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  • 8/20/2019 Low Temperatur Cementing

    1/8

    A Study of

    Low

    T cIl lpe ..atu ..c

    Ce:m.enting

    By W THORVALDSON

    (J3th Annual

    T ec hn ic al M ee ti ng , C al ga ry , M ay ,

      962

    STR CT

    Since

    1957

    Dowel l o f Canada has

    been conducting

    a survey,

    in

    th e

    field an d in th e laboratory, of tem

    per at ur es and cementing

    strengths

    encountered

    drilling

    in Western

    Canada. In an attempt to

    rectify

    th e

    seemingly

    i nadequa te cement

    s tr engths , several different correc

    tive

    measures have

    been developed,

    tested

    an d eva luat ed . This paper is

    designed to

      q u ~ n t th e

    i n d u s ~ r y

    with

    th e

    investigatIOn from

    th e

    mI

    t ia l surveys to th e successful cem

    enting of a string of

    casing

    wholly

    in perma frost.

    INTRODUCTION

    W

    ELL temperatures

    exert

    a pro

    found

    effect

    on th e setting

    propert ies o f cement

    slurries.

    Con

    sequently, cements must be

    carc·

    fully formulated so that

    adequate

    thickening times are obtained fo r a

    proper placement

    of

    th e s lu rry, yet

    WOC times

    are not

    unduly pro

    longed.

    In the Canadian oil f ields,

    especially during the winter

    month s, low

    temperatures present

    a formidable problem,

    especially

    in

    setting

    surface casing,

    where

    th e

    formation temperature i s below th e

    freezing

    point of water_ Oddly

    enough. very few d at a a re available

    on formation

    temperatures

    in

    th e

    depth range

    of surface

    casing,

    or

    th e

    effects that

    these temperatures

    have upon cementing practices.

    The range

    of surface

    tempera-

      W

    M . T ho rv al ds on , Dowen

    of

    Canada, Division

    of

    Dow Chmni-

    ca l

    of Canada, Ltd., Cal.gary, Al -

    berta.

    64

    tures encountered

    is

    shown

    in Fig-

    1O'e

    1, which

    shows

    th e

    mean tem

    peratures characteristic of this

    area.   Assuming a liberal

    temp

    erature

    gradient

    of 2°F. per 100

    feet

    an d an

    average

    surface

    pipe

    depth of 600 feet, it may be seen

    that th e B.H.T. varies

    from

    approx·

    imately 50°F . in t he sou th to

    17°F.

    in

    th e

    north.

    These

    temperatures,

    although modified

    by

    th e penetra

    tion o f d ri ll ing fluids, are danger

    ously

    close

    to an d

    often

    below th e

    minimum temperature necessary

    fo r

    t he s et ti ng

    of

    commonly

    used

    cements.

    As

    a n e xampl e

    o f th e fo rmatio n

    temperatures usual ly encountered

    Fignre

    2 shows

    t he t empe ra tu re

    profiles

    of two wells

    surveyed under

    static conditions.

    One

    of these

    wells was located at

    Resolute

    Bay,

    N.W,T_,

    th e

    other

    in

    northern

    Alaska. Both

    of

    these

    wells are in

    th e continuous Perma-frost zone,

    indicating

    from

    1000 to

     5

    feet

    o f Perma-f rost .

    Low

    TEMPERATURE

    CEMENTING

     

    as to accumulate pert inen t

    well data

    and

    perhaps anticipate

    potential low temperature

    prob

    lems,

    an extensive investigation of

    well

    temperaturcs

    during

    cementing

    operations was conducted, studying

    wells

    in a ll sec tions

    of the country

    and at a ll seasons of th e

    year.

    Sub·

    surface temperatures were

    measur

    ed using a

    bottom

    hole recording

    **Metereological Survey

    of

    Canada.

    thermometer

    in

    some

    SUI VC YS.

    a

    n<

    utilizing Surface

    Recording Contin

    uous

    Surveys on o ther s.

