MATERIAL SAFETY DATA SHEET SILANE PRIMER SAFETY DATA SHEET SILANE PRIMER ......

MATERIAL SAFETY DATA SHEET SILANE PRIMER

Note: This MSDS was prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200) and is to be used only for this product. The information in this MSDS is, to the best of our knowledge, believed to be accurate.

1 - IDENTIFICATION Manufacturer: Kerr Corporation Address: 1717 West Collins Avenue City, State, Zip: Orange, CA 92867-5422 Telephone: 1-800-KERR-123 Emergency: Chemtrec 1-800-424-9300 Date Prepared: July 2009

2 - COMPOSITION INFORMATION Hazardous Ingredients CAS # PEL TLV % Ethyl Alcohol 64-17-5 1000 ppm 1000 ppm 80-85 Other Ingredients Organosilane Ester N/A N/A 15-20

3 - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 173oF (78.5oC) Specific Gravity (H20 = 1): ~0.85 Vapor Pressure (mm Hg): 40mm Hg Melting Point: N/A Vapor Density (AIR = 1): 1.59 Solubility in Water: Soluble Reactivity in Water: N/A Appearance and Odor: Clear, colorless liquid with alcohol odor

4 - FIRE AND EXPLOSION HAZARD DATA Flash Point (Method Used): 55oF (13oC) Flammable Limits: LEL: 4.3 UEL: 19 Extinguishing Media: Carbon dioxide, dry chemical, water spray Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None

5 - REACTIVITY DATA Stability: Stable if stored as directed. Conditions to Avoid: Heat, sparks, open flame Incompatibility (Material to Avoid): Strong oxidizing agents Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide. Hazardous Polymerization: Will not occur

6 - HEALTH HAZARD DATA Routes of Entry: Skin: May cause a mild irritation. Eyes: May cause a mild irritation. Inhalation: May cause irritation of the throat. Ingestion: May be poisonous by ingestion. Carcinogenicity - NTP: No IARC Monographs: No OSHA Regulated Carcinogen: No

7 - EMERGENCY FIRST AID PROCEDURES Skin: Wash thoroughly with soap and water. Use hand cream. Eyes: Flush with water for at 15 minutes. Inhalation: Remove to fresh air. Restore breathing if necessary. Ingestion: Do not give liquids. If victim is unconscious, contact physician.

8 - PRECAUTIONS FOR SAFE HANDLING & USE Steps to be taken in case material is released or spilled: Dilute with water, wipe with cloth and transfer to suitable container for disposal. Waste Disposal Method: Material should not be allowed to drain to sewers. Incinerate liquid in proper equipment. Dispose of in accordance with local regulations. Precautions to be taken in handling and storing: Store in a cool, dry place. Keep away from ignition sources. Other precautions: Use according to directions.

9 - CONTROL MEASURES Respiratory Protection (Specify Type): Not needed VENTILATION: Local Exhaust: Recommended to keep exposure under 1000ppm. Mechanical (General): Should be sufficient Protective Gloves: Recommended Eye Protection: Safety glasses with side shields Work/Hygiene Practices: Handle in accordance with good personal hygiene and safety practices. These practices include avoiding unnecessary exposure.

10 - TRANSPORTATION INFORMATION Regulated: DOT, IATA, IMO Proper Shipping Name: Ethyl Alcohol Solution Hazard Class: 3 Identification Number: 1170 Packaging Group: II Label: Flammable Liquid NOTE: May be shipped ORM-D See 49CFR 173.4

11 - SPECIAL INFORMATION HMIS (Hazardous Material Identification System) Rating: H1 F3 R1 [HMIS Index: 4 - Severe Hazard; 3 -Serious Hazard; 2 - Moderate Hazard; 1 - Slight Hazard; 0 - Minimum Hazard]

Optibond™ Solo Plus

Not available.

Liquid.

GHS product identifier

Other means of identification

Product type

Section 1. Identification:

:

:

Relevant identified uses of the substance or mixture and uses advised against

SAFETY DATA SHEETOptibond™ Solo Plus

Product use : Dental product

Area of application : Professional applications.

CHEMTREC® (24 hours) U.S. : 1-800-424-9300 International: +1-703-527-3887Emergency telephone number (with hours of operation)

:

Manufacturer : Kerr Corporation1717 West Collins AvenueOrange, CA 92867-5422Telephone no.: 1-800-KERR-123

e-mail address of person responsible for this SDS

: [email protected]

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 2SKIN IRRITATION - Category 2EYE IRRITATION - Category 2ASKIN SENSITIZATION - Category 1SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1

Classification of the substance or mixture

:

Signal word : Danger

Hazard pictograms :

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 51.4%

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Health effects are based on the uncured material.

Date of issue/Date of revision : 10/16/2014 Date of previous issue : No previous validation Version : 1 1/13

United States


Section 2. Hazards identificationHazard statements : Highly flammable liquid and vapor.

Causes serious eye irritation.Causes skin irritation.May cause an allergic skin reaction.May cause respiratory irritation.May cause drowsiness and dizziness.Causes damage to organs through prolonged or repeated exposure.

Precautionary statements

Prevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.Contaminated work clothing should not be allowed out of the workplace.

