M.Phil. CHEMISTRYStructural Methods in Inorganic Chemistry - 1987 4. Identification of Organic...

M.Phil. CHEMISTRY SEM SUB CODE COURSE SUBJECT TITLE

HRS / WEEK

CREDIT CIA

Mark ESE

MARK TOTAL MARK

I

20MPCH1CC1 Core – I Research methodology in chemistry 4* 4 25 75 100

20MPCH1CC2 Core – II Advanced physical methods and molecular modelling in chemistry

4* 4 25 75 100

20MPCH1CC3 Core – III Teaching and learning skills 4* 4 25 75 100

20MPCH1CC4

Core - IV (Elective)

Paper on topic of research (the syllabus will be prepared by the guide and examination will be conducted by the COE)

4* 4 25 75 100

*One hour library for each course

TOTAL 16* 16 100 300 400

II 20MPCH2PD

Dissertation## - 8 - - 200

GRAND TOTAL - 24 - - 600

## Evaluation of the Dissertation and Viva Voce shall be made jointly by the Research Supervisor and

the External Examiner.

Course Outcomes:

1. Scholars shall identify various ways to design a research problem.

2. Scholars shall develop the numerical aptitude and computational knowledge in the

fundamental of collection and presentation data

3. Scholars shall get innovative idea for their research work based on the compilation of

literature

4. Scholars shall acquire knowledge for writing and publishing the research paper and

drafting the thesis

5. Scholars shall understand the role of statistical analysis of data in research

6. Scholars shall learn basic concepts of computer knowledge for presentation of

dissertation.

Unit - I Principles of Research 12 hours

Definition - Need for research. Objectives – Motivation – Types of research –

Significance - Formulation of Research Problem – Developing Hypothesis - Preparing

Research Design - Selection of Research Problem – Determining Sample Design

Characteristics of a Good Sample Design - Collection of Data – Methods of Data Collection -

Execution of Work. Analysis of Data – Hypothesis, Testing - Generalization and

Interpretation - Preparation of Report - #Submission of Report in the form of Thesis #

Unit - II Survey of Literature 12 hours

Need for literature survey – Primary, Secondary and Tertiary Sources. Journals,

Chemical Abstracts – Subject index, Substance index, Author index, Formula index and other

indices. Other similar abstracts for special topics. Current Titles – Reviews – Monographs –

Selection of Research topic – Selection of Research Facility – Location of Journals and

Articles. Use of computers in the Literature Survey – Websites – Search Engines -

chemspider, google scholar, scifinder, scopus, Internet, E-mail. #Scientific Information and

Documentation Centers – INSDOC, BANSDOC, NCSI, British Library – Digital Library –

e-Journals – e-Content #.

Unit - III Assignment, Research Paper and Thesis Writing 12 hours

Assignment – Topic selection, Front Page, Text and References. Research Paper –

Preparation of Manuscript for Publication in International Journals Published by Elsevier,

Interscience, Wiley and Springer- submission procedure. Thesis - Rough drafting – Title,

Abstract, Introduction, Scope of the Work, Literature Review, Problem and Time Limitation,

Experimental Methods, Results and Discussion Foot Notes- Data Presentation - Figures and

Tables, Sign Conventions followed, bibliography, Conclusion and Recommendations.

Abbreviations used. #Storing and Retrieval of Information using Computer – CD, Pen Drive,

DVD#.

Semester Code Course Title of the

Course Hours Credits

Max. marks

Internal marks

External marks

I 20MPCH1CC1 Core – I RESEARCH METHODOLOGY

IN CHEMISTRY 4 4 100 25 75

Unit – IV Statistical Analysis of Data 12 hours Various types of errors – precision and accuracy – significant figures, various statistical tests on

the accuracy of results, positive and negative deviation from accurate results – the Gaussian distribution

– the normal distribution of random errors, mean value, variance and standard deviation, reliability

interval, deviations from the Gaussian law of error distribution, t-tests- comparison of the mean with the

expected value, comparison of the results of two different methods, comparison of the precision of two

methods by F-test, Gross errors and elimination of outlying results, graphical methods – Linear

regression, regression line, # standard deviation, correlation coefficient#–Multiple Linear regression (one

variable with two other variables).

Unit – V Computer Application Skill 12 hours

Internet – meaning and importance, types of networking – LAN, WAN and MAN – Internet –

WWW, website and webpage’s, mode of connection, network protocol, browsing the internet –

browsing softwares, URL addresses, domain name, search engines, exploring websites and downloading

materials from websites, E-mail – sending, receiving and storing mail and chatting. Power point –

creating a presentation – slide preparation – # popular websites for data collection in chemistry#.

#............ # Self study TEXT BOOKS 1. Research Methodology (Methods & Techniques), C.R. Kothari. 2nd Edn., Wishwa Prakasam,

2002. 2. Analytical Chemistry, Scoog, West, Holler and Crouch. Thomson – India 8th Edn., 2007. 3. Zikr – ur Rahman , Modern teaching methods and techniques , Anmol Publication Pvt. Ltd. New Delhi,

(2006). 4. T. M. Srinivasan, Use of Computers and Multimedia in Education, Aavisakar publication, Jaipur (2002). UNIT I : Text Book 1 UNIT II : Text Book 1 UNIT III : Text Book 1 UNIT IV : Text Book 2 UNIT V : Text Book 3,4 REFERENCES 1. Thesis and Assignment writing, J. Anderson, B.H. Durston and M.Poole, John Wiley

Publications, Sydney. 1970. 2. How to write a research paper, R. Berry, Pergoman, 1969. 3. Computers in Chemistry, K.V. Raman, Tata McGraw-Hill Publishing company Limited, New

Delhi, 2005.

4. Analytical Chemistry (Theory and Practice) by R.M. Verma. CBS Publishers and

Distributers, 2001.

Relationship Matrix for Course Outcomes, Programme Outcomes and Programme Specific

Outcomes:

Semester Code Title of the Course Hours Credits

I 20MPCH1CC1 Research Methodology in

Chemistry

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)

Programme Specific Outcomes

(PSOs)

PO1 PO2 PO3 PO4 PO5 PSO1 PSO2 PSO3 PSO4 PSO5

CO1

CO2

CO3

CO4

CO5

Number of Matches= 35 Relationship is : High

Prepared by: Checked by: Dr.A.Jahir Hussain Dr.Syed Abuthair



Max. marks

Internal marks

External marks

I 20MPCH1CC2 Core – II ADVANCED PHYSICAL

METHODS AND MOLECULAR MODELLING IN CHEMISTRY

4 4 100 25 75

Course Outcomes:

1. Categorize the features of nonmaterial’s based on their applications.

2. Predict complicated structures using correlation technique

3. Deduce the geometry and magnetic properties of inorganic complexes.

4. Analyse the molecular interactions by adapting molecular modelling.

5. Assess the Drug ability of a molecule by simulation method.

Unit I - Characterization and applications of nano materials 12 hours Surface morphology and nanostructure – Scanning Electron Microscope (SEM), Transmission

Electron Microscope (TEM) and Atomic Force Microscope (AFM); #Structural Characterization - UV-

Visible and FT-IR spectroscopy#; Structure orientation and micro texture-X-ray Diffraction (XRD);

Elemental analysis – Energy Dispersive X-ray Micro analysis (EDX) and Atomic Absorption

Spectroscopy(AAS).

Applications of carbon nanomaterials in the field of fuel cells and batteries; Energy and

environmental applications- Energy production and storage - Applications of nanomaterials in electronics-

semiconductors and chemical sensors, biotechnology- detection of biomolecules and medicine-drug design

and drug delivery.

