Lime for VCI

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    Types of chemical processes

    eg Quicklime Manufacture

    CaCO3(s) CaO(s) + CO2(g)

    In this case the feedstock is the raw material -limestone- that needs only be crushed.

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    In a batch process the kiln .

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    In a batch process the kiln is filled with layersof limestone and fuel....

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    In a batch process the kiln is filled with layersof limestone and fuel....

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    In a batch process the kiln is filled with layersof limestone and fuel....

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    ....and the latter is set alight.

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    When the reaction is complete and the kiln cool the

    contents are removed ready for the next batch.

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    Why is this simple process not done on a large scale ?

    Cost of labourto fill and empty kiln

    Kiln must be allowed to cool wasting energy

    Extent of reaction may vary within the kiln.

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    In a continuous reactor the limestone is fed intoone end of a heated rotating tube and quicklime

    falls out of the other.

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    ...butratherbigger!

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    What are the advantages of this plant?

    It may be automated so labour costs are minimised

    if decomposition is incomplete it is easy to adjustthe flow rate or temperature to correct this.

    BUT

    An expensive plant is needed dedicated to

    making just one product.

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    Continuous reactors are suitable for high tonnageproduction of a single product.

    Batch reactors can be used to make smallerquantities of several products and canaccommodate slow reactions.

    Which type would be used for:

    A dyestuff

    Sulphuric acidA pharmaceutical

    Batch

    BatchContinuous