Response : Get medical attention if you feel unwell. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Store locked up. Store in a well-ventilated place. Keep cool.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

: Avoid contact with skin and clothing. Wash thoroughly after handling.

Hazards not otherwise classified

: Prolonged or repeated contact may dry skin and cause irritation.

Section 3. Composition/information on ingredients

ethanol ethanol 10-30 64-17-52-hydroxyethyl methacrylate 2-hydroxyethyl methacrylate 10-30 868-77-92-hydroxy-1,3-propanediyl bismethacrylate 2-hydroxy-1,3-propanediyl

bismethacrylate1-5 1830-78-0

alkali fluorosilicates(Na) disodium hexafluorosilicate 0.1-1 16893-85-9

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.


: Not available.

CAS number : Not applicable.

Substance/mixture

Product code : Not available.

CAS number/other identifiers

: Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Other names


United States


Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Get medical attention if adverse health effects persist or are severe.

No special measures are required. In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if symptoms occur.

No special measures required. In case of contact, immediately flush skin with plenty of water. Get medical attention if symptoms occur.

No special measures required. If inhaled, remove to fresh air. Get medical attention if symptoms occur.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:

Protection of first-aiders : In case of major fire and large quantities: No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present,the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.

Description of necessary first aid measures

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach.

:Ingestion

Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.

Causes serious eye irritation.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughingnausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness

No specific data.

Adverse symptoms may include the following:irritationrednessdrynesscracking

:

:

:

Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

Potential acute health effects

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary


United States


Section 5. Fire-fighting measures

In case of major fire and large quantities: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxidesphosphorus oxideshalogenated compoundsmetal oxide/oxides

Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

In case of fire, use water spray (fog), foam, dry chemical or CO₂.

Extinguishing media

:

:

:

Do not use water jet.

Suitable extinguishing media

:

Unsuitable extinguishing media

:

Special protective actions for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Small Quantity. For professional use only. Absorb with an inert material and place in an appropriate waste disposal container.

:

: Low release. For professional use only. Handling of product in very small amounts or in situations where release is highly unlikely

Low release. Avoid dispersal of spilled material and runoff and contact with soil,waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :


Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : Low release. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

:

Protective measures No special measures are required for small quantities under normal and intended conditions of product use. For professional use only. Put on appropriate personal protective equipment (see Section 8). Handle with care and dispose in a safe manner.

:

Precautions for safe handling


United States


Section 7. Handling and storageConditions for safe storage,including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

:

ethanol ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes.OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours.NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1900 mg/m³ 10 hours.OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours.

alkali fluorosilicates(Na) ACGIH TLV (United States, 6/2013). TWA: 2.5 mg/m³, (as F) 8 hours.OSHA PEL 1989 (United States, 3/1989). TWA: 2.5 mg/m³, (as F) 8 hours.OSHA PEL Z2 (United States, 2/2013). TWA: 2.5 mg/m³ 8 hours. Form: DustOSHA PEL (United States, 2/2013). TWA: 2.5 mg/m³, (as F) 8 hours.

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

:

:

Body protection No special measures are required for small quantities under normal and intended conditions of product use.

:

Environmental exposure controls

: No special measures are required for small quantities under normal and intended conditions of product use.

Appropriate engineering controls


No special measures are required for small quantities under normal and intended conditions of product use.

Hygiene measures :

Control parameters

Individual protection measures

Occupational exposure limits

Skin protection


United States




Respiratory protection :

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid. [Paste.]

Not available.

~1.25

Not available.

Not available.

Partially soluble in the following materials: cold water and hot water.

Fruity.Odor

pH

Yellow. [Light]Color

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: 18°C (64.4°F) [Ethanol]

Not available.

Not available.

Viscosity Not available.

Not available.Odor threshold

Partition coefficient: n-octanol/water

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point : Not available.

Flammability (solid, gas) :

Lower and upper explosive (flammable) limits

: Not available.

SADT Not available.:

Decomposition temperature : Not available.

Solubility in water : Not available.

Not applicable.

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid Keep away from heat, sparks and flame.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

:

:

:

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Under normal conditions of storage and use, hazardous polymerization will not occur.

Reactive or incompatible with the following materials: oxidizing materials.


United States


Section 11. Toxicological information

Acute toxicity

ethanol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hoursLD50 Oral Rat 7 g/kg -

2-hydroxyethyl methacrylate LD50 Oral Rat 4230 mg/kg -alkali fluorosilicates(Na) LD50 Oral Rat 125 mg/kg -

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary : Based on the criteria of the protocol, this product is considered non-cytotoxic per ISO 10993-5.

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Irritation/Corrosion

ethanol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams

-

Eyes - Moderate irritant Rabbit - 0.066666667 minutes 100 milligrams

-

Eyes - Moderate irritant Rabbit - 100 microliters

-

Eyes - Severe irritant Rabbit - 500 milligrams

-

Skin - Mild irritant Rabbit - 400 milligrams

-

Skin - Moderate irritant Rabbit - 24 hours 20 milligrams

-

alkali fluorosilicates(Na) Skin - Mild irritant Rabbit - 500 milligrams

-

Product/ingredient name Result Score Exposure Observation

Sensitization

Not available.

