Life Cycle Assessment FBSCC - Shonnard_0[1]

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    Life Cycle Assessment of Forest BasedLife Cycle Assessment of Forest Based BiofuelsBiofuels

    David R.David R. ShonnardShonnard; Ph.D.; Ph.D.

    o ns a r ro essor n us a na yo ns a r ro essor n us a na y

    Department of Chemical EngineeringDepartment of Chemical Engineering

    DirectorDirector: Sustainable Futures Institute: Sustainable Futures Institute

    ForestForest BiofuelsBiofuels Statew ide Collaboration Center PresentationStatewide Collaboration Center P resentation

    BiomassProcessing

    e nes ay, u y ,e nes ay, u y ,

    Forest Resources Engines/VehiclesCO2

    Biomass FuelsSustainableDecisions

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    Mana in the Carbon C cle:Mana in the Carbon C cle:A Sustainable Energy ChallengeA Sustainable Energy ChallengeFrom http://www.bom.gov.au/info/climate/change/gallery/index.shtml

    om us on o oss ue s ac s as a ar on ump om us on o oss ue s ac s as a ar on ump

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    COCO and Temperature in theand Temperature in theNorthern Hemisphere are RisingNorthern Hemisphere are Rising

    National Geographic, September 2004, pg 20, National Geographic Society,

    Washington, D.C.

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    WoodWood--toto--Wheels (W2W) ConceptWheels (W2W) ConceptResearch Thematic AreasResearch Thematic Areas

    SustainabilitAssessments /

    Decision-Making

    Bio-Processing Research

    2

    Woody Biomass Resource ResearchVehicle Systems Research

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    An Overview of Life Cycle AssessmentAn Overview of Life Cycle Assessment

    Life Cycle Inventory (LCI)Life Cycle Inventory (LCI)

    Life Cycle Impact Assessment (LCIA)Life Cycle Impact Assessment (LCIA)

    Comparison of ForestComparison of Forest FeedstocksFeedstocks and Powerand Power

    55

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    DecisionDecision--making in industry and governmentmaking in industry and government

    Strategic planning, investments, product/process designStrategic planning, investments, product/process design

    MarketingMarketing

    Environmental claim,Environmental claim, ecolabelingecolabeling

    Communication with stakeholdersCommunication with stakeholders

    Shareholders, regulatory agencies, policy makersShareholders, regulatory agencies, policy makers

    Research and DevelopmentResearch and Development Early evaluations of projects, periodic reEarly evaluations of projects, periodic re--evaluationsevaluations

    66

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    77

    D.T. Allen, University of Texas AustinLife Cycle Assessment: Lesson 1

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    Life C cleLife C cleStagesStagesof a Productof a Product

    88

    . . ,Life Cycle Assessment: Lesson 1

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    Life Cycle AssessmentLife Cycle Assessment

    International Organization for StandardizationInternational Organization for Standardization ISO 14040: Environmental managementISO 14040: Environmental management LifeLife

    cycle assessmentcycle assessment Principles and frameworkPrinciples and framework

    ISO 14041:ISO 14041: Goal and scope definition andGoal and scope definition and

    inventory analysisinventory analysis

    ISO 14042:ISO 14042: Life cycle impact assessmentLife cycle impact assessment

    ISO 14043:ISO 14043: Life cycle interpretationLife cycle interpretation

    99

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    r nc p es an rameworr nc p es an ramewor

    ISO 14040ISO 14040

    Key features of the LCA methodologyKey features of the LCA methodology

    cope must e rom cra e to grave or pro uctscope must e rom cra e to grave or pro ucts

    LCA studies should be transparentLCA studies should be transparent

    S ecific re uirements for com arative assertionsS ecific re uirements for com arative assertions

    Definition of aDefinition of a functional unitfunctional unit

    Goal and scope of the studyGoal and scope of the study

    Goal: intended application, audience, reasons for the studyGoal: intended application, audience, reasons for the study

    Scope: product system, types of impacts, data qualityScope: product system, types of impacts, data quality

    1010

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    Functional UnitFunctional Unit

    Functional Unit examplesFunctional Unit examples

    Incandescent versus fluorescent lampsIncandescent versus fluorescent lamps

    at s t e unct onat s t e unct on g t ng o a space over t meg t ng o a space over t me

    How many lamps and of what wattage are equivalent?How many lamps and of what wattage are equivalent?

