Knowledge

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Brass is susceptible to stress corrosion cracking, especially from ammonia or substances containing or releasing ammonia. The problem is sometimes known as season cracking after it was first discovered in brass cartridge cases used for  rifle ammunition during the 1920s in the Indian Army. The problem was caused by high  residual stresses from cold forming of the cases during manufacture, together with chemical attack from traces of ammonia in the atmosphere. The cartridges were stored in stables and the ammonia concentration rose during the hot summer months, thus initiating brittle cracks. The problem was resolved by annealing the cases, and storing the cartridges elsewhere. The most common example is selective leaching of zinc from brass alloys containing more than 15% zinc (dezincification) in presence of oxygen and moisture, e.g. from brass taps in  chlorine - containing water. It is believed that both copper and zinc gradually dissolved out simultaneously and copper precipitates back from the solution. The material remaining is a copper-rich sponge with poor mechanical properties, and color changed from yellow to red. Dezincification can be caused by water containing sulfur , carbon dioxide andoxygen. Stagnant or low velocity waters tend to promote dezincification. To combat this, arsenic or tin can be added to brass, or  gunmetal  can be used instead. Dezincification resistant brass (DZR),  also known as Brass C352, [1]  is an alloy used to make pipe fittings for use with potable water . Plumbing fittings that are resistant to dezincification are appropriately marked, with the letters "CR" (Corrosion Resistant) or DZR (dezincification resistant) in the UK, and the letters "DR" (dezincification resistant) in Australia.

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Transcript of Knowledge

Brass is susceptible tostress corrosion cracking, especially fromammoniaor substances containing or releasing ammonia. The problem is sometimes known asseason crackingafter it was first discovered in brasscartridge casesused forrifle ammunitionduring the 1920s in theIndian Army. The problem was caused by highresidual stressesfrom cold forming of the cases during manufacture, together with chemical attack from traces of ammonia in the atmosphere. The cartridges were stored in stables and the ammonia concentration rose during the hot summer months, thus initiating brittle cracks. The problem was resolved byannealingthe cases, and storing the cartridges elsewhere.

The most common example is selective leaching of zinc frombrassalloys containing more than 15%zinc(dezincification) in presence of oxygen and moisture, e.g. from brass taps inchlorine-containing water. It is believed that both copper and zinc gradually dissolved out simultaneously and copper precipitates back from the solution. The material remaining is a copper-rich sponge with poor mechanical properties, and color changed from yellow to red. Dezincification can be caused by water containingsulfur,carbon dioxideandoxygen. Stagnant or low velocity waters tend to promote dezincification. To combat this,arsenicortincan be added to brass, orgunmetalcan be used instead.Dezincification resistant brass(DZR), also known asBrass C352,[1]is an alloy used to make pipe fittings for use withpotable water. Plumbing fittings that are resistant to dezincification are appropriately marked, with the letters "CR" (Corrosion Resistant) or DZR (dezincification resistant) in the UK, and the letters "DR" (dezincification resistant) in Australia.