Lecture 12—Ideas of Statistical Mechanics Chapter 4, Monday February 4 th

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Lecture 12—Ideas of Statistical Lecture 12—Ideas of Statistical Mechanics Chapter 4, Mechanics Chapter 4, Monday February Monday February 4 4 th th Finish the model for a rubber band Demonstration Spins on a lattice Reading: Reading: All of chapter 4 (pages 67 - 88) All of chapter 4 (pages 67 - 88) ***Homework 4 due Thu. Feb. 7th**** ***Homework 4 due Thu. Feb. 7th**** Assigned problems, Assigned problems, Ch. 4 Ch. 4 : 2, 8, 10, : 2, 8, 10, 12, 14 12, 14 Exam 1: Exam 1: Fri. Feb. 8th (in class), chapters 1- Fri. Feb. 8th (in class), chapters 1- 4 4 Review: Review: Thu. 7th at 5:30pm, tentatively in Thu. 7th at 5:30pm, tentatively in

description

Lecture 12—Ideas of Statistical Mechanics Chapter 4, Monday February 4 th. Finish the model for a rubber band Demonstration Spins on a lattice. Reading: All of chapter 4 (pages 67 - 88) ***Homework 4 due Thu. Feb. 7th**** Assigned problems, Ch. 4 : 2, 8, 10, 12, 14 - PowerPoint PPT Presentation

Transcript of Lecture 12—Ideas of Statistical Mechanics Chapter 4, Monday February 4 th

Page 1: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

Lecture 12—Ideas of Statistical Lecture 12—Ideas of Statistical Mechanics Chapter 4, Mechanics Chapter 4, Monday February Monday February

44thth

•Finish the model for a rubber band

•Demonstration

•Spins on a lattice

Reading: Reading: All of chapter 4 (pages 67 - 88)All of chapter 4 (pages 67 - 88)***Homework 4 due Thu. Feb. 7th*******Homework 4 due Thu. Feb. 7th****Assigned problems, Assigned problems, Ch. 4Ch. 4: 2, 8, 10, 12, : 2, 8, 10, 12,

1414Exam 1: Exam 1: Fri. Feb. 8th (in class), chapters 1-4Fri. Feb. 8th (in class), chapters 1-4Review:Review: Thu. 7th at 5:30pm, tentatively in Thu. 7th at 5:30pm, tentatively in NPB1220NPB1220

Page 2: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

Rubber band modelRubber band model

n+ = # of forward links; n = # of backward linksN = n+ + n = total # of linksLength l = (n+ n)d = (2n+ N)d

d

! !

,! ! ! !

N NW N n

n n n N n

Dimensionless length:2

1l n

xNd N

Page 3: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

Rubber band modelRubber band model

d

! !

,! ! ! !

N NW N n

n n n N n

ln ln ln lnW N N n n N n N n

Sterling’s approximation: ln(Sterling’s approximation: ln(NN!) = !) = NNlnlnNN NN

ln 1 ln 1n n n n

NN N N N

Page 4: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

Rubber band modelRubber band model

d

! !

,! ! ! !

N NW N n

n n n N n

ln ln ln lnW N N n n N n N n

Sterling’s approximation: ln(Sterling’s approximation: ln(NN!) = !) = NNlnlnNN NN

1 1 1 1ln ln

2 2 2 2

x x x xN

Page 5: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

Rubber band modelRubber band model

2nd law:2nd law: dUdU = = TdSTdS + + FdlFdl

1ln ln ,

2 2 1B B BF k Nd l k k l

T d Nd l d d Nd

2Blk TFNd

Page 6: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

A simple model of spins on a latticeA simple model of spins on a lattice

n1 = # of ‘up’ spins; n = # of ‘down’ spinsN = n1 + n = total # of spinsEnergy U = (n1 n) = (N 2n1)

1

2

B

B

Quantum spinsin a magneticfield

B

2

2

Magneticmoment

Page 7: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

64Statistical Mechanics – ideas and Statistical Mechanics – ideas and

definitionsdefinitions

An example:An example: Coin toss again!!

width

Page 8: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

A simple model of spins on a latticeA simple model of spins on a lattice

n1 = # of ‘up’ spins; n = # of ‘down’ spinsN = n1 + n = total # of spinsEnergy U = (n1 n) = (N 2n1)

1

2

B

B

Quantum spinsin a magneticfield

B

2

2

Magneticmoment

Page 9: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

A simple model of spins on a latticeA simple model of spins on a lattice

-1 0 10.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

S/Nk B

x

1 1 1 1ln ln

2 2 2 2B

x x x xS Nk

121

U nx

N N

Page 10: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

A simple model of spins on a latticeA simple model of spins on a lattice

1 1ln

2 1Bk x

T x

-1 0 1-8

-6

-4

-2

0

2

4

6

8

2/kBT

x

121

U nx

N N

Page 11: Lecture 12—Ideas of Statistical Mechanics Chapter 4,  Monday February 4 th

0 1 2 30.0

0.2

0.4

0.6

0.8

1.0

MV

/N

B/kBT

A simple model of spins on a latticeA simple model of spins on a lattice

tanhB

N BM

V k T