Effect of boric acid doped PEDOT:PSS layer on the performance of ...
Microwave Acid Digestion Method Note Compendium€¦ · Compendium October 1, 2019. Contents...
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MARS 6Microwave Acid Digestion
Method Note Compendium
October 1, 2019
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Contents
Agriculture
Alfalfa 11
Boric Acid HF Neutralization 12
Cannabis (Plant) 13
Coffee Beans 14
Cotton 15
Feed Grain 16
Fertilizer - AOAC Method 2017.02 17
Fertilizer -AOAC Method 2006.03 18
Geranium 19
Impatiens 20
Leather 21
Palm Leaves 22
Plant Tissue 23
Soybean 24
Soybean Meal 25
Spinach Leaves 26
Straw 27
Tea Extract 28
Tea Tannin 29
Tobacco 30
Wheat 31
Wood 32
Wood Pulp 33
Wool 34
Yeast 35
Clinical & Biological
Animal Tissue (Dry) 37
Animal Tissue (Wet) 38
Beef Bone 39
Blood (Human) 40
Bovine Blood 42
Bovine Liver (Wet) 43
Brain Tissue (Dog) 44
Dog Feces (Dry) 45
Fingernails 46
Hair 47
Lobster Hepatopancreas (Tort-CRM) 48
Rat Kidney 49
Urine - Human 50
Consumer Products
Boric Acid HF Neutralization 52
Candle Fragrance in iPrep 53
Cosmetics (Liquid Make-Up) 54
Cotton 55
Deodorant (Powder) 56
Eye Shadow 57
Foam (Mattress) in iPrep 58
Sanitizers (Hand) 59
Shampoo (Dandruff) 60
Soaps (Lotion and Foam) 61
Sunscreen in iPrep 62
Suppository (Capsule) 63
Toothpaste 64
Vaseline 65
Wax (Candle) 66
Environmental & Regulatory
Boric Acid HF Neutralization 68
Fertilizer - AOAC Method 2017.02 69
Fertilizer - AOAC Method 2006.03 70
Fly Ash in iPrep 71
Limestone 73
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NPDES (Waste Water) 74
Pine Needles 75
RoHS (For Pb, Hg, and Cd Analysis) 76
Sediment (BCCS - 1 CRM) (Leach) 77
Sediment (Buffalo River) (Leach) 78
Sludge (Industrial) 79
Soil (Montana - CRM) (Leach) 80
TCLP Extract 81
US EPA 3015 (Aqueous Samples) 82
US EPA 3015a (Aqueous Sample) 83
US EPA 3051 (Solid Sample) 84
US EPA 3051a (Solid Sample) 85
US EPA 3052 (Sludge, Soil, Sediment or Oil) 86
USP 232/233 (Pharmaceuticals) 87
Waste Activated Sludge 88
Water (For Analysis of Phosphorous) 89
Wood 90
Food Testing
Alum 92
Apple 93
Asparagus 94
Aspartame in iPrep 95
Bacon (Cooked) 96
Beef (Ground) 97
Beef Bouillon 98
Beer (Light) 99
Blueberry 100
Broccoli 101
Caramel Color 102
Carrot 103
Celery 104
Cheese (Cracker) 105
Cheese (Powder) 106
Cheese (Processed) 107
Cherry 108
Chewing Gum 109
Chicken (Boneless) 110
Chili Candy (Mexican) 111
Chili Powder in iPrep 112
Chips (Potato) 113
Citrus Leaves 114
Clam Puree 115
Cocoa 116
Coconut 117
Coffee Beans 118
Cucumber 119
Dog Food 120
Fish Tissue 121
Flounder 122
Flour 123
Food 124
Food Coloring (Liquid) 125
Fruit Juice 126
Gelatin 127
Granola Bar 128
Grape 129
Grapefruit 130
Gummy Bear 131
Ham 132
Infant Cereal (Rice Grain) 133
Infant Formula (Liquid) in iPrep 134
Infant Formula (Liquid) 135
Infant Formula (Powder) in iPrep 136
Infant Formula (Powder) 137
Kidney Bean 138
Kielbasa Sausage 139
Maple Syrup 140
Mayonnaise 141
Meal Replacement Shake (Chocolate) 142
Milk (Whole - Liquid) 143
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Milk (Powder) 144
Nutritional Drink (Adult) 145
Olive Oil 146
Orange Juice 147
Oyster Puree 148
Peanut Butter 149
Pear 150
Pepper (Bell, Chili, Etc.) 151
Pistachio Nuts 152
Pizza (Frozen, Pepperoni) 153
Plum 154
Pork (Ground) 155
Potato 156
Potato Chips 157
Pretzel (Salted) 158
Protein Bar 159
Raspberry 160
Rice 161
Safflower Oil 162
Salad Dressing (Ranch) 163
Salami 164
Sausage 165
Soda (Diet) 166
Sodium Free - Seasoning 167
Soybean 168
Spinach 169
Spinach Leaves 170
Spinach Pasta 171
Strawberry 172
Sugar (Granulated) 173
Tea (Chai) in iPrep 174
Tea Leaves 175
Tomato Leaves 176
Tomato Paste (70% Moisture) 177
Tomato Soup 178
Walnut 179
Watermelon 180
Wheat Crackers 181
Whey 182
Whey (Powder) 183
Wine 184
Yogurt (Plain) 185
Geoscience & Mining
Alpha - Alumina in iPrep 187
Alumina Beads (with Silver Substrate) in iPrep 188
Alumina Powder in iPrep 190
Aluminum Nitride 191
Aluminum Oxide 192
Aluminum Oxide (H3PO4) in iPrep 193
Asbestos 194
Automotive Catalyst 195
Barium Titanate (BaTiO3) 196
Bastnaesite Ore 197
Bauxite 199
Bismuth Aluminate Mixture 201
Bismuth Yttrium Iron Oxide in iPrep 202
Boiler Scale (80-90% Fe) 204
Boric Acid HF Neutralization 205
Boron Carbide (B4C) in iPrep 206
Carbon 207
Cement 208
Ceramic (Fused Silica) 209
Ceramics 210
Char - Sulfuric Acid 211
Chromium Carbide 212
Chromium Oxide (Cr2O3) in iPrep 213
Clay 214
Coal in iPrep 215
Coal 216
Coal Ash 217
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Cryolite / Electrolytic Bath 218
Feldspar in iPrep 220
Ferric Oxide in iPrep 222
Furnace Slag 223
Gadolinium Zirconium Oxide in iPrep 224
Gas Atomized Powder in iPrep 226
Glass Fiber 227
Hafnium Oxide 228
Ilmenite (FeTiO3) 229
Iron Ore 230
Kaolin 231
Kerosene 232
Lead Sulfide (PbS) 233
Lithium Nickel Cobalt Manganese Oxide 234
Magnesium Oxide (MgO 40-54%) 235
Manganous Oxide (MnO) 236
Mica in iPrep 238
Mill Tailings 239
Mineral Ore 241
Molybdenum Disulfide (MoS2) 243
Nickel (II) Hydroxide 245
Niobium Pentoxide 246
Petroleum Coke 247
Phosphate (21%) 249
Phosphate Rock 250
Pollucite Ore in iPrep 251
Pyrophyllite (AlSi2)5(OH) 253
Quartz Powder 254
Rock (Pulverized) 255
Rock, High Sulfide in iPrep 256
Rutile Ore 258
Sand 259
Shale in iPrep 260
Silica Sand 261
Silica Sand in iPrep 262
Silicon Dioxide 263
Silicon Nitride in iPrep 264
Silicon Wafer 265
Slag - Furnace 266
Sodium Antimonate in iPrep 267
Spodumene (Lithium Feldspar) 268
Sulfide Bulk Concentrate in iPrep 270
Tantalum Pentoxide (Ta2O5) in iPrep 272
Titanium Dioxide 273
Titanium Slag Ore in iPrep 274
Tungsten Carbide 275
Tungsten Ore (50% W; 10% Fe; 2% Mn) 276
Tungsten Oxide 277
Vermiculite 278
Wollastonite (Calcium Silicate) in iPrep 279
Zeolite 280
Zinc Oxide (ZnO) 281
Zinc Oxide (ZnO) in iPrep 282
Zircon in iPrep 283
Industrial Hygiene
Asbestos 285
Filter (MCE) 286
Filter Paper - 37 mm Mixed Cellulose Ester 287
Filter Paper - 47 mm Polycarbonate 288
Filter Paper - Cellulose 289
Ghost Wipe 290
Paint Chips (For Pb Analysis) 291
Quartz Fiber Filters 292
Toray Filter in iPrep 293
Toray Filter (Anion) 294
Toray Filter (Cation) 295
Materials Science
Acrylic Tape in iPrep 297
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Bismuth Aluminate Mixture 298
Bismuth Yttrium Iron Oxide in iPrep 299
Ceramic Powder 301
Ceramic Powder in iPrep 302
Circuit Board (Cryo - Ground) 303
Ferric Oxide in iPrep 304
Gadolinium Zirconium Oxide in iPrep 305
Gas Atomized Powder in iPrep 307
Glass (Ground) 308
Graphite Composite - Cyanate Ester Resin 309
Graphite Composite - Epoxy Resin 310
Graphite Composite - PEEK Resin 311
Graphite Fiber - Cyanate Siloxane Resin 312
Graphite Fiber - Epoxy Resin (Fiber Content) 313
Pollucite Ore in iPrep 314
Siloxanes 316
Metals & Alloys
Alpha - Alumina in iPrep 318
Aluminum (Metal) 319
Aluminum Alloy 320
Aluminum Alloy (20% SiC) 321
Aluminum Alloy (BCS 182) 322
Aluminum Oxide 323
Aluminum Oxide (H3PO4) in iPrep 324
Boron 325
Boron Carbide (B4C) in iPrep 326
Carbonyl Iron in iPrep 327
Cobalt - Chromium Alloy (Co-Cr) 328
Copper (Metal) 330
Copper Ore 331
Gallium 332
Iron - Chromium Alloy 333
Iron - Chromium Alloy in iPrep 335
Iron - Lignosulfonate 336
Iron - Manganese Alloy 337
Iron - Silicon Alloy 338
Lead Sulfide (PbS) 339
Lithium Nickel Cobalt Manganese Oxide 340
Magnesium Oxide (MgO 40-54%) 341
Manganous Oxide (MnO) 342
Metal Alloy - FeCr 344
Metal Alloy - NiCr 345
Metal Alloy (Ag, Au, Cu) in iPrep 346
Metal Alloy (Ag, Co, Cu) in iPrep 347
Metal Alloy (Ag, Cu, Sn) in iPrep 348
Metal Ore - Precious 349
Metals Alloy (Co-Cr) 351
Nickel (II) Hydroxide 353
Nickel (Metal) 354
Niobium - Titanium Alloy 355
Phosphate (21%) 356
Platinum Metal 357
Platinum Ruthenium in iPrep 358
Rhodium Sponge in iPrep 359
Selenium Alloy 360
Sn - Ag Solder 361
Stainless and Low Carbon Steel in iPrep 362
Stainless Steel 363
Steel (Stainless) 364
Strontium Ferrite in iPrep 365
Titanium Alloy 366
Titanium Dioxide 367
Tungsten Ore (50% W; 10% Fe; 2% Mn) 368
Zinc Oxide (ZnO) 369
Zinc Oxide (ZnO) in iPrep 370
Zircon Alloy 371
Nutraceuticals
Biotin 373
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Cannabis (Plant) 374
Chili Powder in iPrep 375
Citrus Leaves 376
Ginkgo (Ground) 377
Ginkgo (Whole Pill) 378
Infant Formula (Liquid) in iPrep 379
Infant Formula (Liquid) 380
Infant Formula (Powder) in iPrep 381
Infant Formula (Powder) 382
Kelp 383
Milk (Whole - Liquid) 384
Milk (Powder) 385
Plant Tissue 386
USP 232/233 (Pharmaceuticals) 387
Wheat 388
Whey (Powder) 389
Organic Chemicals
Di-(2-ethylhexyl)phosphoric Acid in iPrep 391
Diazo Sulfonyl Chloride 392
Food Coloring (Erythrosine Based) 393
Methylcellulose (Hydroxypropyl) 394
Monoethanolamine 395
Photoresist 396
Polygluteramide 397
Paints & Coatings
Paint (Latex Based Liquid) 399
Paint Chips (For Pb Analysis) 400
Photoresist 401
Polyurethane 402
Polyurethane in iPrep 403
Toner (Ink) in iPrep 404
Toner (Powder) in iPrep 405
Paper & Pulp
Filter Paper - 37 mm Mixed Cellulose Ester 407
Filter Paper - 47 mm Polycarbonate 408
Filter Paper - Cellulose 409
Paper Pulp 410
Personal Care
Boric Acid HF Neutralization 412
Cosmetics (Liquid Make-Up) 413
Eye Shadow 414
Shampoo (Dandruff) 415
Pharmaceutical & Biotech
Allergy Pill (Ground) 417
Allergy Pill (Whole Pill) 418
Antioxidant (Ground) 419
Antioxidant (Whole Pill) 420
APIs with Aromatic Ring Structures in iPrep 421
Ascorbic Acid 422
Aspirin (Ground) 423
Aspirin (Whole) 424
Beta Carotene 425
Biotin 426
Calcium Carbonate 427
Calpan Pantothenic Acid 428
Cephalexin 429
Chromium Chelate 430
Cold & Flu Medicine (Liquid) 431
Cupric Sulfate 432
Diclofenac K 433
Empty Capsule (Gel) 434
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Erythromycin 435
Fish Oil (No Capsule) 436
Flurbiprofen 437
Folic Acid 438
Ginkgo (Ground) 439
Ginkgo (Whole Pill) 440
Hydrocodone 441
Ibuprofen (Ground) 442
Kelp 443
Losartan K 444
Magnesium Carbonate 445
Magnesium Oxide 446
Manganese Carbonate 447
Medroxyprogesterone 448
Metformin (Ground) 449
Mineral Oil 450
Multivitamin (Ground) 451
Multivitamin (Whole) 452
Naproxen Sodium 453
Niacinamide 454
Pantothenic Acid 455
Potassium Chelate 456
Protopic Ointment 457
Pyridoxine 458
Riboflavin 459
Selenium Chelate 460
Sleep Aid 461
Sodium Polystyrene Sulfonate in iPrep 462
Stearic Acid 463
Sudan Orange (4-Fluorophenyl) in iPrep 464
Thiamine 465
Transdermal Patch 466
Trixie Phosphate in iPrep 467
USP 232/233 (Pharmaceuticals) 468
Vitamin B-12 469
Vitamin C (Ground) 470
Vitamin C (Whole) 471
Vitamin Concentrate (High Fe) 472
Vitamin D 473
Vitamin D3 474
Vitamin E 475
Vitamins 476
Zinc Sulfate 477
Plastics, Polymers, & Oils
Acrylamide 479
Brominated Flame Retardant in iPrep 480
Bunker Oil in iPrep 481
Char - Sulfuric Acid 482
Crude Oil 483
Diesel Fuel 484
Epoxy Hardener 485
Fatty Alcohol 486
Fluorinated Ethylene Propylene (FEP) in iPrep 487
Fuel Oil (Slurry) in iPrep 488
Gasoline 490
Glycerol Ester of Wood Rosin (Ground) in iPrep 491
HDPE 492
Kerosene 493
Kevlar in iPrep 494
Lube Oil 495
Methyl Ester of Hydrogenated Wood Rosin (Ground) in iPrep 496
Mineral Oil 497
Motor Oil (New) 498
Motor Oil (Waste) 499
Motor Oil (Waste) in iPrep 500
Nylon 501
Oil Wear Metals 502
PET (Polyethylene Terephthalate) 503
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PET (Polyethylene Terephthalate) in iPrep 504
Petrolatum 505
Plasticizer (Filter) in iPrep 506
Plasticizers in iPrep 507
Polycarbonate Resin 508
Polyethersulfone (Filter Paper) 510
Polyethylene - High Density 511
Polyphenylene Sulfide 512
Polypropylene 513
Polyterpene Resin in iPrep 514
Polyurethane 515
Polyurethane in iPrep 516
PVC (Polyvinyl Chloride Resin) 517
Rubber 518
Rubber (Synthetic) 519
Silane Terminated Polyether in iPrep 520
Silicone Tubing - TiO2 Filler 521
Styrene Acrylate 522
Terephthalic Acid 523
Wax (Petroleum Based) 524
Water & Wastewater Treatment
NPDES (Waste Water) 526
Sludge (Industrial) 527
TCLP Extract 528
US EPA 3015 (Aqueous Samples) 529
US EPA 3015a (Aqueous Sample) 530
Waste Activated Sludge 531
Water (For Analysis of Phosphorous) 532
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Agriculture
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11
Microwave Digestion ofAlfalfa
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
520
Microwave Digestion ofAlfalfa
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12
Microwave Digestion ofBoric Acid HF Neutralization
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample WeightVaries by Sample
ReagentsH₃BO₃ (4%)
Recommended VesselsEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Alternatively, 1-4 g of solid H₃BO₃ + 25 mL deionized H₂O can be used in place of the 4% w/v solution.
