Journal of modern chemistry & chemical technology (vol5, issue1)
-
Upload
stm-journals-publication -
Category
Documents
-
view
233 -
download
0
description
Transcript of Journal of modern chemistry & chemical technology (vol5, issue1)
Journal of Modern Chemistry
& Chemical TechnologyISSN: 2321-5208(JoMCCT)
STM JOURNALSScientific Technical Medical
Jan - April 2014
STM Publication, a strong initiative by Consortium E-Learning Network Private ltd.(Estd. 2006) was launched in the
year 2010 under the support and guidance by our esteemed Editorial and Advisory board members from renowned
institutes.
Objectives of STM Publication(s):
?Scientific, Technical and Medical research promotions.
?Publication of genuine Research/Review, Short Articles and Case Studies through proper review
process.
?Publishing Special Issues on Conferences.
?Preparing online platform for other print Journals.
?Empowering the libraries with online and print Journals in Scientific, Technical and Medical
domains.
?Publishing and distribution of books on various subjects which mainly falls in the category of
Nanotechnology, Scientific and technical writing & Environment, Health and Safety.
Salient Features:
?A bouquet of 100+ Journals that fall under Science, Technical & Medical domains.
?Employs Open Journals System (OJS) A Journal Management & Publishing System.
?The first and one of the fastest growing publication website in India as well as in abroad for its quality
and coverage.
?Rapid online submission and publication of papers, soon after their formal acceptance/ finalization.
?Facilitates linking with the other authors or professionals.
?Worldwide circulation and visibility.
Focus and Scope Covers
is published (frequency: three times a year) in India by STM
Journals (division of Consortium e-Learning Network Private Ltd. Pvt.) The views expressed in the articles do not
necessarily reflect of the Publisher. The publisher does not endorse the quality or value of the advertised/sponsored
products described therein. Please consult full prescribing information before issuing a prescription for any products
mentioned in this publication.
No part of this publication may be reproduced, stored in retrieval system or transmitted in any from without written
permission of the publisher.
To cite any of the material contained in this Journal, in English or translation, please use the full English reference at the
beginning of each article. To reuse any of the material, please contact STM Journals ([email protected])
Journal of Modern Chemistry & Chemical Technology
Journal of Modern Chemistry & Chemical Technology
(ISSN: 2321–5208)
?Structural Analysis, Thermodynamics and Thermo - Science
?Finite element analysis
?Chromatographic studies
?Oxidation-reduction reactions
?Organometallic chemistry
? Finite element analysis
?Macrocyclic Systems, Metalloporphyrins
STM Publication(s)
STM Journals (division of Consortium e-Learning Network Private Ltd. ) having its Marketing office located at Office
No. 4, First Floor, CSC pocket E Market, Mayur Vihar Phase II, New Delhi-110091, India is the Publisher of Journal.
Statements and opinions expressed in the Journal reflect the views of the author(s) and are not the opinion of STM
Journals unless so stated.
Subscription Information and Order:
Cost of Journal:
? National Subscription: Rs. 3750/- per Journal (includes 3 print issues), Single Issue copy purchase Rs.1500/copy
? International Subscription:
? Online Only- $99, Print Only-$149 (includes 3 print issues)
? Online + Print-$199 (includes 3 print issues + online access of published back volumes )
To purchase print compilation of back issues please send your query at [email protected]
Subscription must be prepaid. Rates outside the India includes speed delivery charges. Prices subject to change
without notice.
Mode of Payment: At par cheque, Demand draft, and RTGS (payment to be made in favor of
Consortium E-Learning Network. Pvt. ltd., payable at Delhi/New Delhi.
Online Access Policy
A). For Authors:
In order to provide maximum citation and wide publicity to the authors work, STM Journals also have Open Access
Policy, authors who would like to get their work open access can opt for Optional Open Access publication at
nominal cost as follows
India, SARC and African Countries: INR 2500 or 100 USD including single hard copy of Author's Journal.
Other Countries: USD 200 including single hard copy of Author's Journal.
B). For Subscribers:
? Online access will be activated within 72 hours of receipt of the payment (working days), subject to receipt of
correct information on user details/Static IP address of the subscriber.
? The access will be blocked:
? If the user requests for the same and furnishes valid reasons for blocking.
? Due to technical issue.
? Misuse of the access rights as per the access policy.
