MSDS

p. 1

1 2 0

He a lt h

Fire

Re a c t iv it y

Pe rs o n a lPro t e c t io n

2

1

0

E

Material Safety Data SheetAmmonium sulfate MSDS

Section 1: Chemical Product and Company Identification

Product Name: Ammonium sulfate

Catalog Codes: SLA2851, SLA2011, SLA1168, SLA2674CAS#: 7783-20-2

RTECS: BS4500000

TSCA: TSCA 8(b) inventory: Ammonium sulfateCI#: Not available.

Synonym: Sulfluric Acid, Diammonium Salt

Chemical Name: Ammonium Sulfate

Chemical Formula: (NH4)2SO4

Contact Information:Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396US Sales: 1-800-901-7247International Sales: 1-281-441-4400Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300

International CHEMTREC, call: 1-703-527-3887

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on IngredientsComposition:

Name CAS # % by WeightAmmonium sulfate 7783-20-2 100

Toxicological Data on Ingredients: Ammonium sulfate: ORAL (LD50): Acute: 2840 mg/kg [Rat]. 640 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention.Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medicalattention.

p. 2

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.

Serious Inhalation: Not available.Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.Auto-Ignition Temperature: Not available.Flash Points: CLOSED CUP: Higher than 93.3C (200F).Flammable Limits: Not available.

Products of Combustion: Not available.Fire Hazards in Presence of Various Substances:Flammable in presence of oxidizing materials. Slightly flammable to flammable in presence of heat.Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Explosive in presence of oxidizing materials.Fire Fighting Media and Instructions:SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.Special Remarks on Fire Hazards:A mixture of ammonium sulfate and potassium chlorate decomposes with incandescence when heated. When a littleammonium sulfate is added to fused potassium nitrite, a vigorous reaction occurs attended by flame. Non combustible. Thissubstance itself does not burn, but may decompose upon heating to produce corrosive and/or toxic fumes.Special Remarks on Explosion Hazards:If accidently mixed with oxidizers like potassium chlorate, potassium nitrate or potassium nitrite, there is an explosion hazardduring fire. A mixture of ammonium sulfate and ammonium nitrate can easily be exploded by potassium or sodium-potassiumalloy.

Section 6: Accidental Release Measures

Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water onthe contaminated surface and dispose of according to local and regional authority requirements.Large Spill:Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on thecontaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:

p. 3

Keep away from heat. Keep away from sources of ignition. Do not ingest. Do not breathe dust. Wear suitable protectiveclothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediatelyand show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizingagents.Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommendedexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminantsbelow the exposure limit.Personal Protection:Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystals solid.)Odor: Odorless.Taste: Not available.

Molecular Weight: 132.14 g/moleColor: brownish gray to whitepH (1% soln/water): Not available.Boiling Point: Not available.Melting Point: 280C (536F)Critical Temperature: Not available.Specific Gravity: 1.77 (Water = 1)Vapor Pressure: Not applicable.Vapor Density: Not available.Volatility: Not available.Odor Threshold: Not available.Water/Oil Dist. Coeff.: Not available.Ionicity (in Water): Not available.Dispersion Properties: See solubility in water.Solubility:Soluble in cold water. Insoluble in acetone.

Section 10: Stability and Reactivity Data

p. 4

Stability: The product is stable.Instability Temperature: Not available.Conditions of Instability: Excess heat, incompatible materials.Incompatibility with various substances:Highly reactive with oxidizing agents. Reactive with alkalis.Corrosivity: Non-corrosive in presence of glass.Special Remarks on Reactivity:Incompatible with the following: Potassium + ammonium nitrate, potassium chlorate, potassium nitrate, potassium nitrite,sodium hypochlorite, sodium/potassium alloy + ammonium nitrate. Substance should not contact either zinc or copper bearingmaterials. Reacts with alkali to release ammonia.

Special Remarks on Corrosivity: Not available.Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.Toxicity to Animals: Acute oral toxicity (LD50): 640 mg/kg [Mouse].Chronic Effects on Humans: Not available.Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose/Conc: LDL [Domestic animal - Goat, Sheep) - Route: Oral; Dose: 3500 mg/kgSpecial Remarks on Chronic Effects on Humans:It may be a possible mutagen. It has been tested for mutagenicity, but so far tests have been inconclusive or test informationhas not been made available.Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation. Inhalation: May cause respiratory tractirritation. Ingestion: When ingested, its osmolarity can draw water from the body into the bowel, acting as a laxative. However,if enough is absorbed systemically it may produce Ammonia poisoning. Symptoms may include gastrointestinal (digestive)tract irritation with nausea, vomiting, hypermotility, diarrhea. May also affect eyes (Mydriasis), behavior/central nervous system(somnolence, tremor, convulsions, muscle contraction or spasticity), and respiratory system (respiratory stimulation, dyspnea).Also, with ingestion of large doses of Ammonium Sulfate arises the possibility of sufficient absorption to produce diuresis, anexcessive discharge of urine, and kidney damage (renal tubular disorder, abnormal renal function). Chronic Potential HealthEffects: One Russian occupational standard study discussed chronic exposure effects which may include cardiac contraction,neurotoxicity, and hypertension. This has not been confirmed in other ammonium sulfate exposed workers.

Section 12: Ecological Information

Ecotoxicity: Not available.BOD5 and COD: Not available.Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

p. 5

Waste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).Identification: Not applicable.

Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations:Rhode Island RTK hazardous substances: Ammonium sulfate Pennsylvania RTK: Ammonium sulfate Florida: Ammoniumsulfate Massachusetts RTK: Ammonium sulfate New Jersey: Ammonium sulfate TSCA 8(b) inventory: Ammonium sulfateOther Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.Other Classifications:WHMIS (Canada): Not controlled under WHMIS (Canada).DSCL (EEC):R16- Explosive when mixed with oxidizing substances. R36/38- Irritating to eyes and skin. S24/25- Avoid contact with skin andeyes.

