ICBC – INTERNATIONAL CITRUS & BEVERAGE CONFERENCE

September, 2015

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Mércia F. M. Bettini - Ph.D.

Flavor Tec – Aromas de Frutas Ltda

Brazil

•

A – Citrus Production/ commercial

data in the last 10 years

Concentrated juice (FCOJ)

Essential peel oil (CPOO), essence oil or

oil phase (OP)

Water Phase (WP), D-Limonene (DL)

and citrus pellets (CPP).

2

GLC profiles for citrus oils obtained by

Vaccum Fractionated Distillation

Tables and Flow Charts

B – Technical Data

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Source: CitrusBr 4

CROP

Total Production

of FCOJ 66º Brix

(mtons x 1000)

Industrial yields

included pulp

wash (Boxes/ ton

FCOJ)

Processed

Fruit

(mtons

x 1000)

Boxes of fruit

x 1000

2005/2006 1.161 226,42 10.725.244 262.873

2006/2007 1.357 232,69 12.883.021 315.760

2007/2008 1.377 228,49 12.836.934 314.630

2008/2009 1.141 252,88 11.772.272 288.536

2009/2010 1.009 262,52 10.807.213 264.882

2010/2011 1.044 240,58 10.247.553 251.165

2011/2012 1.500 265,36 16.240.032 398.040

2012/2013 1.445 263,54 15.537.264 380.851

2013/2014 851 282,00 9.792.000 239.982

2014/2015 1.128 240,50 10.073.120 271.284

2015/2016 889 280,15 10.158.792 249.053

AVG 252,28

MAX 1.500 282,00

MIN 851 226,42

Table 1 - FCOJ - Industrial Yields and Production Quantities

1 box = 40.8 Kg

5 Source: CitrusBr

Source: CitrusBr/ MBAgro (related to crops 2005/2006 up to 2012/2013)

( * ) Estimated data - real data not available 6

CROP

Cold Pressed

orange Oil

(CPOO)

D-Limonene

(D-L)

Oil Phase

(OP)

Water

Phase (WP)

Citrus Pellets

(CPP)

2005/2006 29.972,00 19.870,00 2.083,00 6.253,10 1.238.320,30

2006/2007 35.536,60 23.051,30 2.839,00 8.580,50 1.375.028,10

2007/2008 33.528,20 24.263,10 2.442,00 9.916,50 1.387.279,30

2008/2009 31.900,40 22.962,70 2.057,60 5.872,10 1.221.663,50

2009/2010 26.227,20 18.303,30 1.559,90 4.721,80 1.045.352,30

2010/2011 24.104,80 16.400,30 1.841,60 6.959,50 1.037.981,30

2011/2012 40.863,70 27.890,20 2.979,50 10.179,30 1.604.877,20

2012/2013 27.041,50 18.628,80 1.613,40 6.545,58 1.137.502,40

*2013/2014 21.744,00 19.992,00 1.248,00 5.328,00 1.524.000,00

*2014/2015 23.549,90 24.200,30 1.626,00 9.519,50 1.138.200,00

*2015/2016 22.310,40 19.646,10 1.095,60 7.619,40 1.120.500,00

MAX 40.863,70 27.890,20 2.979,50 10.179,30 1.604.877,20

MIN 21.744,00 16.400,30 1.095,60 4.721,80 1.037.981,30

Table 2 - By Products - Production Quantities

Orange By Products (mtons)

Source: CitrusBr/ MBAgro (related to crops

2005/2006 up to 2012/2013)

( * ) Estimated data - real data not available

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CROP

Total production

of CPOO

(mtons )

Industrial Yields

(g/box)

2005/2006 29,972.0 114.05

2006/2007 35,536.6 112.51

2007/2008 33,528.2 106.54

2008/2009 31,900.4 110.60

2009/2010 26,227.2 99.02

2010/2011 24,104.8 96.01

2011/2012 40,863.7 102.65

2012/2013 27,041.5 89.65

*2013/2014 21,744.0 90.60

*2014/2015 23,549.9 86.90

*2015/2016 22,310.4 89.60

Table 2.1 - CPOO

Production Quantities X Industrial yields

CROP

Total production

of O.P.

(mtons)

Industrial Yields

(g/box)

2005/2006 2,083.0 7.93

2006/2007 2,839.0 8.99

2007/2008 2,442.0 7.76

2008/2009 2,057.6 7.13

2009/2010 1,559.9 5.89

2010/2011 1,841.6 7.34

2011/2012 2,979.5 7.48

2012/2013 1,613.4 5.35

*2013/2014 1,248.0 5.20

*2014/2015 1,626.0 6.00

*2015/2016 1,095.6 4.40

Table 2.2 - Oil Phase (OP)

Production Quantities X Industrial yields

CROP

Total

production

of D L.