Species

Specific target organ toxicity (single exposure)

Information on toxicological effects

Classification

ethanol - 1 -alkali fluorosilicates(Na) - 3 -

Product/ingredient name NTPIARCOSHA


United States



Information on the likely routes of exposure

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach.

:Ingestion

Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.


Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughingnausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness

No specific data.

Adverse symptoms may include the following:irritationrednessdrynesscracking

:

:

:


Delayed and immediate effects and also chronic effects from short and long term exposure

Specific target organ toxicity (repeated exposure)

ethanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects

2-hydroxyethyl methacrylate Category 3 Not applicable. Respiratory tract irritation

2-hydroxy-1,3-propanediyl bismethacrylate Category 3 Not applicable. Respiratory tract irritation

Name Category

Name Category

ethanol Category 2 Not determined liveralkali fluorosilicates(Na) Category 1 Not determined bones and teeth

Aspiration hazard

Not available.

Route of exposure

Target organs

Route of exposure

Target organs

: Routes of entry anticipated: Oral, Dermal, Inhalation.


Potential immediate effects

: Not available.

Short term exposure


United States



Not available.

Causes damage to organs through prolonged or repeated exposure. Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.

General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Potential chronic health effects

Numerical measures of toxicity

Oral 3581.7 mg/kgDermal 14580 mg/kgInhalation (vapors) 145.8 mg/l

Route ATE value

Acute toxicity estimates

Potential delayed effects : Not available.


: Not available.

Long term exposure


Section 12. Ecological informationToxicity

ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hoursAcute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hoursAcute LC50 25500 µg/l Marine water Crustaceans - Artemia

franciscana - Larvae48 hours

Acute LC50 42000 µg/l Fresh water Fish - Oncorhynchus mykiss 4 daysChronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hoursChronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki -

Larvae12 weeks

2-hydroxyethyl methacrylate Acute LC50 227000 µg/l Fresh water Fish - Pimephales promelas -Juvenile (Fledgling, Hatchling,Weanling)

96 hours

alkali fluorosilicates(Na) Acute LC50 49000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

2-hydroxyethyl methacrylate 301C Ready Biodegradability -Modified MITI Test (I)

92 to 100 % - 14 days - -

Product/ingredient name Test DoseResult Inoculum


United States


Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

ethanol -0.35 - low2-hydroxyethyl methacrylate 0.42 - low

Product/ingredient name Aquatic half-life Photolysis Biodegradability

ethanol - - Readily2-hydroxyethyl methacrylate - - Readily

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

:Disposal methods

Section 14. Transport information

Ethanol solution

3

II

ETHANOL SOLUTION

3

II

Ethanol solution

UN1170

3

II

UN1170 UN1170

Limited quantityYes.

Packaging instructionPassenger aircraftQuantity limitation: 5 L

Cargo aircraftQuantity limitation: 60 L

Special provisions24, IB2, T4, TP1

Emergency schedules (EmS)F-E, S-D

Special provisions144

Passenger and Cargo AircraftQuantity limitation: 5 LPackaging instructions: 353Cargo Aircraft OnlyQuantity limitation: 60 LPackaging instructions: 364Limited Quantities -Passenger AircraftQuantity limitation: 1 LPackaging instructions: Y341

Special provisionsA3, A58, A180

DOT Classification IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

No. No. No.


United States


Section 14. Transport informationSpecial precautions for user

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.

:

Section 15. Regulatory informationU.S. Federal regulations

The following components are listed: ETHYL ALCOHOL; SODIUM SILICA FLUORIDE;MINERAL WOOL FIBER

Massachusetts

:

:

SARA 313

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)

: Listed

Clean Air Act Section 602 Class I Substances

: Not listed

Clean Air Act Section 602 Class II Substances

: Not listed

DEA List I Chemicals (Precursor Chemicals)

: Not listed

DEA List II Chemicals (Essential Chemicals)

: Not listed

New York : None of the components are listed.

New Jersey : The following components are listed: ETHYL ALCOHOL; ALCOHOL; SODIUM FLUOROSILICATE; SILICATE(2-), HEXAFLUORO-, DISODIUM

Pennsylvania : The following components are listed: DENATURED ALCOHOL

State regulations

TSCA 8(a) PAIR: mequinol

Commerce control list precursor: alkali fluorosilicates(Na)

United States inventory (TSCA 8b): Not determined.

SARA 302/304

SARA 304 RQ : Not applicable.

No products were found.

Composition/information on ingredients

SARA 311/312

Classification : Fire hazardImmediate (acute) health hazardDelayed (chronic) health hazard

ethanol 10-30 Yes. No. No. Yes. Yes.2-hydroxyethyl methacrylate 10-30 No. No. No. Yes. No.2-hydroxy-1,3-propanediyl bismethacrylate

1-5 No. No. No. Yes. No.

alkali fluorosilicates(Na) 0.1-1 No. No. No. Yes. Yes.

Name % Fire hazard

Sudden release of pressure

Reactive Immediate (acute)health hazard

Delayed (chronic)health hazard


Not applicable.


United States


Section 15. Regulatory information

WARNING: This product contains a chemical or chemicals known to the State of California to cause birth defects or other reproductive harm.

methanol No. Yes. No. 23000 µg/day (ingestion)47000 µg/day (inhalation)

Ingredient name Cancer Reproductive No significant risk level

Maximum acceptable dosage level

California Prop. 65

Section 16. Other information

History

IHS

Date of issue/Date of revision

Version

Prepared by

Date of previous issue

:

:

:

:

Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficient

10/16/2014

No previous validation1

Hazardous Material Information System (U.S.A.)

