January 2017 Version 2.1 Coop Negative List for Textile ... und... · January 2017 Version 2.1...

January 2017 Version 2.1

Priority Achieved by Colour Code

1 End of December 2015






Phthalates, SCCPs

Heavy Metals, PAHs, Glycols,

Halogenated Solvents, VOCs,

Formaldehyde

Additional Restricted

Chemical Substances

The Coop negative list for textiles and leather is a dynamic document that takes account of the latest knowledge

from toxicological studies and global legislation, as well as the current technological possibilities, and is

accordingly updated on a regular basis. Suppliers are notified of updated documents by Coop Extranet info-mail.

Coop suppliers are asked to always use these documents and on that basis implement measures to eliminate

hazardous chemicals across the entire supply chain. The supplier must proactively notify Coop if it is currently

unable to conform to these requirements.

Chlorobenzenes, Chlorotoluenes,

Chlorophenols, Organotin

Compounds, Toluene, DMFa, DMFu

APEOs, PFCs

Azo Dyes, Carcinogenic Dyes,

Allergenic-Disperse Dyes,

Brominated and Chlorinated Flame

Retardants, Other Flame Retardants

Coop Negative List for Textile and Leather

The Coop Negative List details substances that are restricted or banned in production due to their negative impact

on human health and the environment.

The Negative List is divided into two parts:

Part B - Coop Restricted Substances List for Products (Coop PRSL)

Part A - Coop Restricted Substances List in Production (Coop MRSL; limit values for input chemicals, wastewater

and sludge)

The Coop MRSL (Part A) outlines limit values for the Detox Priority Substances Groups in input chemicals used

in a production facility as well as wastewater and sludge discharged during production from that facility. All

chemicals used in production processes at a facility must meet these requirements, it is prohibited to use the

substances listed intentionally. For each limit, a test method is specified that must be used for laboratory analysis.

The Coop PRSL (Part B) deliberately sets limits for finished products as well as for cross contamination of these

substances, including when substances are used unintentionally. It contains all substances from Part A in addition

to those which Coop considers to ban in the future. Depending on their priority, chemicals may no longer be

consciously used (= inclusion in the Coop MRSL) or must be gradually replaced with non-toxic alternatives by a

specific date (see priorities).

If several product limit values are stated per substance, the following categories are differentiated: A: baby skin

contact / B: adult skin contact. For each limit, a test method is specified, that must be used for laboratory analysis

of the finished products.

Additional Substances to the ZDHC MRSL 1.1

The status of elimination of the restricted chemicals has been defined by Coop's Detox commitment and each

chemical group has been prioritized for elimination till the year 2020. The priority is highlighted by a colour code

in the document for easy identification and implementation by Coop's supply chain:

Restricted Chemical Group

1/14


Limit Test MethodLimit

[µg/L]

Test

Method

Limit

[mg/kg]

Test

Method

104-40-5

11066-49-2

25154-52-3

84852-15-3

140-66-9

1806-26-4

27196-28-8

9002-93-1

9036-19-5

68987-90-6

9016-45-9

26027-38-3

37205-87-1

68412-54-4

127087-87-0

95-50-1 1,2-dichlorobenzene 1000 ppm

25167-83-3 Tetrachlorophenol (TeCP)

87-86-5 Pentachlorophenol (PCP)

4901-51-3 2,3,4,5-tetrachlorophenol



95-57-8 2-chlorophenol

120-83-2 2,4-dichlorophenol



95-95-4 2,4,5-trichlorophenol










101-14-44,4’ -methylene -bis -(2-chloro -

aniline) 150 ppm

101-77-9 4,4’-methylenedianiline 150 ppm

101-80-4 4,4’-oxydianiline 150 ppm

106-47-8 4-chloroaniline 150 ppm

119-90-4 3,3’-dimethoxylbenzidine 150 ppm

119-93-7 3,3’-dimethylbenzidine 150 ppm

120-71-8 6-methoxy-m-toluidine 150 ppm

137-17-7 2,4,5-trimethylaniline 150 ppm

139-65-1 4,4’-thiodianiline 150 ppm

60-09-3 4-aminoazobenzene 150 ppm

615-05-4 4-methoxy-m-phenylenediamine 150 ppm

838-88-0 4,4’-methylenedi-o-toluidine 150 ppm

87-62-7 2,6-xylidine 150 ppm

90-04-0 o-anisidine 150 ppm

91-59-8 2-naphthylamine 150 ppm

91-94-1 3,’3-dichlorobenzidine 150 ppm

92-67-1 4-aminodiphenyl 150 ppm

Octylphenol ethoxylates (OPEO)

Nonylphenol ethoxylates (NPEO)

250 ppm

250 ppm

500 ppm

500 ppm

Liquid chromatography-

mass spectrometry (LC-

MS),

gas chromatography-

mass spectrometry

(GC-MS)

2. Chlorobenzenes and Chlorotoluenes

Other isomers of mono-, di-, tri-, tetra-, penta- and

hexachlorobenzene and mono-, di-, tri-, tetra- and

pentachlorotoluene

Sum = 200 ppmGC-MS 0.1

Extraction with

reference to EPA

3540C and

analysis by EPA

8270D

Input Chemicals

Part A - Coop Restricted Substances List in Production (Coop MRSL)

Wastewater Sludge

CAS Substance Name

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. Isomers

Nonylphenol (NP), mixed isomers

Octylphenol (OP), mixed isomers

3. Chlorophenols

Sum = 20 ppm

Sum = 50 ppm

GC-MS

EN ISO 17070

4. Dyes - Azo (Forming Restriced Amines)

0.5

Extraction as per

US EPA 3510C

and

quantification as

per EPA 8270D

or ISO

14154:2005

(using GC-ECD)

0.6

Reference to

ASTM

D5369, EPA

3540C (For

extraction) &

EPA 8270D (for

analysis)

With reference to

EN 14362-1 &

EN 14362-3

Or

U.S. EPA 8270D

(Extraction by

EPA 3510C)

0.1

U.S. EPA

8270D

(Extraction by

EPA 3510C)

For NP and OP: EN

ISO 18857-1-2006

(GC-MS) or EN ISO

18857-2-2011

(GC-MS) or ASTM

D7065 (GC-MS)

For NPEO& OPEO

(1-2 moles) :

EN ISO 18857-2-

2011

(GC-MS) or ASTM

D7485 - 09

(LC-MS-MS)

For NPEO&OPEO (3-

18 moles): With

reference to

ISO/DIS 18254-

2014

1

5

0.2

Reference to

ASTM D5369 or

EPA 3540C (for

extraction) and

analysis with

reference to EN

ISO 18857-2-

2011 (for, NP,

OP, 1-2 moles

NPEO, OPEO)

and With

reference to

ISO/DIS 18254-

2014 (for NPEO

and OPEO (3-

18) moles

0.2

U. S. EPA 8260B

(purge and trap

method) or U. S.

EPA 8270D.