Unit II– 2D-NMR and NQR spectroscopy 12 hours

2D- NMR – basic principle and types-homonuclear through-bond correlation methods-Correlation

spectroscopy (COSY- 1H-

1H COSY &

1H-

13C COSY), Exclusive correlation spectroscopy (ECOSY), Total

correlation spectroscopy (TOCSY), Incredible natural-abundance double-quantum transfer experiment

(INADEQUATE)- Heteronuclear through-bond correlation methods-Heteronuclear single-quantum

correlation spectroscopy (HSQC), Heteronuclear multiple-bond correlation spectroscopy (HMBC)- Through-

space correlation methods-Nuclear Overhauser effect spectroscopy (NOESY), Rotating frame nuclear

Overhauser effect spectroscopy (ROESY)-# Resolved-spectrum methods-Higher-dimensional methods

#.

NQR spectroscopy – Characteristics of quadrupolar nucleus – effects of field gradient and magnetic

field upon quadrupolar energy levels – NQR transitions – applications of NQR spectroscopy.

Unit – III –Inorganic Spectroscopy 12 hours 31

P, 14

N and 15

N NMR spectra – basic theory, standard reference, chemical shift, coupling constants

and biological applications.Combined applications of UV-Visible, FT-IR, Raman and EPR spectral data for

solving the structure of metal (Co, Ni, Cu and Zn) complexes- #1

H-NMR spectra of zinc complexes#-

Magnetic studies for the characterization of the complexes by VSM.

Unit -IV Molecular Modeling-I 12-hours

Molecular Modeling – definition and importance-types of molecular model- spheres, ball-and-stick,

skeletal, polyhedral, composite and computer-based models- molecular mechanics- software for molecular

mechanics modeling - coordinate systems- potential energy surfaces- molecular graphics- definition, relation

with molecular models- #non-bonded interactions- electrostatic and van der Waals interactions in molecular

modeling#- hydrogen bonding in molecular mechanics.

Unit-V Molecular Modeling –II 12-hours Computer simulation methods- definition and advantages- data preparation and process for the

preparation of computer simulation model- softwares for simulation- differences between simulation and

model- types of simulation models- force field model for the simulations of liquid water-#calculation of

simple thermodynamic properties, phase space#, drug design and delivery using simulating models.

#......... # Self study

BOOKS FOR STUDY

S.

No. Author Name Book Name Edition Publisher detail

Year

1 F. J. Ownes Introduction to Nano technology - John Wiley and New

Jersey

2003

2 P.S.Kalsi Spectroscopy of Organic

Compounds 6th Edition

New Age International

Publishers. 2007

3 William Kemp NMR in Chemistry - Macmillan Education

Ltd, London 1986

4. R. S. Drago

Physical Methods in Chemistry - W. B. Sounders 1983

5. Alan Hinchliffe

Molecular Modelling for

Beginners 2

nd Edition Wiley Publication 2008

6. Andrew R. Leach

Molecular Modelling 2

nd Edition

Pearson Prentice Hall, England

2001

1. , UNIT I: Text Book 1 UNIT II: Text Book 2 UNIT III: Text Book 3, 4

UNIT IV: Text Book 5 UNIT V: Text Book 6

BOOKS FOR REFERENCES

S.


Year

1 B. P. Straughan and S.

Walker

Spectroscopy, Vol. 1 - Chapman and Hall

1967

2 H. Kaur

Spectroscopy 3rd Edition

Pragati Prakasan

Publications, Meerut 2006

3

E.AV.Ebsworth,

W.H. Rankin and

Cradock

Structural Methods in

Inorganic Chemistry - ELBS 1987

4.

Robert M.

Silverstein, Francis

X.Webster, David

Kiemle

Spectrometric

Identification of Organic

Compounds - John Wiley & sons 2005

5.

A.K.Srivastava

and P.C.Jain

Instrumental approach to

chemical analysis 4th revised

Edition S.Chand company

Ltd. 2009

6.

Willard, Merrit,

Dean and Settle

Instrumental Methods of

Analysis 6th Edition

CBS Publishers and

Distibutors 1986


Outcomes:


I 20MPCH1CC2 ADVANCED PHYSICAL

METHODS AND MOLECULAR

MODELLING IN CHEMISTRY

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)


(PSOs)


CO1 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO2 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO3 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO4 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO5 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

Number of Matches=39, Relationship is : HIGH

Prepared by: Checked by:

Dr.M.Purusothamam Dr.Syed Ali Badusha



Max. marks

Internal marks

External marks

I 20MPCH1CC3 Core – III TEACHING AND LEARNING

SKILLS 4 4 100 25 75

Course Outcomes

1. Compare and differentiate communication and interaction methods

2. Build educative skill

3. Plan teaching strategies

4. Compose teaching materials using technologies

5. Assess the students by guidance and counselling

Unit - I 12 hours

Communication and Interaction The theory of communication – communication cycle – Types of communication,

communication and language, communication in the class room, Lecture and Lecture demonstration as

communication. Interaction methods – Interaction analysis, observation schedule and record. Bale’s

interaction process categories – Flander’s system of interaction analysis – verbal interaction category

system. #Reciprocal category system – Equivalent talk categories#.

Unit – II 12 hours

Educative Skill

Psychology – Definition – Nature – Meaning of Educational Psychology – Definition – Nature –

Scope. Teaching and learning – meaning – characteristics –effective teaching – concept of learning –

comparison between teaching and learning. Mental health – Frustration –# concept of adjustment –

Defence mechanism# – Mental hygiene.

Unit – III 12 hours

Uses of teaching strategies

Group methods of instruction – lecture – demonstration – seminars – workshops – case analysis

– panel discussion – team teaching – individual approaches – Teleconferencing – Video conferencing –

Description – Advantages – Micro teaching –Characteristics of Micro teaching – Teaching skills -

Programmed Instruction - Computer Assisted Instruction (CAI) – # Language Laboratory#.

Unit – IV 12 hours

Educational Technology

Educational technology – definition – objectives – teaching technology – characteristics of

teaching technology – behavioral technology – pedagogy of teaching – General advantage of using

teaching aids – Broad classification of teaching aids – Hardware and software in teaching aids.

Instructional media – media attributes – multimedia and instructional development – # Multimedia

centre – uses and abuses of multimedia#.

Unit-V 12 hours

Guidance and Counselling

Meaning and definition of Guidance and Counselling- need for guidance – aims of

guidance- nature of guidance - principles of guidance philosophy- types of guidance-

educational, vocational, personal and social guidance- benefits of guidance- benefits to

students, teachers, parents community and administrators – role and functions of guidance

cell – Counsellor-definition, qualities of a good counsellor, characteristics of counselling,

#types of counselling# class teacher as a counsellor- specific duties of a teacher in guidance

service, differences between guidance and counselling.

#......... # Self study

Text Books

S.


Year

1 Zikr – ur Rahman

Modern Teaching

Methods and

Techniques

5th

Edition

Anmol

Publications Pvt

Ltd, New Delhi

2000

2 R. A. Sharma

Educational

technology and

management models

media and methods

- R. Lall Book

Depot. Meerut 2007

3 Vanaja Educational

technology

7th

Edition

Neel Kamal

publications Pvt.

Ltd. Hyderabad

2016

4.

K. Nagarajan and

Deva

Seetharaman

Psychology of

learning and Human

Development

2nd

Edition

Sriram Publishers,

Chennai 2014

Books for References

S.


Year

1 Bn Dash

Elementary

Educational

Psychology and

Methods of teaching

-

Neel Kamal

publications Pvt.

Ltd., New Delhi

2007

2

P. Sambasiva

Rao and D.