HMIS (U.S.A.):Health Hazard: 2

Fire Hazard: 1

Reactivity: 0

Personal Protection: E

National Fire Protection Association (U.S.A.):Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:Protective Equipment:Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.Created: 10/10/2005 08:14 PMLast Updated: 11/01/2010 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume

p. 6

no liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

p. 1

0 2 0

He a lt h

Fire

Re a c t iv it y


2

0

0

G

Material Safety Data SheetBarium Chloride TS MSDS


Product Name: Barium Chloride TS

Catalog Codes: SLB2362CAS#: Mixture.

RTECS: Not applicable.

TSCA: TSCA 8(b) inventory: Barium chloride dihydrate;Water

CI#: Not available.

Synonym: Barium Chloride Test Solution

Chemical Name: Not applicable.

Chemical Formula: Not applicable.






Name CAS # % by WeightBarium chloride dihydrate 10326-27-9 12Water 7732-18-5 88

Toxicological Data on Ingredients: Barium chloride dihydrate: ORAL (LD50): Acute: 76 mg/kg [Guinea pig]. 118 mg/kg [Rat].300 mg/kg [Rat].


Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Slightly hazardous in case of skin contact(permeator).Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to kidneys, the nervous system, peripheral nervoussystem, cardiovascular system, upper respiratory tract, central nervous system (CNS). The substance may be toxic to liver.Repeated or prolonged exposure to the substance can produce target organs damage.


p. 2

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention if irritation occurs.Skin Contact:Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold watermay be used.Serious Skin Contact: Not available.Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.

Serious Inhalation: Not available.Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,tie, belt or waistband.

Serious Ingestion: Not available.


Flammability of the Product: Non-flammable.Auto-Ignition Temperature: Not applicable.Flash Points: Not applicable.Flammable Limits: Not applicable.Products of Combustion: Not available.Fire Hazards in Presence of Various Substances: Not applicable.Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.Fire Fighting Media and Instructions: Not applicable.Special Remarks on Fire Hazards: Not available.Special Remarks on Explosion Hazards: Not available.


Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authorityrequirements.Large Spill:Absorb with an inert material and put the spilled material in an appropriate waste disposal. Be careful that the product is notpresent at a concentration level above TLV. Check TLV on the MSDS and with local authorities.


Precautions:

p. 3

Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation,wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes.Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.


Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value.

Personal Protection: Safety glasses. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator orequivalent.Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.Exposure Limits:Barium chloride dihydrate TWA: 0.5 (mg(Ba)/m) from ACGIH (TLV) [United States] Consult local authorities for acceptableexposure limits.


Physical state and appearance: Liquid.Odor: Odorless.Taste: Not available.

Molecular Weight: Not applicable.Color: Clear Colorless.pH (1% soln/water): Not availableBoiling Point: The lowest known value is 100C (212F) (Water).Melting Point: Not available.Critical Temperature: Not available.Specific Gravity: 1.2031 (Water = 1)Vapor Pressure: The highest known value is 2.3 kPa (@ 20C) (Water).Vapor Density: The highest known value is 0.62 (Air = 1) (Water).Volatility: Not available.Odor Threshold: Not available.Water/Oil Dist. Coeff.: Not available.Ionicity (in Water): Not available.Dispersion Properties: See solubility in water, methanol.Solubility:Easily soluble in cold water, hot water. Soluble in methanol. Insoluble in acetone.


p. 4

Stability: The product is stable.Instability Temperature: Not available.Conditions of Instability: Not available.Incompatibility with various substances: Not available.Corrosivity: Non-corrosive in presence of glass.Special Remarks on Reactivity: Not available.Special Remarks on Corrosivity: Not available.Polymerization: Will not occur.


Routes of Entry: Absorbed through skin. Eye contact. Ingestion.Toxicity to Animals:LD50: Not available. LC50: Not available.Chronic Effects on Humans: Not available.Other Toxic Effects on Humans:Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).Special Remarks on Toxicity to Animals: Not available.Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects. May affect genetic material(mutagenic) (Barium chloride dihydrate)Special Remarks on other Toxic Effects on Humans: Not available.


Ecotoxicity: Not available.BOD5 and COD: Not available.Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.Special Remarks on the Products of Biodegradation: Not available.




DOT Classification: Not a DOT controlled material (United States).Identification: Not applicable.Special Provisions for Transport: Marine Pollutant

p. 5


Federal and State Regulations: TSCA 8(b) inventory: WaterOther Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).Other Classifications:

WHMIS (Canada): Not controlled under WHMIS (Canada).DSCL (EEC):R22- Harmful if swallowed. S2- Keep out of the reach of children. S46- If swallowed, seek medical advice immediately andshow this container or label.


Fire Hazard: 0

Reactivity: 0

Personal Protection: g


Flammability: 0

Reactivity: 0

Specific hazard:

Protective Equipment:Not applicable. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriaterespirator when ventilation is inadequate. Safety glasses.



Other Special Considerations: Not available.

Created: 10/10/2005 12:51 AM

Last Updated: 11/01/2010 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

p. 1

0 1 0

He a lt h

Fire

Re a c t iv it y


1

0

0

G

Material Safety Data SheetBorax Solution 1% (w/v) MSDS


Product Name: Borax Solution 1% (w/v)Catalog Codes: SLB3373CAS#: Mixture.


TSCA: TSCA 8(b) inventory: Sodium borate; WaterCI#: Not available.

Synonym:

Chemical Name: Borax Solution 1% (w/v)Chemical Formula: Not applicable.






Name CAS # % by WeightSodium borate 1303-96-4 1Water 7732-18-5 99

Toxicological Data on Ingredients: Sodium borate: ORAL (LD50): Acute: 2660 mg/kg [Rat.].


Potential Acute Health Effects:Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Non-corrosive for skin.

Potential Chronic Health Effects:Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes.Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Notavailable.


p. 2

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention if irritation occurs.Skin Contact:Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold watermay be used.

Serious Skin Contact: Not available.Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.



Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion: Not available.Fire Hazards in Presence of Various Substances: Not applicable.Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.Fire Fighting Media and Instructions: Not applicable.Special Remarks on Fire Hazards: Not available.Special Remarks on Explosion Hazards: Not available.


Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Ifnecessary: Neutralize the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminatedsurface and dispose of according to local and regional authority requirements.Large Spill:Absorb with an inert material and put the spilled material in an appropriate waste disposal. Neutralize the residue with a dilutesolution of acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through thesanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS andwith local authorities.


p. 3

Precautions:Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation,wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label.Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.


Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value.Personal Protection: Safety glasses. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator orequivalent.Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.Exposure Limits:Sodium borate TWA: 0.31 TWA: 5 from ACGIH (TLV) [United States] [1995] Consult local authorities for acceptable exposurelimits.


Physical state and appearance: Liquid.Odor: Not available.Taste: Not available.Molecular Weight: Not applicable.Color: Not available.pH (1% soln/water): Basic.Boiling Point: The lowest known value is 100C (212F) (Water).Melting Point: Not available.Critical Temperature: Not available.Specific Gravity: Weighted average: 1 (Water = 1)Vapor Pressure: The highest known value is 2.3 kPa (@ 20C) (Water).Vapor Density: The highest known value is 0.62 (Air = 1) (Water).Volatility: Not available.Odor Threshold: Not available.Water/Oil Dist. Coeff.: Not available.Ionicity (in Water): Not available.Dispersion Properties: See solubility in water.Solubility:Easily soluble in cold water, hot water. Insoluble in methanol.


p. 4

Stability: The product is stable.Instability Temperature: Not available.Conditions of Instability: Not available.Incompatibility with various substances: Non-reactive with oxidizing agents.Corrosivity: Non-corrosive in presence of glass.Special Remarks on Reactivity: Not available.Special Remarks on Corrosivity: Not available.Polymerization: Will not occur.


Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.Toxicity to Animals: Acute oral toxicity (LD50): 266000 mg/kg (Rat.) (Calculated value for the mixture).Chronic Effects on Humans: Not available.Other Toxic Effects on Humans:Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of ingestion.Special Remarks on Toxicity to Animals: Not available.Special Remarks on Chronic Effects on Humans: Not available.Special Remarks on other Toxic Effects on Humans: Ingestion of 5-10 grams has produced severe vomiting, diarrhea,shock and death. (Sodium borate)




Waste Disposal:


DOT Classification: Not a DOT controlled material (United States).Identification: Not applicable.Special Provisions for Transport: Not applicable.


p. 5

Federal and State Regulations:Pennsylvania RTK: Sodium borate Massachusetts RTK: Sodium borate TSCA 8(b) inventory: Sodium borate; WaterOther Regulations: Not available. or of its ingredientsOther Classifications:

WHMIS (Canada): Not controlled under WHMIS (Canada).DSCL (EEC):This product is not classified according to the EU regulations.


Fire Hazard: 0

Reactivity: 0

Personal Protection: g


Flammability: 0

Reactivity: 0

Specific hazard:

Protective Equipment:Not applicable. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.



Other Special Considerations: Not available.

Created: 10/10/2005 12:52 AM

Last Updated: 11/01/2010 12:00 PM


p. 1

0 2 0

He a lt h

Fire

Re a c t iv it y


2

0

0

H

Material Safety Data SheetCopper Sulfate solution MSDS


Product Name: Copper Sulfate solution

Catalog Codes: SLC1300CAS#: Mixture.


TSCA: TSCA 8(b) inventory: No products were found.CI#: Not applicable.

Synonym: Copper Sulfate Solution








Name CAS # % by WeightWater 7732-18-5 91.8

Copper sulfate pentahydrate 7758-99-8 8.23

Toxicological Data on Ingredients: Copper sulfate pentahydrate: ORAL (LD50): Acute: 300 mg/kg [Rat.]. DERMAL (LD50):Acute: >2000 mg/kg [Rat].


Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant). Slightly hazardous in case of ingestion, . Non-corrosive forskin.Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Copper sulfatepentahydrate]. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance maybe toxic to kidneys, liver. Repeated or prolonged exposure to the substance can produce target organs damage. Repeatedexposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many humanorgans.


p. 2

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention.Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medicalattention.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.



Flammability of the Product: Non-flammable.Auto-Ignition Temperature: Not applicable.Flash Points: Not applicable.Flammable Limits: Not applicable.Products of Combustion: Not available.Fire Hazards in Presence of Various Substances: Not applicable.Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks,of heat.

Fire Fighting Media and Instructions: Not applicable.Special Remarks on Fire Hazards: Not available.Special Remarks on Explosion Hazards: Nitromethanes and copper salts spontaneously form explosive materials (Coppersulfate pentahydrate)


Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authorityrequirements.Large Spill:Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading wateron the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at aconcentration level above TLV. Check TLV on the MSDS and with local authorities.


p. 3

Precautions:Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation,wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes.Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.



Personal Protection:Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.Exposure Limits:Copper sulfate pentahydrate TWA: 1 (mg/m3) from ACGIH (TLV) [United States] Inhalation TWA: 0.1 (mg/m3) from OSHA(PEL) [United States] Inhalation TWA: 1 (mg/m3) from NIOSH InhalationConsult local authorities for acceptable exposurelimits.


Physical state and appearance: Liquid.Odor: Not available.Taste: Not available.

Molecular Weight: Not applicable.Color: Blue.pH (1% soln/water): Not availableBoiling Point: The lowest known value is 100C (212F) (Water).Melting Point: Not available.Critical Temperature: Not available.Specific Gravity: 1.053 (Water = 1)Vapor Pressure: The highest known value is 2.3 kPa (@ 20C) (Water).Vapor Density: The highest known value is 0.62 (Air = 1) (Water).Volatility: Not available.Odor Threshold: Not available.Water/Oil Dist. Coeff.: Not available.Ionicity (in Water): Not available.Dispersion Properties: See solubility in water, methanol.Solubility:Easily soluble in cold water, hot water. Partially soluble in methanol.

p. 4


Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Incompatible materials

Incompatibility with various substances: Slightly reactive to reactive with metals, alkalis.Corrosivity: Corrosive in presence of steel.

Special Remarks on Reactivity:Air Sensitive. Solutions of hyprobromite are decomposed by powerful catalytic action of cupric ions, even as impurities.Incompatible with finely powdered metals. (Copper sulfate pentahydrate)Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.