    Fossil versus ForestFossil versus Forest--Based Transportation FuelsBased Transportation Fuels

    What is the function?What is the function? transport of a vehicle over a distancetransport of a vehicle over a distance

    1 MJ of forest based1 MJ of forest based biofuelsbiofuels isis equivalantequivalant to 1 JM of petroleumto 1 JM of petroleumfuelfuel

    1111

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    ummary o n ro uc onummary o n ro uc on

    Motivation for LCA: Reduce environmental impacts ofMotivation for LCA: Reduce environmental impacts of

    products over their life cycle.products over their life cycle.

    LCA is used for decisionLCA is used for decision--making, communication,making, communication,

    marketing, and strategic planningmarketing, and strategic planning ISO 14040ISO 14040--14043 cover all elements of LCA, from14043 cover all elements of LCA, from

    planning/execution to methodologies.planning/execution to methodologies.

    Setting of goals and scope in LCA studies are amongSetting of goals and scope in LCA studies are amongthe most important elements of an LCAthe most important elements of an LCA

    1212

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    e yc e nven orye yc e nven ory

    ISO 14041ISO 14041

    Categories of inventory dataCategories of inventory data

    Allocation methodAllocation method

    Data quality requirementsData quality requirements

    1313

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    nventory or et y ene pro uct onnventory or et y ene pro uct on

    Life-

    Energy

    Materials

    Energy

    Materials

    Energy

    Materialsyc e

    Stages

    Crude Oil

    Extraction

    Naphtha

    Refining

    Ethylene

    Production

    Ethylene

    Wastes,Emissions

    Wastes,Emissions

    Wastes,Emissions

    Transportation

    EnergyMaterials

    Transportation

    EnergyMaterials

    1414

    Wastes,

    Emissions

    Wastes,

    Emissions

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    Energy resources (process heating and electricity)Energy resources (process heating and electricity) Oil, natural gas, coal, nuclear, hydro, wind, solar, biomassOil, natural gas, coal, nuclear, hydro, wind, solar, biomass

    Other raw materialsOther raw materials

    Fe, NaCl, water, air, CaCOFe, NaCl, water, air, CaCO33, Ni, Zn, etc., Ni, Zn, etc.

    EmissionsEmissions

    to air, water, landto air, water, land

    Other categoriesOther categories

    Land area use (often used in Europe and Japan)Land area use (often used in Europe and Japan)

    1515

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    Inventor Cate oriesInventor Cate ories(Ethylene Example)(Ethylene Example)Allen and Shonnard, Green Engineering: Environmentally Conscious Design of Chemical Processes, Prentice Hall, 2002

    1616

    Boustead, I., Eco-profiles of the European Plastics Industry, Report 1-4,European Center for Plastics in the Environment, Brussels, May 1993.

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    Inventor Cate oriesInventor Cate ories(Ethylene Example), cont.(Ethylene Example), cont.Allen and Shonnard, Green Engineering: Environmentally Conscious Design of Chemical Processes, Prentice Hall, 2002

    1717

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    Inventor Cate oriesInventor Cate ories(Ethylene Example), cont.(Ethylene Example), cont.Allen and Shonnard, Green Engineering: Environmentally Conscious Design of Chemical Processes, Prentice Hall, 2002

    1818

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    a a qua y requ remen sa a qua y requ remen s

    TimeTime--related coverage of data:related coverage of data:

    Geographic coverage of data collection:Geographic coverage of data collection:

    , , , , , , , ,

    Technology coverage of data:Technology coverage of data:

    1919

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    ummary o e cyc e nven oryummary o e cyc e nven ory

    Possibly the most challenging part of LCA.Possibly the most challenging part of LCA. ISO 14041 provides guidelinesISO 14041 provides guidelines

    Categories: energy, raw materials, Categories: energy, raw materials,

    Commercial software tools are available but the mostCommercial software tools are available but the most

    accurate inventories may be generated internally foraccurate inventories may be generated internally for

    manufacturers.manufacturers.