LC, GC 0.1

2/14



[µg/L]

Test

Method

Limit

[mg/kg]

Test

Method

Input Chemicals Wastewater Sludge

CAS Substance Name

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. Isomers92-87-5 Benzidine 150 ppm

95-53-4 o-toluidine 150 ppm

95-68-1 2,4-xylidine 150 ppm

95-69-2 4-chloro-o-toluidine 150 ppm

95-80-7 4-methyl-m-phenylenediamine 150 ppm

97-56-3 o-aminoazotoluene 150 ppm

99-55-8 5-nitro-o-toluidine 150 ppm

118685-33-9Component 1:

C39H23ClCrN7O12S·2Na

Not Allocated Component 2:

C46H30CrN10O20S2·3Na

1937-37-7 C.I. Direct Black 38 250 ppm

2602-46-2 C.I. Direct Blue 6 250 ppm

3761-53-3 C.I. Acid Red 26 250 ppm

569-61-9 C.I. Basic Red 9 250 ppm

573-58-0 C.I. Direct Red 28 250 ppm

632-99-5 C.I. Basic Violet 14 250 ppm

2475-45-8 C.I. Disperse Blue 1 250 ppm

2475-46-9 C.I. Disperse Blue 3 250 ppm

2580-56-5C.I. Basic Blue 26 (with Michler’s

Ketone > 0.1%) 250 ppm

569-64-2C.I. Basic Green 4 (malachite green

chloride) 250 ppm

2437-29-8C.I. Basic Green 4 (malachite green

oxalate) 250 ppm

10309-95-2C.I. Basic Green 4 (malachite

green) 250 ppm

85136-74-9 C.I. Disperse Orange 149 250 ppm

6250-23-3 C.I. Disperse Yellow 23 250 ppm

16071-86-6 C.I. Direct Brown 95 250 ppm

60-09-3 C.I. Solvent Yellow 1 250 ppm



8004-87-3 C.I. Basic Violet 1 250 ppm



6459-94-5 C.I. Acid Red 114 250 ppm

1694-09-3 C.I. Acid Violet 49 250 ppm

1344-37-2 C.I. Pigment Yellow 34 250 ppm

12656-85-8 C.I. Pigment Red 104 250 ppm

119-15-3 Disperse Yellow 1 250 ppm

12222-97-8 Disperse Blue 102 250 ppm



13301-61-6 Disperse Orange 37/59/76 250 ppm

23355-64-8 Disperse Brown 1 250 ppm

2581-69-3 Disperse Orange 1 250 ppm


2872-48-2 Disperse Red 11 250 ppm









730-40-5 Disperse Orange 3 250 ppm

12222-75-2

56524-77-7

56524-76-6

Disperse Blue 35 250 ppm

0.3

ASTM D5369 or

US EPA 3540C

(For

Extraction)

Analysis with

reference to

ISO 16373-2

or EPA 8321B

With reference to

EN 14362-1 &

EN 14362-3

Or

U.S. EPA 8270D

(Extraction by

EPA 3510C)

0.1

U.S. EPA

8270D

(Extraction by

EPA 3510C)

50

With reference to

DIN 54231 (LC-DAD-

MS)

Or

U.S.EPA 8321B

0.3

LC 10

8. Flame Retardants

7. Dyes - Disperse (Sensitising)

LC

LC, GC

5. Dyes - Navy Blue Colourant

250 ppm LC

6. Dyes - Carcinogenic or Equivalent Concern

0.1

10

With reference to

DIN 54231 (LC-

DAD-MS)

Or

Reference to ISO

16373-3:2014

Or

US EPA 8321B

0.3

ASTM D5369 or

US EPA 3540C

(For

Extraction)

Analysis with

reference to

ISO 16373-2

or EPA 8321B

ASTM D5369 or

US EPA 3540C

(For Extraction)

Analysis with

reference to ISO

16373-2 or EPA

8321B

With reference to

DIN 54231 (LC-

DAD-MS)

Or

Reference to ISO

16373-3:2014

Or

US EPA 8321B

3/14



[µg/L]

Test

Method

Limit

[mg/kg]

Test

Method


CAS Substance Name

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. Isomers115-96-8 Tris(2-chloroethyl)phosphate (TCEP) 250 ppm

1163-19-5Decabromodiphenyl ether

(DecaBDE) 250 ppm

126-72-7Tris(2,3,-dibromopropyl)8phosphate

(TRIS) 250 ppm

32534-81-9Pentabromodiphenyl ether

(PentaBDE) 250 ppm

32536-52-0 Octabromodiphenyl ether (OctaBDE) 250 ppm

5412-25-9Bis(2,3-dibromopropyl)phosphate

(BIS) 250 ppm

545-55-1Tris(1-aziridinyl)phosphine oxide)

(TEPA) 250 ppm

59536-65-1 Polybromobiphenyls (PBB) 250 ppm

79-94-7 Tetrabromobisphenol A (TBBPA) 250 ppm

3194-55-6 Hexabromocyclodecane (HBCDD) 250 ppm

3296-90-02,2-bis(bromomethyl)-1,3-

propanediol (BBMP) 250 ppm

13674-87-8Tris(1,3-dichloro-isopropyl)

phosphate (TDCP) 250 ppm

40088-47-9Tetrabromodiphenyl ether

(TetraBDE)250 ppm

36483-60-0Hexabromodiphenyl ethers

(HexaBDE)250 ppm

68928-80-3Heptabromodiphenyl ether

(HeptaBDE)250 ppm

63936-56-1Nonabromodiphenyl ether

(NonaBDE)250 ppm

13674-84-5Tris(1-chloro-2-propyl)phosphate

(TCPP)250 ppm

1303-96-

41330-43-4

12179-04-3

Sodium tetraborate tbd

1303-86-2 Boron trioxide tbd

10043-35-3

11113-50-1Boric acid tbd

1309-64-4 Antimony trioxide tbd

78-30-8 Tri-o-cresyl phosphate tbd

85535-84-8Short-chain chlorinated Paraffins

(SCCP) (C10-C13) 50 ppm EN-ISO-18219 0.5

BS EN ISO

12010:20140.03

Reference to

ASTM

D5369, EPA

3540C &

ISO/PRF 12010

111-96-6 Bis(2-methoxyethyl)-ether 50 ppm

110-80-5 2-ethoxyethanol 50 ppm

111-15-9 2-ethoxyethyl acetate 50 ppm

110-71-4 Ethylene glycol dimethyl ether 50 ppm

109-86-4 2-methoxyethanol 50 ppm

110-49-6 2-methoxyethylacetate 50 ppm

70657-70-4 2-methoxypropylacetate 50 ppm

112-49-2 Triethylene glycol dimethyl ether 50 ppm

107-06-2 1,2-dichloroethane 5 ppm

75-09-2 Methylene chloride 5 ppm

79-01-6 Trichloroethylene 40 ppm

127-18-4 Tetrachloroethylene 5 ppm

Multiple Dibutyltin (DBT) 20 ppm

Multiple Mono-, di- and tri-methyltin

derivatives 5 ppm

Multiple Mono-, di- and tri-butyltin

derivatives 5 ppm

Multiple Mono-, di- and tri-phenyltin

derivatives 5 ppm

Multiple Mono-, di- and tri-octyltin

derivatives 5 ppm

50-32-8 Benzo[a]pyrene (BaP) 20 ppm

120-12-7 Anthracene

129-00-0 Pyrene

191-24-2 Benzo[ghi]perylene

GC-MS

11. Organotin Compounds

GC-MS, low resolution

mass

spectrometry (LRMS)

