Msds Danlain Lain

7/28/2019 Msds Danlain Lain

1/12

BAB XII

HUMAN FACTOR

12.1 Health and Safety Aspects of Plant

Aspects of occupational health and safety (HSE) is important because to support the work of

the best quality of a company. Moreover, this aspect is important because most of the

workers involved tend not concerned with aspects of occupational health and safety for

themselves and others. Therefore, it is imperative to establish a guideline Occupational

Health and Safety (HSE) for the management of a company that cares about employees and

assets across the enterprise. Kesahatan and safety of workers and assets across the enterprise

is an important factor in carrying out an activity anywhere and anytime. In a corporate

environment, HSE is not just the responsibility of the management company, but also all

employees and those workers who are in the area. Guidelines for Occupational Health and

Safety (HSE) is made to create a condition where there is an accident (zero accident).

12.1.1 Basic Principles of Safety

The entire workforce either directly or indirectly shall make HSE a lifestyle while in

the factory environment so it is important to live up to the principles of HSE:


2/12

The basic principle of safety is applied by PT.Cholesterica all workers and people who are in

the work environment companies must comply with the rules and guidelines that K3 has been

applied by the company. In addition, all workers involved shall remind each other to avoid

accidents yourself and others around him.

a. Factory PT.Cholesterica prioritize and safe working environment for sleurug sehiatworkers and people who are in the corporate area.

b. Safety is a measure of job performance. Offenses committed will be subject toappropriate sanctions

c. Response to unsafe conditions must be done with safe work attitude.d. Any accident of any kind must be reported to the Division of Occupational Health and

Safety.

e. If there are less obvious to the working procedure, it shall obtain keternagan andknowledge of the authorities.

f. All workers and people who were in the plant area will get counseling about healthand safety programs in PT.Cholesterica

12.1.2 Behaviour in the Workplacea

Job safely and efficiently requires that all employees comply with company

regulations and fully master the mental and physical abilities during work tasks. At any time,

the following acts are prohibited:

a. Smoking in the factory, except at a designated placeb. Frolic with roughc. Make other people be surprisedd. Fooling around with using compressed air or work equipmente. fightf. Come to work drunk under the influence of alcohol or narcotics or dangerous

drugs

g. To ensure safety in the workplace is a maximum, an employee must notify theemployer / supervisor directly, if he was taking medication under a doctor's advice

will result in loss of control over the physical and mental abilities


3/12

h. Carrying and storing firearms or other weapons and materials flammable /explosive except for the purposes of plant

i. Turn on / run production machinery or other equipment without authorizedpermission.

12.1.3. Safe Work Attitude

In the application of health and safety aspects of the work, it takes work attitude

amandari the workers involved. The following is the safety instructions that must be met:

1. a. Ensure work procedures are unclear at the moment will start the job.2. b. Try to always be at a safe distance when doing work related to heavy equipment.3. c. Mengguunakan not place chemicals used goods for the purpose of storage of goods.4. d. Make sure to always maintain the cleanliness of the workplace.5. e. Using appropriate personal protective equipment while working.In Indonesia there are Safety Act 1 of 1970 which also regulates the obligations and rights

of workers, namely

1. The use of appropriate safety equipment regulations2. Demand for health insurance and workplace safety system3. Compliance with workplace rules and giving clear information about safety in the

workplace.

12.1.4 Safety Program

The management has a responsibility to provide a safe working environment and

healthy so making program Occupational Safety and Health Guidance for both short-term and

long-term future for the benefit and safety of all components of this plant, which is:

a) Training of safety and health at every new employee and corporate guests.b) Checking the existing hydrant system within and outside the area of each plant once a

month.

c) Checking the emergency evacuation system every once in a month.d) Regular meetings every day for 30 minutes before and after surgery with the operator

to discuss the work activities in the day.

e) Program and refresher training HSE every single time in two monthsf)

Availability of trained health personnel

g) Monthly HSE inspection of how the workers and the factory operating system.


4/12

h) Regular meetings of occupational health and safety committee every month.i) The medical examination of all workers on a regular basis

j) Conducting in-depth investigation of the accident and any corrective action that maybe taken.