    TimeTime--related, geographic, and technology coveragerelated, geographic, and technology coverage

    of inventory dataof inventory data reduce uncertaintyreduce uncertainty

    2020

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    ISO 14042ISO 14042

    IdentifyIdentifyimpact categories,impact categories,

    classifyclassifyinventory elements into impact categories,inventory elements into impact categories, characterizecharacterizeimpacts for each inventory elementimpacts for each inventory element

    Optional features of LCIAOptional features of LCIA

    normalizationnormalization

    valuationvaluation

    2121

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    Global warmingGlobal warming

    Stratospheric ozone depletionStratospheric ozone depletion

    mog orma onmog orma on 33AcidificationAcidification

    Ecosytem healthEcosytem health

    Eutro hicationEutro hication

    BiodiversityBiodiversity

    Resource depletionResource depletion

    2222

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    Classify Inventory ElementsClassify Inventory Elementsinto Categoriesinto Categories

    Inventory ElementsInventory Elements Impact CategoriesImpact Categories

    22 m ss onsm ss ons ---------------------------------------------------------------------- o a arm ngo a arm ng

    NONO33-- in Wastewaterin Wastewater ------------------------ Human Health,Human Health, EutrophicationEutrophication

    ------------------------------------------------ ,,

    CFCs EmissionsCFCs Emissions -------------------------- Global Warming, Ozone DepletionGlobal Warming, Ozone Depletion

    ------------------------------------------ ,,

    Water UseWater Use ------------------------------------------------ Resource Depletion, Land UseResource Depletion, Land Use

    2323

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    Energy

    a e r a s

    Energy

    a e r a s

    Energy

    a e r a s

    Energy

    a e r a sLife-

    CycleStages

    RawMaterials

    Extraction

    ChemicalProcessing

    ProductManufacturing

    Use, Reuse,Disposal

    Wastes Wastes Wastes Wastes

    PollutionControl

    PollutionControl

    globalwarming

    ozonedepletion

    smogformation

    acidifi-cation

    ecologicalharm

    Human healthand ecosystem

    Midpoints

    2424

    amageEndpoint

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    OzoneOzone

    PotentialPotential

    2525

    Appendix D in:Allen and Shonnard, Green Engineering: Environmentally Conscious Design of Chemical Processes, Prentice Hall, 2002

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    BI = infrared radiation absorbance band intensity

    2626

    Appendix D in:Allen and Shonnard, Green Engineering: Environmentally Conscious Design of Chemical Processes, Prentice Hall, 2002

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    Appendix D in:

    2727

    Allen and Shonnard, Green Engineering: Environmentally Conscious Design of Chemical Processes, Prentice Hall, 2002

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    2828

    Appendix D in:Allen and Shonnard, Green Engineering: Environmentally Conscious Design of Chemical Processes, Prentice Hall, 2002

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    Lethal dose or concentrationsLethal dose or concentrations Acute exposureAcute exposure

    Reference concentrationsReference concentrations Chronic exposureChronic exposure

    Regulatory limitsRegulatory limits HealthHealth--based standardsbased standards

    RR--PhrasesPhrases European health categoriesEuropean health categories

    2929

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    3030

    Allen and Shonnard, Green Engineering: Environmentally Conscious Design of Chemical Processes, Prentice Hall, 2002

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    Summary ofSummary ofLife Cycle Impact AssessmentLife Cycle Impact Assessment

    ISO 14042 provides guidelinesISO 14042 provides guidelines

    IdentifyIdentifycategories of environmental impacts,categories of environmental impacts, classifyclassify

    pollutants into categories,pollutants into categories, characterizecharacterizepotency ofpotency of

    pollutants for impact categories.pollutants for impact categories. Relative riskRelative riskcalculation using emission estimation,calculation using emission estimation,

    environmental fate modeling, and impact potency.environmental fate modeling, and impact potency.

    Commercial software tools are available (the sameCommercial software tools are available (the same

    tools as shown in the inventory section).tools as shown in the inventory section).

    3131

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    Motivation for LCA: Reduce environmental impacts ofMotivation for LCA: Reduce environmental impacts of

    products over their life cycle.products over their life cycle.

    LCA is used for decisionLCA is used for decision--making, communication,making, communication,

    marketing, and strategic planningmarketing, and strategic planning ISO 14040ISO 14040--14043 cover all elements of LCA, from14043 cover all elements of LCA, from

    planning/execution to methodologies.planning/execution to methodologies.