2

4

0

04

2

*

National Fire Protection Association (U.S.A.)

Health

Special

Instability/Reactivity

Flammability

Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.


United States



To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Notice to reader

Indicates information that has changed from previously issued version.

References : HCS (U.S.A.)- Hazard Communication Standard International transport regulations

MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations


United States

United States

SAFETY DATA SHEET

Gel Etchant

Section 1. Identification

GHS product identifier Other means of identification Product type

: Gel Etchant : Not available.

: Gel.

Relevant identified uses of the substance or mixture and uses advised against Product use : Etching gel. Area of application : Professional applications.

Manufacturer : Kerr Corporation 1717 West Collins Avenue Orange, CA 92867-5422 Telephone no.: 1-800-KERR-123


: [email protected]

Emergency telephone number (with hours of operation)

: CHEMTREC® (24 hours) U.S. : 1-800-424-9300 International: +1-703-527-3887




: SKIN CORROSION - Category 1 SERIOUS EYE DAMAGE - Category 1 CARCINOGENICITY - Category 2 Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1.2%

GHS label elements Hazard pictograms :

Signal word : Danger Hazard statements : Causes severe skin burns and eye damage.

Suspected of causing cancer. Precautionary statements

Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Wash hands thoroughly after handling.


mailto:[email protected]

United States

Gel Etchant


Response : IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician.

Storage : Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and

international regulations. Supplemental label elements


: Do not taste or swallow. Wash thoroughly after handling.

: Causes digestive tract burns.


Substance/mixture Other means of identification

: Mixture : Not available.

CAS number/other identifiers CAS number : Not applicable. Product code : Not available.

Ingredient name Other names % CAS number Phosphoric acid Cobalt aluminate blue spinel

orthophosphoric acid Cobalt aluminate blue spinel

30-60 0.1-1

7664-38-2 1345-16-0

Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.


Description of necessary first aid measures Eye contact

Inhalation

Skin contact

: Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.

: Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

: Get medical attention immediately. Call a poison center or physician. Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.


United States

Gel Etchant


Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.


Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory

system. Skin contact : Causes severe burns. Ingestion : Corrosive to the digestive tract. Causes burns. May cause burns to mouth, throat and

stomach. Over-exposure signs/symptoms

Eye contact : Adverse symptoms may include the following: pain watering redness

Inhalation Skin contact

Ingestion

: No specific data. : Adverse symptoms may include the following:

pain or irritation redness blistering may occur

: Adverse symptoms may include the following: stomach pains

Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large

quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is

suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.



Extinguishing media Suitable extinguishing media Unsuitable extinguishing media

: Use an extinguishing agent suitable for the surrounding fire.

: Do not use water jet.


: In a fire or if heated, a pressure increase will occur and the container may burst.


United States

Gel Etchant



: Decomposition products may include the following materials: carbon dioxide carbon monoxide phosphorus oxides metal oxide/oxides hydrogen.



: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.


Personal precautions, protective equipment and emergency procedures For non-emergency personnel

: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up Small spill :

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). The spilled material may be neutralized with sodium carbonate, sodium bicarbonate or sodium hydroxide. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.


Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -

obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Keep away from alkalis. Empty containers retain product residue and can be hazardous. Do not reuse container.


United States

Gel Etchant



Conditions for safe storage, including any incompatibilities

: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

: Store between the following temperatures: 20 to 25°C (68 to 77°F). Store in

accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Separate from alkalis. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.


Control parameters Occupational exposure limits

Ingredient name Exposure limits Phosphoric acid ACGIH TLV (United States, 6/2013).

TWA: 1 mg/m³ 8 hours. STEL: 3 mg/m³ 15 minutes.

OSHA PEL 1989 (United States, 3/1989). TWA: 1 mg/m³ 8 hours. STEL: 3 mg/m³ 15 minutes.

NIOSH REL (United States, 10/2013). TWA: 1 mg/m³ 10 hours. STEL: 3 mg/m³ 15 minutes.

OSHA PEL (United States, 2/2013). TWA: 1 mg/m³ 8 hours.



: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures Hygiene measures :

Eye/face protection :

Skin protection

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead.


United States

Gel Etchant


Hand protection

Body protection

: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.


Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.


Appearance Physical state Color

Odor Odor threshold pH Melting point

: Liquid. [Gel] : Blue. : Odorless. : Not available. : 1 : Not available.

Boiling point : Not available. Flash point Evaporation rate

: Not available. : Not available.

Flammability (solid, gas) : Not applicable. Lower and upper explosive (flammable) limits

: Not available.

Vapor pressure Vapor density Relative density Solubility

: Not available. : Not available. : Not available. : Soluble in the following materials: cold water and hot water.

Solubility in water : Not available. Partition coefficient: n- octanol/water Auto-ignition temperature

: Not available.

: Not available.

Decomposition temperature : Not available. SADT Viscosity

: Not available. : Not available.

