Materi al Safety Data Sheet -...

MATERIAL SAFETY DATA SHEET 3M Scotchkote Epoxy Concrete Repair 474 (Lt Grey) (Kit) 06/03/10

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Material Safety Data Sheet

Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

PRODUCT NAME: 3M Scotchkote Epoxy Concrete Repair 474 (Lt Grey) (Kit) MANUFACTURER: 3M

DIVISION: 3M United KingdomCorrosion Protection Products Division

ADDRESS: 3M CenterSt. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 06/03/10Supercedes Date: Initial Issue

Document Group: 28-4608-7

ID Number(s):

GR-2001-2161-8

This product is a kit or a multipart product which consists of multiple, independently packaged components. An MSDS for each of these components is included. Please do not separate the component MSDSs from this cover page. The document numbers of the MSDSs for components of this product are:

28-0034-0, 28-0052-2, 28-0068-8, 27-9185-3, 27-9153-1

No revision information is available.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

MATERIAL SAFETY DATA SHEET 3M Scotchkote Epoxy Concrete Repair 474 (Lt Grey) (Kit) 06/03/10

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MATERIAL SAFETY DATA SHEET 3M Scotchkote Epoxy Concrete Repair 474 (Part B) 07/06/10

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SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: 3M Scotchkote Epoxy Concrete Repair 474 (Part B) MANUFACTURER: 3M




Issue Date: 07/06/10Supercedes Date: 01/15/10


Product Use:Intended Use: CoatingSpecific Use: Concrete repair mortar

SECTION 2: INGREDIENTS

Ingredient C.A.S. No. % by WtISOPHORONE DIAMINE 2855-13-2 20 - 35BENZYL ALCOHOL 100-51-6 25 - 35NON-HAZARDOUS MATERIALS Mixture 10 - 20POLY(OXYPROPYLENE)DIAMINE 9046-10-0 5 - 15P-TERT-BUTYLPHENOL 98-54-4 5 - 15SALICYLIC ACID 69-72-7 1 - 5M-XYLENE-ALPHA,ALPHA'-DIAMINE 1477-55-0 1 - 5TRIMETHYLHEXAMETHYLENEDIAMINE 25620-58-0 1 - 5NONYLPHENOL 25154-52-3 1 - 5N-AMINOETHYLPIPERAZINE 140-31-8 1 - 5

SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW


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Odor, Color, Grade: Ammoniacal odor; Pale straw colorGeneral Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause chemical skin burns. May cause allergic skin reaction. May cause chemical gastrointestinal burns. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

3.2 POTENTIAL HEALTH EFFECTS

Eye Contact:Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision.

May be harmful if absorbed through eyes.

Skin Contact:May be harmful if absorbed through skin.

Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction.

Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Prolonged or repeated exposure may cause: Dermal Effects: Signs/symptoms may include changes in skin pigmentation and/or coloration.

Inhalation:May be harmful if inhaled.

Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

May be absorbed following inhalation and cause target organ effects.

Ingestion:May be harmful if swallowed.

Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen.

May be absorbed following ingestion and cause target organ effects.

Target Organ Effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,

slowed reaction time, slurred speech, giddiness, and unconsciousness.

Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.


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Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES

The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.

Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.

Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse.

Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.

If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Autoignition temperature Not ApplicableFlash Point >=100 ºC [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data Available

5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).

Unusual Fire and Explosion Hazards: Not applicable.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautionsEvacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in


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accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode.

Environmental proceduresFor larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.

Clean-up methodsObserve precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLINGFor industrial or professional use only. Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid contact with oxidizing agents.

7.2 STORAGEStore away from areas where product may come into contact with food or pharmaceuticals. Store away from acids. Store away from oxidizing agents. Store at temperatures between 5-32 degrees C (40-90 degrees F).

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLSUse with appropriate local exhaust ventilation. If exhaust ventilation is not available, use appropriate respiratory protection.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Indirect Vented Goggles and Full Faceshield.

8.2.2 Skin ProtectionAvoid skin contact.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl RubberNitrile RubberPolyethylene/Ethylene Vinyl Alcohol. The following protective clothing material(s) are recommended: Boots - NitrileCoveralls - Disposable, Tychem 10,000


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Apron - Polyethylene ethylene vinyl alcohol.

8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Fullface air-purifying respirator with organic vapor cartridges and P100 particulate prefiltersFullface supplied-air respirator. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.