ProcedureAllow vessel to cool. Add 30 mL H₃BO₃ (4%) into the vessel that contains the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSee sample specific method notes.
6
Microwave Digestion ofBoric Acid HF Neutralization
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13
Microwave Digestion ofCannabis (Plant)
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃, or alternatively 9 mL HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
715
Microwave Digestion ofCannabis (Plant)
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14
Microwave Digestion ofCoffee Beans
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may; however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of ground sample into the digestion vessel. Add 10 ml of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 ml.
10
Microwave Digestion ofCoffee Beans
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15
Microwave Digestion ofCotton
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
231
Microwave Digestion ofCotton
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16
Microwave Digestion ofFeed Grain
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g (0.25 g w/Xpress Vessels) of the sample into the digestion vessel. Add 10 ml of HNO₃, and 2 ml of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
232
Microwave Digestion ofFeed Grain
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17
Microwave Digestion ofFertilizer - AOAC Method 2017.02
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis. This method may not provide a total digest of all fertilizer samples.
ProcedureWeigh 1 g (0.5 g for organic matrices) of the sample into the digestion vessel. Add 9 mL of HNO₃, and 3 mL HCl. Gently swirl the mixture and wait approximately 20 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, with some particles (silicates) remaining upon dilution to 50 mL.
535
Microwave Digestion ofFertilizer - AOAC Method 2017.02
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18
Microwave Digestion ofFertilizer -AOAC Method 2006.03
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis method may not provide a total digest of all fertilizer samples.
ProcedureWeigh 1 g (0.5 g for organic matrices) of the sample into the digestion vessel. Add 10 ml of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
233
Microwave Digestion ofFertilizer -AOAC Method 2006.03
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19
Microwave Digestion ofGeranium
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900 -1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
521
Microwave Digestion ofGeranium
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20
Microwave Digestion ofImpatiens
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
522
Microwave Digestion ofImpatiens
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21
Microwave Digestion ofLeather
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
490
Microwave Digestion ofLeather
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22
Microwave Digestion ofPalm Leaves
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL HNO₃, and 2 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
523
Microwave Digestion ofPalm Leaves
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23
Microwave Digestion ofPlant Tissue
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis. Some plant tissues contain silicates which would require HF for total dissolution.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
234
Microwave Digestion ofPlant Tissue
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24
Microwave Digestion ofSoybean
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of (dry weight) sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
235
Microwave Digestion ofSoybean
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25
Microwave Digestion ofSoybean Meal
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
524
Microwave Digestion ofSoybean Meal
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26
Microwave Digestion ofSpinach Leaves
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis. Some plant tissues contain silicates which would require HF for total dissolution.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 ml of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 ml.
236
Microwave Digestion ofSpinach Leaves
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27
Microwave Digestion ofStraw
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization” The addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 ml of HNO₃, and 1 ml of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 ml.
237
Microwave Digestion ofStraw
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28
Microwave Digestion ofTea Extract
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
525
Microwave Digestion ofTea Extract
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29
Microwave Digestion ofTea Tannin
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL HNO₃ and 1 mL HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
526
Microwave Digestion ofTea Tannin
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30
Microwave Digestion ofTobacco
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
238
Microwave Digestion ofTobacco
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31
Microwave Digestion ofWheat
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
239
Microwave Digestion ofWheat
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32
Microwave Digestion ofWood
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
268
Microwave Digestion ofWood
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33
Microwave Digestion ofWood Pulp
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Wet Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (wet weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
527
Microwave Digestion ofWood Pulp
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34
Microwave Digestion ofWool
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
528
Microwave Digestion ofWool
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35
Microwave Digestion ofYeast
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.0 g of dry weight (0.5 g w/Xpress vessels) into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
240
Microwave Digestion ofYeast
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Clinical & Biological
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Microwave Digestion ofAnimal Tissue (Dry)
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may; however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g (0.25 g w/MARSXpress Vessels) into the digestion vessel. Add 10 ml of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 ml.
4
37
Microwave Digestion ofAnimal Tissue (Dry)
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Microwave Digestion ofAnimal Tissue (Wet)
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 g (0.5 g w Xpress Vessels) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
241
38
Microwave Digestion ofAnimal Tissue (Wet)
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Microwave Digestion ofBeef Bone
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Ground)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (ground) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
529
39
Microwave Digestion ofBeef Bone
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Microwave Digestion ofBlood (Human)
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2 mL
ReagentsHNO₃ H₂O₂
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesTake caution when mixing the acids and the sample. The sample may foam slightly.
ProcedureTransfer 2 mL of the sample into the digestion vessel. Add 5 mL of HNO₃ and 2 mL of H₂O₂. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
242
40
Microwave Digestion ofBlood (Human)
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Microwave Digestion ofBlood (Human)
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 mL
ReagentsHNO₃
Recommended Vessels10 mL MARSXpress20 mL MARSXpress
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 0.5 mL of the sample into the digestion vessel. Add 2 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 N/A 1030-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.c) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
737
41
Microwave Digestion ofBlood (Human)
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Microwave Digestion ofBovine Blood
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 1 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
531
42
Microwave Digestion ofBovine Blood
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Microwave Digestion ofBovine Liver (Wet)
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g (Wet Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.0 g (wet weight )(0.5 g w/Xpress Vessels) into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
243
43
Microwave Digestion ofBovine Liver (Wet)
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Microwave Digestion ofBrain Tissue (Dog)
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g (Wet Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1 g (wet weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
532
44
Microwave Digestion ofBrain Tissue (Dog)
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Microwave Digestion ofDog Feces (Dry)
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.2 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
533
45
Microwave Digestion ofDog Feces (Dry)
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Microwave Digestion ofFingernails
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃
Recommended Vessels10 mL MARSXpress20 mL MARSXpress
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.1 g (0.05 g if using the 10 mL vessel) of the sample into the digestion vessel. Add 4 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 15:00 N/A 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.c) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
741
46
Microwave Digestion ofFingernails
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Microwave Digestion ofHair
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃
Recommended Vessels10 mL MARSXpress20 mL MARSXpress
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.1 g (0.05 g if using the 10 mL vessel) of the sample into the digestion vessel. Add 4 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 15:00 N/A 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.c) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
740
47
Microwave Digestion ofHair
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Microwave Digestion ofLobster Hepatopancreas (Tort-CRM)
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.0 g (dry weight) (0.5 g w/Xpress Vessels) into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
244
48
Microwave Digestion ofLobster Hepatopancreas (Tort-CRM)
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Microwave Digestion ofRat Kidney
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g (Wet Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1 g (wet weight) of the sample into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
534
49
Microwave Digestion ofRat Kidney
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Microwave Digestion ofUrine - Human
Clinical aMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight4 mL
ReagentsHNO₃H₂O₂
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesTake caution when mixing the acids and the sample. The sample may foam slightly.
ProcedureTransfer 4 ml of the sample into the digestion vessel. Add 4 mL of HNO₃, and 2 mL of H₂O₂. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 ml.
245
50
Microwave Digestion ofUrine - Human
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Consumer Products
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52
Microwave Digestion ofBoric Acid HF Neutralization
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample WeightVaries by Sample
ReagentsH₃BO₃ (4%)
Recommended VesselsEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Alternatively, 1-4 g of solid H₃BO₃ + 25 mL deionized H₂O can be used in place of the 4% w/v solution.
ProcedureAllow vessel to cool. Add 30 mL H₃BO₃ (4%) into the vessel that contains the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSee sample specific method notes.
6
Microwave Digestion ofBoric Acid HF Neutralization
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53
Microwave Digestion ofCandle Fragrance
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution.The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureAdd 0.1 g of the sample into the digestion vessel. Add 7 mL of HNO₃ and 1 mL HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless upon dilution to 50 mL.
676
Microwave Digestion ofCandle Fragrance in iPrep
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54
Microwave Digestion ofCosmetics (Liquid Make-Up)
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 8 mL of HNO₃ and 2 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
246
Microwave Digestion ofCosmetics (Liquid Make-Up)
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55
Microwave Digestion ofCotton
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
231
Microwave Digestion ofCotton
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56
Microwave Digestion ofDeodorant (Powder)
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 2 mL of HNO₃ and 6 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 25:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
735
Microwave Digestion ofDeodorant (Powder)
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57
Microwave Digestion ofEye Shadow
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 7 mL of HNO₃ and 3 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
247
Microwave Digestion ofEye Shadow
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58
Microwave Digestion ofFoam (Mattress)
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃H₂SO₄
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL HNO₃ and 1 mL of H₂SO₄. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 30:00 15:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
670
Microwave Digestion ofFoam (Mattress) in iPrep
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59
Microwave Digestion ofSanitizers (Hand)
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHClHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAcid addition should be added slowly and in aliquots of 1 mL, as the reaction is vigorous and exothermic upon addition of HNO₃.The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution.The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 1 mL of HCl and 4 mL of HNO₃ in aliquots of 1 mL. Gently swirl after each aliquot is added and allow reaction to subside before adding more HNO3. Allow approximately 45 minutes for pre-digestion.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 190 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
755
Microwave Digestion ofSanitizers (Hand)
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60
Microwave Digestion ofShampoo (Dandruff)
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample.
ProcedureTransfer 1 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
248
Microwave Digestion ofShampoo (Dandruff)
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61
Microwave Digestion ofSoaps (Lotion and Foam)
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 4 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 190 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
754
Microwave Digestion ofSoaps (Lotion and Foam)
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62
Microwave Digestion ofSunscreen
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 8 mL of HNO₃ and 2 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 30:00 15:00 N/A 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 250 mL.
756
Microwave Digestion ofSunscreen in iPrep
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63
Microwave Digestion ofSuppository (Capsule)
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Capsule (Approx 1 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesEnsure that the capsule is completely covered with reagent before sealing the vessel.
ProcedureWeigh 1 Capsule (approx. 1.0 g) into the digestion vessel. Add 12 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
249
Microwave Digestion ofSuppository (Capsule)
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64
Microwave Digestion ofToothpaste
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.1 g of the sample onto a filter disk and insert into the digestion vessel. Add 8 mL HNO₃ and 2 mL HF. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 15:00 800 1030-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) The control / reference vessel must contain the largest and most reactive sample.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
733
Microwave Digestion ofToothpaste
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65
Microwave Digestion ofVaseline
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
250
Microwave Digestion ofVaseline
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66
Microwave Digestion ofWax (Candle)
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
251
Microwave Digestion ofWax (Candle)
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Environmental & Regulatory
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Microwave Digestion ofBoric Acid HF Neutralization
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample WeightVaries by Sample
ReagentsH₃BO₃ (4%)
Recommended VesselsEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Alternatively, 1-4 g of solid H₃BO₃ + 25 mL deionized H₂O can be used in place of the 4% w/v solution.
ProcedureAllow vessel to cool. Add 30 mL H₃BO₃ (4%) into the vessel that contains the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSee sample specific method notes.
6
68
Microwave Digestion ofBoric Acid HF Neutralization
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Microwave Digestion ofFertilizer - AOAC Method 2017.02
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis. This method may not provide a total digest of all fertilizer samples.
ProcedureWeigh 1 g (0.5 g for organic matrices) of the sample into the digestion vessel. Add 9 mL of HNO₃, and 3 mL HCl. Gently swirl the mixture and wait approximately 20 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, with some particles (silicates) remaining upon dilution to 50 mL.
535
69
Microwave Digestion ofFertilizer - AOAC Method 2017.02
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Microwave Digestion ofFertilizer -AOAC Method 2006.03
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis method may not provide a total digest of all fertilizer samples.
ProcedureWeigh 1 g (0.5 g for organic matrices) of the sample into the digestion vessel. Add 10 ml of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
233
70
Microwave Digestion ofFertilizer - AOAC Method 2006.03
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Microwave Digestion ofFly Ash
EnvironmMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsH₂SO₄ H₃PO₄
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureAdd 0.1 g of the sample into the digestion vessel. Add 3 mL of H₂SO₄ and 3 mL of H₃PO₄. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 260 35:00 30:00 N/A 700-1800 Off
71
Microwave Digestion ofFly Ash in iPrep (Step 1 of 2)
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Microwave Digestion ofFly Ash
EnvironmMARS 6 (
ProcedureAllow vessels to cool. Open and add 1.5 mL of HNO₃, 1.5 mL of HCl, and 1.5 mL of HF. Wait approximately 15 minutes before closing the vessel.
Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
ReagentsHNO₃HClHF
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization". The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
649
72
Microwave Digestion ofFly Ash in iPrep (Step 2 of 2)
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Microwave Digestion ofLimestone
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAllow any initial reaction to subside before sealing the vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve in soluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 7.5 mL of HNO₃ and 2.5 ml of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilutionto 50 ml.
2
73
Microwave Digestion ofLimestone
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Microwave Digestion ofNPDES (Waste Water)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeWater
Heating Program
Max Sample Weight50 mL
ReagentsHNO₃ HCl
Recommended Vessels75 mL MARSXpressEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 50 mL of the sample into the digestion vessel. Add 3 mL of HNO₃, and 2 mL HCl. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 165 30:00 0:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
252
74
Microwave Digestion ofNPDES (Waste Water)
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Microwave Digestion ofPine Needles
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃H₂O₂ (30%)
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 8 mL of HNO₃ and 2 mL of H₂O₂ (30%). Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
253
75
Microwave Digestion ofPine Needles
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Microwave Digestion ofRoHS (For Pb, Hg, and Cd Analysis)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃ H₂SO₄
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 10 mL of HNO₃, and 0.02 mL of H₂SO₄. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 10:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
254
76
Microwave Digestion ofRoHS (For Pb, Hg, and Cd Analysis)
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Microwave Digestion ofSediment (BCCS - 1 CRM) (Leach)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis method may not provide a total digest of all samples. Hydrofluoric acid will be required to provide complete digestion of some sample matrixes. The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO3. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
255
77
Microwave Digestion ofSediment (BCCS - 1 CRM) (Leach)
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Microwave Digestion ofSediment (Buffalo River) (Leach)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis method may not provide a total digest of all samples. Hydrofluoric acid will be required to provide complete digestion of some sample matrixes. The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 175 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
256
78
Microwave Digestion ofSediment (Buffalo River) (Leach)
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Microwave Digestion ofSludge (Industrial)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample. The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
257
79
Microwave Digestion ofSludge (Industrial)
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Microwave Digestion ofSoil (Montana - CRM) (Leach)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis method may not provide a total digest of all samples. Hydrofluoric acid will be required to provide complete digestion of some sample matrixes. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 175 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
258
80
Microwave Digestion ofSoil (Montana - CRM) (Leach)
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Microwave Digestion ofTCLP Extract
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeStandard Control
Sample TypeWater
Heating Program
Max Sample Weight25 mL
ReagentsHNO₃
Recommended VesselsEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 25 mL of the sample into the digestion vessel. Add 5 mL of HNO₃. Gently swirl the mixture before closing the vessel. If a high organic content is suspected, a 10 ml sample volume is recommended.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
259
81
Microwave Digestion ofTCLP Extract
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Microwave Digestion ofUS EPA 3015 (Aqueous Samples)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeStandard Control
Sample TypeWater
Heating Program
Max Sample Weight45 mL
ReagentsHNO₃
Recommended Vessels75 mL MARSXpressEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 45 mL of the sample into the digestion vessel. Add 5 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsThis method is intended to be an acid leach, not a total digest. Hydrofluoric acid will be required to provide complete digestion of the sample matrix.
260
82
Microwave Digestion ofUS EPA 3015 (Aqueous Samples)
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Microwave Digestion ofUS EPA 3015a (Aqueous Sample)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeStandard Control
Sample TypeWater
Heating Program
Max Sample Weight45 mL
ReagentsHNO₃HCl (Optional)
Recommended Vessels75 mL MARSXpressEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 45 mL of the sample into the digestion vessel. Add 5 mL of HNO3, or alternatively 4 mL of HNO₃ and 1 mL HCl. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsThis method is intended to be an acid leach, not a total digest. Hydrofluoric acid will be required to provide complete digestion of the sample matrix.
261
83
Microwave Digestion ofUS EPA 3015a (Aqueous Sample)
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Microwave Digestion ofUS EPA 3051 (Solid Sample)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeStandard Control
Sample TypeSolid
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl (Optional)
Recommended VesselsEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 175 5:30 4:30 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsThis method is intended to be an acid leach, not a total digest.
262
84
Microwave Digestion ofUS EPA 3051 (Solid Sample)
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Microwave Digestion ofUS EPA 3051a (Solid Sample)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeStandard Control
Sample TypeSolid
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl (Optional)
Recommended VesselsEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃, or alternatively 9 mL HNO₃, and 1 mL HCl. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 175 5:30 4:30 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsThis method is intended to be an acid leach, not a total digest.