Routes of Entry: Absorbed through skin. Eye contact.Toxicity to Animals:Acute oral toxicity (LD50): 3641 mg/kg (Rat.) (Calculated value for the mixture). Acute dermal toxicity (LD50): 25485 mg/kg(Rat) (Calculated value for the mixture).Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Copper sulfate pentahydrate]. Contains material which maycause damage to the following organs: kidneys, liver.Other Toxic Effects on Humans:Hazardous in case of skin contact (irritant). Slightly hazardous in case of ingestion, of inhalation.Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LDL [Human] - Route: Oral; Dose: 1088 mg/kg (Copper sulfate pentahydrate)Special Remarks on Chronic Effects on Humans: May affect genetic material based on animal data (Copper sulfatepentahydrate)Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation. Inhalation: May cause respiratory tractirritation. Ingestion: May be harmful if swallowed. May cause gastrointestinal tract irritation with nausea, vomiting, diarrhea.May affect metabolism, liver (jaundice), blood (Methemoglobin, hemalytic anemia), urinary system (kidneys), behavior/nervoussystems (somnolence, coma), cardiovascular system (lowering of blood pressure)


Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.Special Remarks on the Products of Biodegradation:If released to soil, copper sulfate may leach to groundwater, be partly oxidized, or bind to humic materials, clay, or hydrousof iron and manganese. In water, it will bind to carbonates as well as humic materials, clay and hydrous oxides of iron andmanganese. Copper is accumulated by plants and animals, but it does not appear to biomagnify from plants to animals. This

p. 5

lack of biomagnification appears common with heavy metals. In air, copper aerosols (in general) have a residence time of 2 to10 days in an unpolluted atmosphere and 0.1 to >4 in a polluted, urban areas. (Copper sulfate pentahydrate)




DOT Classification: Not a DOT controlled material (United States).Identification: Not applicable.

Special Provisions for Transport: Not applicable.


Federal and State Regulations:TSCA 8(b) inventory: Water SARA 313 toxic chemical notification and release reporting: Copper compounds CERCLA:Hazardous substances.: Copper sulfate pentahydrate: 10 lbs. (4.536 kg);Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).Other Classifications:WHMIS (Canada): Not controlled under WHMIS (Canada).DSCL (EEC):This product is not classified according to the EU regulations. Not applicable.HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 0

Reactivity: 0

Personal Protection: h


Flammability: 0

Reactivity: 0

Specific hazard:Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.



Other Special Considerations: Not available.Created: 10/10/2005 01:00 AM

p. 6

Last Updated: 11/01/2010 12:00 PM


Material Safety Data Sheet Page 1 of 2

2008, Scholar Chemistry. All Rights Reserved. 9/19/2009

Glucose Monohydrate MSDS # 308.10 Section 1: Product and Company Identification

Glucose Monohydrate Synonyms/General Names: D-Glucose Monohydrate; Dextrose Monohydrate Product Use: For educational use only Manufacturer: Columbus Chemical Industries, Inc., Columbus, WI 53925.

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800-424-9300 CANUTEC (Canada): 613-424-6666

ScholAR Chemistry; 5100 W. Henrietta Rd, Rochester, NY 14586; (866) 260-0501; www.Scholarchemistry.com

Section 2: Hazards Identification White crystalline powder; no odor. HMIS (0 to 4) This material is not considered hazardous. Target organs: None known. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Section 3: Composition / Information on Ingredients Dextrose, monohydrate (5996-10-1), 100% Section 4: First Aid Measures

Always seek professional medical attention after first aid measures are provided. Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally. Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing. Ingestion: Call Poison Control immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately. Inhalation: Remove to fresh air. If not breathing, give artificial respiration.

Section 5: Fire Fighting Measures Nonflammable solid. When heated to decomposition, emits acrid fumes. 0 Protective equipment and precautions for firefighters: Use foam or dry chemical to extinguish fire. 0 0

Firefighters should wear full fire fighting turn-out gear and respiratory protection (SCBA). Cool container with water spray. Material is not sensitive to mechanical impact or static discharge.

Section 6: Accidental Release Measures Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Sweep up spill and place in sealed bag or container for disposal. Wash spill area after pickup is complete. See Section 13 for disposal information.

Section 7: Handling and Storage Green Handling: Use with adequate ventilation and do not breathe dust or vapor. Avoid contact with skin, eyes, or clothing. Wash

hands thoroughly after handling. Storage: Store in General Storage Area [Green Storage] with other items with no specific storage hazards. Store in a cool, dry,

well-ventilated, locked store room away from incompatible materials.

Section 8: Exposure Controls / Personal Protection Use ventilation to keep airborne concentrations below exposure limits. Have approved eyewash facility, safety shower, and fire extinguishers readily available. Wear chemical splash goggles and chemical resistant clothing such as gloves and aprons. Wash hands thoroughly after handling material and before eating or drinking. Use NIOSH-approved respirator with an dust cartridge. Exposure guidelines: Dextrose: OSHA PEL: Not Available, ACGIH: TLV: Not Available, STEL: Not Available.

Health 0 Fire Hazard 0 Reactivity 0

Material Safety Data Sheet Page 2 of 2

2008, Scholar Chemistry. All Rights Reserved. 9/19/2009

MSDS # 308.10 Glucose Monohydrate Scholar Chemistry Section 9: Physical and Chemical Properties Molecular formula C6H12O6H2O. Appearance White crystalline powder. Molecular weight 198.17. Odor None. Specific Gravity 1.5. Odor Threshold N/A. Vapor Density (air=1) 6.3. Solubility Soluble in water. Melting Point 146C (295F). Evaporation rate N/A. (Butyl acetate = 1). Boiling Point/Range Decomposes. Partition Coefficient N/A. (log POW). Vapor Pressure (20C) Negligible.. pH N/A. Flash Point: N/A. LEL N/A. Autoignition Temp.: N/A. UEL N/A.

N/A = Not available or applicable

Section 10: Stability and Reactivity Avoid heat and moisture. Stability: Stable under normal conditions of use and storage. Incompatibility: Strong oxidizers. Shelf life: Fair shelf life, store in a cool, dry environment.

