UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

4SESD-ASB

MEMORANDUM

February 20,2013

SUBJECT: FINAL Analytical Report

Project: 13-0162, Aberdeen Groundwater

Superfiind Remedial

FROM: Jason Collum

OCS Chemist

THRU: Sallie Hale, Chief

ASB Organic Chemistry Section

TO: Jon Bomholm

Attached are the fmal results for the analytical groups listed below. These analyses were performed in accordance with the Analytical Support Branch's (ASB) Laboratory Operations and Quality Assurance Manual (ASB LOQAM) found at www.epa.gov/region4/sesd/asbsop. Any unique project data quality objectives specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the Report Narrative. Chemistry data have been verified based on the ASB LOQAM specifications and have been qualified by this laboratory if the applicable quality control criteria were not met. Verification is defined in Secfion 5.2 of the ASB LOQAM. For a listing of specific data qualifiers and explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are accurate within the limits of the method(s) and are representative only of the samples as received by the laboratory.

Analyses Included in this report: Method Used: Accreditations:

Organochlorine Pesticides (OCP) Organochlorine pesticides Organochlorine pesticides

EPA 8081 (Soil) EPA 8081 (Water)

ISO ISO

Page 1 of44 EI30307,E1303IOOCPF1NAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens. Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Sample Disposal Policy

Because of the laboratory's limited space for long term sample storage, our policy is to dispose of sampleson a periodic schedule. Please note that within 60 days of this memo, the original samples and all sample extracts anti/or sample digestates will be disposed of in accordance with applicable regulations. The 60-day sample disposal policy does not apply to criminal samples which are held until the laboratory is notified by the criminal investigators that case development and litigation are complete.

These samples may be held in the laboratory's custody for a longer period of time if you have a special project need. If you wish for the laboratory to hold samples beyond the 60-day period, please contact our Sample Control Coordinator, Debbie Colquitt, by e-mail at Colquitt.Debbie(@.cpa.t;ov. and provide a reason for holding samples beyond 60 days

cc: Nardina Turner

Page 2 of44 E130307,EI30310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road. Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

SAMPLES INCLUDED IN THIS REPORT

Project: 13-0162, Aberdeen Groundwater

Sample ID

.-XCGRBOllSn

ACGEVV03

ACGMW28

ACGMW30

ACGOBS04

GE1MWI7D

GEIMW917D

CE1MW39L

SW-09

ACGMW26

ACGM\V27

ACGMW29

ACGMW929

GE1MW29D

GE1MW29L

SD-OI

SW-01

SD-02

SD-902

SW-02

SW-902

SD-09

Laboratory ID

El 30307-01

El 30307-02

El 30307-03

El 30307-04

El 30307-05

El 30307-06

El 30307-07

El 30307-08

El 30307-09

El 30310-02

El 30310-03

El 30310-04

El 30310-05

El 30310-06

El 30310-07

El 30310-08

El 30310-09

EI30310-I0

EI30310-II

EI303I0-12

EI303I0-13

EI303I0-14

iMatrix Date Collected Date Received

Rinse Water Blank

Groundwater

Groundwater

Groundwater

Groundwater

Groundwater

Groundwater

Groundwater

Surface Water

Groundwater

Groundwater

Groundwater

Groundwater

Groundwater

Groundwater

Sediment

Surt'ace Water

Sediment

Sediment

Surface Water

Surface Water

Sediment

1/15/13

1/15/13

1/15/13

1/16/13

1/15/13

1/16/13

1/16/13

1/16/13

1/16/13

1/17/13

1/17/13

1/16/13

1/16/13

1/17/13

1/I7/I3

1/I7/I3

1/17/13

I/I7/I3

I/I7/13

I/16/I3

1/16/13

1/I7/I3

10:45

15:38

18:02

12:40

17:00

10:55

11:00 ,

14:13

14:00

16:15

17:55

16:40

16:40

11:30

11:20

15:35

16:00

15:05

15:05

16:52

16:59

14:45

1/17/13

1/17/13

1/17/13

1/17/13

1/17/13

1/17/13

1/17/13

1/17/13

1/17/13

1/18/13

1/18/13

1/18/13

1/18/13

1/18/13

1/18/13

1/18/13

1/18/13

I/18/I3

1/18/13

1/18/13

1/18/13

1/18/13

10

10

10

10

10

10

10

10

10

11

11

11

11

11

11

11

11

II

II

II

II

11

16

16

16

16

16

16

16

16

16

32

32

32

32

32

32

32

32

32

32

32

32

32

Page 3 of 44 EI30307,EI30310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

DATA QUALIFIER DEFINITIONS

U The analyte was not detected at or above the reporting limit.

D-4 MRL elevated due to interferences.

J The identificauon of the analyte is acceptable; the reported value is an estimate.

QL-1 Laboratory Control Spike Recovery less than method control limits

ACRONYMS AND ABBREVIATIONS

CAS Chemical Abstracts Service Note: Anaiytes with no known CAS identifiers have been assigned codes beginning with "E". the EPA ID as assigned by the EPA Substance Registry System (www.epa.gov/srs). or beginning with "R4-", a unique identifier assigned by the EPA Region 4 laboratory.

ISO The tesL if analyzed after June 26, 2012, is accredited under the EPA Region 4 ASB's ISO/IEC 17025 accreditation issued by ANSI-ASQ National Accreditation Board/ACLASS. Refer to certificate and scope of accredilation AT-I69I.

MDL Method Detection Limit - The minimum concentration of a substance (an analyte) that can be measured and reported with a 99% confidence that the analyte concentration is greater than zero.

MRL Minimum Reporting Limit - Analyte concentration that cortesponds to the lowest demonstrated level of acceptable quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and moisture content of soil/sediments.

TIC Tentatively Identified Compound - An analyte identified based on a match with the instrument software's mass spectral library. A calibration standard has not been analyzed to confirm the compound's identification or the estimated concentration reported.

Page 4 of44 E130307,EI30310 OCP FINAL 02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: ACGRB011513

Stat ion ID:

Lab ID: El30307-01

Mat r ix : Rinse Water Blank

Date Collected: 1/15/13 10:45

i .4.V m.: . . -iM'j Numhe;^..

% Aniiiyie Aim.-

- A M : Results Quultfi'ers'-. < 'nils 'MRL Prepared -inaly.ed' • Method

72-55-9

50-^29-3 •• "'.

309-00-2

319^84-6

5103-71-9

319-85-7

319-86-8

6 0 - 5 7 - i l £ . , : f::ty,-i:.:.

959-98-8

332^-65-1 ftlife, 1031-07-8

:72io-8 . , : : j t t ; i ; . •

7421-93-4

S3494;70r5

58-89-9

5566-34-7'

76-44-8

^24-57-3

72-43-5

SOOfiffe

!$iA

4,4'T'6DD (P,P'-PDD) , , , :l:lii,.. -ylh:

4,4'-DDE(p.p'-DDE)

4,4'-DpT(p,p'-DDT)

Aldnn

• alpha-BHC

alpha-Chlordane

beta-BHC ",^ [

delta-BHC

Dieldrin :1|;,V •.-^^. . ...-•ML: . .

Endosulfan 1 (alpha)

Endosulfan II (betk): i ..:S$,i:a... ...Si:::. . Endosulfan Sulfate

• : : : • : % : :

MP

^1:

• M ,

ft:; JiJ:U

'Endrin;:(W- ' iJJSv ..:.::mu Endrin aldehyde

1 te:

m r . Ml-.,.

m ::.mx-

Endrin ketone,

gamma-BHC (Lindane)

gatruna-Chlordaiie

Heptachlor

Heptachlorepoxide •

Methoxychlor

t6>:aphene

0.040 U

0.020 LI

6:050 U

0.020 U

0.020 II

1:" 0.620*1^'

0.020 l.l • ' ^ j ^ ^ ^ • •

• « ; * : 0.020 U '

0.020 U

^ ':llo;o40 u . , , ,-,te,, , ,

0.050 II

l 0 4 0 U . i ; * i > s . , , -

0.050 U

N' 0 . 0 5 0 %

0.010 11

'• , : ,0.020 U '

0.015 U

;p^020 U

O.IO U

"" 2.0 U

ugli '

ug/L

ug/L;

ug/L

ug/L",

= ., . ug/L

- ug/L ' i ••

ug/L '

:.. "S'L

Ug/L

•.;ug/L

Ugrt-

-UgO,

Ug/L

ug/L'

ug/L

ug/L--,

ug/L

•=,.' u g / L : ; i

ug/L

•fll/L-f

0.040

0.020

0.050

0.020

0.010

0.020

0.020

0.020

0.020

0.020

; 10.040

0.050

" | ; < M 0 0.050

0.050

0.010

0.020

0.015

0.020

O.IO

S;;,- 2.0

-1/22/13 9.U7

i . : 2 / n 1 U7

i ' r / 1 3 <1.OT

" l / i 2 " ' l 3 y 07

1'22/13 9.07 ^

1/22/13* 9 07

1/22/13 9 0 7

l /22/ l '3 ' M07

1/22/13 9 07

i , ' : : / i3 9 07

1/2J/I3 9.U7

i / : : / i 3 9 07

• i / 2 ; / i 3 - I - 9.07

1/22/13 9 07

: 1/22/13 • - 9.'07

1/22/13 9 07

1/22/13 9 0 7 -

1'22/13 9 07

1/22/13' 9.07

1/22/13 9 07

1/22/13 9 07

1/29/13 !4;S8

i , ' :9/i3 14 58

t / 2 9 / n M.S8

] /2 i / l } 14 58

= -.- 1/29/13 :5 j 14:58

I; : ' ) ;I3 14 58

- ' : : i / 2 9 / l 3

l A v J j * ' ^ ' | ; ; 9 / I 3 14 58

' : :-'l/39/13 f, .14:58

1/29/13 14 58

':"'"-1/29/13 •14 58

1/29/13 14 58

1/29/13 14.58

1/29/13 ^ 14 58

t/29/13 14-5S". -

1/29/13 14 58

" • • 1/29/13-j . . , 14-58

1/29/13 14 58

- = -1/29/13 : 14 58

1/29/13 14 58

; '"La9/i3 ' : : 14 38

, EPA SOS 1 . : i. l i : . - .

EPA 8081

£PA 8081

EPA 8081

'EPA,80S1

EPA 8081

EPAMSl

EPA 8081

BPA 8081

EPA 8081

EP.48081

EP.'\8081

EPA 8081-

EPA 8081

EPA 808 L:

EPA 8081

ii 'A 8081

EPA 8081

EPA8i)ai

EPA 8081

EPAsbsi

Page 5 of 44 E I 3 0 3 0 7 , E I 3 0 3 1 0 O C P F I N A L 0 2 2 0 I 3 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: ACGEW03

Starion ID: ACGEW03

Lab ID: E130307-02 Matrix: Groundwater

Date Collected: 1/15/13 15:38

Page 6 of44 EI30307,EI303I0OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: ACGMW28

Station ID: ACGMW28

Lab ID: El30307-03

Matr ix : Groundwater

Date Collected: I / I5/13 18:02

K--''iM>- ':v. V.-;.. -ri-' W:-' • 'A''A^MiA-A^--l;-i 'iV«m/)fr..--tflJ-J'. .diinlyte.ff -'-''• --.J-'-i^Aj-."- -r-J K""-'-! .A'^^^ResultAf QunlifieAi- ir'-J,; 'ii'^^Uniis-,

• - ' - " • ' ' - - • ' . i f ' - ' " - ' -^A-pV:A-

" •y<AA^.MRI:, / ' Prepared;«- ~1 wa/i-:: '*/ MetP> )i-' Tp':P

72-'s4T'".„ ' iff •' 4,"4'-PDD''(p^DDp)l^t;--'--''''. ' " " " ^ g ^ . T ^ ^2£io j i^ 72-55-9

309-00-2

4,4'-DDE (p.p'-DDE) 0.020 U ug/L

•••^\ f.;0.0.44J.'.jr.. 9 07 , ^uM.j^,£a£L£sT..S,j£Jl« . . . .

0.020 "r^^^

• l.'29/t3 ;'15.27 .

i;- 4;4'-6M(p:p'-DDf )M JS^») : ' 051 U P^!?7' Pu&'L

1/2U/I3 15 27

1/22/13 C,^fi729/lT 15 27

Aldrin

31^-84-6. ." -^alpha-BHg:^.;

5103-71-9

0.020 U

90:010/U

0 020

-•nl^aoixi'' alpha-Chlordane 0.020 U ugA-

315.85-7:: ...M:::.:-::j± 319-86-8

959-98-8

delta-BHC

'"^Dieldrin v r ^ -

Endosulfan 1 (alpha)

I^^Mik -#0:020'U.

0.020

9:07 j

1/22/13 9 07

•T/22/i3.' 907

1/22/13 9 07

' iaiiu"' 9 07

0 020 U 0.020 "5^^^

1/29/13 |5 27

M/iii/ij :--|5-27

1/29/13 15 27

•TKo/lS '

1/29/13 15:27

•^oJlS ......t. :it:.i.-i.i, ' .

0.020 U

3 3 2 1 3 ^ 5 ^ -

1031-07-8

•Endpsulfan]l-(beta)

Endosulfan Sulfate A-- ' - - ^ - - - ' ^ - . w - i ' - : - : - ••^?¥:T^:- • — -72-20.8»afflv^ Endrin::: . : .A i.A..AS&Mis ..::£.Si.. - .

Endrin aldehyde 7421-93-4

53494-70-5 ' „ ' Endrin ketone ' ' p :

58-89-9 gamma-BHC (Lindane)

5566-34-7 im'gamma-Chibrdane ;^,^ _ :-ff±^. : t ^

76-44-8 Heptachlor • • v : ^ : : ^ r - : : ^ ^ : ^ . ' • - i . - .x

• |024i5KM'; • • . . . . . • . - . S i d S ^ A ^

72-43-5

0.040-yf:;

0.051 u

0.040 Z \

0.051 U

0.051 U j l

0.010 U

|ao20 u

0.015 U •••• . •^•y^>^T' ;yr .T ' . . ^ ^ . y .

. ; Heptachlor epoxide^H- • " l ^ l •|0l020|U,\

ug/L

lipj ug/L

ug%

ugA-

ug/l^

ug/L

ug/L?J

ug/L

o:o2o.i 0.020

"o^iO-;

0.051

0.04Ct

0.051

^0:05:i!l;"|^^ 1/22/1.1

9:07

1.'22/I3,' 907

1/22/13 9 07

tillin: 9.07

1/22/13 9 07

1/22/13 9.07

1/22/13 9:07

0.010

0.02C^?^^

0.015 "5§

mA : 0.020,'Cfl^^,

Methoxychlor O.IO U ug/L O.IO

8001-35-2-„ Toxaphene -.•2>:o;-u,::;.; •N .cug /1

1/22/13 9U7

, r. 1/22/13 • Z.U - 9.07..

;Ms;27.-, 1/29/13 1527

'BfiKwn iMM}Aff.

1/29/13 15:27

• •Arwwiii •;,-!j|f5:27,

1/29/13 1527

, . . i i i & w i : r . . . 1/29/13 1527

TSS'iJ ;|1W7:._

1/29/13 15:27

"vSKif •13^27K-1/29/13 15 27

• Vivln''-15:27-:

EPA8()«1, ' •pXp.

EPA SOS 1

EPA-SOSI -i-A^A

EP.ASOSI

EP; '8081 p A '

EPA 8081

EPAsqsi p p :

EP.' S081 • " - - i E & T r ; - — n ^ , ; -EPA:8|«L . : i g ^ :

EP.ASOSl

EPA'8081 ^Ifei, ^:rsL:„,-. ,-.ii^,-,.,,

EPA SOS 1 : - : p ^ - r -?!!?-:••

EPA 8081 ' - . . ^ , ^ ^ ^ 4 ^ 4 ^ ^ . -

EPA 8081 •••• r - ? » ' ' - - ; - , ^ T ' f * - ^

EPAS081 •"•i'ii:, •

EP.'kS08l - - . - ' • ^ f f ^ . - ; ' ^ -

EPA' 8081 , : ' i ^ ^ . . .-,

EPA 8081

:EPA8081iV'

EPA 8081

'EPA 8081:

'':m:.