12.1.5 Personal Protective Equipment (PPE)

All employees must wear PPE that is provided for the cleanliness of the direct labor is

considered by the company and has been adapted to the conditions of employment of each

a) Employees working in factories must wear full PPE, as already provided, ie gloves, masks,

work clothing, headgear, safety glasses, and safety shoes.

b) Ring or any personal jewelery should not be worn when working or being around

machinery.

12.2 Safety Analysis

In the safety analysis is usually done based on the rules and codes of conduct, both

international and local levels. In Indonesia alone in providing job safety analysis should be

based on the level of regulation following:

1. ILO Code of Practice for the Prevention of Major Industrial Accidents2. Safety Act No.. 1 of 19703. Per.05/Men/1996 of the Safety Management System and Occupational Health

Analysis of safety and health as a reference, referral, and information standards that

help reduce, avoid, minimize, and protect against accidents in the production process and

prevent losses in the production process. Loss is a fatal accident that resulted in death and

disability for the employee or employees, damage to major appliances and supporting the

process of production, loss of missing or damaged raw materials and supplementary materials

processes, and the loss or damage of the product resulting in loss materially to business

owners and business owners with or consortium of investors. Portable Chemical Toilet 170

Safety analysis includes several things: availability sheet MSDS (Material Safety Data

Sheets) on the properties and physico-chemical properties of raw materials, auxiliary

materials, or materials supporting the production process used. In addition, job safety analysis

is also the Safety Assessment sheet covering sheet Hazard Identification and Risk

Assessment (HIRA), Hazard Identificaiton (HAZID), Hazard Operability Studies (HAZOP).


5/12

12.2.1 MSDS (Material Safety Data Sheet)

To further safeguard the security and safety of both personal and environmental, so

any materials used for production must be equipped with MSDS or Material Safety Data

Sheet. MSDS contains data concerning the properties, use, handling, and storage of materials

or substances contained in the plant for the sake of safety. Any material in the factory must

have a MSDS which serves as the basis for the use of material handling. With the MSDS is

then able to communicate and inform everyone who worked with the material so as to use it

appropriately and act appropriately if there is immediate danger. Here is the MSDS of the raw

materials used :

1.Cremophor EL

1. Hazards IdentificationI. Emergency overview

Avoid contact with the skin, eyes and clothing. Avoid inhalation of mists/vapours. Use with local exhaust ventilation. Wear appropriate respiratory protection. Wear NIOSH-certified chemical goggles. State of matter: liquid Colour: light yellow Odour: faint specific odour

II. Potential health effects Primary routes of exposure: Routes of entry for solids and liquids include eye

and skin contact, ingestion and inhalation. Routes of entry for gases include

inhalation and eye contact. Skin contact may be a route of entry for liquified

gases.

Acute toxicity:Virtually nontoxic after a single ingestion. Virtually nontoxicafter a single skin contact. The inhalation of a highly enriched/saturated vapor-

air-mixture represents an unlikely acute hazard.

Irritation / corrosion:Not irritating to the skin. Not irritating to the eyes. Sensitization:Skin sensitizing effects were not observed in animal studies. Teratogenicity: No indications of a developmental toxic / teratogenic effect

were seen in animal studies.


6/12

Genotoxicity: No mutagenic effect was found in various tests with bacteria andmammalian cell culture. The substance was not mutagenic in studies with

mammals.

2. First-Aid Measures General advice:Remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove

to fresh air and seek medical attention.

If on skin: Wash affected areas thoroughly with soap and water. Removecontaminated clothing. If irritation develops, seek medical attention.

If in eyes: Wash affected eyes for at least 15 minutes under running waterwith eyelids held open.

If swallowed: Rinse mouth and then drink plenty of water. Note to physician Treatment: Symptomatic treatment (decontamination, vital functions).

3. Fire-Fighting Measures Flash point: 257 C (DIN ISO 2592) Autoignition: 405 C (DIN 51794)

Lower explosion limit: not determined Upper explosion limit: not determined Flammability: does not ignite Self-ignition temperature: not self-igniting Suitable extinguishing media: water spray, foam, carbon dioxide, dry powder Hazards during fire-fighting: No particular hazards known. Protective equipment for fire-fighting:Firefighters should be equipped with self-

contained breathing apparatus and turn-out gear. Further information: Dispose of fire debris and contaminated extinguishing

water in accordance with official regulations.