Advertising and Commercial Reprint Inquiries: STM Journals with wide circulation and visibility offer an excellent
media for showcasing/promotion of your products/services and the events-namely, Conferences, Symposia/Seminars
etc. These journals have very high potential to deliver the message across the targeted audience regularly with each
published issue. The advertisements on bulk subscriptions, gift subscriptions or reprint purchases for distribution etc. are
also very welcome.
Lost Issue Claims: Please note the following when applying for lost or missing issues:
? Claims for print copies lost will be honored only after 45 days of the dispatch date and before publication of the
next issue as per the frequency.
? Tracking id for the speed post will be provided to all our subscribers and the claims for the missing Journals will
be entertained only with the proofs which will be verified at both the ends.
? Claims filed due to insufficient (or no notice) of change of address will not be honored.
? Change of Address of Dispatch should be intimated to STM Journals at least 2 months prior to the dispatch
schedule as per the frequency by mentioning subscriber id and the subscription id.
? Refund requests will not be entertained.
Legal Disputes
All the legal disputes are subjected to Delhi Jurisdiction only.
If you have any questions, please contact the Publication Management Team:
[email protected]; Tel : +91 0120-4781211.
Chairman
Mr. Puneet Mehrotra
Managing Director STM Journals, Consortium eLearning Network Pvt. Ltd.(CELNET)
Noida ,India
Group Managing Editor Dr. Archana Mehrotra
DirectorCELNET, Delhi, India
Puneet Pandeya
ManagerMonika Malhotra
Assistant Manager
Assistant Editors
Aditya Sanyal
Himani Garg
Himani Pandey
Publication Management Team
Internal Members
External Members
Dr. Bimlesh Lochab
Industrial Tribology Machine Dynamics & Maintenance
Engineering Centre (ITMMEC)
Indian Institute of Technology Delhi, India
Prof. S. Ramaprabhu
Alternative Energy Technology Laboratory,
Department of Physics,
Indian Institute of Technology, Chennai, India
Dr. Rajiv Prakash
School of Materials Science and Technology,
Institute of Technology, Banaras Hindu University,
Varanasi, India
Dr. Rakesh Kumar
Assistant Professor, Department of
Applied Chemistry, BIT Mesra,
Patna, India
Associate Editors
Gargi Asha Jha
Nupur Anand
Priyanka Aswal
Sona Chahal
STM Journal (s) Advisory Board
Dr. Ashish RunthalaLecturer, Biological Sciences Group,
Birla Institute of Technology & Science, Pilani Rajasthan, India.
Dr. Baldev RajDistinguished Scientist & Director,
Indira Gandhi Centre for Atomic Research
(ICGAR)Kalpakkam, India.
Dr. Baskar KaliyamoorthyAssociate Professor, Department
of Civil Engineering National Institute of Technology Trichy, India.
Prof. Bankim Chandra RayProfessor and Head, Department of
Metallurgical and Materials Engineering National Institute of Technology,
Rourkela, India.
Prof.D. N. Rao Professor, Department of Biochemistry,
AIIMS, New Delhi, India.
Prof. Jugal KishoreProfessor, Department of Community
Medicine, Maulana Azad Medical College, New Delhi, India.
Dr. Pankaj PoddarScientist, Physical & Materials ChemistryDivision, National Chemical Laboratory,
Pune, India.
Dr. Hardev Singh VirkProfessor Emeritus, Eternal
University, Baru Sahib, India.
Dr. Nandini Chatterjee SinghAssociate Professor,
National Brain Research Centre, Manesar, India.
Dr. Shankargouda PatilAsst. Prof., Department of Oral
Pathology, KLE Society's Institute of Dental Sciences, Bangalore, India.
Prof. Subash Chandra MishraProfessor, Metallurgical & Materials
Engineering Department, NIT, Rourkela, India.
Prof. Yuwaraj Marotrao GhugalProfessor and Head Department, Govt.College of Engineering Station Road,
Osmanpura, Aurangabad, India.
Prof. Sundara RamaprabhuProfessor, Department of Physics
Indian Institute of Technology Madras, India.
Dr. Shrikant Balkisan DhootHead Research & Development,
Nurture Earth R&D Pvt LtdMIT Campus, Beed bypass road,
Aurangabad, India.