Density : 1 g/cm³ Physical/chemical properties comments

: Solvents: water, ≥60% Solid: ≥2%


United States

Gel Etchant



Chemical stability : The product is stable.




Conditions to avoid : No specific data.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials, reducing materials, metals, acids, alkalis and moisture. Incompatible with peroxides. Amines.


: Under normal conditions of storage and use, hazardous decomposition products should not be produced.


Information on toxicological effects Acute toxicity

Product/ingredient name Result Species Dose Exposure Phosphoric acid LD50 Dermal

LD50 Oral Rabbit Rat

2740 mg/kg 1.25 g/kg

- -

Conclusion/Summary : Based on analysis and test results, this product is not considered as biocompatible per EN ISO 7405:2008 and EN ISO 10993-1:2009.

Irritation/Corrosion Not available.

Sensitization Not available.

Mutagenicity Not available.

Carcinogenicity Not available.

Classification

Product/ingredient name OSHA IARC NTP Cobalt aluminate blue spinel - 2B -

Reproductive toxicity Not available.

Teratogenicity Not available.

Specific target organ toxicity (single exposure) Not available.

Specific target organ toxicity (repeated exposure) Not available.


United States

Gel Etchant


Aspiration hazard Not available.




Eye contact : Causes serious eye damage. Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory

system. Skin contact : Causes severe burns. Ingestion : Corrosive to the digestive tract. Causes burns. May cause burns to mouth, throat and

stomach.

Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following:

pain watering redness

Inhalation Skin contact

Ingestion

: No specific data. : Adverse symptoms may include the following:

pain or irritation redness blistering may occur

: Adverse symptoms may include the following: stomach pains


Short term exposure Potential immediate effects

: Not available.

Potential delayed effects : Not available. Long term exposure


: Not available.

Potential delayed effects : Not available. Potential chronic health effects Not available.

General : Carcinogenicity :

Mutagenicity : Teratogenicity :

No known significant effects or critical hazards. Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. No known significant effects or critical hazards. No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.




United States

Gel Etchant

Section 11. Toxicological information Route ATE value

Oral Dermal

3198.8 mg/kg 7198.8 mg/kg


Toxicity

Product/ingredient name Result Species Exposure Phosphoric acid Acute EC50 105 ppm Fresh water

Acute LC50 60 ppm Fresh water Daphnia - Daphnia magna Fish - Lepomis macrochirus

48 hours 96 hours

Persistence and degradability Not available.

Bioaccumulative potential Not available.

Mobility in soil Soil/water partition coefficient (KOC)

: Not available.


Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal

of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.



UN number UN1805 UN1805 UN1805

UN proper Phosphoric acid solution RQ PHOSPHORIC ACID shipping name (Phosphoric acid) SOLUTION

Phosphoric acid, solution

Transport 8 8 hazard class(es)

8


United States

Gel Etchant

Section 14. Transport information Packing group


III III III

No. No. No.


Reportable quantity 12719.1 lbs / 5774.5 kg [1525.5 gal / 5774.5 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. Limited quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: 5 L Cargo aircraft Quantity limitation: 60 L

Emergency schedules (EmS) F-A, S-B Special provisions 223

Passenger and Cargo Aircraft Quantity limitation: 5 L Packaging instructions: 852 Cargo Aircraft OnlyQuantity limitation: 60 L Packaging instructions: 856 Limited Quantities - Passenger AircraftQuantity limitation: 1 L Packaging instructions: Y841 Special provisions A3

Special provisions A7, IB3, N34, T4, TP1

Special precautions for user


: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.


U.S. Federal regulations

: United States inventory (TSCA 8b): All components are listed or exempted. Clean Water Act (CWA) 311: Phosphoric acid

Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 302/304

: Not listed : Not listed : Not listed : Not listed : Not listed




Gel Etchant


United States

SARA 304 RQ : Not applicable. SARA 311/312

Classification : Immediate (acute) health hazard Delayed (chronic) health hazard


Name % Fire hazard


Reactive Immediate (acute) health hazard

Delayed (chronic) health hazard

Phosphoric acid Cobalt aluminate blue spinel

30-60 0.1-1

No. Yes.

No. No.

No. No.

Yes. No.

No. Yes.

SARA 313 Not applicable.

State regulations Massachusetts :

The following components are listed: PHOSPHORIC ACID

New York : The following components are listed: Phosphoric acid New Jersey : The following components are listed: PHOSPHORIC ACID; COBALT compounds Pennsylvania : The following components are listed: PHOSPHORIC ACID; COBALT COMPOUNDS California Prop. 65

None of the components are listed.



Health * 3

Flammability 0

Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.


Health

0 Flammability 3 0 Instability/Reactivity

Special



History


United States

Gel Etchant


Date of issue/Date of revision Date of previous issue Version Prepared by

: 12/08/2014

: No previous validation : 1 : IHS

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations


Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.


NX3 Nexus® Third Generation Dual Cure Base and Catalyst

Not available.

Paste.



Product type


:

:


SAFETY DATA SHEETNX3 Nexus® Third Generation Dual Cure Base and Catalyst

Product use : Dental product: Permanent cement



:



: [email protected]


SKIN IRRITATION - Category 2EYE IRRITATION - Category 2ASPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3


:

Signal word : Warning

Hazard statements : Causes serious eye irritation.Causes skin irritation.May cause respiratory irritation.