4. Accidental release measures Personal precautions:No special precautions necessary. Environmental precautions:Do not discharge into drains/surface

waters/groundwater.

Cleanup:Dispose of absorbed material in accordance with regulations.


7/12

For small amounts: Contain with absorbent material (e.g. sand, silica gel, acidbinder, general purpose binder, sawdust).

For large amounts: Dike spillage. Vacuum up spilled product. Place into suitablecontainer for disposal. Pick up with suitable absorbent material (e.g. sand,sawdust, general-purpose binder, kieselguhr).

5. Handling and Storagea. Handling

General advice:Avoid contact with the skin, eyes and clothing. Handle in

accordance with good industrial hygiene and safety practice.

b. Storage General advice:Keep container tightly closed and dry; store in a cool place. Storage stability: Storage temperature: 100 C Vapour pressure: No data available. Density: 1.05 - 1.06 g/cm3 ( 25 C) Relative density: 1.05 - 1.06 Bulk density: not relevant Vapour density: not determined Partitioning coefficient noctanol/water (log Pow): not determined Viscosity, dynamic: 650 - 800 mPa.s ( 25 C) Solubility in water: 100 g/l ( 20 C) Solubility (qualitative): soluble


8/12

solvent(s): organic solvents,7. Stability and Reactivity

Conditions to avoid:Avoid heat.

Substances to avoid:No substances known that should be avoided. Hazardous reactions:No hazardous reactions if stored and handled as

prescribed/indicated.

Decomposition products: Hazardous decomposition products: Nohazardous decomposition products if stored and handled as

prescribed/indicated.

Thermal decomposition: approx. 300 C

Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: not fire-propagating

8. Transport Information Land transport : USDOT Not classified as a dangerous good under

transport regulations

Sea transport : IMDG Not classified as a dangerous good undertransport regulations

Air transport : IATA/ICAO Not classified as a dangerous good undertransport regulations

9. Other Information Recommended use: Pharmaceutical agent NFPA Hazard codes: Health : 1 Fire: 1 Reactivity: 0

Special: none

HMIS III rating : Health: 1 Flammability: 1 Physical hazard: 0


9/12

2.Ethyl Acetate

1. Hazard Identification

Potential Acute Health Effects:Hazardous in case of ingestion, of inhalation.Slightly hazardous in case of skin contact (irritant, permeator), of eye

contact(irritant).

Potential Chronic Health Effects:o CARCINOGENIC EFFECTS: A4 (Not classifiable for human or

animal.) by ACGIH.

o MUTAGENIC EFFECTS: Not available.o TERATOGENIC EFFECTS: Not available.o DEVELOPMENTAL TOXICITY: Not available. The substance is

toxic to mucousmembranes, upper respiratory tract. The substance

may be toxic to blood, kidneys, liver, central nervous system (CNS).

Repeated or prolonged exposure to the substance can produce target

organs damage.

2.First aid measurement

Eye Contact:Check for and remove any contact lenses. In case of contact,immediately flush eyes with plenty of water for at least 15minutes. Cold water

may be used. Get medical attention.

Skin Contact:Wash with soap and water. Cover the irritated skin with anemollient. Get medical attention if irritation develops. Cold watermay be used.

Serious Skin Contact: Not available. Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial

respiration. If breathing is difficult, give oxygen. Get medical attention ifsymptoms appear.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible.Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is

difficult, administer oxygen. If the victim is not breathing, perform mouth-to-

mouth resuscitation. Seek medicalattention.

Ingestion: Do NOT induce vomiting unless directed to do so by medicalpersonnel. Never give anything by mouth to an unconscious person. Loosen

tight clothing such as a collar, tie, belt or waistband. Get medical attention if

symptoms appear.

Serious Ingestion: Not available.3. Fire and Explosion Data

o Flammability of the Product: Flammable.o Auto-Ignition Temperature: 426.67C (800F)o Flash Points: CLOSED CUP: -4.4C (24.1F). (TAG) OPEN CUP: 7.2C

(45F) (Cleveland).

o Flammable Limits: LOWER: 2.2% UPPER: 9%o Products of Combustion: These products are carbon oxides (CO, CO2).o Fire Hazards in Presence of Various Substances: Highly flammable in

presence of open flames and sparks, of heat. Slightly flammable to flammable

in presence of oxidizing materials, of acids, of alkalis. Non-flammable in

presence of shocks.