12. Polycyclic Aromatic Hydrocarbons (PAHs)

Sum = 200 ppm

GC-MS

US EPA Method

8015 D

modified with

ENVI-Carb Plus

SPE

Or

US EPA 8270

(LC-MS)

1

tbd

10. Halogenated Solvents

DIN 38407-39

(2011-09)

Or

US EPA 610

0.6

U.S. EPA

8270D and EPA

3510C

1

ISO 10301:1997

Or

US EPA Methods

524.2, 5030C,

8260 B

0.3

With reference

to U.S. EPA

8260C ,

5035A, 5021,

8021B &

8260B

0.01 ISO 17353 50

Reference to

ASTM

D5369, EPA

3540C (for

extraction) &

DS/EN ISO

23161

GC-MS 5

ISO 22032:2006

(for polyBDEs)

and US EPA 527

with

quantification by

US EPA 8321B

(GC-MS or LC-MS-

MS)

0.25

ASTM D5369-

93 (2008)e1 or

EPA 3540C

(Standard for

extraction) with

1) DIN ISO

22032-2009

Or

2) US EPA 527

and U.S. EPA

8321B.

50

tbd tbd tbd tbd

9. Glycols

High-performance

liquid

chromatography

(HPLC), LC-MS

US EPA Method

8015 D modified

with ENVI-Carb

Plus SPE

Or

US EPA 8270

(LC-MS)

50

4/14



[µg/L]

Test

Method

Limit

[mg/kg]

Test

Method


CAS Substance Name

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. Isomers192-97-2 Benzo[e]pyrene

193-39-5 Indeno[1,2,3-cd]pyrene

205-82-3 Benzo[j]fluoranthene

205-99-2 Benzo[b]fluoranthene

206-44-0 Fluoranthene

207-08-9 Benzo[k]fluoranthene

208-96-8 Acenaphthylene

218-01-9 Chrysene

53-70-3 Dibenz[a,h]anthracene

56-55-3 Benzo[a]anthracene

83-32-9 Acenaphthene

85-01-8 Phenanthrene

86-73-7 Fluorene

91-20-3 Naphthalene GC-MS, LC

335-67-1 Perfluorooctanic acid (PFOA)

375-22-4 Perfluorobutanoic acid (PFBA)

2706-90-3 Perfluoropentanoic acid (PFPA)

307-24-4 Perfluorohexanoic acid (PFHxA)

375-85-9 Perfluoroheptanoic acid (PFHpA)

375-95-1 Perfluorononanoic acid (PFNA)

335-76-2 Perfluorodecanoic acid (PFDA)

2058-94-8 Perfluoroundecanoic acid (PFUnA)

307-55-1 Perfluorododecanoic acid (PFDoA)

72629-94-8 Perfluorotridecanoic acid (PFTrDA)

376-06-7 Perfluorotetradecanoic acid (PFTeA)

1763-23-1Perfluorooctane sulphonic acid

(PFOS)

375-73-5 Perfluorobutane sulphonic acid

(PFBS)

355-46-4Perfluorohexane sulphonic acid

(PFHxS)

375-92-8Perfluoroheptane sulphonic acid

(PFHpS)

335-77-3Perfluorodecane sulphonic acid

(PFDS)

172155-07-6Perfluoro-3,7-dimethyl octanoic acid

(PF-3,7-DMOA)

1546-95-87H-Dodecafluoroheptanoic acid

(HPFHpA)

27854-31-52H,2H-Perfluorodecanoic acid

(H2PFDA)

27619-97-2

1H,1H,2H,2H-

perfluorooctanesulfonate, (H4PFOS

6:2 FTS)

754-91-6Perfluoro-1-octanesulfonamide

(PFOSA)

31506-32-8N-methylperfluoro-1-

octanesulfonamide

(N-MeFOSA)

4151-50-2N-ethylperfluoro-1-

octanesulfonamide

(N-EtFOSA)

24448-09-72-(N-methylperfluoro-1-

octanesulfonamido)-ethanol

(NMeFOSE)

1691-99-22-(N-ethylperfluoro-1-

octanessulfonamido)-ethanol

2043-47-21H,1H,2H,2H-Perfluoro-1-hexanol

(4:2 FTOH)

647-42-71H,1H,2H,2H-Perfluoro-1-octanol

(6:2 FTOH)

678-39-71H,1H,2H,2H-Perfluoro-1-decanol

(8:2 FTOH)

865-86-11H,1H,2H,2H-Perfluoro-1-dodecanol

(10:2 FTOH)

17527-29-61H,1H,2H,2H-Perfluorooctylacrylate

(6:2 FTAC)

27905-45-91H,1H,2H,2H-Perfluorodecylacrylate

(8:2 FTAC)

17741-60-5

1H,1H,2H,2H-

Perfluorododecylacrylate

(10:2 FTAC)

0.01

ISO 25101:2009

or DIN 38407-42

(modified)

0.001

ASTM D5369,

EPA 3540C (for

extraction) and

with reference to

CEN/TS 15968

(LC-MS-MS)

13. Perfluorinated and Polyfluorinated Chemicals (PFCs)

Sum = 200 ppm

GC-MS1

14. Phthalates - including all other esters of ortho-phthalic acid

2 ppm LC-MS

DIN 38407-39

(2011-09)

Or

US EPA 610

0.6

U.S. EPA

8270D and EPA

3510C

5/14



[µg/L]

Test

Method

Limit

[mg/kg]

Test

Method


CAS Substance Name

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. Isomers117-81-7 Di(ethylhexyl) phthalate (DEHP)

117-82-8Bis(2-methoxyethyl) phthalate

(DMEP)

117-84-0 Di-n-octyl phthalate (DNOP)

26761-40-0 Di-iso-decyl phthalate (DIDP)

28553-12-0 Di-isononyl phthalate (DINP)

84-75-3 Di-n-hexyl phthalate (DnHP)

84-74-2 Dibutyl phthalate (DBP)

85-68-7 Butyl benzyl phthalate (BBP)

84-76-4 Dinonyl phthalate (DNP)

84-66-2 Diethyl phthalate (DEP)

131-16-8 Di-n-propyl phthalate (DPRP)

84-69-5 Di-isobutyl phthalate (DIBP)

84-61-7 Di-cyclohexyl phthalate (DCHP)

27554-26-3 Di-iso-octyl phthalate (DIOP)