Page 7 of44 EI30307.EI303I0OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: ACGMWjO

Station ID: ACGMVV30

Lab ID: El30307-04

Matrix: Groundwater

Date Collected: 1/16/13 12:40

'C4.v^ wmmp: immzz:'-Pm%6 -lifsF •'*""{> f@;'--v' '^"^^^Pj. Z '^'i0^^'"8Z""'^lfSW^Z

«>TJ=% .aj^j-

. ,i '^W.n^'1: MRL: VPreparedt-- •lnalrr,edi< .Meiho'd -, i : ' ^ ' v ' ^ f ' B . -•: -xj '- -

72:54-8' J i'A-' 4,4^DDd(p;p'2DDDn^Sf^^^^ ^ ^ f g ' - ' 0.040-1;

8001-35-:

Page 8 of44 E130307.EI30310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: ACGOBS04

Station ID: ACGOBS04

Date Collected: 1/1.S/13 17:00

Lab ID: E130307-05

Matrix: Groundwater

Nttmber Ri:-:^idts (ft.ta!'i MRI .

72-55-9

309-00-2

319-84^' '"

5103-71-9

319-85-7

3l'i-S<i-8

60-57-1

95Q-4,S-H

33213-65-9

1 0 J I - ( ) 7 - , S

72-20-8

7421-93-4

53494-70-5

58-89-9

5566-34-7

76-44-X

1024-57-3

72-43-s

8001-35-2

4.4'-DDD {p,p'-DDD)

4 4 ' - O I ) l : ( p . p ' - D D L )

4,4'-DDT (p.p'-DDT)

Aldnn

alpha-BHC

alpha-ClilorJane

beta-BHC

dclta-BllL

Dieldi

I ndosullan 1 (alpha)

Endosulfan II (beta:

Tndo'iullan Sulfate

Endnn

lndnn aldehyde

Endrin ketoi

gamina-BIIC (Lindane)

gamma-Chlordane

Heptachlor

Heptachlor epoxide;

Methoxychlor

Toxaphene

l/22;"t3 9.07

1 22 1 ?

|.'22/13 9:07

1 22 n

1/22/13 9:07

1/29/13 15 56

1 ;•' 1)

1.'29/I3 15:56

1 2" 1 1 H V,

t/29/13 15:56

1 1 1 M

1/22 I j 9 0 7 ^ ^

1 ' 2 1 3 " ' " ' 0 7

122 13 9 07

I 29yH

1/29/1 1 15 5(

1 29/1 3 1^ 56

1 1 I I

1 ' 2 n 9 07

1 29 1 1 15 s(.

1 1 I I 1

1 22 n 9 07

\ l l ) , 9 07

1/22/13 9:07

1 2 2 1 . ;

1/22.11 9 0 7

1 22 11 * (17

1 22 13 9 07

1/22/13 9 07

9 07

1 29 13 15 56

1 ; " 11 1 ^ . (.

I,''29/I3 15:56

1 ; ' i l.i 1 f.

1 2»'13 15 56

1 ; ' 11 1> S(

1 21 H 15 5')

1/29/13 15 56

15 56

EPASOg;

f:i>-\sii8i

EPA 8081

i;i>.\ SUS 1

EPA 8081

I P\SllSI

EPA 8081

LP\-ll)Sl

FPA 8081

1 i'\SIISI

LPA 8081

I I \ s i i s i

EPA 8081

i:p.A siis 1

EPA 8081

HP.ASOSl

EPA 801

IPX SOS I

I P \ 8 0 :

EPA 8081

Page 9 of44 EI30307,E130310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater- Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: GEIMWI7D

Station ID: GEIMW17D

Lab ID: E130307-06

Matrix: Groundwater

Date Collected: 1/16/13 10:55

<"4.V

.^umber 4iiatyte. " fe

Results Qualifiers-^ Units MRL Prepared ' -Analyzed .\fethpi1 :'p

72-54',8#S^'^'.;, 4,4'-DDp'(p;p'-DDp)j':'fe'.,r'r'f

72-55-9

50-29-3"

!^-'-^i:;;w;o.040;U1 •f:%Z.=--. • " ^ U g / L ^ " - :

• i s S s ^ '

M 1/23/13 4 ' ^ ' 1/30/13j,; 12.43.i.-|

•rvr^i'ncf^Tp^rr^.,''.-^ 1 EPA 8081.., -"-^'Aiifi--:

309-00-2

4,4'-DDE (p.p'-DDE)

U,4'-DD"r.(p;p'-DDT)

Aldnn : ^ A « i , i

0.020 U

0 . 0 5 1 - u ' " . " ^ . .

0.020 IJ

319-84:6f-^^,^H'- 'alplia-BHG-r';'

5103-71-9

319-85-7

319-86-8

- i ' - \A . - - W^''- ' ' .:f-'o:010?U^ti;giJe':-'' '

alpha-Chlordane

beta-BHC ~ 1 ; . \

delta-BHC

0.020 U

0.020 IJ 0.020 U

60- ' s74 ' | ^

959-98-8 ,

33213-65-9

1031-07-8

•Ammz -4Jjbieldrin*;.;,.ftC"2-;'': - '

Endosulfan I (alpha)

Endosulfan H (betaX.-

Endosulfan Sulfate

•:-5'-0:p204JH^<iC 0.020 l.l

Mz^^llZE.. 0 051 U

ug/L

ug/L

•o.mpAp%!^j : ; i /30/13-> ; EPA 8081-

0.020

0.040'

0.051 'T3'l,

1/23/13 9 30

| / 2 3 ' 1 3 , .. 9,.3l)--;

1/30/13 12 43

" 1/30/13" 12.43

1/30/13 12 43

EPA 8081

EPA 8081

EPA 8081

72-20-8: ^TTT: '-'£•"- " *S5' 'Z.

r^Bisr-::^.-#i'^',w0.040 U . ':•

"V^ " ^ "TT^ •"-;??£• jT^;gg'"7:'--' -

'•' • ' ' ' "T^Z" ' ' -0:040- g i 1/23/13-S

-r';.9.3o; !"--- 1/30/13" , .. 12-43--

'TT!?^-"-;?',»."'•A:^i»'j";-: E P A 8 0 8 l - ' ' ' ; H ^ p j ; ^

Endnn aldehyde

Endrin ketotie :

gamma-BHC (Lindane)

0.051 U

•"MTOSI U

ug/L

'"i ,,.::^ Ug/L ..^oiAj^-ri 1,1. :

0.051

'0.051

0010 U ug/L 0.010

1/23/13 9 10

• 'inSiP 9-30

1/23/13 9 30

1/30/13 12 43

' i /30/I3 ,ftJ2:43 .

E P A 8 0 8 1

EPA-8081-

1/30/13 12 43 EPA 8081

. /y.-ji '^iy •AMbfo^ou' J"garnma-,Ghlbrdane' - :v"4|

Heptachlor

•'A- Heptachlor epoxide

''ug/ia

Methoxychlor

0.015 U

(MoZZ' 0.10 u

U g / L

ug/L

ro.020. 0.015

•0.020

• : T I > 1 / 2 3 / I 3 . ' ' - = 1 9 ' 3 0

1/23/13 9 30

1/23/13 9 30 ,

U g / L O.IO 1/23/13 9.30

! 1/30/13,1

1/30/13 12 43

"^"""1/30/13 .,^^^^.1.2 43 ^

1/30/13 12:43

EPA 8081

EPA 8081

EPA 8081

"i-; Tbxaphe'nb"s-:i^:|J • . i . i . ^ , - i g .%" i ' I'l,

'^:"V2.Q4U..::|-:";: 'iAfi{7! ^ v - A p A i . ••TO -'-; 1/23/13 S - - '*9.30-J

L i ; 1/30/13; .-.- ! 2 : 4 3 - '

—?R.---»r; , , a - ' . » .y^ . ,y j . fEPA-gOSl -,-;•,-.?:«.

Page 10 of 44 EI30307,EI303IOOCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: GEIMWOnD

Station ID: GEIMW17D

Lab ID: El30307-07

Mat r ix : Groundwater

Date Collected: 1/16/13 11:00

t"5^^Sfe""^if0D'^-^^Sv ;•' -A; ;.-;-5'-t-;-'2? .-=r522;'V;¥:'>sa;.4fe- « f?JJ •;: : . : j i r^ i -i%liji>iUiResiiltsigOtmtifie>^MAA

Ph&^M- A. UiiilA- {MRL

Z':^i^,^^^^AA^-^^AP)iPh •-: -AA--..^*P.repared^:.-.i-Analyze.d ^Method^-ii..^ j - h 2 -' '^ .. i

7 2 . 5 4 2 ^ ; ' •^•'*'''^R^lP'PL-DDD);.:ftj;,

72-55-9 . -* : . .L-M^:i^. . .-..- 2iL.a :

4.4'-DDE (p.p'-DDE) 0.020 U

5 ( | 2 9 - 2 ^ ; ' " ' 'W ' -DDT(p ,p ; rDDT)

309-00-2 Aldrin

319-84^ ' ^ h a - B H C f:!::,

5103-71-9 alpha-Chlordane

3l|:^85-7 - ^ a - B H C K";

"Wi: -^K0.051 U 'AAMrliA: 0.020 U

h"0.010 U^

0.020 Ll

^0.020 u , . - ' ^ ' : '

319-86-8-

6o37-l

delta-BHC

Dieldrin'--

0.020 Ll

/o:o20 ZAMA'-

Ug/L

ug/L

ug/L

,;,, ug/L

Ug/L

•:i0'040.- '!."-.-9.30, •EPA 8081':

0.020

"oWI 0.020

0.020

'oW

1/23/13 9.30

TvT^TniiT •'.:-, 9:30

1/2.1/13 9 30

1/10/13 12 57

1/30/13 12 57

1/23/13 • 311/30/13 9:10 ;!:';:Sl2.:'57

EPA 8081

EP^SiDSi^p

EPA 8081

EP/3.8031«f'

i..^.^^!!

1/23/13 930

•"irivTi^. 9'30f,i

. : « •

1/10/13 12:57 EPA 8081

959-98-8, Endosulfan I (alpha) 0 020 IJ

33213;65;.gf;;:*;EndbaifanjII (beta^JT^.': -'.•av;;,.,i.o;o4o u- . ''Uji^W'^.-..j:.^a.,.'i^,~:.>.uaatt;w_.ft ..'...•.i ^ 'aai.a:—.'--

ug/L

0.020

0.020

'^i^jEPASOfi ' i ;^-' ? : ? ] a ^ \ : £M2._:

1/30/13 12 57

1/23/13 930

• " v i m r m ' t'30/i3"Spp. a Jg",. .30,.- t 12.57,.' •g, ' ' ™''.';

1/23/13 9 30

1/30/13 12:57

m&p^zm^^mi tjihAM^imM EPA-SOgllUi; M L

• •mm

1031-07-8 Endosulfan Sulfate

72;20-8' ^VX -f'^Ehariiil'.,-'^! A:s^ - -.1 i . i .

0.051 U ug/L 0.051 1/23/13 9 30

1/30/13 12:57 EPA 8081

!'; ' .itj^: 1 "•i'J't'g';<Ki»-.;'.',:i"jv"asi-.t;.:'a:-V'1ia"J"i

ApM-\- " ^ p f j ^ ^ B t ^ ^ Z . ii,.k... sA...XiL..:$s.;;A.i!..:.• :..s.ttAS:X:S^ti•,.i-.:tih.tSm'i^rtima,'Af.j^lMt^al 7421-93-4 Endrin aldehyde 0 051 U

' • - A ^ T ;i 0.051 Us: i f ;g i -« : .a.t,:av.: .^^-.tiji,?^..*'.-

0.010 u

Ug/L

't-j4: •- ug/L -

ua/L

0.051 1/23/13 9 30

1/30/13 12 57 EPAS

.JM0:651 1/23/13--,:9'3or'.;

.1/30/13 .12 m

-i. 76-44-8

If24-S-^F 2li. ....

72-43-5

8001,-35-2 Z-^

l:ganima-Ghlbfdaner?«B':. --'- - -1 . . - . .^ .^ . . :.jym>-.

p ; - ':05020U- : f i ^ t e

Heptachlor

iHeptaehlor epoxide lil: ..iiJ.-... , . .„ j5a , i . . . . :bk

Methoxychlor

toxaphene

0.015 U

oWZ 0.10 u

2 .0M

ugrt-

ug/L

;|i/L-

0.010

*l=f0:020

0.015

0.10

To'

1/23/13 9:30

1/30/13 12:57 EPA 8081

l/23/l'3j';:;. -.: J^::i..aa;ii,^L.^: •,;.

1 /23 /13 9 : 3 0

"•l/23/13'l 9:3(8;i

1/30/135 12:571

1/23/13 9:30

1/30/13 12:57

'l/30/l'?1 _ 12:57;.-

1/30/13 12:57

^ ^ • • r t x m - r : J E P A S O S I -

EPA 8081

»EPA8013#;:

EPA 8031

l.'23/13 1,:>

s v!-:$a 1/30/13 12:57: : : 'EPA808l | mi

Page I I of44 E130307,E1303IOOCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: G E I M W 3 9 L

Stat ion ID: GEIMVV39L

Lab ID: El30307-08

Mat r ix : Groundwater

Date Collected: 1/16/13 14:13

" ' • m h l r S . p i i ' P : . 4 i i • ' ' -"• '=• '••" ' -- -=-*--•*•- •-

\ . :A: - (^ -"

':'i'--.--(:'nitx-'.

if-f'^- mi: i^lU : '.JC:^ .- -; .:.• : ; ^ ^ '*^.^i^^'v-.^&gf^t'iifi ;^M::::.;i,-:iJl!^i: •••'f I ' .T ' i ' - - •-..:.».i.\."-!ir.is^ts-t^i*:.:n.^/tf.--;.^l:ij^.^: ''t"::S.-MRI:-:,:Prepared.-k-.-U'iah-zedy.'Hetliiid i i '>?<>*.'»-:'-:

——"—.. '.^.yi^, T- "'T'' .:..j,i.. .r-— 7 2 - 5 4 - 8 , . | g . - . • 4,4':DpD (p.p'-DDD).,:j:;, ':' -mom u ;• ' sC--72-55-9

50-29-3

309-00-2

4.4'-DDE (p.p'-DDE)

iv»';4'-DD'F(p,p'-DDT)

Aldrin

0.020 U

...^—ar„:i,i.vrt:rKAl«

0.020 U

3:1958426 ::^pHa-BHC 'A

alpha-Chlordane

befaSBHC —:.1JJ*> ,

delta-BHC

0.010 vp%:..,

0.020 U

6.02"o u • " ^

0.020 U

..Asa^.i^ - f . | 0 ; 0 2 0 U 'AM. . .

UgA.

Ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

'AJ^C-

•l/23n3<>:-f -,-?,3,0jy',t

^rr:^r?r;-;.-i^s' 'Sg' 2'-'-a.«'»''?q^ •13:25 EPA?.'?.Wl^'''W*'1

959-98-8 Endosulfan 1 (alpha)

33213--65-9R;^Erid6su1faii4I.(beta)' ;;:-•:*---

0.020 U ug/L 0.020 1/23/13 9 30 EPA 8081

"iJ-' /tl'i kU-' ".'-'.'.—":"^:-"gy*'^:t"'"

•• oro40iM.:v. A- Am- iug/P':=>; 1031-07-; Endosulfan Sulfate 0.051 U ugO.

72-20-8fe'4B*'«j:Endfini-?^i aX,u»-: ->-:yg.>i.-H gl !',i'2-2a4aj

~I--;T'JS^'-

''.-r-«a; : .5; - .

5.2 A ' v j i r i y r ^ T T ^ "

•jv():^o;-u^-v,^^..,-,.

0.040-..

0.051

•'O^Sdi^^

n,1/23/131;-? :&.30 - -' • ' ' ' & - ' * ' • *- ' ^ ' ^ t -

1/23/13 930

-=9.30-,<'-:.

