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24590-WTP-DB-PET-17-001, Rev 0

Process Inputs Basis of Design (PIBOD) for LAW and EMF

Page ii

24590-PADC-F00041 Rev 6 (1/22/2009)

History Sheet

Rev Reason for revision Revised by

0 Initial issue Daniel Choroser

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Contents

History Sheet ................................................................................................................................. ii

Acronyms and Abbreviations .................................................................................................... vii

1 Introduction ...........................................................................................................................1

1.1 Purpose of the Process Inputs Basis of Design (PIBOD) .................................................................... 1

2 Scope and Use of the PIBOD ................................................................................................3

2.1 Function of PIBOD within the Process Flowsheet ............................................................................... 4

3 Overview of the PIBOD ........................................................................................................7

3.1 Terminology for Dissolved and Undissolved Solids used in PIBOD .................................................. 8

3.2 Normal Operating Pressure and Temperature Ranges ...................................................................... 9

4 LAW Vitrification Facility ....................................................................................................9

4.1 LCP System ............................................................................................................................................ 9

4.2 LFP System ........................................................................................................................................... 10

4.3 LMP System .......................................................................................................................................... 10

4.4 LOP System .......................................................................................................................................... 11

4.5 LVP System .......................................................................................................................................... 12

4.6 RLD System .......................................................................................................................................... 13

5 Effluent Management Facility ............................................................................................14

5.1 DEP System .......................................................................................................................................... 14

6 References ............................................................................................................................16

7 External References .............................................................................................................17

Appendices

Appendix A Physical Properties of LAW Streams ................................................................. A-i

Appendix B Physical Properties of EMF Streams .................................................................. B-i

Appendix C Comparison of PTF and DFLAW APPS Results for Selection of PIBOD

Inputs .................................................................................................................................. C-i

Tables

Table 2-1. Process Calculations Directory ................................................................................................ 7

Table 3-1. Example Process Stream Property Table ............................................................................... 8

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Table 4-1. LCP System Stream Cross Walk ........................................................................................... 10

Table 4-2. LFP System Stream Cross Walk ........................................................................................... 10

Table 4-3. LMP System Stream Cross Walk .......................................................................................... 11

Table 4-4. LOP System Stream Cross Walk ........................................................................................... 11

Table 4-5. LVP System Stream Cross Walk ........................................................................................... 12

Table 4-6. RLD System Stream Cross Walk .......................................................................................... 13

Table 5-1. DEP System Stream Cross Walk ........................................................................................... 14

Table A-1. LCP01 .................................................................................................................................... A-2

Table A-2. LCP07 .................................................................................................................................... A-3

Table A-3. LFP04 .................................................................................................................................... A-4

Table A-4. LFP05 .................................................................................................................................... A-5

Table A-5. LFP06 .................................................................................................................................... A-6

Table A-6. LMP01 ................................................................................................................................... A-7

Table A-7. LMP02 ................................................................................................................................... A-8

Table A-8. LMP03 ................................................................................................................................... A-9

Table A-9. LMP06 ................................................................................................................................. A-10

Table A-10. LMP09 ............................................................................................................................... A-11

Table A-11. LMP11 ............................................................................................................................... A-12

Table A-12. LMP13 ............................................................................................................................... A-13

Table A-13. LMP14 ............................................................................................................................... A-14

Table A-14. LMP15 ............................................................................................................................... A-15

Table A-15. LMP16 ............................................................................................................................... A-16

Table A-16. LOP01 ............................................................................................................................... A-17

Table A-17. LOP02 ............................................................................................................................... A-18

Table A-18. LOP04 ............................................................................................................................... A-19

Table A-19. LOP05 ............................................................................................................................... A-20

Table A-20. LOP06 ............................................................................................................................... A-21

Table A-21. LOP07 ............................................................................................................................... A-22

Table A-22. LOP08 ............................................................................................................................... A-23

Table A-23. LOP09 ............................................................................................................................... A-24

Table A-24. LVP01 ................................................................................................................................ A-25

Table A-25. LVP03 ................................................................................................................................ A-26

Table A-26. LVP04 ................................................................................................................................ A-27

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Table A-27. LVP06 ................................................................................................................................ A-28

Table A-28. LVP08 ................................................................................................................................ A-29

Table A-29. LVP09 ................................................................................................................................ A-30

Table A-30. LVP10 ................................................................................................................................ A-31

Table A-31. LVP11 ................................................................................................................................ A-32

Table A-32. LVP12 ................................................................................................................................ A-33

Table A-33. LVP13 ................................................................................................................................ A-34

Table A-34. LVP14 ................................................................................................................................ A-35

Table A-35. LVP17 ................................................................................................................................ A-36

Table A-36. LVP18 ................................................................................................................................ A-37

Table A-37. LVP19 ................................................................................................................................ A-38

Table A-38. LVP20 ................................................................................................................................ A-39

Table A-39. LVP21 ................................................................................................................................ A-40

Table A-40. LVP23 ................................................................................................................................ A-41

Table A-41. LVP26 ................................................................................................................................ A-42

Table A-42. RLD21 ............................................................................................................................... A-43

Table A-43. RLD25 ............................................................................................................................... A-44

Table A-44. RLD27 ............................................................................................................................... A-45

Table A-45. RLD32 ............................................................................................................................... A-46

Table A-46. RLD33 ............................................................................................................................... A-47

Table A-47. RLD34 ............................................................................................................................... A-48

Table A-48. RLD35 ............................................................................................................................... A-49

Table A-49. RLD41 ............................................................................................................................... A-50

Table B-1. DEP01 .................................................................................................................................... B-2

Table B-2. DEP02 .................................................................................................................................... B-3

Table B-3. DEP03 .................................................................................................................................... B-4

Table B-4. DEP03b .................................................................................................................................. B-5

Table B-5. DEP04 .................................................................................................................................... B-6

Table B-6. DEP05 .................................................................................................................................... B-7

Table B-7. DEP06 .................................................................................................................................... B-8

Table B-8. DEP07 .................................................................................................................................... B-9

Table B-9. DEP08 .................................................................................................................................. B-10

Table B-10. DEP09 ................................................................................................................................ B-11

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Table B-11. DEP13 ................................................................................................................................ B-12

Table B-12. DEP14 ................................................................................................................................ B-13

Table B-13. DEP15 ................................................................................................................................ B-14

Table B-14. DEP16 ................................................................................................................................ B-15

Table B-15. DEP17 ................................................................................................................................ B-16

Table B-16. DEP18 ................................................................................................................................ B-17

Table B-17. DEP19 ................................................................................................................................ B-18

Table B-18. DEP20 ................................................................................................................................ B-19

Table B-19. DEP24 ................................................................................................................................ B-20

Table C-1. LAW Process Streams for Comparison ............................................................................. C-1

Table C-2. Excel Comparison of LAW Streams in PTF versus DFLAW Configuration ................. C-3

Figures

Figure 1-1. WTP Operating Configurations ............................................................................................. 1

Figure 2-1. APPS Applications for the PIBOD and Ancillary Calculations .......................................... 6

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Acronyms and Abbreviations

APPS Aspen Process Performance Simulation

BOF Balance of Facilities

CDG Container Decontamination System

DEP Direct Feed LAW Effluent Management Facility Process System

DF decontamination factor

DFLAW Direct Feed Low-Activity Waste

EMF Effluent Management Facility

HLW High-Level Waste

ICD Interface Control Document

LAB Analytical Laboratory

LAW Low-Activity Waste

LAWPS Low-Activity Waste Pretreatment System

LCP LAW Concentrate Receipt Process System

LFP LAW Melter Feed Process System

LMP LAW Melter Process System

LOP LAW Primary Offgas Process System

LVP LAW Secondary Offgas/Vessel Vent Process System

M&EB material and energy balance

PFD process flow diagram

PIBOD process inputs basis of design

PT(F) Pretreatment (Facility)

RLD Radioactive Liquid Waste Disposal System

SBS submerged bed scrubber

TCP Treated LAW Concentrate Storage Process System

WESP wet electrostatic precipitator

WIPSD WTP Integrated Processing Strategy Description

WTP Hanford Tank Waste Treatment and Immobilization Plant

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1 Introduction

The Hanford Tank Waste Treatment and Immobilization Plant (WTP) will treat and immobilize wastes

received from underground radioactive waste storage tanks at the Hanford site, which contain a mixture

of sludge, salt cake, and liquids totaling approximately 53 million gallons of waste. The WTP consists of

five major facilities: Pretreatment (PT) Facility, Low-Activity Waste (LAW) Facility, High-Level Waste

(HLW) Facility, Analytical Laboratory (Lab), and Balance of Facilities (BOF).

The WTP mission will be completed in phases, beginning with treatment of the low-activity waste

fraction, prior to completion of the PT and HLW Facilities. The low-activity waste fraction will be

delivered by the Hanford tank farms Low-Activity Waste Pretreatment Facility (LAWPS), and will be

transferred directly to the LAW Facility for vitrification. Secondary liquid wastes generated by LAW

vitrification will be concentrated in the Effluent Management Facility (EMF) and recycled to the front

end of the LAW vitrification process. This configuration is referred to as Direct Feed Low-Activity Waste

(DFLAW).

Upon completion of the PT and HLW Facilities, WTP will transition to concurrent production of

immobilized LAW and HLW. Hanford tank farms waste will be received by the PT Facility where it is

separated into the LAW and HLW fractions. LAW and HLW will be vitrified in their respective facilities

and secondary liquid wastes generated by the vitrification processes will be returned to the PT Facility for

recycle. This configuration is referred to as the PTF configuration.

As shown in Figure 1-1, the HLW and PT Facilities will only be operational under the PTF configuration

while the EMF and LAWPS are only operational during DFLAW. The LAW Facility, BOF and Lab are

operational for both PTF configuration and DFLAW. Note that design, construction, and operation of

LAWPS is outside the WTP prime contract scope and is being delivered by the Hanford tank operations

contractor. Thus, LAWPS is not addressed further in this report.

Figure 1-1. WTP Operating Configurations

1.1 Purpose of the Process Inputs Basis of Design (PIBOD)

The purpose of the PIBOD documents are to report the physical properties of WTP process streams based

on rigorous mass balance calculations using tank waste feed vectors and processing scenarios

representative of the entire WTP process. The resultant stream properties, in conjunction with data from

other sources, are to be used in design confirmation. This PIBOD document will support design

confirmation of the LAW Facility and EMF. Once completed, these two facilities, along with Lab and the

remaining BOF, will allow DFLAW processing to commence.