    A typical survey, made in Centrn

    Alberta, is

    shown

    in j i ' igl l l ( 3. A

    total

    of

    300 sacJ  s

    o f n ormal

    ( em

    en t slurry containing 2(,;· C akium

    chloride accelerator (slur ry weight

    14.5 lbs. per

    gallon) wa s

    used t

    cement 303 feet of 107. i.

    inC 1l

    dia

    meter

    surface

    casing. SUl faee tpm

    perature was 20

    F. ;

    that of tll

    slurry was

    32 F.

    CirCUlating tem

    perature was 40 F. an d tile temp

    erature of th e

    s lu rry n ·turns wa

    36 F. Thi s cha rt shows

    the record

    ed

    temperatures

    at three diffet pn

    wel l dcp ths, as recorded at inter

    mittent

    time

    intervals.

    A

    similar

    example is

    shown

    i

    FigllTe 4. This

    well. loeated

    in

    Northern

    Alberta, require(l -la

    sacks of oil well ( cment

    containin

    2 /

    c alc ium chlo ri de

    aceelerato

    (slurrv wcight, 1 1.7

    lbs. pC r gallon

    in onjer to cement

    620

    feet of 10

    inch surface casing. ]n tlIis casl

    surface tempemture was 20 F

    while

    that

    of

    th e

    slurry

    was

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    2/8

      igure I . -Map of princ ipal

    Canadian

    oil f ie lds

    showing

    mean temperature isotherms.

    vice of CanadaJ

    MetereologicaI Ser-

    14.5

    lbs.

    pe r

    gallon)

    to

    cement

    491

    feet of 8

    diameter surface

    casing.

    Surface temperature

    was

    20°F.

    that

    of th e

    slurry when int roduced into

    th e well was

    38°F.,

    an d th e circu-

    lating temperature was recorded as

    40°F. The t empe ra tu re

    changes

    occurring at th e 420

    it depth, dur

    in g the first 12 hours following

    slurry placement, ar e s hown. This

    particUlar cementing

    jo b failed

    after

    24

    hours shut-in

    time.

    A series of laboratory

    tests

    was

    conducted t o det ermine th e com·

    TechnologYr

     umm r

    r

     96 lg ry

    pressive

    strengths

    obtainable

    from

    oi l well cement

    slurries

    containing

    2 calc ium chlori de accele ra to r,

    an d

    having

    a slurry

    weight

    of 15.6

    lbs. per gallon,

    allowed

    to

    se t  

    t empe ra tu re s r anging f rom 40° to

    70°F.

    The compressive strengths

    attained over a 30-hour per iod are

    shown

    graphically

    in   igure  

    In Canadian oi l field cementing

    operations,

    most

    c ommon ly u se d

    slurries f or sur fa ce  casing strings

    are 15

    lbs. per gallon or

    less.

    Out

    of 160 cementing

    jobs

    evaluated,

    only

    24

    used

    slurries

    that

    were

    heavier than 15.2 lbs. pe r gallon.

    As

    may

    be

    seen

    in

      igure

    7 which

    shows

    Z4 hour

    compressive

    strengths

    fo r dif ferent weight slur ries   dif-

    ferent temperatures ,

    a

    reduct ion in

    slurry weight

    resu lts i n

    a corres

    pondingly lowered compressive

    strength.

    I t

    will

    be

    noted

    however

    that

    increased

    strength

    is

    attain·

    able fo r lower weight slurries by

    increasing their curing

    temperature.

    For example, 6 hours at 70°F.

    produced a compressive strength of

    65

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    3/8

    404 psi,

    whereas the same

    slurry

    in

    6 hours at

    50°F.

    had only a com

    pressive strength

    of 38 psi . Thus, a

    temperature in cre as e o f only

    20°F.

    re-sulted

    in

    10 times a s g re at a

    com

    press ive s tre ng th . Th es e

    tests

    in

    dicated

    that

    heating

    up th e cement

    slurry

    should

    y ie ld benef ic ia l re

    sults. insofar

    as producing

    higher

    compressive

    strengths

    in

    the set

    cement.

