Lecture 3 Characterization and Composition of MSW

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    SBT 4635

    Waste Management and Usage : Characterization of SolidWaste

    Photo credit to ecoideal.com.my

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    Objectives

    !

    Determine why quantification andcharacterization of MSW is important

    ! Understand the methodology used toquantify MSW

    ! Explain why it is important to characterize

    MSW.

    ! Become familiar with MSW descriptors.

    ! Describe the physical, chemical, and biological

    properties associated with MSW.

    !

    Perform calculations using waste compositionand properties.

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    Why reliable data on waste compositionand quantities are essential?

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    Why reliable data on waste composition andquantities are essential?

    Recycling

    Material recovery facilities/ incinerator

    Waste as fuel

    Leachate composition and treatment

    Transportation

    Combustion characteristics

    Processing requirements

    Landfill lifetime

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    Composition studies

    !

    Direct sampling! Material flows

    ! Surveys

    ! Multipliers for projecting waste quantities

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    Direct sampling

    !

    Useful on small scale! Involves physical sampling and sorting MSW at the source

    of generation

    ! Accurate judgements

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    conduct at several randomly selected locations within thecommunity

    ! Different locations-single and multifamily homes, commercialestablishments, institutions

    ! @ direct sampling at centralized tipping point (transfer

    station! ASTM method D5231- sample size 91-136kg

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    Direct sampling

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    Disadvantage! Limited number of samples

    ! Misleading data-unexpected circumstances such as severe wet

    or dry season.

    ! Did not provide accurate information about trends-unless

    consistent sampling over a long period of time

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    Direct sampling protocol

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    Vehicle Unloading! Sample Selection and Retrieval

    ! Container Preparation

    ! Sample Placement

    !

    Sorting

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    Direct sampling

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    Material flows

    !

    Useful (waste composition and trends) for regional basis! Based on production data (by weight) for materials and

    products

    ! Oversimplification, need to consider that the communityis an open system having numerous imports and exports

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    Surveys

    !

    Distributing questionnaires to waste producers! Detailed questions

    ! Quantities

    ! Composition-category

    ! Others- seasonal variation of waste generation, recycling

    program

    ! Disadvantage

    ! no accurate record

    ! Companys confidential data

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    Multipliers

    !

    Use to estimate waste quantities from sources in aparticular region

    ! Value of multipliers-based on surveys, published data anddirect sampling for an area. E.g population size, numberand type of livestock, number of employees

    ! The value varied widely. Estimate of households wasteproduction based on per capita generation.

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    Chemical composition of waste

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    Ultimate analysis! Proximate analysis

    ! Energy content

    ! Fusion point of ash

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    Content of nutrients and other substrate! Carbohydrates

    ! Crude fibers

    ! Proteins

    !

    Lipids! Biodegradability

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    Ultimate analysis

    !

    Total elemental analysis! % of molecular composition (C, H, N, O, P, etc.) of the

    organic fraction

    ! The oxygen value is calculated by subtracting the othercomponents including ash and moisture, from 100%

    ! Usage -

    ! Waste as fuel

    ! Emission from combustion

    ! Suitable nutrient ratios (e.g., C/N) for biological conversion -

    composting

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    Physical properties of MSW

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    Density! Moisture content

    ! Particle size distribution

    ! Field capacity

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    Hydraulic conductivity