263
85
Microwave Digestion ofUS EPA 3051a (Solid Sample)
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Microwave Digestion ofUS EPA 3052 (Sludge, Soil, Sediment or Oil)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeStandard Control
Sample TypeSolid
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 3 mL HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 5:30 9:30 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
264
86
Microwave Digestion ofUS EPA 3052 (Sludge, Soil, Sediment or Oil)
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Microwave Digestion ofUSP 232/233 (Pharmaceuticals)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL HCl. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
265
87
Microwave Digestion ofUSP 232/233 (Pharmaceuticals)
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Microwave Digestion ofWaste Activated Sludge
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃H₂O₂
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) (0.25 g w/Xpress Vessels) of the sample into the digestion vessel. Add 5 mL of HNO₃, and 5 mL of H₂O₂. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
266
88
Microwave Digestion ofWaste Activated Sludge
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Microwave Digestion ofWater (For Analysis of Phosphorous)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeWater
Heating Program
Max Sample Weight50 mL
ReagentsK₂S₂O₈ H₂SO₄
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6
Notes
ProcedureTransfer 50 mL of H₂O into the digestion vessel. Add 0.5 g of K₂S₂O₈ and 1 mL of H₂SO₄. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
267
89
Microwave Digestion ofWater (For Analysis of Phosphorous)
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Microwave Digestion ofWood
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
268
90
Microwave Digestion ofWood
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Food Testing
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Microwave Digestion ofAlum
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 3 mL of HCl, 5 mL of HF, and 2 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain therequired results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at orbelow room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vesselsdetected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
536
92
Microwave Digestion ofAlum
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Microwave Digestion ofApple
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain therequired results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at orbelow room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vesselsdetected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
269
93
Microwave Digestion ofApple
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Microwave Digestion ofAsparagus
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
Resultssample was clear, colorless, and particle free upon dilution to 50 mL.
270
94
Microwave Digestion ofAsparagus
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Microwave Digestion ofAspartame
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 15:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
758
95
Microwave Digestion ofAspartame in iPrep
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Microwave Digestion ofBacon (Cooked)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃DI H₂O
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.0 g of the sample into the digestion vessel. Add 8 mL of HNO₃ and 2 mL of DI H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
271
96
Microwave Digestion ofBacon (Cooked)
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Microwave Digestion ofBeef (Ground)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.0 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
272
97
Microwave Digestion ofBeef (Ground)
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Microwave Digestion ofBeef Bouillon
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
537
98
Microwave Digestion ofBeef Bouillon
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Microwave Digestion ofBeer (Light)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight4 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 4 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
273
99
Microwave Digestion ofBeer (Light)
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Microwave Digestion ofBlueberry
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
275
100
Microwave Digestion ofBlueberry
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Microwave Digestion ofBroccoli
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 20 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
277
101
Microwave Digestion ofBroccoli
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Microwave Digestion ofCaramel Color
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2.0 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 2.0 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
Resultssample was clear, colorless, and particle free upon dilution to 50 mL.
278
102
Microwave Digestion ofCaramel Color
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Microwave Digestion ofCarrot
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
279
103
Microwave Digestion ofCarrot
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Microwave Digestion ofCelery
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
280
104
Microwave Digestion ofCelery
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Microwave Digestion ofCheese (Cracker)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of ground sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
281
105
Microwave Digestion ofCheese (Cracker)
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Microwave Digestion ofCheese (Powder)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO3. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
538
106
Microwave Digestion ofCheese (Powder)
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Microwave Digestion ofCheese (Processed)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 ml of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
282
107
Microwave Digestion ofCheese (Processed)
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Microwave Digestion ofCherry
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
283
108
Microwave Digestion ofCherry
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Microwave Digestion ofChewing Gum
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis. The use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 ml.
284
109
Microwave Digestion ofChewing Gum
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Microwave Digestion ofChicken (Boneless)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
285
110
Microwave Digestion ofChicken (Boneless)
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Microwave Digestion ofChili Candy (Mexican)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
286
111
Microwave Digestion ofChili Candy (Mexican)
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Microwave Digestion ofChili Powder
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2 g
ReagentsHNO₃DI H₂O
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 2 g of the sample into the digestion vessel. Add 10 mL HNO₃ and 5 mL deionized H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless with some small particles (silicates) remaining upon dilution to 50 mL.
680
112
Microwave Digestion ofChili Powder in iPrep
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Microwave Digestion ofChips (Potato)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
287
113
Microwave Digestion ofChips (Potato)
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Microwave Digestion ofCitrus Leaves
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃DI H₂OHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 6 mL of HNO₃, 3 mL of deionized H₂O, and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
539
114
Microwave Digestion ofCitrus Leaves
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Microwave Digestion ofClam Puree
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g (Wet Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1 g (wet weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
540
115
Microwave Digestion ofClam Puree
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Microwave Digestion ofCocoa
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO3. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
541
116
Microwave Digestion ofCocoa
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Microwave Digestion ofCoconut
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g (Wet Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1 g (wet weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
542
117
Microwave Digestion ofCoconut
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Microwave Digestion ofCoffee Beans
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may; however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of ground sample into the digestion vessel. Add 10 ml of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 ml.
10
118
Microwave Digestion ofCoffee Beans
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Microwave Digestion ofCucumber
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
289
119
Microwave Digestion ofCucumber
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Microwave Digestion ofDog Food
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of (dry weight) up to 1 g (wet weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 Ml
290
120
Microwave Digestion ofDog Food
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Microwave Digestion ofFish Tissue
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) up to 2 g (wet weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
543
121
Microwave Digestion ofFish Tissue
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Microwave Digestion ofFlounder
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2.0 g (Wet Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 2 g (wet weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
544
122
Microwave Digestion ofFlounder
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Microwave Digestion ofFlour
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
292
123
Microwave Digestion ofFlour
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Microwave Digestion ofFood
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g dry weight (0.25 g w/Xpress vessels) of the sample into the digestion vessel. Add 10 mL of HNO₃ . Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
294
124
Microwave Digestion ofFood
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Microwave Digestion ofFood Coloring (Liquid)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 mL.
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 0.5 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
293
125
Microwave Digestion ofFood Coloring (Liquid)
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Microwave Digestion ofFruit Juice
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2.5 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 2.5 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
295
126
Microwave Digestion ofFruit Juice
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Microwave Digestion ofGelatin
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
545
127
Microwave Digestion ofGelatin
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Microwave Digestion ofGranola Bar
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of ground sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
296
128
Microwave Digestion ofGranola Bar
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Microwave Digestion ofGrape
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
297
129
Microwave Digestion ofGrape
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Microwave Digestion ofGrapefruit
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
298
130
Microwave Digestion ofGrapefruit
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Microwave Digestion ofGummy Bear
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
729
131
Microwave Digestion ofGummy Bear
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Microwave Digestion ofHam
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.0 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
299
132
Microwave Digestion ofHam
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Microwave Digestion ofInfant Cereal (Rice Grain)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
300
133
Microwave Digestion ofInfant Cereal (Rice Grain)
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Microwave Digestion ofInfant Formula (Liquid)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2 mL
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 2 mL of of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
Results Sample was clear, colorless and particle free upon dilution to 50 mL
301
134
Microwave Digestion ofInfant Formula (Liquid) in iPrep
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Microwave Digestion ofInfant Formula (Liquid)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 1 mL (0.5 mL w/Xpress Vessels) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
302
135
Microwave Digestion ofInfant Formula (Liquid)
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Microwave Digestion ofInfant Formula (Powder)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
303
136
Microwave Digestion ofInfant Formula (Powder) in iPrep
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Microwave Digestion ofInfant Formula (Powder)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g (0.25 g w/Xpress Vessels) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
304
137
Microwave Digestion ofInfant Formula (Powder)
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Microwave Digestion ofKidney Bean
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
305
138
Microwave Digestion ofKidney Bean
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Microwave Digestion ofKielbasa Sausage
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g (Wet Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1 g (wet weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
546
139
Microwave Digestion ofKielbasa Sausage
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Microwave Digestion ofMaple Syrup
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
306
140
Microwave Digestion ofMaple Syrup
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Microwave Digestion ofMayonnaise
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
307
141
Microwave Digestion ofMayonnaise
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Microwave Digestion ofMeal Replacement Shake (Chocolate)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Mix)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry mix) of the sample into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
547
142
Microwave Digestion ofMeal Replacement Shake (Chocolate)
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Microwave Digestion ofMilk (Whole - Liquid)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight4 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 4 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
309
143
Microwave Digestion ofMilk (Whole - Liquid)
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Microwave Digestion ofMilk (Powder)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
310
144
Microwave Digestion ofMilk (Powder)
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Microwave Digestion ofNutritional Drink (Adult)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 1.0 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
276
145
Microwave Digestion ofNutritional Drink (Adult)
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Microwave Digestion ofOlive Oil
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
312
146
Microwave Digestion ofOlive Oil
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Microwave Digestion ofOrange Juice
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2.5 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 2.5 ml of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
313
147
Microwave Digestion ofOrange Juice
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Microwave Digestion ofOyster Puree
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g (Wet Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1 g (wet weight) of the sample into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
548
148
Microwave Digestion ofOyster Puree
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Microwave Digestion ofPeanut Butter
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
314
149
Microwave Digestion ofPeanut Butter
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Microwave Digestion ofPear
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
315
150
Microwave Digestion ofPear
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Microwave Digestion ofPepper (Bell, Chili, Etc.)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
316
151
Microwave Digestion ofPepper (Bell, Chili, Etc.)
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Microwave Digestion ofPistachio Nuts
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
549
152
Microwave Digestion ofPistachio Nuts
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Microwave Digestion ofPizza (Frozen, Pepperoni)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.0 g (homogenized) into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
Resultssample was clear, colorless, and particle free upon dilution to 50 mL.
317
153
Microwave Digestion ofPizza (Frozen, Pepperoni)
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Microwave Digestion ofPlum
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
318
154
Microwave Digestion ofPlum
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Microwave Digestion ofPork (Ground)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 2.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
319
155
Microwave Digestion ofPork (Ground)
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Microwave Digestion ofPotato
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
320
156
Microwave Digestion ofPotato
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Microwave Digestion ofPotato Chips
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Ground)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (ground) of the sample into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
550
157
Microwave Digestion ofPotato Chips
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Microwave Digestion ofPretzel (Salted)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
321
158
Microwave Digestion ofPretzel (Salted)
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Microwave Digestion ofProtein Bar
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
322
159
Microwave Digestion ofProtein Bar
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Microwave Digestion ofRaspberry
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO3. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
323
160
Microwave Digestion ofRaspberry
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Microwave Digestion ofRice
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
324
161
Microwave Digestion ofRice
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Microwave Digestion ofSafflower Oil
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
325
162
Microwave Digestion ofSafflower Oil
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Microwave Digestion ofSalad Dressing (Ranch)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Mix)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry mix) of the sample into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
551
163
Microwave Digestion ofSalad Dressing (Ranch)
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Microwave Digestion ofSalami
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
326
164
Microwave Digestion ofSalami
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Microwave Digestion ofSausage
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
327
165
Microwave Digestion ofSausage
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Microwave Digestion ofSoda (Diet)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight 1 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 1 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
328
166
Microwave Digestion ofSoda (Diet)
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Microwave Digestion ofSodium Free - Seasoning
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
552
167
Microwave Digestion ofSodium Free - Seasoning
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Microwave Digestion ofSoybean
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of (dry weight) sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
235
168
Microwave Digestion ofSoybean
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Microwave Digestion ofSpinach
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
331
169
Microwave Digestion ofSpinach
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Microwave Digestion ofSpinach Leaves
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis. Some plant tissues contain silicates which would require HF for total dissolution.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
330
170
Microwave Digestion ofSpinach Leaves
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Microwave Digestion ofSpinach Pasta
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
553
171
Microwave Digestion ofSpinach Pasta
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Microwave Digestion ofStrawberry
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
332
172
Microwave Digestion ofStrawberry
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Microwave Digestion ofSugar (Granulated)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
333
173
Microwave Digestion ofSugar (Granulated)
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Microwave Digestion ofTea (Chai)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2.5 g
ReagentsHNO₃ DI H₂O
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 2.5 g of the sample into the digestion vessel. Add 10 mL HNO₃ and 5 mL deionized H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless with some small particles (silicates) remaining upon dilution to 50 mL.
679
174
Microwave Digestion ofTea (Chai) in iPrep
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Microwave Digestion ofTea Leaves
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
334
175
Microwave Digestion ofTea Leaves
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Microwave Digestion ofTomato Leaves
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesSome plant tissues contain silicates which would require HF for total dissolution.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, with white silica particles upon dilution to 50 mL.
335
176
Microwave Digestion ofTomato Leaves
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Microwave Digestion ofTomato Paste (70% Moisture)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 2 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
554
177
Microwave Digestion ofTomato Paste (70% Moisture)
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Microwave Digestion ofTomato Soup
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight5 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 5 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
336
178
Microwave Digestion ofTomato Soup
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Microwave Digestion ofWalnut
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
337
179
Microwave Digestion ofWalnut
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Microwave Digestion ofWatermelon
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
338
180
Microwave Digestion ofWatermelon
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Microwave Digestion ofWheat Crackers
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
555
181
Microwave Digestion ofWheat Crackers
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Microwave Digestion ofWhey
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO3. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
340
182
Microwave Digestion ofWhey
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Microwave Digestion ofWhey (Powder)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
339
183
Microwave Digestion ofWhey (Powder)
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Microwave Digestion ofWine
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 1 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
341
184
Microwave Digestion ofWine
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Microwave Digestion ofYogurt (Plain)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.0 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
342
185
Microwave Digestion ofYogurt (Plain)
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Geoscience & Mining
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187
Microwave Digestion ofAlpha - Alumina
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeHCl
Heating Program
Max Sample Weight0.5 g
ReagentsHCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The maximum number of vessels that can be run for this method is 6.
Ensure that particles are well suspended in acid mixture prior to sealing vessel.
Stirring may be helpful to keep particles suspended in solution during digestion.
ProcedureWeigh 0.5 g of sample into the digestion vessel. Add 10 mL HCl. Gently swirl the vessel to thoroughly mix the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 59:59 N/A 900-1800 N/A
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain therequired results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at orbelow room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vesselsdetected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
343
Microwave Digestion ofAlpha - Alumina in iPrep
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188
Microwave Digestion ofAlumina Beads (w/ Silver substrate)
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsH₃PO₄H₂SO₄
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 6.5 mL of H₃PO₄, and 3.5 mL of H₂SO₄. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 280 30:00 45:00 N/A 700-1800 Off
Microwave Digestion ofAlumina Beads (with Silver Substrate) in iPrep (Step 1 of 2)
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189
Microwave Digestion ofAlumina Beads (w/ Silver substrate)
GeoscienMARS 6 (
ProcedureAllow vessel to cool after completion of Step 1. Proceeding step one, add 3 mL of HNO₃, and 3 mL HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
ReagentsHNO₃HF
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 25:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
616
Microwave Digestion ofAlumina Beads (with Silver Substrate) (Step 2 of 2)
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190
Microwave Digestion ofAlumina Powder
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsH₃PO₄
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureAdd 0.1 g of the sample into the digestion vessel. Add 8 mL of H₃PO₄. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 275 30:00 45:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, gold colored, and particle free upon dilution to 50 mL.
672
Microwave Digestion ofAlumina Powder in iPrep
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191
Microwave Digestion ofAluminum Nitride
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsH₃PO₄ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 5 mL H₃PO₄ and 10 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 175 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
560
Microwave Digestion ofAluminum Nitride
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192
Microwave Digestion ofAluminum Oxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsH₃PO₄H₂SO₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesEasyPrep Plus requires a high temperature probe for this method.
Ensure that particles are well suspended in acid mixture prior to sealing vessel.
Stirring may be helpful to keep particles suspended in solution during digestion.
ProcedureWeigh 0.25 g of sample into the digestion vessel. Add 6.5 mL H₃PO₄ and 3.5 mL H₂SO₄. Gently swirl the vessel to thoroughly mix the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 270 30:00 20:00 N/A 900-1800 N/A
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
344
Microwave Digestion ofAluminum Oxide
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193
Microwave Digestion ofAluminum Oxide (H₃PO₄)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1g
ReagentsH₃PO₄
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This method may not provide a total digest of all samples. Hydrofluoric acid may be required to provide complete digestion of some sample matrixes.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 8 mL H₃PO₄. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 260 25:00 45:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless with some white particles remaining upon dilution to 50 mL.
673
Microwave Digestion ofAluminum Oxide (H3PO4) in iPrep
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194
Microwave Digestion ofAsbestos
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHClHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesHF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 6 mL of HCl, 3 mL of HNO₃, and 3 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
492
Microwave Digestion ofAsbestos
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195
Microwave Digestion ofAutomotive Catalyst
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.4 g
ReagentsHClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. Reducing the particle size increases the efficiency of digestion and may decrease the digestion time.
ProcedureWeigh 0.4 g of the sample into the digestion vessel. Add 10 mL of HCl and 0.5 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
345
Microwave Digestion ofAutomotive Catalyst
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196
Microwave Digestion ofBarium Titanate (BaTiO₃)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesHF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel. This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 5 mL of HNO3 and 10 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
493
Microwave Digestion ofBarium Titanate (BaTiO3)
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197
Microwave Digestion ofBastnaesite Ore
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHClHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
This method could potentially form HF. It is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 9 mL of HCl and 3 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 30:00 800 900-1800 Off
Microwave Digestion ofBastnaesite Ore (Step 1 of 2)
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198
Microwave Digestion ofBastnaesite Ore
GeoscienMARS 6 (
ProcedureAllow vessels to cool. Open and add 1 g solid Boric Acid and 20 mL deionized H₂O. Wait approximately 15 minutes before closing the vessel.
