55, Rue d` Aguesseau, 92774, Boulogne Billancourt, Cedex, FranceTelephone :+33-1-41-31-71-30 Facsimile :+33-1-41-31-71-39E-mail :[email protected]://www.seiko-instruments.frSeiko Instruments (H.K.) Ltd.4-5 / F, Wyler Centre 2,200 Tai Lin Pai Road, Kwai Chung,N.T., Kowloon, Hong KongTelephone :+852-2421-8611 Facsimile :+852-2480-5479E-mail :[email protected]://www.sih.com.hkSeiko Instruments Taiwan Inc.4FL, No.40, Sec. 2, Min-Chuan E. Rd., Taipei 104, Taiwan, R.O.C.Telephone :+886-2-2563-5001 Facsimile :+886-2-2521-9519E-mail :[email protected]://www.sii.com.twSeiko Instruments Singapore Pte. Ltd.2, Marsiling Lane, Woodlands New Town, Singapore 739144Telephone :+65-6269-1370 Facsimile :+65-6269-9729http://www.sii.com.sg

(Specification are subject to change without notice.)

www.sii.co.jp/compo

printed on 100% recycled paper and with soy ink.

Network Business Unit Micro Batteries - ABCDEOur microbatteries have a stable operating voltage over...

Documents

Transcript of Network Business Unit Micro Batteries - ABCDEOur microbatteries have a stable operating voltage over...