1/31/13 13 25

1/31/13 11 25 EPA 8081

;,'pj'^5^-S'D'A-'808i';'-

7421-93-4 Endrin aldehyde

5 3 4 ^ 7 0 - 5 n ^ i i S r i n l e i S n P ^

0.051 U

'^A. '•0 05I;4:I'.;

ug/L

ue/L

0.051

' aos'i •

1/23/13 9 10

1/31/13 13 25

..; 1/23/13 .,^•9:30 : i;aEPA8081.'-

58-89-9

556635^7

76-44-8

1 0 2 4 - 5 7 ^

72-43-5

gamma-BHC (Lindane) 0.010 u

garnma-Chlordane*^,.

Heptachlor

Heptachlor epoxide

Methoxychlor

8ppi-35-2'3^^^xapSJ?:' '• '

0.020>U^

0.015 U

0.020 U„

O.IO U

Fizolf ~ r , ^ . ~

ug/L

ug/L

ug/L

ug/L

ug/L

0.010

0 . 0 2 0 '

(LOI 5

0.020

0.10

1/23/13 9 30

"l'/i3/l'3.i - 9:30 •

1/23/13 9 30

1/23/13:» 9.30.*.

1/23:13 9 30

I/23/I3 , 9.30 ,

1/31/13 13 25

ri/3l"/l~ 1325

I/3I/I3 13 25

"1/31/13 ••'UA I/3I/I3 13:25

3Twi3? 13*1 lii

EPA 8081

EPA-8081^ •-;;.';;

EPA 8081

EPA 8081; ; . . i- ,

EPA 8081

EPAsosi :;:

Page 12 o f 4 4 E 1 3 0 3 0 7 , E 1 3 0 3 I O O C P F 1 N A L 0 2 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700

D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater- Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: SW-09

Stat ion ID: SW-09

Lab ID: EI30307-09

Mat r i x : Surface Water

Date Collected: 1/16/13 14:00

• f- 'fj i ,

•MRIkr- .Prepared •-Uiiilyzed .VWAflrf -;•: i --•r':.A. V . 1 - . y ^ i - - .= :^-^-

cAstm Number. '

•m •\iialvte

•m' '" •-MP

• 'Z ' RiAiiits Qualifiers '-; A--H M A '-.,WS•:^ :pMiUnii.Am-

72-S,4-;8

72-55-9

50:29-3

4,4'-DDD (p.p'rDDD)

4,4'-DDE (p.p'-DDE)

0 040 l.l:

0.020 U

4,'4'-Dt>'r;(p.p:-pDT), ,;,:5 Fn jmi.oso' ^A

Ug/L

309-00-2

•319-'84-'6''-.=?« "•-:

Aldrin

5103-71-9

31955-7

319-86-8

60-51-1

959-98-8

y2T3'-'6.5.,9!Hi

ralpha^'HCjf^-yS.'f.-^;

alpha-Chlordane

bSk-BHcFW'

JSiJM:

0.020 U

i:.r;'^i*;f;^^o!oo9M^i'r; ug/L 0.020

V-;?iS4'''<-.L-'>^5ll/Ll^S>o.¥699'/ f .^i:-.... • .-.,:: g.=^-V'*"-..-'- -•.'---,-x-iii-.. ........ 1 .::t,:fl,^iM '.'.....'-

..r. ; 1/23/13-•|.-l,>..,'i7307l-ipAiipAsidilAilS: : ' i -9-30 • - ' ' • :%^.n-2 l i^%^- 9"° 1 . j t ; - !

0 020 U UgA- 0 020 1/23/13 9 30

1/10/13 13 2o EPA 8081

••r#0.020;Uk*-j-:, —'W^ HiSei, L_

1031-07-8

delta-BHC

Dieldrin.^r-J-|2: p

Endosulfan 1 (alpha)

-;Eridosu1fari II (beta)-H^-i''' i i i liX-e '-': ,-—j^-jj^-a^ Endosulfan Sulfate

0.020 U

6.02jnj

0.020 U

^iSt; 0.04,0 IJ

7pi:- 0.020-

ugA- 0.020

ug/L j " ^ ' 0.020 ,

ug/L 0.020

'^''' ^oTo4o;-ug4-1J:,

1/23/13-•;:,-s9,-30 •

' l/23/T3~ 9 30

-T&3/I3 : • :9.30

'T72.VI3 ' 9 30

' f/fj/ITTi 9.30 ' . : : ,

1/30/13:-13-26:

1/30/13 13 26

. 1/30/13 .^13.26

1/30/13 13 26

:-', 1/30/13-r»!.13.26,-/

EPA 8081 :•;

EPA 8081

EPA 8081>

EPA 8081

EP.A'808r-

0 050 U ug/L 0.050 1/23/13 9 30

1/30/13 13 26 EPA 8081

'Endrin Af: A^'Mf^A^^AViAiAA. ^-.j^u-^^aMi.::^^;: -. j : .^s:aE^. . . ^6^:040®*^ :PM

h^r- - i:.iimiftMAi..,.. o:040»i:-•~:..i^L.£.....:tii.ll:^.^^. i S i a s :.zi.AxSi2

• 1/23/13-;',-:9.30 .

vmiwiir .liMiiiiS::

Endnn aldehyde 0.050 U

Endnn ketone *»

58-89-9

^134-7

76-44-8

gamma-BHC (Lindane)

ganima-Chlbfdane

Heptachlor

__j|^.050i|ij:

0.0099 U

f"o.02pT.r 0.015 U

ug/L

•iff '^^ ' ug/L

ugj ug/L

0.050

opo5 0.0099

J!020 0.015

1/23/13 9 30

;;EP/¥80,8,1-

1/30/13 13 26

1/23/13 ;r' 9-30 -'-i-i-x? 13'26

Jl/30/13

EPA 8081

EPA 808!

1/2,1/13 930

'1/2'3/Tr" 9 30 "-

1/23/13 9 30

1/30/13 13 26

'1/30/13" 13 16.2

1/30/13 13 26

EPA 8081

'•'E'PASOSI

EPA 8081

1024?S7-3

72-43-5

Heptacl'ilof'e[X)xide-;';.te.'

Methoxvchlor

t'.ta'"!'.—^——'Wr?—-• • ••.*=• • : -o .020:U. , aa—tf4Ka.Xiwiui..JU>-jr;.i';iii&r>.r.h- ^ ' ^ i ^

- — ™ j t —

-USL'. ,.0.020 : 1/23/13.:. - ; ' 9 3 o r . .

••I/3tVt'3"i*: -'. !3:26j;rr :• EPA 8081

800R35-'2 Tc»(aphetieP ; :q |y^ ; ' v ' ' . ^ ^ f '• ' ' ^ . ^ ^

0.099 U ug/L 0.099 1/23/13 9:30

2;0:;U,=r=-i ,-iSig^--ug^^ :¥!:»>-2:o l/23/13t

1/30/13 13:26

•' i^S'"M/30/l3"i -g.-:*-' 13:26;^ SEPA 8081*51

Page 13 of 44 E130307EI303I0OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: ACGMVV26

Station ID: ACGMW26

Lab ID: EI30310-02

Matrix: Groundwater

Date Collected: 1/17/13 16:15

UAS'. Number.

- -^,v

AiialytA.

KWAiU:

:;i;i«:.

-•Ammp--A^'^A-'-' • vZPP. •;:gtfci«f.wta' -Quiitifiers "pi'^.- '•-

••^.A^hAy

Units MRL

!A-W^iP.Pp:'' •''-PV^-. r •-•••i^'.i^AS''''^ " •A, : ' -J : Prepared^Analyzed iileihod --:

. - r « s < * . : r . " . --•-•li

72-54-8

72-55-9

4.4'-DD,D(p,p'-DDD)-'-.,

4.4'-DDE (p.p'-DDE)

',4,4'-DDT ( p l ^ D T ) •

6:040-'I.C

0.020 U

0.050,Us.'^H,: - ............IJ.iiA-.

jig/L';,:;

ug/L

».,ia:,..,r.ija=.

: 0.040

0.020

'ao5b''

1/23/13 :::--'• 1/31/13 9.30- -';:-*-13 39

1/23/13 930

EPA 8081,

13 39

. .-fiiTyi^rff EP.A SOS I

• "wl ) ' . -:;-'l3'3if2:-EPAS0SI, ^ y i

0.020 U ug/L 0.020 1/23/13 9 30

3l9.284':6t ., ... rJsalpha-BHC:-,U;#'.''i''''>-".-i--:'J r . ' " ' i 'p . ' ^ d VW'.O.OlOrU.'f.r ;k-''' ;i'. v (i :t!g4i L_£^. ..-^: - -. .^=S-a^->.--j{.£h ir.Hh..

1/31/13 13 19

SWSl/i'38

EPA 8081

yioioi ;1!^ '^ i ;^*«yf^ '^PiES808i^*p:f8p^

5103-71-9

319^.85-7;

319-86-8

60-5^-1

959-98-8

l3213?655r-' " 1031-07-8

alpha-Chlordane

." ta-BHC £ l '

72yo:8^;^^, ^•Endr ih :? V ^ ^ - .ji; f ^ 'ZymSM'P ± S i "g/L.^.

7421-93-4

53494-7015

58-89-9

5566-34:7 ,

76-44-8

Endrin aldehyde

Endrin ketone •' W

0.050 U

gamma-BHC (Lindane)

gamma-Chfordane ' ^ r . .

Heptachlor

o'o"50lu^ 0.010 U

"•^'';0.020 U

0.015 U

ug/L

,-/T- : ; < i > - : l -

ug/L

ug/L

ug/L

o^to-0.050

OOSO

0.010

0^020-

0.015

r r i / i i / i r S T i T J i / n ^ f ^ ,;-;-,p;.3pi' i., --i-13:39'"- -:AA.^.,

1/23/13 9 30 EPA

1/23/13 K:- 1/31/13

''-i?la!^iiJliL-1'23/13

9 30

1024'';S7-3r::yi:, '--src*.-:~.Heptach1or'epoxide, r e ^ - ^ ^ , , .. ; . - J " ' f t ^^ ' ^»^ j , . ' ^

'=-y=?fc'.- -:- -0010\\A; .ug/L .0.020. - . . i i i i .

I/23/I3 9 30

1/23/13 9 30

•^.xirmT • .930- '

1/31/13 13 39

""1:131713? - 13 3 g ^

1/31/13 13 39

• , , i , l 33 ! ) i | | -

EPA'

EPA

EPA

EPA

:EPA

8081. . :',

8081

808J

8081

8081"'. *;•

8081

8oa^i^-;^|JR

72-43-5 Metho.wchlor 0.10 U Ugrt- 0.10 1/2.1/13 9.30

1/31/13 1319

ifiJtpxapheneiSS^^ - iTot.i'j- -JH' • I /3"J/l3.;.M«,l/30/I3|H •9.30:: jA>vi3:45| | ; j

808lJte"''*'^^ •:,v,;fW^! BtSi» 800r-35r;2,?^„ ~m-.' 'im- EPA

Page 14 of44 E130307,EI303I0OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: ACGMW27

Station ID: ACGMW27

Date Collected: 1/17/13 17:55

Lab ID: E130310-03

Matrix: Groundwater

72-54-8

72-55-9

50-29-3

309-00-2

319-84-6

5103-71-9

319-85-7

319-86-8

60-57-1

959-98-8

33213-65-'?

1031-07-8

72-20-8

7421 -9.1-4

53494-70-5

S8-.S9-9

5566-34-7

76-44-8

1024-57-3

72-43-5

»0Oi.35-2

4.4'-DDD(p,p'-DDD)

4,4'-DI)i:(p.p'-UI)l )

4.4'.DD'I (p.p'-DDT)

,\klnn

alpha-BHC

alpha-Chlordane

beta-BI

delta-BHC

Dieldrl

L.ndosulfan I (alpha)

Endosulfan II (beta):

l:ndosult'an Sulfate

Endrin

l:ndrm aldeh\d:

Endrin kctoi

gainnia-BI IC (Lindane)

gainma-Chlordane

Heptachlor

Heptachlor epioxida

Mclhowchlor

Toxaphene

Page 15 of 44 EI30307,EI303I0OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: ACGMW29

Station ID: ACGMW29

Lab ID: EI30310-04

Matrix: Groundwater

Date Collected: I/I6/I3 16:40

Page 16 of 44 E130307,E1303IOOCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater- Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: ACGMW929

.Station ID: ACGMW29

Lab ID: El30310-05

Matrix: Groundwater

Date Collected: 1/16/13 16:40 ^^'"••. .•••• 'A;if:tf-A'-- '"; .A^A'.-i:

Number. t A ^ i •'•-. 41'lhlvii'n •- : ' ' tns-^^hA\ -m^-Ufi:-

*:r^'i>te^> • '-A'-Mi^'"''"" ^ • n ^ ^ g : { i . •

' ; ? * • . '•-'ihA-f/'i.A:- - .. , .MRI'A-k'Pr'epared r.UwI'A.ed-• .tlethod-i .^ u

.:t:!Crt';s-.= - ' j ' = -,. - : - ' , - - . - • :.--.,£.2-:-

72-54^8'J|%-5^^j1; 4,4'-PDD (p,p'-DpD)i:..; •

72-55-9

••tx:;:-!., '•: • ' l i ' i i ' . iggj*! ' ; '-"- ' ' . ' ' • • ' " -:-'•:• . • ' T ^ # ' - - ':^MO.-040 U . ••'-.••:••- %' l i S ^ ::-iMr.A!y.....-.... .^lix.^, .'..I,..

4.4'-DDE (p.p'-DDE)

50-29l3|r;j:j,fif';4,4'-DD,T(p,p'-DDT<)''-;-r 2i-.,-..,.:itr..,a:i.a: . t i X ^ j ^ . . . . . .-,^-rfJ^lirffV ^,'::^/^?^M>

309-00-2 Aldnn

1730/13

- J i i ! ' ' 1/10/13 14 28

- 1/30/13* .-Ji'iS

1/30/13" 14 28

"T/io/is i ' i ' r5„

1/10/13 14 28

' '\JlS\i _:i4_;_8_

1/30/13 14 28

"ia'3/i,3

-AiM. 1/30/13 14 28

1/30/13 14,28

1/30/13 14 28

'l730/13 .,14-28 I'30/13 14 28

"wd/is" 14-28^_

1/30/13 14 28

mmt 14-28

1/30/13 14 28

WO'll '" 14.28 .

EPA^SOSU.!;:

EPA 8081

EPA'SOSJ-'-

EPA 8081

EPAS081

EPA 8081

EPA 8081^

EPA 8081

EPA 8081

EPA 8081

EPA 8081

EPA 8081

EPA 8081

EP,A808I

EPA 8081

EPA808I

EPA 8081-

EPA 8081

E P . A ; 8 0 8 1 ;

EPA 8081

EPA'808i

Page 17 of 44 E130307,E130310OCPFlNAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

S a m p l e I D : G E I M W 2 9 D

Stat ion ID: G E I M W 2 9 D

Date Collected: 1/17/13 11:30

Lab ID: E130310-06

Mat r i x : Groundwater

.^umbe. •1 Htth't Re.'iults (Jt4iilffiers I.'It its MRI.

