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![Page 1: Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts by Nataliya V. Maksimchuk, Olga V. Zalomaeva, Igor Y. Skobelev, Konstantin.](https://reader036.fdocuments.in/reader036/viewer/2022062517/56649e795503460f94b78d65/html5/thumbnails/1.jpg)
Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts
by Nataliya V. Maksimchuk, Olga V. Zalomaeva, Igor Y. Skobelev, Konstantin A. Kovalenko, Vladimir P. Fedin, and Oxana A. Kholdeeva
Proceedings AVolume 468(2143):2017-2034
July 8, 2012
©2012 by The Royal Society
![Page 2: Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts by Nataliya V. Maksimchuk, Olga V. Zalomaeva, Igor Y. Skobelev, Konstantin.](https://reader036.fdocuments.in/reader036/viewer/2022062517/56649e795503460f94b78d65/html5/thumbnails/2.jpg)
Schematic of MIL-101 structure.
Nataliya V. Maksimchuk et al. Proc. R. Soc. A 2012;468:2017-2034
©2012 by The Royal Society
![Page 3: Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts by Nataliya V. Maksimchuk, Olga V. Zalomaeva, Igor Y. Skobelev, Konstantin.](https://reader036.fdocuments.in/reader036/viewer/2022062517/56649e795503460f94b78d65/html5/thumbnails/3.jpg)
Formation of coordinatively unsaturated chromium sites in the Cr3O-carboxylate cluster of the MIL-101 structure.
Nataliya V. Maksimchuk et al. Proc. R. Soc. A 2012;468:2017-2034
©2012 by The Royal Society
![Page 4: Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts by Nataliya V. Maksimchuk, Olga V. Zalomaeva, Igor Y. Skobelev, Konstantin.](https://reader036.fdocuments.in/reader036/viewer/2022062517/56649e795503460f94b78d65/html5/thumbnails/4.jpg)
Effect of Cr-MIL-101 activation on its catalytic properties in cyclohexene oxidation with TBHP. Reaction conditions: 0.1 M cyclohexene, 0.17 M TBHP, 2.5 mg Cr-MIL-101, 1 ml benzene, 50°C, 10
h.
Nataliya V. Maksimchuk et al. Proc. R. Soc. A 2012;468:2017-2034
©2012 by The Royal Society
![Page 5: Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts by Nataliya V. Maksimchuk, Olga V. Zalomaeva, Igor Y. Skobelev, Konstantin.](https://reader036.fdocuments.in/reader036/viewer/2022062517/56649e795503460f94b78d65/html5/thumbnails/5.jpg)
(a) Hot catalyst filtration test and (b) catalyst reuse for Cr-MIL-101-catalysed oxidation of cyclohexene with TBHP. Reaction conditions as in figure 3.
Nataliya V. Maksimchuk et al. Proc. R. Soc. A 2012;468:2017-2034
©2012 by The Royal Society
![Page 6: Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts by Nataliya V. Maksimchuk, Olga V. Zalomaeva, Igor Y. Skobelev, Konstantin.](https://reader036.fdocuments.in/reader036/viewer/2022062517/56649e795503460f94b78d65/html5/thumbnails/6.jpg)
XRD patterns for Cr-MIL-101: (a) initial, (b) after treatment with 0.5 M TBHP in MeCN at 80°C for 10 h, and (c) after cyclohexene oxidation with TBHP.
Nataliya V. Maksimchuk et al. Proc. R. Soc. A 2012;468:2017-2034
©2012 by The Royal Society
![Page 7: Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts by Nataliya V. Maksimchuk, Olga V. Zalomaeva, Igor Y. Skobelev, Konstantin.](https://reader036.fdocuments.in/reader036/viewer/2022062517/56649e795503460f94b78d65/html5/thumbnails/7.jpg)
FT-IR spectra of Fe-MIL-101: (a) initial, (b) after four runs of solvent-free cyclohexene oxidation with O2 and (c) after five runs of solvent-free cyclohexane oxidation with TBHP.
Nataliya V. Maksimchuk et al. Proc. R. Soc. A 2012;468:2017-2034
©2012 by The Royal Society
![Page 8: Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts by Nataliya V. Maksimchuk, Olga V. Zalomaeva, Igor Y. Skobelev, Konstantin.](https://reader036.fdocuments.in/reader036/viewer/2022062517/56649e795503460f94b78d65/html5/thumbnails/8.jpg)
Effect of cyclohexane/TBHP molar ratio on the selectivity of cyclohexane oxidation and TBHP efficiency in the presence Cr-MIL-101 (70°C, 8 h).
Nataliya V. Maksimchuk et al. Proc. R. Soc. A 2012;468:2017-2034
©2012 by The Royal Society
![Page 9: Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts by Nataliya V. Maksimchuk, Olga V. Zalomaeva, Igor Y. Skobelev, Konstantin.](https://reader036.fdocuments.in/reader036/viewer/2022062517/56649e795503460f94b78d65/html5/thumbnails/9.jpg)
Hot catalyst filtration test for the coupling reaction of styrene oxide and CO2 over Fe-MIL-101.
Nataliya V. Maksimchuk et al. Proc. R. Soc. A 2012;468:2017-2034
©2012 by The Royal Society