Dr. Rakesh KumarAssistant Professor,
Department of Applied Chemistry, BIT Mesra, Patna, India
Dr. Priyavrat TharejaHead, Materials and Metallurgical
Engineering department, PEC University of Technology,
Chandigarh, India.
STM Journal (s) Advisory Board
Editorial Board
Prof. K. C GuptaIndian Institute of Technology,
Rorkee, India.
Dr. Ashok kumarSr. Manager Lupin Pharmaceuticals.,
India.
Dr. Lakhwinder SinghAssistant Professor, Department of Applied
Sciences Rayat & Bahra Institute of
Engineering and Biotechnology
Punjab, India.
Professor Sanjoy BandyopadhyayDepartment of Chemistry Indian Institute of
Technology, Kharagpur, West Bengal, India.
Dr. Rakesh KumarAssistant Professor, Department of
Applied Chemistry BIT Mesra, Patna Campus, Patna, India.
Dr. Jagdishkumar P. TandalePandurang Tandale Dbt-Ceb, Institute
of Chemical Technology,N.P.Marg, Matunga(E),Mumbai India.
Professor Har Mohindra Lal ChawlaDepartment of Chemistry Indian Institute
of Technology Delhi, India.
Dr. Subhendu Sekhar BagIndian Institute of Technology
Guwahati, India.
Dr. Gopal DasDepartment of Chemistry
IIT Guwahati, India.
Dr. Sunil K. SharmaChief Scientist - Fire Research, CSIR-CBRI,
Roorkee (UK) Professor, Academy of Scientific & Innovative Research,
New Delhi, India.
I take the privilege to present the hard copy compilation for the [Volume 5 Issue (1)] of Journal of
Modern Chemistry & Chemical Technology (JoMCCT). The intension of JoMCCT is to create
an atmosphere that stimulates creativeness, research and growth in the area of Modern Chemistry
& Chemical Technology.
The development and growth of the mankind is the consequence of brilliant Research done by
eminent Scientists and Engineers in every field. JoMCCT provides an outlet for Research findings
and reviews in areas of Modern Chemistry & Chemical Technology found to be relevant for
National and International recent developments & research initiative.
The aim and scope of the Journal is to provide an academic medium and an important reference for
the advancement and dissemination of Research results that support high level learning, teaching and
research in the domain of Modern Chemistry & Chemical Technology.
Finally, I express my sincere gratitude and thanks to our Editorial/ Reviewer board and Authors for
their continued support and invaluable contributions and suggestions in the form of authoring write-
ups/ reviewing and providing constructive comments for the advancement of the journals. With
regards to their due continuous support and co-operation, we have been able to publish quality
Research/Reviews findings for our customers base.
I hope you will enjoy reading this issue and we welcome your feedback on any aspect of the Journal.
Dr. Archana Mehrotra
Director
STM Journals
Director's Desk
STM JOURNALS
1. Removal of CO using Aqueous Blends of Amines by Chemical Absorption Method: Modeling2
Shubham Singh, Soham Roy Chowdhury, Bindushree R P, Kinnera P, Sainath K 1
2. Spectral, Thermal, Electrochemical and Biological Studies of Co(II), Ni(II), Cu(II) and Zn(II) Complexes Derived from 4-(3-bromo-4-hydroxy-5-methoxybenzylideneamino)-3-mercapto-6-methyl-5-oxo-1,2,4-triazine Kiran Singh, Sunita Raparia, Chetan Sharma 6
3. Synthesis and Characterization of Composites of Beryllia and Lithium-titanate Produced by Solid State RouteB N Rath, S J Ghanwat, R. Mishra, C. Danani, D Sathiyamoorthy, S Anantharaman 17
4. Thermogravimetric and Crystallinity Studies of ER/PS BlendsVijayakumar PC, R Jeevan Kumar, Rajashekhara KM, Tom Cherian, Jobish Johns 28
5. Tracer Application in Study of Reaction Kinetics using Duolite ARA-9366B and Duolite A-638P. U. Singare 34
ContentsJournal of Modern Chemistry & Chemical Technology
JoMCCT (2014) © STM Journals 2014. All Rights Reserved
Journal of Modern Chemistry & Chemical Technology ISSN: 2321-5208
Volume 5, Issue 1
www.stmjournals.com
Removal of CO2 using Aqueous Blends of Amines by
Chemical Absorption Method: Modeling
Shubham Singh, Soham Roy Chowdhury, Bindushree R P, Kinnera P, Sainath K* Department of Chemical Engineering, BMS College of Engineering, # 1908, Bull Temple Road
Basavanagudi, Bangalore, India
Abstract Carbon capture from point source emissions has been recognized as one of the several
strategies necessary for mitigating unfettered release of greenhouse gases (GHG’s) into
the atmosphere to prevent global warming. To keep the GHG’s at manageable level,
large decrease of CO2 should take place through capture technologies like chemical
absorption. Alkanolamines such as monoethanolamine (MEA), diethanolamine (DEA), and N-methyldiethanolamine (MDEA) have been used for gas treating at industries.