:72-54-8

72-55-9

50-29-3

309-00-2

319-84-6

5103-71-9

319-85-7

319-86-X

60-57-1

959-98-8

•33213-65-9

1031-07-,S

.72-20-8

7421-93-4

53494-70-5

58-89-9

5566-34-7

76-44-8

j(024-57-3

72-4V^

8001-35-2

4,4'-DDD (p,p'-DDD)

4 4 ' -DDL; (p.p'-DDE)

4.4'-DDT (p.p'-DDT)

Aldnn

alpha-BHC

alpha-Clilordanc

beta-BHC

dclta-BIIC

Dtcldnn

Endosulfan 1 (alpha)

Endosulfan II (beta'

I iidosiilian -Sulfate

Endrin

I ndnn aldolntio

Lndnn ketone

L'Jiiiina-lillC 11 indane)

gamma-Chlordajsg,

llept.ichlor

Heptachlor cpoxidel

MethowLlilor

Toxaphene

1.'23/13 9,30

1/30/13 14,42

' ^A!:' 'P.P ! 2-- n

0 -u

1 2 i 1 > ' 0

1 23'13 9 30

1 2 1 ) 1 ,

I 23 1 ! 9 )0

1 2 : 1 1 ) 0

I 23 13 9 30

1 2 , 1

1 2>13 9 30

1 in 13 14 42

1 " 1 1 144 :

t 28 13 l o o t

1 111 1 t ..z

I 30 13 14 43

1 11 11 14 42

1 10.13 14 42

1 '111 1 1 42

1 30 11 14 42

1 1 I ' l > u M i :

1 2) 11 9 3U

1/23/13 9 30

MTif t f ' " '> iO

' 2 1

1 23 i ! 9 30

1 21 1>

1 2 } ' !3 9 30

1 _,. 1,1

l,/23/0 9 30

1 .0 11 14 42

1/30/13 14 42

14 42

1 s 1 1 ' ) |

I 30 13

1/30/13 14 42

1142

1 ..0 1 .: 14 42

1,'30/13 14:42

EPA 8081

l,P,\snsi

E PA 801

[I'VSnsi

EPA 8081

r I'xsnsi

EPA 8081

I PX'illSl

EPA 8081

I i'\s(isi

t PA 8081

I P \ S ( I S 1

1 I ' X M I M

EPA 8081

EPA ROM

I I'VSIISI

hP\8081

EP\S(lSI

rp\808i

l.PAsnsi

EPA 8081

Page 18 of 44 EI30307,E130310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: G E I M W 2 9 L

Stat ion ID: G E I M W 2 9 L

Lab ID: El30310-07

Mat r ix : Groundwater

Date Collected: 1/17/13 11:20

< -I.V

Numlier 4nnfyte

"M---': - . K . , : ^ •

Sft-;.

A A • ;:•• - A m •

Resulti Qualifiers ,;.: If a', ': Untt\ ::[£, •• , :V:fm^::

mP: MRL'.APrepared ..fnalyzed .M.-thod:

72-54-8 : ^ i . r ; 4,4'-DDD.(p,p'-DDD)

72-55-9 4,4'-DDE (p.p'-DDE) - A ? - \ •••" • • ' T - ' ^ ^ T f V • • • . " ^ ? - ' i ' ^ : ' . - . • • • • • • •

50-29-3: i a i i j - ' 4,4'-DDT(p.p'-DDT), ,• ' ^ • i • • ' • • ' • i ^ M ^ M ^ ' ^ • • • • • • ^ M ^ ^ ^ • • • • • • • ' •

309-00-2 Aldnn

319-84-€r^ffl^alph£iilG--•

5103-71-9 alpha-Chlordane

3 I 9 - 8 5 - l ^ ^ ' b e t ^ M G | - " 7 "

319-86-8

60-57-1 ' ••

959-98-8

33173-65-9-•MH .,

1031-07-8

72-20-8 . . i S i 7421-93-4

53494-70-5

58-89-9

5566i34-7

76-44-8

1024-5,7-3

72-43-5

8001-35-2 „

delta-BHC

. Dieldnn

Endosulfan 1 (alpha)

-'i'EndosultSn:ll:(beta')

Endosulfan Sulfate

•• ,''EiSrin' PSP '" . . : . i . - M l . : „ „ , : ; i * : - , - ,

Endrin aldehyde

Endrin ketone-

gamma-BHC (Lindane)

ganima-Chloridane

Heptachlor

Heptachlor epoxide,

Methoxychlor

Toxaphene ;^, ':

Am:

- . : : ^ ^ i -

- .;£li^-.^.

''WP

m\

o;o4o u 0.020 U

• ^ • ^ • : •• •

0:050 U

0.020 IJ

O^Oli) Ll •=,ZV,:

0.020 Ll : - r r ^ , :

0.020 U - - , • ( * • ; .

0.020 U

0.020 U

0-04ff|tr

0.050 u

o.04a^ . : .U,22 :

0.050 U

0.050 U

0.010 u

0.020lu

0.015 U

^b.O20.0

O.IO u

" 1,2.0 iP

:Am.

'P'WIM' —iAyi ii£S^Aiy.

'mm-'

_...'.w-i.;iJj^

m. •• ' . ' i^.^. '^^p'

P.Z.^m^....

'W^

m

ugfl. ; ; ;

ug/L

ug/L fY

ug/L

Ug/L

ug/L^;,^

ug/L

ug/lF-:-'

ug/L

ug/L.',':'

ug/L

ug/T2 • • •

ug/L

ugrtjfts;

ua/L

• :^^: . ,,„.^2i;,„

U g / L

1 ug/Llfv U g / L

,:§: ug/L ,fj:,^

0.04^"

0.020

o.o5,a-0.020

QMO^I

0.020

.alMi!.:::

0.020

M2(y . ,ii,U,s;.,i,i

0.020 • • ^ " ( • r > „ -

0-OJO.

0.050

. j ; U * i : .

0.050

PMo. „ , . . i a ^ „ : . ,

O.OIO

I/23/I3 -9 ,30

1/23/13 9 30

1/23/13 9:30

1/23/13 9 10

"ini/iy' 9:30

1/23'13 9,10

I/23/I3 9:30

1 /23/13' 9,30

l /23/i3"-9:30

1/23/13 9,30

1/23/13 "• 9:30 -

1/23/13 9 10

, ! /23/ l3 • 9:30 ,

1/23/13 9 30

l/2J/i '3 " 9:30

1/23/13 9,30

1/30/13 .- If."

1..10/13 14 57

^1/30/13 , ' 14:57

1/30/13 14,57

• -;:r-«-|i|«--

EPASOSLt^'; .••.:..:i^ih^.iW j . . . . . .

EPA 8081

•'•'i:;«w-s;-":'-EP^SOSt

EPA 8081

5:i5'!:i/30/13 ::,;;s* H:57 _

1/10/13 14:57

f|PT iiioin

1/30/13 14:57

-'EPA:8081 ..Ji:SA?":i:-:-

1/30/13 .. ' ' ' : 5 ' '

1/30/13 14:57

' 1/30/13 14:57

1/30/13 14:57

1/30/13" 14:57

1/10/13 14:57

1/311/13" 14:57

1/10/13 14:57

0.020;

0.015

0-mP • . : :s iS:L

O.IO :-:-:rf^^:-• • • ' 2 : ( X V

1/23/13 9:J0

1/23/13 9,30

1/23/13 9:30

1/23/13 9,30

1/23/13 : | 9,30 •;:

, mw\3 14:57

1/10/13 14:57,

1/30/13

1/30/13 1457

Bl'ioo/u % | . ; ! , 4 : 5 7

i f C T A ' M S l •

E P A 8081

|EP/isoai

E P A 8 0 8 1

, :E iA ,8d8 l

EPA 8081

'"iEPAksi

:»&:-,-, EPA 8081

W ^ ^ " ' ' « , ,*EPASp8! . mt-i:.'-.: . . . .

EPA 8081

,'ip/y808i , . : - ^ . ^ . . • : . : : . . : . .

EPA 8 0 8 1

, E P A % 0 8 i . .:.'.Si&S^i&..:...

EPA 8 0 8 1

" •• ?-^,imt^^-.-- -EPA:8,081

.:'-,S4

1

• ^ii^.

, : | l l l

Page 19 o f 4 4 E130307,E 130310 O C P FINAL 02 2 0 1 3 1 7 0 6 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens. Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater- Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: SD-01

Station ID: SW-01

L a b ID : E 1 3 0 3 1 0 - 0 8

Matrix: Sediment

Date Collected: I/I7/13 15:35

'CAS ( .

Number Analyte Results Qitnlij'tiirs Units A', MRL ftepared Analrtid -Method-

72-54-8,

72-55-9

50-29-3

309-00-2

3I9-84-6 :A:„ 5103-71-9

3^ ,85-7 : •;

' 4.4'-DDD (p,j)'-DDD)

4.4'-DDE (p.p'-DDE)

4;4'-DDT (P ,P ' - 'DDT)

Aldrin

alptia-4}HC

alpha-Chlordane • l ^ i ^^S?:? : : •

beta-BH© ' • ' » ;

319-86-8

^- i - \PA." S i i,ixAi,- „

959-98-8

3^:3-6^^: - : : ...:fe..h.....:.^f£.iR.i-i:::...

1031-07-8

''•^X, 7421-93-4

delta-BHC

Dieldrin , '•:

Endosulfan 1 (alpha)

Endosulfan 11 (beta) • ,

Endosulfan Sulfate

; Endrin

Endrin aldehyde

53494-70-5 :"ig'Ehdrin,ketone%|:

58-89-9

5566-34-7 Si:. . 76-44-8

1624-57-3 :ih,.. . , , „ , „ . „ . 72-43-5

S31-35-2;.:-"

gamma-BHC (Lindane)

tm tm:^ ' : ^ . , •;v:;*SJf'' ,ganirna-Chlordane;is;

. , „ ^ ^ ^ , ^ J , : : , , „ • :.Sy:»f:-.:--

Heptachlor

Heptachlor epoxidelll ' ' • . ; ^ u : ^ ^ ^ ; , • . - • . • / : . ' M . U . - :

Metho.xychlor

Toxaphstie - f i '

iii,:

Ai-iiJi^:^ ••

• * : : , •

. • • 4 6 i y W '

23 U, 0-4

58 L L D - i

23 U. D-4

12 Ll.p-4^'' '

23 11. D-4

23U, D^ " "

23 l.l. D-4

- 23 U, D-4 l i

23 U, D-4

; 46 1J, D ^ - I '

58 U, I)-4

i;v 46 U, D-4 : [ ; • - "

58 U, J, D-4. f.)L-l

' •• '58 u . ' D - 4 " V . ;

16 11. D-4

'23.LCD-4

17 U. D-4

23 uH)-4

120 1.1,0-4

2300U;:iC| |

ug/kg'dry .

ug/kg dry

ug/kgdfy

ug/kg dry

ug/kg dry,

ug/kg dry

ug/kg dry-

ug/kg dry

ug/kg dry-

ug/kg dry

ug/kg do' '

ug/kg dry

ug/kg dry

ug/kg dry

• , ug/kg dry

ug/kg dry

;i ^ug/kgdiy

ug/kg dry

tig/kg diy

ug/kg dry

ug/kg diy

..•>ilB: :-5lSA

46 i

23

23

z 23

23 '

23

23;:

23

46-

58

46

58

58

16

- 1/23/13 ^ 8.19

1/23/13 S 19

P i / 2 3 / 1 3 , -mAi:i9. :

1/2.3/13 8,19

lHl/23/fs,"'' Ms?-'? •

1/2.3/13 8 |9

-'Ve: i v.BT

1/23/13 8,19

• ffcS:.2i . 1/23/13

8:19 V^,'2"3>!3"; sJtew'- ,

1/23/13 S 19

"UiAl'} 8;J» ..'

1/23/13 8:19

"• 'itiSnWf'

1/23/13 8 19

2/08/13 ' '3 . '3 , : ;

2 08/13 11 13

2mm}-', i3: i j^

2,08/13 13 13

2/OS/13-: 13.13;j

2nS'13 11 13

2/08/13 1313 ;j

2 08 13 13 11

2/08/13''

'?,IV.. 2 0S/I3

13 11

2/08/13'-13 13

2'0S/ll 13 13

2/08/13 13:13

2,'08/l 1 II 13

2/08/13 ^^13:13

2/08/13 13:13

•fpp'23

Pi])^'P;y'i . i i ^ ! . : . ..:

120 •:.'--;^'^.'V.A^i^^ • ••

f ]2300.

l/23/l£v||»M2/08/13-

,«:!»UlK:, '3^» 1/23/13 2/08/13

8:19 13:13 l/23/13K®::2/Cl8/i3

s.i9^ •:afei3:i3 1/23/13

8:19

l. '2.3/I3'-S'^ ,• S .19 : , : ^ ^

2/08/13 13:13

Tf/ds/u' :;: 0.12

EPA 8081-

EPA 8031

EPA 8081*

EPA 8081

EPA 3081

EPA 3081

;EPA80S1;

EPA 3081

EPA 8081:

EPA 8081

: EPA 8081

EPA 3081

:'EPA 8081

EPA 3081

EPA 8081

EPA 8081

EPA'ioSl

EPA 8081

EP^SOSl

EPA 8081

Ei%f8081

• iSiJi •

Page 20 of 44 EI30307,EI30310OCPFlNAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: SW-01

Station ID: SW-01

Lab ID: El30310-09

Matrix: Surface Water

Date Collected: 1/17/13 16:00

feii'V-^j^^a'^tfe"' 'P^fippppp ^Nifittbi'r70.^A(im-k^ ^ibZiSk^A-_l;x?mipnaj:::^ij^MiiiAA:il3biAL^

72-'54^5i' f- •''. '• 4,4'^DD (p.p'-DDD)-:."' '.

72-55-9 4,4'-DDE (p.p'-DDE) 0.021 U

:c'.l|/>--'-.ug/L.

ue/L ^l^pW 9 . 3 0 i 3 ^ C 15.11 'A . uiictA'.C',. -. ^^XP7 ''•-••

0.021

4,4'-DpT.(p,p'-DDtl

A l d n n

a lp i i a^C

alpha-Chlordane

f ? r - •" '-- j 'X 0.0521U \ifi:,, ug/L

309-00-2

319-8^6^""

5103-71-9

319-85p-^^>.. bela-BHCi

319-86-8 delta-BHC

60-57-1 ."."JWrlj-Dieldnn".'':-;.' • , a,r?i .„.'ii •, - , :, ..'a^a.-

0.021 U

o.fmyi

0 021 U

0.02 ryj 0.021 U

v'.0.021'=Uy;. ,:.X. i.,.,i,Cai,,i

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

Hfofo?!"

0.021

^i^ow;

0.021

0.021

Z6Ti'

1/23/13 930

"V23,'i^C^ S.JO.'.S^

1/23/13 9 30

' i/'237rnr: 9 30'^V,-,

1/23'13 9 30

' i /23/ l '3 ' ' ' : " ' ' 9-30;.;

i/23/13 9 10

1/30/13 1511 EPA 8081

'P ,Tf^ 1/30/13 |5 II

' i'3ij/73 15.11

1/30/13 15 11

1/30/13 .-•-t5IL

EPA

MEPA

EPA

EPA

8081

sus I

808 i

3081

808 i

'-A:

1/30/13 15 11 EPA 3081

1/23/13,-t', 1/30/13-, 15 Hi: EPA 8081;

959-98-8 Endosulfan 1 (alpha)

332l'3-65-9>:3sMEn"dosulfahII'(beta) " --•t^^.t— ". .-^-^--aif^!^^,:,:^ --.,- , , ^ . . , , , ' , - . . , .

1031-07-8 Endosulfan Sulfate

0.021 U ug/L 0.021 1/23/13 9 30

^>g/L •0:04 Iv ' ' 2 ^ ! ^ ^ : ; :

0.052 U ug/L 1/23/13 9 30

'(^"(l^EPA'808lSU-;:

EPA 3081

- ^ . ' . M ^ ' ' . ;J'**' i j tr", '^',"- ' ' ^^r^r-r-rtt!---- -! j'.i''-..-. *>".'a"i'.;i'v li'Hi'Ty'j'-' irsi"-

; ":;;ISK;/\;^0:041;.iySsj^ :^ Pni '

0 . 0 5 2 9 30 |5 n C i m QUO 1

'ZoM^^'^f^^^p^^^mfW - ^ : . . ? •,:„ '..„ •---i.„«-r ;•'.'. ,f M».:^..P.:.' '.-»•: ,fa-S'--., vf-fT-'-» r:

0 0 5 7 " P i ' J 1(30/13 £p^8Q8 ,

72i2038.%^:t;i-¥Ehdnn P;- - ^'lA-lA- ' ' > i ^ : v ; -- J

7421-93-4 Endrin aldehyde

fflEndrin ketone'

0.052 U ug/L 0.052

;i^'I-o.052|uL, .-A,^i-',i,, - fA:.,f

;:-vs 0.010 u

Ug/L 0 , 0 5 2 r/jo l's 11 EPA 8081

....11 n n i r v 1/23/13 1/30/13 , - „ . „ , . „ .

5566?34-7 ::gamma-Chlordane:i-; • .- •v/-y:fe^,: ..Mjii^i^::... Pm..........