Hazard pictograms :


GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 43%




United States


Section 2. Hazards identificationPrevention : Wear protective gloves. Wear eye or face protection. Use only outdoors or in a well-

ventilated area. Avoid breathing vapor. Wash hands thoroughly after handling.

Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Store locked up.



: None known.


Poly(oxy-1,2-ethanediyl), α,α'-[(1-methylethylidene)di-4,1-phenylene]bis[ω-[(2-methyl-1-oxo-2-propen-1-yl)oxy]-

Not available. 5-10 41637-38-1

7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl bismethacrylate


5-10 72869-86-4

2,2'-ethylenedioxydiethyl dimethacrylate 2,2'-ethylenedioxydiethyl dimethacrylate

5-10 109-16-0

2-hydroxyethyl methacrylate 2-hydroxyethyl methacrylate 5-10 868-77-93-trimethoxysilylpropyl methacrylate 3-trimethoxysilylpropyl

methacrylate0.1-1 2530-85-0

1,1,3,3-tetramethylbutyl hydroperoxide 1,1,3,3-tetramethylbutyl hydroperoxide

0.1-1 5809-08-5




: Not available.


Substance/mixture



: Mixture


Other names


United States







Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:

Protection of first-aiders : In case of major fire and large quantities: No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present,the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.





Inhalation : May cause respiratory irritation.

No known significant effects or critical hazards.:Ingestion

Skin contact : Causes skin irritation.



Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing

No specific data.

Adverse symptoms may include the following:irritationredness

:

:

:






United States



In case of major fire and large quantities: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.



Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxidesphosphorus oxideshalogenated compoundsmetal oxide/oxides

In a fire or if heated, a pressure increase will occur and the container may burst.



Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

:

:

:



:


:


:





:



Large spill :


Small spill :







:


:



United States



Conditions for safe storage,including any incompatibilities

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.

:

None.


Hand protection


Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.


Eye/face protection


:

:


:






Hygiene measures :

Control parameters



Skin protection



Physical state Liquid. [Paste.]

Fruity ester-likeOdor

pH

VariousColor

Not available.


:

:

:

:

:

Appearance


United States


Section 9. Physical and chemical propertiesMelting point

Vapor pressure

Relative density

Vapor density

Solubility

Not available.

2 to 2.5 [Water = 1]

Not available.

Not available.

Insoluble in the following materials: cold water and hot water.



Flash point

Not available.

Not available.

Not available.



:

:

:

:

:

:

:

:

:

:




: Not available.




Not applicable.



Conditions to avoid Keep away from heat and direct sunlight. Heat can cause polymerization with rapid release of energy.


The product is stable.Chemical stability :

:

:



: Hazardous reactions or instability may occur under certain conditions of storage or use.


Hazardous polymerization may occur under certain conditions of storage or use.

Reactive or incompatible with the following materials: oxidizing materials and reducing materials.Amines. Peroxide.


Acute toxicity



United States



2,2'-ethylenedioxydiethyl dimethacrylate

LD50 Oral Rat 10837 mg/kg -

2-hydroxyethyl methacrylate LD50 Oral Rat 4230 mg/kg -3-trimethoxysilylpropyl methacrylate




Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.


Not available.


3-trimethoxysilylpropyl methacrylate

Eyes - Mild irritant Rabbit - 24 hours 500 milligrams

-

Skin - Mild irritant Rabbit - 24 hours 500 milligrams

-


Sensitization

Not available.

Conclusion/Summary

Skin : Kligman score: Grade I (weak sensitizer)

Species




Category 3 Not applicable. Respiratory tract irritation



2,2'-ethylenedioxydiethyl dimethacrylate Category 3 Not applicable. Respiratory tract irritation


1,1,3,3-tetramethylbutyl hydroperoxide Category 3 Not applicable. Respiratory tract irritation

Name Category

Not available.

Aspiration hazard

Not available.

Route of exposure

Target organs


United States



Not available.




Skin contact : Causes skin irritation.


No known significant effects or critical hazards.General :







Skin contact

Ingestion


No specific data.


:

:

:





Oral 53278.7 mg/kg

Route ATE value





: Not available.

Short term exposure



: Not available.

Long term exposure



United States









3.43 to 5.62 2372 high


3 - low


1.88 - low

2-hydroxyethyl methacrylate 0.42 - low3-trimethoxysilylpropyl methacrylate

2.1 - low

1,1,3,3-tetramethylbutyl hydroperoxide

2.9 - low


2-hydroxyethyl methacrylate - - Readily

Toxicity


96 hours




92 to 100 % - 14 days - -



: Not available.

Mobility in soil


United States



:Disposal methods


-

-

-

-

-

-

-

Not regulated.

-

-

Not regulated. Not regulated.

- - -


UN number



Packing group





No. No. No.


: Not available.

:

Section 15. Regulatory informationU.S. Federal regulations :


: Listed


: Not listed


: Not listed


: Not listed


: Not listed

TSCA 8(a) PAIR: mequinol

United States inventory (TSCA 8b): All components are listed or exempted.

SARA 302/304


United States



The following components are listed: MINERAL WOOL FIBER

WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. This product may contain trace amounts of the compound listed below.

Massachusetts :

SARA 313

ethylene oxide Yes. Yes. Yes. Yes.