10/12

o Explosion Hazards in Presence of Various Substances: Risks of explosion ofthe product in presence of static discharge: Not available. Slightly explosive in

presence of heat. Nonexplosive in presence of shocks.

o Fire Fighting Media and Instructions: Flammable liquid, soluble or dispersedin water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use

alcohol foam, water spray or fog.o Special Remarks on Fire Hazards: Vapor may travel considerable distance to

source of ignition and flash back. When heated to decomposition it emits acrid

smoke and irritating fumes.

o Special Remarks on Explosion Hazards: The liquid produces a vapor thatforms explosive mixtures with air at normal temperatures. Explosive reaction

with lithium

o tetrahydroaluminate.4. Accidental release measures

o Small Spill: Dilute with water and mop up, or absorb with an inert drymaterial and place in an appropriate waste disposal container.

o Large Spill: Flammable liquid. Keep away from heat. Keep away from sourcesof ignition. Stop leak if without risk. Absorb with DRY earth,sand or other

non-combustible material. Do not touch spilled material. Prevent entry into

sewers, basements or confined areas; dike if needed. Be careful that the

product is not present at a concentration level above TLV. Check TLV on the

MSDS and with local authorities

5. Handling and Storage Precautions:Keep away from heat. Keep away from sources of ignition.

Ground all equipment containing material. Do not ingest. Do not breathe

gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of

insufficient ventilation, wear suitable respiratory equipment. If ingested, seek

medical advice immediately and show the container or the label. Keep away

from incompatibles such as oxidizing agents, acids, alkalis.

Storage: Store in a segregated and approved area. Keep container in a cool,well-ventilated area. Keep container tightly closed and sealed until ready for

use. Avoid all possible sources of ignition (spark or flame). Moisture sensitive.

6. Physical and Chemical Properties Physical state and appearance: Liquid. Odor: Ethereal. Fruity. (Slight.)

Taste: Bittersweet, wine-like burning taste Molecular Weight: 88.11 g/mole


11/12

Color: Colorless. pH (1% soln/water): Not available. Boiling Point: 77C (170.6F)

Melting Point: -83C (-117.4F) Critical Temperature: 250C (482F) Specific Gravity: 0.902 (Water = 1) Vapor Pressure: 12.4 kPa (@ 20C)p. 4 Vapor Density: 3.04 (Air = 1) Volatility: Not available. Odor Threshold: 3.9 ppm Water/Oil Dist. Coeff.: The product is more soluble in oil; log(oil/water) = 0.7 Ionicity (in Water): Not available. Dispersion Properties: See solubility in water, diethyl ether, acetone. Solubility: Soluble in cold water, hot water, diethyl ether, acetone, alcohol, benzene.7. Transport Information DOT Classification: CLASS 3: Flammable liquid. Identification: : Ethyl Acetate UNNA: 1173 PG: II Special Provisions for Transport: Not available8. Stability and Reactivity

Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Heat, ignition sources (flames, sparks, static),

incompatible materials Incompatibility with various substances: Reactive with

oxidizing agents, acids, alkalis.

Corrosivity: Non-corrosive in presence of glass. Special Remarks on Reactivity: Also incompatible with nitrates,

chlorosulfonic acid, oleum, potassium-tert-butoxide, and lithium

tetrahydroaluminate. Moisturesensitive. On storage, it is slowly decomposed

by water.

Special Remarks on Corrosivity: Not available. Polymerization: Will not occur.


12/12

9. Other Infotrmation

HMIS (U.S.A.):o Health Hazard: 2o Fire Hazard: 3o Reactivity: 0

Personal Protection: g National Fire Protection Association (U.S.A.):

o Health: 1o Flammability: 3o Reactivity: 0

Protective Equipment: Gloves. Lab coat. Vapor respirator. Be sure to use anapproved/certified respirator or equivalent. Wear appropriate respirator when

ventilation is inadequate. Safety glasses.

Msds Danlain Lain

Documents

Transcript of Msds Danlain Lain