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The purpose of this document, Process Inputs Basis of Design (PIBOD) for LAW and EMF, is to report

physical properties for process streams that comprise the LAW Facility and EMF. Sections 4 and 5 list

and provide descriptions of the process streams included in this report. Appendices A and B provide

values of key physical properties for each of the streams. Process stream properties reported for the EMF

are applicable only to DFLAW operations. Process stream properties reported for the LAW Facility,

however, are applicable to both PTF configuration and DFLAW. The existing PIBOD report for the WTP

facility reflecting PTF operation, 24590-WTP-DB-PET-09-001, Process Inputs Basis of Design (PIBOD)

is revised to remove all LAW process streams. 24590-WTP-DB-PET-09-001 will therefore contain only

PT and HLW process stream property results. Process Inputs Basis of Design (PIBOD) for LAW and

EMF will be the only PIBOD report containing stream data for the LAW facility.

This PIBOD document reports the following stream properties used in confirming the design of the LAW

Facility and EMF:

1. Static Pressure (psia)

2. Vapor Pressure (psi)

3. Temperature (°F)

4. Boiling Point Temperature (°F)

5. Dew Point Temperature (°F)

6. Relative Humidity (%)

7. Suspended Solids (wt%)

8. Total Salts (wt%)

9. Slurry or Vapor Density (lb/ft3)

10. Liquid Density (lb/ft3)

11. Viscosity (cP)

12. Thermal Conductivity (Btu/hr-ft-R)

13. Heat Capacity (Btu/lb-R)

14. pH

15. Na+ Molarity

These physical properties are provided as a subset of the information requested by Mechanical Systems to

complete design confirmation. The complete list of requested information from Process engineering is

documented in CCN 158961 which provides the basis for the physical property parameters reported in

this document. Mass balance calculations used to support the PIBOD report are based on a steady-state

model of the WTP process. As such, overall and individual constituent flow rates are not provided as

results because they do not represent actual flow rates realized during batch processing scenarios. The

scope and limitations of the PIBOD are discussed further in section 2. An overview of the Process

engineering body of work, as it pertains to the appropriate sources for information needed by subsequent

engineering disciplines to complete design confirmation, is likewise provided in section 2.

Note: When considering values provided by the PIBOD, the system engineer must evaluate the need

for application of design margin and conservatisms before using the values as design inputs. Values

provided in the PIBOD do not include margin. The values are to be used by WTP Engineering as

per any applicable procedures and/or instructions as the basis for the values selected for the design

(after applying contingency, safety factors, and other design conservatisms if necessary). It is up to

the discretion of the responsible engineering discipline(s) whether to adopt the new value or keep the

existing value as the basis for the design value if the existing value is bounding.

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2 Scope and Use of the PIBOD

Lower and upper normal operating values of the key physical properties identified in Appendices A and B

of this document are provided by two calculations: 24590-LAW-M4C-V11T-00001, Calculation of

Process Stream Properties for the LAW Facility and 24590-BOF-M4C-V11T-00006, Calculation of

Process Stream Properties for the Effluent Management Facility. The remainder of the

properties/component mass rates required for design confirmation are to be derived from other documents

as discussed in Section 2.1. The following conditions apply when PIBOD results sourced from these two

calculations are to be used in design:

The PIBOD calculations listed above use selected values as leach factors, decontamination factors (DFs),

separation factors, reaction completion percentages along with other process inputs as a basis for

calculation of the stream compositions and the resulting range of properties documented in Appendices A

and B. These values used are based on the expected operating conditions of equipment and processes

within the facilities during normal operations and do not cover off-normal operations of equipment, nor

do they cover operations at processing set points outside the currently planned set points for the facility.

As such, the PIBOD calculation(s) results reflect expected and normal operations and steady state

conditions. The results are not intended to bound properties that may occur under off-normal, localized,

transient scenarios, or extremes of operation. Also, the values provided in this document are based on

correlations used by the ASPEN Process Performance Simulation (APPS) model and do not include any

contingency to account for potential variation in results due to deviations that may occur when applying

the developed correlations to individual feeds.

The results of the PIBOD calculations are not universally applicable in design calculations. They are

intended solely to represent the lower and upper values of the thermal, transport, and physical properties

encountered during normal operations while processing a full range of LAW feeds represented by the

feed vectors associated with Tank Farms Contractor Operation and Utilization Plan, TFCOUP6,

(documented in CCN 159204) and 24590-WTP-RPT-ENV-16-001, One System – Feed Vector

Development in Support of WTP Environmental Risk Assessment Activities. Because data are derived

from a steady-state model, flow rates provided by the model are not representative of actual flow rates

during batch processing operations. Instantaneous process flowrates are determined based on the required

facility throughputs as defined in Section C.7 of the WTP Contract, DE-AC27-01RV14136. The

responsible engineering discipline should consider all applicable criteria when sizing the equipment to

meet minimum flow rates established by Process Engineering. This includes minimum velocity for slurry

lines (24590-WTP-3DG-M11T-00003) and general engineering practices (e.g., adding capacity for a

minimum recirculation line if required for specific pump application).

In addition to lower and upper normal operating values sourced from the PIBOD calculations, this

document reports physical property values from the balance of Process Engineering design calculations

when their results bound the physical property values given by the PIBOD calculations. These bounding

values are listed in Appendices A and B alongside results of the PIBOD calculations to assist engineers in

selecting appropriate Process design inputs by informing the reader that an alternate Process Engineering

calculation provides a more bounding value. These bounding values are labeled as the minimum and

maximum operating values in Appendices A and B. Table 3-1 provides an example of the format in which

stream data is provided in the Appendices.

Note: Minimum and maximum operating values presented in this PIBOD represent the operational ranges

of physical property values as determined by Process Engineering. These values are not equivalent to the

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design temperature and pressure ratings assigned to the systems, structures, or components (SSCs) to

which they are attributed.

The thermal, transport, and physical property values provided in this PIBOD document should be

evaluated relative to the corresponding property values currently used in committed and confirmed

calculations. Previous calculations contain estimates of process stream properties that have been used

prior to issue of this document; thus, they may still contain relevant limiting values.

2.1 Function of PIBOD within the Process Flowsheet

This section provides background information on the appropriate sources of process inputs for the

engineering disciplines requiring confirmed inputs from Process Engineering. The PIBOD report is one of

many Process Engineering deliverables used by other disciplines, or internal “customers.” These Process

Engineering deliverables, including calculations, reports, datasheets, and drawings, are discussed here

with respect to which engineering disciplines should refer to which deliverable(s) for process inputs.

The WTP Process Flowsheet is defined as the collection of information that describes how the WTP will

process waste from the Hanford Tank Farms and turn that waste in to High-Level Waste (HLW) and

Low-Activity Waste (LAW) glass products. The “Process Flowsheet” consists of the following items:

• Process Flow Diagrams (PFDs)

• Process Description

• Process Model/Simulation

PFDs are used to illustrate:

• Flow sequence/routing

• Unit operations

• The major Process control loops

• Equipment selection (as required by Process)

• Stream numbering (these tie to the Process Model/Simulation)

• Equipment data (batch volumes, duties)

• Stream data (as warranted)

Equipment data will come from Process calculations and stream data will come from a mass and energy

balance and/or Process calculations. At the WTP, PFDs are generated for the process systems within PT,

LAW, HLW, and EMF. PFDs are also generated for the processing portions of the Lab and the “wet

chemical” portion of the BOF.

The Process Description provides:

• Definition of operating modes/required process functions

• Sequence of operating modes

• Operating and design parameters

• Definition of the major process control loops

At the WTP, the Process Description is captured in the WTP Integrated Processing Strategy Description

(WIPSD).

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The Process Model is typically generated from process simulation software. The Process Model

architecture reflects the connectivity as defined on the PFDs as well as the operating logic as described in

the Process Description. The Process Model is utilized to generate mass and energy balances (M&EBs) in

support of the design. The M&EBs may be supplemented by Process calculations to provide input to

downstream design activities (Process datasheets; material/equipment/piping/instrument specifications;

safety evaluations; etc.). These M&EBs provide:

• Stream compositions

• Stream physical properties

• Load requirements (heating/cooling)

When using the APPS model, the User (Process Engineer who is setting up and running APPS) works

with the Customer to specify the configuration (PTF configuration or DFLAW), the feeds, and the

operating scenario(s). The selection of the feed and operating scenario is established based upon the need

of the Customer the work is supporting. Input variables and controls are also set by the User with input

from the Customer. These include (but are not limited to):

• Throughput

• Cesium ion exchange column (CsIX) DF

• Melter DFs

• Submerged bed scrubber (SBS) / wet electrostatic precipitator (WESP) DFs

• Evaporator DFs

• Reaction conversions

At the WTP, the Process Model is the APPS and M&EBs are generated by Process Engineering to

support the work of a number of disciplines (e.g., Customers). These include:

• Process Engineering – input to Process datasheet calculations

• Mechanical Engineering – input to equipment/piping calculations and/or data sheets (primarily

physical property information)

• Radiological Engineering – input to shielding and source term calculations

• Nuclear Safety Engineering – input to accident analyses and facility classification (includes

Inhalation Dose, Hydrogen Generation, NOx, Chemical)

• Permitting – emissions estimates

• Materials Engineering Technology – input to materials selection

Because the selected inputs to the Process Model are adjusted based on the needs of the end users,

M&EBs should not be considered interchangeable. For example, M&EBs generated for inputs to Nuclear

Safety calculations are typically based on Contract conditions. While M&EBs for inputs to Mechanical

calculations provide a range of normal operations. Use of the M&EB results outside of the intended

purpose will require the permission of Process Engineering.

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Figure 2-1. APPS Applications for the PIBOD and Ancillary Calculations

APPS Model

PIBODCalculation

(WTP-M4C-V11T-00012)

PIBOD Report(WTP-DB-PET-09-001)

Process Corrosion Data

Calculation(WTP-M4C-V11T-00024)

Process Corrosion

Datasheets(WTP-RPT-PR-04-0001

-01 to -06)

Hydrogen Generation Calculation

(WTP-M4C-V11T-00011)

Offgas (NOx) Calculation

(new)

Chemical Toxicity

Calculation(new)

Inhalation Dose Calculation

(WTP-M4C-V11T-00021)

Shielding/Beta Calculation

(WTP-M4C-V11T-00020

and -00027)

Emissions Estimate

(WTP-MRR-PE-13-017)

User specifies feed and operating scenario. Input variables and controls include HLW/LAW throughput, melter/evaporator/SBS/WESP DFs, CsIX DFs, reaction

conversions, etc...

MechanicalNuclear Safety

Materials

Rad Engineering

Multiple

Permitting

Several APPS runs are performed for each need. The run inputs are determined by the User and are selected for purpose.