ReagentsSolid Boric AcidDI H₂O
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 175 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
559
Microwave Digestion ofBastnaesite Ore (Step 2 of 2)
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199
Microwave Digestion ofBauxite
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsH₃PO₄ H₂SO₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 6.5 mL of H₃PO₄ and 3.5 mL of H₂SO₄. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 15:00 15:00 800 900-1800 Off
Microwave Digestion ofBauxite (Step 1 of 2)
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200
Microwave Digestion ofBauxite
GeoscienMARS 6 (
ProcedureProceeding step 1 add 1 mL of HNO₃, 1 mL of HCl, and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
ReagentsHNO₃HClHF
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
599
Microwave Digestion ofBauxite (Step 2 of 2)
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201
Microwave Digestion ofBismuth Aluminate Mixture
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHClHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 9 mL HCl and 3 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 190 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon diltuion to 50 mL.
746
Microwave Digestion ofBismuth Aluminate Mixture
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202
Microwave Digestion ofBismuth Yttrium Iron Oxide
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeHCl
Heating Program
Max Sample Weight0.1 g
ReagentsHCLHNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
HF should be added slowly and carefully to the sample.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 6 mL of HCl, 2 mL of HNO₃, and 0.5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 25:00 15:00 N/A 700-1800 Off
Microwave Digestion ofBismuth Yttrium Iron Oxide in iPrep (Step 1 of 2)
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203
Microwave Digestion ofBismuth Yttrium Iron Oxide
GeoscienMARS 6 (
ProcedureAllow vessel to cool. Add 1.75 g of solid H₃BO₃ + 20 mL deionized H₂O into the vessel that contains the sample and acid.
ReagentsSolid H₃BO₃DI H₂O
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeStandard
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 25:00 10:00 N/A 700-1800 Off
General Precautiona) If using HF, follow restrictions listed in HF Addendum.b) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, yellow in color, and particle free upon dilution to 50 mL.
743
Microwave Digestion ofBismuth Yttrium Iron Oxide in iPrep (Step 2 of 2)
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204
Microwave Digestion ofBoiler Scale (80-90% Fe)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 5 mL of HNO₃ and 5 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
494
Microwave Digestion ofBoiler Scale (80-90% Fe)
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205
Microwave Digestion ofBoric Acid HF Neutralization
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample WeightVaries by Sample
ReagentsH₃BO₃ (4%)
Recommended VesselsEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Alternatively, 1-4 g of solid H₃BO₃ + 25 mL deionized H₂O can be used in place of the 4% w/v solution.
ProcedureAllow vessel to cool. Add 30 mL H₃BO₃ (4%) into the vessel that contains the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSee sample specific method notes.
6
Microwave Digestion ofBoric Acid HF Neutralization
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206
Microwave Digestion ofBoron Carbide (B₄C)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃H₂SO₄HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “BoricAcid HF Neutralization”.
Reducing the particle size increases the efficiency of digestion and may decrease the digestion time.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 5 mL of HNO₃ and 5 mL of H₂SO₄. Gently swirl to mix the sample particles in the acid. Slowly and carefully add 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 270 30:00 30:00 800 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
674
Microwave Digestion ofBoron Carbide (B4C) in iPrep
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207
Microwave Digestion ofCarbon
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe structure, form and surface area of carbon samples varies widely. Higher temperatures and use of other reagents may be necessary in order to digest certain samples.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 10 mL of HNO₃ . Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 215 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
348
Microwave Digestion ofCarbon
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208
Microwave Digestion ofCement
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHNO₃HClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 3 mL of HNO₃ , 6 mL of HCL, and 3 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 175 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
349
Microwave Digestion ofCement
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209
Microwave Digestion ofCeramic (Fused Silica)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesHF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing the vessel. This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Slowly add 2 mL of HNO₃ , and 8 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 190 10:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
350
Microwave Digestion ofCeramic (Fused Silica)
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210
Microwave Digestion ofCeramics
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0. 2 g of the sample into the digestion vessel. Add 5 mL of HNO₃ , and 5 ml of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
351
Microwave Digestion ofCeramics
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211
Microwave Digestion ofChar - Sulfuric Acid
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample WeightVaries by sample
ReagentsH₂SO₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesEasyPrep Plus requires a high temperature probe for this method. This method is for the pretreatment of large sample sizes or difficult organic samples that are resistant to oxidation. After the char is complete, the vessel is opened and a normal oxidation with HNO₃ can be run, usually at around 200C.
ProcedureAdd 6 mL H₂SO₄ into the vessel that contains the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 260 15:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSee sample specific method notes.
352
Microwave Digestion ofChar - Sulfuric Acid
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212
Microwave Digestion ofChromium Carbide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃ and 10 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
558
Microwave Digestion ofChromium Carbide
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213
Microwave Digestion ofChromium Oxide (Cr₂O₃)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeStandard
Heating Program
Max Sample Weight50 mg
ReagentsH₂SO₄HNO₃H₂O₂ (30%)
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
Stirring is required for complete dissolution of this sample type.
ProcedureWeigh 50 mg of the sample into the digestion vessel. Insert stir bar into the vessel. Add 4.5 mL of H₂SO₄ and 4 mL of HNO₃ to the vessel, then 1.5 mL of H₂O₂ (30%) dropwise. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 280 30:00 59:59 N/A 900-1800 Med
2 280 0:00 30:01 N/A 900-1800 Med
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and turquoise colored upon dilution to 50 mL.
681
Microwave Digestion ofChromium Oxide (Cr2O3) in iPrep
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214
Microwave Digestion ofClay
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHFHNO₃HCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
The addition of Conc. HCl (0-4 Ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 3 mL of HNO₃ , 1 mL of HCl, and 5 ml of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
353
Microwave Digestion ofClay
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215
Microwave Digestion ofCoal
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. The use of HF may be required to digest any silicates found in the sample. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless with some particles remaining upon dilution to 50 mL.
355
Microwave Digestion ofCoal in iPrep
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216
Microwave Digestion ofCoal
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
356
Microwave Digestion ofCoal
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217
Microwave Digestion ofCoal Ash
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHNO₃HClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 3 mL of HNO₃ , 3 mL of HCl and 3 ml of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
354
Microwave Digestion ofCoal Ash
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218
Microwave Digestion ofCryolite / Electrolytic Bath
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesCryolite / Electrolytic Bath is approximately 55% Cryolite (Na₃AlF₆) and 30% Chiolite (Na₅Al₃F₁₄).
ProcedureWeigh 0.5g of the sample into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
Microwave Digestion ofCryolite / Electrolytic Bath (Step 1 of 2)
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219
Microwave Digestion ofCryolite / Electrolytic Bath
GeoscienMARS 6 (
ProcedureAllow vessel to cool after completion of Step 1. Open and add 30 mL of Deionized Water and 2 g Boric Acid (solid). Gently swirl the mixture and seal the vessel.
ReagentsDI H₂OBoric Acid (solid)
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 175 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
496
Microwave Digestion ofCryolite / Electrolytic Bath (Step 2 of 2)
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220
Microwave Digestion ofFeldspar
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHCl HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. This procedure uses hydrofluoric acid. It is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 2 mL of HCl and 8 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 25:00 N/A 700-1800 Off
Microwave Digestion ofFeldspar in iPrep (Step 1 of 2)
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221
Microwave Digestion ofFeldspar
GeoscienMARS 6 (
ProcedureAllow vessels to cool. Open and add 4 g solid boric acid and 30 mL of deionized H2O. Wait approximately 15 minutes before closing the vessel.
ReagentsSolid Boric AcidDI H₂O
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 30:00 10:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
647
Microwave Digestion ofFeldspar (Step 2 of 2)
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222
Microwave Digestion ofFerric Oxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHClHNO₃DI H₂O
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 10 mL of a 1:1:1 HCl, HNO₃, and Deionized H₂O mixture. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 25:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, yellow in color, and particle free upon dilution to 50 mL.
744
Microwave Digestion ofFerric Oxide in iPrep
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223
Microwave Digestion ofFurnace Slag
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureAdd 0.5 g of the sample into the digestion vessel. Add 3 mL of HNO₃, 2 mL of HCl, and 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
498
Microwave Digestion ofFurnace Slag
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224
Microwave Digestion ofGadolinium Zirconium Oxide
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeStandard
Heating Program
Max Sample Weight0.1 g
ReagentsH₂SO₄HNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
HF should be added slowly and carefully to the sample.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 4 mL of H₂SO₄, 1.5 mL of HNO₃ and 1.5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 280 35:00 30:00 N/A 700-1800 High
Microwave Digestion ofGadolinium Zirconium Oxide in iPrep (Step 1 of 2)
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225
Microwave Digestion ofGadolinium Zirconium Oxide
GeoscienMARS 6 (
ProcedureAllow vessel to cool. Add 1.5 g of solid H₃BO₃ + 20 mL deionized H₂O into the vessel that contains the sample and acid.
ReagentsH₃BO₃DI H₂O
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeStandard
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 25:00 10:00 N/A 700-1800 High
General Precautiona) If using HF, follow restrictions listed in HF Addendum.b) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
742
Microwave Digestion ofGadolinium Zirconium Oxide in iPrep (Step 2 of 2)
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226
Microwave Digestion ofGas Atomized Powder
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HClHF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 8 mL of HNO₃, 2 mL of HCl, and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSamples were clear, green in color and particle free upon dilution to 50 mL.
721
Microwave Digestion ofGas Atomized Powder in iPrep
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227
Microwave Digestion ofGlass Fiber
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.4 g
ReagentsHNO₃HClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureAdd 0.4 g of the sample into the digestion vessel. Add 2 mL of HNO₃, 4 mL of HCl, and 4 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
499
Microwave Digestion ofGlass Fiber
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228
Microwave Digestion ofHafnium Oxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HCl or H₂OHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel. HNO3:HF:H2O (1:1:1) can be substituted for HNO3:HCl:HF (1:1:1) using the same heating program if the use of HCl is not desired. Mixtures are made from acids in their concentrated form.
ProcedureAdd 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃:HCl:HF (1:1:1) or alternatively, HNO₃:H₂O:HF (1:1:1). (See Notes) Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
500
Microwave Digestion ofHafnium Oxide
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229
Microwave Digestion ofIlmenite (FeTiO₃)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 5 mL of HNO₃, 1 mL of HCl, and 10 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
501
Microwave Digestion ofIlmenite (FeTiO3)
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230
Microwave Digestion ofIron Ore
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsH₂OHClHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization” The addition of Conc. HCl (0-8 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 g of the sample into the digestion vessel. Add 4 mL of H₂O, 8 ml of HCl, 4 mL of HNO₃, and 4 mL of HF. Gently swirl the mixture and wait approximately 15 minute before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
358
Microwave Digestion ofIron Ore
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231
Microwave Digestion ofKaolin
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHClHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 3 mL of HCl, 1 mL of HNO3, and 7 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
502
Microwave Digestion ofKaolin
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232
Microwave Digestion ofKerosene
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe pre-digestion step will allow the lighter fuel fractions to react before sealing the vessels.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
359
Microwave Digestion ofKerosene
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233
Microwave Digestion ofLead Sulfide (PbS)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 5 mL of HNO₃ and 5 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
503
Microwave Digestion ofLead Sulfide (PbS)
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234
Microwave Digestion ofLithium Nickel Cobalt Manganese Oxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HCl
Recommended VesselsMARSXpress
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 4 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 10:00 N/A 1030-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsThe samples were clear, green in color, and particle free upon dilution.
724
Microwave Digestion ofLithium Nickel Cobalt Manganese Oxide
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235
Microwave Digestion ofMagnesium Oxide (MgO 40 -54 %)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsH₂O (deionized)HClHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution.The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 5 mL of DI H₂O, 5 mL HCl, and 5 mL HNO₃. Gently swirl and allow approximately 15 minutes for pre-digestion.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
762
Microwave Digestion ofMagnesium Oxide (MgO 40-54%)
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236
Microwave Digestion ofManganous Oxide (MnO)
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.2g of the sample into the digestion vessel. Add 10 mL HNO₃ and 3 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 10:00 800 900-1800 Off
Microwave Digestion ofManganous Oxide (MnO) (Step 1 of 2)
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237
Microwave Digestion ofManganous Oxide (MnO)
GeoscienMARS 6 (
ProcedureAllow vessel to cool after completion of Step 1. Open and add 5 mL of HCl. Gently swirl the mixture and seal the vessel.
ReagentsHCl
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
505
Microwave Digestion ofManganous Oxide (MnO) (Step 2 of 2)
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238
Microwave Digestion ofMica
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsH₃PO₄HClHF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 4 mL of H₃PO₄, 3 mL of HCl, and 0.5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
690
Microwave Digestion ofMica in iPrep
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239
Microwave Digestion ofMill Tailings
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsH₃PO₄H₂SO₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesEasyPrep Plus vessels require a high temperature probe for this method.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 3 mL of H₃PO₄, and 2 mL of H₂SO₄. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 270 15:00 30:00 800 900-1800 Off
Microwave Digestion ofMill Tailings (Step 1 of 2)
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240
Microwave Digestion ofMill Tailings
GeoscienMARS 6 (
ProcedureCool, vent and open vessel after step 1. Add 2.5 mL HNO₃, 2.5 mL HCl, 2.5 mL HF, and 2.5 ml H₂O. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing the vessel.
ReagentsHNO₃HClHFH₂O
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in method note entitled “Boric HF Neutralization” The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
600
Microwave Digestion ofMill Tailings (Step 2 of 2)
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241
Microwave Digestion ofMineral Ore
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHNO₃ HClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 3 mL of HNO₃, 3 mL of HCl, and 3 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 10:00 800 900-1800 Off
Microwave Digestion ofMineral Ore (Step 1 of 2)
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242
Microwave Digestion ofMineral Ore
GeoscienMARS 6 (
ProcedureProceeding step 1 add 25 mL of Boric Acid (4%). Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
ReagentsH₃BO₃ (4%)
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
516
Microwave Digestion ofMineral Ore (Step 2 of 2)
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243
Microwave Digestion ofMolybdenum Disulfide (MoS₂)
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureAdd 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
Microwave Digestion ofMolybdenum Disulfide (MoS2) (Step 1 of 2)
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244
Microwave Digestion ofMolybdenum Disulfide (MoS₂)
GeoscienMARS 6 (
ProcedureAllow vessel to cool after completion of Step 1. Add 10 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
ReagentsHCl
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
506
Microwave Digestion ofMolybdenum Disulfide (MoS2) (Step 2 of 2)
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245
Microwave Digestion ofNickel (II) Hydroxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HCl
Recommended VesselsMARSXpress
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 4 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 10:00 N/A 1030-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsThe samples were clear, light green in color, and particle free upon dilution.
725
Microwave Digestion ofNickel (II) Hydroxide
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246
Microwave Digestion ofNiobium Pentoxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureAdd 1.0 g of the sample into the digestion vessel. Add 2 mL of HNO₃, and 10 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
508
Microwave Digestion ofNiobium Pentoxide
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247
Microwave Digestion ofPetroleum Coke
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsH₂SO₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 10 mL of H₂SO₄. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 260 15:00 15:00 800 900-1800 Off
Microwave Digestion ofPetroleum Coke (Step 1 of 2)
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248
Microwave Digestion ofPetroleum Coke
GeoscienMARS 6 (
ProcedureProceeding step 1 add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
ReagentsHNO₃
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
601
Microwave Digestion ofPetroleum Coke (Step 2 of 2)
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249
Microwave Digestion ofPhosphate (21%)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsH₂O₂ (30%)HClHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 5 mL of H₂O₂ (30%), 5 mL HCl dropwise (wait for reaction to subside before adding next acid), and 5 mL HNO₃. Gently swirl the mixture and wait approximately 1 hour before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
761
Microwave Digestion ofPhosphate (21%)
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250
Microwave Digestion ofPhosphate Rock
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HBF₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureAdd 0.5 g of the sample into the digestion vessel. Add 5 mL of HNO₃, 5 mL of HBF₄. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
509
Microwave Digestion ofPhosphate Rock
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251
Microwave Digestion ofPollucite Ore
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃ HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 3 mL of HNO₃ and 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 25:00 25:00 N/A 700-1800 Off
Microwave Digestion ofPollucite Ore in iPrep (Step 1 of 2)
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252
Microwave Digestion ofPollucite Ore
GeoscienMARS 6 (
ProcedureAllow vessel to cool. Add 2.5 g H₃BO₃ and 25 mL of deionized H₂O into the vessel that contains the sample and acid.
ReagentsH₃BO₃ DI H₂O
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 25:00 15:00 N/A 700-1800 Off
General Precautiona) If using HF, follow restrictions listed in HF Addendum.b) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.c) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and particle free upon dilution to 50 mL.