Bhaskar Rao

Techniques of

Teaching Psychology -

Sonali publications,

New Delhi 2006

3 S. K. Kochhar

Methods and

Techniques of

Teaching

- Sterling Publisher

Pvt. Ltd, New Delhi 2004

4.

K. Sampath, A.

Panner selvam

and S. Santhanam

Introduction to

Educational

Technology

4th revised

ed

Sterling Publisher

Pvt. Ltd 2000

5. S. Robinson Fundamentals of

Education Psychology 2nd Edition Ane Books Pvt. Ltd 2008

6. T.M. Srinivasan

Use of Computers and

Multimedia in

Education

- Aavisakar

publication, Jaipur 2002

7. K. Sundarrajan Internet -

Kannadhasan

publications,

Chennai

1998

Web References:

https://swayam.gov.in/nd2_ntr20_ed21/preview


Outcomes:


I 20MPCH1CC3 TEACHING AND

LEARNING SKILLS

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)


(PSOs)


CO1 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO2 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO3 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO4 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO5 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

Number of Matches= 44, Relationship is : High


Dr.K.Loganathan Dr.Syed Ali Badusha

https://swayam.gov.in/nd2_ntr20_ed21/preview



Max. marks

Internal marks

External marks

I 20MPCH1CC4 Core – IV SYNTHETIC ORGANIC

CHEMISTRY 4 4 100 25 75

Course Outcomes: 1. Apply various concepts, applications and interpretation of NMR and mass spectroscopy

2. Solve structural elucidation of organic compounds by NMR spectroscopy

3. Appraise the principle of XRD in structure determination

4. Investigate special techniques used in synthetic methods

5. Design the idea of innovative routes to organic synthesis using reagents

UNIT - I

NMR Spectroscopy: 1H- NMR principles, chemical shift and its applications. Coupling constant and its

applications. Fourier transforms NMR – Second order spectra –Systems with chemical

exchange – Study of fluxional behavior of molecules. 13C- NMR spectroscopy – Basic theory of FT-NMR – Relaxation – Broad band

decoupling – Off resonance decoupling and chemical shift correlations (CH, CH2, CH3,

aromatic). Identification of structure based on NMR data. Application of Dept, 1H- 1H COSY,

NOESY in structure elucidation of organic compounds.

UNIT- II

Mass Spectroscopy:

Instrumentation – Resolution, base peak, isotopic peaks, metastable peak, parent peak

– determination and use of molecular formula, recognition of molecular ion peak – ionization

by EI, CI, FAB and ESI methods – Fragmentation – General rules –Pattern of fragmentation

for various classes of compounds – McLafferty rearrangement – Importance of metastable

peaks –Molecular fragmentations – Ion reactions.

X-ray diffraction studies:

Bragg’s equation, Experimental methods, structure determination.

UNIT - III

Special Techniques in synthetic methods:

Phase transfer catalysis, Micellar medium synthesis, polymer supported synthesis,

ionic liquids, microwave assisted synthesis, sonochemistry.

UNIT - IV

Important Reagents in organic synthesis:

Use of following reagents in organic synthesis and functional group transformations –

complex metal hydrides, Gilman’s reagent, lithium dim ethyl cuprate, LDA, DCC, 1,3 -

Dithane (reactivity umpolung). Merrifield resin, Peterson’s synthesis, Lawesson’s reagent.

Wilkinson’s catalyst, Bakeryeast., hypervalent organo iodine’s (introduction) and reagents

of non-transition metals – Zn, Cd, Sn and In.

UNIT – V

Reagents for Oxidation: Osmium tetroxide, Sharpless asymmetric epoxidation, Chromyl chloride, Ozone,

DDQ, Dioxiranes, Lead tetra acetate, Selenium dioxide, DMSO either with Ac2O or Oxalyl

chloride, Dess-Martin reagent. LDA, Phase transfer catalysis (PTC), Merrifield resin, Baker’s

yeast.

Reagents for Reduction: Catalytic hydrogenation and dehydrogenation, Reduction with LiAlH4, NaBH4,

Tritertiarylbutoxy aluminum hydride, NaCNBH3, Tributyltin hydride, Me3SiCN, Alkali

metals for reduction, Reductions with hydrazine’s.

Books for Reference: 1. Rusell S.Drago, Physical Methods in Chemistry, W.B.Saunders Company.

2. G.Aruldhas, Molecular structure and spectroscopy, second edition, PHI learning Pvt.

Ltd., New Delhi, 2008.

3. Jerry March – “Advanced organic chemistry reactions mechanism and sturcure”, 4th

Ed., (2006), Wiley India Pvt. Ltd.

4. F.A. Carey and R.J. Sundberg – “Advanced organic chemistry” Vol. I and II– 3rd Ed.,

(1984), Plenum Publications.

5. R.O.C. Norman – “Principles of Organic Synthesis” – 2nd Ed., (1986), Chapman and

Hall Publications, New York.

6. O.P. Agarwal – “Reactions and Reagents in Organic Chemistry”, 5th Ed., (2005), Goel

Publishing House, Meerut.

7. Robert M. Silverstein, Francis X. Webster, David Kiemle “Spectrometric Identification

of Organic Compounds”, John Wiley & sons (2005).

Web References:

https://nptel.ac.in/courses/102/103/102103044/ https://nptel.ac.in/courses/104/104/104104101/


Outcomes:


I 20MPCH1CC4 SYNTHETIC ORGANIC

CHEMISTRY

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)


(PSOs)


CO1

CO2

CO3

CO4

CO5



Dr. M. Seeni Mubarak

http://www.amazon.ca/s/180-1123734-4863060?_encoding=UTF8&field-author=Robert%20M.%20Silverstein&search-alias=books-ca

http://www.amazon.ca/s/180-1123734-4863060?_encoding=UTF8&field-author=Francis%20X.%20Webster&search-alias=books-ca

http://www.amazon.ca/s/180-1123734-4863060?_encoding=UTF8&field-author=David%20Kiemle&search-alias=books-ca



Max. marks

Internal marks

External marks

I 20MPCH1CC4 Core – IV CORROSION STUDIES 4 4 100 25 75

Course Outcomes

1. Identify oxidizing/reducing agents in chemical reaction.

2. become familiarized with electrochemical process involved in corrosion process

3. apply standard reduction potential data to determine the relative strength of

oxidizing/reducing agents.

4. get knowledge to control corrosion of metals and alloys by using inhibitors

5. Construct an electrochemical cell diagram, including identifying the anode, cathode,

direction of electron flow, sign of the electrodes, direction of ion flow in salt bridge,

from a redox reaction or from short hand cell notation.

Unit-I

Corrosion - Definition, causes and cost - consequence - Theories of corrosion -

Direct chemical attack, electrochemical theory and acid theory - Different forms of

corrosion- uniform, pitting, galvanic, crevice, stress, erosion, film forming, intergranular,

dealloying, exfoliation and fretting - factors influencing corrosion - Nature of the metal -

oxidation potential, over voltage, purity and passive character - Nature of the environment -

temperature, moisture, impurities, pH and conductance.

Unit-II

Electrochemical aspects of corrosion - activation polarization, exchange current,

current density, concentration polarization, corrosion potential, corrosion current, charge

transfer resistance, linear polarization resistance, fmax and double layer capacitance, phase

angle - applications of Nernst, Tafel and Butler - Volmer's equations- corrosion rate-

expressions for corrosion rate.

Unit-III

Corrosion monitoring techniques - non electrochemical methods - weight loss

measurements and gasometric method – electro chemical methods - potentiodynamic

polarization and A.C impedance spectroscopy – Determination of surface coverage –

Biocidal efficiency and its determination - methods of corrosion control - modification of

metal, modification of environment and change of metal environment potential.