8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES

Ingredient Authority Type Limit Additional InformationBENZYL ALCOHOL AIHA TWA 44 mg/m3 M-XYLENE-ALPHA,ALPHA'-DIAMINE ACGIH CEIL 0.1 mg/m3 Skin Notation*

* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.

SOURCE OF EXPOSURE LIMIT DATA:ACGIH: American Conference of Governmental Industrial HygienistsCMRG: Chemical Manufacturer Recommended GuidelineOSHA: Occupational Safety and Health AdministrationAIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Odor, Color, Grade: Ammoniacal odor; Pale straw colorGeneral Physical Form: Liquid Autoignition temperature Not ApplicableFlash Point >=100 ºC [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableBoiling point >=200 ºCDensity 1.0 g/mlVapor Density No Data Available

Vapor Pressure No Data Available

Specific Gravity 1.0 [Ref Std: WATER=1]pH > 8 Melting point Not Applicable

Solubility in Water NegligibleEvaporation rate No Data AvailableVolatile Organic Compounds 0 g/l [Test Method: Estimated] [Details: EU Definition]Kow - Oct/Water partition coef No Data AvailablePercent volatile 0 % weight


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Viscosity No Data Available

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.

Materials and Conditions to Avoid: 10.1 Conditions to avoidAvoid curing large quantities of material to prevent a premature reaction (exotherm) with production of intense heat and smoke.Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature reaction (exothem) with production of intense heat and smoke.

10.2 Materials to avoidAminesReaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure buildup.Strong acidsStrong basesStrong oxidizing agents

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products

Substance ConditionCarbon monoxide During CombustionCarbon dioxide During CombustionOxides of Nitrogen During Combustion

SECTION 11: TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

Not determined.

CHEMICAL FATE INFORMATION

Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS


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Waste Disposal Method: Dispose of completely cured (or polymerized) wastes in a sanitary landfill.As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible material.

EPA Hazardous Waste Number (RCRA): Not regulated

Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION

ID Number(s):GR-2001-1241-9, GR-2001-1245-0

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONSContact 3M for more information.

311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes

STATE REGULATIONSContact 3M for more information.

CHEMICAL INVENTORIESContact 3M for more information.

INTERNATIONAL REGULATIONSContact 3M for more information.


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This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION

NFPA Hazard ClassificationHealth: 3 Flammability: 1 Reactivity: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Revision Changes:Section 3: Potential effects from skin contact information was modified.Section 3: Potential effects from inhalation information was modified.Section 8: Eye/face protection information was modified.Section 8: Skin protection - recommended gloves information was modified.Section 8: Respiratory protection - recommended respirators information was modified.Section 8: Skin protection - protective clothing information was modified.Section 3: Immediate other hazard(s) was modified.Section 3: Other health effects information was modified.Sections 3 and 9: Odor, color, grade information was modified.Section 9: Specific gravity information was modified.Section 2: Ingredient table was modified.Section 8: Exposure guidelines ingredient information was modified.Section 10: Materials to avoid physical property was modified.Section 10: Conditions to avoid physical property was modified.Section 6: Environmental procedures heading was added.Section 6: Personal precautions heading was added.Section 6: Clean-up methods heading was added.Section 6: Release measures heading was deleted.Sections 3 and 9: Specific physical form information was deleted.Sections 3 and 9: Specific physical form heading was deleted.



3M MSDSs are available at www.3M.com

MATERIAL SAFETY DATA SHEET 3M Scotchkote Epoxy Repair Primer 080 (Part A) 10/04/10

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PRODUCT NAME: 3M Scotchkote Epoxy Repair Primer 080 (Part A) MANUFACTURER: 3M






Product Use:Intended Use: CoatingSpecific Use: Concrete sealer


Ingredient C.A.S. No. % by Wt4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER 25068-38-6 50 - 70PHENOL-FORMALDEHYDE POLYMER GLYCIDYL ETHER 28064-14-4 20 - 30OXIRANE, MONO[(C12-14-ALKYLOXY)METHYL]DERIVATIVES 68609-97-2 10 - 20



Specific Physical Form: LiquidOdor, Color, Grade: Faint Epoxy Odor Clear Yellow ColorGeneral Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause allergic skin reaction.


Eye Contact:


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Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.


Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.




Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.

Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse.


If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention.



Autoignition temperature >=400 ºCFlash Point >=130 ºC [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data Available






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Personal precautionsEvacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode.

Environmental proceduresFor larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.