757
Microwave Digestion ofPollucite Ore in iPrep (Step 2 of 2)
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253
Microwave Digestion ofPyrophyllite (AlSi₂)5(OH)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureAdd 0.25 g of the sample into the digestion vessel. Add 3 mL of HNO₃, 1 mL of HCl, and 7 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
510
Microwave Digestion ofPyrophyllite (AlSi2)5(OH)
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254
Microwave Digestion ofQuartz Powder
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 1 g of the sample into the digestion vessel. Add 10 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
511
Microwave Digestion ofQuartz Powder
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255
Microwave Digestion ofRock (Pulverized)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHClHFHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 5 mL of HNO₃, 3 mL of HCl, and 3 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
361
Microwave Digestion ofRock (Pulverized)
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256
Microwave Digestion ofRock, High Sulfide
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 30:00 15:00 N/A 700-1800 Off
Microwave Digestion ofRock, High Sulfide in iPrep (Step 1 of 2)
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257
Microwave Digestion ofRock, High Sulfide
GeoscienMARS 6 (
ProcedureProceeding step 1 add 3 mL of HF, and 2 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
ReagentsHFHCl
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 25:00 10:00 N/A 700-1800 Off
General Precautiona) If using HF, follow restrictions listed in HF Addendum.b) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.c) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.d) The control / reference vessel must contain the largest and most reactive sample.e) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
628
Microwave Digestion ofRock, High Sulfide in iPrep (Step 2 of 2)
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258
Microwave Digestion ofRutile Ore
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HF H₃PO₄.
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization”
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 4 mL of HNO₃, 3 mL of H₃PO₄, and 8 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 15:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 ml.
362
Microwave Digestion ofRutile Ore
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259
Microwave Digestion ofSand
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HFHCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization” The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 3 mL of HNO₃, 2 mL of HCl, and 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
363
Microwave Digestion ofSand
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260
Microwave Digestion ofShale
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHFHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.5 g of sample into the digestion vessel. Add 7 mL of HF, 3 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 25:00 15:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
698
Microwave Digestion ofShale in iPrep
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261
Microwave Digestion ofSilica Sand
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsH₂OHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAdd HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides. The above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization” Reducing the particle size increase the efficiency of digestion and may decrease the digestion time.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 5 mL of H₂O, 3 mL of HNO₃, and 8 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
364
Microwave Digestion ofSilica Sand
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262
Microwave Digestion ofSilica Sand
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHClHF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 2 mL of HCl and 8 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 25:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsThe sample was clear, colorless and particle free upon dilution to 50 mL.
700
Microwave Digestion ofSilica Sand in iPrep
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263
Microwave Digestion ofSilicon Dioxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAdd HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides. The above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization” Reducing the particle size increase the efficiency of digestion and may decrease the digestion time.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 2 mL of HNO₃, and 8 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 10:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
365
Microwave Digestion ofSilicon Dioxide
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264
Microwave Digestion ofSilicon Nitride
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureAdd 0.1 g of the sample into the digestion vessel. Add 1 mL of HNO₃ and 5 mL HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
701
Microwave Digestion ofSilicon Nitride in iPrep
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265
Microwave Digestion ofSilicon Wafer
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Piece (Approx 0.5 g)
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureAdd 1 piece (approx. 0.5 g) of the sample into the digestion vessel. Add 6 mL of HF and 3 mL of HNO3. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 10:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
366
Microwave Digestion ofSilicon Wafer
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266
Microwave Digestion ofSlag - Furnace
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization” The addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 3 mL of HNO₃, 5 mL of HCl, and 5 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
367
Microwave Digestion ofSlag - Furnace
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267
Microwave Digestion ofSodium Antimonate
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHClHNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.5 g of sample into the digestion vessel. Add 10 mL of HCl, 3 mL of HNO₃, and 2 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 30:00 15:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
702
Microwave Digestion ofSodium Antimonate in iPrep
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268
Microwave Digestion ofSpodumene (Lithium Feldspar)
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHClHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh .25 g of the sample into the digestion vessel. Add 3 mL of HCl, 1 mL of HNO₃ and 4 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 20:00 800 900-1800 Off
Microwave Digestion ofSpodumene (Lithium Feldspar) (Step 1 of 2)
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269
Microwave Digestion ofSpodumene (Lithium Feldspar)
GeoscienMARS 6 (
ProcedureAllow vessel to cool after completion of Step 1. Open and add 30 mL of Deionized H₂O and 2 g H₃BO₃ (solid). Gently swirl the mixture and seal the vessel.
ReagentsDeionized H₂OH₃BO₃ (solid)
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
512
Microwave Digestion ofSpodumene (Lithium Feldspar) (Step 2 of 2)
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270
Microwave Digestion ofSulfide Bulk Concentrate
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 30:00 20:00 N/A 700-1800 Off
Microwave Digestion ofSulfide Bulk Concentrate in iPrep (Step 1 of 2)
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271
Microwave Digestion ofSulfide Bulk Concentrate
GeoscienMARS 6 (
ProcedureProceeding step 1 add 5 mL of HCl, and 5 mL of Deionized Water. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
ReagentsHClDI H₂O
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 30:00 10:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
635
Microwave Digestion ofSulfide Bulk Concentrate in iPrep (Step 2 of 2)
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272
Microwave Digestion ofTantalum Pentoxide (Ta₂O₅)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of sample into the digestion vessel. Add 3 mL of HNO₃, and 7 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 25:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
707
Microwave Digestion ofTantalum Pentoxide (Ta2O5) in iPrep
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273
Microwave Digestion ofTitanium Dioxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃ and 2 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
489
Microwave Digestion ofTitanium Dioxide
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274
Microwave Digestion ofTitanium Slag Ore
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.25 g of sample into the digestion vessel. Add 5 mL of HNO₃, and 10 mL of HF. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing the vessel.
Reducing the particle size increases the efficiency of digestion and may decrease the digestion time.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
708
Microwave Digestion ofTitanium Slag Ore in iPrep
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275
Microwave Digestion ofTungsten Carbide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAdd HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides. The above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization” Reducing the particle size increase the efficiency of digestion and may decrease the digestion time.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Slowly add 5 mL of HNO₃, and 10 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 20:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
369
Microwave Digestion ofTungsten Carbide
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276
Microwave Digestion ofTungsten Ore (50% W; 10% Fe; 2% Mn)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 9 mL of HCl and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 25:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
513
Microwave Digestion ofTungsten Ore (50% W; 10% Fe; 2% Mn)
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277
Microwave Digestion ofTungsten Oxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAdd HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides. The above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization” Reducing the particle size increase the efficiency of digestion and may decrease the digestion time.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Slowly add 2 mL of HNO₃, and 7 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 20:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
370
Microwave Digestion ofTungsten Oxide
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278
Microwave Digestion ofVermiculite
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureAdd 0.25 g of the sample into the digestion vessel. Add 1 mL of HNO₃, 4 mL of HCl, and 10 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
514
Microwave Digestion ofVermiculite
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279
Microwave Digestion ofWollastonite (Calcium Silicate)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsH₃PO₄HNO₃HBF₄
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.1 g of sample into the digestion vessel. Add 3 mL of H₃PO₄, 2 mL of HNO₃, and 3 mL of HBF₄. HBF₄ should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
711
Microwave Digestion ofWollastonite (Calcium Silicate) in iPrep
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280
Microwave Digestion ofZeolite
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAdd HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides. The above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization”
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 5 mL of HNO₃, 4 mL of HCl, and 2 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
371
Microwave Digestion ofZeolite
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281
Microwave Digestion ofZinc Oxide (ZnO)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 5 mL of HNO₃ and 2 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
393
Microwave Digestion ofZinc Oxide (ZnO)
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282
Microwave Digestion ofZinc Oxide (ZnO)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.25 g of the sample (onto a filter disk) into the digestion vessel. Add 5 mL HNO₃ and 2 mL HF. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 25:00 15:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
712
Microwave Digestion ofZinc Oxide (ZnO) in iPrep
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283
Microwave Digestion ofZircon
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight50 mg
ReagentsH₂SO₄HNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureAdd 50 mg of the sample into the digestion vessel. Add 4 mL of H₂SO₄, 1.5 mL of HNO₃, and 1.5 mL HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 270 40:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
713
Microwave Digestion ofZircon in iPrep
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Industrial Hygiene
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285
Microwave Digestion ofAsbestos
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHClHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesHF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 6 mL of HCl, 3 mL of HNO₃, and 3 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
492
Microwave Digestion ofAsbestos
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286
Microwave Digestion ofFilter (MCE)
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight60 mg
ReagentsHClHNO₃
Recommended Vessels20 mL MARSXpress
Recommended EquipmentMARS 6 iWave
NotesThis method was completed in the 20 mL disposable liner.
ProcedureWeigh one 37mm filter and one 25 mm filter (60 mg total) into the digestion vessel. Add 1 mL of HCl and 1 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 20:00 10:00 N/A 1050-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
745
Microwave Digestion ofFilter (MCE)
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287
Microwave Digestion ofFilter Paper - 37 mm Mixed Cellulose Ester
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Filter (Approx 0.3 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 filter (approx 0.3 g) into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
373
Microwave Digestion ofFilter Paper - 37 mm Mixed Cellulose Ester
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288
Microwave Digestion ofFilter Paper - 47 mm Polycarbonate
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Filter (Approx 0.4 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 filter (approx 0.4 g) into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
374
Microwave Digestion ofFilter Paper - 47 mm Polycarbonate
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289
Microwave Digestion ofFilter Paper - Cellulose
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Filter (Approx 0.9 g)
ReagentsH₂OHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAdd H₂O before HNO₃. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 filter (approx 0.9 g) of the sample into the digestion vessel. Add 5 mL of H₂O, and 5 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
372
Microwave Digestion ofFilter Paper - Cellulose
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290
Microwave Digestion ofGhost Wipe
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Wipe (Approx 2.5 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesEnsure that the entire wipe is covered with reagent.
ProcedureWeigh 1 wipe (approx 2.5 g) into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
375
Microwave Digestion ofGhost Wipe
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291
Microwave Digestion ofPaint Chips (For Pb Analysis)
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesHF may be required for a total dissolution.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, with some remaining inorganic particles upon dilution to 50 mL.
399
Microwave Digestion ofPaint Chips (For Pb Analysis)
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292
Microwave Digestion ofQuartz Fiber Filters
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.35 g (1 filter)
ReagentsHNO₃HF
Recommended VesselsMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis method should not exceed 180 degrees celsius.
This application should only be completed using the 75 mL Xpress or 110 mL Xpress Plus vessels. It is not suitable for the smaller Xpress vessels (55 mL, 20 mL, or 10 mL).
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureWeigh 1 filter (approximately 0.35 g) of the sample into the digestion vessel. Add 8 mL of HNO₃ and 2 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 20:00 15:00 N/A 1030-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSamples were clear, colorless, and particle free upon dilution to 50 mL with deionized water.
727
Microwave Digestion ofQuartz Fiber Filters
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293
Microwave Digestion ofToray Filter
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Filter (Approx 0.3 - 0.5 g)
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 1 filter (approximately 0.3-0.5 g) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 20:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
376
Microwave Digestion ofToray Filter in iPrep
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294
Microwave Digestion ofToray Filter (Anion)
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Filter (Approx 0.3 - 0.5 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureAdd 1 toray filter (Approx. 0.3 - 0.5 g) into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
561
Microwave Digestion ofToray Filter (Anion)
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295
Microwave Digestion ofToray Filter (Cation)
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Filter (Approx 0.3 -0.5 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureAdd 1 toray filter (Approx. 0.3 - 0.5 g) into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 20:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
562
Microwave Digestion ofToray Filter (Cation)
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Materials Science
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297
Microwave Digestion ofAcrylic Tape
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃DI H₂OHClHF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 3 mL of Deionized water, 7 mL of HNO₃, 1.5 mL of HCl, and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 30:00 10:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
720
Microwave Digestion ofAcrylic Tape in iPrep
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298
Microwave Digestion ofBismuth Aluminate Mixture
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHClHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 9 mL HCl and 3 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 190 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon diltuion to 50 mL.
746
Microwave Digestion ofBismuth Aluminate Mixture
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299
Microwave Digestion ofBismuth Yttrium Iron Oxide
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeHCl
Heating Program
Max Sample Weight0.1 g
ReagentsHCLHNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
HF should be added slowly and carefully to the sample.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 6 mL of HCl, 2 mL of HNO₃, and 0.5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 25:00 15:00 N/A 700-1800 Off
Microwave Digestion ofBismuth Yttrium Iron Oxide in iPrep (Step 1 of 2)
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300
Microwave Digestion ofBismuth Yttrium Iron Oxide
GeoscienMARS 6 (
ProcedureAllow vessel to cool. Add 1.75 g of solid H₃BO₃ + 20 mL deionized H₂O into the vessel that contains the sample and acid.
ReagentsSolid H₃BO₃DI H₂O
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeStandard
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 25:00 10:00 N/A 700-1800 Off
General Precautiona) If using HF, follow restrictions listed in HF Addendum.b) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, yellow in color, and particle free upon dilution to 50 mL.
743
Microwave Digestion ofBismuth Yttrium Iron Oxide in iPrep (Step 2 of 2)
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301
Microwave Digestion ofCeramic Powder
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HFBoric Acid (solid)H₂O
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. It is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed with boric acid.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 5 mL of HNO₃, 10 mL of HF, 4.4 g of Boric Acid solid, and 25 mL of H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 195 15:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
752
Microwave Digestion ofCeramic Powder
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302
Microwave Digestion ofCeramic Powder
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HFBoric Acid (solid)H₂O
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis Application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed with boric acid.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 5 mL of HNO₃, 10 mL of HF, 4.4 g of Boric Acid solid, and 25 mL of H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 195 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
753
Microwave Digestion ofCeramic Powder in iPrep
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303
Microwave Digestion ofCircuit Board (Cryo - Ground)
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHClHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesHCl should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel. This method is considered a leach and may not provide a total digestion.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 3 mL of HNO₃ and 9 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 1030-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, with particles upon dilution to 50 mL.
377
Microwave Digestion ofCircuit Board (Cryo - Ground)
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304
Microwave Digestion ofFerric Oxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHClHNO₃DI H₂O
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 10 mL of a 1:1:1 HCl, HNO₃, and Deionized H₂O mixture. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 25:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, yellow in color, and particle free upon dilution to 50 mL.
744
Microwave Digestion ofFerric Oxide in iPrep
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305
Microwave Digestion ofGadolinium Zirconium Oxide
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeStandard
Heating Program
Max Sample Weight0.1 g
ReagentsH₂SO₄HNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
HF should be added slowly and carefully to the sample.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 4 mL of H₂SO₄, 1.5 mL of HNO₃ and 1.5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 280 35:00 30:00 N/A 700-1800 High
Microwave Digestion ofGadolinium Zirconium Oxide in iPrep (Step 1 of 2)
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306
Microwave Digestion ofGadolinium Zirconium Oxide
GeoscienMARS 6 (
ProcedureAllow vessel to cool. Add 1.5 g of solid H₃BO₃ + 20 mL deionized H₂O into the vessel that contains the sample and acid.
ReagentsH₃BO₃DI H₂O
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeStandard
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 25:00 10:00 N/A 700-1800 High
General Precautiona) If using HF, follow restrictions listed in HF Addendum.b) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
742
Microwave Digestion ofGadolinium Zirconium Oxide in iPrep (Step 2 of 2)
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307
Microwave Digestion ofGas Atomized Powder
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HClHF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 8 mL of HNO₃, 2 mL of HCl, and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSamples were clear, green in color and particle free upon dilution to 50 mL.
721
Microwave Digestion ofGas Atomized Powder in iPrep
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308
Microwave Digestion ofGlass (Ground)
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHClHFHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 2 mL of HNO₃, 4 mL of HCl, and 3 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
378
Microwave Digestion ofGlass (Ground)
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309
Microwave Digestion ofGraphite Composite - Cyanate Ester Resin
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.5 g of the sample into the digestion vessel. Add 30 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 150 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
563
Microwave Digestion ofGraphite Composite - Cyanate Ester Resin
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310
Microwave Digestion ofGraphite Composite - Epoxy Resin
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.0 g of the sample into the digestion vessel. Add 30 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 150 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
564
Microwave Digestion ofGraphite Composite - Epoxy Resin
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311
Microwave Digestion ofGraphite Composite - PEEK Resin
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1.0 g of the sample into the digestion vessel. Add 30 mL of HNO3. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 160 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
565
Microwave Digestion ofGraphite Composite - PEEK Resin
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312
Microwave Digestion ofGraphite Fiber - Cyanate Siloxane Resin
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Laminate Square (Approx. 1 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesSample must be completely covered with acid prior to digestion.
After digestion the samples are filtered and the fibers are rinsed with deionized water.
This method is for the gravimetric (weight) determination of fiber content.
ProcedureAdd 1 Laminate Square (Approx. 1 g) of the sample into the digestion vessel. Add 35 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 150 10:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was digested, but the fiber filler material is left undigested for subsequent gravimetric analysis.
567
Microwave Digestion ofGraphite Fiber - Cyanate Siloxane Resin
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313
Microwave Digestion ofGraphite Fiber - Epoxy Resin (Fiber Content)
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesSample must be completely covered with acid prior to digestion.
After digestion the samples are filtered and the graphite fibers are rinsed with deionized water.
This method is for the gravimetric (weight) determination of fiber content.