Unit-IV

Corrosion inhibitors - Definition, need and importance - classification of inhibitors -

acid, alkaline, neutral inhibitors and green inhibitors- vapour phase inhibitors - Recent

classification - neutralizers, barrier layer formers and scavengers – Theories of inhibition of

corrosion - mode of actions of inhibitors - adsorption - electrostatic, physical and chemical -

adsorption isotherms - Langmuir and Temkin's - principle and applications – Biocidal

efficiencies.

Unit-V

Organic inhibitors - advantages – anodic and cathodic inhibitors- nitrogen, oxygen

and sulphur containing organic compounds - mechanism of inhibition - formation of a

physical barrier, reduction in metal reactivity and change in the electrical double layer

structure - correlation between adsorption and inhibition of corrosion.

References:

1. Advanced physical chemistry, J.N, Gurtu and A.Gurtu, Pragati publications,

8th revised edition, 2007.

2. Essential of physical chemistry, Bahl, Tuli and Arun bahl, S.Chand publications,

2004.

3. An introduction to electrochemistry, Samuel.Glasstone, Affiliated East-west

private limited, New Delhi.

Online Reference

1. https://swayam.gov.in/nd1_noc20_mm27/preview


Outcomes:


I 20MPCH1CC4 CORROSION

STUDIES

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)


(PSOs)


CO1 √ √ √ √ √ √ √ √ √

CO2 √ √ √ √ √ √ √

CO3 √ √ √ √ √ √ √ √ √

CO4 √ √ √ √ √ √ √ √

CO5 √ √ √ √ √ √ √ √ √ √



Dr. A. Jamal Abdul Jafar

https://swayam.gov.in/nd1_noc20_mm27/preview



Max. marks

Internal marks

External marks

I 20MPCH1CC4 Core – IV PHYTOCHEMICAL

TECHNIQUES 4 4 100 25 75

Course Outcomes

After completion of the course the students

1. will able to isolate and separate the phytochemical compounds using various

techniques.

2. will know about characteristics of the phytochemical compounds.

3. Will Apply the microbial techniques using various procedure.

4. Analyze the compounds using various spectral techniques.

5. Evaluate the Nanoparticles using various Nano techniques.

UNIT - I Phytochemical Analysis

Methods of separation - Isolation and identification - Qualitative and quantitative analysis

of phenolic compounds - Anthocyanins – Alkaloids - Flavonoids - Xanthones - Stibenes -

Terpenoids, Steroids- Tannins- Saponins- Carbohydrates - Poly Phenols -Amino acids.

UNIT - II Separation Techniques

Methods of Extraction - cold percolation method - soxhlet method - methods of isolation -

methods of separation.

Chromatography - Definition – Principle – Classification - Paper Chromatography -

Column Chromatography - Thin layer Chromatography - Gas Chromatography - High

performance Liquid Chromatography - Vacuum distillation - Crystallization techniques.

UNIT - III Microbial Techniques

Classification of plants - Nomenclature - Cells - Tissues - Structures and functions of

Cells and tissues - Primary metabolites - Secondary metabolites - Microorganism - Biological

activities - Microbial studies - techniques.

UNIT - IV Spectral Techniques

Spectroscopy - Principle - Classification - UV - VIS spectroscopy - IR spectroscopy-

Proton and carbon -13 NMR spectroscopy - FTIR - GC – MS, LC - MS - Mass spectroscopy

- Principle - Instrumentation and Applications.

UNIT - V Nano Techniques

Nano Particles - Classification of Bio synthesis Nano particles - Characterization -

Scanning Electron Microscopy (SEM) -Atomic Force Microscopy (AFM) - Transmission

Electron Microscopy (TEM) - Resolution and Scanning Transition Electron Microscopy

(STEM) - Scanning Tunneling Microscopy (STM) - Scanning Near field Optical Microscopy

(SNOM).

Reference Books:

1. Francis A.Carey, “Organic chemistry”, 5th edition, Tata McGraw Hill, New Delhi,

1993.

2. Graham Solomns T.W, “Organic chemistry”, Vol. I & II 5th edition, John Wiley &

Sons, New York, 1992.

3. O.P.Agarwal, “Organic chemistry” Reactions and Reagents. Published by Krishna

Prakashan media (P) Ltd. 2016.

4. Morrison and Boyd, “Organic chemistry”, Paramount Communications,2007

5. Atta-Ur-Rahman and M.I.Choudhary, New Trends in Natural Products chemistry,

Gordon & Breach Science Publishers, I Edn., 1998.

6. Principle of Nano Technology by Michael Wilson, Overseas press India (P.Ltd)

New Delhi-110002, 1st Edition 2005.

Mapping:


I 20MPCH1CC4 PHYTOCHEMICAL

TECHNIQUES

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)


(PSOs)


CO1

CO2

CO3

CO4

CO5

Number of Matches= 34 Relationship is : Moderate


Dr. A. Zahir Hussain



Max. marks

Internal marks

External marks

I 20MPCH1CC4 Core – IV PLANT AND

ENVIRONMENTAL CHEMISTRY

4 4 100 25 75

Course outcome

After completion of the course students were able to

1. Check the water quality of sample

2. Create awareness to the public regarding water quality standard parameters.

3. Isolate and characterize the phytochemical present in plant sources.

4. Use the phytochemicals for drug synthesis.

5. To elucidate the structures of isolated compounds from plant source.

UNIT- I

Environment

Concept of environmental chemistry - components of environment- factors affecting

environment, segments of environment- formation of physical chemical and biological

weathering, composition of soil- process of soil formation. Physical and chemical properties

of Air, soil and water, Atmosphere composition- pressure and temperature changes of

troposphere, stratosphere, mesosphere and ionosphere.

UNIT- II

Analysis of Water Pollution

Objectives of analysis - Sampling techniques- parameter for analysis – color ,turbidity

- total solids - conductivity - acidity - alkalinity - hardness - chloride sulphate - fluoride

phosphate, nitrate, DO, BOD, COD and heavy metal analysis- Impact of cadmium,

chromium, copper, lead, zinc, manganese, mercury and arsenic- Prevention and control

measures.

UNIT- III

Spectroscopy technique

Laws of absorption – Beer Lambert’s law- Instrumentation and applications of

turbidimetry, nephelometry and colorimetery. AAS-principle, instrumentation and

applications. Atomic Emission spectroscopy – principle, instrumentation and applications. FT

–IR- theory and applications.

UNIT- IV

Phytochemical analysis

Introduction and plant chemicals, methods of extraction, isolation, separation and

identification- Soxlet method- principle - procedure - uses. Preliminary phytochemical

screening and detection of various plant constituents. Bioactive compounds and its biological

activities- Applications.

UNIT- V

Chromatography and separation Techniques

Definition, Types, column chromatography, HPLC, TLC. Principle - Experimental

techniques – Applications.. GC -MS, principle, technique and applications.

REFERENCES:

1. B. K. Sharma and H. Kaur, Water Pollution Krishna Prakashan Mandir, Meerut.

2. T. H.Y. Tebbut, Principles of Water Quality Control A. Butterworth-Heinemann

Cleaning our environment - a chemical perspective 2nd edition, American

Chemical Society.

3. J Shapiro Radiation Protection 4th Ed. Harvard University Press, London.

4. S K Banedee Environmental Chemistry Goel Publishing House, Meerut.

5. G. W. Ewing Instrumental Method of Chemical Analysis, McGraw- Hill, New

York.