There has been a growing interest today for gas treating by using blended amines. The
mixed amine systems, which combine the higher equilibrium capacity of the tertiary amine with the higher reaction rate of the primary or secondary amine, can bring about
considerable improvement in gas absorption like MDEA/MEA and MDEA/DEA are compared based on the reaction kinetics. Modeling is applied for absorption rate
constants for the above blended amines using MATLAB.
Keywords: CO2, chemical absorption, blended amines, rate kinetics
JoMCCT (2014)© STM Journals 2014. All Rights Reserved
Journal of Modern Chemistry & Chemical Technology ISSN: 2321-5208
Volume 5, Issue 1
www.stmjournals.com
Spectral, Thermal, Electrochemical and Biological Studies
of Co(II), Ni(II), Cu(II) and Zn(II) Complexes Derived from
4-(3-bromo-4-hydroxy-5-methoxybenzylideneamino)-3-
mercapto-6-methyl-5-oxo-1,2,4-triazine
Kiran Singh1*, Sunita Raparia
1, Chetan Sharma
2
1Department of Chemistry, Kurukshetra University, Kurukshetra-136119, India
2Department of Microbiology, Kurukshetra University, Kurukshetra-136119, India
Abstract The Schiff base4-(3-bromo-4-hydroxy-5-methoxybenzylideneamino)-3-mercapto-6-methyl-5-oxo-1,2,4-triazine and its Co(II), Ni(II), Cu(II) and Zn(II) complexes have been
synthesized and characterized by IR, NMR, electronic, ESR, fluorescence, thermal,
magnetic moment and electrochemical studies. IR and thermal data support the presence of coordinated water in the metal complexes. The electronic spectral and magnetic
moment measurements indicate octahedral geometry for Co(II), Ni(II) and Zn(II) complexes and square planar for Cu(II) complexes. Biological studies of the ligand and
its metal complexes have been carried out in vitro against Gram-positive
(Staphylococcus aureus, Bacillus subtilis), Gram-negative (Escherichia coli) bacteria and fungi (Aspergillus niger, Aspergillus flavus). The results show increased
antibacterial and antifungal activity of the metal complexes as compared to the ligand.
Keywords: Synthesis, 1,2,4-triazine, Schiff base, antimicrobial activity, metal
complexes
JoMCCT (2014) © STM Journals 2014. All Rights Reserved
Journal of Modern Chemistry & Chemical Technology ISSN: 2321-5208
Volume 5, Issue 1
www.stmjournals.com
Synthesis and Characterization of Composites of Beryllia
and Lithium-titanate Produced by Solid State Route
B N Rath1*, S J Ghanwat
2, R. Mishra
3, C. Danani
4,
D Sathiyamoorthy5, S Anantharaman
1
1Post Irradiation Examination Division, RLG, BARC, Trombay, Mumbai-400085
2 PMD, BARC, Vashi Complex, Navi Mumbai, India, 400705
3 ChD, BARC, Trombay, Mumbai-400085
4Institute for plasma research, Gandhinagar, India-382428
5Ex-head, PMD, BARC, Vashi Complex, Navi Mumbai, India, 400705
Abstract Beryllium oxide (BeO) is proposed to be used as a constituent for lithium titanate
(Li2TiO3) based composite material for neutron multiplication and breeding in International Thermonuclear Experimental Reactor (ITER) for its high thermal
conductivity, low neutron absorption cross-section and high neutron reflection cross
section. In the present investigation, we report the synthesis of single phase BeO-Li2TiO3
composites with BeO to Li2TiO3 (produced through solid state route) in volume ratios of
80:20, 75:25, 65:35 and 55:45. The samples have been characterized by X-ray diffraction and scanning electron microscopy. The values of thermal conductivity for
BeO-Li2TiO3 composites with BeO to Li2TiO3 in volume ratios of 80:20, 75:25, 65:35 and
55:45 have been obtained by thermal diffusivity measurements and specific heat measurements. The electrical conductivity of the composites has been obtained from
impedance measurements. The mechanical properties of the materials have been evaluated. From the present investigation, it could be concluded that it is possible to
achieve tritium breeding ratio (TBR) more than 1.1 by optimizing the BeO and Li2TiO3
ratio with better mechanical, thermal and electrical properties compared to the use of lithium titanate alone in the fusion reactor with metallic Be.