California Prop. 65


New Jersey : The following components are listed: FLUORIDES

Pennsylvania : None of the components are listed.

State regulations

SARA 304 RQ : 104821.8 lbs / 47589.1 kg [5587.4 gal / 21150.7 L]

ethylene oxide <0.0106 Yes. 1000 - 10 -


Name % EHS (lbs) (lbs)(gallons) (gallons)

SARA 302 TPQ SARA 304 RQ

SARA 311/312

Classification : Immediate (acute) health hazard




5-10 No. No. Yes. Yes. No.


5-10 Yes. No. No. Yes. No.

2-hydroxyethyl methacrylate 5-10 No. No. No. Yes. No.3-trimethoxysilylpropyl methacrylate 0.1-1 No. No. No. Yes. No.1,1,3,3-tetramethylbutyl hydroperoxide 0.1-1 No. No. Yes. Yes. No.

Name % Fire hazard





Not applicable.


United States



History


Version

Notice to reader


:

:

:



Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations

05/15/2015

No previous validation

1


2

0

0

00

2

*


Health

Special


Flammability

Health

Flammability

Physical hazards






United States


Section 16. Other informationTo the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.


United States

NX3 Nexus® Third Generation Light-Cure Cement

Not available.

Paste.



Product type


:

:


SAFETY DATA SHEETNX3 Nexus® Third Generation Light-Cure Cement




:



: [email protected]


SKIN IRRITATION - Category 2EYE IRRITATION - Category 2ASKIN SENSITIZATION - Category 1SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3


:


Hazard statements : Causes serious eye irritation.Causes skin irritation.May cause an allergic skin reaction.May cause respiratory irritation.

Hazard pictograms :


Prevention : Wear protective gloves. Wear eye or face protection. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash hands thoroughly after handling.Contaminated work clothing should not be allowed out of the workplace.

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 36.1%




United States


Section 2. Hazards identificationResponse : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for

breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Store locked up.



: None known.



Not available. 5-10 41637-38-1



5-10 72869-86-4

2,2'-ethylenedioxydiethyl dimethacrylate 2,2'-ethylenedioxydiethyl dimethacrylate

5-10 109-16-0

2-hydroxyethyl methacrylate 2-hydroxyethyl methacrylate 1-5 868-77-93-trimethoxysilylpropyl methacrylate 3-trimethoxysilylpropyl

methacrylate0.1-1 2530-85-0




: Not available.


Substance/mixture



: Mixture


Other names






Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:






United States



Protection of first-aiders : In case of major fire and large quantities: No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present,the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.Wash contaminated clothing thoroughly with water before removing it, or wear gloves.





Skin contact : Causes skin irritation. May cause an allergic skin reaction.


Skin contact

Ingestion


No specific data.


:

:

:








Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxideshalogenated compoundsmetal oxide/oxides





Extinguishing media

:

:

:



:


:


:


United States






:



Large spill :


Small spill :








Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.

:

:


:


None.









Hygiene measures :

Control parameters



Skin protection


United States


Section 8. Exposure controls/personal protectionHand protection




:


:



Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid. [Paste.]

Not available.

2 to 2.5 [Water = 1]

Not available.

Not available.

Insoluble in the following materials: cold water and hot water.

Fruity ester-likeOdor

pH

VariousColor



Flash point

Not available.

Not available.

Not available.

Not available.




:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Appearance




: Not available.




Not applicable.








United States




Conditions to avoid Keep away from heat and direct sunlight. Heat can cause polymerization with rapid release of energy.


:

:

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials and reducing materials.Amine. Peroxide.


Acute toxicity



2-hydroxyethyl methacrylate LD50 Oral Rat 4230 mg/kg -3-trimethoxysilylpropyl methacrylate




Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.


Not available.


3-trimethoxysilylpropyl methacrylate

Eyes - Mild irritant Rabbit - 24 hours 500 milligrams

-


-


Sensitization

Not available.

Species







2,2'-ethylenedioxydiethyl dimethacrylate Category 3 Not applicable. Respiratory tract irritation


Name Category Route of exposure

Target organs



United States



Not available.




Skin contact : Causes skin irritation. May cause an allergic skin reaction.


Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.

General :







Skin contact

Ingestion


No specific data.


:

:

:




Not available.


Oral 245583 mg/kg

Route ATE value


Aspiration hazard

Not available.




: Not available.

Short term exposure



: Not available.

Long term exposure



United States









3.43 to 5.62 2372 high


3 - low


1.88 - low

2-hydroxyethyl methacrylate 0.42 - low3-trimethoxysilylpropyl methacrylate

2.1 - low


2-hydroxyethyl methacrylate - - Readily

Toxicity


96 hours




92 to 100 % - 14 days - -



: Not available.

Mobility in soil


:Disposal methods


United States



-

-

-

-

-

-

-

Not regulated.

-

-


- - -


UN number



Packing group





No. No. No.


: Not available.

:



: Listed


: Not listed


: Not listed


: Not listed


: Not listed

TSCA 8(a) PAIR: mequinol; oxybenzone


SARA 302/304

SARA 304 RQ : 126262.6 lbs / 57323.2 kg [6730.3 gal / 25477 L]

ethylene oxide <0.0088 Yes. 1000 - 10 -


Name % EHS (lbs) (lbs)(gallons) (gallons)

SARA 302 TPQ SARA 304 RQ

SARA 311/312




United States



The following components are listed: MINERAL WOOL FIBER

WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm.