68515-42-4

1,2-benzenedicarboxylic acid, di-C7-

11-branched

and linearalkyl esters (DHNUP)

71888-89-61,2-benzenedicarboxylic acid,di-C6-

8-branched

alkyl esters,C7-rich (DIHP)

7440-38-2 Arsenic (As) 50 ppm 0.1ISO 11885 (ICP-

OES) or ISO 17294-

2 (ICP-MS)

7440-43-9 Cadmium (Cd)

20 ppm

(50 ppm for

pigments)

0.1ISO 11885 (ICP-

OES) or ISO 17294-

2 (ICP-MS)

7439-97-6 Mercury (Hg)

4 ppm

(25 ppm for

pigments)

0.01ISO 12846 or

178520.02 U.S. EPA 7471B

7439-92-1 Lead (Pb) 100 ppm 0.1ISO 11885 (ICP-

OES) or ISO 17294-

2 (ICP-MS)

1

U.S. EPA 3051A,

3050B (for

digestion) ;

analysis by EPA

6011

18540-29-9 Chromium (VI) 10 ppm 0.05 ISO 18412 1

U.S. EPA 3060A

(for digestion) ;

With reference to

7199

71-43-2 Benzene 50 ppm 30US EPA 8260

C

1330-20-7 Xylene 500 ppm 15 US EPA 8260 B

95-48-7 o-cresol 500 ppm

106-44-5 p-cresol 500 ppm

108-39-4 m-cresol 500 ppm

85535-84-8Short-chain chlorinated Paraffins

(SCCP) (C10-C13) 250 ppm EN-ISO-18219 0.5

BS EN ISO

12010:20140.03

Reference to

ASTM

D5369, EPA

3540C &

ISO/PRF 12010

15. Total Heavy Metals

16. Volatile Organic Compounds (VOCs)

GC-MS

US EPA 8041A10

2 ISO 11423-1

1

EPA 3540C

(For extraction)

&

EPA 8270D (for

analysis)

1

U.S. EPA 3051A,

3050B (for

digestion) ;

analysis by EPA

6011

Listed metals are banned from intentional use in textile manufacturing/finishing. Additionally, residual traces of antimony, zinc, copper, nickel, tin, barium, cobalt,

iron,

manganese, selenium and silver in colourants are expected to comply with the Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers

(ETAD)

concentration limits (http://www.etad.com/).

Sum of all

phthalates

= 250 ppm

GC-MS

1) ISO 18856

(Scope: DMP,

DEP, TPP, DiBP,

DBP, BBP, DCHP,

DEHP, DOP,

DDcP and DUP)

2) U.S. EPA

8270D and EPA

3510C (for

extraction)

10

Reference to

ASTM D5369 or

EPA 3540C

(For Extraction)

and analysis by

EPA 8270D

0.3

Inductively coupled

plasma-

optical emission

spectrometry (ICP-

OES),

atomic absorption

spectroscopy (AAS)

Cr (III) Tanning agents

can be

monitored for Cr(VI)

EN ISO 17075 (Current

Use)

ISO/DIS 19071 (Draft)

17. Fat Liquoring Agents

6/14


Priority Substance Name CAS NumberLimit

[mg/kg]Test Method

104-40-511066-49-225154-52-384852-15-39016-45-926027-38-337205-87-168412-54-4127087-87-0

140-66-9, 1806-26-41806-26-427196-28-89002-93-19036-19-568987-90-6

Dichlorobenzenes various1,2-Dichlorobenzene 95-50-11,3-Dichlorobenzene 541-73-11,4-Dichlorobenzene 106-46-7Trichlorobenzenes various1,2,3-Trichlorobenzene 87-61-61,2,4-Trichlorobenzene 120-82-11,3,5-Trichlorobenzene 108-70-3Tetrachlorobenzene 12408-10-51,2,3,4-Tetrachlorobenzene 634-66-21,2,3,5-Tetrachlorobenzene 634-90-21,2,4,5-Tetrachlorobenzene 95-94-3Pentachlorobenzene 608-93-5Hexachlorobenzene 118-74-1

2-Chlorotoluene 95-49-83-Chlorotoluene 108-41-84-Chlorotoluene 106-43-42,3-Dichlorotoluene 32768-54-02,4-Dichlorotoluene 95-73-82,5-Dichlorotoluene 19398-61-92,7-6 Dichlorotoluene 118-69-43,4-Dichlorotoluene 95-75-02,3,6-Trichlorotoluene 2077-46-52,4,5-Trichlorotoluene 6639-30-1

α,2,4-Trichlorotoluene 94-99-5α,2,6-Trichlorotoluene 2014-83-7α,3,4-Trichlorotoluene 102-47-6α,α,2,6-Tetrachlorotoluene 81-19-6α,α,α,2-Tetrachlorotoluene 2136-89-2α,α,α,4-Tetrachlorotoluene 5216-25-12,3,4,5,6-Pentachlorotoluene 877-11-2Benzotrichloride 98-07-7

Monochlorophenol various 0.5Dichlorophenols (DiCP) 25167-81-12-Chlorophenol 95-57-82,3-Dichlorophenol 576-24-92,4-Dichlorophenol 120-83-22,5-Dichlorophenol 583-78-82,6-Dichlorophenol 87-65-03,4-Dichlorophenol 95-77-23,5-Dichlorophenol 591-35-53-Chlorophenol 108-43-04-Chlorophenol 106-48-9Trichlorophenol (TriCP) 25167-82-22,4,6-Trichlorophenol 88-06-22,3,4-Trichlorophenol 15950-66-02,3,5-Trichlorophenol 933-78-82,3,6-Trichlorophenol 933-75-52,4,5-Trichlorophenol 95-95-43,4,5-Trichlorophenol 609-19-8Tetrachlorophenols (TeCP) diverse 25167-83-32,3,4,5-Tetrachlorophenol 4901-51-32,3,4,6-Tetrachlorophenol 58-90-2

Part B - Coop Restricted Substances List for Products (Coop PRSL)

Restriction on Inadmissible Substances in Finished Products

2. Chlorobenzenes

3. Chlorotoluenes

4. Chlorophenols


Nonylphenol (NP) & mixed isomers

Nonylphenol ethoxylates (NPEOs)

Octylphenol (OP) & mixed isomers

Octylphenol ethoxylates (OPEOs)

10

1. For textile articles:

ISO/DIS 18254-1:2016

(NPEO & OPEO)

Solvent extraction GC-MS

(NP & OP)

2. For leather and

process auxillaries:

a) ISO 18218-1:2015 (1

to 16 moles NPEO and

OPEO)

b) ISO 18218-2:2015 (1

to 16 moles NPEO &

OPEO + NP & OP)

100

10

Sum of all <10

Sum of all <0.5

100

Sum of all <1 DIN 54232

§64 LFGB BVL B 82.02-8

(2001) (for textiles) and

ISO 17070:2015 (for

leather)

