Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are...

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Lecture 2: Types of Equilibria Steady Flow of Reaction Chains Chemical Equilibrium of Individual Reactions Complete Chemical Equilibrium (NSE) Clusters of Chemical Equilbrium (QSE) QSE Clusters linked by a Steady Flow Friedrich-Karl Thielemann Department of Physics University of Basel

Transcript of Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are...

Page 1: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

Lecture 2: Types of Equilibria

Steady Flow of Reaction Chains Chemical Equilibrium of Individual Reactions Complete Chemical Equilibrium (NSE) Clusters of Chemical Equilbrium (QSE) QSE Clusters linked by a Steady Flow

Friedrich-Karl ThielemannDepartment of Physics

University of Basel

Page 2: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

CNO(I)-Cycle in Steady Flowthe network entry for nuclei with mass numbers A=12, 13, 14, 15 is governed in each case by a production reaction (proton reaction on A-1) and a distruction reaction (proton reaction on A). In case of a steady flow they cancel and lead to Y=0 for all A, linking all of these identical terms (A=14 is useful as this encounters the slowest reaction and essentially all mass assembles in 14N)

summing all mass fractions of CNO nuclei for solar metallicity

Page 3: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

s-process and steady flow

s-process

r-processp-process

(from Anders & Grevesse)

Solar abundances (Anders & Grevesse)

shown are s-, r-, and p-only nuclei!

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s-process and steady flowpossible destruction of nucleus (Z,A)

beta-decay to (Z+1,A)

only one nucleus per A needs to be considered!

in case of steady flow =0

= therefore

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The sigma*N-curve

a complete steady flow is not given, but in between magic numbers (where the neutron capture cross sections are small) almost attained!

double values due to branchings

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Käppeler et al. (2007): needed cross sections with uncertainties between 1 and 5%

for complete set of isotopes from 12C to 210Po, including unstable samples (branching points)

n_TOF (CERN), FRANZ (Frankfurt)

Page 7: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

s- and r-decomposition

the almost constant sigma*N-curve leads to a large odd-even staggering in the abundances (due to the odd-even staggering in n-capture cross sections!

Page 8: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

Steady flows and chem. equilibrium in stellar burning

pp-cycles and CNO-cycle lead to steady flows in H-burning

4He+4He 8Be is in chemical equilibriumreleased neutrons lead to steady flow in neutron capture

Page 9: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

Complete chem. equilibrium (NSE)

Si-burning in stellar evolution and expl. Si-burning at high densities lead to NSE!

Page 10: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

QSE in explosive Si-burning

full NSE is not attained, but there exist equilibrium groups around 28Si, 56Ni and n,p,4He, which are separated by slow reactions

Sample Calculations from B.S. Meyer and Hix and Thielemann

small Q-values of reactions out of Z=20, N=20 cause small cross sections and hold up equilibrium

Page 11: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

QSE Formalismlight group

Si-group

Ni/Fe-group

time evolution for those quantities which are in equilibrium and the individual abundances of nuclei with slow reactions which link equilibrium groups (Hix, Parete-Koon, Freiburghaus, Thielemann 2007)

binding energy differences, i.e. masses enter directly

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Obtaining equilibrium at high T

at T=4 GK the equilibrium description is correct after about 10-3 s!

accuracy

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Incomplete Si-burning with freeze-out

energy generation

charged-particle freeze-out below T=3.5 GK

circles >10-6, squares >10-12, triangles >10-20

filled/open network size

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Normal and alpha-rich freeze-out

Page 15: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

Interim conclusions steady flows are approached in many hydrostatic

burning stages during stellar evolution, including the s-process. They are determined by rates (often the smallest ones), which are/can be related to small Q-values.

NSE/QSE equilibria are obtained in hydrostatic Si-burning and in explosive burning. Abundance distribution depends directly on mass differences, but for these applications mostly close to stability.

How about QSE-equilibria linked by steady flows (and far from stability)?

Page 16: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

The classical r-process

Assume conditions where after a charged-particle freeze-out the heavy QSE-group splits into QSE-subgroups containing each one isotopic chain Z, and a high neutron density is left over

these QSE-groups are connected by beta-decays from Z to Z+1

neutrons are consumed to form heavier nuclei is a steady flow of beta-decays conceivable?

Page 17: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

s- and r-decoposition

Heavy Elements are made by slow and rapid neutron capture events

which timescale is shorter? neutron capture inverse proportional to n

n !

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High neutron densities lead to nuclei far from stability

......

Page 19: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

The classical r-process

Page 20: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

classical calculation with nn=const and T=const

conditions with reproduce A=130 at t=1.7s

A=130

Page 21: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

A=80 and 195 peaks

t=1.5s t=2.5sthree components can produce the A=80, 130, and 195 peaks during “comparable” timescales (for the first time experimental half-lives and masses were known in the r-process path at A=80 and 130)!