7.2 STORAGEStore away from acids. Store away from oxidizing agents. Store at temperatures between 5-32 degrees C (40-90 degrees F).


8.1 ENGINEERING CONTROLSUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.


8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Indirect Vented Goggles.

8.2.2 Skin Protection


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Avoid skin contact.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber. The following protective clothing material(s) are recommended: Apron - Neoprene.

8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.



None Established


Specific Physical Form: LiquidOdor, Color, Grade: Faint Epoxy Odor Clear Yellow ColorGeneral Physical Form: Liquid Autoignition temperature >=400 ºCFlash Point >=130 ºC [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableBoiling point >=200 ºCDensity 1.130 g/mlVapor Density No Data AvailableVapor Pressure <=0.00001 mbar [@ 20 ºC]Specific Gravity 1.130 [Ref Std: WATER=1]pH No Data AvailableMelting point Not ApplicableSolubility in Water NegligibleEvaporation rate No Data AvailableKow - Oct/Water partition coef No Data AvailablePercent volatile 0 % volumeViscosity No Data Available


Stability: Stable.



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10.2 Materials to avoidAcceleratorsAminesStrong acidsStrong basesStrong oxidizing agents



Substance ConditionAldehydes During CombustionCarbon monoxide During CombustionCarbon dioxide During Combustion




ECOTOXICOLOGICAL INFORMATIONNot determined.

CHEMICAL FATE INFORMATIONNot determined.


Waste Disposal Method: Cure (harden, set, or react) the product according to product instructions.Dispose of completely cured (or polymerized) wastes in a sanitary landfill.As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible material.Combustion products will include HCl. Facility must be capable of handling halogenated materials.




ID Number(s):GR-2001-2381-2


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For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.



311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes


CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.

All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.

Contact 3M for more information.






Revision Changes:Section 8: Eye/face protection information was modified.Section 8: Skin protection - recommended gloves information was modified.Section 8: Respiratory protection - recommended respirators information was modified.Section 8: Skin protection - protective clothing information was modified.Section 14: Transportation legal text was modified.Section 9: Vapor pressure value was modified.Section 1: Initial issue message was modified.


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Section 14: ID Number(s) Template 1 was modified.Section 10: Materials to avoid physical property was modified.Section 10: Conditions to avoid physical property was modified.Section 6: Environmental procedures heading was added.Section 6: Personal precautions heading was added.Section 6: Clean-up methods heading was added.Section 6: Release measures heading was deleted.




MATERIAL SAFETY DATA SHEET 3M Scotchkote Epoxy Concrete Repair 474 (Part A) 12/07/10

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PRODUCT NAME: 3M Scotchkote Epoxy Concrete Repair 474 (Part A) MANUFACTURER: 3M








Ingredient C.A.S. No. % by Wt4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER 25068-38-6 55 - 65PHENOL-FORMALDEHYDE POLYMER GLYCIDYL ETHER 28064-14-4 20 - 30OXIRANE, MONO[(C12-14-ALKYLOXY)METHYL]DERIVATIVES 68609-97-2 10 - 20



Odor, Color, Grade: Faint epoxy odor; Clear yellow colorGeneral Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause allergic skin reaction.


Eye Contact:Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.


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Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.













Autoignition temperature >=400 ºCFlash Point >=130 ºC [Test Method: Closed Cup]Flammable Limits(LEL) No Data AvailableFlammable Limits(UEL) No Data Available



Special Fire Fighting Procedures: Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).


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6.1. Personal precautions, protective equipment and emergency proceduresEvacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode.

6.2. Environmental precautionsFor larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.





7.2 STORAGEStore away from acids. Store away from oxidizing agents. Store at temperatures between 5-32 degrees C (40-90 degrees F).


8.1 ENGINEERING CONTROLSUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.


8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Indirect Vented Goggles.


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Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: NeopreneNitrile Rubber.

8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.



None Established


Odor, Color, Grade: Faint epoxy odor; Clear yellow colorGeneral Physical Form: Liquid Autoignition temperature >=400 ºCFlash Point >=130 ºC [Test Method: Closed Cup]Flammable Limits(LEL) No Data AvailableFlammable Limits(UEL) No Data AvailableBoiling Point >=200 ºCDensity 1.130 g/mlVapor Density No Data AvailableVapor Pressure <=0.00001 mbar [@ 20 ºC]Specific Gravity 1.130 [Ref Std: WATER=1]pH No Data AvailableMelting point Not ApplicableSolubility in Water NegligibleEvaporation rate No Data AvailableVolatile Organic Compounds 0 g/l [Test Method: Estimated] [Details: EU Definition (Part A and

Part B Mix)]Kow - Oct/Water partition coef No Data AvailablePercent volatile 0 % weightViscosity No Data Available


Stability: Stable.

