Thermal & Kinetic Lecture 6 The Maxwell-Boltzmann distribution
Lecture 22 — The Maxwell Distribution Chapter 7, Friday February 29 th
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Transcript of Lecture 22 — The Maxwell Distribution Chapter 7, Friday February 29 th
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Lecture 22 — The Maxwell Distribution Lecture 22 — The Maxwell Distribution Chapter 7, Friday February 29Chapter 7, Friday February 29thth
•Final points from Ch. 6 – molecular hydrogen
•Maxwell-Boltzmann probability
•Density of states in k-space
•Single-particle density of states in energy
•Maxwell distribution of speeds in a classical gas
Reading: Reading: All of chapter 7 (pages 144 - 157)All of chapter 7 (pages 144 - 157)Assigned problems, Assigned problems, Ch. 6Ch. 6: 2, 4*, 6, 8, : 2, 4*, 6, 8,
(+1)(+1)Homework 6 due today by 5pmHomework 6 due today by 5pmAssigned problems, Assigned problems, Ch. 7Ch. 7: 6, 8, 12, 14, : 6, 8, 12, 14,
1616Homework 7 due next FridayHomework 7 due next FridayExam 2 on Wed. after spring breakExam 2 on Wed. after spring break
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SpinSpin3 51
2 2 2: , , ,....
: 0, , 2 , 3 ,....
Fermions
Bosons
12 space spin
1
2
3
4
Symmetric
Antisymmetric
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12 1 2 1 2
12 1 2 1 2
i j j i
i j j i
x x x x
x x x x
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Diatomic molecules: ortho and para Diatomic molecules: ortho and para 11HH22
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LxLy
Lz
1 2 3sin sin sinix y z
n x n y n zA
L L L
2 2 2 2 21 2 32 2 22ix y z
n n n
m L L L
Particle (standing wave) in a boxParticle (standing wave) in a box
3/ 2
22B
x y z
mk TZ L L L
/i Bk T
i i
en Np N
Z
Boltzmann probability:
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kkyy
kkxx
kkzz
Density of states in Density of states in kk-space-space
1
2
3
xx
yy
zz
nk
L
nk
L
nk
L
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dVk
k
k
k
k kkyy
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Convert to spherical coordinatesConvert to spherical coordinates
dk
2 2 2x y zk k k k
2 sinkdV k dk d d
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n(u)
u
Maxwell speed distributionMaxwell speed distribution