A=80

A=195

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42 44 46 48 50 52 54 56 58 60 62 64 66 68 70 72 74 76 78 80 82

FeCo

Ni

CuZn

GaGe

AsSe

Br

Kr

Rb

SrY

ZrNb

Mo

TcRu

RhPd

Ag

CdIn

Sn

Z N

SbTe

IXe

CsBa

82 84 86 88 90 92 94

r-Process paths for nn=1020, 1023 and 1026

„waiting-point“ isotopes for nn=1020, 1023 and1026

nn=1023

nn=1020

K.-L. Kratz

nn=1026

Page 23: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

Following three Sn's for timescales t

1,t

2,t

3

constant nn and T for timescale t and afterwards instantaneous beta-decay

Kratz, Bitouzet, Thielemann, Möller, Pfeiffer and permutations 1993-1999

Page 24: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

Multi-components and steady beta-flow?

superposition with weights w(n

n)=8.36 106n

n-0.247 and t(n

n)=6.97 10-2 n

n0.062s

decay rate of complete Z-chain multiplied with total abundance of Z-chain close to constant in between magic numbers (where long half-lives are encountered).

close to steady beta-flow

Page 25: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

r-Process Path

G. Martinez-Pinedo

whether such a classical r-process is established, along contour-lines of constant S

n,

due to (n,γ)-(γ,n) equilibrium, depends on the temperature, providing photons with sufficient energy (=>hot r-process). In matter with fast expansion and still high neutron densities at low temperatures this might not be established (=>smeared-out distribution, cold r-process)

Page 26: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

Explosive Si-Burning

Explosive Burning above a critical temperature destroys (photodisintegrates) all nuclei and (re-)builds them up during the expansion. Dependent on density, the full NSE is maintained and leads to only Fe-group nuclei (normal freeze-out) or the reactions linking 4He to C and beyond freeze out earlier (alpha-rich freeze-out).

5

increasing entropyS T⁓ 3/ρ

for Ye=0.498

Page 27: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

n/seed ratios for high entropy conditions are are function of entropy

Farouqi et al. (2010)

n/seed =Y

n/Y

seed

The essential quantity for a successful r-process to occur is to have an/seed ratio so that A

seed+n/seed=A

actinides!

Page 28: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

n/seed ratios as function of S and Ye

Freiburghaus et al. (1999)neutrino wind? Neutron star mergers and polar jets?

Page 29: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

Explosive H/He-burning and the onset of the rp-process

at temperatures around 1-2 108 K only hot CNO-type cycles exist

except for 19Ne

increasing temperatures up to 3-4 108 K break up cycles via proton captures

bridging by alpha reactions beyond 6 108 K

Fisker et al. 2005, Cooper & Narayan 2006, Tan et al. 2007, Heger et al. 2007, Fisker et al. 2007, 2008, Parikh et al. 2008, Galaviz et al. 2010, Cybert et al. 2010, José et al. 2010, Haettner et al. 2011, Tu et al. 2011

Woosley & Taam 1976,Joss 1977, 1978,Taam 1980, Wallace & Woosley 81,Fujimoto et al. 1981,Ayasli & Joss 1982,Woosley & Waever 84,Wiescher et al. 86,Fushiki & Lamb 1987,van Wormer et al. 94,Lewin et al. 1995,Rembges et al. 97,Bildsten 1998, 2000Schatz et al. 98, 01,Wiescher et al. 1999,Brown et al. 2002,Cumming 2003,Narayan & Heyl 2003,Strohmayer&Bildsten 2003,Woosley et al. 2003,.

.

Page 30: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

Test calculations as functions of T

T=1.5 108 K

hot CNO cycle

no break-out yet

early evaluations: van Wormer et al. (1994)

for T=2-3 108 K more CNO-type cycles develop up to Ca

Page 31: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

T = 4 x 108 K

between 1-2 108 K already a strong flow of reactions can move matter from Ne towards heavier nuclei via CNO-type cycles, which becomes even stronger (break-out of CNO-type cycles) with further increasing temperatures

Page 32: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

T = 6 x 108 K

CNO-breakout has occurred, triple-alpha starts still insignificantly

Page 33: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

T = 8 x 108 K

triple-alpha fully active, i.e. He can be burned towards heavy nuclei

Page 34: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

T = 1.5 109 K

(alpha,p)-reactionspossible up to Ar, Ca

Page 35: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

Break-out from hot CNO at 4-5 108 K

at Z above 20 a sequence of rapid proton captures and beta-decays (rp-process), for smaller target charges (Coulomb barriers) (a,p) reactions possible

Wiescher, Görres, Thielemann, van Wormer, Schatz, Rembges ..

Page 36: Lecture 2: Types of Equilibria · constant in between magic numbers (where long half-lives are encountered). close to steady beta-flow. r-Process Path G. Martinez-Pinedo whether such

rp-process (encounters p-drip line, endpoint Sb-Te cycle)

develops features of QSE-groups along isotonic lines with links via beta-decays (waiting points) and alpha-induced reactions (tested for energy generation by Rembges et al. 1997)

Schatz et al. (1998, 2001 ..) in one-zone models

Fisker, Thielemann, Wiescher (2004),Woosley, Heger, Keek …. (2013),Fehlmann et al. (2014)full multi-zone hydro