MORPHISTO GmbH Safety Data Sheet€¦ · according to Regulation (EC) No 1907/2006 Safety Data...
Transcript of MORPHISTO GmbH Safety Data Sheet€¦ · according to Regulation (EC) No 1907/2006 Safety Data...
according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumpermanganat-Schwefelsäure
Revision date: 13.02.2020 Product code: 15436.xxxxx Page 1 of 7
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Kaliumpermanganat-Schwefelsäure
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
laboratory reagent
none
Uses advised against
1.3. Details of the supplier of the safety data sheet
MORPHISTO GmbHCompany name:
Street: Weismüllerstr. 45
Place: D-60314 Frankfurt am Main
Telephone: Telefax:+49 (0) 69 / 400 3019-60 +49 (0) 69 / 400 3019-64
http://www.morphisto.deInternet:
Poison Information Center Mainz, Germany, Tel: +49(0)6131/192401.4. Emergency telephone
number:
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Regulation (EC) No. 1272/2008
This mixture is not classified as hazardous in accordance with Regulation (EC) No. 1272/2008.
2.2. Label elements
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Hazardous components
QuantityChemical nameCAS No
EC No Index No REACH No
GHS Classification
1 - < 5 %7664-93-9 sulphuric acid ... %
231-639-5 016-020-00-8
Skin Corr. 1A; H314
Full text of H and EUH statements: see section 16.
Further Information
Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article
59 (REACH)
SECTION 4: First aid measures
4.1. Description of first aid measures
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data
sheet if possible).
General information
Provide fresh air. In case of respiratory tract irritation, consult a physician.
After inhalation
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumpermanganat-Schwefelsäure
Revision date: 13.02.2020 Product code: 15436.xxxxx Page 2 of 7
After contact with skin, wash immediately with: Water and soap. If skin irritation occurs: Get medical
advice/attention.
After contact with skin
In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently consult an ophthalmologist.
After contact with eyes
Rinse mouth immediately and drink plenty of water. (200-500 ml)
Do NOT induce vomiting. Call a physician immediately.
After ingestion
4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Carbon dioxide (CO2). Dry extinguishing powder. alcohol resistant foam. Atomized water.
Suitable extinguishing media
High power water jet.
Unsuitable extinguishing media
5.2. Special hazards arising from the substance or mixture
Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2). Sulphur oxides
In case of fire: Wear self-contained breathing apparatus.
5.3. Advice for firefighters
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
Additional information
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment. See protective measures under point 7 and 8.
Do not allow to enter into surface water or drains.
Discharge into the environment must be avoided.
6.2. Environmental precautions
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Suitable material for diluting or neutralizing: caustic soda, diluted.
Treat the recovered material as prescribed in the section on waste disposal .
Clear contaminated areas thoroughly.
6.3. Methods and material for containment and cleaning up
See protective measures under point 7 and 8.
6.4. Reference to other sections
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid contact with skin, eyes and clothes.
Wear suitable protective clothing. ( See section 8. )
Use extractor hood (laboratory).
Advice on safe handling
The product is not: Combustible.
Advice on protection against fire and explosion
Print date: 13.02.2020GB - ENRevision No: 1,1
according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumpermanganat-Schwefelsäure
Revision date: 13.02.2020 Product code: 15436.xxxxx Page 3 of 7
Usual measures for fire prevention.
7.2. Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a cool, well-ventilated place. Suitable material for Container: polyethylene.
Glass.
Unsuitable materials for Container: Aluminium. Zinc.
Requirements for storage rooms and vessels
Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Infectious substances. Radioactive
substances.
Hints on joint storage
Store small packages in a suitable, robust cabinet. Keep container tightly closed in a cool, well-ventilated place.
Protect against: UV-radiation/sunlight.
Further information on storage conditions
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Exposure limits (EH40)
Categoryfibres/mlmg/m³ppmSubstanceCAS No Origin
TWA (8 h)-Sulphuric acid (mist)7664-93-9 0.05 WEL
8.2. Exposure controls
Provide adequate ventilation as well as local exhaustion at critical locations.
@1001.B010017 Use extractor hood (laboratory).
Appropriate engineering controls
Always close containers tightly after the removal of product.
Protective and hygiene measures
Wear safety glasses; chemical goggles (if splashing is possible).
Eye/face protection
In case of prolonged or frequently repeated skin contact:
Pull-over gloves of rubber. EN ISO 374
Suitable material:
(penetration time (maximum wearing period): >= 8 h)
Butyl rubber. (0,5 mm)
Protective clothing should be selected, depending on concentration and quantity of the hazardous substance.
The chemical resistance of the products should be discussed with suppliers.
Hand protection
No special measures are necessary.
Skin protection
With correct and proper use, and under normal conditions, breathing protection is not required.
Respiratory protection necessary at:
exceeding exposure limit values
Suitable respiratory protective equipment: gas filtering equipment (EN 141). Typ: E
Respiratory protection
No special measures are necessary.