    Software tools are available to aid in LCA studiesSoftware tools are available to aid in LCA studies

    Demo version ofDemo version of SimaProSimaPro 7.2 is useful introduction.7.2 is useful introduction.

    3232

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    Potential CellulosicPotential Cellulosic FeedstocksFeedstocksin the Upper Midwestin the Upper Midwest

    Hardwoods

    Bi

    Forest Products Softwoods

    Residues

    r

    BioPower

    Residues

    Energy

    Grasses

    Crops

    Hybrid Willow

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    Harvest residues: 4-10 dry tac-1

    from a single harvest, perhaps 0.5dry tac-1yr-1, with no inputs

    Mill Residues: production dependson mill capacity and production

    efficiency

    Other removals: 5-25 dry tac-1 froma thinning treatment, with no inputs

    Roundwood to Chips: more than4 dry tac-1yr-1 in Aspen,

    perpetua y an w t no nputs

    Dr. Robert Froese, School of Forest Resources and Environmental Sciences, Michigan Tech

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    Hybrid Poplar: 4-10 dry tac-1yr-1 on

    a 10-year rotation starting frombare land

    Low-Intensity, High-Diversityperennials: 2-4 dry tac-1yr-1

    perpetually with low inputs

    Hybrid Willow: 3-14 dry tac-1yr-1 ona 3-year cycle for a 21 year rotation

    starting from bare land

    Switchgrass monoculture: 4-10dry tac-1yr-1 in a single fall

    ,from bare land

    Dr. Robert Froese, School of Forest Resources and Environmental Sciences, Michigan Tech

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    Rapid Thermal ProcessingRapid Thermal ProcessingRTPRTP TMTM TechnologyTechnology

    Pyrolysis Oil

    Solid Biomass

    plus

    Commercially Proven Patented Technology ENV 5233-04

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    RTPRTPTMTM Product YieldsProduct Yields

    Feed, wt%

    400 BDMTPD of Hardwood Whitewood

    Hardwood Whitewood 100

    Typical Product Yields,wt% Dry Feed Biomass

    Typical PyrolysisOil Yield, wt% of

    Yie s For Various Fee s

    Pyrolysis Oil 70

    By-Product Vapor 15

    Char 15

    Hardwood 70 75

    Softwood 70 80

    Softwood Bark 55 65

    Corn Fiber 65 75

    agasse

    Waste Paper 60 80

    Cellulosic Feedstock Flexible

    With High Y ields of Pyrolysis Oil ENV 5233-06

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    oura e an ranspor a e qu ue

    High oxygenate content Contains 55-60% the energy content of crude-based fuel oils

    As produced, can be corrosive

    Comparison of Heating Value of Pyrolysis OilComparison of Heating Value of Pyrolysis Oil

    and Typical Fuelsand Typical Fuels

    Fuel MJ / Litre BTU / US Gallon

    Methanol 17.5 62,500

    . ,

    Pyrolysis Oil (Bark) 22.7 81,500

    Ethanol 23.5 84,000

    Suitable for Energy Applications

    g t ue ese . ,

    ENV 5233-07

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    Life Cycle Pathway DiagramsLife Cycle Pathway Diagrams

    Power from CoPower from Co--firingfiringPlant (PyOil loggingPlant (PyOil logging

    residue)residue)

    Power from ParasiticPower from ParasiticPlant (PyOil SRF)Plant (PyOil SRF)

    Power from CoPower from Co--firingfiringPlant (PyOil SRF)Plant (PyOil SRF)

    Power from ParasiticPower from ParasiticPlant (PyOil loggingPlant (PyOil logging

    residue)residue)

    LoggingResidue

    WoodLogging

    Logging

    SRFFarming

    LoggingResidue

    WoodLogging

    Logging

    SRFFarming

    Logging

    Residue

    ResidueCollection

    SRFTransport

    Logging

    Residue

    ResidueCollection

    SRFTransport

    Production

    PyOil

    PyOilProduction

    Production

    PyOil

    PyOilProduction

    100km

    PyOil

    Combustionin Power

    Plant

    PyOilCombustionin Power

    Plant

    PyOilCombustion inPower Plant

    PyOilCombustion inPower Plant

    100km

    ENV 5233-12

    Electricity

    ElectricityElectricity

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    Feedstock Cultivation andFeedstock Cultivation and