Section 11: Toxicology Information Acute Symptoms/Signs of exposure: Eyes: Redness, tearing, itching, burning, conjunctivitis. Skin: Redness, itching. Ingestion: Irritation and burning sensations of mouth and throat, nausea, vomiting and abdominal pain. Inhalation: Irritation of mucous membranes, coughing, wheezing, shortness of breath, Chronic Effects: No information found. Sensitization: none expected Dextrose: LD50 [oral, rat]; N/A; LC50 [rat]; N/A; LD50 Dermal [rabbit]; N/A Material has not been found to be a carcinogen nor produce genetic, reproductive, or developmental effects.

Section 12: Ecological Information Ecotoxicity (aquatic and terrestrial): Not considered an environmental hazard.

Section 13: Disposal Considerations Check with all applicable local, regional, and national laws and regulations. Local regulations may be more stringent than regional or national regulations. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

Section 14: Transport Information DOT Shipping Name: Not regulated by DOT. Canada TDG: Not regulated by TDG. DOT Hazard Class: Hazard Class: Identification Number: UN Number:

Section 15: Regulatory Information EINECS: Listed (200-333-3). WHMIS Canada: Not WHMIS Controlled. TSCA: All components are listed or are exempt. California Proposition 65: Not listed. The product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

Section 16: Other Information Current Issue Date: September 19, 2009 Disclaimer: Scholar Chemistry and Columbus Chemical Industries, Inc., (S&C) believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because S&C has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. S&C makes no warranty, expressed or implied, including (without limitation) warranties with respect to the completeness or continuing accuracy of the information contained herein or with respect to fitness for any particular use.

p. 1

0 2 0

He a lt h

Fire

Re a c t iv it y


3

0

0

Material Safety Data SheetHydrochloric Acid, 5% (1+19) MSDS


Product Name: Hydrochloric Acid, 5% (1+19)Catalog Codes: SLH1339CAS#: Mixture.


TSCA: TSCA 8(b) inventory: Hydrochloric acid; WaterCI#: Not applicable.

Synonym: Hydrochloric Acid, 5% (1+19) SolutionChemical Name: Not applicable.







Name CAS # % by WeightHydrogen chloride 7647-01-0 1.85Water 7732-18-5 98.2

Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant). Hazardous in case of ingestion. Slightly hazardous incase of skin contact (corrosive, permeator), of eye contact (corrosive), of inhalation (lung sensitizer). Non-corrosive for lungs.Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skincontact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized bycoughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skininflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable forhuman.) by IARC [Hydrogen chloride]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, mucous membranes, upperrespiratory tract, skin, eyes, , teeth. Repeated or prolonged exposure to the substance can produce target organs damage.

p. 2

Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated orprolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.


Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention immediately.Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly cleanshoes before reuse. Get medical attention immediately.Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention immediately.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medicalattention.

Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,tie, belt or waistband.






Products of Combustion: Not available.Fire Hazards in Presence of Various Substances: Not applicable.Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks.Fire Fighting Media and Instructions: Not applicable.Special Remarks on Fire Hazards:Non combustible. Calcium carbide reacts with hydrogen chloride gas with incandescence. Uranium phosphide reacts withhydrochloric acid to release spontaneously flammable phosphine. Rubidium acetylene carbides burns with slightly warmhydrochloric acid. Lithium silicide in contact with hydrogen chloride becomes incandescent. When dilute hydrochloric acid isused, gas spontaneously flammable in air is evolved. Magnesium boride treated with concentrated hydrochloric acid producesspontaneously flammble gas. Cesium acetylene carbide burns hydrogen chloride gas. Cesium carbide ignites in contact withhydrochloric acid unless acid is dilute. Reacts with most metals to produce flammable Hydrodgen gas. (Hydrochloric Acid)Special Remarks on Explosion Hazards:Hydrogen chloride in contact with the following can cause an explosion, ignition on contact, or other violent/vigorous reaction:Acetic anhydride AgClO + CCl4 Alcohols + hydrogen cyanide, Aluminum Aluminum-titanium alloys (with HCl vapor), 2-Amino

p. 3

ethanol, Ammonium hydroxide, Calcium carbide Ca3P2 Chlorine + dinitroanilines (evolves gas), Chlorosulfonic acid Cesiumcarbide Cesium acetylene carbide, 1,1-Difluoroethylene Ethylene diamine Ethylene imine, Fluorine, HClO4 Hexalithiumdisilicide H2SO4 Metal acetylides or carbides, Magnesium boride, Mercuric sulfate, Oleum, Potassium permanganate,beta-Propiolactone Propylene oxide Rubidium carbide, Rubidium, acetylene carbide Sodium (with aqueous HCl), Sodiumhydroxide Sodium tetraselenium, Sulfonic acid, Tetraselenium tetranitride, U3P4 , Vinyl acetate. Silver perchlorate with carbontetrachloride in the presence of hydrochloric acid produces trichloromethyl perchlorate which detonates at 40 deg. C.


Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Ifnecessary: Neutralize the residue with a dilute solution of sodium carbonate.

Large Spill:Corrosive liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get waterinside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers,basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution ofsodium carbonate. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS andwith local authorities.


Precautions:Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. If ingested, seekmedical advice immediately and show the container or the label. Avoid contact with skin and eyes.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.



Personal Protection:Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits:Hydrogen chloride STEL: 7.5 (mg/m3) from ACGIH (TLV) [United States] STEL: 5 (ppm) from ACGIH (TLV) [United States]CEIL: 5 (ppm) from NIOSH CEIL: 7.5 (mg/m3) from NIOSH CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3)from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.


Physical state and appearance: Liquid.Odor: Not available.Taste: Acid.

Molecular Weight: Not applicable.

p. 4

Color: Clear Colorless.pH (1% soln/water): Acidic.Boiling Point: The lowest known value is 100C (212F) (Water).Melting Point: Not available.Critical Temperature: Not available.Specific Gravity: Weighted average: 1 (Water = 1)Vapor Pressure: The highest known value is 2.3 kPa (@ 20C) (Water).Vapor Density: The highest known value is 0.62 (Air = 1) (Water).Volatility: Not available.Odor Threshold: Not available.Water/Oil Dist. Coeff.: Not available.Ionicity (in Water): Not available.Dispersion Properties: See solubility in water, diethyl ether.Solubility:Easily soluble in cold water, hot water. Soluble in diethyl ether.