Environmental exposure controls
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Safety Data SheetMORPHISTO GmbH
Kaliumpermanganat-Schwefelsäure
Revision date: 13.02.2020 Product code: 15436.xxxxx Page 4 of 7
dark violet
liquidPhysical state:
Colour:
9.1. Information on basic physical and chemical properties
SECTION 9: Physical and chemical properties
stingingOdour:
pH-Value (at 20 °C): not determined
Changes in the physical state
>100 °CFlash point:
none
Explosive properties
Lower explosion limits:
Upper explosion limits:
none
Oxidizing properties
Density (at 20 °C): ~1,03 g/cm³
Water solubility: miscible.
SECTION 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
Stable under normal storage and handling conditions.
10.3. Possibility of hazardous reactions
No information available.
heat.
10.4. Conditions to avoid
metals in powder form. strong alkalis. Reducing agents, strong.
10.5. Incompatible materials
No information available.
10.6. Hazardous decomposition products
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicocinetics, metabolism and distribution
No information available.
Acute toxicity
Based on available data, the classification criteria are not met.
No information available.
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Safety Data SheetMORPHISTO GmbH
Kaliumpermanganat-Schwefelsäure
Revision date: 13.02.2020 Product code: 15436.xxxxx Page 5 of 7
Chemical nameCAS No
SourceSpeciesDoseExposure route Method
7664-93-9 sulphuric acid ... %
RatLD50 2140
mg/kgECHA Dossieroral
inhalation (4 h) aerosol LC50 (0,85)
mg/l
Mouse. ECHA Dossier
Based on available data, the classification criteria are not met.
Irritant effect on the eye: slightly irritant but not relevant for classification.
Irritant effect on the skin: slightly irritant but not relevant for classification.
Irritation and corrosivity
Sensitising effects
Based on available data, the classification criteria are not met.
No information available.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
No information available.
STOT-single exposure
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
No information available.
STOT-repeated exposure
Aspiration hazard
Based on available data, the classification criteria are not met.
No information available.
Specific effects in experiment on an animal
SECTION 12: Ecological information
12.1. Toxicity
No information available.
CAS No Chemical name
[h] | [d]Aquatic toxicity Dose SourceSpecies Method
sulphuric acid ... %7664-93-9
Acute fish toxicity 96 h ECHA DossierLC50 16 mg/l Lepomis macrochirus
Acute algae toxicity 72 h ECHA DossierErC50 >100
mg/l
Desmodesmus
subspicatus
Acute crustacea toxicity 48 h ECHA DossierEC50 >100
mg/l
Daphnia magna
12.2. Persistence and degradability
The methods for determining the biological degradability are not applicable to inorganic substances.
12.3. Bioaccumulative potential
No information available.
No information available.
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
No information available.
SECTION 13: Disposal considerations
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Safety Data SheetMORPHISTO GmbH
Kaliumpermanganat-Schwefelsäure
Revision date: 13.02.2020 Product code: 15436.xxxxx Page 6 of 7
13.1. Waste treatment methods
Disposal recommendations
Contents / container can be disposed of in accordance with national regulations. Product is acid. The product
needs to apply neutralizing agents before draining to wastewater treatment plants.
List of Wastes Code - residues/unused products
160509 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and
discarded chemicals; discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16
05 08
List of Wastes Code - used product
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and
discarded chemicals; discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16
05 08
160509
List of Wastes Code - contaminated packaging
WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; absorbents, filter materials, wiping
cloths and protective clothing; absorbents, filter materials, wiping cloths and protective clothing other
than those mentioned in 15 02 02
150203
Non-contaminated packages may be recycled.
Contaminated packaging
SECTION 14: Transport information
Land transport (ADR/RID)
14.1. UN number: No dangerous good in sense of these transport regulations.
Inland waterways transport (ADN)
14.1. UN number: No dangerous good in sense of these transport regulations.
Marine transport (IMDG)
14.1. UN number: No dangerous good in sense of these transport regulations.
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: No dangerous good in sense of these transport regulations.
14.5. Environmental hazards
noENVIRONMENTALLY HAZARDOUS:
14.6. Special precautions for user
No information available.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
No information available.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
No information available.2004/42/EC (VOC):
National regulatory information
1 - slightly water contaminatingWater contaminating class (D):
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information
Print date: 13.02.2020GB - ENRevision No: 1,1
according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumpermanganat-Schwefelsäure
Revision date: 13.02.2020 Product code: 15436.xxxxx Page 7 of 7
Changes
Rev. 1,0 ; 11.07.2013 Initial release
Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route ( European Agreement
concerning the
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations
Concerning the International Transport of Dangerous Goods by Rail )
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
NOAEL: No observed adverse effect level
NOAEC: No observed adverse effect concentration
H314 Causes severe skin burns and eye damage.
Relevant H and EUH statements (number and full text)
The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the product
named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be
transferred to other products. In the case of mixing the product with other products or in the case of
processing, the information on this safety data sheet is not necessarily valid for the new made-up material.
Further Information
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)
Print date: 13.02.2020GB - ENRevision No: 1,1