The selected conditions for one run may not be comparable to other run results. Therefore, Process Engineering should be consulted whenever using APPS results not provided in the

Results of the calculations.

Customer

Process Datasheet

Calculations(numerous)

Process datasheet calculations are required to establish batch volumes,

utilization timelines, time allowances, minimum transfer rates,

and to document throughput.

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Table 2-1. Process Calculations Directory

Subject LAW Calculation Number

EMF (BOF) Calculation

Number

PIBOD Calculation 24590-LAW-M4C-V11T-00001 24590-BOF-M4C-V11T-00006


Calculation

24590-WTP-M4C-V11T-00024 24590-BOF-M4C-V11T-00004


Sheets

24590-WTP-RPT-PR-04-0001-01 to -06 24590-BOF-RPT-PR-15-001

Hydrogen Generation

Calculation

24590-LAW-M4C-V11T-00003

24590-WTP-M4C-V11T-00004

24590-WTP-M4C-V11T-00011

24590-BOF-M4C-V11T-00003

Radionuclide Shielding

Calculation

24590-WTP-M4C-V11T-00020

24590-WTP-M4C-V11T-00027

24590-BOF-M4C-V11T-00001

Radionuclide Inhalation

Dose Calculation

24590-WTP-M4C-V11T-00021 24590-BOF-M4C-V11T-00002

Emissions Estimate 24590-WTP-MRR-PE-13-017 24590-BOF-M4C-DEP-00001

LAW Melter NOx

Analysis

24590-LAW-M4C-V11T-00002 N/A

Unit Sum of Fractions

(USOF) Calculation

24590-LAW-M4C-V11T-00004 24590-BOF-M4C-V11T-00005

Chemical Toxicity

Calculation

24590-WTP-M4C-V11T-00013 N/A

3 Overview of the PIBOD

Physical properties for LAW and EMF process streams are provided in Appendices A and B,

respectively. The process streams are numbered in accordance with the current issued process flow

diagrams. Stream numbering used for the APPS 3.0 model does not align in all cases with stream

numbering on the process flow diagrams. Tables 4-1 through 4-6 and Table 5-1 provide a stream cross

walk which maps each of the process stream numbers to the corresponding stream in the APPS 3.0 model.

The APPS 3.0 flowsheet, showing all streams and unit operations included in the model, may be viewed

on 24590-RMVD-03086 file name: APPS v3.0 Model Schematic - VIT.png.

The tables in Appendices A and B should be used in conjunction with Tables 4-1 through 4-6 and Table

5-1 as well as the corresponding process flow diagrams in order to identify which streams flow into/out of

the plant equipment being evaluated.

The physical properties reported in the appendices for each process stream provides up to four values:

these values are “minimum operating,” “lower normal operating,” “upper normal operating,” and

“maximum operating.” Lower and upper normal operating values are sourced exclusively from the

PIBOD calculations for LAW and EMF: 24590-LAW-M4C-V11T-00001 and 24590-BOF-M4C-V11T-

00006, respectively. Minimum and maximum operating values are reported in addition to the normal

operating values when an alternate source of information provides a value that bounds the lower and/or

upper normal operating value. These values are sourced from process data calculations for LAW and

EMF vessels, flowsheet basis calculations (e.g. 24590-LAW-M4C-LOP-00001), and other process basis

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documents, as identified in Appendices A and B. Table 3-1 is provided as an example of the format

presented in Appendices A and B.

Table 3-1. Example Process Stream Property Table

Stream Number

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating

Static Pressure psia

Physical

property

value below

the lower

normal

operating

value, when

available

from an

alternate

process

calculation

or basis

document

Minimum

value from

APPS

model runs

supporting

24590-

LAW-

M4C-

V11T-

00001 and

24590-

BOF-M4C-

V11T-

00006 (3)

Maximum

value from

APPS

model runs

supporting

24590-

LAW-

M4C-

V11T-

00001 and

24590-

BOF-M4C-

V11T-

00006 (3)

Physical

property

value

exceeding

the upper

normal

operating

value, when

available

from an

alternate

process

calculation

or basis

document

Vapor Pressure psia

Temperature °F

Boiling Point

Temperature (1) °F

Dew Point Temperature (2) °F

Relative Humidity (2) %

Suspended Solids (1) wt%

Total Salts (1) wt%

Slurry or Vapor Density lb/ft3

Liquid Density (1) lb/ft3

Viscosity cP

Thermal Conductivity BTU/hr·ft·R

Heat Capacity BTU/lb·R

pH (1) –––

Na+ Molarity (1) [M]

(1) Boiling point temperature, suspended solids, total salts, liquid density, pH, and Na+ molarity are marked

n/a for all vapor streams

(2) Dew point temperature and relative humidity are marked n/a for all liquid streams

(3) Unless otherwise noted

NOTE: Where minimum and maximum operating values are provided in Appendix B based on

information from committed (alpha revision) calculations, these values may not be used for design

confirmation until the calculations are converted to confirmed status. Upon completion of the

confirmed revisions of the EMF process calculations, this PIBOD report will be updated to reflect

confirmed data.

3.1 Terminology for Dissolved and Undissolved Solids used in PIBOD

This document uses the following terminology to describe the solids content of streams:

Suspended solids (wt. %) - Weight percent of undissolved solids in suspension.

Total Salts (wt. %) - Weight percent of all undissolved and dissolved solids (including organics). Weight

percent of dissolved solids may be calculated by subtracting suspended solids from total salts.

24590-WTP-DB-PET-17-001, Rev 0


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24590-PADC-F00041 Rev 6 (1/22/2009)

Slurry or Vapor Density (lb/ft3) - Bulk density. For slurry streams, it is the density including all solids;

dissolved and undissolved.

Liquid Density (lb/ft3) - Density for liquid streams with undissolved solids portion removed, taking into

account only the density of the liquid portion.

Slurry density for liquid streams with zero or negligible amounts of undissolved solids will be equal to the

liquid density. For streams in Appendices A and B where this is the case, only the liquid density is

reported. Slurry density in these cases is listed as n/a.

3.2 Normal Operating Pressure and Temperature Ranges

Static pressures of the process streams reported in Appendices A and B represent the operating pressures

of the equipment from which the streams originate. As an example, a process stream that represents the

liquid outlet of a vessel is assigned a static pressure equal to the operating pressure of said vessel. Lower

and upper normal operating values provided for static pressure are results from APPS model runs for

24590-LAW-M4C-V11T-00001 and 24590-BOF-M4C-V11T-00006. A consequence of using the APPS

model to provide pressure operating ranges is that the lower and upper normal operating static pressure

may be reported as the same values. This is due to equipment operating pressures in APPS being fixed-

variables set to same values across all model runs. Therefore, reported lower and upper normal operating

static pressures may be equal and not reflect variation in static pressure during normal operations.

Similarly, there are cases where the lower and upper normal operating temperatures may be reported as

the same values for process streams in Appendices A and B. The operating temperatures of certain

equipment within the APPS model are fixed-variables that remain constant through all model runs.

Likewise, reagents including air, steam, demineralized water, and sodium hydroxide are assigned fixed

temperatures within the APPS model. Therefore, reported lower and upper normal operating temperatures

may be equal and not reflect variation in temperature during normal operations.

Engineering disciplines making use of static pressure and temperature values from this report are advised

that the values reflect expected, normal operations at steady state conditions and may not always exhibit

an operating range. Therefore, when using PIBOD lower/upper normal operating static pressure or

temperature values in design, engineers should take this into account and consider complete operating

ranges and transient conditions. As with all values sourced from the PIBOD, users are advised to apply

margin, contingency, and/or conservatisms as instructed by Section 1.1 of this report.

4 LAW Vitrification Facility

4.1 LCP System

The LAW Concentrate Receipt Process (LCP) system is designed to receive LAW concentrate within the

LAW facility from the Treated LAW Concentrate Storage Process (TCP) system in the PT facility during

PTF configuration. In DFLAW configuration, the LCP system receives LAW concentrate from LAWPS

and effluent concentrate recycle from EMF. It is then required to stage and transfer the concentrate to the

LAW Melter Feed Process (LFP) System. The summary of minimum and maximum physical properties

of the LCP process streams are listed in Appendix A, pages A-2 and A-3. The LCP system is depicted on

PFDs 24590-LAW-M5-V17T-00001 and 24590-LAW-M5-V17T-00002.

24590-WTP-DB-PET-17-001, Rev 0


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24590-PADC-F00041 Rev 6 (1/22/2009)

Table 4-1. LCP System Stream Cross Walk

Stream

APPS 3.0

Stream(s) Description

Configuration

LCP01 LCP01 LAW concentrate from the concentrate receipt vessels

(LCP-VSL-00001/2) sent to the melter feed preparation

vessels (LFP-VSL-00001/3) for mixture with glass

formers

PTF & DFLAW

LCP07 LCP07c Direct Feed LAW from LAWPS to concentrate receipt

vessels (LCP-VSL-00001/2)

DFLAW Only

4.2 LFP System

The LFP system receives LAW concentrate from the LCP system, receives glass formers from the GFR

system, mixes LAW concentrate with glass formers to meet product compliance requirements, and

continuously feeds the melters. The summary of minimum and maximum physical properties of the LFP

process streams are listed in Appendix A, pages A-4 through A-6. The LFP system is depicted on PFDs

24590-LAW-M5-V17T-00001 and 24590-LAW-M5-V17T-00002.

Table 4-2. LFP System Stream Cross Walk

Stream

APPS 3.0


Configuration

LFP04 LFP04 LAW waste with added glass formers continuously fed

by the melter feed vessels (LFP-VSL-00002/4) into the

melters (LMP-MLTR-00001/2) for glass production

PTF & DFLAW

LFP05 LFP05 LAW waste with added glass formers and water from

the melter feed preparation vessels (LFP-VSL-

00001/3) batch fed into the melter feed vessels (LFP-

VSL-00002/4)

PTF & DFLAW

LFP06 LCP06a

LFP06a

LFP06b

Vessel vent outlet stream for LCP/LFP system vessels PTF & DFLAW

4.3 LMP System

The LAW Melter Process (LMP) system is designed to receive LAW concentrate mixed with glass

formers and turn it into a molten glass product. The melter has two outputs; vapor to the LOP offgas

treatment system, and the glass product batch fed to the Container Decontamination (CDG) system. The

summary of minimum and maximum physical properties of the LMP process streams are listed in

Appendix A, pages A-7 through A-16. The LMP system is depicted on PFDs 24590-LAW-M5-V17T-

00004 and 24590-LAW-M5-V17T-00005.