6. H. Kaur - "Instrumental methods of Chemical Analysis", 6,j' edition, (2010),

Pragati prakasan Publications, Meerut.

7. Willard, Meenitt, Dean and Settle - "Instrumental Methods of Analysis", 7 th

Ed.,(2006), CBS Publishers.

8. B.K. Sharma - "Instrumental methods of Analysis", (2000), Goel Publications.

9. S.M. Khopkar, "Basic Concepts of Analytical Chemistry", Revised edition (2006)

Wiley Eastern Ltd.

10. R.A. Day and A.L. Underwood - "Quantitative Analysis", (1999), PrenticeHall of

India Pvt., Ltd., New Delhi.

11. H. Kaur - "Instrumental methods of Chemical Analysis", 6,j' edition, (2010),

Pragati prakasan Publications, Meerut.

12. Willard, Meenitt, Dean and Settle - "Instrumental Methods of Analysis", 7 th

Ed.,(2006), CBS Publishers

13. Principles of Instrumental Analysis by Donglas A. Skoog, James, J. Leary,

4th Edition.

14. Instrumental Methods of Chemical Analysis – B. K. Sharma - 9th Edition.

15. Instrumental Methods of Analysis – Hobert H. Willard, 7th Edition.

Online Course References

1. https://swayam.gov.in/nd2_cec19_bt03/preview

2. https://swayam.gov.in/nd1_noc19_bt17/preview

Relationship Matrix for Course Outcomes, Programme Outcomes and Programme

Specific Outcomes:


I 20MPCH1CC4 PLANT AND

ENVIRONMENTAL

CHEMISTRY

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)


(PSOs)


CO1 √ √ √ √

CO2 √ √ √ √ √ √ √ √

CO3 √ √ √ √ √ √ √ √

CO4 √ √ √ √ √ √ √ √ √

CO5 √ √ √ √ √ √ √



Dr. J. Sirajudeen

https://swayam.gov.in/nd2_cec19_bt03/preview

https://swayam.gov.in/nd1_noc19_bt17/preview



Max. marks

Internal marks

External marks


CHEMISTRY 4 4 100 25 75

Course Outcomes: Learners will be able to

1. Investigate the purity of a reaction mixture by various chromatographic techniques

2. Formulate a reaction pathway for the target material by disconnection approach

3. Design and validate various reactions, reagents and solvents

4. Determine the structure of unknown molecular entity by X-ray diffraction and NMR

spectroscopic techniques

5. Solve and generate molecular structure by various spectroscopic techniques

UNIT-I 12 hours

Chromatography :

Principle-types- Thin Layer Chromatography-Principle, experimental techniques,

applications of TLC. Paper chromatography-principle, types, experimental techniques of

paper chromatography, applications. Column Chromatography-definition, principle types,

Experimental techniques – Characteristics of good adsorbent – developers – techniques of

separation – detectors, applications. HPLC- principle, experimental technique, applications.

UNIT-II 12 hours

Disconnection approach:

An introduction to Synthons and synthetic equivalents, disconnection approach,

functional group interconversions. One group C-X and two group disconnections in 1, 2, 1, 3

-,1,4- & 1,5 difunctional compounds , Retro- synthesis of Alkene ,acetylenes and aliphatic

nitro Alcohols and carbonyl compounds, amines , the importance of the order of events in

organic synthesis, chemoselectivity, regioselectivity. Diels Alder reaction, Michael addition

and Robinson annulation. Retro- synthesis of aromatic Heterocycles and 3, 4, 5 and 6

membered carbocyclic and heterocyclic rings. Reversal of polarity (Umpolung).

UNIT-III 12 hours

Application of the following in synthesis:

Application of following reagents in synthesis. Complex metal hydrides, lithium

dialkyl cuprate, lithium diisopropylamide(LDA) Dicyclohexylcarbodiimide(DCC), Trimethyl

silyl iodide, tributyltin hydride, peracids, lead tetra acetate, Diazomethane , phase transfer

catalyst, Selenium dioxide, DDQ, periodic acid, KMnO4, CrO4, MnO2 and OsO4. Solvents -

comparative study on solvents like protic, aprotic, acidic and basic

UNIT-IV 12 hours

X-ray diffraction:

Fundamentals of X-ray diffraction, theory of X-ray diffraction, diffraction of x-rays

by crystals, determination of crystal structure (powder as well as single crystals),

Instrumentation, determination of lattice parameters, X-ray intensity calculations and

application of X-rays.

2D NMR spectroscopy:

Basic principles of COSY, ROSY and NOESY.

UNIT-V 12 hours

Reactions and reactivity of phenol, resorcinol, pyridine, pyrimidine and active methylene

compound ( malonic acid, malonic ester and malono nitrile)

Combined Spectroscopic problems of IR, 1H NMR, 13C NMR and Mass spectroscopy.

Books for Reference: S.


Year

1 H. Kaur Instrumental methods of

chemical analysis 12th Edition

Pragati prakashan,

Meerut

2016

2 A. K. Srivastava

and P.C. Jain



S. Chand & Co.,

New Delhi 2009

3 Stuart Warren

Organic Synthesis:

The Disconnection

Approach

- John Wiley & Sons. New

York 2008

4. R.O.C. Norman Principle of organic

synthesis. 3th Edition Taylor & Francis Ltd 1993

5.

Carey, Francis

A., Sundberg,

Richard J.

Advanced Organic Chemistry. Part B: Reaction

and Synthesis.

5th Edition Springer US 2007

6. P.S.Kalsi Spectroscopy of Organic



Publishers. 2007

7.

Robert M.

Silverstein,

Francis X.

Webster,

David J.

Kiemle,

David L. Bryce

Spectrometric


Compounds

8th Edition John Wiley & sons, Inc. 2014

Web References:


https://www.wiley.com/en-us/search?pq=%7Crelevance%7Cauthor%3ARobert+M.+Silverstein


https://www.wiley.com/en-us/search?pq=%7Crelevance%7Cauthor%3AFrancis+X.+Webster


https://www.wiley.com/en-us/search?pq=%7Crelevance%7Cauthor%3ADavid+J.+Kiemle


https://www.wiley.com/en-us/search?pq=%7Crelevance%7Cauthor%3ADavid+L.+Bryce

https://nptel.ac.in/courses/102/103/102103044/



Specific Outcomes:


I 20MPCH1CC4 SYNTHETIC

ORGANIC

CHEMISTRY

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)


(PSOs)


CO1 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO2 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO3 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO4 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO5 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

Number of Matches= 44 , Relationship is : High


Dr. K. Loganathan



Max. marks

Internal marks

External marks

I 20MPCH1CC4 Core – IV CORROSION INHIBITORS 4 4 100 25 75

Course Outcomes:

Learners will be able to

1. Investigate the types and influencing factors of corrosion

2. Assess the electrochemical aspects of corrosion

3. Evaluate the corrosion rate by Corrosion monitoring techniques

4. Solve corrosion by inhibitors

5. Generate new organic corrosion inhibitors

UNIT-I 12 hours

Corrosion

Corrosion-Definition, causes and cost- Theories of corrosion-Direct chemical attack,

electrochemical theory and acid theory -Types of corrosion - uniform, pitting, galvanic,

crevice, stress, erosion, film forming, intergranular, dealloying, exfoliation and fretting -

factors influencing corrosion - Nature of the metal - oxidation potential, over voltage, purity

and passive character - Nature of the environment - temperature, moisture, impurities, pH and

conductance.