    Residue SRF Crops

    Logging Willow Poplar

    GHG Contribution by P rocessGHG Contribution by P rocessLogging ResidueLogging Residue

    Total of all Processes

    Combustion of Dieselmass

    mass 0.030.03

    0.0250.025

    Biomass Yield

    odt/ha/yr 0.62 11.95 13.50

    GHG

    Diesel, Low-sulphur

    Building Machinery

    gCO

    gCO22eq/kgBi

    eq/kgBi

    0.020.02

    0.0150.015

    0.010.01

    0.0050.005kg CO2-eq/kg Biomass 0.027 0.032 0.053

    kk

    00Reis and Shonnard, 2007Reis and Shonnard, 2007

    WillowWil low

    GHG Contribution by ProcessGHG Contribution by ProcessHybrid/PoplarHybrid/Poplar

    Total of all ProcessesTotal of all Processes

    Ammonium NitrateAmmonium Nitrate

    COCO22 Emissions from Diesel CombustionEmissions from Diesel Combustionmass

    0.050

    0.045

    0.040

    Total of all ProcessesTotal of all Processes

    NN22O Emissions from N Fertilizer UseO Emissions from N Fertilizer Use

    COCO 22 Emissions from Diesel CombustionEmissions from Diesel Combustion

    Ammonium Sulfate, as N, at RegionalAmmonium Sulfate, as N, at Regionalomass

    0.035

    0.03

    NN22O Emissions from N Fertilizer UseO Emissions from N Fertilizer Use

    Single Superphosphate, as P205Single Superphosphate, as P205Diesel, LowDiesel, Low--sulfursulfur

    OtherOther

    gCO2eq/kg

    Bi

    0.0300.025

    0.015

    0.035

    0.020

    Storehouse/ RER SStorehouse/ RER S

    Diesel, LowDiesel, Low--sulphur, at Regionalsulphur, at Regionalstorage/ RER Sstorage/ RER S

    COCO 22 from Heavy Fuel Oil Combustionfrom Heavy Fuel Oil Combustion

    OtherOther

    gCO2eq/kg

    Bi

    0.02

    0.01

    .

    0.015

    k 0.010

    0.005

    0.000

    0.005

    0.000

    ENV 5233-13Heller et al., 2003 Gasol et al., 2008Gasol et al., 2008

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    PyrolysisPyrolysis Oil ProductionOil Production

    gCO2 eq /MJ Logging Residue

    Willow

    Poplar

    Waste

    Biomass Cultivationand Harvesting

    2.08 2.41 4.0 0

    Biomass Transportation 3.84 0.87 0.82 0

    Pyrolysis 8.59 8.59 8.59 8.59

    . . . .

    rcircle= (Wright et. al. 2008)2

    F

    * *

    : the tortuosity factor of the road (1.5)f : fraction of land devoted to biomass cro s 0.1

    * *

    ENV 5233-14

    F: feedstock biomass required (400*365 metric tons / acre / yr)Y: yield of biomass (metric tons / acre / yr)

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    Sensitivit Anal sis of Trans ortation:Sensitivit Anal sis of Trans ortation:f Value (Fraction of Land in Cultivation)f Value (Fraction of Land in Cultivation)

    Transportat ion Distance vs. fTransportat ion Distance vs. f

    f=0.03 f=0.1 f=0.3 f=0.6 f=0.9

    rcircle(miles)Poplar

    20.05 10.98 6.34 4.48 3.66 PyOil GHG Emissions vs fPyOil GHG Emissions vs f20

    circle

    (miles)Willow

    21.34 11.69 6.75 4.77 3.90

    rcircle

    (miles)

    93.74 51.34 29.64 20.96 17.11

    14

    16

    18

    MJ

    8

    10

    gCO2eq/

    2

    4

    PyOil fromPoplarPyOil fromResiduePyOil fromWillowPyOil fromWaste

    f=0.03 f=0.1 f=0.3 f=0.6 f=0.9

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    Sensitivity Analyses of Power SourceSensitivity Analyses of Power Source