Table 4-3. LMP System Stream Cross Walk

Stream

APPS 3.0


Configuration

LMP01 LMP01 Air inleakage into the melter (LMP-MLTR-00001/2)

from the wet process cell to prevent flammable gas

concentrations in the melter offgas system

PTF & DFLAW

24590-WTP-DB-PET-17-001, Rev 0


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24590-PADC-F00041 Rev 6 (1/22/2009)

Stream

APPS 3.0


Configuration LMP02 LMP02_03 Melter bubbler and air lift air fed into LMP-MLTR-

00001/2 for mixing purposes

PTF & DFLAW

LMP03 LMP01a Melter instrumentation/purge air fed into LMP-MLTR-

00001/2

PTF & DFLAW

LMP06 LMP06 Primary melter offgas from LMP-MLTR-00001/2 to

the primary melter offgas film cooler (LOP-FCLR-

00001/3)

PTF & DFLAW

LMP09 LMP09 LAW molten glass product from LMP-MLTR-00001/2

fed to ILAW canister for subsequent decontamination

in the CDG system. Note the CDG system is not

modeled in APPS

PTF & DFLAW

LMP11 LMP11 Plant service air in-bleed fed to the film cooler (LOP-

FCLR-00001/3)

PTF & DFLAW

LMP13 LMP13 Control air added to the film cooler (LOP-FCLR-

00001/3)

PTF & DFLAW

LMP14 LMP14 Primary offgas stream from LOP-FCLR-00001/3, sent

to the submerged bed scrubber (LOP-SCB-00001/2)

PTF & DFLAW

LMP15 LMP14 Standby offgas stream from LOP-FCLR-00002/4 to

LOP-SCB-00001/2. Not used in normal operation.

Physical properties of this stream are represented by

LMP14

PTF & DFLAW

LMP16 LOP09 Demineralized water sent to LOP-FCLR-00001. This

stream is not modeled in APPS but will have the

stream properties of LOP09

PTF & DFLAW

4.4 LOP System

The LOP system is designed to remove particulates/components from the melter offgas vapor stream prior

to release. The summary of minimum and maximum physical properties of the LOP process streams are

listed in Appendix A, pages A-17 through A-24. The LOP system is depicted on PFDs 24590-LAW-M5-

V17T-00007 and 24590-LAW-M5-V17T-00008.

Table 4-4. LOP System Stream Cross Walk

Stream

APPS 3.0


Configuration

LOP01 LOP01 Submerged bed scrubber (LOP-SCB-00001/2)

condensate overflow sent to the SBS condensate vessel

(LOP-VSL-00001/2)

PTF & DFLAW

LOP02 LOP02 Submerged bed scrubber (LOP-SCB-00001/2) offgas

discharge to the wet electrostatic precipitator (LOP-

WESP-00001/2)

PTF & DFLAW

LOP04 LOP04 Submerged bed scrubber condensate recycle from

LOP-VSL-00001/2 to LOP-SCB-00001/2

PTF & DFLAW

LOP05 LOP05_1 LOP-SCB-00001/2 condensate purge to RLD-VSL-

00005

PTF & DFLAW

LOP06 LOP06 Bulge air purge sent to LOP-WESP-00001/2 PTF & DFLAW

LOP07 LOP07_1 Condensate drain from LOP-WESP-00001/2 to RLD-

VSL-00004

PTF & DFLAW

24590-WTP-DB-PET-17-001, Rev 0


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24590-PADC-F00041 Rev 6 (1/22/2009)

Stream

APPS 3.0


Configuration LOP08 LOP08 LOP-WESP-00001/2 offgas discharge to secondary

treatment, LVP-HTR-00001A/B

PTF & DFLAW

LOP09 LOP09 Demineralized water addition line to LOP-WESP-

00001/2

PTF & DFLAW

4.5 LVP System

The LVP system is designed to remove unwanted particulates/components from the melter offgas vapor

stream prior to release in the stack. The summary of minimum and maximum physical properties of the

LVP process streams are listed in Appendix A, pages A-25 through A-42. The LVP system is depicted on

PFDs 24590-LAW-M5-V17T-00010 and 24590-LAW-M5-V17T-00011.

Table 4-5. LVP System Stream Cross Walk

Stream

APPS 3.0

Stream(s)

Description

Configuration

LVP01 LVP01 LAW vessel ventilation header offgas PTF & DFLAW

LVP03 LVP03a Combined vessel ventilation and LOP-WESP-00001

offgas to HEPA filters pre-heater (LVP-HTR-

00001A/B)

PTF & DFLAW

LVP04 LVP04 LVP-HTR-00001A/B offgas to HEPA filters (LVP-

HEPA-00001A/B, -00002A/B, & -00003A)

PTF & DFLAW

LVP06 LVP08 HEPA filters offgas to carbon bed adsorber (LVP-

ADBR-00001A/B)

PTF & DFLAW

LVP08 LVP18a Exhauster offgas (LVP-EXHR-00001A/B/C) to the

stack

PTF & DFLAW

LVP09 LVP09 Catalytic oxidizer heat recovery exchanger hot-side

outlet (LVP-HX-00001) to caustic scrubber (LVP-

SCB-00001)

PTF & DFLAW

LVP10 LVP10 Cold-side outlet of LVP-HX-00001 to catalytic

oxidizer electric heater (LVP-HTR-00002)

PTF & DFLAW

LVP11 LVP11 Offgas discharge from LVP-HTR-00002 to catalytic

oxidizer (LVP-SCO-00001)

PTF & DFLAW

LVP12 LVP12 Offgas discharge from LVP-SCO-00001 to NOx

selective catalytic reducer (LVP-SCR-00001)

PTF & DFLAW

LVP13 LVP13a Combined ammonia (AMR03) /dilution air to LVP-

SCR-00001. The combined stream is not modeled in

APPS 3.0 however the flow rate of dilution air is much

greater than the ammonia addition. Therefore, the

stream properties of the dilution air are used to

represent this stream

PTF & DFLAW

LVP14 LVP14 LVP-SCR-00001 offgas to LVP-HX-00001 PTF & DFLAW

LVP17 LVP17a Caustic scrubber solution recirculation stream from

LVP-TK-00001 to LVP-SCB-00001

PTF & DFLAW

LVP18 LVP18 LVP-SCB-00001 offgas discharge to exhausters LVP-

EXHR-00001A/B/C

PTF & DFLAW

LVP19 LVP19 5M NaOH from SHR-TK-00003 to LVP-TK-00001 PTF & DFLAW

LVP20 LVP20 Process water addition to LVP-TK-00001 PTF & DFLAW

24590-WTP-DB-PET-17-001, Rev 0


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24590-PADC-F00041 Rev 6 (1/22/2009)

Stream

APPS 3.0

Stream(s)

Description

Configuration LVP21 LVP21 Caustic scrubber bottoms effluent from LVP-TK-

00001 to RLD-VSL-000017A/B (primary

configuration) or DEP-VSL-00004A/B (DFLAW)

PTF & DFLAW

LVP23 LVP23 LVP-SCR-00001 inlet (LVP12 and LVP13 combined) PTF & DFLAW

LVP26 LVP26 LVP-ADBR-00001A/B offgas discharge to LVP-HX-

00001

PTF & DFLAW

4.6 RLD System

The Radioactive Liquid Waste Disposal (RLD) System is designed to receive, store, and transfer

contaminated liquid effluents produced by LAW melter offgas treatment in the LOP and LVP systems.

The summary of minimum and maximum physical properties of the RLD process streams are listed in

Appendix A, pages A-43 through A-50. The RLD system is depicted on PFD 24590-LAW-M5-V17T-

00014. Stream RLD41 is depicted on PFD 24590-LAB-M5-V17T-00029.

Table 4-6. RLD System Stream Cross Walk

Stream

APPS 3.0

Stream(s) Description Configuration

RLD21 RLD21 Submerged bed scrubber and WESP effluents from

RLD-VSL-00005 to TLP-VSL-00009A/B (PTF

configuration) or DEP-FILT-00003 (DFLAW)

PTF & DFLAW

RLD25 RLD25 LAW facility sumps/washes sent to RLD-VSL-

00003. Includes vessels:

• LCP-VSL-00001, -00002

• LFP-VSL-00001, -00002, -00003, -00004

• LOP-VSL-00001, -00002

• LVP-TK-00001

• RLD-VSL-00004

• RLD-VSL-00005

• TCP-VSL-00001 (PTF configuration only)

PTF & DFLAW

RLD27 RLD27 LAW facility sumps/washes from RLD-VSL-

00003 to PWD-VSL-00044 (PTF configuration) or

DEP-FILT-00003 (DFLAW).

PTF & DFLAW

RLD32 RLD32 RLD-VSL-00005 vessel vent outlet stream PTF & DFLAW



RLD35 RLD35 WESP drains and miscellaneous washes from

RLD-VSL-00004 to RLD-VSL-00005

PTF & DFLAW

RLD41 RLD41 LAB effluent stream from LAB Area Sink Drain

Collection Vessel (RLD-VSL-00164) to DEP-

FILT-00003

DFLAW Only

24590-WTP-DB-PET-17-001, Rev 0


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24590-PADC-F00041 Rev 6 (1/22/2009)

5 Effluent Management Facility

5.1 DEP System

The Direct Feed LAW Effluent Management Facility Process (DEP) System is designed to concentrate

liquid effluents resulting from treatment of LAW melter offgas in the LOP and LVP systems and recycle

the concentrate to the front end of LAW. The DEP system is depicted on PFDs 24590-BOF-M5-V17T-

00011 through 24590-BOF-M5-V17T-00014. The summary of minimum and maximum physical

properties of the DEP process streams are listed in Appendix B, pages B-2 through B-20.