(mtons)

Industrial

Yields

(g/box)

2005/2006 19,870.0 75.61

2006/2007 23,051.3 72.98

2007/2008 24,263.1 77.10

2008/2009 22,962.7 79.61

2009/2010 18,303.3 69.10

2010/2011 16,400.3 65.32

2011/2012 27,890.2 70.06

2012/2013 18,628.8 61.76

*2013/2014 19,992.0 83.30

*2014/2015 24,200.3 89.30

*2015/2016 19,646.1 78.90

Table 2.3 - D-Limonene (D-L)

Production Quantities X Industrial yields

Source: CitrusBr/ MBAgro (related to crops 2005/2006 up to 2012/2013)

( * ) Estimated data - real data not available 8

Source: CitrusBr/ MBAgro (related to crops 2005/2006 up to 2012/2013)

( * ) Estimated data - real data not available 9

Source: CitrusBr/ MBAgro (related to crops 2005/2006 up to 2012/2013)

( * ) Estimated data - real data not available 10

Source: CitrusBr/ MBAgro (related to crops 2005/2006 up to 2012/2013)

( * ) Estimated data - real data not available

11

12

25.46 % 25.15%

5.89% 7.74 %

3.46 % 2.15 %

3.64 %

US

A

NE

TH

ER

LA

ND

S

UK

GE

RM

AN

Y

IND

IA

SP

AIN

CH

INA

Fig 5 - Exportation data of CPOO in 2014 (Jan to Dec)

Source: http://aliceweb.mdic.gov.br/

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14 Source: http://aliceweb.mdic.gov.br/

15 Source: http://aliceweb.mdic.gov.br/

16 Source: http://aliceweb.mdic.gov.br/

17

0

1

2

3

4

5

6

7

8

92005

2006

2007

2008

2009

2010

2011

2012

2013

2014

2015

US

$/K

g

Fig 9 - Market Price of Orange Oil

Citrus Oils Processing at Flavor Tec

by Vacuum Fractional Distillation

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Flavor Tec – Line Products

1 – Citrus Distillation Area:

• Citrus Aromas (FTNF)

• Folded Citrus Oils (5F, 10F, 20F)

• Folded Orange Essence Oils (5F, 10F)

• Citrus Terpenes

•Special Flavour Fractions

• Special formulations as required by the customers

2 – Juices Area:

• Fruttini - Natural Sweetened Concentrated Juices

19

Fractional Distillation Industrial

Plant at Flavor Tec

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Fig. 10 - Original Orange Oil Phase

Fig. 11 - 10 Folded Orange Oil Phase, concentrated by

vacuum distillation

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CHROMATOGRAPHIC PROFILES

Fig 12 - Special light fraction of orange

oil phase by V.D.

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TABLE 6- Orange Oil Phase (O.P.) -

GLC data (mg/l)

23

24

0

2

4

6

8

10

12

to

tal ald

eh

yd

es

(%)

Total yield = 7.20%

FIG 13 – LEMON / LIME OILS - TOTAL ALDEHYDES (%) X SPECIAL FRACTIONS

Lemon Lime

25

0

1

2

3

4

5

6

7

8

9

To

tal ald

eh

yd

es (

%)

Total yield = 4 - 5 %

FIG 14 – MANDARINE / CRAVO OILS - TOTAL ALDEHYDES (%) X SPECIAL FRACTIONS

Mandarine Cravo

26

0

5

10

15

20

25

30

35

40

45

Cit

ral

(are

a %

)

FIG 15 – LEMON / LIME - CITRAL (AREA %) BY GLC

Lemon Lime

27

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YieldArea % GLC

(Citral)

Total

Aldehydes

%

YieldArea % GLC

(Citral)Total

Aldehydes %

Essential oil - 4.23 2.5 - 2.51 3.6

Fraction 1 1.44 8.72 7 1.44 37.37 7

Fraction 2 1.44 17.8 7.5 1.44 36.91 7.1

Fraction 3 1.44 42.76 7.89 1.44 28.85 7.5

Fraction 4 1.44 40.15 8.5 1.44 17.34 8

Fraction 5 1.44 30.41 10 1.44 6.2 10

Total Yield 7.2 - - 7.2 - -

Total area % GLC (Citral) - 28.85 - - 25.84 -

Total aldehydes % (Tritation) - - 8.20 - - 7.90

Lemon Lime

TABLE 07 - LEMON X LIME - ANALYTICAL DATA

Products

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Yield

Area % GLC

(Dimethyl

Antranilate)

Aldehydes % Yield Aldehydes %

Essential oil - 0.25 0.86 - 0.75

Fraction 1 1 0.47 6.5 1 6

Fraction 2 1 0.5 7 1 6.5

Fraction 3 1 0.55 7.2 1 7

Fraction 4 1 0.92 8 1 8

Fraction 5 1 1.20 8.5 - -

Total Yield 5 - - 4 -

% area total GLC (Dimethyl

Antranilate) - 0.73 - - -

Total aldehydes % - - 7.44 - 6.88

Products

Mandarine Cravo

TABLE 8 - MANDARINE X CRAVO ANALYTICAL DATA

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Fig. 17 – Lemon – Original Essential Oil

and Concetrated Fractions

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Fig. 18 – Lime – Original Essential Oil

and Concentrated Fractions

32

Fig. 19 – Tangerines – Original Essential

Oils - Mandarine and Cravo

Prediction

•Brazilian crop 2015 / 2016

- 250 MM boxes for processing

- FCOJ – 890,000 mtons

- CPOO – 27,000 mtons

- O.P. – 1,930 mtons

- D-L – 18,300 mtons

- WP – 6,700 mtons

- CPP – 1,066,700 mtons

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• Fractional Distillation

-Efficient process if conducted correctly

-FTNF – Wide acceptance by sensory

evaluations as by the legislations

- The challenge – to develop and produce more

and more natural flavors.

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THANK YOU!!!

Dr Mércia F M Bettini

www.flavortec.com.br

Email: mercia@flavortec.com.br

Phone: ++55 17 3572 1000

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