    A

    number

    of

    techniques

    have been developed to

    accomplish

    this purpose , and

    have

    yielded grato

    ifying

    results

    in

    the field. In gen

    eral,

    these techniques

    may

    be

    class

    ified

    in

    three categories:  1 elec

    t r ic heat ing;

     2 chemical heating;

    an d  3 use of h igh Alumina cern·

    ents.

    ELECTRIC HEATING

    METHOD

    Electric heating of cement

    slur

    ries,

    a comparatively recent devel

    opment,

    is

    depicted

    schematically

    in

    Figu ·e

    8. After th e casing ha s

    been cemented, and th e plug dis·

    placed, an

    e lect ri ca l connect ion i s

    made with th e

    cas ing and

     5

    volts

    D.C. is applied. Approximately

    1000 amps of current flows from th e

    cas ing i nt o th e ground.

    The

    elec

    tric circuit is

    completed

    through

    *Patent applied

    for.

    one or more back-electrodes, loca

    ed at a d is tance f rom

    th e

    we

    The

    electrical

    power

    is su pp lie

    from a mobile 450 volt, 105

    amp

    generator, driven by a 700 h.

    Allison motor.

    In general, field test s showe

    that two

    types

    of

    back-electrode

    were

    suitable fo r this application

    (1 )

    an

    offset

    cased

    well,

    or

     2

    number of special ly dri ll ed sli

    holes containing 2-inch tubing

    (n

    coverable)

    connected

    in

    paralle

    Resu lt s o f field tests compar ing di

    ferent types

    of installations

    an

    shown in

    Table 1

    Figure 2.--Subsurface

    temperature

    profiles

    of two

    typical

    wells in th e perrna-frost zone, one located

    at

    Resolute

    Bay, N.W.T., and the other

    i n Nor th ern

    Alaska.

    24

    WELL

    A

    CENTR L  L ERT

    6 12 18

    TIME   HOURS

    1

    I

    I

    f---L

      7  

    I

    Oepth: 5

    Fl

    I

    -

    Oeplh: 125

    Ft

    I

    r ·

    -

    --

    I

    Oep h ;

     5

    60

    40

    60

    40

    60

    u

    °

    _____ NORTH

      ALASKA

      ~ E S O L j U T E \ l j

    BAY N.W.T.

    w

     

    ::>

     

    «

     

    a

    :::E

    8 0 0 0 c - - - - - c 1 ~ 0 , - - - - ~ 2 0 - - . . . , 3 ~ 0 , - - - - - - - - ; ' 4 0 ~

    TEMPERATURE

    OF

    200

     

    W

    W

    u

    I

    400

     

    a

    w

    0

    600

    WELL

    C

    SOUTHERN L ERT

    6 0 ~ ~ = = ~ ~ ~ ~

    Figure 3.-Temperatur€ survey of well in Central

    Alberta,

    dur ing sur fa ce

    c as in g cementing opera

    tions;

    temperatures

    recorded at 50 ft., 125 ft., and

    250 1t. depths.

     

    w

    50

      or

     

    J

    >-

    «

     

    40

     

    w

     

    c..

    ::t

    Veplh: 42

    Fl

    w

    >-

    30

    0 3

    6 9  

    TIME HOURS

     

    o

      6

    12

    TIME HOURS

    4

     

    l

    -

    Vepih: 55 Fi

    I

    70

    WELL

    B

    NORTHERN

     L ERT

    60

    Figu re 4.-Temperature

    survey of wen

    in Northern

    Alberta, dur ing sur fa ce ca sin g c ementin g ope ra

    tions; temperatures recorded at 550 ft .

    depth.

    Figure 5.-Temperature sur vey o f

    well in

    Southern

    Alberta, during

    surface

    casing cementing

    operations;

    temperatures

    recorded at 420 f t. d ep th .