    ..SystemSystem

    12

    14

    16

    Pyrolysis

    Feedstock

    Trans ortation

    6

    8

    10

    gCO2eq/MJ

    Feedstock

    Cultivation/Harvesting

    2

    4

    Oilfrom

    Poplar

    plar(Par

    asitic)

    ilfromResid

    ue

    due(Pa

    rasit

    ic)

    ilfromWillo

    w

    llow(Pa

    rasitic)

    Oilfrom

    Waste

    aste

    (Parasitic)

    P

    PyOilfrom

    P Py

    Py

    Oilfrom

    Re Py

    P

    yOilfrom

    PPy

    Oilfrom

    P l iP l i Oil (Oil ( i i ) F il F li i ) F il F l

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    PyrolysisPyrolysis Oil (nonOil (non--parasitic) vs. Fossil Fuelparasitic) vs. Fossil Fuel

    Pyrolysis Oil Production foot print100

    120

    Life CycleLife Cycles m ar o o er energy a erna ves

    Assumed biomass transport distances 200 km for logging residues

    40

    60

    80

    gCO2eq/MJ GHG EmissionsGHG Emissions

    throughthroughproductionproduction

    0

    20

    PetroleumCrude Oil

    HardCoal

    NaturalGas

    CanadianOil Sands

    Crude Oil

    PyOilfrom

    LoggingResidues

    PyOilfrom

    Willow

    PyOilfrom

    Poplar

    Pyrolysis Oil Life Cyclefoot print100

    120

    Life CycleLife Cyclereener an o er a erna ves

    70-88% lower GHG emissions

    SOx emissions similar to Natural Gas40

    60

    80

    gCO2eq/MJ m ss onsm ss ons

    throughthroughcombustioncombustion

    ENV 5233-15

    0

    20

    Petroleum

    Fuel Oil

    Hard

    Coal

    Natural

    Gas

    PyOil

    fromLoggingResidues

    PyOil

    fromWillow

    PyOil

    fromPoplar

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    LCA Results forLCA Results for PyrolysisPyrolysis Oil to PowerOil to Power

    400 BDMTPD400 BDMTPD

    Multiple Scenarios EvaluatedMultiple Scenarios Evaluated

    Co-firing Cases (lowest capital) Fuel Oil Power Plant

    Coal Power Plant

    Natural Gas Power Plant

    Gas Turbine Combined Cycle (GTCC) with heat recovery

    Distributed Diesel Generator located at site

    omparison to Direct Biomass om ustion B Dedicated facility at 18% efficiency (existing BC1)

    Dedicated facilit at 25% efficienc modern BC2

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    PyrolysisPyrolysis Oil CoOil Co--fired in Coal Power Plantfired in Coal Power Plant

    ,,

    US CoalUS Coal

    12001200

    PyOi Com ustionPyOi Com ustion

    PyOil Transportation (100km)PyOil Transportation (100km)

    PyrolysisPyrolysis

    Feedstock Transportat ionFeedstock Transportat ion

    10001000

    800800kWh

    kWh

    Feedstock Cultivation/ HarvestingFeedstock Cultivation/ Harvesting

    600600

    g

    CO

    g

    CO22eqeq//

    400400

    200200

    PyOilPyOilSubstitutionSubstitutionCoal (poplar)Coal (poplar)

    PyOilPyOilSubstitutionSubstitution

    Coal (residue)Coal (residue)

    PyOilPyOilSubstitutionSubstitutionCoal (waste)Coal (waste)

    PyOilPyOilSubstitutionSubstitutionCoal (wil low )Coal (wil low )

    US CoalUS Coal00

    84.7%84.7% 83.5%83.5% 89.8%89.8%GHG SavingsGHG Savings 86.3%86.3%

    Ad d P G ti S hAd d P G ti S h 11

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    Advanced Power Generation SchemeAdvanced Power Generation Scheme --11