UNIT-II 12 hours

Electrochemical aspects of corrosion

Electrochemical aspects of corrosion- exchange current, current density, activation

polarization, concentration polarization, corrosion potential, corrosion current, charge transfer

resistance and double layer capacitance - applications of Nernst, Tafel and Butler - Volmer's

equations- expressions for corrosion rate.

UNIT-III 12

hours

Corrosion monitoring techniques

Non electrochemical methods - weight loss measurements and gasometric method – electro

chemical methods - potentiodynamic polarization and A.C impedance spectroscopy -

methods of corrosion control - modification of metal, modification of environment and

change of metal environment potential.

UNIT-IV 12

hours

Corrosion inhibitors Definition, need and importance - classification of inhibitors - acid, alkaline and neutral

inhibitors - vapour phase inhibitors - Recent classification - neutralizers, barrier layer formers

and scavengers - mode of actions of inhibitors - adsorption - electrostatic, physical and

chemical - adsorption isotherms - Langmuir and Temkin's - principle and applications.

UNIT-V 12 hours

Organic inhibitors

Organic inhibitors- advantages - nitrogen and sulphur containing organic compounds -

mechanism of inhibition - formation of a physical barrier, reduction in metal reactivity and

change in the electrical double layer structure - correlation between adsorption and inhibition

of corrosion.



Year

1 J. N. Gurtu and

A. Gurtu

Advanced physical

chemistry

8th revised

edition Pragati Publication

2007

2 Bahl, Tuli and

Arun Bahl

Essential of Physical

Chemistry 4th Edition S. Chand Publications 2004

3. Samuel

Glasstone

An introduction to

Electrochemistry -

Affiliated East-West Private

Limited, New Delhi 2000

Web References: https://swayam.gov.in/nd1_noc20_mm04/preview


Outcomes:



INHIBITORS

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)


(PSOs)


CO1 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO2 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO3 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO4 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO5 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔



Dr. M. Anwar Sathiq




Max. marks

Internal marks

External marks


CHEMISTRY 4 4 100 25 75


1. Investigate the purity of a reaction mixture by various chromatographic techniques

2. Formulate a reaction pathway for the target material by disconnection approach

3. Design and validate various reactions, reagents and solvents

4. Determine the structure of unknown molecular entity by X-ray diffraction and NMR

spectroscopic techniques

5. Solve and generate molecular structure by various spectroscopic techniques

UNIT-I 12 hours

Chromatography :

Principle-types- Thin Layer Chromatography-Principle, experimental techniques,

applications of TLC. Paper chromatography-principle, types, experimental techniques of

paper chromatography, applications. Column Chromatography-definition, principle types,

Experimental techniques – Characteristics of good adsorbent – developers – techniques of

separation – detectors, applications. HPLC- principle, experimental technique, applications.

UNIT-II 12 hours

Disconnection approach:

An introduction to Synthons and synthetic equivalents, disconnection approach,

functional group interconversions. One group C-X and two group disconnections in 1, 2, 1, 3

-,1,4- & 1,5 difunctional compounds , Retro- synthesis of Alkene ,acetylenes and aliphatic

nitro Alcohols and carbonyl compounds, amines , the importance of the order of events in

organic synthesis, chemoselectivity, regioselectivity. Diels Alder reaction, Michael addition

and Robinson annulation. Retro- synthesis of aromatic Heterocycles and 3, 4, 5 and 6

membered carbocyclic and heterocyclic rings. Reversal of polarity (Umpolung).

UNIT-III 12 hours

Application of the following in synthesis:

Application of following reagents in synthesis. Complex metal hydrides, lithium

dialkyl cuprate, lithium diisopropylamide(LDA) Dicyclohexylcarbodiimide(DCC), Trimethyl

silyl iodide, tributyltin hydride, peracids, lead tetra acetate, Diazomethane , phase transfer

catalyst, Selenium dioxide, DDQ, periodic acid, KMnO4, CrO4, MnO2 and OsO4. Solvents -

comparative study on solvents like protic, aprotic, acidic and basic

UNIT-IV 12 hours

X-ray diffraction:

Fundamentals of X-ray diffraction, theory of X-ray diffraction, diffraction of x-rays

by crystals, determination of crystal structure (powder as well as single crystals),

Instrumentation, determination of lattice parameters, X-ray intensity calculations and

application of X-rays.

2D NMR spectroscopy:

Basic principles of COSY, ROSY and NOESY.

UNIT-V 12 hours

Reactions and reactivity of phenol, resorcinol, pyridine, pyrimidine and active methylene

compound ( malonic acid, malonic ester and malono nitrile)

Combined Spectroscopic problems of IR, 1H NMR, 13C NMR and Mass spectroscopy.



Year

1 H. Kaur Instrumental methods of


Pragati prakashan,

Meerut

2016

2 A. K. Srivastava

and P.C. Jain



S. Chand & Co.,

New Delhi 2009

3 Stuart Warren

Organic Synthesis:

The Disconnection

Approach

- John Wiley & Sons. New

York 2008

4. R.O.C. Norman Principle of organic

synthesis. 3th Edition Taylor & Francis Ltd 1993

5.

Carey, Francis

A., Sundberg,

Richard J.

Advanced Organic Chemistry. Part B: Reaction

and Synthesis.

5th Edition Springer US 2007

6. P.S.Kalsi Spectroscopy of Organic



Publishers. 2007

7.

Robert M.

Silverstein,

Francis X.

Webster,

David J.

Kiemle,

David L. Bryce

Spectrometric


Compounds

8th Edition John Wiley & sons, Inc. 2014

Web References:








https://www.wiley.com/en-us/search?pq=%7Crelevance%7Cauthor%3ADavid+L.+Bryce




Specific Outcomes:


I 20MPCH1CC4 SYNTHETIC

ORGANIC

CHEMISTRY

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)


(PSOs)


CO1 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO2 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO3 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO4 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO5 ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔ ✔



Dr. M. Purushothaman



Max. marks

Internal marks

External marks

I 20MPCH1CC4 Core – IV PHYSICAL ORGANIC

CHEMISTRY 4 4 100 25 75


1. Investigate the reaction rate and explain the theories of reaction rate. 2. Criticise the thermodynamic parameters and different types of catalysis. 3. Apply thevarious methods of reaction mechanism and linear free energy

relationship by Hammett and Taft equation. 4. Generate molecular structure by IR,UV,1 H NMR, and Mass spectroscopic

techniques 5. Design the reactions using different oxidizing reagents and solve the error by

statistical method.

UNIT-I Chemical Kinetics 1.1 Chemical Kinetics: Rate and rate constant – Order , Molecularity of the reaction- factors affecting rate of reactions – Experimental Determination of order of the reaction – First order reaction , characteristics and Examples of first order reactions 1.2 :Temperature effect on reaction rate - Arrhenius rate equation, energy of activation and its significance,Theories of reaction rates – simple collision theory, Absolute Reaction Rate Theory (ARRT) to simple uni-molecular and bimolecular processes - Comparison of collision theory & ARRT UNIT-II Kinetics of Thermodynamics and Catalysis 2.1 Thermodynamic parameters: Enthalpy, Entropy ,Energy of activation and Gibbs functions – some useful thermodynamics relationships. Applications of thermodynamic parameters: The applications of thermodynamics to rate processes – properties of transition state – uses of activation parameters. 2.2 Catalysis: Catalyst, types of catalysts - homogeneous and heterogeneous catalysis- Enzyme catalysis – Mechanism of single substrate reactions –Michaeli’s –Menten law- Influence of pH and temperature UNIT-III Correlation of Structure with reactivity 3.1 Methods of determining reaction mechanism: Energy profile diagrams – thermodynamic control and kinetic control of organic reactions – Isotope effects – Kinetic and non – kinetic methods of determination of reaction mechanisms – Product analysis and its importance. 3.2 Correlation Analysis: Linear free energy relationships – Hammett Equation- significance of sigma and rho applications deviations and limitations – Taft Equation and application.