Table 5-1. DEP System Stream Cross Walk

Stream

APPS 3.0


DEP01 DEP01 Effluent stream from the Overhead Sampling

Vessel (DEP-VSL-00004A/B) to the Process

Condensate Lag Storage Vessel (DEP-VSL-

00005A/B)

DFLAW Only

DEP02 DEP02 Evaporator feed stream from the Evaporator

Feed Vessel (DEP-VSL-00002) to the DEP

Evaporator (DEP-EVAP-00001)

DFLAW Only

DEP03 DEP03 Effluent stream from the Low Point Drain

Vessel (DEP-VSL-00001) to DEP-VSL-00002

DFLAW Only

DEP03b DEP03b Filter backflush stream from DEP-FILT-00003

to Evaporator Concentrate Vessel (DEP-VSL-

00003A/B/C)

DFLAW Only

DEP04 DEP04e Combined evaporator overheads condensate

stream from the DEP Evaporator Primary,

Inter-, and After-Condensers (DEP-COND-

00001/2/3) to DEP-VSL-00004A/B

DFLAW Only

DEP05 DEP05 Evaporator concentrate stream from DEP-

EVAP-00001 to the Evaporator Concentrate

Vessel (DEP-VSL-00003A/B/C)

DFLAW Only

DEP06 DEP15e_o Vent stream from DEP-VSL-00004A/B to the

vent header

DFLAW Only

DEP07 DEP15b_o Vent stream from DEP-VSL-00002 to the vent

header

DFLAW Only

DEP08 DEP15a_o Vent stream from DEP-VSL-00001 to the vent

header

DFLAW Only

DEP09 DEP15g_o Vent stream from DEP-COND-00003 to the

vent header

DFLAW Only

DEP13 DEP13 Recycle stream from the Evaporator

Concentrate Vessel (DEP-VSL-00003A/B/C)

to LCP-VSL-00001/2

DFLAW Only

DEP14 DEP15f_o Vent stream from DEP-VSL-00005A/B to the

vent header

DFLAW Only

DEP15 DEP15 Combined vent header stream processed

through the vent exhaust system, beginning

DFLAW Only

24590-WTP-DB-PET-17-001, Rev 0


Page 15

24590-PADC-F00041 Rev 6 (1/22/2009)

Stream

APPS 3.0


with the HEPA pre-heaters (DVP-HTR-

00001A/B) DEP16 DEP16 Vent stream between the HEPA pre-heaters

(DVP-HTR-00001A/B) and the first stage

HEPA filters (DVP-HEPA-00003A/B)

DFLAW Only

DEP17 DEP17 Vent stream between the second stage HEPA

filters (DVP-HEPA-00004A/B) and the

exhausters (DVP-EXHR-00001A/B)

DFLAW Only

DEP18 DEP18 Process exhaust stream to the atmosphere

through the stack

DFLAW Only

DEP19 DEP19 Overheads from DEP-EVAP-00001 to the

primary condenser (DEP-COND-00001)

DFLAW Only

DEP20 DEP20 Effluent from DEP-VSL-00005A/B transferred

to LERF/ETF

DFLAW Only

DEP24 DEP15d_o Vent stream from DEP-VSL-00003A/B/C to

the vent header

DFLAW Only

24590-WTP-DB-PET-17-001, Rev 0


Page 16

24590-PADC-F00041 Rev 6 (1/22/2009)

6 References

6.1 24590-LAW-M4C-V11T-00001, Rev. 1, Calculation of Process Stream Properties for the LAW

Facility

6.2 24590-BOF-M4C-V11T-00006, Rev. 1, Calculation of Process Stream Properties for the

Effluent Management Facility

6.3 24590-WTP-ICD-MG-01-030, Rev. 0, ICD 30 – Interface Control Document for Direct LAW

Feed

6.4 24590-LAW-M5-V17T-00001, Rev. 6, Process Flow Diagram LAW Concentrate Receipt and

Melter 1 Feed (System LCP, GFR, and LFP)

6.5 24590-LAW-M5-V17T-00002, Rev. 6, Process Flow Diagram LAW Concentrate Receipt and

Melter 2 Feed (System LCP, GFR, and LFP)

6.6 24590-LAW-M5-V17T-00004, Rev. 4, Process Flow Diagram LAW Vitrification Melter 1

(System LMP & LOP)

6.7 24590-LAW-M5-V17T-00005, Rev. 4, Process Flow Diagram LAW Vitrification Melter 2

(System LMP & LOP)

6.8 24590-LAW-M5-V17T-00007, Rev. 4, Process Flow Diagram Melter 1 Primary Offgas

Treatment System (System LOP)

6.9 24590-LAW-M5-V17T-00008, Rev. 4, Process Flow Diagram Melter 2 Primary Offgas

Treatment System (System LOP)

6.10 24590-LAW-M5-V17T-00010, Rev. 4, Process Flow Diagram LAW Vitrification Ammonia &

Secondary Offgas System (System AMR & LVP)

6.11 24590-LAW-M5-V17T-00011, Rev. 6, Process Flow Diagram LAW VIT Secondary Offgas

Treatment (System LVP)

6.12 24590-LAW-M5-V17T-00014, Rev. 6, Process Flow Diagram LAW Liquid Effluent (System

RLD)

6.13 24590-BOF-M5-V17T-00011, Rev. 0, Process Flow Diagram Direct Feed Effluent Transfer

(System DEP)

6.14 24590-BOF-M5-V17T-00012, Rev. 0, Process Flow Diagram Direct Feed Effluent Evaporator

(System DEP)

6.15 24590-BOF-M5-V17T-00013, Rev. 0, Process Flow Diagram Direct Feed Concentrate Transfer

(System DEP and DVP)

6.16 24590-BOF-M5-V17T-00014, Rev. 0, Process Flow Diagram Direct Feed Process Condensate

Transfer (System DEP)

6.17 24590-BOF-MVC-DEP-00007, Rev. A, Process Data for the Overhead Sampling Vessels (DEP-

VSL-00004A/B) and Pumps (DEP-PMP-00004A/B/C)

6.18 24590-BOF-MVC-DEP-00003, Rev. A, Process Data for the Evaporator Feed Vessel (DEP-

VSL-00002), Transfer Pumps (DEP-PMP-00002A/B), and Recirculation Pumps (DEP-PMP-

00012A/B/C)

6.19 24590-BOF-MVC-DEP-00011, Rev. B, Process Data for the Low Point Drain Vessel, DEP-VSL-

00001, and Pumps, DEP-PMP-00001 A/B

6.20 24590-BOF-MVC-DEP-00010, Rev. A, Process Data for the Evaporator Concentrate Vessels,

DEP-VSL-00003A/B/C, and Pumps, DEP-PMP-00003A/B

6.21 24590-BOF-MVC-DEP-00008, Rev. A, Process Data for the Process Condensate Lag Storage

Vessels (DEP-VSL-00005A/B), Transfer Pumps (DEP-PMP-00005A/B), and Recirculation

Pumps (DEP-PMP-00015A/B/C)

6.22 24590-LAW-MVC-LCP-00002, Rev. 2, LAW Concentrate Receipt Process System (LCP) Data

6.23 24590-LAW-MVC-LFP-00001, Rev 1, LAW Melter Feed Process System (LFP) Data

24590-WTP-DB-PET-17-001, Rev 0


Page 17

24590-PADC-F00041 Rev 6 (1/22/2009)

6.24 24590-LAW-M4C-LOP-00001, Rev. 4, LAW Melter Offgas System Design Basis Flowsheets

6.25 24590-LAW-3PS-AE00-T0001, Rev. 6, Engineering Specification for the Low Activity Waste

Melters

6.26 24590-101-TSA-W000-0009-06-06A, Rev. NA, Literature Survey of Physical Properties for

LAW Container Fill Model

6.27 24590-LAW-MVC-LOP-00001, Rev. 0, Process Data Input for LAW SBS Condensate Vessels

and Pumps (LOP-VSL-00001/2 and LOP-PMP-00001/2/4/5) and SBS Water Purge Pumps (LOP-

PMP-00003A/B and LOP-PMP-00006A/B)

6.28 24590-LAW-MVC-RLD-00009, Rev. 0, Process Data Input for LAW C3/C5 Drains/Sump

Collection Vessel (RLD-VSL-00004) and Transfer Pumps (RLD-PMP-00002A/B)

6.29 24590-LAW-MVC-RLD-00007, Rev. 0, Process Input for LAW SBS Condensate Collection

Vessel, RLD-VSL-00005 and Discharge Pumps (RLD-PMP-00003A/B)

6.30 24590-LAW-MVC-RLD-00008, Rev. 0, Process Data Input for LAW Plant Wash Vessel (RLD-

VSL-00003) and Discharge Pumps (RLD-PMP-00001A/B)

6.31 24590-LAB-M5-V17T-00029, Rev. 4, WTP Analytical Laboratory Process Flow Diagram

Radioactive Liquid Disposal

6.32 24590-LAB-MVC-RLD-00002, Rev. 0, Process and Materials Selection Data for Laboratory

Area Sink Drain Collection Vessel (RLD-VSL-00164)

6.33 24590-WTP-3DG-M11T-00003, Rev. 0, Minimum Flow Velocity for Slurry Lines

6.34 24590-WTP-RPT-ENV-16-001, Rev. 0, One System – Feed Vector Development in Support of

WTP Environmental Risk Assessment Activities

6.35 24590-RMVD-03086, Rev. NA, APPS V3.0 Support Files

6.36 CCN 158961, Rev. NA, Mechanical Systems PT Facility Data Confirmation Required from the

Process Engineering and Technology Organization

6.37 24590-BOF-MEC-DEP-00001, Rev. A, DFLAW EMF Process System (DEP) Evaporator

Operating Conditions, Heating/Cooling Duty, and Utility Requirements

6.38 24590-WTP-DB-ENG-01-001, Rev. 6, Basis of Design

6.39 24590-WTP-PL-PE-16-0001, Rev. 0, WTP Direct Feed LAW Integrated Processing Strategy

Description

6.40 CCN 159204, Rev. NA, TFCOUP Rev 6 Feed Vector

7 External References

7.1 Oxychem, 2013. Oxychem Caustic Soda Handbook. Occidental Chemical Corporation. Dallas,

TX. 2013.