Sum of all <1

DIN 54232

P1

P3

P3

P3

7/14



[mg/kg]Test Method

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. Isomers2,3,5,6-Tetrachlorophenol 935-95-5Pentachlorophenol (PCP) 87-86-5 0.05/0.54-Chloro-3-methylphenol 59-50-7 1000

2,4,5-Trimethylaniline 137-17-7 202,4-Diaminoanisole 615-05-4 202,4-Toluenediamine 95-80-7 202,4-Xylidine 95-68-1 202,6-Xylidine 87-62-7 202-Amino-4-nitrotoluene 99-55-8 202-Naphthylamine 91-59-8 203,3’-Dichlorobenzidine 91-94-1 203,3’-Dimethoxybenzidine 119-90-4 203,3’-Dimethyl-4,4’diaminodiphenylmethane 838-88-0 203,3’-Dimethylbenzidine 119-93-7 204,4’-Diaminodiphenylmethane 101-77-9 204,4’-Methylene-bis(2-chloroaniline) 101-14-4 204,4’-Oxydianiline 101-80-4 204,4’-Thiodianiline 139-65-1 204-Aminobiphenyl 92-67-1 204-Chloro-o-toluidine 95-69-2 20Benzidine 92-87-5 20o-Aminoazotoluene 97-56-3 20o-Anisidine 90-04-0 20o-Toluidine 95-53-4 20p-Aminoazobenzene 60-09-3 20p-Chloroaniline 106-47-8 20p-Cresidine 120-71-8 20

C.I. Disperse Blue 1 2475-45-8 5 mg/LC.I. Disperse Orange 11 82-28-0 5 mg/LC.I. Disperse Orange 149 85136-74-9 5 mg/LC.I. Disperse Yellow 23 6250-23-3 5 mg/L

Component 1: C39H23ClCrN7O12S∙2Na (Navy

Blue Colourant)118685-33-9 5 mg/L

Component 2: C46H30CrN10O20S2∙3Na (Navy

Blue Colourant)Not Allocated 5 mg/L

C.I. Acid Red 26 3761-53-3 5 mg/LC.I. Direct Black 38 1937-37-7 5 mg/LC.I. Direct Blue 6 2602-46-2 5 mg/LC.I. Direct Red 28 573-58-0 5 mg/LC.I. Basic Blue 26 2580-56-5 5 mg/LC.I. Basic Green 4 (Malachite Green) 10309-95-2 5 mg/LC.I. Basic Red 9 569-61-9 5 mg/LC.I. Basic Violet 14 632-99-5 5 mg/LC.I. Direct Brown 95 16071-86-6 5 mg/LC.I. Disperse Yellow 3 2832-40-8 5 mg/LC.I. Solvent Yellow 1 60-09-3 5 mg/LC.I. Solvent Yellow 2 60-11-7 5 mg/LC.I. Solvent Yellow 3 97-56-3 5 mg/LC.I. Solvent Yellow 14 842-07-9 5 mg/LC.I. Basic Violet 1 8004-87-3 5 mg/LC.I. Direct Blue 15 2429-74-5 5 mg/LC.I. Direct Blue 218 28407-37-6 5 mg/LC.I. Acid Red 114 6459-94-5 5 mg/LC.I. Acid Violet 49 1694-09-3 5 mg/L

C.I. Basic Green 4 (malachite green oxalate) 2437-29-8 5 mg/L

C.I. Basic Green 4 (malachite green chloride) 569-64-2 5 mg/L

C.I. Pigment Yellow 34 1344-37-2 5 mg/L

C.I. Pigment Red 104 12656-85-8 5 mg/L

C.I. Disperse Blue 1 2475-45-8 5 mg/LC.I. Disperse Blue 102 12222-97-8 5 mg/LC.I. Disperse Blue 106 12223-01-7 5 mg/LC.I. Disperse Blue 124 61951-51-7 5 mg/LC.I. Disperse Blue 26 3860-63-7 5 mg/LC.I. Disperse Blue 3 2475-46-9 5 mg/L

C.I. Disperse Blue 3512222-75-2; 56524-77-7;

56524-76-65 mg/L

C.I. Disperse Blue 7 3179-90-6 5 mg/LC.I. Disperse Brown 1 23355-64-8 5 mg/LC.I. Disperse Orange 1 2581-69-3 5 mg/LC.I. Disperse Orange 3 730-40-5 5 mg/LC.I. Disperse Orange 37/59/76 13301-61-6 5 mg/LC.I. Disperse Red 1 2872-52-8 5 mg/L

5. Azo Dyes (reductively cleavable, carcinogenic arylamines)

6. Carcinogenic Dyes

7. Allergenic-Disperse Dyes

Sum of all <0.5§64 LFGB BVL B 82.02-8

(2001) (for textiles) and

ISO 17070:2015 (for

leather)

For textiles:

EN 14362-1:2012

EN 14362-3:2012 (for 4-

Aminoazobenzene)

Natural leather :

EN ISO 17234-1:2015

EN ISO 17234-2:2011

(for

4-Aminoazobenzene)

Products for China

market:

Textiles: GB/T 17592

(China Standard:

GB18401)

Natural leather: GB/T

19942 (China Standard:

GB20400)

P3

P2

P2

P2

DIN 54231:2005 (for all

listed colourants)

ISO 16373-2:2014

DIN 54231:2005 (for all

listed colorants)

ISO 16373-2:2014

8/14



[mg/kg]Test Method

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. IsomersC.I. Disperse Red 11 2872-48-2 5 mg/LC.I. Disperse Red 17 3179-89-3 5 mg/LC.I. Disperse Yellow 1 119-15-3 5 mg/LC.I. Disperse Yellow 3 2832-40-8 5 mg/LC.I. Disperse Yellow 9 6373-73-5 5 mg/LC.I. Disperse Yellow 39 12236-29-2 5 mg/L

C.I. Disperse Yellow 49 54824-37-2 5 mg/L

Tris(2-chloroethyl)phosphate (TCEP) 115-96-8 10Bis(2,3-dibromopropyl)phosphate 5412-25-9 10Tetrabromodiphenyl ether (TetraBDE) 40088-47-9 10Pentabromodiphenyl ether (PentaBDE) 32534-81-9 10Hexabromodiphenyl ethers (HexaBDE) 36483-60-0 10Heptabromodiphenyl ether (HeptaBDE) 68928-80-3 10Octabromodiphenyl ether (OctaBDE) 32536-52-0 10Nonabromodiphenyl ether (NonaBDE) 63936-56-1 10Decabromodiphenyl ether (DecaBDE) 1163-19-5 10

Hexabromocyclodecane (HBCDD)

25637-99-4, 3194-55-6,

134237-50-6, 134237-51-

7, 134237-52-8

10

2,2-Bis(bromomethyl)-1,3-propanediol (BBMP) 3296-90-0 10

Polybromobiphenyl (PBB) 59536-65-1 10

Tetrabromobisphenol A (TBBPA) 79-94-7 10

Tris(1,3-dichloro-isopropyl) phosphate (TDCP) 13674-87-8 10

Tris(1-chloro-2-propyl)phosphate (TCPP) 13674-84-5 10Tris(2,3,-dibromopropyl)-phosphate (TRIS) 126-72-7 10