Materials and Conditions to Avoid: 10.1 Conditions to avoidAvoid curing large quantities of material to prevent a premature reaction (exotherm) with production of intense heat and smoke.


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Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature reaction (exothem) with production of intense heat and smoke.

10.2 Materials to avoidAcceleratorsAminesReaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure buildup.Strong acidsStrong basesStrong oxidizing agents










Waste Disposal Method: Dispose of completely cured (or polymerized) wastes in a sanitary landfill.As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible material.Combustion products will include HCl. Facility must be capable of handling halogenated materials.





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ID Number(s):GR-2001-1244-3, GR-2001-1247-6




311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No



All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information.






Revision Changes:Section 15: Inventories information was modified.Section 9: Boiling point information was modified.Section 5: Flammable limits (UE) information was modified.Section 5: Flammable limits (LEL) information was modified.Section 9: Flammable limits (LEL) information was modified.


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Section 9: Flammable limits (UEL) information was modified.Section 14: ID Number(s) Template 1 was modified.Section 6: 6.2. Environmental precautions heading was modified.Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was modified.




MATERIAL SAFETY DATA SHEET 3M Scotchkote Epoxy Repair Primer 080 (Part B) 11/30/10

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PRODUCT NAME: 3M Scotchkote Epoxy Repair Primer 080 (Part B) MANUFACTURER: 3M






Product Use:Intended Use: CoatingSpecific Use: Concrete Sealer


Ingredient C.A.S. No. % by WtNON-HAZARDOUS INGREDIENTS Mixture 50 - 60BENZYL ALCOHOL 100-51-6 10 - 20ISOPHORONE DIAMINE 2855-13-2 5 - 15TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL)PHENOL 90-72-2 1 - 10ETHANOL 64-17-5 1 - 10P-TERT-BUTYLPHENOL 98-54-4 1 - 5N-AMINOETHYLPIPERAZINE 140-31-8 1 - 5PINE OIL 8002-09-3 < 5



Specific Physical Form: LiquidOdor, Color, Grade: Ammoniacal Odor; Amber ColorGeneral Physical Form: Liquid Immediate health, physical, and environmental hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.


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May cause chemical eye burns. May cause allergic skin reaction. May cause chemical skin burns. May cause chemical gastrointestinal burns. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Contains a chemical or chemicals which can cause cancer.


Eye Contact:Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision.

Ocular Effects: Signs/symptoms may include redness, pain, and blurred or impaired vision.

Skin Contact:Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction.


Prolonged or repeated exposure may cause: Dermal Effects: Signs/symptoms may include changes in skin pigmentation and/or coloration.


May be absorbed following inhalation and cause target organ effects.

Ingestion:May be harmful if swallowed.

Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen.

May be absorbed following ingestion and cause target organ effects.

Target Organ Effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,

slowed reaction time, slurred speech, giddiness, and unconsciousness.

Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.

Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice.

Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased


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protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.

Contains a chemical or chemicals which can cause birth defects or other reproductive harm.Note: This product contains ethanol. There are data associating human consumption of alcoholic beverages (ethanol) with developmental toxicity. This is not an expected effect during the foreseeable use of this product.

Carcinogenicity:NOTE: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of

ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Contains a chemical or chemicals which can cause cancer.

Ingredient C.A.S. No. Class Description RegulationETHANOL 64-17-5 Grp. 1: Carcinogenic to

humansInternational Agency for Research on Cancer




Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.

Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse.


If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention.



Autoignition temperature >=300 ºCFlash Point 45 ºC [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data Available



Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained


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breathing apparatus (SCBA).

Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.



Personal precautionsEvacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard.

Environmental proceduresPlace in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.

Clean-up methodsRefer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container.



7.1 HANDLINGFor industrial or professional use only. Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.

7.2 STORAGEStore away from areas where product may come into contact with food or pharmaceuticals. Store away from heat. Store out of direct sunlight. Store away from acids. Store away from oxidizing agents. Store at Temperatures between 5-32 degrees C (40-90 degrees F).


8.1 ENGINEERING CONTROLSUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits


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and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.