ProcedureWeigh 1 g of the sample into the digestion vessel. Add 30 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 150 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was digested, but the fiber filler material is left undigested for subsequent gravimetric analysis.
379
Microwave Digestion ofGraphite Fiber - Epoxy Resin (Fiber Content)
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314
Microwave Digestion ofPollucite Ore
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃ HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 3 mL of HNO₃ and 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 25:00 25:00 N/A 700-1800 Off
Microwave Digestion ofPollucite Ore in iPrep (Step 1 of 2)
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315
Microwave Digestion ofPollucite Ore
GeoscienMARS 6 (
ProcedureAllow vessel to cool. Add 2.5 g H₃BO₃ and 25 mL of deionized H₂O into the vessel that contains the sample and acid.
ReagentsH₃BO₃ DI H₂O
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 25:00 15:00 N/A 700-1800 Off
General Precautiona) If using HF, follow restrictions listed in HF Addendum.b) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.c) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and particle free upon dilution to 50 mL.
757
Microwave Digestion ofPollucite Ore in iPrep (Step 2 of 2)
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316
Microwave Digestion ofSiloxanes
Materials MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 2 mL of HNO₃ and 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
760
Microwave Digestion ofSiloxanes
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Metals & Alloys
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318
Microwave Digestion ofAlpha - Alumina
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeHCl
Heating Program
Max Sample Weight0.5 g
ReagentsHCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The maximum number of vessels that can be run for this method is 6.
Ensure that particles are well suspended in acid mixture prior to sealing vessel.
Stirring may be helpful to keep particles suspended in solution during digestion.
ProcedureWeigh 0.5 g of sample into the digestion vessel. Add 10 mL HCl. Gently swirl the vessel to thoroughly mix the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 59:59 N/A 900-1800 N/A
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
343
Microwave Digestion ofAlpha - Alumina in iPrep
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319
Microwave Digestion ofAluminum (Metal)
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHCl DI H₂O
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesHCl should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HCl and 3 mL of DI H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
382
Microwave Digestion ofAluminum (Metal)
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320
Microwave Digestion ofAluminum Alloy
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHClH₂O
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAdd H₂O before HCl. Add HCl slowly, and allow vessels to stand in the fume hood until initial reaction subsides.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 5 mL of H₂O and 5 mL of HCl .Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 190 10:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
381
Microwave Digestion ofAluminum Alloy
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321
Microwave Digestion ofAluminum Alloy (20% SiC)
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization". The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 5 mL of HCl and 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
569
Microwave Digestion ofAluminum Alloy (20% SiC)
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322
Microwave Digestion ofAluminum Alloy (BCS 182)
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHClH₂O₂ (30%)HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization". The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 20 mL of HCl, 10 mL of H₂O₂ (30%), and 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 10:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
568
Microwave Digestion ofAluminum Alloy (BCS 182)
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323
Microwave Digestion ofAluminum Oxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsH₃PO₄H₂SO₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesEasyPrep Plus requires a high temperature probe for this method.
Ensure that particles are well suspended in acid mixture prior to sealing vessel.
Stirring may be helpful to keep particles suspended in solution during digestion.
ProcedureWeigh 0.25 g of sample into the digestion vessel. Add 6.5 mL H₃PO₄ and 3.5 mL H₂SO₄. Gently swirl the vessel to thoroughly mix the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 270 30:00 20:00 N/A 900-1800 N/A
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
344
Microwave Digestion ofAluminum Oxide
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324
Microwave Digestion ofAluminum Oxide (H₃PO₄)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1g
ReagentsH₃PO₄
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This method may not provide a total digest of all samples. Hydrofluoric acid may be required to provide complete digestion of some sample matrixes.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 8 mL H₃PO₄. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 260 25:00 45:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless with some white particles remaining upon dilution to 50 mL.
673
Microwave Digestion ofAluminum Oxide (H3PO4) in iPrep
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325
Microwave Digestion ofBoron
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 5 mL of HNO₃ and 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 175 15:00 25:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
570
Microwave Digestion ofBoron
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326
Microwave Digestion ofBoron Carbide (B₄C)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃H₂SO₄HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “BoricAcid HF Neutralization”.
Reducing the particle size increases the efficiency of digestion and may decrease the digestion time.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 5 mL of HNO₃ and 5 mL of H₂SO₄. Gently swirl to mix the sample particles in the acid. Slowly and carefully add 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 270 30:00 30:00 800 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
674
Microwave Digestion ofBoron Carbide (B4C) in iPrep
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327
Microwave Digestion ofCarbonyl Iron
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HClHBF₄
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 6 mL HNO₃, 2 mL HCl, and 1 mL HBF₄ slowly. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, yellow in color with no visible particles upon dilution to 50 mL.
678
Microwave Digestion ofCarbonyl Iron in iPrep
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328
Microwave Digestion ofCobalt - Chromium Alloy (Co-Cr)
Metals anMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HFDI H₂O
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization". Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
ProcedureAdd 0.5 g of the sample into the digestion vessel. Add 5 mL of HNO₃, 5 mL of HF, and 5 mL of deionized H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
Microwave Digestion ofCobalt - Chromium Alloy (Co-Cr) (Step 1 of 2)
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329
Microwave Digestion ofCobalt - Chromium Alloy (Co-Cr)
Metals anMARS 6 (
ProcedureAllow vessels to cool. Open and add 4 mL of H₂O₂ (30%) dropwise. Wait approximately 15 minutes before closing the vessel.
ReagentsH₂O₂ (30%)
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
572
Microwave Digestion ofCobalt - Chromium Alloy (Co-Cr) (Step 2 of 2)
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330
Microwave Digestion ofCopper (Metal)
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
384
Microwave Digestion ofCopper (Metal)
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331
Microwave Digestion ofCopper Ore
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃, HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis method is intended to be an acid leach, not a total digest. Hydrofluoric acid will be required to provide complete digestion of the sample matrix. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g (0.25 g w/Xpress Vessels) of the sample into the digestion vessel. Add 10 mL of Aqua Regia (3:1 HCl:HNO₃ ,). Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, and colorless with some remaining particles upon dilution to 50 mL.
383
Microwave Digestion ofCopper Ore
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332
Microwave Digestion ofGallium
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHNO₃ HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 2 mL of HNO₃ and 8 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
573
Microwave Digestion ofGallium
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333
Microwave Digestion ofIron - Chromium Alloy
Metals anMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHClHFDI H₂O
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization". The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureAdd 0.5 g of the sample into the digestion vessel. Add 5 mL of HCl, 5 mL of HF, and 2 mL of deionized H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
Microwave Digestion ofIron - Chromium Alloy (Step 1 of 2)
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334
Microwave Digestion ofIron - Chromium Alloy
Metals anMARS 6 (
ProcedureAllow vessels to cool. Open and add 5 mL of HNO₃. Wait approximately 15 minutes before closing the vessel.
ReagentsHNO₃
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
575
Microwave Digestion ofIron - Chromium Alloy (Step 2 of 2)
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335
Microwave Digestion ofIron - Chromium Alloy
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHClHFHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 5 mL of HCl, 5 mL of HF, and 5 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 30:00 15:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
685
Microwave Digestion ofIron - Chromium Alloy in iPrep
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336
Microwave Digestion ofIron - Lignosulfonate
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
574
Microwave Digestion ofIron - Lignosulfonate
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337
Microwave Digestion ofIron - Manganese Alloy
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization". The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HCl and 2 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
576
Microwave Digestion ofIron - Manganese Alloy
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338
Microwave Digestion ofIron - Silicon Alloy
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HFHCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Noteshis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HF, 5 mL HCl, and 3 mL HNO₃. Gently swirl the mixture and allow any initial reaction to subside before sealing vessel. HF should be added slowly and carefully to the sample.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
577
Microwave Digestion ofIron - Silicon Alloy
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339
Microwave Digestion ofLead Sulfide (PbS)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 5 mL of HNO₃ and 5 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
503
Microwave Digestion ofLead Sulfide (PbS)
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340
Microwave Digestion ofLithium Nickel Cobalt Manganese Oxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HCl
Recommended VesselsMARSXpress
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 4 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 10:00 N/A 1030-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsThe samples were clear, green in color, and particle free upon dilution.
724
Microwave Digestion ofLithium Nickel Cobalt Manganese Oxide
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341
Microwave Digestion ofMagnesium Oxide (MgO 40 -54 %)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsH₂O (deionized)HClHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution.The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 5 mL of DI H₂O, 5 mL HCl, and 5 mL HNO₃. Gently swirl and allow approximately 15 minutes for pre-digestion.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
762
Microwave Digestion ofMagnesium Oxide (MgO 40-54%)
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342
Microwave Digestion ofManganous Oxide (MnO)
GeoscienMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.2g of the sample into the digestion vessel. Add 10 mL HNO₃ and 3 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 10:00 800 900-1800 Off
Microwave Digestion ofManganous Oxide (MnO) (Step 1 of 2)
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343
Microwave Digestion ofManganous Oxide (MnO)
GeoscienMARS 6 (
ProcedureAllow vessel to cool after completion of Step 1. Open and add 5 mL of HCl. Gently swirl the mixture and seal the vessel.
ReagentsHCl
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
505
Microwave Digestion ofManganous Oxide (MnO) (Step 2 of 2)
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344
Microwave Digestion ofMetal Alloy - FeCr
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHClHFHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization”
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 5 mL of HCl, 5 mL of HNO₃, and 5 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
385
Microwave Digestion ofMetal Alloy - FeCr
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345
Microwave Digestion ofMetal Alloy - NiCr
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsH₂OHNO₃ HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization”
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 5 mL of H₂O, 5 mL of HNO₃, and 5 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
386
Microwave Digestion ofMetal Alloy - NiCr
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346
Microwave Digestion ofMetal Alloy (Ag, Au, Cu)
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeHCl
Heating Program
Max Sample Weight0.1 g
ReagentsHClHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This method may not provide a total digest of all samples. Hydrofluoric acid may be required to provide complete digestion of some sample matrices.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 9 mL HCl, 1 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 25:00 25:00 N/A 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was yellow in color, with some white particles remaining upon dilution to 50 mL.
686
Microwave Digestion ofMetal Alloy (Ag, Au, Cu) in iPrep
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347
Microwave Digestion ofMetal Alloy (Ag, Co, Cu)
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃Deionized H₂OHF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 3 mL HNO₃, 3 mL Deionized H₂O and 3 mL HF (in this order). Add HF slowly and carefully. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 25:00 25:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
687
Microwave Digestion ofMetal Alloy (Ag, Co, Cu) in iPrep
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348
Microwave Digestion ofMetal Alloy (Ag, Cu, Sn)
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃DI H₂OHF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 3 mL HNO₃, 3 mL Deionized Water, and 3 mL HF in this order. Add HF slowly and carefully. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 25:00 25:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
688
Microwave Digestion ofMetal Alloy (Ag, Cu, Sn) in iPrep
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349
Microwave Digestion ofMetal Ore - Precious
Metals anMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃ HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization”
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 10 mL of HNO₃, and 0.5 ml of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 20:00 800 900-1800 Off
Microwave Digestion ofMetal Ore - Precious (Step 1 of 2)
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350
Microwave Digestion ofMetal Ore - Precious
Metals anMARS 6 (
ProcedureCool, vent and open vessel after step 1. Add 5 ml of HCl.
ReagentsHCl
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
603
Microwave Digestion ofMetal Ore - Precious (Step 2 of 2)
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351
Microwave Digestion ofMetals Alloy (Co-Cr)
Metals anMARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HFH2O
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Deionized Water may improve solubility of metal alloys.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 5 ml of HNO₃, 5 ml of HF, and 5 of ml H2O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
Microwave Digestion ofMetals Alloy (Co-Cr) (Step 1 of 2)
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352
Microwave Digestion ofMetals Alloy (Co-Cr)
Metals anMARS 6 (
ProcedureCool, vent and open vessel after step 1. Add 4 ml of H₂O₂, (30%)
ReagentsH₂O₂
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
602
Microwave Digestion ofMetals Alloy (Co-Cr) (Step 2 of 2)
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353
Microwave Digestion ofNickel (II) Hydroxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HCl
Recommended VesselsMARSXpress
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 4 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 10:00 N/A 1030-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsThe samples were clear, light green in color, and particle free upon dilution.
725
Microwave Digestion ofNickel (II) Hydroxide
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354
Microwave Digestion ofNickel (Metal)
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃DI H₂O
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of sample into the digestion vessel. Add 5 mL of HNO₃ and 5 mL of DI H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
387
Microwave Digestion ofNickel (Metal)
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355
Microwave Digestion ofNiobium - Titanium Alloy
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHFHNO₃DI H₂O
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Noteshis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 1 mL of HF, 5 mL HNO₃, and 5 mL of deionized H₂O. Gently swirl the mixture and wait approximately 15 minutes before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
578
Microwave Digestion ofNiobium - Titanium Alloy
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356
Microwave Digestion ofPhosphate (21%)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsH₂O₂ (30%)HClHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 5 mL of H₂O₂ (30%), 5 mL HCl dropwise (wait for reaction to subside before adding next acid), and 5 mL HNO₃. Gently swirl the mixture and wait approximately 1 hour before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
761
Microwave Digestion ofPhosphate (21%)
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357
Microwave Digestion ofPlatinum Metal
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of Aqua Regia (3:1 HCl:HNO₃). Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
388
Microwave Digestion ofPlatinum Metal
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358
Microwave Digestion ofPlatinum Ruthenium
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeHCl
Heating Program
Max Sample Weight0.1 g
ReagentsHClHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 6 mL of HCl, and 2 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 59:59 N/A 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
694
Microwave Digestion ofPlatinum Ruthenium in iPrep
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359
Microwave Digestion ofRhodium Sponge
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeHCl
Heating Program
Max Sample Weight0.1 g
ReagentsHClH₂O₂
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The maximum number of vessels that can be run with this method is 6.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 10 mL of HCl and 2 mL of H₂O₂ dropwise. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 25:00 45:00 N/A 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless upon dilution to 50 mL.
697
Microwave Digestion ofRhodium Sponge in iPrep
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360
Microwave Digestion ofSelenium Alloy
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1 g (0.5 g w/Xpress Vessels) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
389
Microwave Digestion ofSelenium Alloy
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361
Microwave Digestion ofSn - Ag Solder
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsH₂OHNO₃HF
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesCaution must be taken when adding the acid solution to the sample as the reaction is very vigorous and exothermic.
Allow any initial reaction to subside before sealing the vessel.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Slowly add dropwise 10 ml of 1:1:1 H₂O:HNO₃:HF (premixed) to the sample. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
390
Microwave Digestion ofSn - Ag Solder
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362
Microwave Digestion ofStainless and Low Carbon Steel
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeHCl
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureAdd 0.25 g of the sample into the digestion vessel. Add 3 mL of HNO₃, and 9 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 25:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, gold colored, and particle free upon dilution to 50 mL.
704
Microwave Digestion ofStainless and Low Carbon Steel in iPrep
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363
Microwave Digestion ofStainless Steel
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HFHCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization”
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 ml of HCl, 3 mL of HNO₃, and 3 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
391
Microwave Digestion ofStainless Steel
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364
Microwave Digestion ofSteel (Stainless)
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHClHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis method may not provide a total digest of all samples. Hydrofluoric acid will be required to provide complete digestion of some sample matrixes.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 3 mL of HNO₃ and 9 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
392
Microwave Digestion ofSteel (Stainless)
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365
Microwave Digestion ofStrontium Ferrite
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeHCl
Heating Program
Max Sample Weight0.5 g
ReagentsHClHF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution.
ProcedureWeigh 0.5 g of sample into the digestion vessel. Add 10 mL of HCl and 0.5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 30:00 15:00 N/A 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
705
Microwave Digestion ofStrontium Ferrite in iPrep
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366
Microwave Digestion ofTitanium Alloy
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HFHCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe above procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric HF Neutralization”
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 5 mL of HNO₃, 2 mL of HCl, and 5 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
479
Microwave Digestion ofTitanium Alloy
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367
Microwave Digestion ofTitanium Dioxide
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃ and 2 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
489
Microwave Digestion ofTitanium Dioxide
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368
Microwave Digestion ofTungsten Ore (50% W; 10% Fe; 2% Mn)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHClHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 9 mL of HCl and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 25:00 20:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
513
Microwave Digestion ofTungsten Ore (50% W; 10% Fe; 2% Mn)
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369
Microwave Digestion ofZinc Oxide (ZnO)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 5 mL of HNO₃ and 2 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.HF should be added slowly and carefully to the sample. Allow any initial reaction to subside before sealing vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
393
Microwave Digestion ofZinc Oxide (ZnO)
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370
Microwave Digestion ofZinc Oxide (ZnO)
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.25 g of the sample (onto a filter disk) into the digestion vessel. Add 5 mL HNO₃ and 2 mL HF. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 25:00 15:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
712
Microwave Digestion ofZinc Oxide (ZnO) in iPrep
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371
Microwave Digestion ofZircon Alloy
Metals anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHFHNO₃DI H₂O
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureAdd 1.0 g of the sample into the digestion vessel. Add 5 mL of HF, 1 mL HNO₃, and 10 mL of deionized H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
580
Microwave Digestion ofZircon Alloy
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Nutraceuticals
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373
Nutraceuticals
Microwave Digestion ofBiotin
NutraceutiMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
394
Microwave Digestion ofBiotin
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374
Microwave Digestion ofCannabis (Plant)
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃, or alternatively 9 mL HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
715
Microwave Digestion ofCannabis (Plant)
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375
Microwave Digestion ofChili Powder
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2 g
ReagentsHNO₃DI H₂O
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 2 g of the sample into the digestion vessel. Add 10 mL HNO₃ and 5 mL deionized H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless with some small particles (silicates) remaining upon dilution to 50 mL.