Tris(1-aziridinyl)phosphine oxide) (TEPA) 545-55-1 10Acetone extraction,

followed by LC-MS

Sodium tetraborate1303-96-4;1330-43-4;

12179-04-31000

Boron trioxide 1303-86-2 1000Boric acid 10043-35-3; 11113-50-1 1000

Antimony trioxide 1309-64-4 200 (as Sb)

Indirect method for the

analysis: Acid digestion

ICP-OES / ICP-MS for

analysis

Tri-o-cresyl phosphate 78-30-8 10

Extraction following IEC

62321-6:2015 // LC-MS,

GC-MS-NCI

P4Short-chain chlorinated Paraffins (SCCPs) with

C10 - C1385535-84-8 50 ISO 18219:2015

2-Ethoxyethanol 110-80-5 5

2-Methoxyethanol 109-86-4 5

2-Methoxyethylacetate 110-49-6 5

2-Methoxypropylacetate 70657-70-4 5

Ethylene glycol dimethyl ether (EDGME) 110-71-4 100

Triethylene glycol dimethyl ether 112-49-2 5

Bis(2-methoxyethyl)-ether 111-96-6 5

2-Ethoxyethyl acetate 111-15-9 80

1,1,1,2-Tetrachloroethane 630-20-6 21,1,1-Trichloroethane 71-55-6 21,1,2,2-Tetrachloroethane 79-34-5 21,1,2-Trichloroethane 79-00-5 21,1-Dichloroethane 75-34-3 21,1-Dichloroethylene 75-35-4 21,2-Dichloroethane 107-06-2 2Chloroform 67-66-3 5Methylene chloride, Dichloromethane 75-09-2 5Pentachloroethane 76-01-7 2Tetrachloroethylene 127-18-4 1Tetrachloromethane 56-23-5 2Trichloroethylene 79-01-6 40

Mono, Di & Tri-butyltin derivatives Various Sum <0.2

8. Brominated and Chlorinated Flame Retardants

12. Organotin Compounds

11. Halogenated Solvents

Solvent extraction / GC-

MS or LC-MS

For China market:

GB/T 24279-2009

Recommended: Acid

digestion/ICP-OES or ICP-

MS for analysis

Textile:

Extraction with MeOH //

GC-MS or LC-MS

Plastic:

2-Step extraction with

THF and

MeOH // GC-MS or LC-MS

Methanol extraction

followed by Headspace

GC-MS

ISO/TS 16179:2012 (for

all listed analytes)

P5

P3

9. Short-Chain Chlorinated Paraffins (SCCPs)

P2

P2

P2

Subgroup: Other Flame Retardants

10. Glycols

DIN 54231:2005 (for all

listed colorants)

ISO 16373-2:2014

P5

9/14



[mg/kg]Test Method

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. IsomersMono, Di & Tri-methyltin derivatives Various Sum <0.2Mono, Di & Tri-phenyltin derivatives Various Sum <0.2Mono, Di & Tri-octyltin derivatives Various Sum <0.5Tetraethyltin (TET) 597-64-8 Sum <0.5Tributyltin oxode (TBTO) 56-35-9 Sum <0.2Dibutyltin dichloride (DBTC) 683-18-1 Sum <0.2Dibutyltin hydrogen borate (DBB) 75113-37-0 Sum <0.2Tricyclohexyltin Various Sum <0.5Tripropyltin Various Sum <0.5

Benzo-[a]-pyrene (BaP) 50-32-8 1Benzo-[a]-anthracene (BaA) 56-55-3 1Benzo-[b]-fluoranthene (BbFA) 205-99-2 1Benzo-[e]-pyrene (BeP) 192-97-2 1Benzo-[j]-fluoranthene (BjFA) 205-82-3 1Benzo-[k]-fluoranthene (BkFA) 207-08-9 1Chrysene (CHR) 218-01-9 1Dibenzo(a,e)pyrene 192-65-4 1Dibenzo(a,h)pyrene 189-64-0 1Dibenzo(a,i)pyrene 189-55-9 1Dibenzo(a,l)pyrene 191-30-0 1Dibenzo-[a,h]-anthracene (DBAhA) 53-70-3 1Acenaphthene 83-32-9Acenaphthylene 208-96-8Anthracene 120-12-7Benzo[ghi]perylene 191-24-2Fluoranthene 206-44-0Fluorene 86-73-7Indeno[1,2,3-cd]pyrene 193-39-5Naphthalene 91-20-3Phenanthrene 85-01-8Pyrene 129-00-0Cyclopenta(c,d)pyrene 27208-37-3

1-Methylpyrene 2381-21-7

Total of all PAHs - 10

Perfluorooctanic acid (PFOA) 335-67-1 1 µg/m²Perfluorobutanoic acid (PFBA) 375-22-4 10Perfluoropentanoic acid (PFPA) 2706-90-3 10Perfluorohexanoic acid (PFHxA) 307-24-4 10Perfluoroheptanoic acid (PFHpA) 375-85-9 10Perfluorononanoic acid (PFNA) 375-95-1 10Perfluorodecanoic acid (PFDA) 335-76-2 10Perfluoroundecanoic acid (PFUnA) 2058-94-8 10Perfluorododecanoic acid (PFDoA) 307-55-1 10Perfluorotridecanoic acid (PFTrDA) 72629-94-8 10Perfluorotetradecanoic acid (PFTeA) 376-06-7 10

Perfluorooctane sulphonic acid (PFOS) 1763-23-1 1 µg/m²Perfluorobutane sulphonic acid (PFBS) 375-73-5 10Perfluorohexane sulphonic acid (PFHxS) 355-46-4 10Perfluoroheptane sulphonic acid (PFHpS) 375-92-8 10Perfluorodecane sulphonic acid (PFDS) 335-77-3 10

Perfluoro-3,7-dimethyl octanoic acid (PF-3,7-

DMOA) 172155-07-6 10

7H-Dodecafluoroheptanoic acid (HPFHpA) 1546-95-8 102H,2H-Perfluorodecanoic acid (H2PFDA) 27854-31-5 10

1H,1H,2H,2H-perfluorooctanesulfonate,

(H4PFOS 6:2 FTS)27619-97-2 10

Perfluoro-1-octanesulfonamide (PFOSA) 754-91-6 10

N-methylperfluoro-1-octanesulfonamide

(N-MeFOSA) 31506-32-8 10

N-ethylperfluoro-1-octanesulfonamide

(N-EtFOSA) 4151-50-2 10

2-(N-methylperfluoro-1-octanesulfonamido)-

ethanol (NMeFOSE) 24448-09-7 10

2-(N-ethylperfluoro-1-octanessulfonamido)-

ethanol 1691-99-2 10

1H,1H,2H,2H-Perfluoro-1-hexanol

(4:2 FTOH) 2043-47-2 150

1H,1H,2H,2H-Perfluoro-1-octanol (6:2 FTOH) 647-42-7 150

1H,1H,2H,2H-Perfluoro-1-decanol (8:2 FTOH) 678-39-7 150

P1

13. Polycyclic Aromatic Hydrocarbons (PAHs)

Polyfluorinated Carboxylic Acids

ISO/TS 16179:2012 (for

all listed analytes)P3

P5

Perfluorooctane Sulfonamide Ethanol (FOSE)