8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Indirect Vented Goggles and Full Faceshield.


Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl RubberPolyethylene/Ethylene Vinyl Alcohol. The following protective clothing material(s) are recommended: Apron - Polyethylene ethylene vinyl alcoholBoots - Rubber.

8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Fullface air-purifying respirator with organic vapor cartridges and N95 particulate prefilters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.



Ingredient Authority Type Limit Additional InformationBENZYL ALCOHOL AIHA TWA 44 mg/m3 ETHANOL ACGIH STEL 1000 ppm ETHANOL OSHA TWA 1900 mg/m3 PINE OIL CMRG TWA 100 ppm TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL)PHENOL

CMRG TWA 5 ppm



Specific Physical Form: LiquidOdor, Color, Grade: Ammoniacal Odor; Amber ColorGeneral Physical Form: Liquid Autoignition temperature >=300 ºCFlash Point 45 ºC [Test Method: Closed Cup]


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Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableBoiling point >=80 ºCDensity 1.00 g/mlVapor Density No Data AvailableVapor Pressure <=10 mmHg [@ 25 ºC]Specific Gravity 1.000 [Ref Std: WATER=1]pH >=8 [Details: Alkaline]Melting point No Data AvailableSolubility in Water Slight (less than 10%)Evaporation rate No Data AvailableVolatile Organic Compounds 16.5 g/l [Test Method: Estimated] [Details: EU Definition (Part A

and B mix)]Kow - Oct/Water partition coef No Data AvailablePercent volatile 5 % weightViscosity No Data Available


Stability: Stable.


10.2 Materials to avoidAminesReaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure buildup.Strong acidsStrong basesStrong oxidizing agents



Substance ConditionCarbon monoxide During CombustionCarbon dioxide During CombustionOxides of Nitrogen During Combustion





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Waste Disposal Method: Dispose of waste product in a permitted hazardous waste facility.

EPA Hazardous Waste Number (RCRA): D001 (Ignitable)



ID Number(s):GR-2001-1251-8, GR-2001-1253-4




311/312 Hazard Categories:Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes



All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.

Contact 3M for more information.



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Revision Changes:Section 2: Ingredient table was modified.Section 8: Exposure guidelines ingredient information was modified.Section 3: Carcinogenicity table was modified.




MATERIAL SAFETY DATA SHEET 3M Scotchkote Epoxy Concrete Repair 474 (Aggregate), Light Grey 12/21/10

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PRODUCT NAME: 3M Scotchkote Epoxy Concrete Repair 474 (Aggregate), Light Grey MANUFACTURER: 3M








Ingredient C.A.S. No. % by WtQUARTZ SILICA 14808-60-7 80 - 90OXIDE GLASS CHEMICALS 65997-17-3 10 - 20ALUMINUM OXIDE 1344-28-1 1 - 54,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER 25068-38-6 < 1OXIRANE, MONO[(C12-14-ALKYLOXY)METHYL]DERIVATIVES 68609-97-2 < 1PHENOL-FORMALDEHYDE POLYMER GLYCIDYL ETHER 28064-14-4 < 1EPICHLOROHYDRIN-PHENOL-FORMALDEHYDE RESIN 9003-36-5 < 1



Specific Physical Form: Colored aggregateOdor, Color, Grade: Faint epoxy odor; Light grey colorGeneral Physical Form: Solid Immediate health, physical, and environmental hazards: May cause allergic skin reaction. Contains a chemical or chemicals which can cause cancer.


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Eye Contact:Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.

Skin Contact:Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.



Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests.

Silicosis: Signs/symptoms may include breathlessness, weakness, chest pain, persistent cough, increased amounts of sputum, and heart disease.


Carcinogenicity:Contains a chemical or chemicals which can cause cancer.

Ingredient C.A.S. No. Class Description RegulationQUARTZ SILICA 14808-60-7 Grp. 1: Carcinogenic to

humansInternational Agency for Research on Cancer

SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE)

SEQ677 Grp. 1: Carcinogenic to humans

International Agency for Research on Cancer

SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE)

SEQ677 Known human carcinogen National Toxicology Program Carcinogens






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Autoignition temperature >=400 ºCFlash Point No flash pointFlammable Limits(LEL) Not ApplicableFlammable Limits(UEL) Not Applicable







6.1. Personal precautions, protective equipment and emergency proceduresEvacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode.

6.2. Environmental precautionsPlace in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.

Clean-up methodsObserve precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Collect as much of the spilled material as possible. Clean up residue.