76-44-8 Heptachlor

•ys^^.-^-r;-,':- «r^r^^,-••---^-^^T^^rr:"-

."'^^^^£:_"^'''?^-f^?'*^:, 72-43-5 Methoxychlor

tig/L 0.010 "5/(1,' '(^5<

ip^'ugi'^ri|psr^''^s~"^ -iiWi*.-; :• j,i^ili&MK!s,.u„.:. ,i>..ii.£i;^i i l i .

Ug/L 0.015 " J ^ ' '( / "'••JiiSio}! • •WB^Tl'' ' ' 'Ai^2}inA''' ' 'Aiu

EPA 8081

-Toxaphene: Nfct-

1/30/13 15 II

•'30/'-5 I

AO'-Y ""EP.ASOSr 1 J 1 i

"'(l^ffl^EPAaoiiri",'

•j ,"]! EPA8o7l

Page 21 of 44 E130307,EI30310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: SD-02

Station ID: SW-02

Lab ID: E130310-10

Matrix: Sediment

Date Collected: 1/17/13 15:05

Page 22 of 44 EI30307,EI303IOOCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: SD-902

Station ID: SW-02

Lab ID: E130310-11

Matrix: Sediment

Date Collected: 1/17/13 15:05

Page 23 of 44 E130307,E1303I0OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: SW-02

Stat ion ID: SW-02

Lab ID: E130310-12

.Matrix: Surface Water

Date Col lected: 1/I6/I3 16:52

C'l.V

Number .4iiiilyte.%";.: Results. Qtinlijiers Units •MRLA:. Prepared Uialyz:ed .Method • ' • - ' " - - - • ? > - " ' J - ' ! : '2 ' . -

72i54-S • J ; > - D D D ( ^ p ^ D D |

4.4'-DDE (p.p'-DDE)

,4,.4'iDpT (p.'p'iPPT)-'.:

!2^^»L 1/30/13 ,15.21i;

0.020 U 0.020 1/23/13

9 30

E"PA8081^- ;3 . .',.'-

T-*F-—'-TTt'^Ttr ug/L' JiMiMal'*-''' -'

1/30/13 15 26

'15:26;; -. S^A 8081 -Iiitg*£iiiT-£M'^>*h..X*>i

0.020 U

0.010 U

0.020 U

^ 2 0 U

ug/L

ug/L

ug/L

'-T -V-ug/L- -.......t^.i':,,.^.-..,!.--:

0.020 V^J

0.010 .1/23/13-r- 9'30 :

0.020 '?,;[;

delta-BHC 0.020 U ug/L

0.020 " ^ ^ ^ ^ ^ •

0.020 1/23/13 9 30

1/30/13 15 26

l/3'o/l'3 15-26

1/10/13 15 26

1/30/13 15:26 ^

1/30/13 15 26

EPA 8081

EPASOSn

EPA 8081 .-. ... —,—.,., EPA 8081 i

EPA 8081

60-57-1 b^ - i ; ' ••;' Dieldrin"-" AtAMi., A ' : -?•••' .£' ajjj—?3.-Li,'i^;jL:u.2:^'^:. , ' , . - ;n '^ ,^ , :F ,a^ .Ti : - - . : ' -M , . i i ;

: ; j ' - ^ ' ; .V? ; . . •;,,u»l..', • 'lifrnnl'-^'-' 1/23/13".-*i 4' .'j.E,PA.8081Vjsi.i-;,-3V-r' . l i . ^ / i , S , „ I->,lh^f.wn1fm„ 1,1< ^ ' ^ i , J^.i.:

1/30/13 15-26-

Endosulfan 1 (alpha)

Endosulfan II (beta)

Endosulfan Sulfate

Endrii)'=ff-1-. _- - , ." .^. . : , .„-

0.020 U ugfl. 0.020 1/23/13 9 30

-^-yw-

Endrin aldehyde

0.040 j l^;

0.050 U

^0.040 U

0.050 U

ug/L

0.040'

0.050

1/23/13 9.30

1/23/13 9 30

:^0.040: w: 1/23/13 >.9.30 .

ug/L

'-•' -Endrin ke tone-^^nt - ., ••'m.i-i'o.o5a?ir;\,r?i> ..v^T'rtnS m.2j;jiE^a^ai2fc;:aa

tr:i? sfug*.; LLu

0.050

•oTosF

1/23/11 930

1/30/13 15 26

*J730/T3~ M.5 26: :

1/10'13 15 26

l/Sft'lS IS-26

1/30/13 15:26

EPA 8081

EPA 8081V

EPA 8081

ElVVSOSI

EPA 8081

"~i^3/t3.'^PT/-Wi3';" " ;.St5:26i., ':9-3ff|

58-89-9

5566=3427.-

76-44-8

l024"3'7-3;

72-43-5

8001-35-2. • •f^^ri;. •

gamma-BHC (Lindane)

-;eamma-Chlbrd.anC;

Heptachlor

Heptachlor epoxide

Methoxychlor

O.OIO U ugA. 0.010 1/23/13

9 30

- - ^ ' i * - - , - o;o2a.u^' ••:'^r/\x<^ 0.020 ' :Ei^F-0.015 U

0.020'u'

O.IO IJ

Ug/L

ugiol.

ug/L

0.015

6.020

0.10

1/23/13 9 30

1/23/13 9 30

1/23/13 9:30

' PS^^^ ^-mp,. "Sh '•r2.o,u =3 :,^>-.^ •-.sir2.i

1/23/13 9 30

Page 24 of 44 E130307E130310 OCP FINAL 02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater- Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: •SW-902

Stat ion ID: SW-02

L a b I D : E 1 3 0 3 1 0 - 1 3

Mat r ix : Surface Water

Date Collected: 1/16/13 16:59

' ' ' ~ . ? i j s i • ' A M '

N u m b e r . ' , - - i i : . . inal \ te9! ' • ri-'i'ii ' •jj- : : ^ . : -^ : : : . A . . - f . A ! : H i A --•:.• : ' ^ A :

•\*^Jf : ? • Z ' •••• ^ n

Units:)^^.-'- •:. ' MRl:i • PreparedA- .-tiialyzedf .Method' .- ''.-j ='.' .' „

.yf4.4'-DDD(p;p'.rDDD)" ' ZZMKM'PJ''-Z'?'^Z!Mi^^.' '^^M:.o'.o4o -J '• .j-a's sAti., ,- ,. •...^;j:kiiA....u i.mfc.2.:.^ 2. :

72-55-9

S0-.29-3,

3O9-00-2

4,4'-DDE (p.p'-DDE)

i 4,4'-DDT([SJj3'-DDT)

Aldnn

319-84-6';..•.,;• i.'-.alpha-BHC-,.'

5103-71-9

0.020 U

o.osTu

0.020 IJ

'oBio'\JPMM

ug/L

ug/L

ug/L

U g / L | ; , , . ' - ,0 .010 .

0.020

' j Z 0.051 . 0.020

1/23/13 ' ^^9 - j lo - . ,

1/23/13 9 30

'•|7i37l3' ,:9.30

1/2.1/13 9 30

•--;'l/30/13--

1/30/13 15 40

sEPA

EPA

^ 3 " ^ , E P A

EPA

1/23/13 : - 9 30:

j(i *iV30/13 " t S & | 3 40,-.

^•a,,*iF;jnr„ EPA

8 0 8 1 ; . -

8031

8081; :•

8081

8081 ..

alpha-Chlordane 0.020 U —jMW(™»i~3W' -^"" -;: •"iWM!>p^*'V!'7*g""^J-L'*t3':"-*'^'

319-:85-7-i:-: . - :4betji'-BHC^''«f -I ' ^^fri-1'' 'r .1= •. .1 -,_ „.f. i lrc:f^..• ' TlA-iH -n

•"r;:i/A'A.-'-:rM ..l:Mi.(-'-:.li#:- o.o2o;'U"-'-T.'';.-.

ug/L 0 020 1/23/13 9 30

1/30/13 15 40

: 'W.i'ionmAFPA 8 0 8 1/23/13'

' 5 9 - 3 0

319-86-8 delta-BHC - -:^n':

60.-S'7-l

959-98-8

33.2D^65-9'

1031-07-8

^ipieldrin ' k

Endosulfan I (alpha)

2;Ehdosulfan ]l'(beta)

Endosulfan Sulfate

0.020 U

o.oioli

0.020 U

o.oJcTij

0.051 U

1/30/13 15 40

1/30/13'ri ?15 '40J- ,

EPA 8 0 8 1

EPA soar;

8081 EPAS

,,-$5fel/30/13,:,: pp . ,-;-g;,l_5.4(j i; •. '7'^"

1/30/13 Tp^" 15 40 •^'^'^

808 r

72i20-{S' ; s ^ ^ : E i i a r i n ^ V ,> r^.t£';i - ' ' i ^ ' k A ; - . ^ m ^ A A -ik.....d.:J:-^i..J..^~.:.MSSi^.: .-j^l^,.....^: . .',-?'t%,;fe?.^-,'aii;-,,-,::..

Endrin aldehyde

-—-34 J^^::f:^'^^.^^^•L-•':'^.:,,?^"i"^^'^^'=|'.t:^^"<^.;^^..^'•.F^^.v^ •..^;...,..,.. ••0.040^ ur; , i^s:*;?rf^^". :Ja 'yjgf t-^H:V^*^p:040. i ' P , ' , • ' -•'-f^ * •* ' • • ' - ^ -^^ f l t i 11 -jirii- r •• :iiJ:^iifeiiff'i ' . ' 'rim • : l .nITJ <n?iaiMTiiTfei mrL - .— ^T^.^^

• " ' - IA 1 S ; 4 0 * V „ K ^ -1/23/13,

8081 ;-4-;V*i|i?:'

7421-93-4

53494^70-5='

58-89-9

55663'4-7 -"=,

Endrin ketone -I-'

gamma-BHC (Lindane)

0.051 U

• ^ 0 5 1 m

gam'rfiatChlordane (-',- • '^'S' -'

O.OIO Ll

PoMoWi-.

ug/L

^ug/L

ug/L

0.051

T05l' O.OIO

1/23/13 930

"iVij'/B " - ; , 9 30

1/23/13 9 3 0

EPA

1.'30/13 : 15 .40 . '

1/30/13 15 40

:EPA

EPA

8081

8081

8031

';Tir^

ug/L ( i o:o2oj _",l3-'40?,V.t2EPA8

76-44-8 Heptachlor -•f- -• •r". ' 'T—?r t.»v •...,...,.,MJ',j.' .g<r-T -rr—i:y7f—;'.•:' j*t : ' .^^^,IA•-• i, , , ,, t«* 1024^-57-3' •• r^Heptaclilor'epoxide:- ,*.T/•-.•:thiW''>-K-'s-J"-'"-

72-43-5 Methoxychlor

0.015 U ug/L 0.015 1/23/13

9 30 EPA 8081

..u,.....^.u.^..„.j,,^,f,^,^....,^^.i.„.u^r,.r.^

. '0:020: Ur ' : ; -S ;y&'k" ;ugps^^:"-mp:o20 i 1/23/13' -:-9-302! 'iEPA 8081'.

0.10 Ll

SOOII.35-; •^Toxaphene 2;o u

Ug/L 1/23/13 9 30

"i/BTiir 9.30,

1/30/13 15:40

"T/IO/LT 15,40 EPA ,808)',

Page 25 of 44 E 1 3 0 3 0 7 , E 1 3 0 3 I O O C P F I N A L 0 2 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700

D.A.R.T Id: 13-0162

Project 13-0162, Aberdeen Groundwater- Reported by Jason Collum

Organochlorine Pesticides

Project: 13-0162, Aberdeen Groundwater

Sample ID: SD-09

Stat ion ID: SW-09

Lab ID: E130310-

Matr ix : Sediment

14

Date Col lected: 1/17/13 14:45

C-I.V •,^k> •.yu'niber.-'-ftTl'.A- Analyte

• » - ' . • • ' . ;<.*?»:- . - : - : • , . ! ' : . ' . - .

'4Ar^ :&&<,:. ,

:>^>;...: - • ' - . i f t S ^ - - ' . '.Riisiitts^Qiihlifiers .: „:.?i'^ • i ••-:!^«S^-,"-.--. •;-?:•' ' . - ; :v ' --- i '*,- ;- .- . ' ' • i ; A ' "

•JnZ^Z- . . ... '-i.l7itii^&.p...'"j MRLp • >:^-U~a%£'•,-,--.• '.; A

AmP-:J •' , 'A-0T- " A ' W r - ^ i •Prepared : 'AmdyzedR'.Melhod .-.-"i , ^ % S i : h

72-54;8 ;,:.,•:::

72-55-9

50-29-3

309-00-2

319-84.-:6

'p4'A?DW{pp-UaSZ

4.4'-DDE (p.p'-DDE)

4,4'-DD'F(p|'-DDT) "•

Aldnn

~?rph£iHC~*'^^a'. '

'..Ij-.'H'S^g^" •2 .2 .1J

'A£1.

i£i- S*::h.i,:

lig/kg'dry

ug/kg dry

jug/kg dry

ug/kg dry

,u&1cgaoB:J?"^,^^'o.56 ,n„.,/-„.,M.„ „ . i^ , i , iagB. ' :^ i>t f r^r -,n,... . .

- . '"tzZ': 1.1

- ^ • - • " :

1/23/13 -:;-j*2/08/13v4 •- 8 19 2l£! . i J i i ' "

1/23/13 S 19

. 1/23/13

.. 8:19 I«3/I3

» 19 •

T-'iS/TF ' -- .8'„l?,f^5.

2/08/13 14 08

J.'iis/fs'v 1408 ;;<

2/08/13 14 OS

•^i'mStT' . -.14 08

•EPAS()8 i ia j , ; r= '

EPA 3081

EPA 8081:-:"" -

EPASnsi

i EPA 3031-

5103-71-9 alpha-Chlordane l.l U ug/kg dry 1.1 1/23/13

8 19 2/08/13 14 OS EPA 8081

319J5-7

319-86-8

60-S7T-

959-98-8

33213-65-9. '» l

-^'^•'DuA'-~i-'*'-i •> -'- -.AAVt—^- --:- : ; f r f e - . i - : - ,r% :,'.s*sd--.;.-:.Un.i;, "...Slia... -.if.t.ai.':,„.r. ,.,-, • •.:-:.;i&.C...-:....',t;S,:t,s',i,;,i,-i-a. ,:=.