    66

     ournal

     

    anadian Petroleum

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    TABLE  

    Low

    Temperature Cementing Jobs Using

    Electric

    Heating

    700

    1000

    1025

    1000

    0' .54

    10 '

    120' /60' .43

    120' /60' .46

    120' .72

    1

    10

    4

    2

     

    4

    2

     

    2

    2

    2

    2

     

    1

    2

    Back Electrodes

    No. Size Depth

    1 5 12 517

    1 5 h 4880

    1

    5 12

    3135

    197'

    700'

    700'

    215'

    700'

    215'

    8

    Surface Cwing

    Size Depth

    5 12 333

    8 400'

    7

    420'

    8

    215'

    540 I n p ara ll el w it h 4b

    satisfactory

    440 With Red Deer

    River

    in

    parallel satisfactory

    460 Without Red Deer River

    in parallel

    satisfactory

    505

    With Red Deer

    River in

    parallel unsatisfactory

    *Sur fa ce ca sing o f nearby abandoned well u sed

    as

    back

    electrode.

    This phase of th e cementing operation

    was considered

    satisfactory,

    m spit e of th e h igh overall

    resistance.

    The

    relatively

    shallow

    wel l d ep th

    (215

    ft )

    made

    possible

    sufficient

    heating

    at

    th e

    reduced current of

    850

    amps.

    5a

    10 '''

    5e 10,.

    5b 10,.

    4c 8

    Job

    No

    1

    2

    3

    4a

    4b

      n

    Western

    Canada,

    500 ps i is

    usually

    accepted as a satisfactory minimum

    s treng th for drilling out and subsequent hole deepening.

    TABLE

    II .

    Est imated Strength of

    Cement Set

    with

    Electric Heating

    Slurry

    Estimated

    Weight

    Oa1Jl

    Curing

    Electric

    Maximu:rn

    Compress

    Job

    Lbs.

    Additive

    Time

    Heating

    Temp.

    at

    Strength

    No

    U.S. Gal.

    Percent

    Hou rs

    Time Hrs.

    Bottom·oF.

    ps i

    1

    15.6 0

    6 hrs.;

    4

    hrs.

    117

    800

    30 min.

    2

    15.6

    2 12

    hrs.

    7hrs.;

    80.5

    800

    30

    min.

    3 15.0 2

    10

    hrs.

    8hrs.

    83.5 900

    4

    15.0

    2 9

    hrs.

    6hrs.;

    113

    1000

    40 min.

    5

    15.0

    2

    13

    hrs.

    8hrs.

    87.5 1000

    ent, th us ra lsmg its tempera tu re.

    In effect, th e unset

    cement

    acts as

    a

    heating element.

      t

    was found

    that

    enough

    heat was genera ted i n

    the

    cement

    by

    this method

    to jus

    tify

    the

    power

    losses elsewhere.

    Temperature surveys were run

    on a

    well

    i n Central Alberta during

    a

    cementing

    jo b uti lizing elect ric

    heating.

    Th e

    results are shown

    in

    Figu re

    9

    Altogether,

    250

    sacks of

    15.6 lbs . per

    gal lon cemen t s lu rry,

    containi ng 2

    calc ium chlo ri de

    accelerator, were

    used in

    this

    well.

    Surface

    temperature

    wa s

    32°F

     •

    slurry t emperature was 46°F., and

    circulating

    t emperature was

    53°F.

    The

    back·electrode

    was loeate d 1320

    feet

    from

    the

    well.

    The

    four

    curves

    shown

    in

    this

    figure represent:

    (1 ) Well

    temperatures

    immediat

    ely

    after placement of th e

    cement

    slurry;

    (2)

    Well

    temperatures after

    one

    hour

    shut-in time, no

    elec

    tric power applied;

    (3) Temperature

    survey

    after

    4

    1/ 3 hour s o f power applica

    tion;

    and

    survey

    after

    power

    applica-

    (4)

    Temperature

    5

    hours of

    tion.

    121

    173

    219

    262

    300

    Temperature

    Rise

    _

    OF.