Massachusetts :

SARA 313

ethylene oxide Yes. Yes. Yes. Yes.Titanium dioxide Yes. No. No. No.



California Prop. 65


New Jersey : The following components are listed: FLUORIDES

Pennsylvania : None of the components are listed.

State regulations




5-10 No. No. Yes. Yes. No.


5-10 Yes. No. No. Yes. No.

2-hydroxyethyl methacrylate 1-5 No. No. No. Yes. No.3-trimethoxysilylpropyl methacrylate 0.1-1 No. No. No. Yes. No.

Name % Fire hazard




Not applicable.

Section 16. Other informationHazardous Material Information System (U.S.A.)

2

0

0

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2

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Health

Special


Flammability

Health

Flammability

Physical hazards




United States



History

IHS


Version

Prepared by


Notice to reader


:

:

:

:




04/02/2015


1




United States

NX3 Nexus® Third Generation Try-In Gel

Not available.

Paste.



Product type


:

:


SAFETY DATA SHEETNX3 Nexus® Third Generation Try-In Gel




:



: [email protected]


EYE IRRITATION - Category 2BClassification of the substance or mixture

:


Hazard statements : Causes eye irritation.


Prevention : Wear eye or face protection. Wash hands thoroughly after handling.

Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Not applicable.

Disposal : Not applicable.

GHS label elements




: None known.


United States



glycerol glycerol 60-100 56-81-5




: Not available.


Substance/mixture



: Mixture


Other names






Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.



Inhalation : No known significant effects or critical hazards.


Skin contact : No known significant effects or critical hazards.

Causes eye irritation.:Eye contact


Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

:

:

:

Eye contact : Adverse symptoms may include the following:irritationwateringredness




United States



Protection of first-aiders : In case of major fire and large quantities: No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.







Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides





Extinguishing media

:

:

:



:


:


:





:



Large spill :


Small spill :





United States






Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

:

:


:


glycerol OSHA PEL 1989 (United States, 3/1989). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 10 mg/m³ 8 hours. Form: Total dustOSHA PEL (United States, 2/2013). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust


Ingredient name Exposure limits








Hygiene measures :

Control parameters



Skin protection


United States


Section 8. Exposure controls/personal protectionHand protection




:


:



Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid. [Paste.]

Not available.

1.7 [Water = 1]

Not available.

Not available.

Partially soluble in the following materials: cold water and hot water.

Odorless.Odor

pH

VariousColor



Flash point

Not available.

Not available.

Not available.

Not available.




:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Appearance




: Not available.




Not applicable.


United States




Conditions to avoid No specific data.



:

:






No specific data.


Acute toxicity

glycerol LD50 Oral Rat 12600 mg/kg -


Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.


Not available.


glycerol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams

-


-


Sensitization


skin Guinea pig Not sensitizing

Product/ingredient name Route of exposure

Species Result

Species


Not available.



United States



Not available.


Inhalation : No known significant effects or critical hazards.


Skin contact : No known significant effects or critical hazards.

Causes eye irritation.:Eye contact

No known significant effects or critical hazards.General :







Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

:

:

:

Eye contact : Adverse symptoms may include the following:irritationwateringredness




Not available.



Aspiration hazard

Not available.




: Not available.

Short term exposure



: Not available.

Long term exposure



United States



Oral 40918.3 mg/kg

Route ATE value






glycerol -1.76 - low

Toxicity

Not available.


glycerol 301D Ready Biodegradability -Closed Bottle Test

93 % - 30 days - -



: Not available.

Mobility in soil


:Disposal methods


-

-

-

-

-

Not regulated.

-



UN number




United States


Section 14. Transport information- - -

- - -

Packing group





No. No. No.


: Not available.

:


SARA 313


: Listed


: Not listed


: Not listed


: Not listed


: Not listed

State regulations

TSCA 4(a) final test rules: hexa-2,4-dienoic acid


SARA 302/304

SARA 304 RQ : Not applicable.



SARA 311/312


glycerol 60-100 No. No. No. Yes. No.

Name % Fire hazard





Not applicable.


United States


Section 15. Regulatory informationThe following components are listed: TITANIUM DIOXIDE; MINERAL WOOL FIBER;GLYCERINE MIST

WARNING: This product contains a chemical known to the State of California to cause cancer.

Massachusetts :

Titanium dioxide Yes. No. No. No.



California Prop. 65


New Jersey : The following components are listed: TITANIUM DIOXIDE; TITANIUM OXIDE (TiO2);GLYCERIN; 1,2,3-PROPANETRIOL

Pennsylvania : The following components are listed: TITANIUM OXIDE (TIO2); 1,2,3-PROPANETRIOL


History


Version


:

:

:

04/01/2015


1


1

0

0

00

1

*


Health

Special


Flammability

Health

Flammability

Physical hazards






United States


Section 16. Other informationIHSPrepared by


Notice to reader

:





United States

MATERIAL SAFETY DATA SHEET SILANE PRIMER SAFETY DATA SHEET SILANE PRIMER ......

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