680
Microwave Digestion ofChili Powder in iPrep
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376
Microwave Digestion ofCitrus Leaves
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃DI H₂OHF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 6 mL of HNO₃, 3 mL of deionized H₂O, and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
539
Microwave Digestion ofCitrus Leaves
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377
Microwave Digestion ofGinkgo (Ground)
NutraceutiMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
395
Microwave Digestion ofGinkgo (Ground)
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378
Microwave Digestion ofGinkgo (Whole Pill)
NutraceutiMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Pill (Approx 1.0 g)
ReagentsHNO₃H₂O₂
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 pill (approx 1.0 g) into the digestion vessel. Add 10 mL of HNO₃ and 2 mL of H₂O₂. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
396
Microwave Digestion ofGinkgo (Whole Pill)
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379
Microwave Digestion ofInfant Formula (Liquid)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight2 mL
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 2 mL of of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
Results Sample was clear, colorless and particle free upon dilution to 50 mL
301
Microwave Digestion ofInfant Formula (Liquid) in iPrep
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380
Microwave Digestion ofInfant Formula (Liquid)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 1 mL (0.5 mL w/Xpress Vessels) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
302
Microwave Digestion ofInfant Formula (Liquid)
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381
Microwave Digestion ofInfant Formula (Powder)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
303
Microwave Digestion ofInfant Formula (Powder) in iPrep
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382
Microwave Digestion ofInfant Formula (Powder)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g (0.25 g w/Xpress Vessels) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
304
Microwave Digestion ofInfant Formula (Powder)
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383
Microwave Digestion ofKelp
NutraceutiMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight 0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
421
Microwave Digestion ofKelp
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384
Microwave Digestion ofMilk (Whole - Liquid)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight4 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 4 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
309
Microwave Digestion ofMilk (Whole - Liquid)
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385
Microwave Digestion ofMilk (Powder)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
310
Microwave Digestion ofMilk (Powder)
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386
Microwave Digestion ofPlant Tissue
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis. Some plant tissues contain silicates which would require HF for total dissolution.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
234
Microwave Digestion ofPlant Tissue
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387
Microwave Digestion ofUSP 232/233 (Pharmaceuticals)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL HCl. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
265
Microwave Digestion ofUSP 232/233 (Pharmaceuticals)
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388
Microwave Digestion ofWheat
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
239
Microwave Digestion ofWheat
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389
Microwave Digestion ofWhey (Powder)
Food TestMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
339
Microwave Digestion ofWhey (Powder)
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Organic Chemicals
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391
Microwave Digestion ofDi-(2-ethylhexyl)phosphoric Acid
Organic CMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 mL
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureTransfer 0.5 mL of the sample into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 30:00 15:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
682
Microwave Digestion ofDi-(2-ethylhexyl)phosphoric Acid in iPrep
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392
Microwave Digestion ofDiazo Sulfonyl Chloride
Organic CMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
581
Microwave Digestion ofDiazo Sulfonyl Chloride
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393
Microwave Digestion ofFood Coloring (Erythrosine Based)
Organic CMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
582
Microwave Digestion ofFood Coloring (Erythrosine Based)
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394
Microwave Digestion ofMethylcellulose (Hydroxypropyl)
Organic CMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃DI H₂O
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 10 mL of HNO₃ and 2 mL of deionized H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
583
Microwave Digestion ofMethylcellulose (Hydroxypropyl)
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395
Microwave Digestion ofMonoethanolamine
Organic CMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 5 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
584
Microwave Digestion ofMonoethanolamine
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396
Microwave Digestion ofPhotoresist
Organic CMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureAdd 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
398
Microwave Digestion ofPhotoresist
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397
Microwave Digestion ofPolygluteramide
Organic CMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
585
Microwave Digestion ofPolygluteramide
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Paints & Coatings
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399
Microwave Digestion ofPaint (Latex Based Liquid)
Paints anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesHF is required for a total dissolution of inorganic filler if present.
If this procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 1 g (0.5 g w/Xpress Vessels) of sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
400
Microwave Digestion ofPaint (Latex Based Liquid)
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400
Microwave Digestion ofPaint Chips (For Pb Analysis)
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesHF may be required for a total dissolution.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, with some remaining inorganic particles upon dilution to 50 mL.
399
Microwave Digestion ofPaint Chips (For Pb Analysis)
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401
Microwave Digestion ofPhotoresist
Organic CMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureAdd 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
398
Microwave Digestion ofPhotoresist
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402
Microwave Digestion ofPolyurethane
Paints anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
468
Microwave Digestion ofPolyurethane
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403
Microwave Digestion ofPolyurethane
Paints anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 6 mL HNO₃, and 3 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
696
Microwave Digestion ofPolyurethane in iPrep
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404
Microwave Digestion ofToner (Ink)
Paints anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. The use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 20:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless with some particles remaining upon dilution to 50 mL.
401
Microwave Digestion ofToner (Ink) in iPrep
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405
Microwave Digestion ofToner (Powder)
Paints anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The use of HF may be required to digest any silicates found in the sample.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.e) If using HF, follow restrictions listed in HF Addendum.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
709
Microwave Digestion ofToner (Powder) in iPrep
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Paper & Pulp
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407
Microwave Digestion ofFilter Paper - 37 mm Mixed Cellulose Ester
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Filter (Approx 0.3 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 filter (approx 0.3 g) into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
373
Microwave Digestion ofFilter Paper - 37 mm Mixed Cellulose Ester
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408
Microwave Digestion ofFilter Paper - 47 mm Polycarbonate
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Filter (Approx 0.4 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 filter (approx 0.4 g) into the digestion vessel. Add 10 mL HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
374
Microwave Digestion ofFilter Paper - 47 mm Polycarbonate
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409
Microwave Digestion ofFilter Paper - Cellulose
Industrial MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Filter (Approx 0.9 g)
ReagentsH₂OHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAdd H₂O before HNO₃. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 filter (approx 0.9 g) of the sample into the digestion vessel. Add 5 mL of H₂O, and 5 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
372
Microwave Digestion ofFilter Paper - Cellulose
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410
Microwave Digestion ofPaper Pulp
Paper anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
473
Microwave Digestion ofPaper Pulp
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Personal Care
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412
Microwave Digestion ofBoric Acid HF Neutralization
AgriculturMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample WeightVaries by Sample
ReagentsH₃BO₃ (4%)
Recommended VesselsEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure can be used if it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed by reaction of certain analytes with hydrofluoric acid.
Alternatively, 1-4 g of solid H₃BO₃ + 25 mL deionized H₂O can be used in place of the 4% w/v solution.
ProcedureAllow vessel to cool. Add 30 mL H₃BO₃ (4%) into the vessel that contains the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSee sample specific method notes.
6
Microwave Digestion ofBoric Acid HF Neutralization
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413
Microwave Digestion ofCosmetics (Liquid Make-Up)
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 8 mL of HNO₃ and 2 mL of HF. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
246
Microwave Digestion ofCosmetics (Liquid Make-Up)
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414
Microwave Digestion ofEye Shadow
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 7 mL of HNO₃ and 3 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
247
Microwave Digestion ofEye Shadow
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415
Microwave Digestion ofShampoo (Dandruff)
ConsumeMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 mL
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample.
ProcedureTransfer 1 mL of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
248
Microwave Digestion ofShampoo (Dandruff)
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Pharmaceutical & Biotech
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417
Microwave Digestion ofAllergy Pill (Ground)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain therequired results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at orbelow room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vesselsdetected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
402
Microwave Digestion ofAllergy Pill (Ground)
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418
Microwave Digestion ofAllergy Pill (Whole Pill)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Pill (Approx 1.0 g)
ReagentsHNO₃H₂O₂ (30%)
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 pill (Approx 1.0 g) into the digestion vessel. Add 10 mL of HNO₃ and 2 mL of H₂O₂ (30%). Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
403
Microwave Digestion ofAllergy Pill (Whole Pill)
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419
Microwave Digestion ofAntioxidant (Ground)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
404
Microwave Digestion ofAntioxidant (Ground)
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420
Microwave Digestion ofAntioxidant (Whole Pill)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Pill (Approx 1.4 g)
ReagentsHNO₃H₂O₂ (30%)
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 pill (approx 1.4 g) into the digestion vessel. Add 10 mL of HNO₃ and 2 mL of H₂O₂ (30%). Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
405
Microwave Digestion ofAntioxidant (Whole Pill)
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421
Microwave Digestion ofAPIs with Aromatic Ring Structures
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 30:00 25:00 N/A 700-1800 N/A
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL. If the sample contains precious metals the diluted sample may be the color associated with the metals.
406
Microwave Digestion ofAPIs with Aromatic Ring Structures in iPrep
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422
Microwave Digestion ofAscorbic Acid
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
407
Microwave Digestion ofAscorbic Acid
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423
Microwave Digestion ofAspirin (Ground)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
408
Microwave Digestion ofAspirin (Ground)
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424
Microwave Digestion ofAspirin (Whole)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight 1 pill (Approx 1.0 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 pill (Approx 1.0 g) into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
409
Microwave Digestion ofAspirin (Whole)
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425
Microwave Digestion ofBeta Carotene
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
410
Microwave Digestion ofBeta Carotene
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426
Microwave Digestion ofBiotin
NutraceutiMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
394
Microwave Digestion ofBiotin
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427
Microwave Digestion ofCalcium Carbonate
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis. Allow initial reaction to subside before sealing vessel.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Slowly add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
411
Microwave Digestion ofCalcium Carbonate
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428
Microwave Digestion ofCalpan Pantothenic Acid
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight 0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
412
Microwave Digestion ofCalpan Pantothenic Acid
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429
Microwave Digestion ofCephalexin
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
413
Microwave Digestion ofCephalexin
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430
Microwave Digestion ofChromium Chelate
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
Resultsample was clear, colorless, and particle free upon dilution to 50 mL.
414
Microwave Digestion ofChromium Chelate
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431
Microwave Digestion ofCold and Flu Medicine (Liquid)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.75 mL
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 0.75 mL of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
415
Microwave Digestion ofCold & Flu Medicine (Liquid)
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432
Microwave Digestion ofCupric Sulfate
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, blue in color, and particle free upon dilution to 50 mL.
416
Microwave Digestion ofCupric Sulfate
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433
Microwave Digestion ofDiclofenac K
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃H₂O₂ (30%)
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃ and 2 mL of H₂O₂ (30%). Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
417
Microwave Digestion ofDiclofenac K
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434
Microwave Digestion ofEmpty Capsule (Gel)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Capsule (Approx 0.1 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 capsule (Approx 0.1 g) into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
418
Microwave Digestion ofEmpty Capsule (Gel)
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435
Microwave Digestion ofErythromycin
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
586
Microwave Digestion ofErythromycin
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436
Microwave Digestion ofFish Oil (No Capsule)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
419
Microwave Digestion ofFish Oil (No Capsule)
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437
Microwave Digestion ofFlurbiprofen
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
587
Microwave Digestion ofFlurbiprofen
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438
Microwave Digestion ofFolic Acid
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
420
Microwave Digestion ofFolic Acid
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439
Microwave Digestion ofGinkgo (Ground)
NutraceutiMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
395
Microwave Digestion ofGinkgo (Ground)
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440
Microwave Digestion ofGinkgo (Whole Pill)
NutraceutiMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Pill (Approx 1.0 g)
ReagentsHNO₃H₂O₂
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 pill (approx 1.0 g) into the digestion vessel. Add 10 mL of HNO₃ and 2 mL of H₂O₂. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
396
Microwave Digestion ofGinkgo (Whole Pill)
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441
Microwave Digestion ofHydrocodone
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 25:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
588
Microwave Digestion ofHydrocodone
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442
Microwave Digestion ofIbuprofen (Ground)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 8 mL HNO₃ and 2 mL HF. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 20:00 15:00 800 1030-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
730
Microwave Digestion ofIbuprofen (Ground)
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443
Microwave Digestion ofKelp
NutraceutiMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight 0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
421
Microwave Digestion ofKelp
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444
Microwave Digestion ofLosartan K
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃H₂O₂ (30%)
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃ and 2 mL of H₂O₂ (30%). Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
422
Microwave Digestion ofLosartan K
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445
Microwave Digestion ofMagnesium Carbonate
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesAllow any reaction to subside before sealing the vessel. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
423
Microwave Digestion ofMagnesium Carbonate
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446
Microwave Digestion ofMagnesium Oxide
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
424
Microwave Digestion ofMagnesium Oxide
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447
Microwave Digestion ofManganese Carbonate
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
426
Microwave Digestion ofManganese Carbonate
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448
Microwave Digestion ofMedroxyprogesterone
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
589
Microwave Digestion ofMedroxyprogesterone
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449
Microwave Digestion ofMetformin (Ground)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
427
Microwave Digestion ofMetformin (Ground)
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450
Microwave Digestion ofMineral Oil
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
459
Microwave Digestion ofMineral Oil
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451
Microwave Digestion ofMultivitamin (Ground)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
428
Microwave Digestion ofMultivitamin (Ground)
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452
Microwave Digestion ofMultivitamin (Whole)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Pill (Approx 2.5 g)
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 pill (Approx 2.5 g) into the digestion vessel. Add 10 mL of HNO₃ and 2 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
429
Microwave Digestion ofMultivitamin (Whole)
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453
Microwave Digestion ofNaproxen Sodium
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃ and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 25:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
590
Microwave Digestion ofNaproxen Sodium
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454
Microwave Digestion ofNiacinamide
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight 0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
430
Microwave Digestion ofNiacinamide
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455
Microwave Digestion ofPantothenic Acid
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
431
Microwave Digestion ofPantothenic Acid
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456
Microwave Digestion ofPotassium Chelate
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
432
Microwave Digestion ofPotassium Chelate
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457
Microwave Digestion ofProtopic Ointment
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 25:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
591
Microwave Digestion ofProtopic Ointment
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458
Microwave Digestion ofPyridoxine
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight 0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended Equipment
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
434
Microwave Digestion ofPyridoxine
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459
Microwave Digestion ofRiboflavin
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 20:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
435
Microwave Digestion ofRiboflavin
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460
Microwave Digestion ofSelenium Chelate
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
436
Microwave Digestion ofSelenium Chelate
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461
Microwave Digestion ofSleep Aid
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃ and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 25:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
592
Microwave Digestion ofSleep Aid
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462
Microwave Digestion ofSodium Polystyrene Sulfonate
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsDI H₂OHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 6 mL of HNO₃ and 2 mL of deionized H₂O. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 25:00 25:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless upon dilution to 50 mL.
703
Microwave Digestion ofSodium Polystyrene Sulfonate in iPrep
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463
Microwave Digestion ofStearic Acid
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
437
Microwave Digestion ofStearic Acid
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464
Microwave Digestion ofSudan Orange (4-Fluorophenyl)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 25:00 25:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
706
Microwave Digestion ofSudan Orange (4-Fluorophenyl) in iPrep
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465
Microwave Digestion ofThiamine
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight 0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
438
Microwave Digestion ofThiamine
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466
Microwave Digestion ofTransdermal Patch
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HClNH₄F
Recommended VesselsEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses ammonium fluoride, which creates in-situ hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 9 mL of HNO₃, 1 mL of HCl, and 0.1 g of NH₄F. Gently swirtl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsCompleted samples were clear, colorless and particle free upon dilution to 50 mL.
593
Microwave Digestion ofTransdermal Patch
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467
Microwave Digestion ofTrixie Phosphate
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight50 mg
ReagentsHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 50 mg of the sample into the digestion vessel. Add 6 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 30:00 25:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
710
Microwave Digestion ofTrixie Phosphate in iPrep
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468
Microwave Digestion ofUSP 232/233 (Pharmaceuticals)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL HCl. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
265
Microwave Digestion ofUSP 232/233 (Pharmaceuticals)
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469
Microwave Digestion ofVitamin B-12
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
439
Microwave Digestion ofVitamin B-12
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470
Microwave Digestion ofVitamin C (Ground)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
440
Microwave Digestion ofVitamin C (Ground)
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471
Microwave Digestion ofVitamin C (Whole)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Pill (Approx 1.4 g)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 1 pill (Approx 1.4 g) into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
441
Microwave Digestion ofVitamin C (Whole)
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472
Microwave Digestion ofVitamin Concentrate (High Fe)
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO3HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 5 mL of HNO3 and 5 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 180 15:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
519
Microwave Digestion ofVitamin Concentrate (High Fe)
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473
Microwave Digestion ofVitamin D
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 20:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
442
Microwave Digestion ofVitamin D
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474
Microwave Digestion ofVitamin D3
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
443
Microwave Digestion ofVitamin D3
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475
Microwave Digestion ofVitamin E
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃ HCl
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 9 mL of HNO₃, and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 20:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
444
Microwave Digestion ofVitamin E
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476
Microwave Digestion ofVitamins
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HFHCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled “Boric Acid HF Neutralization”. The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g (0.25 g w/Xpress Vessels) of the sample into the digestion vessel. Add 9 mL of HNO₃, 1 mL HCl, and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
445
Microwave Digestion ofVitamins
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477
Microwave Digestion ofZinc Sulfate
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
446
Microwave Digestion ofZinc Sulfate
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Plastics, Polymers, & Oils
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479
Microwave Digestion ofAcrylamide
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
447
Microwave Digestion ofAcrylamide
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480
Microwave Digestion ofBrominated Flame Retardant
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeStandard
Heating Program
Max Sample Weight50 mg
ReagentsH₂SO₄HNO₃H₂O₂
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
Stirring is required for complete dissolution of this sample type.
