Molten Salt Oxidation - EU-project PREDIS
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This project has received funding from the Euratom research and training programme 2014-2018 under grant agreement No 945098. Molten Salt Oxidation JAN HADRAVA, CVREZ VOJT Ě CH GALEK Contact:[email protected]
Transcript of Molten Salt Oxidation - EU-project PREDIS
This project has received funding from the Euratom research and trainingprogramme 2014-2018 under grant agreement No 945098.
Molten Salt Oxidation
JAN HADRAVA, CVREZ
VOJTĚCH GALEKContac t : j an .had rava@ cv rez . cz
This project has received funding from the Euratom research and trainingprogramme 2014-2018 under grant agreement No 945098.
Laboratory of Radioactive Waste Management
• For R&D of innovative method forflameless oxidation of liquid (oils) andsemi-liquid (spent ion resins) organicwaste
• Aim of this technology is to evaluate itsreal operational applicability for disposalof liquid and semi-liquid waste from theenvironmental and technological point ofview.
• Applicability will be based onexperimental experience
• Possibility to use MSO for disposal ofthe organic waste from GEN IV reactors
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This project has received funding from the Euratom research and trainingprogramme 2014-2018 under grant agreement No 945098.
Laboratory of Radioactive Waste ManagementFlameless oxidation occurs within the moltensalt with high temperatures (to 1000 °C)Alkaline based salts are the best as moltenbaths
Na2CO3, K2CO3,Ternary melts: Na2CO3 + K2CO3 + Li2CO3
MSO is used for lowering the volume of theorganic wasteMSO consist:
Fuel dosage system (for solid/ liquidmaterials)Two-stage reactor systemFlue gas treatmentAnalyzer system for online, offline analysisof the flue gasSystem of spent molten salt disposal
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This project has received funding from the Euratom research and trainingprogramme 2014-2018 under grant agreement No 945098.
Laboratory of Radioactive Waste Management
§ MSO – laboratory scale:• One stage reactor vessel with
volume of 2 l (0,5 l of moltensalt)
• For small scale laboratoryexperiments• New salts melts• Organic waste disposal• Material (metal and ceramic)
corrosion experiments
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This project has received funding from the Euratom research and trainingprogramme 2014-2018 under grant agreement No 945098.
Laboratory of Radioactive Waste Management
§ Reactor MSO – pilot scale:• Reactor vessels are made from Inconel 600• Reactors volume is 80 l (40 maximum volume of
the molten salt)• Reactor vessel is protected from overpressure• Concentration of CO is limited to 100 mg/m3 for
dry flue gas• Traces of SO2 and NOx• Oxidizing agent – air• Surplus of oxidizing agent - λ=2• Temperature during process
400 – 1000 °C
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This project has received funding from the Euratom research and trainingprogramme 2014-2018 under grant agreement No 945098.
Laboratory of Radioactive Waste Management
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This project has received funding from the Euratom research and trainingprogramme 2014-2018 under grant agreement No 945098.
Laboratory ofRadioactiveWasteManagementProjects
MSO (TaČR) and NCCDevelopment of the methodfor disposal of saturated ionresins in the molten saltDevelopment of the methodfor disposal of hazardouswaste in the molten salt
EurofusionR&D in separation andcapture of tritium
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