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7.1 HANDLINGFor industrial or professional use only. Avoid breathing of airborne material. Avoid eye contact with dust or airborne particles. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid contact with oxidizing agents.

7.2 STORAGEStore away from acids. Store away from oxidizing agents. Store at temperatures between 5-32 degree C (40-90 degrees F).


8.1 ENGINEERING CONTROLSUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment.


8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Safety Glasses with side shields.


Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: NeopreneNitrile Rubber.

8.2.3 Respiratory ProtectionAvoid breathing of dust.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with N95 particulate filters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.



Ingredient Authority Type Limit Additional InformationALUMINUM OXIDE CMRG TWA 1 fiber/cc ALUMINUM OXIDE OSHA TWA, respirable

fraction5 mg/m3

ALUMINUM OXIDE OSHA TWA, as total dust 15 mg/m3 ALUMINUM OXIDE (FIBROUS FORMS ONLY)

OSHA TWA, respirable fraction

5 mg/m3

ALUMINUM OXIDE (FIBROUS FORMS ONLY)

OSHA TWA, as total dust 15 mg/m3

Aluminum, insoluble compounds ACGIH TWA, respirable fraction

1 mg/m3

OXIDE GLASS CHEMICALS 3M TWA, as dust 10 mg/m3


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QUARTZ SILICA ACGIH TWA, respirable fraction

0.025 mg/m3

QUARTZ SILICA OSHA TWA concentration, respirable

0.1 mg/m3

QUARTZ SILICA OSHA TWA concentration, as total dust

0.3 mg/m3



Specific Physical Form: Colored aggregateOdor, Color, Grade: Faint epoxy odor; Light grey colorGeneral Physical Form: Solid Autoignition temperature >=400 ºCFlash Point No flash pointFlammable Limits(LEL) Not ApplicableFlammable Limits(UEL) Not ApplicableBoiling Point >=200 ºCDensity 2.630 g/mlVapor Density No Data AvailableVapor Pressure <=0.001 mmHg [@ 20 ºC]Specific Gravity 2.630 [Ref Std: WATER=1]pH No Data AvailableMelting point No Data AvailableSolubility in Water NegligibleEvaporation rate No Data AvailableVolatile Organic Compounds 0 g/l [Test Method: Estimated] [Details: EU definition]Kow - Oct/Water partition coef No Data AvailablePercent volatile 0 % weightViscosity No Data Available


Stability: Stable.


10.2 Materials to avoidAcceleratorsAminesReaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure buildup.Strong acidsStrong basesStrong oxidizing agents


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Waste Disposal Method: For quantities <100 lbs. (50kg): dispose of waste product in a sanitary landfill. For larger quantities: incinerate in an industrial or commercial facility in the presence of a combustible material. Combustion products will include HCl. Facility must be capable of handling halogenated materials.




ID Number(s):GR-2001-1242-7, GR-2001-1246-8





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311/312 Hazard Categories:Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by WtALUMINUM OXIDE 1344-28-1 1 - 5ALUMINUM OXIDE (ALUMINUM OXIDE (FIBROUS FORMS ONLY))

1344-28-1 1 - 5


CALIFORNIA PROPOSITION 65

Ingredient C.A.S. No. ClassificationSILICA, CRYSTALLINE (AIRBORNE

PARTICLES OF RESPIRABLE SIZE)SEQ677 **Carcinogen

** WARNING: contains a chemical which can cause cancer.


All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information.






Revision Changes:


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Section 8: Eye/face protection information was modified.Section 8: Skin protection - recommended gloves information was modified.Section 8: Respiratory protection - recommended respirators information was modified.Section 14: Transportation legal text was modified.Section 15: Inventories information was modified.Section 9: Vapor pressure value was modified.Section 9: Boiling point information was modified.Section 5: Flammable limits (UE) information was modified.Section 5: Flammable limits (LEL) information was modified.Section 5: Flash point information was modified.Section 1: Initial issue message was modified.Section 9: Flash point information was modified.Section 9: Flammable limits (LEL) information was modified.Section 9: Flammable limits (UEL) information was modified.Section 2: Ingredient table was modified.Section 10: Materials to avoid physical property was modified.Section 10: Conditions to avoid physical property was modified.Section 6: 6.2. Environmental precautions heading was added.Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was added.Section 6: Clean-up methods heading was added.Section 6: Release measures heading was deleted.




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