Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy...
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Transcript of Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy...
![Page 1: Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy 20Interface%20Spring%2005.pdf.](https://reader036.fdocuments.in/reader036/viewer/2022062322/56649e7b5503460f94b7cd8d/html5/thumbnails/1.jpg)
Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy
http://www.phi.com/Interface/PHI%20Interface%20Spring%2005.pdf
![Page 2: Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy 20Interface%20Spring%2005.pdf.](https://reader036.fdocuments.in/reader036/viewer/2022062322/56649e7b5503460f94b7cd8d/html5/thumbnails/2.jpg)
What is Nanotechnology?
Nanoscale science: investigates the properties of matter in the critcal range of 1nm – 100 nm.
Nanotechnology: Is building and using devices from 1 nm – 100 nm.
Nano = 10-9
![Page 3: Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy 20Interface%20Spring%2005.pdf.](https://reader036.fdocuments.in/reader036/viewer/2022062322/56649e7b5503460f94b7cd8d/html5/thumbnails/3.jpg)
What Leads to Unsual Properties?
Any solid or liquid has 2 components:
•surface
•bulk
![Page 4: Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy 20Interface%20Spring%2005.pdf.](https://reader036.fdocuments.in/reader036/viewer/2022062322/56649e7b5503460f94b7cd8d/html5/thumbnails/4.jpg)
The Macroscopic Case
One drop of water:
100,000 bulk molecules per
1 surface molecule
![Page 5: Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy 20Interface%20Spring%2005.pdf.](https://reader036.fdocuments.in/reader036/viewer/2022062322/56649e7b5503460f94b7cd8d/html5/thumbnails/5.jpg)
Another Example...
•2 surface layers vs. ~10,000,000 internal layers
•2 surface layers vs. ~5,000,000 internal layers
•Percentage of surface:
0.000002% vs 0.000004%
![Page 6: Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy 20Interface%20Spring%2005.pdf.](https://reader036.fdocuments.in/reader036/viewer/2022062322/56649e7b5503460f94b7cd8d/html5/thumbnails/6.jpg)
Shrinking Down to the Nanoscale
5%
10%
50%
100%
Properties of surface atoms/molecules now
affect the overall properties.
C60
![Page 7: Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy 20Interface%20Spring%2005.pdf.](https://reader036.fdocuments.in/reader036/viewer/2022062322/56649e7b5503460f94b7cd8d/html5/thumbnails/7.jpg)
Properties Change According to Size!
Different sizes of gold particles = different optical properties.
![Page 8: Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy 20Interface%20Spring%2005.pdf.](https://reader036.fdocuments.in/reader036/viewer/2022062322/56649e7b5503460f94b7cd8d/html5/thumbnails/8.jpg)
• Nano is all about surface!• Surfaces are thin.• Most surface coatings are
organic.
Boyen, H.-G.; Kastle, G.; Weigl, F. et al. Science 2002, 297, 1533-1536.
Nanoparticle Surfaces: What’s the Problem?
![Page 9: Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy 20Interface%20Spring%2005.pdf.](https://reader036.fdocuments.in/reader036/viewer/2022062322/56649e7b5503460f94b7cd8d/html5/thumbnails/9.jpg)
http://www.almaden.ibm.com/st/scientific_services/materials_analysis/xps/
XPS: How Does it Work?
X-Ray
ejected electron
KEelectron = hX-ray – BEelectron
![Page 10: Nanoparticle Surface Characterization by X-Ray Photoelectron Spectroscopy 20Interface%20Spring%2005.pdf.](https://reader036.fdocuments.in/reader036/viewer/2022062322/56649e7b5503460f94b7cd8d/html5/thumbnails/10.jpg)
XPS Spectrometer: Basic Components
Settle, F., ed. Handbook of Instrumental Techniques for Analytical Chemistry. Prentice Hall. 1997.
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300 295 290 285 280 275
0
200
400
600
800
1000
1200
Co
un
ts /
s
C(1s) Binding Energy (eV)
Peak Position Area % C1s Carbon- ID
1 285.50 1457.1 52% Pristine C60
2 287.45 489.75 18% Mono-oxidized C
3 289.73 836.67 30% Di-oxidized C