Stability: The product is stable.Instability Temperature: Not available.Conditions of Instability: Incompatible materialsIncompatibility with various substances: Slightly reactive to reactive with oxidizing agents, organic materials, metals,alkalis.

Corrosivity: Non-corrosive in presence of glass.Special Remarks on Reactivity:Absorption of gaseous hydrogen chloride on mercuric sulfate becomes violent @ 125 deg. C. Sodium reacts very violently withgaseous hydrogen chloride. Calcium phosphide and hydrochloric acid undergo very energetic reaction. It reacts with oxidizersreleasing chlorine gas. Incompatible with, alkali metals, carbides, borides, metal oxides, vinyl acetate, acetylides, sulphides,phosphides, cyanides, carbonates. Reacts with most metals to produce flammable Hydrogen gas. Isolate hydrogen chloridefrom heat, direct, alkalies (reacts vigorously), organic materials(reacts vigorously with many organic materials), and oxidizers(especially nitric acid and chlorates), amines, metals, copper and alloys (e.g. brass), hydroxides, zinc (galvanized materials),lithium silicide (incandescence), sulfuric acid(increase in temperature and pressure) Hydrogen chloride gas is emitted whenthis product is in contact with sulfuric acid. Adsorption of Hydrochloric Acid onto silicon dioxide results in exothmeric reaction.Hydrogen chloride causes aldehydes and epoxides to violently polymerize. Hydrogen chloride or Hydrochloric Acid in contactwith the folloiwng can cause explosion or ignition on contact or other violent/vigorous reaction: Acetic anhydride, Alcohols +hydrogen cyanide, Aluminum, Aluminum phosphide, Aluminum-titanium alloys (with HCl vapor), 2-Amino ethanol, Ammonium,Ammonium hydroxide, 1,4-Benzoquinone diimine, Calcium acetylide (incandescence upon warming), Calcium carbide,Calcium phosphide, Carbon tetrachloride + silver perchlorate (produce trichlormethyl perchlorate), Cesium acetylene carbide,Cesium carbide, Cesium telluroacylates, Chlorine + dinitroanilines (evolves gas), Chloroacetaldehyde oxime, Chlorosulfonicacid, Cyanogen chloride (when catalyzed by HCl), 1,1-Difluoroethylene, Dinitroanilines, Ethylene, Ethylene diamine, Ethyl 2-formylpropionate oxime (when generated by using HCl as a catalyst), Ethylene imine, Fluorine, HClO4, Hexalithium disilicide,Hydrogen peroxide, Metal acetylides, carbides, Magnesium boride, Methyl vinyl ether, Mercuric sulfate, Nitric acid + glycerol,Oleum, Perchloric acid, Potassium, Potassium permanganate, beta-Propiolactone, Propylene oxide, Rubidium acetylide,Rubidium carbide, Rubidium a c e t y l e n e c a r b i d e , S i l i c o n d i o x i d e , S i l v e r c h l o r i t e , S o d i u m ( w i t ha q u e o u s H C l ) , S o d i u m 2-allyloxy-6-nitrophenylpyruvate oxime, Sodium hydroxide, Sodium tetraselenium, Sulfonicacid, Sulfuric acid, Tetraselenium tetranitride, 2,4,6-Tri(2-acetylhydrazino)-1,3,5-trinitrobenzene, Uranium phosphide, Vinylacetate. Hydrogen chloride gas can react with formaldehyde to form bis(chloromethyl)ether, a human carcinogen. Most

p. 5

metals, as well as certain coatings, plastics, and rubbers, are attacked by hydrogen chloride. Addition of hydrochloric acid tothe following results in an exothermic reaction: Cesium cyanotridecahydrodecarborate(2-), Potassium ferricyanide, Vinylidenefluoride. Addition of hydrochloric acid to potassium ferrocyanide or ammonium hexacyanoferrate(II) results in an endothermicreaction. Hydrochloric acid in the presence of alcohol and glycols results in dehydration reactions. (Hydrochloric Acid)Special Remarks on Corrosivity:This compound is highly corrosive when in solution (especially to most metals except: gold, mercury, platinum, silver, andtantalum). The anhydrous gas is not corrosive . (Hydrogen chloride)Polymerization: Will not occur.


Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.Toxicity to Animals:LD50: Not available. LC50: Not available.Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrogen chloride]. Contains material whichmay cause damage to the following organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, , teeth.Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant). Hazardous in case of ingestion, of inhalation (lung corrosive). Slightlyhazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive), .Special Remarks on Toxicity to Animals: Not available.Special Remarks on Chronic Effects on Humans: Not available.Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Mildly Corrosive. Causes skin irritation and possible burns. Eyes: Mildly Corrosive.Causes eye irritation possible burns. Inhalation: May cause irritation of the nose, throat, bronchi (upper respiratorytract), coughing, sneezing, hoarseness. May affect the lungs/respiration. May affect the liver. Ingestion: Causes irritationgastrointestinal tract with nausea, vomitting abdominal cramps, and diarrhea. May affect behavior, the cardiovascular system,respiration and urinary system (kidneys). Chronic Potential Health Effects: Prolonged or repeated inhalation or ingestionmay affect liver, respiration(changes in pulmonary function, chronic bronchitis), teeth (yellowing of teethand erosion of toothenamel), kidneys, and behavior. Prolonged or repeated skin contact may cause dermatitis.






p. 6

DOT Classification: Class 8: Corrosive materialIdentification: : Hydrochloric Acid Solution UNNA: 1789 PG: IIISpecial Provisions for Transport: Not available.