7.2 HNF-SD-WM-SP-012, Rev. 6, Tank Farm Contractor Operation and Utilization Plan

7.3 DE-AC27-01RV14136, WTP Contract, as amended

24590-WTP-DB-PET-17-001, Rev 0


Page A-i

24590-PADC-F00041 Rev 6 (1/22/2009)

Appendix A

Physical Properties of LAW Streams

24590-WTP-DB-PET-17-001, Rev 0


Page A-1

24590-PADC-F00041 Rev 6 (1/22/2009)

Appendix A

Physical Properties of LAW Streams

Stream Page Stream Page

. LCP01 A-2 . RLD25 A-44

. LCP07 A-3 . RLD27 A-45

. LFP04 A-4 . RLD32 A-46

. LFP05 A-5 . RLD33 A-47

. LFP06 A-6 . RLD34 A-48

. LMP01 A-7 . RLD35 A-49

. LMP02 A-8 . RLD41 A-50

. LMP03 A-9

. LMP06 A-10

. LMP09 A-11

. LMP11 A-12

. LMP13 A-13

. LMP14 A-14

. LMP15 A-15

. LMP16 A-16

. LOP01 A-17

. LOP02 A-18

. LOP04 A-19

. LOP05 A-20

. LOP06 A-21

. LOP07 A-22

. LOP08 A-23

. LOP09 A-24

. LVP01 A-25

. LVP03 A-26

. LVP04 A-27

. LVP06 A-28

. LVP08 A-29

. LVP09 A-30

. LVP10 A-31

. LVP11 A-32

. LVP12 A-33

. LVP13 A-34

. LVP14 A-35

. LVP17 A-36

. LVP18 A-37

. LVP19 A-38

. LVP20 A-39

. LVP21 A-40

. LVP23 A-41

. LVP26 A-42

. RLD21 A-43

24590-WTP-DB-PET-17-001, Rev 0


Page A-2

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-1. LCP01

LCP01

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating

Static Pressure psia Full Vacuum 14.3 14.3 Atmospheric

Vapor Pressure psia - 1.4 (2) 2.3 -

Temperature °F 77 124 (2) 139 140 (7)

Boiling Point

Temperature °F - 217 230 -

Dew Point Temperature °F n/a n/a n/a n/a

Relative Humidity % n/a n/a n/a n/a

Suspended Solids wt% 0 (4) 0.1 (5) 3 (2) 3.4

Total Salts wt% - 24 40 -

Slurry or Vapor Density lb/ft3 62.4 72.9 83.6 91.1

Liquid Density lb/ft3 - 72.8 83.6 -

Viscosity cP 0.4 1.3 3.7 15

Thermal Conductivity BTU/hr·ft·R - 0.37 0.38 -

Heat Capacity BTU/lb·R - 0.67 0.81 -

pH ––– - 13.9 14.7 -

Na+ Molarity [M] - 3.6 7.9 10 (6)

(1) Unless otherwise stated all lower and upper normal operating values are sourced from 24590-LAW-M4C-

V11T-00001, Rev 1 (24590-RMVD-03242-05 "LAW PIBOD RESULTS.xlsx")

(2) Value(s) sourced from 24590-BOF-M4C-V11T-00006, Rev 1 (see Appendix C)

(3) Unless otherwise stated all minimum and maximum operating values are sourced from 24590-LAW-MVC-

LCP-00002, Rev 2

(4) The minimum value is not expressly stated in 24590-LAW-MVC-LCP-00002 however 0% is a bounding

minimum value

(5) Sufficient significant figures reported to indicate non-zero value. Number of significant figures implies

neither accuracy nor precision

(6) Maximum operating Na+ molarity for LCP01 sourced from 24590-WTP-DB-ENG-01-001, Basis of Design,

pg. 6-10

(7) The temperature of transfers from the DEP evaporator is controlled to be consistent with a 140°F maximum

as a key process control strategy (24590-WTP-PL-PE-16-0001, pg. 70)

(8) If a minimum or maximum operating value is omitted it is either unavailable or bounded by lower and

upper normal operating value sourced from 24590-LAW-M4C-V11T-00001 or 24590-BOF-M4C-V11T-

00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-3

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-2. LCP07

LCP07

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating

Static Pressure psia - 14.4 14.4 -

Vapor Pressure psia - 1.9 2.3 -


Boiling Point Temperature °F - 221 230 -



Suspended Solids wt% - 0 0 3.4


Slurry or Vapor Density lb/ft3 - 75.4 84.3 -


Viscosity cP - 1.9 3.8 15



pH ––– 12.00 14.0 14.5 -

Na+ Molarity [M] 5.00 5.3 8.0 -

(1) Unless otherwise stated all lower and upper normal operating values are sourced from 24590-BOF-M4C-

V11T-00006, Rev 1 (Support Files-Volume 5 "DFLAW PIBOD Final Results.xlsx")

(2) Unless otherwise stated all minimum and maximum operating values are sourced from 24590-WTP-

ICD-MG-01-030, Rev 0, Table 5


upper normal operating value sourced from 24590-BOF-M4C-V11T-00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-4

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-3. LFP04

LFP04

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 77 132 145 -

Boiling Point




Suspended Solids wt% - 28 59 64




Viscosity cP 0.4 2.5 15.0 90


Heat Capacity BTU/lb·R - 0.79 0.86 (2) -

pH ––– - 13.9 14.6 -

Na+ Molarity [M] - 2.7 6.8 -

(1) Unless otherwise stated all lower and upper normal operating values are sourced from 24590-LAW-

M4C-V11T-00001, Rev 1 (24590-RMVD-03242-05 "LAW PIBOD RESULTS.xlsx")


(3) Unless otherwise stated all minimum and maximum operating values are sourced from 24590-LAW-

MVC-LFP-00001, Rev 1



00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-5

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-4. LFP05

LFP05

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 77 126 (2) 137 -

Boiling Point




Suspended Solids wt% - 28 59 64




Viscosity cP 0.4 2.5 15.0 90


Heat Capacity BTU/lb·R - 0.79 0.86 (2) -

pH ––– - 13.9 14.6 -

Na+ Molarity [M] - 2.7 6.8 -





MVC-LFP-00001, Rev 1



00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-6

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-5. LFP06

LFP06

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating

Static Pressure psia 11.8 14.3 14.3 -


Temperature °F 59 124 (2) 145 -

Boiling Point Temperature °F n/a n/a n/a n/a

Dew Point Temperature °F - 113 (2) 142 -

Relative Humidity % 50 100 100 -

Suspended Solids wt% n/a n/a n/a n/a

Total Salts wt% n/a n/a n/a n/a

Slurry or Vapor Density lb/ft3 0.05 0.06 0.06 -

Liquid Density lb/ft3 n/a n/a n/a

Viscosity cP - 0.02 0.02 -


Heat Capacity BTU/lb·R 0.24 0.26 0.28 -

pH ––– n/a n/a n/a n/a

Na+ Molarity [M] n/a n/a n/a n/a




(3) Unless otherwise stated all minimum and maximum operating values are sourced from LVP01 stream

data in 24590-LAW-M4C-LOP-00001, Rev 4


upper normal operating values sourced from 24590-LAW-M4C-V11T-00001 or 24590-BOF-M4C-

V11T-00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-7

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-6. LMP01

LMP01

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 59 86 86 113


Dew Point Temperature °F - 57 57 -

Relative Humidity % 30 40 40 100




Liquid Density lb/ft3 n/a n/a n/a n/a



Heat Capacity BTU/lb·R - 0.24 0.24 0.25






M4C-LOP-00001, Rev 4



00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-8

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-7. LMP02

LMP02

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating





Dew Point Temperature °F - -293 -293 -

Relative Humidity % - 0 0 -




Liquid Density lb/ft3 n/a n/a











upper normal operating value sourced from 24590-LAW-M4C-V11T-00001

24590-WTP-DB-PET-17-001, Rev 0


Page A-9

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-8. LMP03

LMP03

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






















24590-WTP-DB-PET-17-001, Rev 0


Page A-10

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-9. LMP06

LMP06

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






Relative Humidity % 0.07 0.3 (3) 0.4 (3) 0.8


















24590-WTP-DB-PET-17-001, Rev 0


Page A-11

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-10. LMP09

LMP09

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating


Vapor Pressure psia n/a n/a n/a n/a

Temperature °F 2012 2100 2100 2192






Slurry or Vapor Density lb/ft3 - 152.1 152.9 (2) 153.6 (4)


Viscosity cP 1000 n/a n/a 15000

Thermal Conductivity BTU/hr·ft·R n/a n/a n/a n/a

Heat Capacity BTU/lb·R n/a 0.34 (4) 0.34 (4) n/a







3PS-AE00-T0001, Rev 6, Section 3.2

(4) Values from 24590-101-TSA-W000-0009-06-06A, Sections 5 & 6



00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-12

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-11. LMP11

LMP11

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






















24590-WTP-DB-PET-17-001, Rev 0


Page A-13

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-12. LMP13

LMP13

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






















24590-WTP-DB-PET-17-001, Rev 0


Page A-14

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-13. LMP14

LMP14

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






Relative Humidity % 0.2 1 1 2.6
















24590-WTP-DB-PET-17-001, Rev 0


Page A-15

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-14. LMP15

LMP15

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






Relative Humidity % 0.2 1 1 2.6
















24590-WTP-DB-PET-17-001, Rev 0


Page A-16

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-15. LMP16

LMP16

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 77 77 -




Suspended Solids wt% - 0 0 -


Slurry or Vapor Density lb/ft3 n/a n/a n/a n/a





pH ––– - 7.0 7.0 -

Na+ Molarity [M] - 0.0 0.0 -





00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-17

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-16. LOP01

LOP01

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating

Static Pressure psia 7.60 12.7 13.1 14.85






Suspended Solids wt% - 0.1 (3) 1 -




Viscosity cP 0.49 0.5 0.7 0.68



pH ––– - 2.9 12.6 -

Na+ Molarity [M] - 0.05 (3) 0.1 -




MVC-LOP-00001, Rev 0





24590-WTP-DB-PET-17-001, Rev 0


Page A-18

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-17. LOP02

LOP02

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






















24590-WTP-DB-PET-17-001, Rev 0


Page A-19

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-18. LOP04

LOP04

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating











Viscosity cP 0.49 0.6 0.6 0.68



pH ––– - 2.9 12.6 -

Na+ Molarity [M] - 0.05 (3) 0.1 -









24590-WTP-DB-PET-17-001, Rev 0


Page A-20

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-19. LOP05

LOP05

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating











Viscosity cP 0.49 0.6 0.6 0.68



pH ––– - 2.9 12.6 -

Na+ Molarity [M] - 0.05 (3) 0.1 -









24590-WTP-DB-PET-17-001, Rev 0


Page A-21

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-20. LOP06

LOP06

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating

Static Pressure psia - 14.5 14.5 15.7








Slurry or Vapor Density lb/ft3 - 0.07 0.07 0.08













24590-WTP-DB-PET-17-001, Rev 0


Page A-22

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-21. LOP07

LOP07

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F - 106 136 - (4)

Boiling Point





Total Salts wt% - 0.4 (5) 11 -



Viscosity cP 0.406 0.5 0.7 1.14



pH ––– - 3.8 13.1 -

Na+ Molarity [M] - 0.03 (5) 0.8 -




MVC-RLD-00009, Rev 0



(4) Maximum operating temperature limited to LOP-WESP-00001 outlet temperature identified as Upper

Normal Operating value



24590-WTP-DB-PET-17-001, Rev 0


Page A-23

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-22. LOP08

LOP08

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






















24590-WTP-DB-PET-17-001, Rev 0


Page A-24

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-23. LOP09

LOP09

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating














pH ––– - 7.0 7.0 -

Na+ Molarity [M] - 0.0 0.0 -





00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-25

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-24. LVP01

LVP01

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 59 123 (2) 141 -


Dew Point Temperature °F - 116 (2) 136 -

Relative Humidity % 50 73 92 100

















00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-26

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-25. LVP03

LVP03

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






Relative Humidity % 55.6 59 (2) 100 -
















upper normal operating value sourced from 24590-LAW-M4C-V11T-00001or 24590-BOF-M4C-V11T-