" jugkg 'd jy j^ j •;;.'•..'" ' • ' ' ' ' '

del ta-BHC

Dieldrin

Endosulfan I (alpha)

K:ndostilfaii;il-(beta) ...PS^^

1.1 u

I.I u

ug/kg dry

1031-07-8 Endosulfan Sulfate U

ug/kg dry,';;

ug/kg dry

_'u&1cgciry'

ug/kg dry

l . l

1.1

1/23/13-^.. r'8-19 -,,.' 1/23/13

8 19

fSi/iT' :8 19 ?;;

l/2'37l3 8 19

2/0S/13J" —'•' '°ia

2/08/13 14 08

2/08/13' 14 08

2/08/13 1408

.^2:3. ' l"/23'/13^':W£'ti8/l S"':' 8.l9^^^j^%14:08:;

1/23/13 8 19

2/08/13 14:08

EPA 8031

*EPA80ai'--

EPA8031 —mri^ :'-. ;E.PA,SO8Ii :

EPA 8081 '

• • •2 .3 'U ' ; . - ssr ;:ug/kg'dry;;;.>^^f^;.g3 -' '•1/23/1 i i iM?2m! \ iAM

. . - . - - . r r f S ^ . - . . — • •

5349,4i;70-S . - . - 4 f e ^

58-89-9

TsePPPi-piP

Endrin ketone ':'".'

gamma-BHC (Lindane)

76-44-8

gamma-Chldfdane

Heptachlor

2.8 U. J, QL-I

" ^ J Z Z 0.56 U

zIll^M 0.84 U

2.8 ug/kg dry

. u ^ g d r y

ug/kg dry 0.56

':^^-8 '

ug/kg d o ^ f ^ ^ 1.1

ugrtcgdry 0.84

1/23/13 8,19

•"i/23"/"i3' 819

1/23/13 S, 19

"imfiT'

1/23/13 8 19

2/08/13 14 08

14 082; 2/08/13 14 08

"SSi/n^ _ - ] 4 _ 0 8 ^

2/08/13 14 OS

EPA 8081

EPA'SlDSi:

EPA 8031

:EPAS081

EPA 8031

1024 ?11F rrTTT<!t!rr;^?i •.-l.-;U':s.."'ji>|i'.'..-: ugrtcg-dry:!* .:.' .-';-', )..-i:

. . . .-^.,r,'^,r'V.-T^f::fi,^-|fil,i.li ' 1 ' .<: ; E P A 8 0 8 I "-i,:.;-.^>. .Heptachlof epoxide

i :.:--:^.iii:.fi,.....i : ' - P : 1/23/13 K1,Ti ;2/b8/f3- '

H ; 8 , 1 9 } "•»14:08";

72-43-5

8"oai735-:

Methoxychlor

::;Tbxaphene " ^ . • ^ P T :

mi '•'Afi:

5.6 U

U O U

ug/kg dry 5.6

•'lig^gdryW^lfllb"

1/23/13 8:19

2/08/13 14 08

1/23A3.-:-:- 2/08/13 •8.19 S ; . - 2 16

EPA 8081

EPA 8081

Page 26 of 44 E130307,EI30310OCPFlNAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

Analyte Result Reponing

Limit Units Spike Source "'oREC Level Result "oREC Limits RPD

RPD Limit Notes

Batch 1301071-E 3520 LLE

Blank (1301071-BLKl) Prepared: 01/22/13 Analyzed: 01/29/13

EPA 8081 alpha-BHC

alpha-BHC [20]

gamma-BHC (Lindane)

gamma-BHC (Lindane) (20)

beta-BHC

beta-BHC [2C]

delta-BHC

delta-BHC (2C]

Heptachlor

Heptachlor [2C]

Aldrin

Aldrin [2C1

Heptachlor epoxide

Heptachlor epoxide [2C]

gamma-Chlordane

gamma-Chlordane [2C]

alpha-Chlordane

alpha-Chlordane [2C]

4,4'-DDE (p,p'-DDE)

4,4'-DDE (p.p'-DDE) |2C]

Endosulfan 1 (alpha)

Endosulfan I (alpha) [2C]

Dieldrin

Dieldrin [2C]

Endrin

Endrin 12C1

4,4'-DDD (p,p'-DDD)

4,4'-DDD (p,p'-DDD) [20]

Endosulfan 11 (beta)

Endosulfan II (beta) [2CJ

4.4'-DDT (p.p'-DDT)

4.4'-DDT (p.p'-DDT) [2C]

Endrin aldehyde

Endrin aldehyde [2C]

Methoxychlor

Methoxychlor [2C]

Endosulfan Sulfate

Endosulfan Sulfate I2C]

Endrin ketone

u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u 0

O.OIO

0.010

0.010

0.010

0.020

0.020

0.020

0.020

0.015

0.015

0,020

0.020

0.020

0.020

0.020

0.020

0.020

0.020

0.020

0.020

0.020

0.020

0.020

0.020

0.040

0,040

0.040

0.040

0.040

0,040

0.050

0.050

0.050

0.050

O.IO

O.IO

0.050

0.050

0,050

ug/L U

U

U

U

U

U

U

U

U

u u u u u u u u V

u u u u u u u u u u u

. u u u u u u u u u u

Page 27 of 44 E130307,EI303IOOCPF1NAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 '

D.A.R.T. Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Endrin ketone |2C]

To.xaphene

Toxaphene I2C|

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

u

u

u

0,050

2,0

2,0

ug/L

" "

.Analyte Result

Reporting

Limit Units

Spike Source "-'oREC

Level Result %REC Limits RPD

RPD

Limit Notes

Batch 1301071-E 3520 LILE

Blank(130107T-BLKl) Prepared; 01/22/13 Analyzed: 01/29/13

LCS(130I071-BS1) Prepared; 01/22/13 Analyzed; 01/25/13

EPA 8081

alpha-BHC

alpha-BHC [2CJ

gamma-BHC (Lindanel

gamma-BHC (Lindanel |2C1

beta-BHC

beta-BHC I2C]

delta-BHC

delta-BHC [2C|

Heptachlor

Heptachlor (2C1

Aldrin

Aldrin |2C]

Heptachlor epoxide

Heptachlor epoxide (2CJ

gamma-Chlordane

gamma-Chlordane |2C1

alpha-Chlordane

alpha-Chlordane |2C1

4,4'-DDE (p.p'-DDE)

4.4'-DDE (p.p'-DDE) 12C]

Endosulfan I (alpha)

Endosulfan I (alpha) |2C1

Dieldrin

Dieldrin |2C|

Endrin

Endrin [2C1

4.4'-DDD(p.p'.DDD)

4.4'-DDD (p.p'-DDD) I2C]

Endosulfan II (beta)

Endosulfan II (beta) |2C|

4.4'-DDT (p.p'-DDT)

4.4'-DDT (p.p'-DDT) |2C1

Endrin aldehyde

Endrin aldehyde 12C]

0.15220

0.14965

U

U

0,29550

0,29390

0,31515

0,30705

U

U

U

U

U

U

0.31220

0.30705

0,31685

0,30800

0.25415

0,25240

U

U

u

u

0,69005

0,66615

0,66595

0,62945

U

U

U

U

U

U

0,050 ug/L 0.20000

0.050

0.050

0.050

0.10

O.IO

0.10

O.IO

0,075

0,075

0.10

0.10

O.IO

0,10

O.IO

OIO

0,10

0,10

O.IO

OIO

0,10

0,10

0,10

0.10

0.20

0.20

0.20

0.20

0.20

0,20

0.25

0.25

0.25

0.25

0,20000

0,40000

0.40000 ,

0.40000

0 40000

0,40000

0,40000

0,40000

0.40000

0,40000

0,40000

0,80000

0,80000

0,80000

0.80000

76.1

74.8

73,9

73,5

78.8

76,8

78.0

76.3

79.2

77.0

63.5

63.1

86.3

33.3

83,2

78.7

45-85

44-88

27-105

28-105

45-105

43-108

55-90

55-92

14-110

16-111

24-95

23-95

28-112

30-113

45-101

49-102

48-100

49-101

39-85

38-88

30-108

32-108

36-105

39-104

50-114

52-III

53-97

52-99

39-1.32

40-129

21-108

20-103

36-130

22-153

Page 28 of 44 E130307,E130310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Methoxychlor

Methoxychlor [2C]

Endosulfan Sulfate

Endosulfan Sulfate [2C]

Endrin ketone

Endrin ketone [2C]

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

u u

093685

0,89560

1.0192

0.97015

0.50

0,50

0,25

0.25

0.25

0.25

ug/L

" " -" "

1.0000

1.0000

1,0000

1,0000

93.7

39.6

102

97.0

41-121

34-133

68-103

68-103

69-102

62-112

/Vnalyte Result Reporting

Limit Units

Spike Source "i,REC Level Result %REC Limits RPD

RPD

Limit Notes

Batch 1301071 - E 3520 LLE

LCS(1301071-BS1) Prepared: 01/22/13 Analyzed: 01/25/13

MRL Verification (t30I071-PSl) Prepared; 01/22/13 Analyzed: 01/29/13

EPA 8081 alpha-BHC

alpha-BHC 12C]

gamma-BHC (Lindane)

gamma-BHC (Lindane) [2C]

beta-BHC

beta-BHC [20]

delta-BHC

delta-BHC [2C]

Heptachlor

Heptachlor [2C]

Aldrin

Aldrin [2C]

Heptachlor epoxide

Heptachlor epoxide [2C]

gamma-Chlordane

gamma-Chlordane (2C]

alpha-Chlordane

alpha-Chlordane [2C]

4,4'-DDE (p.p'-DDE)

4,4'-DDE (p.p'-DDE) [2C]

Endosulfan 1 (alpha)

0.0077900

0.0065600

u u

0,014120

0.010330

0.015590

0.012050

U

u u u u u

0.015400

0.014330

0,014970

0,013350

0,015030

0.011960

u

0.010

0.010

0010

0.010

0.020

0.020

0.020

0.020

0.015

0.015

0.020

0.020

0.020

0.020

0.020

0.020

0,020

0,020

0.020

0.020

0.020

ug/L

"

" -"

' •

••

••

" " ••

" " "

-

••

-

"

••

"

0.010000

0.010000

0,020000

0.020000

0.020000

0.020000

0.020000

0.020000

0.020000

0,020000

0,020000

0.020000

77.9

65.6

70.6

51.6

78.0

60.2

77.0

71.6

74.8

66.8

75.2

S9.8

48-92

42-94

30-105

35-113

30-117

31-115

56-89

33-118

12-141

41-100

29-104

20-132

30-117

40-115

44-104

30-128

46-97

42-100

50-113

44-123

30-125

MRL-2, MRL-8,

U MRL-2. MRL-8,

U

U U

MRL-2, U

MRL-2, U

MRL-2, U

MRL-2, MRL-8,

U U

u u u u u

MRL-2, U

MRL-2, U

MRL-2. U

MRL-2, U

MRL-2, U

MRL-2, U

u

Page 29 of 44 E130307,EI30310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

Endosulfan 1 (alpha) |2C)

Dieldrin

Dieldrin |2C1

Endrin

Endrin [2C|

4.4'-DDD(p.p'-DDDl

4.4'-DDD(p.p'-DDDi|2Cl

Endosulfan II (beta)

Endosulfan II (beta) [2C]

4.4'-DDT (p.p'-DDT)

4.4'-DDT (p.p'-DDT) [JC]

Endrin aldehyde

Endrin aldehyde [2CJ

Methoxychlor

Methoxychlor [2C1

Endosulfan Sulfate

Endosulfan Sulfate [2C]

Endrin ketone

Endrin ketone [2C]

u u u

0.031300

0.029290

0.030810

0.028200

u LI

LI •

u u

0,040480

LI

U

0,047060

0.037620

0,047720

0,038850

0,020

0.020

0,020

0,040

0,040

0.040

0.040

0 040

0.040

0,050

0.050

0.050

0.050

O.IO

O.IO

0.050

0,050

0,050

0,050

ug/L

" " "

"

"

"

••

0,040000

0.040000

0.040000

0.040000

0,050000

0,050000

0,050000

0,050000

78,2

73,2

77,0

70.5

94,1

,75.2

95.4

77.7

44-130

54-123

50-109

47-123

44-127

64-125

53-134

38-155

47-148

26-143

26-135

54-153

31-210

33-129

37-135

52-124

58-125

50-134

41-135

.Anafyte Result

Reponing

Limit Units

Spike Source '!oREC

Level Result "'oREC Limits RPD

RPD

Limit Notes

Batch 1301071-E 3.520 L L E

M R L Ver incat ion ( I30I071-PS1) Prepared; 01/22/13 Analyzed; 01/29/13

U

u u

MRL-2.

U

MRL-2.

U

MRL-2. U

MRL-2,

MRL-8.

U

U

U

u u u u u u

MRL-2. U

MRL-2.

U MRL-2.

U MRL-2.

U

Batch 1301082 - E 3,520 LLE

Blank (1301082 -BLK l ) Prepared: 01/23/13 Analyzed; 01/30/13

EPA 8081 alpha-BHC

alpha-BHC |2C1

gamma-BHC (Lindane)

gamma-BHC (Lindane) [2C]

beta-BHC

beta-BHC [20]

delta-BHC

delta-BHC 12C1

Heptachlor

Heptachlor |2C]

u u u u u u u u u u

0,010

0.010

O.OIO

0,010

0.020

0,020

0.020

0,020

0,015

0,015

Ug/L

Page 30 of 44 E 130307,E 130310 OCP FINAL 02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

Aldrin

Aldrin [2C1

Heptachlor epoxide

Heptachlor epoxide [2C]

gamma-Chlordane

gamma-Chlordane [2C]

alpha-Chlordane

alpha-Chlordane [2C]

4,4'-DDE (p.p'-DDE)

4,4'-DDE (p.p'-DDE) [2C]

Endosulfan 1 (alpha)

Endosulfan I (alpha) [2C]

Dieldrin

Dieldrin [2CI

Endrin

Endrin [2C)

4,4'-DDD (p.p'-DDD)

4,4'-DDD (p.p'-DDD) [2C]

Endosulfan 11 (beta)

Endosulfan II (beta) [2C]

4,4'-DDT (p.p'-DDT)

4,4'-DDT (p,p'-DDT) [2C]

Endrin aldehyde

Endrin aldehyde [2C]

Methoxychlor

Methoxychlor [2C]

Endosulfan Sulfate

Endosulfan Sulfate (20)

Endrin ketone

Endrin ketone [2C]

Toxaphene

Toxaphene [2C] •

u u V

u u u u u u u u u u u u u u u u u u u u u u u u u u u u u

0.020

0.020

0,020

0,020

0,020

0.020

0,020

0.020

0.020

0.020

0.020

0.020

0.020

0.020

0.040

0.040

0.040

0.040

0.040

0.040

0.050

0.050

0,050

0.050

0.10

0.10

0.050

0.050

0050

0.050

2.0

2.0

ug/L

Analyte Result

Reporting Limit Units

Spike Source %REC Level Result %REC Limits RPD

RPD Limit Notes

Batch 1301082 - E 3520 LLE

Blank (1301082-BLKl) Prepared: 01/23/13 Analyzed: 01/30/13

u u u u u u V

u u u u u u u u u u u u u u u u u u u u u u u u u

Page 31 of 44 EI30307,E1303I0OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

EPA 8081 alpha-BHC

alpha-BHC |2C]

gamma-BHC (Lindane)

gamma-BHC (Lindane) I2C]

beta-BHC

beta-BHC (2C|

delta-BHC

delta-BHC I2C)

Heptachlor

Heptachlor [2C]

.Aldrin

Aldrin (2C1

Heptachlor epoxide

Heptachlorepoxide 120)

gamma-Chlordane

gamma-Chlordane [2C1

alpha-Chlordane

alpha-Chlordane |2C1

4.4'-DDE (p.p'-DDEi

4.4'-DDE (p.p'-DDE) 12C1

Endosulfan I (alpha)

Endosulfan I (alpha) |2C1

Dieldrin

Dieldrin (2C|

Endrin

Endrin [20]

4.4'-DDD (p.p'-DDD)

4.4'-DDDfp.p'-DDD)|2Cl

Endosulfan 11 (beta)

Endosulfan 11 (beta) 12C]

4.4'-DDT (p.p'-DDT)

4.4'-DDT (p.p'-DDT) |2C1

Endrin aldehyde

Endrin aldehyde f2Cl

Methoxychlor

Methoxychlor 120]

Endosulfan Sulfate

Endosulfan Sulfate [20]

Endrin ketone

0.13065

0.12315

u U

0.27900

0.26485

0.29775

0.27465

U

U

U

U

U

U

0.23415

0.26765

0.29245

0 27070

0.23620

0.22440

U

U

U

U

0,50700

0.56285

0,63795

0,57685

U

u u u u u u u

0,92080

0,84870

1,0231

0,050 ug/L 0,20000

0,050

0,050

0,050

0,10

0,10

O.IO

0,10

0,075

0,075

O.IO

0,10

O.IO

O.IO

0,10

0,10

0.10

O.IO

OIO

0,10

O.IO

O.IO

0,10

0,10

0,20

0,20

0,20

0,20

0,20

0,20

0,25

0,25

0,25

0,25

0.50

0,50

0,25

0,25

0,25

0.20000

0,40000

0,40000

0,40000

0.40000

0.40000

0.40000

0,40000

0.40000

0,40000

0.40000

0.80000

0.80000

0,80000

0,80000

1,0000

LOOOO

1,0000

65.3

61.6

69.8

66.2

74.4

68.7

71,0

66,9

73,1

6 7 7

59,0

56,1

,

75,9

70,4

79.7 ,

72.1

92,1

84,9

102

45-85

44-88

27-105

28-105

45-105

43-108

55-90

55-92

14-110

16-111

24-95

23-95

28-112

30-113

45-101

49-102

48-100

49-101

39-85

38-88

30-108

32-108

36-105

39-104

50-114

52-111

53-97

52-99

39-132

40-129

21-108

20-108

36-130

22-153

41-121

34-133

68-103

63-103

69-102

.Analyte Result

Reporting

Limit Units

Spike Source 'J'oREC

Level Result '!'oREC Limits RPD

RPD

Limit Notes

Batch 1301082-E 3520 LLE

LCS(130I082-BS1) Prepared: 01 /23/13 Analyzed: 01 /28/13

Page 32 of 44 EI30307,EI303IOOCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Endrin ketone [20]