Keywords: Beryllium oxide, lithium titanate, ITER, Tritium breeding ratio, neutron
multiplier, neutron breeder
JoMCCT (2014)© STM Journals 2014. All Rights Reserved
Journal of Modern Chemistry & Chemical Technology ISSN: 2321-5208
Volume 5, Issue 1
www.stmjournals.com
Thermogravimetric and Crystallinity Studies
of ER/PS Blends
Vijayakumar PC1, 2
, R Jeevan Kumar3, Rajashekhara KM
4, Tom Cherian
5, Jobish Johns
1* 1Rajarajeswari College of Engineering, Bangalore, India
2Jawaharlal Nehru Technical University, Ananthapur, AP, India
3SK University, Ananthapur, AP, India
4SJCIT, Chikballapur, Bangalore, India
5Christ College, Irinjalakuda, Kerala, India
Abstract Thermoplastic elastomeric blends of polystyrene (PS) and exudated resin (ER) were
prepared by solution casting technique. The decomposition behavior of these blends was
studied by thermogravimetric analysis. The effect of blend ratio and cross linking on the
thermal behavior of ER/PS blend system was studied. An enhancement in thermal
stability was observed by the addition of ER into polystyrene. The activation energy of degradation was calculated by using Horowitz-Metzger equation. X-ray diffraction
technique was employed to study the crystalline nature of the blend system. A decrease in crystallinity was found for the blends with increase in ER content.
Keywords: Thermogravimetry, polymer blend, polystyrene, crystallinity
JoMCCT (2014)© STM Journals 2014. All Rights Reserved
Journal of Modern Chemistry & Chemical Technology ISSN: 2321-5208
Volume 5, Issue 1
www.stmjournals.com
Tracer Application in Study of Reaction Kinetics using
Duolite ARA-9366B and Duolite A-638
P. U. Singare*
Bhavan’s College, Andheri (West), Mumbai 400058, India
Abstract Radiotracer isotopes
131I and
82Br were used to study the iodide and bromide ion-isotopic
exchange reactions taking place in two anion exchange resins Duolite ARA-9366B
(nuclear grade) and Duolite A-638 (non-nuclear grade) under different operational parameters like temperature and ionic concentration of exchanging medium. The results
of present investigation indicate an existence of strong positive linear co-relationship
between amount of ions exchanged and concentration of ionic solution; while existence of strong negative co-relationship between amounts of ions exchanged and temperature of
exchanging medium. It was observed that during iodide ion-isotopic exchange reaction under identical experimental conditions of 40.0 °C, 1.000 g of ion exchange resins and
0.003 M labeled iodide ion solution, the values of specific reaction rate (min−1
), amount
of iodide ion exchanged (mmol), initial rate of iodide ion exchange (mmol/min) and log Kd were 0.185, 0.417, 0.077 and 10.2 respectively for Duolite ARA-9366B resin, which
was higher than 0.118, 0.338, 0.040 and 6.4 respectively for Duolite A-638 resins. It was observed that using Duolite ARA-9366B resins, at a constant temperature of 40.0 °C, as
the concentration of labeled iodide ion solution increases from 0.001–0.004 M, the
percentage of iodide ions exchanged increases from 51.70–57.5%. While using Duolite A-638 resins under identical experimental conditions, the percentage of iodide ions
exchanged increases from 43.20–45.80%. The identical trend was observed for the two
resins during bromide ion-isotopic exchange reaction. The overall results indicate superior performance of Duolite ARA-9366B resins over Duolite A-638 resins under
identical operational parameters.
Keywords: Radiotracer isotopes, 131
I; 82
Br, non-destructive technique, ion-isotopic
exchange reactions, radio analytical technique, anion exchange resins, nuclear
grade resin, Duolite ARA-9366B, Duolite A-638