00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-27

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-26. LVP04

LVP04

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating























00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-28

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-27. LVP06

LVP06

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating























00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-29

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-28. LVP08

LVP08

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F - 190 197 289



Relative Humidity % 5.4 21 28 -
















24590-WTP-DB-PET-17-001, Rev 0


Page A-30

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-29. LVP09

LVP09

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 289 324 387 (2) 406



Relative Humidity % - 0.4 (2,3) 1 -















(4) Unless otherwise stated all minimum and maximum operating values are sourced from 24590-LAW-M4C-

LOP-00001, Rev 4



00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-31

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-30. LVP10

LVP10

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 494 578 713 (2) -



Relative Humidity % - 0 0.1 (3) -



















00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-32

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-31. LVP11

LVP11

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






Relative Humidity % 0.01 0.03 (3) 0.05 (3) -


















24590-WTP-DB-PET-17-001, Rev 0


Page A-33

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-32. LVP12

LVP12

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating
























24590-WTP-DB-PET-17-001, Rev 0


Page A-34

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-33. LVP13

LVP13

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






Relative Humidity % - 0 0 58
















24590-WTP-DB-PET-17-001, Rev 0


Page A-35

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-34. LVP14

LVP14

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 496 627 779 (2) -



Relative Humidity % - 0.03 (3) 0.05 (3) -



Slurry or Vapor Density lb/ft3 - 0.02 (2) 0.03 -
















00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-36

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-35. LVP17

LVP17

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating














pH ––– - 9.0 9.5 (2) -

Na+ Molarity [M] - 2.0 2.0 -





upper normal operating value sourced from 24590-LAW-M4C-V11T-00001, Rev 1 or 24590-BOF-

M4C-V11T-00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-37

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-36. LVP18

LVP18

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating






Relative Humidity % 95 100 100 -
















24590-WTP-DB-PET-17-001, Rev 0


Page A-38

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-37. LVP19

LVP19

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 59 (2) 77 77 95 (2)







Liquid Density lb/ft3 - 68.9 68.9 74.4

Viscosity cP 1.1 2.9 2.9 -

Thermal Conductivity BTU/hr·ft·R 0.36 0.37 0.37 0.38


pH ––– - 14.7 14.7 -

Na+ Molarity [M] - 5.0 5.0 -



(2) The minimum and maximum operating temperatures are set to the minimum and maximum ambient

temperatures of SHR-TK-00003 per 24590-WTP-DB-ENG-01-001, Basis of Design, Table 12-1

(3) Unless otherwise stated all minimum and maximum operating values are sourced from Oxychem Caustic

Soda Handbook (Reference 7.1) using data for 17wt% NaOH



24590-WTP-DB-PET-17-001, Rev 0


Page A-39

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-38. LVP20

LVP20

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating














pH ––– - 7.0 7.0 -

Na+ Molarity [M] - 0.0 0.0 -





00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-40

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-39. LVP21

LVP21

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating














pH ––– - 9.0 9.5 (2) -

Na+ Molarity [M] - 2.0 2.0 -






00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-41

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-40. LVP23

LVP23

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating
























24590-WTP-DB-PET-17-001, Rev 0


Page A-42

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-41. LVP26

LVP26

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating























00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-43

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-42. RLD21

RLD21

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




Boiling Point




Suspended Solids wt% 0 (3) 0.1 (5) 1 -




Viscosity cP 0.40 0.5 0.5 0.68



pH ––– - 3.0 12.6 -

Na+ Molarity [M] - 0.1 0.1 -





(3) The minimum value is not expressly stated in 24590-LAW-MVC-RLD-00007 however 0% is a bounding

minimum value





24590-WTP-DB-PET-17-001, Rev 0


Page A-44

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-43. RLD25

RLD25

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F - 59 (2) 145 166

Boiling Point






Slurry or Vapor Density lb/ft3 61.7 62.4 109 -


Viscosity cP 0.38 0.5 15 -



pH ––– - 2.9 14.7 -

Na+ Molarity [M] - 0.03 (5) 7.9 -








00006



24590-WTP-DB-PET-17-001, Rev 0


Page A-45

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-44. RLD27

RLD27

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F - 59 (2) 145 166

Boiling Point






Slurry or Vapor Density lb/ft3 61.7 62.4 109 -


Viscosity cP 0.4 0.5 15 -



pH ––– - 2.9 14.7 -

Na+ Molarity [M] - 0.03 (5) 7.9 -








00006



24590-WTP-DB-PET-17-001, Rev 0


Page A-46

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-45. RLD32

RLD32

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




Boiling Point

Temperature °F n/a n/a n/a n/a


















24590-WTP-DB-PET-17-001, Rev 0


Page A-47

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-46. RLD33

RLD33

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




Boiling Point


Dew Point Temperature °F - 43 73 (2) -


















00006

24590-WTP-DB-PET-17-001, Rev 0


Page A-48

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-47. RLD34

RLD34

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




Boiling Point



















24590-WTP-DB-PET-17-001, Rev 0


Page A-49

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-48. RLD35

RLD35

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




Boiling Point








Viscosity cP 0.406 0.6 1.0 1.14



pH ––– - 3.8 (2) 13.1 -

Na+ Molarity [M] - 0.03 (5) 0.8 -








00006



24590-WTP-DB-PET-17-001, Rev 0


Page A-50

24590-PADC-F00041 Rev 6 (1/22/2009)

Table A-49. RLD41

RLD41

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating

Static Pressure psia - 14.3 14.3 Atmospheric







Total Salts wt% - 0.5 0.5 -






pH ––– - 6.0 (2) 8.0 (2) -

Na+ Molarity [M] - 0.0 0.0 -



(2) pH adjusted to a normal range of 6-8 per section 5.14.1 in 24590-BOF-M4C-V11T-00006, Rev 1

(3) Unless otherwise stated all minimum and maximum operating values are sourced from 24590-LAB-MVC-

RLD-00002, Rev 0



24590-WTP-DB-PET-17-001, Rev 0


Page B-i

24590-PADC-F00041 Rev 6 (1/22/2009)

Appendix B

Physical Properties of EMF Streams

24590-WTP-DB-PET-17-001, Rev 0


Page B-1

24590-PADC-F00041 Rev 6 (1/22/2009)

Appendix B

Physical Properties of EMF Streams

Stream Page

. DEP01 B-2

. DEP02 B-3

. DEP03 B-4

. DEP03b B-5

. DEP04 B-6

. DEP05 B-7

. DEP06 B-8

. DEP07 B-9

. DEP08 B-10

. DEP09 B-11

. DEP13 B-12

. DEP14 B-13

. DEP15 B-14

. DEP16 B-15

. DEP17 B-16

. DEP18 B-17

. DEP19 B-18

. DEP20 B-19

. DEP24 B-20

24590-WTP-DB-PET-17-001, Rev 0


Page B-2

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-1. DEP01

DEP01

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




Boiling Point







Liquid Density lb/ft3 61.6 62.3 62.4 65.8

Viscosity cP 0.5 0.7 0.7 1.6



pH ––– - 9.0 9.6 -

Na+ Molarity [M] - 0.05 (3) 0.1 -



(2) Unless otherwise stated all minimum and maximum operating values are sourced from 24590-BOF-

MVC-DEP-00007, Rev A





24590-WTP-DB-PET-17-001, Rev 0


Page B-3

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-2. DEP02

DEP02

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




Boiling Point




Suspended Solids wt% 0 (4) 0.04 (5) 0.1 (5) -




Viscosity cP 0.4 0. 7 0.7 2.5



pH ––– - 12.0 12.6 -

Na+ Molarity [M] - 0.1 0.1 -







(4) The minimum value is not expressly stated in 24590-BOF-MVC-DEP-00003 however 0% is a bounding

minimum value



24590-WTP-DB-PET-17-001, Rev 0


Page B-4

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-3. DEP03

DEP03

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




Boiling Point




Suspended Solids wt% - 0 0.05 (4) 3.4 (5)




Viscosity cP 0.54 0.8 0.8 2.5



pH ––– - 12.4 12.9 -

Na+ Molarity [M] - 0.1 0.2 -




MVC-DEP-00011, Rev B





(5) Maximum suspended solids content of DEP-VSL-00001 based on maximum solids content of feed

transfer per 24590-LAW-MVC-LCP-00002, Rev 2

24590-WTP-DB-PET-17-001, Rev 0


Page B-5

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-4. DEP03b

DEP03b

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating





Dew Point Temperature °F - n/a n/a -

Relative Humidity % - n/a n/a -




Liquid Density lb/ft3 - 62.3 62.6 (3) -


Thermal Conductivity BTU/hr·ft·R - 0.36 (3) 0.37 -


pH ––– - 7.0 12.6 (3) -

Na+ Molarity [M] - 0.0 0.1 (3) -

(1) Unless otherwise stated all lower and upper normal operating values are sourced from 24590-BOF-

M4C-V11T-00006, Rev 1 (Support Files-Volume 5 "DFLAW PIBOD Final Results.xlsx")



(3) APPS 3.0 models DEP-FILT-00003 filter backflush as DIW. Current mechanical design uses pressurized

air to back pulse the filter permeate. A DIW connection is provided for backup. Noted values (3) have

been set equal to stream DEP02 values (filter permeate) to capture the range of physical properties

representative of planned operations

24590-WTP-DB-PET-17-001, Rev 0


Page B-6

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-5. DEP04

DEP04

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F - 105 107 109 (4)





Total Salts wt% - 0.01 (3) 0.02 (3) -






pH ––– - 9.0 9.6 -

Na+ Molarity [M] - 0.0 0.0 -







(4) Maximum operating temperature sourced from 24590-BOF-MEC-DEP-00001, Rev A

24590-WTP-DB-PET-17-001, Rev 0


Page B-7

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-6. DEP05

DEP05

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F - 115 116 139 (5)






Slurry or Vapor Density lb/ft3 - 65.6 67.8 84.3 (4)


Viscosity cP - 0.8 0.9 15 (4)



pH ––– - 13.1 13.6 -

Na+ Molarity [M] - 1.0 1.6 -







(4) Maximum operating slurry density and viscosity sourced from 24590-BOF-MVC-DEP-00010, Rev A

(5) DEP05 maximum operating temperature is based on the maximum operating temperature for DEP-

EVAP-00001 which is set at 139°F per 24590-WTP-PL-PE-16-0001, WTP Direct Feed LAW Integrated

Process Strategy Description, Section 5.2.1.3.1.1

24590-WTP-DB-PET-17-001, Rev 0


Page B-8

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-7. DEP06

DEP06

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




Boiling Point



Relative Humidity % 10 (4) 100 (4) 100 (4) -
















(4) Minimum operating relative humidity based on intake air supply per 24590-WTP-DB-ENG-01-001,