UNIT-IV Spectro – Analytical Methods, Kinetics of Solutions 4.1 Spectro – Analytical Methods: Theory of spectrophotometry and colorimetry – Classifications of methods of colour measurements – Instrumentation of photoelectric colorimeter and spectrophotometers – Experimental colorimetric determination of chromium compounds – Introduction of spectroscopy-- types – electromagnetic spectrum – Instrumentations of IR,UV, 1H NMR and Mass spectroscopy 4.2 Kinetics of Solutions :Factors influencing reaction rates in solution – Applications of ARRT to Solution kinetics, Effects of solvents, double sphere and single sphere model- Effects of ionic Strength. UNIT-V Oxidation Reactions and Error Analysis 5.1 Oxidation Reactions Oxidation of Alcohols to aldehydes and ketones- Chromium Reagents such as K2Cr2O7 / H2SO4(Jones reagent) – Pyridinium chloro chromate (Corey’s reagent ), CrO3- Pyridine (Collins reagent) Oxidation involving C-C bond cleavage using HIO4,cycloalkanones using CrO3,Oxidation of C=C usingNalO4 and OsO4 aromatic ring using RuO4 5.2Error Analysis: Definition of Accuracy- Precision –classifications of errors- significant figures and computations – Mean deviation - Normal distribution Comparison of results the number of parallel determinations – the value of statistics Books for Reference:

S. No.

Author Name Book Name Edition Publisher detail Year

1 Laidler Chemical Kinetics 3rd edition Tata Mc Graw Hill.Co. New Delhi

1984

2

Kuriacose and Rajaram

Kinetics and Mechanism of Chemical transformation

1st edition Macmillan & Co 1993

3 V. B.Putania

Chemical kinetics 1st edition Campus Books International New Delhi

2004

4 Neil . S. Isaacs

Physical Organic Chemistry

2nd edition Longman Scientific and technical, New York

1987

5 Jerry March

Advanced Organic chemistry, Reactions, Mechanism and structure

4th edition wiley India PVT Ltd 2006

6 John R. Dyer

Applications of Absorption Spectroscopy of Organic Compounds

3rd edition Prentice Hall of India, New Delhi

1984

7 G. M. Barrow Introduction to Molecular Spectroscopy

6th edition Tata Mc Graw Hill.Co. New Delhi

1993

8

C. N. Banwell and E. M. Mccash

Fundamentals of Molecular Spectroscopy

4th edition Tata, McGraw-Hill Publishing Company Limited, New Delhi

2009

9

J. N. Gurtu and R. Kapoor

Organic Reactions Reagents”

1st edition, Sultan chand Company PVT, Ltd

1988

10 O. P. Agarwal

Reactions and Reagents in Organic chemistry

5th edition, “,Goel Publishing House, Meerut

2005

11 H. Kaur

Instrumental methods of chemical analysis

6th edition , Pragati Prakasan, Meerut

2010

12 Willard ,Meritt, Dean and Settle

Instrumental Methods of Analysis

7th edition CBS Publishers 1983

13 B. K. Sharma

Instrumental Methods of Analysis

19th edition Goel Publications 2000

Web References: https://nptel.ac.in/courses/102/103/102103044/

Relationship Matrix for Course Outcomes, Programme Outcomes and Programme Specific Outcomes:


I 20MPCH1CC4 PHYSICAL ORGANIC CHEMISTRY

4 4

Course Outcomes

(COs)

Programme Outcomes (POs)

Programme Specific Outcomes (PSOs)

PO1 PO2 PO3 PO4 PO5 PSO1

PSO2 PSO3

PSO4 PSO5

CO1 ✔ ✔ ✔ ✔ ✔ ✔

CO2 ✔ ✔ ✔ ✔ ✔

CO3 ✔ ✔ ✔

CO4 ✔ ✔ ✔ ✔ ✔ ✔ ✔

CO5 ✔ ✔ ✔ ✔ ✔



Dr. K. Periyasamy




Max. marks

Internal marks

External marks

I 20MPCH1CC4 Core – IV PHYTOCHEMISTRY 4 4 100 25 75

Course outcomes:

At the end of the course the learners could be able to

1. Understand about the phytochemicals.

2. Use the of medicinal plants for various diseases

3. Analyze the structure of various phytochemicals

4. Deduce new compounds in pharma industry

5. Summarize the new compounds in pharma industry.

UNIT‐ I

Introduction: An overview of Indian Medicine Ayuveda .Traditional medicine /

Ethnomedicine Classification, taxonomy and phytochemistry of Medicinal Plants.

Therapeutic potential of Medicinal plants ‐ A global perspective. Recent development of

some natural products.

UNIT‐ II

Secondary Metabolites

Definition, types (Alkaloids, Steroids, glycosides and flavonoids).Structure, Chemistry,

Biosynthesis, Metabolism and Regulation of Secondary Metabolites, Secondary metabolites

as plant therapeutics, Economic importance of Secondary products.

UNIT –III

Free radicals and Anti-oxidant Free radicals –Introduction, Modern theory of free radical, Oxidative Stress, Free radicals

Scavengers. Antioxidants‐Definition, property and biological significance, Antioxidants –

Enzymes and Vitamins. Antioxidants as markers for liver and kidney disease. Medicinal

plants as a source of Direct and Indirect antioxidant activity.

UNIT –IV

Methods of Extraction – Cold Percolation Method – Soxhlet Method – Methods of Isolation

– Methods of Separation.

Chromatography Principle and applications of Thin layer, Paper, Column, Gas and High

performance Liquid Chromatography.

Distillations – Steam, fractional, vacuum distillation and Crystallization Techniques.

UNIT‐ V

Phytochemical analysis, Biochemical methods, qualitative and quantitative analysis –

Separation procedures, Purification, and structural elucidation of secondary compounds of

therapeutic potential by Mass and Proton and Carbon-13 NMR Spectroscopy.

Reference:

1. Harborne JB, 1988, Phytochemical Methods: A Guide to Modern Techniques of Plant

Analysis, II Ed., London and New York, Chapman and Hall.

2. Furniss BS, Hannaford AJ, Smith PWG and Tatchell AR, 1989, Vogel’s Text book of

Practical Organic Chemistry, V Ed., Essex, England, ELBS with Longman.

3. Finar I.L. Organic Chemistry, Vol. 2. ELBS London.

4. Raphael Ikan, 1969, Natural Products: A Laboratory Guide, Jerusalem, Israel University

Press.

5. Jeffrey C, 1982, An Introduction Plant Taxonomy, II Ed., Cambridge, Cambridge

University Press.

6. William J and Sham M, 1976, Microorganisms, London, Mills and Boon Limited.

7. Ari Koskinen, 1993, Asymmetric Synthesis of Natural Products, Chichester, New York,

Brisbane, Toronto, Singapore, John Wiley and Sons.