    TABLE

     

    Heat

    Liberated

    by

    Chemical Reaction

    Lbs.

    NaOH

    Heat evolved

    _per

    gal.

    Hal

    B.T.U.

    1.02 1016

    1.55 1542

    2.11 2106

    2.71 2695

    3.31 3289

    10

    15

    20

    25

     3

    Hydrochloric

    Acid·

    Percent

    When

    the circuit is complete, the

    power is

    dissipated

    in a number

    of

    ways: (1 )

    losses

    i n sur face cables;

    (2) los ses in

    casing;

    (3) losses in

    unset cement;

    (4) losses

    through

    the earth; and (5) losses in th e

    back-electrodes. These power losses

    are manifested

    in the form

    of hea t,

    and

    th e purpose of the t reatment

    is

    to

    produce

    heat

    in

    th e

    unset

    cern-

    The beneficial

    heating

    effect

    of

    the

    electric

    current

    on

    th e cement

    slurry may

    be

    seen in Table

    II

    which shows est imated

    compressive

    strength data on

    five

    different

    wells

    that

    were cemented using the

    elec-

    Technology Summer 962 algary

    67

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    17 0

     

    15.0 16,0

    SLURRY WEIGHT - LB/GAL.

    - - -

    --t--I -7 o.---I-- ? : --I

    ,

      .

     

    ,

     

    7  ·· ._ .

    ,0°

    .

    1000

    3000, r - - - - : : - : - - - - - : - - r - - - - , - - -_- - - ,

    T MP R TUR

    70°F

      -

    60°

    F -  

    50

    0

    F-············

    40

    0

    F ·_

    2000

    --------,- .--+1---. . . .-_,

    // /

    1000

    700

     

    -

      ~ j

    . /

     -

     

    ......

      -7/

    j

      -

    I

    400

    l-

    . • I

    I

     

    /

    I

    Z

     

    u.J

    200

    i .r 1 j

    z

     

    u.J

    I-

     

    :

    /

     

    l-

    i

    + i ~ ~ j

    < /

    u. J

    >

    100

    u.J

     

    >

     

    70

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    6/8

    TABLE IV.

    IJaboTatory Tests o f H igh A lumina Cement Slu rries

    Slurry

      ont press

    Slurry

    Weight

    Strength

    Volume

    S l l trr y Co mp o si t io n

    Lb Gal

    A v g. p si

    a

    ft .

    High

    Alumina

    Neat

    15.32

    6745

    1.160

    High Alumina -

    Ash

    1:1

    14.26

    960

    2  525

    High

    Alumina - Ash -

    8

    Gel

    13.34

    538

    3.109

    High Alumina - Ash - 10

    Gel

    13.16

    460

    3.257

    High Alumina

    - Litepoz 2

    12.6

    551

    2.31

    High

    Alumina

    - Litepoz 2

    12.8

    727

    2.19

    High Alumina - Litepoz 2 -

    6 Gel· 4 CaCl

    13.45

    828

    2.09

    High Alumina - Litepoz 2 -

    8

    Gel

    -

    4

    CaCI

    13.49

    885

    2.11

    High

    Alumina· Litepoz

    2 - 10

    Gel

    - 4

    CaCI

    13.54

    856

    2.13

    HlGH

    ALUMINA CEMENT

    The

    most

    successful approach to

    the

    low

    temperature problem has

    been

    th e

    use of h ig h Alumina cem

    ents.   normal

    cement

    freezes

    shortly after

    th e

    initial

    se t

    has

    taken place

    th e

    water which

    ha s

    not yet entered into combination

    with

    th e

    cement

    expands

    and dis

    rupts the cement. At

    th e

    same

    time

    chemical

    action

    ceases.

    Even

    though

    the

    cement

    may

    thaw ou t

    later allOWing the chemical action

    to recommence

    th e

    hardening takes

    p lace in

    a

    disrupted

    concrete which

    is inevitably

    much weaker.