Basis of Design, Table 12-1. Lower and upper normal relative humidity of 100% was selected as a

conservative assumption for ventilation sizing purposes. Actual relative humidity will range between 10-

100%

24590-WTP-DB-PET-17-001, Rev 0


Page B-9

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-8. DEP07

DEP07

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating


















(2) Unless otherwise stated all minimum and maximum operating values are sourced from 24590-BOF-MVC-

DEP-00003, Rev A



(4) Minimum operating relative humidity based on intake air supply per 24590-WTP-DB-ENG-01-001, Basis

of Design, Table 12-1. Lower and upper normal relative humidity of 100% was selected as a conservative

assumption for ventilation sizing purposes. Actual relative humidity will range between 10-100%

24590-WTP-DB-PET-17-001, Rev 0


Page B-10

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-9. DEP08

DEP08

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



















DEP-00011, Rev B






24590-WTP-DB-PET-17-001, Rev 0


Page B-11

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-10. DEP09

DEP09

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




















(3) Minimum operating relative humidity based on intake air supply per 24590-WTP-DB-ENG-01-001,

Basis of Design, Table 12-1. Lower and upper normal relative humidity of 100% was selected as a

conservative assumption for ventilation sizing purposes. Actual relative humidity will range between 10-

100%

24590-WTP-DB-PET-17-001, Rev 0


Page B-12

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-11. DEP13

DEP13

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 40 70 79 140 (3)

Boiling Point






Slurry or Vapor Density lb/ft3 - 65.9 68.1 84.3

Liquid Density lb/ft3 61.2 65.4 67.1 -

Viscosity cP 0.4 1.1 1.4 15



pH ––– - 13.1 13.5 -

Na+ Molarity [M] - 1.0 1.5 -





(3) Maximum operating temperature based on maximum LCP-VSL-00001/2 temperature per 24590-LAW-

MVC-LCP-00002, Section 8. The DFLAW WIPSD, 24590-WTP-PL-PE-16-0001, establishes

operational controls for the DEP evaporator to be operated below 140°F (Section 5.2.1.3.1.1)



24590-WTP-DB-PET-17-001, Rev 0


Page B-13

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-12. DEP14

DEP14

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



















DEP-00008, Rev A



24590-WTP-DB-PET-17-001, Rev 0


Page B-14

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-13. DEP15

DEP15

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




















24590-WTP-DB-PET-17-001, Rev 0


Page B-15

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-14. DEP16

DEP16

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




















24590-WTP-DB-PET-17-001, Rev 0


Page B-16

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-15. DEP17

DEP17

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




















24590-WTP-DB-PET-17-001, Rev 0


Page B-17

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-16. DEP18

DEP18

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




















24590-WTP-DB-PET-17-001, Rev 0


Page B-18

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-17. DEP19

DEP19

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating









Slurry or Vapor Density lb/ft3 - 4E-03 4E-03 -











24590-WTP-DB-PET-17-001, Rev 0


Page B-19

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-18. DEP20

DEP20

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating




Boiling Point








Viscosity cP 0.5 0.8 0.9 1.6



pH ––– - 9.0 9.6 -

Na+ Molarity [M] - 0.05 (3) 0.1 -









24590-WTP-DB-PET-17-001, Rev 0


Page B-20

24590-PADC-F00041 Rev 6 (1/22/2009)

Table B-19. DEP24

DEP24

Properties Units

Minimum

Operating

Lower

Normal

Operating

Upper

Normal

Operating

Maximum

Operating



Temperature °F 40 70 79 140 (3)
















DEP-00010, Rev A

(3) Maximum operating temperature based on maximum temperature in DEP-VSL-00003A/B/C (see stream

DEP13, Table B-11)






24590-WTP-DB-PET-17-001, Rev 0


Page C-i

24590-PADC-F00041 Rev 6 (1/22/2009)

Appendix C

Comparison of PTF and DFLAW APPS Results for

Selection of PIBOD Inputs

24590-WTP-DB-PET-17-001, Rev 0


Page C-1

24590-PADC-F00041 Rev 6 (1/22/2009)

Appendix C

Comparison of PTF and DFLAW APPS Results for

Selection of PIBOD Inputs

C1. Introduction

This appendix documents the selection of lower and upper normal operating physical property values for

LAW process streams from two sets of viable data for use in this PIBOD. The two sets of LAW process

stream data are results from the following calculations: 24590-LAW-M4C-V11T-00001, Calculation of

Process Stream Properties for the LAW Facility and 24590-BOF-M4C-V11T-00006, Calculation of

Process Stream Properties for the Effluent Management Facility. This appendix documents the following

steps taken:

• Select lower and upper physical property data for the APPS streams listed in Table C-1 from the

results of 24590-BOF-M4C-V11T-00006. This step is performed in the following Excel files

which are included as Support Files for this report:

o System LCP_DFLAW.xlsx

o System LFP_DFLAW.xlsx

o System LMP_DFLAW.xlsx

o System LOP_DFLAW.xlsx

o System LVP_DFLAW.xlsx

o System RLD_DFLAW.xlsx

• Compare lower and upper data points from 24590-LAW-M4C-V11T-00001 and 24590-BOF-

M4C-V11T-00006 and select overall lower and upper normal operating physical property values

of LAW streams for use in the PIBOD. This step is performed in Excel file: LAW-DFLAW

Compare.xlsx which is included as a Support File for this report.

Table C-1. LAW Process Streams for Comparison

LCP01 LFP06ain LOP01 LOP09 LVP17 RLD21

LCP01a LFP06b LOP02 LVP01 LVP17a RLD25

LCP01fl LFP06bin LOP02a LVP03 LVP17b RLD27

LCP02fl LMP01 LOP04 LVP03a LVP18 RLD32

LCP06a LMP01a LOP05_1 LVP04 LVP18a RLD32a

LCP06ain LMP02_03 LOP05_2 LVP08 LVP20 RLD33

LCP07c LMP06 LOP06 LVP09 LVP21 RLD33a

LFP01 LMP09 LOP07_1 LVP10 LVP21b RLD35

LFP01a LMP11 LOP07_2 LVP11 LVP23 RLD41

LFP04 LMP12 LOP08 LVP12 LVP26

LFP05 LMP13 LOP08_1 LVP13a RLD04

LFP06a LMP14 LOP08_2 LVP14 RLD04a

24590-WTP-DB-PET-17-001, Rev 0


Page C-2

24590-PADC-F00041 Rev 6 (1/22/2009)

C2. Background

The staged approach being taken at WTP to begin DFLAW processing before completion of PT and

HLW means that the LAW facility will operate under two scenarios over the facility lifetime. There is the

potential for different operating conditions with respect to the physical properties of process streams from

one operating scenario to the other. 24590-LAW-M4C-V11T-00001, Calculation of Process Stream

Properties for the LAW Facility calculates process stream properties for the LAW facility under the PTF

operating scenario (PT, HLW, and LAW operational) while 24590-BOF-M4C-V11T-00006, Calculation

of Process Stream Properties for the Effluent Management Facility calculates the process stream

properties for the LAW facility under the DFLAW operating scenario (LAW and EMF). The objective of

this PIBOD is to report the expected range of physical properties for LAW streams regardless of whether

the facility is operating in DFLAW or PTF configuration. Therefore, results from the two calculations are

compared and overall lower and upper values are selected.

C3. Description of Supporting Excel Files

System LCP_DFLAW.xlsx

Lower and upper physical property values for the LCP streams listed in Table C-1 are selected from the

APPS runs for 24590-BOF-M4C-V11T-00006. Results for these streams are compiled on sheet

“LCP_PIBOD”.

System LFP_DFLAW.xlsx

Lower and upper physical property values for the LFP streams listed in Table C-1 are selected from the


“LFP_PIBOD”. Note: maximum viscosity values reported for LFP04 and LFP05 are provided from

24590-BOF-M4C-V11T-00006 (Section 5.14.4).

System LMP_DFLAW.xlsx

Lower and upper physical property values for the LMP streams listed in Table C-1 are selected from the


“LMP_PIBOD”.

System LOP_DFLAW.xlsx

Lower and upper physical property values for the LOP streams listed in Table C-1 are selected from the


“LOP_PIBOD”. Note: the minimum pH value for LOP04 is provided from 24590-BOF-M4C-V11T-

00006 (Section 7.11). LOP01, LOP05_1, and LOP05_2 are equivalent to LOP04 and therefore, are given

the same minimum pH value as LOP04.

System LVP_DFLAW.xlsx

Lower and upper physical property values for the LVP streams listed in Table C-1 are selected from the


“LVP_PIBOD”.

System RLD_DFLAW.xlsx

Lower and upper physical property values for the RLD streams listed in Table C-1 are selected from the


24590-WTP-DB-PET-17-001, Rev 0


Page C-3

24590-PADC-F00041 Rev 6 (1/22/2009)

“RLD_PIBOD”. Note: corrected pH values for RLD21, RLD35, and RLD41, as well as all physical

property values for RLD27 are provided from 24590-BOF-M4C-V11T-00006 (Sections 7.11 and 7.13).

RLD25 is equivalent to RLD27, therefore the physical property values for RLD25 are set equal to the

results for RLD27 (see Table 4-6, RLD System Stream Cross Walk).

LAW-DFLAW Compare.xlsx The contents of LAW-DFLAW Compare.xlsx are discussed in Table C-2.

Table C-2. Excel Comparison of LAW Streams in PTF versus DFLAW Configuration

Sheet Name Contents

LAW PIBOD Results Copy of results from LAW PIBOD calculation (24590-LAW-M4C-V11T-

00001). The Excel file from which these results are directly transcribed

can be found under 24590-RMVD-03242-05, LAW PIBOD RESULTS.xlsx

DFLAW PIBOD Results Compiles the results from the individual LAW system spreadsheets:

• System LCP_DFLAW.xlsx

• System LFP_DFLAW.xlsx

• System LMP_DFLAW.xlsx

• System LOP_DFLAW.xlsx

• System LVP_DFLAW.xlsx

• System RLD_DFLAW.xlsx

Compare Displays the results from the LAW PIBOD calculation (LAW Min and

Max columns) alongside the results from the DFLAW PIBOD calculation

(DFLAW Min and Max columns).

The Excel file shows cases where the lower and upper values from the DFLAW PIBOD calculation

bound the results from the LAW PIBOD calculation. Such cases are identified in the summary tables in

Appendix A of this report by the note which states: “Value(s) sourced from 24590-BOF-M4C-V11T-

00006, Rev 1 (see Appendix C).”

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