Perfluoralkyl Sulfonamide (FOSA)

Polyfluorinated Sulfonates

14. Perfluorinated and Polyfluorinated Carbons (PFCs)

AfPS GS 2014:01 PAK

Extraction with organic

solvent,

LC/MS based on CEN/TS

15968

Included in sum

of all PAH <10

If PAH analysis

shows only

naphthalene in

product, apply

limit value as

100 mg/kg for

naphthalene

Perfluoroalkyl Sulfonates (PFSA)

Perfluorocarboxylic Acids

Fluortelomer Alcohols (FTOH)

10/14



[mg/kg]Test Method

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. Isomers1H,1H,2H,2H-Perfluoro-1-dodecanol

(10:2 FTOH) 865-86-1 150

1H,1H,2H,2H-Perfluorooctylacrylate

(6:2 FTAC) 17527-29-6 150

1H,1H,2H,2H-Perfluorodecylacrylate

(8:2 FTAC) 27905-45-9 150

1H,1H,2H,2H-Perfluorododecylacrylate

(10:2 FTAC) 17741-60-5 150

Butyl benzyl phthalate (BBP) 85-68-7

1,2-Benzenedicarboxylic acid, di-C7-11-

branched and linear alkyl esters (DHNUP)68515-42-4

Di-(2-methoxyethyl) phthalate (DMEP) 117-82-8Di(ethylhexyl) phthalate (DEHP) 117-81-7Dibutyl phthalate (DBP) 84-74-2

1,2-Benzenedicarboxylic acid, di-C6-8-branched

alkyl esters, C7-rich (DIHP)71888-89-6

Di-isobutyl phthalate (DIBP) 84-69-5Di-iso-decyl phthalate (DIDP) 26761-40-0, 68515-49-1Di-isononyl phthalate (DINP) 28553-12-0, 68515-48-0Di-n-hexyl phthalate (DnHP) 84-75-3Di-n-octyl phthalate (DNOP) 117-84-0Di-isopentyl phthalate (DIPP) 605-50-5Di-n-propyl phthalate (DPRP) 131-16-8

1,2-benzenedicarboxylic acid, dipentyl ester,

branched and linear84777-06-0

Di-iso-octyl phthalate (DIOP) 27554-26-3Dinonyl phthalate (DNP) 84-76-4N-pentyl-isopentylphthalate (NPIPP) 776297-69-9Di-cyclohexyl phthalate (DCHP) 84-61-7Diethy phthalate (DEP) 84-66-2Dipentyl phthalate (DPP) 131-18-0Dihexylphthalate, branched + linear 68515-50-4

1,2-benzenedicarboxylic acid, di-C6-10-alkyl

esters;1,2-benzenedicarboxylic acid, mixed

decyl and hexyl and octyl diesters with ≥ 0.3%

of dihexyl phthalate

68515-51-5

68648-93-1

Dimethyl phthalate (DMP) 131-11-3Diisohexyl phthalate 71850-09-4

Lead (Pb) Various 40

Total lead content:

CPSC-CH-E1001-08

(metals)

CPSC-CH-E1003-09

(coating)

CPSC-CH-E1002-08 (Non-

metal polymeric

material)/

ISO 17072-2 (leather)

Cadmium (Cd) Various 50 Total cadmium : EN 1122

Arsenic (As) Various 10

ISO 17072-2 (Leather) /

EN16711- 1 (textiles) /

Microwave Digestion

followed by ICP-MS

Mercury (Hg) Various 0.5

Microwave digestion with

H202/HNO3 followed by

EN ISO 17294-2:2014

Antimony (Sb) 7440-36-0 30Arsenic (As) Various 0.2Barium (Ba) 7440-39-3 1000Cadmium (Cd) Various 0.1Chromium (Cr; total) 7440-47-3 1Cobalt (Co) 7440-48-4 1Copper (Cu) 7440-50-8 25Lead (Pb) Various 0.2Mercury (Hg) Various 0.02Zinc (Zn) 7440-66-6Tin (Sn) 7440-31-5

500 each and

Sum of all

phthalates

<1000

P1

Extractable Metal Content

Total Digestion Metal Content

15. Phthalates

16. Heavy Metals

P4

ISO 17072-1 (leather) /

prEN

16711-2 (others)

P5

Extraction with organic

solvent,

LC/MS based on CEN/TS

15968

1) CPSC-CH-C-1001-09.3

(Mandatory for US market

for determination of

phthalates in childeren

toys and childcare

articles)

2) ISO 14389 (For textile)

3. ISO/TS 16181:2011

(For footwear materials)

Fluorotelomer Acrylates (FTAC)

11/14



[mg/kg]Test Method


Chromium, hexavalent, Cr(VI) Various 3

Extractable Cr VI in

leather: ISO 17075.

Testing is to be performed

after ageing (ageing

condition 24 hours at

80'C and 20% RH)

Nickel (Ni) 7440-02-0 1

Nickel is generally tested

for releasable metal

content. Recommended

to add limit and test

method for Nickel release.

Selenium (Se) 7782-49-2 500

Nickel (Ni) 7440-02-0

0.5 μg/cm²/week

0.2

μg/cm²/week

(pierced part)

For metallic parts without

a surface coating or

plating, test in accordance

with method EN 1811. For

metallic parts with a

surface coating or plating,

perform EN 12472, then

test in accordance with

method EN 1811

2-Ethoxyethylacetate 111-15-9 80Benzene 71-43-2 5Bis-(2-methoxyethyl) ether 111-96-6 1000Xylene 1330-20-7 20Methyl-ethyl ketone 78-93-3 100

P3 Toluene 108-88-3 1000

Ethylbenzene 100-41-4 15Styrene 100-42-5 10Cyclohexanone 108-94-1 101,2,3-Trichloropropane 96-18-4 1000Acetophenone 98-86-2 20

P3 N,N-Dimethylformamide (DMFa) 68-12-2 500 ISO/TS 16189:2013

1-Methyl-2-pyrrolidone 872-50-4 102-Phenyl-2-propanol 617-94-7 1/10

N,N-Dimethylacetamide (DMAc) 127-19-5 1000Extraction with MeOH //

Headspace GC-MSo-Cresol 95-48-7 20m-Cresol 108-39-4 20p-Cresol 106-44-5 20

P5 Formaldehyde 50-00-0 16/75

Textile:

ISO 14184-1

JISL 1041-1983 Method A

(Japan law 112)

Natural Leather:

Products for markets

other than China:

ISO 17226-2

Products for China

market:

GB/T 19941

Glyoxal and other short chain aldehydes (mono-

and di-aldehydes up to C6)107-22-2 & Various 100


HPLC

Bisphenol A 80-05-7 1Solvent extraction /GC-

MS or LC-MS

Polychlorinated biphenyls (PCB) Various 1

Polychlorinated terphenyls (PCT) Various 1

P3 Dimethyl fumarate (DMFu) 624-49-7 0.1Test method for footwear:

ISO/TS 16186:2012

P5

19. Biocides

Textile:


GC-MS

Add head space for

Benzene, Xylene,

Toluene, etylbenzenes,

Styrene, Cyclohexanone,

1,2,3-Trichloropropane,

N,N-Dimethylacetamide

(DMAc)


GC-MS

Extraction with KOH // GC-

MS

P5

Releasable Metal Content (from sundries & jewellery)

P6

P5

P5

17. Volatile Organic Compounds (VOCs)

18. Various Substances

Solvent extraction /GC-

MS or LC-MS

12/14



[mg/kg]Test Method

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. IsomersTriclosan 3380-34-5 1

Solvent extraction,

derivatisation

followed by GC-MS

analysisOctylisothiazolinone 26530-20-1 150Chloromethylisothiazolinone 26172-55-4 1Methylisothiazolinone 2682-20-4 11,2-Benzisothiazolin-3-one 2634-33-5 150

o-Phenylphenol (OPP) 90-43-7 50/100

Textiles: Extraction with

KOH, derivatization and

testing on GC-MS

Test method for leather:

ISO 13365:2011

N-Nitrosodimethylamine (NDMA) 62-75-9 0.5

N-Nitrosodiethylamine (NDEA) 55-18-5 0.5

N-Nitrosodi-n propylamine (NDPA) 621-64-7 0.5

N-Nitrosodi-n-butylamine (NDBA) 924-16-3 0.5

N-Nitrosopiperidine (NPIP) 100-75-4 0.5

N-Nitrosopyrrolidine (NPYR) 930-55-2 0.5

N-Nitrosomorpholine (NMOR) 59-89-2 0.5

N-Nitroso-N-methyl-N-phenylamine

(NMPhA)614-00-6 0.5

N-Nitroso-N-ethyl-N-phenylamine (NEPhA) 612-64-6 0.5

Aldrin 309-00-2Captafol 2425-06-01Chlordane 57-74-9DDT 50-29-3o,p'-DDT 789-02-6Dieldrin 60-57-1Endrin 72-20-8Heptachlor 76-44-8Hexachlorobenzene 118-74-1α-Hexachlorocyclohexane 319-84-6ß-Hexachlorocyclohexane 319-85-7δ-Hexachlorocyclohexane 319-86-82,4,5-Trichlorophenoxyacetic acid 93-76-52,4-Dichlorophenoxyacetic acid 94-75-7Chlordimeform 6164-98-3Ethyl-4,4'-dichlorobenzilate 510-15-6Dinoseb 88-85-7Monocrotophos 6923-22-4Pentachlorophenol 87-86-5Toxaphene 8001-35-2Methamidophos 10265-92-6Methyl parathion 298-00-0Parathion 56-38-2Phosphamidon 13171-21-6Lindane 58-89-92,4′-DDD (Dichlorodiphenyldichloroethane) 53-19-04,4′-DDD (Dichlorodiphenyldichloroethane) 72-54-8Diazinon 333-41-5Propetanfos 31218-83-4Chlorfenvinphos 470-90-6Dichlofenthion 97-17-6Chlorpyrifos 5598-15-2Fenchlorphos 299-84-3Diflubenzuron 35367-38-5Triflumuron 64628-44-0Cypermethrin 52315-07-8Deltamethrin 52918-63-5Fenvalerate 51630-58-1Cyhalothrin 91465-08-6Flumethrin 69770-45-2Azinphos methyl 86-50-0Azinphos ethyl 2642-71-9Bromophos-ethyl 4824-78-6Carbaryl 63-25-2Coumaphos 56-72-4Cyfluthrin 68359-37-5DEF (1,2,4-Tributyl phosphortrithioate) 78-48-8

4,4′-DDE (1,1-Dichloro-2,2-bis(4-

chlorophenyl)ethene)3424-82-6; 72-55-9

U.S. EPA Methods:

8081 A / 8151 A /

8141 A / 8270 C

P6

P6

P6

Solvent extraction / GC-

MS, LCMS

for confirmation

EN 12868:1999 (It is

applicable for rubber

articles)

GB/T 24153-2009

(described in GB25038-

2010 "Rubber shoes

healthy and safety

specification and

GB25036-2010

"Children’s Canvas

Rubber Footwear")

21. Pesticides

Sum of all <0.5 /

Sum of all <1

20. Nitrosamines

13/14



[mg/kg]Test Method

1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. IsomersDichlorprop 120-36-2Dicrotophos 141-66-2Dimethoate 60-51-5Endosulfan, α- 959-98-8Endosulfan, ß- 33213-65-9Esfenvalerate 66230-04-4Heptachloroepoxide 1024-57-3Isodrin 465-73-6Kelevan 4234-79-1Kepone 143-50-0Malathion 121-75-5

2-Methyl-4-chlorophenoxyacetic acid (MCPA) 94-74-6MCPB 94-81-5Mecoprop 93-65-2Mirex 2385-85-5Methoxychlor 72-43-5Perthane 72-56-0Phosdrin/Mevinphos 7786-34-7Profenophos 41198-08-7Quinalphos 13593-03-8Strobane 8001-50-1Telodrin 297-78-9Trifluralin 1582-09-08

Diphenylmethane diisocyanates (MDI) Various 50Hexamethylene diisocyanate (HDI) 822-06-0 50Isophorone diisocyanate (IPDI) 4098-71-9 100Tetramethylxylene diisocyanate (TMXDI) 2778-42-9 100Toluene diisocyanate (TDI) 584-84-991-08-7 15Napthylene-1,5,diisocyanate (1,5-NDI) 3173-72-6 50

Acrylamide 79-06-1 0.1/1Extraction with MeOH /

HPLC

Acrylonitrile 107-13-1 1Multiple headspace /

GC-MS

Butyl acrylate 141-32-2 50Butyl methacrylate 97-88-1 50Ethyl acrylate 140-88-5 10Ethyl methacrylate 97-63-2 50Methyl methacrylate 80-62-6 50

P6Solvent extraction /

GC-MS

U.S. EPA Methods:

8081 A / 8151 A /

8141 A / 8270 C

Solvent extraction /

GC-MS

P6

P6

23. Unreacted / Free Monomers

22. Isocyanates

Sum of all <0.5 /

Sum of all <1

14/14

January 2017 Version 2.1 Coop Negative List for Textile ... und... · January 2017 Version 2.1...

Documents

Transcript of January 2017 Version 2.1 Coop Negative List for Textile ... und... · January 2017 Version 2.1...