    During the

    initial

    set of

    high

    Alumina cement considerable heat

    is generated increasing

    th e

    temper

    ature

    of the slurry.

    In the

    case of

    a reasonably rich

    mix

    and appre

    ciable

    bulk

    of slurry sufficient heat

    is generated to p revent

    th e

    cement

    10 0

    0

    1382

    10

    1.5 0

    1399

    10

    3.0

    0

    1742

    10

    3.0

    4

    1286

    10

    3.0 8

    1087

    10

    3.0

    12

    632

    20 0

    0

    1764

    20

    1.5 0

    1473

    20

    3.0 0

    1490

    30

    0

    0

    2200

    30

    1.5

    0

    1815

    30

    3.0

    0

    1875

    40

    0

    0

    5206

    40

    1.5

    0

    2679

    40

    3.0

    0

    2953

    40

    3.0

    4

    1667

    40

    3.0

    8

    1173

    40

    3.0

    12

    896

    24

    24

    24

    24

    24

    24

    24

    24

    24

    24

    24

    24

    I t

    was

    concluded

    that

    this method

    of

    heating

    cement

    slur ries in low

    temperature

    holes, is ess entially

    simple and

    successful. Although

    practically no expensive supplemen.

    tary

    equipment is required

    th e bulk

    of

    the

    chemicals required

    fo r

    this

    process makes the

    method

    imprac

    tical in remote locations.

    TABLE VI.

    Oompressive

    Strengths

    of

    High

    Alumina

      ements

    Curinp Temp.

    Oomvr. Strength

    Time-Hrs_

    OF Salt

      el

    Average

    ps i

    72

    72

    72

    72

    72

    72

    at

    th e

    time

    of

    cementing

    and at

    v ari ous time intervals thereafter.

    Figure 12 shows a similar jo b con

    ducted

    through

    1500 ft . of 4 -inch

    pipe.

    These tes ts

    indicated

    that

    due

    to

    the heating effect of the injected

    chemicals the cement should have

    a compressive

    strength

    of at least

    500 psi, within 4 to 5 hours time.

    TABLE V

    Thickening

    Times

    o f H ig h

    Alumina

    Cements

    High Alumina -

    Neat

    1 hr .

    40

    min.

    High Alumina -

    1.5

    NaCI

    4

    hr .

    10min.

    High Alumina -

    3

    NaCl 7

    hr .

    34 min.

    High Alumina -

    4

    Gel

    -

    3 NaCI

    2

    hr .

      2min.

    High Alumina -

    8 Gel -

    3 NaCI

    1 hr . 19 min.

    High Alumina -

    12 Gel

    - 3 NaCl 3 hr .

    35

    min.

    Based on t he se dat a an actual

    cementing

    treatment in

    Southern

    Alberta was performed utilizing

    this te chnique. On this

    job

    7 feet

    of

    8

    inch

    diameter

    cas ing was

    set

    using

    15.6 lbs. pe r

    gallon

    slurry

    containing 2 calcium

    chloride

    acce ler ator . Sur fa ce

    temperature

    was

    26°F., wat er t empera tu re was

    32°F.,

    and

    th e

    slurry temperature

    wa s

    38°F.

    Dur ing thi s

    cementing

    operation 700 lbs. of caustic was

    mixed in 5 barrels of water and

    neutralized with 200 gallons

    of

    28

    hydrochloric acid. Two pump trucks

    were used to pump these solutions

    which

    were

    mixed

    immediately

    prior

    to injection down

    the

    casing.

    Figttre 11

    shows

    comparative

    tem

    perature surveys run

    on

    this

    well

    ti c

    solution

    was

    prepared and pump·

    ed down

    th e

    casing.

    Even without

    neutralization considerable benefi

    cial

    heating

    of

    th e

    cement

    slurry in

    the annulus occurred.

    TechnologYr Summer

    962

    algary

    69

  • 8/20/2019 Low Temperatur Cementing

    7/8

     

    -

     _

     

    - .

