9.1 IUPAC Nomenclature of Alcohols, Ethers and Phenols 9.1.1 Naming Alcohols
Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with...
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Transcript of Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with...
![Page 1: Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with the general formula; C n H 2n+1 OH A suffix, -ol,](https://reader035.fdocuments.in/reader035/viewer/2022062222/5697c0141a28abf838ccd388/html5/thumbnails/1.jpg)
Naming and physical properties of alcohols.
![Page 2: Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with the general formula; C n H 2n+1 OH A suffix, -ol,](https://reader035.fdocuments.in/reader035/viewer/2022062222/5697c0141a28abf838ccd388/html5/thumbnails/2.jpg)
Naming alcohols
Alcohols are an homologous series
with the general formula; CnH2n+1OH
A suffix, -ol, is used to indicate the presence of an hydroxyl group.
Eg; CH3CH(OH)CH3 propan- 2-ol
![Page 3: Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with the general formula; C n H 2n+1 OH A suffix, -ol,](https://reader035.fdocuments.in/reader035/viewer/2022062222/5697c0141a28abf838ccd388/html5/thumbnails/3.jpg)
Classifying alcohols
Look at the number of alkyl groups attatched to the carbon which bears the hydroxyl group.
![Page 4: Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with the general formula; C n H 2n+1 OH A suffix, -ol,](https://reader035.fdocuments.in/reader035/viewer/2022062222/5697c0141a28abf838ccd388/html5/thumbnails/4.jpg)
Primary alcohols
Have ONE alkyl group on the carbon that bears the hydroxyl group.
R
Eg; CH3CH2OH
![Page 5: Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with the general formula; C n H 2n+1 OH A suffix, -ol,](https://reader035.fdocuments.in/reader035/viewer/2022062222/5697c0141a28abf838ccd388/html5/thumbnails/5.jpg)
Secondary alcohols
Have TWO alkyl groups on the carbon with the hydroxyl group.
R
R(CH3)2CHOH
![Page 6: Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with the general formula; C n H 2n+1 OH A suffix, -ol,](https://reader035.fdocuments.in/reader035/viewer/2022062222/5697c0141a28abf838ccd388/html5/thumbnails/6.jpg)
Tertiary alcohols
Have THREE alkyl groups on the carbon with the hydroxyl group.
RR
R
(CH3)3COH
![Page 7: Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with the general formula; C n H 2n+1 OH A suffix, -ol,](https://reader035.fdocuments.in/reader035/viewer/2022062222/5697c0141a28abf838ccd388/html5/thumbnails/7.jpg)
Name the following alcohols, stating whether they are primary, secondary or
tertiary;
• CH3OH
• CH3CH2CH(OH)CH
3
• (CH3)2(C2H5)COH
• CH3C(CH3)2CH2OH
• Methanol (1o)• Butan 2 ol (2O)• 2 methyl butan 2
ol (3O)• 2,2 dimethyl
propan 1 ol (1o)
![Page 8: Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with the general formula; C n H 2n+1 OH A suffix, -ol,](https://reader035.fdocuments.in/reader035/viewer/2022062222/5697c0141a28abf838ccd388/html5/thumbnails/8.jpg)
Draw out the structures of the following alcohols, stating whether they are
primary, secondary or tertiary;
• Heptan 1 ol• 2,2 dimethyl
hexan 3 ol• 4 methyl octan 4
ol
• CH3(CH2)5CH2OH
• (1o)• (CH3)3 CH(OH)
(CH2)2CH3
• (2O)• CH3(CH2)2CH(OH)
(CH2)2 CH3
• (3O)
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Boiling points
Alkane BP oC Alcohol BP oC
methane -163.4 methanol 65
ethane -88.5 ethanol 78
propane -42 propanol 98
butane -0.4 butanol 117
pentane 36.2 pentanol 138
Plot BP against Mr and comment on the trends.
![Page 10: Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with the general formula; C n H 2n+1 OH A suffix, -ol,](https://reader035.fdocuments.in/reader035/viewer/2022062222/5697c0141a28abf838ccd388/html5/thumbnails/10.jpg)
BPs of alkanes and alcohols compared
0
100
200
300
400
500
600
700
800
900
C1 C2 C3 C4 C5 C6
Number of carbons
BP
(K) alcohol
alkane
Alcohols have much higher BPs than those of the corresponding alkane.
The intermolecular bonds in alkanes are only weak van der Waals.
But in alcohols there are much stronger hydrogen bonds.
BPs of alcohols compared with those of alkanes.
![Page 11: Naming and physical properties of alcohols.. Naming alcohols Alcohols are an homologous series with the general formula; C n H 2n+1 OH A suffix, -ol,](https://reader035.fdocuments.in/reader035/viewer/2022062222/5697c0141a28abf838ccd388/html5/thumbnails/11.jpg)
Solubility of alcohols
Alcohols are miscible in
water.
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δ-
δ+
δ-
δ+
δ-δ+
δ+ δ+The hydroxyl group can hydrogen bond with water.
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Solubility decreases with chain length.
But hydrocarbon chains can only make van der Waals interactions.
The hydroxyl group can hydrogen bond…