Federal and State Regulations:Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloricacid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTKhazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid MassachusettsRTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list:Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid TSCA 8(b)inventory: Hydrochloric acid; Water TSCA 4(a) proposed test rules: Hydrochloric acid SARA 302/304/311/312 extremelyhazardous substances: Hydrochloric acid SARA 313 toxic chemical notification and release reporting: Hydrochloric acid 5%CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg);Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).Other Classifications:WHMIS (Canada): CLASS E: Corrosive liquid.DSCL (EEC):R34- Causes burns. S24/25- Avoid contact with skin and eyes. S26- In case of contact with eyes, rinse immediately withplenty of water and seek medical advice. S28- After contact with skin, wash immediately with plenty of [***] S36/37/39- Wearsuitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical adviceimmediately (show the label where possible).HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 0

Personal Protection:


Flammability: 0

Reactivity: 0

Specific hazard:Protective Equipment:Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Face shield.



Other Special Considerations: Not available.Created: 10/10/2005 10:32 AMLast Updated: 11/01/2010 12:00 PM

p. 7


p. 1

0 3 0

He a lt h

Fire

Re a c t iv it y


3

0

0

Material Safety Data SheetHydrochloric acid, 20%(v/v) MSDS


Product Name: Hydrochloric acid, 20%(v/v)Catalog Codes: SLH2932CAS#: Mixture.


TSCA: TSCA 8(b) inventory: Hydrochloric acid; WaterCI#: Not applicable.

Synonym:








Name CAS # % by WeightHydrogen chloride 7647-01-0 4.8-9.12Water 7732-18-5 90.9-95.2

Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Hazardous in case of skin contact(corrosive), of eye contact (corrosive). Slightly hazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. Liquidor spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skincontact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized bycoughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skininflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable forhuman.) by IARC [Hydrogen chloride]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, mucous membranes, upperrespiratory tract, skin, eyes, , teeth. Repeated or prolonged exposure to the substance can produce target organs damage.

p. 2

Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated orprolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.


Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention immediately.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly cleanshoes before reuse. Get medical attention immediately.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention immediately.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medicalattention.

Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,tie, belt or waistband.






Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks.

Fire Fighting Media and Instructions: Not applicable.Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.


Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Ifnecessary: Neutralize the residue with a dilute solution of sodium carbonate.

p. 3

Large Spill:Corrosive liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get waterinside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers,basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution ofsodium carbonate. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS andwith local authorities.


Precautions:Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case ofinsufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show thecontainer or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as alkalis, moisture. May corrodemetallic surfaces. Store in a metallic or coated fiberboard drum using a strong polyethylene inner package.Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.



Personal Protection:Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.Exposure Limits:Hydrogen chloride STEL: 7.5 (mg/m3) from ACGIH (TLV) [United States] STEL: 5 (ppm) from ACGIH (TLV) [United States]CEIL: 5 (ppm) from NIOSH CEIL: 7.5 (mg/m3) from NIOSH CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3)from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.


Physical state and appearance: Liquid.Odor: Disagreeable and choking. (Strong.)Taste: Acid. (Strong.)Molecular Weight: Not applicable.Color: Clear Colorless.pH (1% soln/water): Acidic.Boiling Point: The lowest known value is 100C (212F) (Water).Melting Point: Not available.Critical Temperature: Not available.Specific Gravity: Weighted average: 1.01 (Water = 1)Vapor Pressure: The highest known value is 2.3 kPa (@ 20C) (Water).Vapor Density: The highest known value is 0.62 (Air = 1) (Water).

p. 4

Volatility: Not available.Odor Threshold: Not available.Water/Oil Dist. Coeff.: Not available.Ionicity (in Water): Not available.Dispersion Properties: See solubility in water, diethyl ether.Solubility:Easily soluble in cold water, hot water. Soluble in diethyl ether.


Stability: The product is stable.Instability Temperature: Not available.Conditions of Instability: Incompatible materialsIncompatibility with various substances:Reactive with alkalis. Slightly reactive to reactive with oxidizing agents, organic materials.Corrosivity:Extremely corrosive in presence of aluminum. Highly corrosive in presence of zinc. Corrosive in presence of steel, of copper.Slightly corrosive in presence of stainless steel(304), of stainless steel(316). Non-corrosive in presence of glass.Special Remarks on Reactivity:Reacts violently (moderate reaction with heat of evolution) with water especially when water is added to the product. Isolatehydrogen chloride from heat, direct, alkalies (reacts vigorously), organic materials, and oxidizers (especially nitric acid andchlorates), amines, copper and alloys (e.g. brass), hydroxides, zinc (galvanized materials), lithium silicide (incandescence),sulfuric acid(increase in temperature and pressure) Hydrogen chloride causes aldehydes and epoxides to violently polymerize.It reacts with oxidizers releasing chlorine gas. Hydrogen chloride gas is emitted when this product is in contact with sulfuricacid. Adsorption of Hydrochloric Acid onto silicon dioxide results in exothmeric reaction. Hydrogen chloride causes aldehydesand epoxides to violently polymerize. Hydrogen chloride or Hydrochloric Acid in contact with the folloiwng can causeexplosion or ignition on contact or other violent/vigorous reaction: Acetic anhydride, Alcohols + hydrogen cyanide, Aluminum,Aluminum phosphide, Aluminum-titanium alloys (with HCl vapor), 2-Amino ethanol, Ammonium, Ammonium hydroxide, 1,4-Benzoquinone diimine, Calcium acetylide (incandescence upon warming), Calcium carbide, Calcium phosphide, Carbontetrachloride + silver perchlorate (produce trichlormethyl perchlorate), Cesium acetylene carbide, Cesium carbide, Cesiumtelluroacylates, Chlorine + dinitroanilines (evolves gas), Chloroacetaldehyde oxime, Chlorosulfonic acid, Cyanogen chloride(when catalyzed by HCl), 1,1-Difluoroethylene, Dinitroanilines, Ethylene, Ethylene diamine, Ethyl 2-formylpropionate oxime(when generated by using HCl as a catalyst), Ethylene imine, Fluorine, HClO4, Hexalithium disilicide, Hydrogen peroxide,Lithium silicide, Metal acetylides, carbides, Magnesium boride, Methyl vinyl ether, Mercuric sulfate, Nitric acid + glycerol,Oleum, Perchloric acid, Potassium, Potassium permanganate, beta-Propiolactone, Propylene oxide, Rubidium acetylide,Rubidium carbide, Rubidium acetylene carbide, Silicon dioxide, Silver chlorite, Sodium (with aqueous HCl), Sodium 2-allyloxy-6-nitrophenylpyruvate oxime, Sodium hydroxide, Sodium tetraselenium, Sulfonic acid, Sulfuric acid, Tetraseleniumtetranitride, 2,4,6-Tri(2-acetylhydrazino)-1,3,5-trinitrobenzene, Uranium phosphide, Vinyl acetate. Hydrogen chloride gascan react with formaldehyde to form bis(chloromethyl)ether, a human carcinogen. Most metals, as well as certain coatings,plastics, and rubbers, are attacked by hydrogen chloride. Addition of hydrochloric acid to the following results in an exothermicreaction: Cesium cyanotridecahydrodecarborate(2-), Potassium ferricyanide, Vinylidene fluoride. Addition of hydrochloric acidto potassium ferrocyanide or ammonium hexacyanoferrate(II) results in an endothermic reaction. Hydrochloric acid in thepresence of alcohol and glycols results in dehydration reactions. (Hydrogen chloride)Special Remarks on Corrosivity:This compound is highly corrosive when in solution (especially to most metals except: gold, mercury, platinum, silver, andtantalum). The anhydrous gas is not corrosive . (Hydrogen chloride) Will not occur.Polymerization:


p. 5

Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:Acute oral toxicity (LD50): 900 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 1108 ppm, 1 hours [Mouse]. Acute toxicity ofthe vapor (LC50): 3124 ppm, 1 hours [Rat]. (Hydrochloric Acid)Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrogen chloride]. Contains material whichmay cause damage to the following organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, , teeth.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive), of eye contact(corrosive). Slightly hazardous in case of inhalation (lung sensitizer, lung corrosive).Special Remarks on Toxicity to Animals:Lowest Published Lethal Doses (LDL/LCL) LDL [Man] -Route: Oral; 2857 ug/kg LCL [Human] - Route: Inhalation; Dose: 1300ppm/30M LCL [Rabbit] - Route: Inhalation; Dose: 4413 ppm/30M (Hydrochloric Acid)Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects (fetoxicity). May affect genetic material. (Hydrochloric Acid)Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Corrosive. Causes severe skin irritation and burns. Eyes: Corrosive. Causes severe eyeirritation and burns. May cause permanent damage to the eyes. Inhalation: Inhalation of vapor or mist may be destructiveto tissue of the mucous membranes and upper respiratory tract. It may affect the lungs/respiration. Inhalation of mist orvapor may produce nose, throat, and laryngeal burning, and irritation, pain and inflammation, coughing, sneezing, chokingsensation, hoarseness, laryngeal spasms, upper respiratory tract edema, chest pains, as well has headache, and palpitations.Inhalation of high concentrations may also cause chemical burns of the upper respiratory tract, constriction of the larynx andbronchi, nasospetal perforation, glottal closure, dyspnea, bronchitis. Chemical pneumonitis and pulmonary edema can alsooccur, particularly if exposure is prolonged. It may affect the liver Ingestion: Causes irritation and burns of the mouth, throat,esophagous (gastrointestinal tract) with nausea, vomitting abdominal cramps, diarrhea. It can also cause thirst, difficultyswallowing, salivation, chills, fever, uneasiness, shock, strictures and stenosis (esophogeal, gastric, pyloric). May affectbehavior (excitement), the cardiovascular system (weak rapid pulse, tachycardia), respiration (shallow respiration), and urinarysystem (kidneys - renal failure, nephritis). Chronic Potential Health Effects: Prolonged or repeated inhalation or ingestionmay affect liver, respiration(changes in pulmonary function, chronic bronchitis), teeth (yellowing of teethand erosion of toothenamel), kidneys, and behavior. Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contactwith vapor/mist may cause conjunctivitis


Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.Special Remarks on the Products of Biodegradation: Not available.




p. 6

DOT Classification: Class 8: Corrosive materialIdentification: : Hydrochloric acid, solution UNNA: 1789 PG: IISpecial Provisions for Transport: Not available.


Federal and State Regulations:Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloricacid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTKhazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid MassachusettsRTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list:Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid TSCA 8(b)inventory: Hydrochloric acid; Water TSCA 4(a) proposed test rules: Hydrochloric acid SARA 302/304/311/312 extremelyhazardous substances: Hydrochloric acid SARA 313 toxic chemical notification and release reporting: Hydrochloric acid 24%CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg);Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).Other Classifications:WHMIS (Canada):CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.DSCL (EEC):R34- Causes burns. S24/25- Avoid contact with skin and eyes. S26- In case of contact with eyes, rinse immediately withplenty of water and seek medical advice. S28- After contact with skin, wash immediately with plenty of water. S36/37/39- Wearsuitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical adviceimmediately (show the label where possible).HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 0Personal Protection:


Flammability: 0Reactivity: 0Specific hazard:

Protective Equipment:Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Face shield.



Other Special Considerations: Not available.Created: 10/10/2005 10:32 AMLast Updated: 11/01/2010 12:00 PM

p. 7


p. 1

1 2 0

He a lt h

Fire

Re a c t iv it y


2

1

0

E

Material Safety Data SheetMethyl orange MSDS


Product Name: Methyl orange

Catalog Codes: SLM2938, SLM4318CAS#: 547-58-0

RTECS: DB6327000

TSCA: TSCA 8(b) inventory: Methyl orangeCI#: 13025

Synonym: Acid Orange 52; SodiumDimethylaminobenzenesulfonate; 4-[Dimethylamino)pnenylazo]benzenesulfonic Acid, sodiumsalt; Orange III; Tropaeolin D

Chemical Name: Methyl Orange

Chemical Formula: C14H14N3NaO3S






Name CAS # % by WeightMethyl orange 547-58-0 100

Toxicological Data on Ingredients: Methyl orange: ORAL (LD50): Acute: 60 mg/kg [Rat].


Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Severe over-exposure can resultin death.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENICEFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated exposure to a highly toxic material mayproduce general deterioration of health by an accumulation in one or many human organs.


p. 2

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at

MSDS

Documents

Transcript of MSDS