Unsaturated Hydrocarbons Double and Triple bonds between Carbons.
Mullis1 Hydrocarbons Unsaturated hydrocarbons –Double and triple bonds between carbons –Not...
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![Page 1: Mullis1 Hydrocarbons Unsaturated hydrocarbons –Double and triple bonds between carbons –Not every carbon has each of its 4 electrons bonded to 4 different.](https://reader036.fdocuments.in/reader036/viewer/2022083005/56649f1b5503460f94c31608/html5/thumbnails/1.jpg)
Mullis 1
HydrocarbonsUnsaturated hydrocarbons
– Double and triple bonds between carbons
– Not every carbon has each of its 4 electrons bonded to 4 different atoms
– More chemically reactive than saturated compounds, or alkanes
– Unsaturated hydrocarbons include alkenes (double bonds) and alkynes (triple bonds)
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Mullis 2
Naming Organic Compounds1. Name the parent hydrocarbon: Use the
LONGEST STRAIGHT chain of carbon atoms.2. Add the name of the alkyl groups attached to the
chain. If more than one group is attached, use the proper numerical prefix to indicate how many groups are attached. (2=di, 3-tri,etc.)
3. Assign numbers to the carbons in the parent chain. Assign so that attached groups are at the lowest number possible.
4. Insert the numbers in front of the proper group.5. Separate position numbers from names with
hyphens.
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Mullis 3
Example: Naming Organic Compounds1. Name the parent hydrocarbon.
CH3 – CH – CH2 – CH – CH – CH3 hexane
CH3 CH3 CH3
2. Add the name of the alkyl groups attached to the chain. 3 methyl groups: trimethylhexane 3. Assign numbers to the carbons in the parent chain.6 5 4 3 2 1
CH3 – CH – CH2 – CH – CH – CH3
CH3 CH3 CH3
4-5. Insert position numbers and add hyphens.2,3,5-trimethylhexane
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Mullis 4
Name the following compounds1. CH3 – CH – CH2 – CH2 – CH3
CH3
2. CH3 – CH – CH2 – CH2 – CH – CH3
| |
CH3 CH3
3. CH3 – CH – CH2 – CH2 – CH3
CH2
CH2
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Mullis 5
Unsaturated hydrocarbons
• Single bond between carbons: -ane CnH2n+1
• Double bond between carbons: -ene CnH2n
• Triple bond between carbons: -yne CnHn
• Examples:
C
H
HH C
HH
H
ethaneC2H6
C CH H
H H
etheneC2H4
CCH H
ethyneC2H2
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Mullis 6
Other Functional GroupsCompound Formula Example
Alcohol R-OH hydroxyl group 1-propanol
Alkyl Halide -X X = any halide 1,2-dibromopropane
Ether R-O-R’ one oxygen bonded to 2 hydrocarbon groups
diethyl ether CH3-CH2 –O--CH2--CH3
Aldehyde O ||R-C-H
Carbonyl group attached to end carbon
Ethanal O || CH3—C--H
Ketone O ||R-C-R’
Carbonyl group attached to a middle carbon
2-propanone O || CH3—C-- CH3
Carboxylic Acid O ||R-C-OH
Carboxyl group ethanoic acid O || CH3—C—OH
Ester O ||R-C-O-R’
Carboxyl group without the H
methyl ethanoate O || CH3—C—O-- CH3
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Mullis 7
Cyclic Compounds• Cycloalkanes
– Saturated carbons joined in a ring
– Example is cyclohexane, C6H12
– Add cyclo- to beginning of name if the alkane is known to be arranged in a circle (CnH2n). No position number is needed if only one alkyl group is attached.
• Aromatic compounds– Unsaturated: Contains 3 double bonds
– Example is benzene, C6H6
C-H
C-H
C-H
H-C
H-C
H-Cbenzene1-ethyl-4-methylbenzene
CH3CH2- -CH3
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Mullis 8
Addition Reactions• Water adds to ethene: The double bond is broken and
an H attaches to one carbon and the OH attaches to the other carbon.
H H H H
C C + H-OH H-C-C-H
H H H H• Ethene can add to itself, breaking double bonds to
attach to one molecule after another.
• A monomer is a small unit; when additional monomers are attached repeatedly, a long-chain polymer is formed.
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Mullis 9
Addition Polymers• Polyethylene is a polymer made from the monomer
ethene. Zip-lock bags are usually made from low-density polyethylene.
• Common polymer variations replace one of ethene’s hydrogens with another unit, such as a halogen atom (F or Cl), Cyanide (CN), or benzene (C6H6).
– Vinyl chloride polyvinyl chloride– Acrylonitrile polyacrylnitrile– Styrene polystyrene
• Atoms that compose the monomers determine the properties of the polymer.
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Mullis 10
Petrochemicals• Petrochemicals are compounds produced from
oil or natural gas.
• Most are used to produce other synthetic products, especially plastics.
• Builder molecules are those small-molecule compounds such as ethene.
• Ethene is a 2-carbon hydrocarbon with a double bond (2 pairs of shared electrons).
• Compounds with double and triple bonds are more reactive than those with single bonds.