8.Plant Biochemistry by Dey and J.B. Harborne

Relationship Matrix for Course Outcomes, Programme Outcomes and Programme Specific Outcomes :


I 20MPCH1CC4 PHYTOCHEMISTRY 4 4

Course Outcomes

(COs)

Programme Outcomes (POs)

Programme Specific Outcomes (PSOs)


CO1 √ √ √ √

CO2 √ √ √ √ √ √ √

CO3 √ √ √ √ √ √ √ √

CO4 √ √ √ √ √ √ √ √ √

CO5 √ √ √ √ √ √ √



Dr. J. MUNEER AHAMATH



Max. marks

Internal marks

External marks

I 20MPCH1CC4 Core – IV ENVIRONMENTAL

POLLUTION: WATER, AIR AND SOIL

4 4 100 25 75

OUTCOMES:

At the end of the course the learners could be able to

1. Understand about the environmental pollution

2. Know the importance of water quality parameters

3. Gain to get the knowledge of pollution control and adapt suitable methods

4. Treat the waste water by adapting suitable techniques

5. Aware the disease caused by pollutants

Unit-I

Introduction and Classification: Introduction-environmental science- Environmental

chemistry-Ecology-Definition-Ecosystem-Cycling of mineral elements and gases-

Phosphate cycle-Carbon cycle-Hydrogen cycle-Nitrogen cycle-Hydrological cycle-

Environmental segment-Pollution and its type: air pollution - Water pollution - Soil

pollution -Other type of pollution-and its effect and control-Remedial measures.

Unit II

Air pollution: Introduction - Source of air pollution - air pollutant - Classification and

effects of air pollutants-oxides of nitrogen, sulphur and carbon-acid rain-effects and control

–hydrogen sulphide - effects and control – carbon mono oxide – effects and control –

photochemical smog- effects and control –fly ash – effects and control – green house

effects – global warming – effects and control – ozone layer – ozone depletion –chloro

fluoro carbons – effects and control.

Unit III

Water pollution: Introduction – types of water – Water pollution – sources of water

pollution – water pollutants – classification – physical, chemical and biological – inorganic

pollutants and toxic metals – organic pollutants – radioactive pollutants in water –

pesticides and fertilizers – suspended particles – water quality- water quality index – ill

effects of water pollutants – fluorosis – water pollution control – water treatment – primary,

secondary and tertiary treatment – desalination- reverse osmosis – sewage and industrial

waste water treatment. Unit IV

Soil pollution: Introduction – type of soil –soil pollution - types – indicators of soil pollution –

plants as indicators of pollution - sources of soil pollution – fertilizers and pesticides –

radioactive pollutants – solids waters – soil sediments as pollutants – soil erosion –

treatment of soil pollutants –treatment of solid wastes – thermal methods – land filling –

composting – land protection – remedial measures for soil pollution.

Unit V

Analysis of pollutants: Introduction-analysis of water pollution – units – sampling –

devices and methods for sampling – measurement: Turbidimetry nephelometry -

Conductometry – analysis of water pollutants – units – sampling – devices and methods for

sampling – measurement : Atomic Absorption spectroscopy – titration – analysis of

different water quality parameters – BOD – COD analysis and monitoring of Pesticides,

carcinogens and industrial pollutants.

Suggested Readings:

1. B. K. Sharma and H. kaur, Environmental chemistry, Krishina Prakashan, Meerut, 1997

2. A.K. De, Environmental chemistry, Wiley Eastern Ltd., Meerut,1994

3. A.K. Mukherjee, Environmental pollution and Health Hazards causes and control,

Galgotia press, New Delhi, 1986.

4. N. Manivasakam, Physico-chemical examination of water, sewage and industrial

effluents, Pragati Prakashan Publ.Meerut, 1985.

5. B.K. Sharma - "Instrumental methods of Analysis", (2000), Goel Publications.

6. S.M. Khopkar, "Basic Concepts of Analytical Chemistry", revised edition (2006) Wiley

Eastern Ltd.

7. R.A. Day and A.L. Underwood - "Quantitative Analysis", (1999), Prentice Hall of India

Pvt., Ltd., New Delhi.


Specific Outcomes:

Semester I Code Title of the Course Hours Credits

I 20MPCH1CC4 Environmental Pollution:

Water, Air and Soil

4 4

Course

Outcomes

(COs)

Programme Outcomes (POs) Programme Specific Outcomes (PSOs)


CO1 √ √ √ √ √ √ √ √ √

CO2 √ √ √ √ √ √ √ √

CO3 √ √ √ √ √ √ √ √

CO4 √ √ √ √ √ √ √

CO5 √ √ √ √ √ √ √ √



Dr. R. Abdul vahith



Max. marks

Internal marks

External marks

I 20MPCH1CC4 Core – IV CORROSION INHIBITORS 4 4 100 25 75

Outcomes

At the end of the course, the student has

1. acquired basic electrochemical knowledge to understand corrosion processes

2. become familiarized with electrochemical process involved in corrosion process

3. been trained in corrosion protection measures

4. get knowledge to control corrosion of metals and alloys by using inhibitors

5. apply Nernst equation and the Tafel equation to different electrochemical systems

Unit-I

Corrosion - Definition, Historical lessons - causes and cost- consequence -

Orthodontic wires-Types – Uses- Theories of corrosion-Direct chemical attack,

electrochemical theory and acid theory - Different forms of corrosion- uniform, pitting,

galvanic, crevice, stress, erosion, film forming, intergranular, dealloying, exfoliation and

fretting - factors influencing corrosion - Nature of the metal - oxidation potential, over

voltage, purity and passive character - Nature of the environment - temperature, moisture,

impurities, pH and conductance.

Unit-II

Electrochemical aspects of corrosion - current density, exchange current, activation

polarization, concentration polarization, corrosion potential, corrosion current, charge

transfer resistance, linear polarization resistance, phase angle, fmax and double layer

capacitance - applications of Nernst, Tafel and Butler - Volmer's equations- corrosion rate-

expressions for corrosion rate.

Unit-III

Corrosion monitoring techniques - non electrochemical methods - weight loss

measurements and gasometric method – electro chemical methods - potentiodynamic

polarization and A.C impedance spectroscopy – Determination of surface coverage –

Biocidal efficiency and its determination - methods of corrosion control - modification of

metal, modification of environment and change of metal environment potential.

Unit-IV

Corrosion inhibitors - Definition, need and importance - classification of inhibitors -

acid, alkaline, neutral inhibitors and green inhibitors- vapour phase inhibitors - Recent

classification - neutralizers, barrier layer formers and scavengers – Theories of inhibition of

corrosion - mode of actions of inhibitors - adsorption - electrostatic, physical and chemical -

adsorption isotherms - Langmuir and Temkin's - principle and applications – Biocidal

efficiencies – Determination of biocidal efficiency –CFU.

Unit-V

Organic inhibitors - advantages – anodic and cathodic inhibitors- nitrogen, oxygen

and sulphur containing organic compounds - mechanism of inhibition - formation of a

physical barrier, reduction in metal reactivity and change in the electrical double layer

structure - correlation between adsorption and inhibition of corrosion.

References:

4. Advanced physical chemistry, J.N, Gurtu and A.Gurtu, Pragati publications,

8th revised edition, 2007.

5. Essential of physical chemistry, Bahl, Tuli and Arun bahl, S.Chand publications,

2004.

6. An introduction to electrochemistry, Samuel.Glasstone, Affiliated East-west

private limited, New Delhi.

Online Reference

1. https://swayam.gov.in/nd1_noc20_mm27/preview

Relationship Matrix for Course Outcomes, Programme Outcomes and

Programme Specific Outcomes:



INHIBITORS

4 4

Course

Outcomes

(COs)

Programme Outcomes

(POs)


(PSOs)


CO1 √ √ √ √ √ √ √ √

CO2 √ √ √ √ √ √ √

CO3 √ √ √ √ √ √ √ √

CO4 √ √ √ √ √ √ √ √

CO5 √ √ √ √ √ √ √ √



Dr. S. S. Syed Abuthahir


M.Phil. CHEMISTRYStructural Methods in Inorganic Chemistry - 1987 4. Identification of Organic...

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