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

0.93925 0.25 ug/L 1,0000 93.9 62-112

/\nalyte Result Reporting

Limit Units Spike Source "'oREC Level Result %REC Limits RPD

RPD Limit Notes

Batch 1301082 - E 3520 LLE

LCS(130I082-BS1) Prepared: 01/23/13 Analyzed: 01/28/13

Matrix Spike (1301082-MSl) Source: E130307-08 Prepared: 01/23/13 Analyzed: 01/28/13 EPA 8081 alpha-BHC

alpha-BHC [20]

gamma-BHC (Lindane)

gamma-BHC (Lindane) [20]

beta-BHC

beta-BHC [20]

delta-BHC

delta-BHC [2C]

Heptachlor

Heptachlor [20]

Aldrin

Aldrin [20]

Heptachlor epoxide

Heptachlor epoxide [20]

gamma-Chlordane

gamma-Chlordane [20]

alpha-Chlordane

alpha-Chlordane [20]

4,4'-DDE (p.p'-DDE)

4,4'-DDE (p.p'-DDE) [20]

Endosulfan 1 (alpha)

Endosulfan 1 (alpha) [20]

Dieldrin

Dieldrin [2C]

Endrin

Endrin [20]

4,4'-DDD (p.p'-DDD)

4,4'-DDD (p.p'-DDD) [20]

Endosulfan 11 (beta)

Endosulfan II (beta) [20]

4,4'-DDT (p.p'-DDT)

4,4'-DDT (p.p'-DDT) [2C]

Endrin aldehyde

Endrin aldehyde [20]

Methoxychlor

Methoxychlor (2C]

0.30278

0.27732

U

U

0,71392

0,66577

0.74907

0.69134

U

U

U

u u u

0.65608

2.6984

0,66402

0.61186

0,58907

0,55062

U

U

U

U

15108

1.3810

1.4799

1.3309

U

U

U

U

U

U

u u

0.10

0.10

O.IO

0.10

0,21

0.21

0.21

0.21

0.15

0.15

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.41

0.41

0.41

0.41

0.41

0.41

0.52

0.52

0.52

0.52

1.0

LO

ug/L

" ••

-" " " ••

» • " " -K

" " " " --" » " « " " " --« " " " 1

" "

041237

041237

0,82474

0,82474

0,82474

0.82474

0,82474

0,82474

0.82474

0.82474

0.82474

0.82474

1.6495

1.6495

1.6495

1,6495

U

U

u u u u u u u u u u u u u u u u u u u V

u u u u u u u V

u u u u u u

73.4

67.3

86.6

80.7

90.8

83.8

79.6

327

80.5

74.2

71.4

66.8

91.6

83.7

89.7

80.7

46-82

43-86

14-112

10-129

53-98

53-96

59-92

55-97

10-131

10-177

14-101

23-90

16-110

29-104

51-106

49-109

53-104

51-106

47-90

50-86

10-117

29-101

10-126

33-100

52-123

46-123

59-99

53-102

10-146

12-138

I M U

14-99

23-131

33-122

10-142

10-140

u u u u u u

X-2

U

U

u u

u u u V

u u u u

Page 33 of 44 EI30307,EI30310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Endosulfan Sulfate

Endosulfan Sulfate [20]

Endrin ketone

Endrin ketone [20]

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

1.9462

1.7841

2.0930

1.9212

0.52

0.52

0.52

0.52

ug/L

" " -

2.0619

2.0619

2.0619

2.0619

U

U

u u

94.4

86,5

102

93.2

66-108

62-108

63-106

54-113

Analyte Reporting

Result Limit Units Spike Source %REO Level Result %REO Limits RPD

RPD Limit Notes

Batch 1301082 - E 3520 LLE

Matrix Spike (1301082-MSl) Source: E130307-08 Prepared: 01/23/13 Analyzed: 01/28/13

Matrix Spike Pup (1301082-MSDl) Source: E130307-08 Prepared: 01/23/13 Analyzed: 01/28/13

EPA 8081 alpha-BHC

alpha-BHC [20]

gamma-BHC (Lindane)

gamma-BHC (Lindane) [2C]

beta-BHC

beta-BHC [20]

delta-BHC

delta-BHO [20]

Heptachlor

Heptachlor [20]

Aldrin

Aldrin [20]

Heptachlor epoxide

Heptachlor epoxide [20]

gamma-Chlordane

gamma-Chlordane [20]

alpha-Chlordane

alpha-Chlordane [20]

4.4'-DDE (p.p'-DDE)

4,4'-DDE (p.p'-DDE) (20]

Endosulfan 1 (alpha)

Endosulfan 1 (alpha) [20]

Dieldrin

Dieldrin [20]

Endrin

Endrin [20]

4.4'-DDD (p.p'-DDD)

4.4'-DDD (p.p'-DDD) [20]

Endosulfan II (beta)

Endosulfan 11 (beta) [20]

4.4'-DDT (p.p'-DDT)

4.4'-DDT (p.p'-DDT) [2C]

Endrin aldehyde

Page 34 of 44

0.33649

0.31186

U

U

0.71082

0.66763

0.75340

0.69588

U

u u u u u

0.68814

2.6955

0.70433

0.63526

0,59701

0.55969

U

u u u

1.5466

1.4040

14755

1.3322

U

U

u u u

0 10

0.10

0.10

0.10

0.21

0.21

0.21

0.21

0.15

0.15

0.21

0,21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.21

0.41

0.41

0.41

0.41

0.41

0.41

0.52

0.52

0.52

ug/L

EI30307,E130310OCPFINAL02 20 13 1706

0.41237

0.41237

0.82474

0.82474

0.82474

0.82474

0.82474

0.82474

0.82474

0.32474

0.82474

0.82474

1,6495

1.6495

1,6495

1,6495

U

U

U

U

u u u u u u u u U

u u u u u u u u u u u u u u u u u u u u

81.6

75.6

862

81.0

91.3

84.4

83.4

327

85.4

77.0

72.4

67.9

93.8

85.1

89.4

80.8

46-82

43-86

14-112

10-129

53-98

53-96

59-92

55-97

10-131

10-177

14-101

23-90

16-110

29-104

51-106

49-109

53-104

51-106

47-90

50-86

10-117

29-101

10-126

33-100

52-123

46-123

59-99

53-102

10-146

12-138

10-114

14-99

23-131

10.5

11.7

0434

0.278

0.576

0.654

4.77

0.0688

5.S9

3.75

1.34

1.63

2.34

1.65

0.300

0,0929

30.3

30.3

17

17

27.4

27.4

32.5

32.5

31.2

31,2

24.5

24.5

24

24

16.6

16.6

16.4

16.4

18.8

18.8

20.7

20.7

28.2

28.2

17,3

17,8

298

298

22,6

22,6

23.5

23,5

30.9

2/20/13

U

u

u u u u u u

x-2

U

u u u

u u u u u

17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 13-0162

Project: 13-0162, Aberdeen Groundwater- Reported by Jason Collum

Endrin aldehyde [20|

Methoxychlor

.Methoxychlor [20]

Endosulfan Sulfate

Endosulfan Sulfate [20|

Endrin ketone

Endrin ketone [20]

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

u u u

1,9729

1,8113

2.1260

1,9604

0,52

LO

1,0

0,52

0.52

0,52

0,52

ug/L

2.0619

2.0619

2,0619

2.0619

U

U

U

U

U

U

U

95,7

87,3

103

95,1

33-122

10-142

10-140

65-108

62-108

63-106

54-113

1,36

1,51

1,56

, 2,02

30,9

30,4

30,4

21,3

21,3

22,3

22,8

.Analyte

Reporting

Result Limit Units

Spike Source 'JiREC

Level Result %REC Limits RPD

RPD

Limit Notes

Batch 1301082-E 3520 LLE

M a t r i x Spike D u p ( 1 3 0 l 0 8 2 - M S D I ) Source: El30307-08 Prepared; 01/23/13 Analyzed; 01/28/13

MRL Verification (1301082-PSl) Prepared; 01/23/13 Analyzed; 01/30/13

EPA 8081 alpha-BHC

alpha-BHC [2CJ

gamma-BHC (Lindane)

gamma-BHC (Lindane) |2C|

beta-BHC

bcta-BHO [20]

delta-BHO

delta-BHC [20]

Heptachlor

Heptachlor [20]

Aldrin

Aldrin 120]

Heptachlor epoxide

Heptachlor epoxide [20]

gamma-Chlordane

gamnia-Chlordane [20]

alpha-Ohlordanc

alpha-Chlordane [2C|

4.4'-DDE (p.p'-DDE)

4.4'-DDElp.p'-DDEl |2C|

Endosulfan I (alpha)

0.0076200

0,0062300

U

0.016420

0.0II610

0,016170

0,014280

U

U

U

U

U

U

0,012430

0.024660

0.017000

0,014950

0,017680

0,014750

U

O.OIO ug/L

0,010

0,010

0,010

0,020

().020

0.020

0.020

0.015

0.015

0.020

0,020

0,020

0.020

0.020

0,020

0,020

0,020

0.020

0.020

0.020

0,010000

0,010000

0.020000

0.020000

0,020000

0,020000

0,020000

0,020000

0,020000

0,020000

0.020000

0.020000

76.2

62.3

48-92

82,1

58.0

80,9

71.4

52.2

123

85,0

74.8

38.4

73,3

30-105

35-113

30-117

31-115

56-39

33-118

12-141

41-100

29-104

20-132

30-117

40-115

44-104

30-128

46-97

42-100

50-113

44-123

30-125

MRL-2. MRL-8.

U MRL-2, MRL-8.

U U

U

MRL-2. U

MRL-2. U

MRL-2, U

MRL-2. • U

u

u

u

u

u

u MRL-2.

U MRL-2

MRL-2. U

MRL-2. U

MRL-2. U

MRL-2. U U

Page 35 of44 E130307,E1303IOOCPF1NAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

Endosulfan I (alpha) [20]

Dieldrin

Dieldrin [20]

Endrin

Endrin |2C]

4.4'-DDD (p.p'-DDD)

4.4'-DDD (p.p'-DDD) [20]

Endosulfan II (beta)

Endosulfan II (beta) [20]

4,4'-DDT (p.p'-DDT)

4.4'-DDT (p.p'-DDT) [20]

Endrin aldehyde

Endrin aldehyde [20]

Methoxychlor

Methoxychlor [2C]

Endosulfan Sulfate

Endosulfan Sulfate [20]

Endrin ketone

Endrin ketone [20]

u u u

0.034140

0.032090

0,033700

0,034330

U

U

U

U

U

U

U

V

0,046720

0,042010

0,051820

0,043840

0,020

0.020

0.020

0.040

0.040

0,040

0,040

0,040

0.040

0 050

0,050

0.050

0,050

0,10

0,10

0,050

0.050

0.050

0.050

ug/L

" " •

"

" " " " " " "

"

" "

0,040000

0,040000

0,040000

0,040000

0,050000

0,050000

0,050000

0.050000

85,4

80,2

84,2

85,3

93.4

84.0

104

87.7

44-130

54-123

50-109

47-123

44-127

64-125

53-134

38-155

47-148

26-143

25-135

54-153

31-210

33-129

37-135

52-124

58-126

50-134

41-135

Analyte Result

Reporting

Limit Units

Spike Source l iREC

Level Result %REC Limits RPD

RPD

Limit Notes

Batch 1301082-E 3520 LLE

M R L V e r i n c a t i o n ( 1 3 0 1 0 8 2 - P S l ) Prepared; 01 /23/13 Analyzed; 01 /30/13

u u u

MRL-2. U

MRL-2. U

MRL-2, U

MRL-2, U U

u u u u u u u

MRL-2.

U

MRL-2.

U MRL-2

MRL-2,

Batch 1301083 - E 3545A Modified

Blank (1301083-BLKI) Prepared; 01/23/13 Analyzed; 02/08/13

EPA 8081 alpha-BHO

alpha-BHO [20]

gamma-BHC (Lindane)

gamma-BHC (Lindanel [2C|

beta-BHC

beta-BHC [20]

delta-BHC

delta-BHC [20]

Heptachlor

Heptachlor [20]

.Aldrin

Aldrin [20]

u u u u u u u u u u u u

0.33 ug/k

0.33

0.33

. 0.33

0.67

0,67

0,67

0.67

0,50

0.50

0.67

0.67

Page 36 of 44 E130307,EI303IOOCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

Heptachlor epoxide

Heptachlor epo.xide |2C)

gamina-Chlordane

gamma-Chlordane [20]

alpha-Chlordane

alpha-Chlordane |2C]

4.4'-DDE<p-p'-DDE)

4.4'-DDE (p.p'-DDE) [2C]

Endosulfan I (alpha)

Endosulfan 1 (alpha) t2C]

Dieldrin

Dieldrin i:ci

Endrin

Endrin 12C]

4.4'-DDD(p,p'-DDD)

4,4'-DDD (p.p'-DDD) 12C]

Endosulfan II (beta)

Endosulfan 11 (beta) [2CJ

4.4'-DDT (p.p'-DDT)

4.4'-DDT (p.p'-DDT) [2C1

Endrin aldehyde

Endrin aldehyde |2C1

Methoxychlor

Methiwychlor [2C]

Endosulfan Sulfate

Endosulfan Sulfate [2C]

Endrin ketone

Endrin ketone |2C]

Toxaphene

Toxaphene |2C]

u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u

0,07

0,67

0.67

0.67

0.57

0,67

0.67

0.67

0.67

0.57

0.57

0,57

1,3

1

1

I

1

1

1

I

I

I

3

3

I

1

1

I

3

3

3

3

7

7

7

7

3

3

7

7

7

7

67

t 7

ug/kg dry

Analyte Result

Reporting

Limit Units

Spike Source .%REC

Le\d Result "iiREC Limits ' RPD

RPD

Limit Notes

Batch 1301083 - E 3545A Modified

Blank (1301083-BLKI ) Prepared: 01/23/13 Analyzed: 02/08/13

Page 37 of 44 E130307.EI30310OCPF1NAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

EPA 8081 alpha-BHC

alpha-BHO [20]

gamma-BHC t Lindane)

gamma-BHC (Lindane) [20]

beta-BHC

beta-BHC [20]

delta-BHC

delta-BHC [20]

Heptachlor

Heptachlor [20]

.Aldrin

Aldrin [2C]'

Heptachlor epoxide

Heptachlor epoxide [20]

ganuna-Chlordane

ganuna-Chlordane [20]

alpha-Chlordane

alpha-Chlordane [20]

4.4'-DDE fp.p'-DDE)

•i.4-DDE (p.p'-DDE) [20]

Endosulfan I (alpha)

Endosulfan I (alpha) [20]

Dieldrin

Dieldrin [20]

Endrin

Endrin [20]

4.4'-DDD (p.p'-DDD)

4.4'-DDD( p.p'-DDD) [20]

Endosulfan II (beta),

Endosulfan II (beta) [20]

4.4'-DDT (p.p'-DDT)

4.4'-DDT (p.p'-DDT) [20]

Endrin aldehyde

Endrin aldehyde [20]

Metho.xychlor

Methoxychlor [20]

Endosulfan Sulfate

Endosulfan Sulfate [20]

Endrin ketone

u u

5,5372

5.4988

U

U

U

U

8.9156

9 7 I 8 I

10,939

9.9349

11,647

11,383

U

U

u u u u

7.7060

7.5843

12.262

12.581

U

U

U

u 14,590

15.374

23.560

26.208

12.201

13.742

59225

66,121

u u u

1,7 ug/kg dry

1,7

1,7

1,7 • "