    (9.62MW, 42.9% efficiency, net efficiency 39%)(9.62MW, 42.9% efficiency, net efficiency 39%)12001200

    oaoa

    PyOilPyOi l CombustionCombustion

    PyrolysisPyrolysis

    Feedstock Transportat ionFeedstock Transportat ion

    10001000

    hh

    ee s oc u va on arves ngee s oc u va on arves ng

    600600

    OO22eqeq/k/k

    gCgC

    400400

    200200

    PyOilPyOil PyOilPyOil PyOilPyOil PyOilPyOil US CoalUS Coal00

    95.5%95.5% 95.5%95.5% 99.6%99.6% 96.9%96.9%GHG SavingsGHG Savings

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    Advanced Power Generation SchemeAdvanced Power Generation Scheme -- 22

    (5MW at site, 45% efficiency, net efficiency 40.9%)(5MW at site, 45% efficiency, net efficiency 40.9%)12001200

    US CoalUS Coal

    PyOilPyOi l CombustionCombustion

    PyrolysisPyrolysis

    Feedstock Transportat ionFeedstock Transportat ion

    10001000

    hh

    Feedstock Cultivation/ HarvestingFeedstock Cultivation/ Harvesting

    600600

    OO

    22eqeq/k/k

    gg400400

    PyOilPyOil PyOilPyOil PyOilPyOil PyOilPyOil US CoalUS Coal00

    95.8%95.8% 96.3%96.3% 99.6%99.6% 97.2%97.2%GHG SavingsGHG Savings

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    Comparisons of LCComparisons of LC--GHG EmissionsGHG Emissions

    180

    w rec omass om us onw rec omass om us on

    Low Capex Pyrolysis Oil CoLow Capex Pyrolysis Oil Co--firingfiring

    120

    140

    160 Poplar

    Residue

    80

    100

    C

    O2eq/kW Direct CombustionDirect Combustion

    AdvancedAdvancedPower FacilityPower Facility

    20

    40

    60g

    0

    BC1 BC2 Coal co-

    fire 33%

    Coal co-

    fire 37%

    NG co-

    fire 42%

    NG co-

    fire 58%

    PyOil

    GTCC

    Py Oil

    Diesel5-10 MW scale

    en.

    BC1= existing combustion/ steam turbine unit at 18% efficiency

    BC2= modern combustion/ steam turbine at 25% efficiency

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    There is a variety of forest resources that can be convertedThere is a variety of forest resources that can be converted

    toto pyrolysispyrolysis biobio--oil using RTPoil using RTPTMTM process technologyprocess technology PyrolysisPyrolysis biobio--oil can be utilized by a wider spectrum of poweroil can be utilized by a wider spectrum of power

    generation technologies compared to biomass combustiongeneration technologies compared to biomass combustion

    Biomass combustion: limited to coBiomass combustion: limited to co--firing with coalfiring with coal

    P rol sisP rol sis biobio--oil: com atible with NG coal and oil s stemsoil: com atible with NG coal and oil s stems

    Greenhouse gas emissions ofGreenhouse gas emissions of pyrolysispyrolysis biobio--oil electricityoil electricity

    GHG impacts of RTPGHG impacts of RTPTMTM pyrolysispyrolysis oil production ~ fossil fuelsoil production ~ fossil fuels

    aras caras c pyro ys spyro ys s o pro uc on re uces y ~o pro uc on re uces y ~

    Savings of GHG emissions of between 76Savings of GHG emissions of between 76 99% is achieved for99% is achieved forpyrolysispyrolysis oil electricity compared to US Grid electricityoil electricity compared to US Grid electricity

    g e c ency app ca ons org e c ency app ca ons or pyro ys spyro ys s o e ec r c y are moreo e ec r c y are morefavorable compared to direct biomass combustion electricityfavorable compared to direct biomass combustion electricity

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    This material is based upon work supported by the Department ofEnergy under award number DEEE0000280.

    Disclaimer:

    This report was prepared as an account of work sponsored by an agency ofthe United States Government. Neither the United States Government norany agency thereof, nor any of their employees, makes any warranty,express or implied, or assumes any legal liability or responsibility for theaccuracy, completeness, or usefulness of any information, apparatus,

    , ,privately owned rights. Reference herein to any specific commercial product,or service by trade name, trademark, manufactured, or otherwise does notnecessarily constitute or imply its endorsement, recommendation, or favoringy t e Unite States Government or any agency t ereo . T e views an

    opinions of authors expressed herein do not necessarily state or reflect thoseof the United States Government or any agency thereof.

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    Questions?Questions?

    Central Research Station image)