Modification of Tracegas Scenarios
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Transcript of Modification of Tracegas Scenarios
GOME2 Error Study
Action Item PM1.2: Tracegas scenarios
PM2 10/2001
Modification of Tracegas Scenarios
Brapho Box/Slimcat CTM derived stratospheric climatology (Marco Bruns) SZA and albedo dependence of photochemistry tropospheric modification introduced
constant tropospheric O3 number density profile (all)biomass burning/ biogenic emission (5N, July)
H2CO 2ppb < 3 km (may affect BrO fit) NO2 taken from MPI-2D CTM O3 doubled < 5 km
free tropospheric BrO (55N, April) BrO 1ppt < 10 km (Fitzenberger et al., 2001)
PBL BrO explosion (75S, October) BrO 50ppt < 2 km O3 0ppm < 2 km
24 trace gas profile scenarios
GOME2 Error Study
Action Item PM1.2: Tracegas scenarios
PM2 10/2001
Tracegas scenarios: total column O3 NO2 BrO OClO
file [DU] [1019/m2] [1018/m2] [1016/m2]
9610am_lat18N_lon300_SZA40_a10.tg 252 1.944 0.180 0.0959610am_lat18N_lon300_SZA40_a90.tg 250 1.704 0.187 0.0889610am_lat55N_lon300_SZA69_a10.tg 276 1.796 0.267 0.2499610am_lat55N_lon300_SZA69_a90.tg 275 1.712 0.277 0.2459610am_lat77N_lon000_SZA86_a10.tg 262 0.952 0.324 0.4989610am_lat77N_lon000_SZA86_a90.tg 262 0.945 0.327 0.4959610am_lat77S_lon000_SZA90_a10.tg 152 1.539 3.174 4.261 PBL BrO / high OClO/9610am_lat77S_lon000_SZA90_a90.tg 151 1.549 3.172 3.947 ozone hole9701am_lat18N_lon300_SZA50_a10.tg 219 1.844 0.177 0.0909701am_lat18N_lon300_SZA50_a90.tg 218 1.647 0.182 0.0859701am_lat55N_lon000_SZA80_a10.tg 288 1.136 0.285 0.3479701am_lat55N_lon000_SZA80_a90.tg 288 1.114 0.289 0.3419704am_lat18N_lon300_SZA40_a10.tg 250 2.016 0.173 0.0889704am_lat18N_lon300_SZA40_a90.tg 247 1.781 0.180 0.0819704am_lat55N_lon300_SZA49_a10.tg 320 2.478 0.388 0.163 free tropospheric BrO9704am_lat55N_lon300_SZA49_a90.tg 319 2.250 0.414 0.1629704am_lat77N_lon000_SZA69_a10.tg 294 2.889 0.211 0.1879704am_lat77N_lon000_SZA69_a90.tg 293 2.769 0.229 0.1949707am_lat18N_lon300_SZA41_a10.tg 285 2.420 0.197 0.094 biomass burning9707am_lat18N_lon300_SZA41_a90.tg 282 2.171 0.206 0.0899707am_lat55N_lon300_SZA39_a10.tg 311 3.424 0.234 0.1179707am_lat55N_lon300_SZA39_a90.tg 309 3.050 0.270 0.1189707am_lat77N_lon000_SZA59_a10.tg 292 4.235 0.208 0.0779707am_lat77N_lon000_SZA59_a90.tg 290 3.918 0.238 0.077
GOME2 Error Study
Action Item PM1.2: Tracegas scenarios
PM2 10/2001
Antarctic Ozone hole (77S, Oct 1996)
Ozone „hole“ profile (151 DU) zero surface ozone
50 ppt BrO < 2km (BrO explosion) stratospheric maximum at 16-17 km
GOME2 Error Study
Action Item PM1.2: Tracegas scenarios
PM2 10/2001
Antarctic Ozone Hole (Part II)
High OClO
Free tropospheric BrO (55N, Apr)
1 ppt BrO < 10 km
GOME2 Error Study
Action Item PM1.2: Tracegas scenarios
PM2 10/2001
Biomass burning (18N, July)
Formaldehyde 2ppb < 3 km
troposperic NO2 from MPI-2D
GOME2 Error Study
Action Item PM1.2: Tracegas scenarios
PM2 10/2001
Conclusions: more realistic scenarios developed CDI simulation repeated (see ftp server) basic and SNR error assessment with new
scenarios
Biomass burning (Part II)
tropospheric O3 doubled <5 km