    -

    _

     

    ...

     

    ·

    J ~

    _  e l t ~

     

    SURFACE)

    160

    u..

    0

    VICAT

      FINAL

    UJ

    a:::

    SET

      >

    I

    80

    -

    ::

     

    O l

     

    a:::

    .

    .

    . - .

    UJ

    a...

    40

    .  -

    UJ

    I

    TIME

    HOURS

    Figure

    1 0 . ~ L a b o r a t o r y temperature tests

    on

    cement s lu rr ies dur ing

    setting,

    ut il izing chemical heating, in

    sim

    ulated format ion.

    from freezing,

    even

    though

    th e

    tem

    perature may be

    many

    degrees

    below

    th e

    freezing point. This prop

    erty of

    high Alumina

    cement slur

    ries recommends

    i t for

    low tempera

    ture use, in

    spite

    of its p remium

    price. Ano th er a dv an ta ge o f

    this

    material

    is that it enables consid

    erable l ightening of th e

    slurry,

    a

    definite

    advantage

    in

    surface

    pipe

    cementing,

    w ith resultant

    lower

    costs

    pe r

    cubic foot

    of

    slurry_

    Various m ixture s of high Alum

    i na cemen t s lu rr ie s wer e

    laboratory

    tested

    at

    40°F., th e borderline

    tem

    perature

    fo r

    normal

    cements. The

    cement,

    additives,

    water an d moulds

    were

    al l

    precooled at

    ·10

    F. fo r 2·

    hours. Mixing an d poring proce

    dures

    wer e car ri ed out al controlled

    temperatures of ·10 >F. The

    resulls

    of these tests ar e shown

    in

    Tn hI

    IV.

    Th e favorable results

    of thesl

    tests, which showed

    adequatf

    I

      -.J

    I .

    I I A F T E R

    \   • CEMENT

    If

     J

    BEFORE

    C E M E N T

    O - - ~ ~ - I ~ - - . - - , - - - r - - - - ,

    ., •.-. ,

     k

    HRS_ LATER

     

    I

    r

    .........

     

    \

    I

    -

    / /

    { : .

    vi

    v Vf HRS

    LATER

    1 5 0 0 0 ; 5 ~ 0 ~ ~ 1 0 ~ 0 : 1 : : . 5 0

    TEMPERA TURE _ OF

    0 . . . .

    ---PRE-CEMENT

    3 0 0 3 ~ 0 - - - - - - - - - - = 5 : : - 0 - - - - - - = 7 : : - 0 - - ~ 9 ; : - 0

    - - ~ 1 l 0

    TEMPERATURE

    OF

    >-

    w

    w  

    500

    ..

    w

    w

    u

    I

    >-

    0

    W

    200

    :r:

    0

     

    0

    W

    Cl

    1000

    Figw e H.-Subsurface

    temperature surveys

    on a

    well in

    Southern

    Alberta

    following surface casing

    cementing operat ions,

    ut il izing chemical heating.

    Figure 12.-Subsurface temperature surveys

    on 1

    well in Southern Alber ta following

    casing

    cement

    in g ope ra ti ons, u ti li zi ng chemica l hea ti ng .

    70

    Journal of Canadian

    Petroleum

  • 8/20/2019 Low Temperatur Cementing

    8/8

    Temperature

    of cement

    returns

    No.1 42°

    No.2

    43

    0

    Temperature at top

    of

    cement

    7 hours

    after

    plug down: 55°

    Top

    of

    cement found to

    be quite

    hard.

    TABLE

    VII.

    Surface Casing Cementing

    Job Done on

    Dome

     

    al Winter

    Harbour

    No 1

    September

    30th,

    1961.

    Conductor pipe: 20 to 77'

    Hole size:  7: 4

    to 1048'

    Casing size: 13 355

    54,5Ib,

    Outside temperature:

    above

    zero

    Wind:

    N.N.W. at

    12 m,p.h,

    Temperature of

    dry

    cement:

    8

    0

    Temperature

    of

    salt

    water

    gel: go

    Temperature

    of

    mix

    water

    (lst 25 bbls.) :45

    0

    Temperature

    o f remaining mix

    water

    (125

    bbls.):

    60

    0

    Started

    mixing:

    6:00

    a.m.