ProcedureWeigh 50 mg of the sample into the digestion vessel. Insert stir bar into the vessel. Add 4.5 mL H₂SO₄ and 4.0 mL HNO₃ to the vessel, then add 1.5 mL H₂O₂ dropwise. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 270 30:00 45:00 N/A 900-1800 Med
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless, and particle free upon dilution to 50 mL.
675
Microwave Digestion ofBrominated Flame Retardant in iPrep
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481
Microwave Digestion ofBunker Oil
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.3 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. The pre-digestion step will allow the lighter fuel fractions to react before sealing the vessels.
ProcedureWeigh 0.3 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
451
Microwave Digestion ofBunker Oil in iPrep
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482
Microwave Digestion ofChar - Sulfuric Acid
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample WeightVaries by sample
ReagentsH₂SO₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesEasyPrep Plus requires a high temperature probe for this method. This method is for the pretreatment of large sample sizes or difficult organic samples that are resistant to oxidation. After the char is complete, the vessel is opened and a normal oxidation with HNO₃ can be run, usually at around 200C.
ProcedureAdd 6 mL H₂SO₄ into the vessel that contains the sample and acid.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 260 15:00 30:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSee sample specific method notes.
352
Microwave Digestion ofChar - Sulfuric Acid
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483
Microwave Digestion ofCrude Oil
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
452
Microwave Digestion ofCrude Oil
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484
Microwave Digestion ofDiesel Fuel
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe pre-digestion step will allow the lighter fuel fractions to react before sealing the vessels
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃ . Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
357
Microwave Digestion ofDiesel Fuel
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485
Microwave Digestion ofEpoxy Hardener
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
453
Microwave Digestion ofEpoxy Hardener
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486
Microwave Digestion ofFatty Alcohol
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃HCl
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.1 g of the sample into the digestion vessel. Add 2 mL of HNO₃ and 4 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
454
Microwave Digestion ofFatty Alcohol
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487
Microwave Digestion ofFluorinated Ethylene Propylene (FEP)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight120 mg
ReagentsH₂SO₄HNO₃H₂O₂
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 120 mg of the sample into the digestion vessel. Add 4.5 mL of H₂SO₄, 4 mL of HNO₃, and 1.5 mL of H₂O₂ slowly. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 280 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless upon dilution to 50 mL.
717
Microwave Digestion ofFluorinated Ethylene Propylene (FEP) in iPrep
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488
Microwave Digestion ofFuel Oil (Slurry)
Plastics, MARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃ HF
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
This procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid or other neutralization step should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 9 mL of HNO₃ and 1 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 30:00 30:00 N/A 700-1800 Off
Microwave Digestion ofFuel Oil (Slurry) in iPrep (Step 1 of 2)
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489
Microwave Digestion ofFuel Oil (Slurry)
Plastics, MARS 6 (
ProcedureAllow vessels to cool. Open and add 2 mL H₂O₂ (30%) dropwise. Wait approximately 15 minutes before closing the vessel.
ReagentsH₂O₂ (30%)
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear and colorless upon dilution to 50 mL.
650
Microwave Digestion ofFuel Oil (Slurry) in iPrep (Step 2 of 2)
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490
Microwave Digestion ofGasoline
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.1 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe pre-digestion step will allow the lighter fuel fractions to react before sealing the vessels.
ProcedureAdd 0.1 g of the sample into the digestion vessel. Slowly add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
455
Microwave Digestion ofGasoline
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491
Microwave Digestion ofGlycerol Ester of Wood Rosin (Ground)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.5 g (ground) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to predigest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL with deionized water.
684
Microwave Digestion ofGlycerol Ester of Wood Rosin (Ground) in iPrep
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492
Microwave Digestion ofHDPE
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
456
Microwave Digestion ofHDPE
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493
Microwave Digestion ofKerosene
GeoscienMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe pre-digestion step will allow the lighter fuel fractions to react before sealing the vessels.
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
359
Microwave Digestion ofKerosene
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494
Microwave Digestion ofKevlar
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. Ensure that all fibers are completely covered with acid and not adhered to the vessel liner wall.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
457
Microwave Digestion ofKevlar in iPrep
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495
Microwave Digestion ofLube Oil
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
458
Microwave Digestion ofLube Oil
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496
Microwave Digestion ofMethyl Ester of Hydrogenated Wood Rosin (Ground)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃ . Gently swirl the mixture and wait approximately 15 minutes to predigest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL with deionized water.
689
Microwave Digestion ofMethyl Ester of Hydrogenated Wood Rosin (Ground) in iPrep
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497
Microwave Digestion ofMineral Oil
PharmaceMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
459
Microwave Digestion ofMineral Oil
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498
Microwave Digestion ofMotor Oil (New)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
460
Microwave Digestion ofMotor Oil (New)
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499
Microwave Digestion ofMotor Oil (Waste)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe pre-digestion step will allow the lighter fuel fractions to react before sealing the vessels.
ProcedureWeigh 0.25 g (0.1 g w/Xpress Vessels) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
360
Microwave Digestion ofMotor Oil (Waste)
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500
Microwave Digestion ofMotor Oil (Waste)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel. The pre-digestion step will allow the lighter fuel fractions to react before sealing the vessels.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 240 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
461
Microwave Digestion ofMotor Oil (Waste) in iPrep
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501
Microwave Digestion ofNylon
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
462
Microwave Digestion ofNylon
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502
Microwave Digestion ofOil Wear Metals
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
598
Microwave Digestion ofOil Wear Metals
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503
Microwave Digestion ofPET (Polyethylene Terephthalate)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃H₂SO₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 8 mL of HNO₃ and 2 mL of H₂SO₄. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
463
Microwave Digestion ofPET (Polyethylene Terephthalate)
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504
Microwave Digestion ofPET (Polyethylene Terephthalate)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.4 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.4 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 250 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
464
Microwave Digestion ofPET (Polyethylene Terephthalate) in iPrep
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505
Microwave Digestion ofPetrolatum
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
594
Microwave Digestion ofPetrolatum
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506
Microwave Digestion ofPlasticizer (Filter)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 6 mL HNO₃, and 3 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
691
Microwave Digestion ofPlasticizer (Filter) in iPrep
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507
Microwave Digestion ofPlasticizers
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution.The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 6 mL HNO₃ and 3 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
692
Microwave Digestion ofPlasticizers in iPrep
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508
Microwave Digestion ofPolycarbonate Resin
Plastics, MARS 6 (
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1.0 g
ReagentsH₂SO₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesEasy Prep Plus requires a high temperature probe for this method.
ProcedureChar Step Weigh 1.0 g of the sample into the digestion vessel. Add 6 mL of H₂SO₄. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 260 15:00 15:00 800 900-1800 Off
Microwave Digestion ofPolycarbonate Resin (Step 1 of 2)
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509
Microwave Digestion ofPolycarbonate Resin
Plastics, MARS 6 (
ProcedureProceeding step one, add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
ReagentsHNO₃
Notes
Heating Program
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as one touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL
604
Microwave Digestion ofPolycarbonate Resin (Step 2 of 2)
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510
Microwave Digestion ofPolyethersulfone (Filter Paper)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight1 Filter (Approx 0.1 g)
ReagentsHNO₃H₂SO₄
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 1 filter paper (Approx 0.1 g) into the digestion vessel. Add 8 mL of HNO₃ and 2 mL H₂SO₄. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
465
Microwave Digestion ofPolyethersulfone (Filter Paper)
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511
Microwave Digestion ofPolyethylene - High Density
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g (0.1 g w/Xpress Vessels) of the sample into the digestion vessel. Add 10 ml of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
466
Microwave Digestion ofPolyethylene - High Density
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512
Microwave Digestion ofPolyphenylene Sulfide
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
596
Microwave Digestion ofPolyphenylene Sulfide
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513
Microwave Digestion ofPolypropylene
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g (0.1 g w/Xpress)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 (0.1 g w/Xpress vessels) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
467
Microwave Digestion ofPolypropylene
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514
Microwave Digestion ofPolyterpene Resin
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in an iPrep.
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes to predigest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 30:00 30:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL with deionized water.
695
Microwave Digestion ofPolyterpene Resin in iPrep
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515
Microwave Digestion ofPolyurethane
Paints anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
468
Microwave Digestion ofPolyurethane
![Page 516: Microwave Acid Digestion Method Note Compendium€¦ · Compendium October 1, 2019. Contents Agriculture Alfalfa 11 Boric Acid HF Neutralization 12 Cannabis (Plant) 13 Coffee Beans](https://reader031.fdocuments.in/reader031/viewer/2022013010/5f074f137e708231d41c586b/html5/thumbnails/516.jpg)
516
Microwave Digestion ofPolyurethane
Paints anMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 6 mL HNO₃, and 3 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes to pre-digest before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless and particle free upon dilution to 50 mL.
696
Microwave Digestion ofPolyurethane in iPrep
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517
Microwave Digestion ofPVC (Polyvinyl Chloride Resin)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight 0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g (0.1 g w/Xpress Vessels) of sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
469
Microwave Digestion ofPVC (Polyvinyl Chloride Resin)
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518
Microwave Digestion ofRubber
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO3. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 220 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
471
Microwave Digestion ofRubber
![Page 519: Microwave Acid Digestion Method Note Compendium€¦ · Compendium October 1, 2019. Contents Agriculture Alfalfa 11 Boric Acid HF Neutralization 12 Cannabis (Plant) 13 Coffee Beans](https://reader031.fdocuments.in/reader031/viewer/2022013010/5f074f137e708231d41c586b/html5/thumbnails/519.jpg)
519
Microwave Digestion ofRubber (Synthetic)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 210 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
470
Microwave Digestion ofRubber (Synthetic)
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520
Microwave Digestion ofSilane Terminated Polyether
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HCl
Recommended VesselsiPrep
Recommended EquipmentMARS 6 iWave
NotesThis application can only be run in the iPrep vessel.
The addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes.
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 6 mL HNO₃ and 3 mL of HCl. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 30:00 20:00 N/A 700-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.d) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
699
Microwave Digestion ofSilane Terminated Polyether in iPrep
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521
Microwave Digestion ofSilicone Tubing - TiO₂ Filler
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃HF
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThis procedure uses hydrofluoric acid. If it is necessary to complex the residual hydrofluoric acid or redissolve insoluble fluorides formed, an additional complexation step with boric acid should be used. This procedure can be found in the One Touch Method note entitled "Boric Acid HF Neutralization".
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 2 mL HNO₃ and 5 mL of HF. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel. Add HF slowly, and allow vessels to stand in the fume hood until the initial reaction subsides.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
557
Microwave Digestion ofSilicone Tubing - TiO2 Filler
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522
Microwave Digestion ofStyrene Acrylate
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
597
Microwave Digestion ofStyrene Acrylate
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523
Microwave Digestion ofTerephthalic Acid
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.2 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.2 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 230 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
472
Microwave Digestion ofTerephthalic Acid
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524
Microwave Digestion ofWax (Petroleum Based)
Plastics, MARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.25 g
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.25 g of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
595
Microwave Digestion ofWax (Petroleum Based)
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Water & Wastewater Treatment
![Page 526: Microwave Acid Digestion Method Note Compendium€¦ · Compendium October 1, 2019. Contents Agriculture Alfalfa 11 Boric Acid HF Neutralization 12 Cannabis (Plant) 13 Coffee Beans](https://reader031.fdocuments.in/reader031/viewer/2022013010/5f074f137e708231d41c586b/html5/thumbnails/526.jpg)
526
Microwave Digestion ofNPDES (Waste Water)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeWater
Heating Program
Max Sample Weight50 mL
ReagentsHNO₃ HCl
Recommended Vessels75 mL MARSXpressEasyPrepEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 50 mL of the sample into the digestion vessel. Add 3 mL of HNO₃, and 2 mL HCl. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 165 30:00 0:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
252
Microwave Digestion ofNPDES (Waste Water)
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527
Microwave Digestion ofSludge (Industrial)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe use of HF may be required to digest any silicates found in the sample. The addition of Conc. HCl (0-4 ml) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureWeigh 0.5 g (dry weight) of the sample into the digestion vessel. Add 10 mL of HNO₃. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
257
Microwave Digestion ofSludge (Industrial)
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528
Microwave Digestion ofTCLP Extract
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeStandard Control
Sample TypeWater
Heating Program
Max Sample Weight25 mL
ReagentsHNO₃
Recommended VesselsEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 25 mL of the sample into the digestion vessel. Add 5 mL of HNO₃. Gently swirl the mixture before closing the vessel. If a high organic content is suspected, a 10 ml sample volume is recommended.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
259
Microwave Digestion ofTCLP Extract
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529
Microwave Digestion ofUS EPA 3015 (Aqueous Samples)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeStandard Control
Sample TypeWater
Heating Program
Max Sample Weight45 mL
ReagentsHNO₃
Recommended Vessels75 mL MARSXpressEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureTransfer 45 mL of the sample into the digestion vessel. Add 5 mL of HNO₃. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsThis method is intended to be an acid leach, not a total digest. Hydrofluoric acid will be required to provide complete digestion of the sample matrix.
260
Microwave Digestion ofUS EPA 3015 (Aqueous Samples)
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530
Microwave Digestion ofUS EPA 3015a (Aqueous Sample)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeStandard Control
Sample TypeWater
Heating Program
Max Sample Weight45 mL
ReagentsHNO₃HCl (Optional)
Recommended Vessels75 mL MARSXpressEasyPrep PlusMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
NotesThe addition of Conc. HCl (0-4 mL) is appropriate for the stabilization of Ag, Ba and Sb, and high concentrations of Fe and Al in solution. The amount of HCl will vary depending on the matrix and the concentration of the analytes. The addition of HCl may, however, limit the techniques or increase the difficulties of analysis.
ProcedureTransfer 45 mL of the sample into the digestion vessel. Add 5 mL of HNO3, or alternatively 4 mL of HNO₃ and 1 mL HCl. Gently swirl the mixture before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 10:00 10:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsThis method is intended to be an acid leach, not a total digest. Hydrofluoric acid will be required to provide complete digestion of the sample matrix.
261
Microwave Digestion ofUS EPA 3015a (Aqueous Sample)
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531
Microwave Digestion ofWaste Activated Sludge
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeOne Touch
Control TypeRamp to Temperature
Sample TypeOrganic
Heating Program
Max Sample Weight0.5 g (Dry Weight)
ReagentsHNO₃H₂O₂
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6MARS 6 iWave
Notes
ProcedureWeigh 0.5 g (dry weight) (0.25 g w/Xpress Vessels) of the sample into the digestion vessel. Add 5 mL of HNO₃, and 5 mL of H₂O₂. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 200 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
266
Microwave Digestion ofWaste Activated Sludge
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532
Microwave Digestion ofWater (For Analysis of Phosphorous)
EnvironmMARS 6
* Ramp times and power may vary depending on the type and number of vessels.
Method TypeClassic
Control TypeRamp to Temperature
Sample TypeWater
Heating Program
Max Sample Weight50 mL
ReagentsK₂S₂O₈ H₂SO₄
Recommended VesselsEasyPrepEasyPrep PlusMARSXpressMARSXpress Plus
Recommended EquipmentMARS 6
Notes
ProcedureTransfer 50 mL of H₂O into the digestion vessel. Add 0.5 g of K₂S₂O₈ and 1 mL of H₂SO₄. Gently swirl the mixture and wait approximately 15 minutes before closing the vessel.
Stage Temp (°C) *Ramp (mm:ss) Hold (mm:ss) Pressure (psi) * Power (W) Stirring
1 170 15:00 15:00 800 900-1800 Off
General Precautiona) This procedure is a reference point for sample digestion using a CEM system and may need to be modified or changed to obtain the required results on your sample.b) If using a vessel other than the recommended choice, adjust sample size and pressure limit to values appropriate for the vessel chosen.c) The control / reference vessel must contain the largest and most reactive sample.d) Manual venting of CEM vessels should be performed when wearing hand/eye/body protection and when the vessel contents are at or below room temperature to avoid the potential for chemical burns. Always point the vent hole away from the operator.e) If programming as One Touch, the ramp time and power will be automatically determined based on the number and type of vessels detected.
ResultsSample was clear, colorless, and particle free upon dilution to 50 mL.
267
Microwave Digestion ofWater (For Analysis of Phosphorous)