3,3

3,3

3,3

3,3

2.5

2.5

3.3

3,3

3.3

3.3

3,3

3,3

3,3

3,3

3,3

3.3

3.3

3.3

3.3

3,3

6,7

6,7

6,7

6,7

6,7

6.7

8.3

8.3

8.3

8,3

17

17

8.3

8,3

8,3

5,6733

5,6733

10.010

10,010

13,347

13:347

13,347

13,347

13,347

13,347

13,347

13.347

26.693

26,593

33.367

33,367

33,367

33,357

56733

65.733

83,0

82,4

891

971

82.0

74,4

87.3

85.3

57,7

56,8

91.9

94,3

54,7

57.6

70,6

78,5

3 6 5

41,2

88.8

99.1

50,9-116

50,')-lI6

50-109

50-109

62,3-121

62,3-121

50.I-I11

50,1-111

71,8-106

71,8-106

61-112

61-112

71-110

71-110

56.3-123

56.3-128

56.5-125

56,5-125

59-120

59-120

23,5-123

23,5-123

65,1-113

65. l-I 13

70.3-122

70.3-122

02,5-120

62.5-120

26,2-125

26,2-125

69 2-121

69.2-121

43,3-115

43.3-115

81.3-128

81.8-128

57.3-126

57.3-126

62.2-121

.Analyte Result

Reporting

Limit Units

Spike

Level

Source "oREC

Result ''bREC Limits RPD

RPD

Limit Notes

Batch 1301083 - E 3545A Modified

LCS(I301083-BSI) Prepared; 01 /23/13 Analyzed: 02 /08/13

110-2

QL-1

QL-1

QO-2

U

U

U

Page 38 of 44 E130307EI30310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater- Reported by Jason Collum

Endrin ketone [2C|

To.xaphene

To,vaphene [201

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

8,3 ug'kg dry

330

330

62,2-121

75-113

75-113

.Analyte Result

Reponing

Limit Units

Spike SomT;e "ioREC

Level Result 'J-iREO Limits RPD

RPD

Limit Notes

Batch 1301083 - E 3.545A Modified

L C S ( I 3 0 I 0 8 3 - B S 1 ) Prepared: 01/23/13 Analyzed; 02/08/13

M a t r i x S p i k e ( l 3 m 0 8 3 - M S I ) S o u r c e : E 1 3 0 3 I 0 - I 4 Prepared; 01 /23 /13 Analyzed; 02 /08/13

EPA 8081 alpha-BHO

alpha-BHC 120]

gamma-BHC (Lindane)

gamma-BHC (Lindane) [2C|

beta-BHC

beta-BHC [201

delta-BHC

delta-BHO [20]

Heptachlor

Heptachlor [20]

Aldrin

Aldrin [20]

Heptachlor epoxide

Heptachlor epoxide [20]

gamma-Chlordane .

gamma-Chlordane [20]

alpha-Chlordane

alpha-Chlordane [2C1

4.4'-DDE (p.p'-DDE)

4.4'-DDE (p.p'-DDE) (20]

Endosulfan I (alpha)

Endosulfan I (alpha) [20]

Dieldrin

Dieldrin [20]

Endrin

Endrin [20]

4.4-DDD (p.p'-DDD)

4.4-DDD( p.p'-DDD) [20]

Endosulfan 11 (beta)

Endosulfan 11 (beta) [2C1

4.4-DDT (p.p'-DDT)

4.4-DDT (p.p'-DDT) [201

Endrin aldehyde

Endrin aldehyde [20]

U

U

10,070

10,149

U

u 2.3858

1,8302

16,077

17,129

17 109

17,359

19.814

19,213

U

U

U

U

2.4563

U

19,667

19,616

22,353

25,508

U

U

U

U

38,519

43,474

35,351

48438

23.655

32.688

!.8 ug/kg dry

2,8

5,6

5,6

5,6

5,6

4.2

4,2

5,6

5.6

5.6

5,5

5.6

5,5

5.6

5.6

5,6

5,6

5,6

5,6

5,6

5,6

I

11,280

11.280

16.920

16,920

22,561

22,551

22,551

22,551

22.561

22.561

22.561

22.561

45,121

45.121

56,402

56,402

56,402

56.402

U

U

U

U

U

U

U

0,52646

U

7,5756

U

0,73941

0,93029

U

U

U

1,6926

U

0,76914

1.9932

U

U

U

U

U

U

U

u u u

1,3361

U

U

U

8 9 3

90,0

95,0

56.5

75.8

73.5

83.5

35,2

87.2

87.0

99.1

113

35,4

96,4

62.1

85.9

41.9

53.0

23-132

23-132

53-104

53-104

34.7-137

34.7-137

30.1-129

30.1-129

44,9-114

44,9-114

40,8-117

40,8-117

49.9-114

499-114

16.9-155

16.9-155

29.2-140

292-140

10-166

10-166

35.6-118

35.6-118

31,3-118

31,3-118

53-135

53-135

19,9-151

19,9-151

32,2-135

32,2-135

42,9-130

42.9-130

10-118

10-118

00-2

Page 39 of 44 E130307E130310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 DA.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater- Reported by Jason Collum

Methoxychlor

Methoxychlor [20]

Endosulfan Sulfate

Endosult'an Sulfate [2C]

Endrin ketone

Endrin ketone [20]

To.xaphene

Toxaphene [20]

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

96.689

127.69

U

U

• U

U

U

U

28

28

14

14

14

14

HO

HO

ug/kg dry

" "

112

112

SO

30

U

U

U

U

U

U

0,0000

0.0000

35.7

113

41.3-143

41.3-143

40.3-138

40.3-138

37,5-135

37,5-135

52-96

62-96

.Analyte

Reporting

Result Limit t-Inits

Spike Source ".iREC

Level Result 'i'oREC Limits RPD

RPD

Limit Notes

Batch 1301083 - E 3545A Modified

M a t r i x S p i k e ( 1 3 0 1 0 8 3 - M S I ) S o u r c e : E l 3 0 3 1 0 - 1 4 Prepared: 01 /23/13 Analyzed: 02 /08/13

00-2

u u u u u u

Matrix Spike Pup (1301083-MSDI) Source: El 3031 O-l 4 Prepared: 01/23/13 Analyzed: 02/08/13

EPA 8081 alpha-BHC

alpha-BHC [20]

gamnia-BHC (Lindane)

gamma-BHO (Lindane) [20]

beta-BHC

beta-BHC [20]

delta-BHC

delta-BHC [20]

Heptachlor

Heptachlor [20]

Aldrin

.Aldrin [20]

Heptachlor epoxide

Heptachlorepoxide [20]

gamma-Chlordane

gamma-Chlordane [20]

alpha-Chlordane

alpha-Ohlordane [20]

4.4'-DDE (p.p'-DDE)

4.4'-DDE (p.p'-DDE) |2C]

Endosulfan I (alpha)

Endosulfan I (alpha) [20]

Dieldrin

Dieldrin |2CJ

Endrin

Endrin (20)

4.4'-DDD (p.p'-DDD)

4.4'-DDD (p.p'-DDD) [2C],

Endosulfan II (beta)

Page 40 of 44

u u

9.6984

10,643

u U

U

U

16.759

18.472

17.663

17,594

20.550

19.526

U

U

U

U

U

U

19.862

21.063

22.618

23.892

U

U

U

U

37.555

FINAL 02 20 13

2.8 ug/kg dry

2.8

2.8

2,8

5,6

5,6

5,6

5,6

4.2

4.2

5.6

5.5

5,6

5,6

5.6

5,6

- 5,6

5,6

5,6

5,6

5,6

5,6

5.6

5.6

II

II

II

II

II

1706

11.274

11.274

16.911

16.911

22.548

22.548

22.548

22.548

22.548

22.548

22.548

22.548

45.096

U

U

U

U

U

U

U

0,52646

U

7,5766

U

0,78941

0.98029

U

U

U

1.6925

U

0.76914

1.9932

U

U

u U

u Ll

U

U

U

35,0

94.4

99.1

64,4

78.3

75.0

87,3

86,6

88,1 .

93.4

IOO

106

83.3

28-132

28-132

53-104

53-104

34.7-137

34.7-137

30.1-129

30,1-129

44,9-114

44,9-114

40,8-117

40,8-117

49,9-114

49.9-114

16,9-155

16,9-155

29,2-140

29,2-140

10-166

10-165

35.5-II8

35,6-118

3I .3-II8

31.3-II8

53-135

53-135

19.9-151

19.9-151

32.2-135

3,76

4,74

4,15

7,55

3,19

1,86

4,18

162

0,985

7,11

I.I3

6.54

2.53

24

24

45,6

45,6

19,8

19,8

195

195

51.9

51,9

34,6

34,6

34

34

23.4

23,4

24,7

24,7

63,3

63,3

56,8

56,8

573

57.3

21.3

21.3

50

50

28.8

2/20/1

U

U ,

U

U

U

U

QC-2

U

U

U

U

U

U

u u u u

3 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Endosulfan II (betal [20|

4.4'-DDT (p.p'-DDT)

4.4'-DDT (p.p'-DDT) [20]

Endrin aldehyde

Endrin aldehyde [20]

Methoxychlor

Metho.xychlor (2C| -

Endosulfan Sulfate

Endosulfan Sulfate |2C1

Endrin ketone

Endrin ketone [20]

Toxaphene

Toxaphene |2C]

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

.Analyte

Reporting

Result Limit L'nits

Sptke Source "iREC

Level Result »bREO Limits RPD

RPD

Limit Notes

B a t c h 1 3 0 1 0 8 3 - E 3 5 4 5 A M o d i f i e d

M a t r i x S p i k e D u p ( I 3 U I 0 8 3 - M S D I ) S o u r c e : E l 3 0 3 1 0 - 1 4 Prepared; 01 /23 /13 Analyzed: 02 /08/13

43.326

37.342

40,059

23.537

30,600

95.536

121.43

U

U

U

U

U

U

11 ug/kg dry

14

14

14

14

23

28

14 " , ,

14

14

14

HO

110

45

56

55

55

55

II

II

095

370

370

370

370

2,74

174

U

1.3361

U

U

U

U

U

U

U

U

U

0.0000

0.0000

96.1

63,9

71,1

41,8

54,3

84.7

108

32.2-135

42,9-130

42,9-130

10-118

10-118

41,3-143

41,3-143

40,3-138

40,3-133

37,5-135

37.5-135

52-96

62-96

0,342

2,69,

18,9

0,498

6,50

1,20

5,03

28,8

78,2

78,2

58,3

58,3

37,5

37,6

28,5

28,5

27,8

27,8

IOO

100

QC-2

U

U

U

U

U

U

MRL Verincation (I30I083-PSI) Prepared; 01/23/13 Analyzed; 02/08/13 EPA 8081 alpha-BHC

alpha-BHC [2C|

gamma-BHO (Lindane)

gamma-BHO (Lindane) [2C]

beta-BHC

beta-BHO [20]

delta-BHC

delta-BHC [20]

Heptachlor

Heptachlor [2C]

.Aldrin

Aldnn [20]

Heptachlor epoxide

Heptachlor epoxide [20]

gamma-Ch lordane

gamma-Chlordane [20]

U

u

0.34523

0.35557

U

U '

U

U

0,59206

0,59206

0,69880

0,53042

1,4109

0.78185

U

0.33 ug/kg dry

0,33

0.33

0.33

0.57

0.57

0.67

0.67

0,50

0,50

0,67

0.D7

0.67

0.57

0.57

0,33356

0.33356

• •

0,50033

0,50033

0,66711

0,56711

0.66711

0.56711

104

107

118

113

105

94,5

212

117

30,0-136

30,9-136

40-129

40-129

42,8-141

42.8-I4I

30.1-I3I

30.1-131

51.8-126

51.8-126

41-132

41-132

51-130

51-130

36,3-148

0.67 36,3-148

MRL-3.

U

MRL-3.

U

MRL-3

MRL-3

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3

MRL-3.

QC-2

MRL-3

MRL-3.

U

MRL-3.

QR-2

MRL-3

MRL-3.

U

MRL-3.

U

Page 41 of44 E130307E1303I0OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road. Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

alpha-Chlordane

alpha-Chlordane (2C1

4,4'-DDE (p.p'-DDE)

4,4'-DDE (p.p'-DDE) [2C|

Endosulfan 1 (alpha)

Endosulfan 1 (alpha) [2C]

Dieldrin

Dieldrin [2C|

Endrin

Endrin |2C1

4.4'-DDD (p.p'-DDD)

4,4'-DDD(p,p'-DDD)[2Cl

Endosulfan 11 (beta)

Endosulfan 11 (beta) [2C]

4,4'-DDT (p.p'-DDT)

4.4'-DDT (p.p'-DDT) 120]

Endrin aldehyde

Endrin aldehyde [2C]

Metho.icychior

Methoxychlor I2C|

Endosulfan Sulfate

Endosulfan Sulfate 12C1

Endrin ketone

Endrin ketone |2r]

Toxaphene

Toxaphene t2Cl

u

u

u

u

0,72315

0,57812

0.68012

0.79820

0.71681

U

U

U

1.1684

1.3002

I 6081

1.5727

0,89960

0,67 ug/kg dry

0.67

0,67

0,67

0,67

0,67

0,67

0,67

1.3

1.3

1.3

1.3

1,3

1,3

1,7

1,7

1,7

0,56711

0.65711

0.65711

0.65711

1.3342

1.3342

1.6678

1.6678

1.6678

103

102

102

120

87,6

97.4 •

96.4

94.3

53,9

36,5-145

.165-145

39-140

19-140

10-143

10-143

45.1-133

45.1-133

50.8-142

50,8-142

42,5-140

42.5-140

10-145

10-145

49.2-141

49.2-141

23.3-135

1.7 1.6678 23,3-135

3 6234

3.3309

U

• U

u

u

, u

u

3.3

3.3

1.7

1.7

1.7

1.7

67

67

3,3

3.3

56

56

109

115

61.3-148

61.3-148

37,3-146

37,3-146

42,2-141

422-141

55-133

55-133

.Analyte Result

Reporting

Limit Units

Spike Source %REC

Level Result '?»REC Limits RPD

RPD

Limit Notes

Batch 1301083 - E 3545A Modified

M R L Neri f ica t ion ( U 0 1 0 S 3 - P S I ) Prepared: 01/23/13 Analyzed; 02/08/13

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3

MRL-3

MRL-3

MRL-3

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

MRL-8.

U

MRL-3.

U

MRL-3

MRL-3.

QO-2

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

U

MRL-3.

U

Page 42 of 44 EI30307EI30310OCPFINAL02 20 13 1706 2/20/13 17:06

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division

980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162

Project: 13-0162, Aberdeen Groundwater - Reported by Jason Collum

Organochlorine Pesticides (OCP) - Quality Control

US-EPA, Region 4, SESD

Analyte Result

Reporting

Limit Units

Spike Source "JoREC

Level Result ';'oREC . Limits RPD

RPD

Limit Notes

Batch 1301083 - E 354,5A Modified

MRL Verincation (I30I083-PSI) Prepared; 01/23/13 Analyzed; 02/07/13

Page 43 of 44 E130307EI30310OCPFINAL02 20 13 1706 2/20/13 17:06

/ ^ , , ^ ^ UNITED STATES ENVIRONMENTAL PROTECTION AGENCY /*" 1 ^ 3 ^ ^ Region 4 Science and Ecosystem Support Division ( | V \ ^ 7 : 1/ 980 College Station Road, Athens, Georgia 30605-2700 \;^^:£/ D.A.RT Id: 13-0162

Nj£pRo;t$X Project: 13-0162, Aberdeen Groundwater-Reported by Jason Collum

Notes and Definitions for QC Samples

U The analyte was not detected at or above the reporting limit.

MRL-2 MRL verillcation for Non-Potable Water matri.x

MRL-3 MRL verification for Soil matri.x

MRL-8 MRL verification result less than the LOD.

OC-2 Analyte concentration high in continuing calibration verification standard

QL'I Laboratory Control Spike Recovery less than method control limits

0 '^- - MRL verification recovery greater than upper control limits.

•^•2 Manix interference precludes recovery calculation

Paae44of44 E130307,EI30310 OCP FINAL 02 20 13 1706 2/20/13 17:06