    September

    30th,

    1961

    Temperature

    of slurry

    at mixing tub:

    No.1 300 (Mix water at 45°)

    No.2 40° (changing

    temperature

    of mix

    water)

    No.3 500 (mix

    water at

    60

    0

    )

    No.4

    50°

     m ix

    water

    at

    60

    0

    )

    No.5

    51

    0

    (mix water at 600)

    End mixing: 8:00

    a,m.

    September

    30th,

    1961

    Total

    mix:

    600

    Ciment Fondu w/12 salt water

    gel.

    75

    neat Ciment

    Fondu

    mixing

    water:

    Ocean

    at 3 salt

    Plug released:

    8:08 a.m.

    Plug

    down: 8:30 a.m. Pumped by

    rig

    pump,

    Temperature of mud returns while displacing plug.

    No, 1 45

    0

    No.2 44°

    No,

    3 45

    0

    strength, resulted in s im ilar

    tests

    under more s tr ingent t empe ra tu re

    conditions.

    These

    latter

    t es ts were

    conducted

    at

    temperatures as

    low

    as 10°F in an effort to

    solve

    th e

    problems of extended

    W.O.C. time

    on normal

    surface

    cas ing j ob s

    in

    WesteTIl

    Canada and in th e Perma-

    frost

    zones.

    In

    these

    tests, aU

    cem

    ent, additives, moulds

    and

    cover

    plates were

    brought

    to constant

    temperature at

    10°F.,

    w ith the

    ex

    ception of the

    mix

    water whi ch was

    maintained

    at 40°F.

    Tests were

    mixed i n a Cold Room at

    lOGF.

    an d

    placed

    under

    water

    containing anti

    freeze.

    Thickening

    t imes were de

    t ermined by

    AP I

    Schedule I modi

    fied

    to

    70°F,

    an d

    500

    psi.

    Th e

    reo

    sultant thickening

    times

    an d com

    pressive strengths ar e

    shown

    in

    Tables

    V

    an d

    VI,

    respectively.

    The

    d ata a re

    no t

    fully

    developed

    on

    these tes ts due

    to their severity

    .

    Many

    samples

    were spoiled by con

    taminat ion with antifreeze. Sodium

    chloride was used as

    a

    retarder

    to

    offset th e acceleration effect

    of ben

    tonite

    on t he h igh Alumina

    cement.

    Thickening

    t ime of 12 ge l

    cement

    at 70°F.

    was onl y 12

    minutes.

    Based on

    th e encouraging

    results

    obtained

    dur in g t he se l abo ra to ry

    tests,

    a cementing

    job util izing high

    Alumina

    cement slurry

    was

    per

    formed . Deta ils

    of this

    treatment

    are shown in Table

    VII. In

    spite

    of

    th e

    extremely

    r igorous temper

    ature

    conditions

    under which this

    cementing

    t reatment was conduct

    ed,

    the job

    proved

    highly

    success

    ful

    CONCLUSIONS

    Evaluation of laboratory tests

    an d

    field

    cementing

    treatments

    in

    dicates

    that

    in most cases surface

    cas ing can be successfully an d sec

    urely cemented, even

    a t extremely

    low

    temperatures.

    Apparently. i f

    th e mixing water

    can

    be

    hea ted to

    a temperature

    of

    70 to 80

    o

    F. , th e

    additional heat of

    hydration

    of th e

    h igh Alumina cemen t

    will

    prevent

    freezing from

    occurring

    before th e

    final

    set.

    Additional modification

    an d

    improvement o f

    heating tech

    niques should a ssur e the successful

    performance

    of

    surface casing cem

    enting jobs, even

    under

    rigorous

    low

    temperature

    conditions.