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है”ह”ह

IS 15068 (2001): Oil of Cardamom (Elettaria CardamomumMaton) [PCD 18: Natural and Synthetic Fragrance Materials]

-+

IS 15068:2001

Indian StandardOIL OF CARDAMOM (Elettaria cardamomum

Maton) — SPECIFICATION

lCS 71,100,60

0 BIS 2001

BUREAU OF INDIAN STANDARDSMANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG

NEW DELHI 110002

December 2001 Price Group 3

Natural and Synthetic Fragrance Materials Sectional Committee, PCD 18

FOREWORD

This Indian Standard was adopted by the Bureau of Indian Standards, after the draft finalized by the Natural

and Synthetic Fragrance Materials Sectional Committee had been approved by the Petroleum, Coal and RelatedProducts Division Council.

This standard is based on data generated at CFTRI, Mysore on cardamom oil (Elettaria cardamomum Maton)obtained by steam distillation of cardamom from Mysore variety, Malabar variety, Ceylon variety as well asfrom different regions including Guatemala and also the data available from the Indian manufacturer.1S0 4733:1981 ‘Specification for oil of cardamom’ has also been consulted. Chromatographic profile asshown in Table 2 is based on CFTRI data as well as data available from Indian manufacturers and has beenincludwl in the standard keeping in mind the recent practices being adopted by ISO for formulation of standardson essential oils,

This standard differs from 1S0 4733:1981 oil of cardamom mainly in respect of the following:

a) The temperature for determination of relative density, optical rotation and refractive index is 27QC asmentioned in the Indian Standard against 20”C in the ISO Standard.

b) While the range for relative density has been kept the same, the range for optical rotation and refractiveindex have been changed from 22 to 41° and 1.4620-1.4680 respectively as mentioned in 1S0Standard.

c) The maximum specified value for the requirement of acid value has been enhanced to 7.0 Max against6.0 as mentioned in 1S0 Standard.

d) The value for 1.8 cineole content has been stipulated as 26-41 percent against no stipulation at presentin 1S0 Standard,

The composition of the Committee responsible for formulation of this standard is given in Annex B.

For the purpose of deciding whether a particular requirement of this standard is complied with the final value,observed or calculated expressing the result of a test or analysis, it shall be rounded off in accordance withIS 2: 1960 ‘Rules for rounding off numerical values (revised)’. The number off significant places retained inthe rounded off value should be the same as that of the specified value in this standard.

,i%

IS 15068:2001

Indian Standard

OIL OF CARDAMOM (Elettaria cardamomumMaton) — SPECIFICATION

1 SCOPE

This standard prescribes the requirements and themethods of sampling and test for oil of cardamom.

2 REFERENCES

The following standards contain provisions which

through reference in this text constitute the provisionsof the standard. At the time of publication, the editionsindicated were valid. All standards are subject torevision and parties to agreements based on thisstandard are encouraged to investigate the possibilityof applying the most recent edition of the standardsindicated below:

Is No.326

(Part 1): 1984(Part 2): 1980

(Part 3): 1980

(Part 4) :1980(Part 5) :1986

(Part 6): 1986

(Part 7): 1980.

(Part 8): 1980

(Part 13) :1981(Part 19) :1998

1070:19922284:1988

6597:2001

TitleMethods of sampling and test fornatural and synthetic perfumerymaterialsSampling (second revision)Preliminary examination perfumerymaterials and samples (secondrevision)

Determination of relative density(second revision)Determination of optical relationDetermination of refractive index(second revision)Determination of volubility inethanol (second revision)Determination of acid value (secondrevision)Determination of ester value,contents of esters and combinedalcohols (second revision)Determination of cineole contentGas chromatographic analysis ofperfumery materialsReagent grade water (third revision)Method for olfactory assessment ofnatural and synthetic perfumerymaterials (second revision)Glossary of terms relating to naturaland synthetic perfume~ materials(second revision)

3 TERMINOLOGY

For the purpose of this standard, the definitions given

in IS 6597 shall apply.

4 REQUIREMENTS

4.1 Description

4.1.1 The oil shall be obtained by steam distillation offruits of Elettaria cardamomum (Linn) Maton,Var.minuscula Burkhill.

4.1.2 The oil of cardamom shall be a clear liquid freefrom sediment, suspended matter, separated water andadded adulterants, when tested as per IS 326 (Part 2).

4.2 Volubility in Ethanol

Material is completely soluble in two to five volumeof ethanol (70 percent by volume) when tested asprescribed in IS 326 (Part 6).

4.3 The material shall also comply with the require-ments given in Table 1 and Table 2.

4.4 Chromatographic Profile

Analysis of the essential oil shall be carried out byGas Chromatography as per Annex A. In the chroma-togram obtained, the representative and characteristiccomponents shown in Table 2 shall be identified. Theproportions of these components indicated by theintegrator shall be as shown in Table 2. Thisconstitutes the chromatographic profile of the essentialoil.

5 PACKING AND MARKING

5.1 Packing

5.1.1 The material shall be supplied in well closedcontainer, permitting a minimum of air space, asagreed between the purchaser and the supplier.

5.1.2 The material shall be well protected from thelight and stored in a cool dry place.

5.2 Marking

The container shall be marked with the followinginformation:

a) Name of the material;

b) Manufacturer’s name and address and/or hisrecognized trade-mark, if any;

c) Net mass of the material;

:

.>...-

1

1S 15068:2001

Table 1 Requirements for Oil of Cardamom

(Clauses 4,3 and 7.1)

slNo.

(1)

i)

ii)

iii)

iv)

v)

vi)

vii)

viii)

Characteristics

(2)

Colour and appearance

Odour

‘)Relativedensityat 27°C

Opticalrotationat 27°C

‘)Reti’activeIndex at 27°C

Acid value, Max

Estervalue

1,8Cineo]econtent,percent by mass

Requirements

(3)

Almostcolorless to yellow,liquid

Characteristic,spicy and camphorous

0.9190-0.9360

+ 16”to41°

1.4575-1.4605

7.0

92-150

26.0-41.0

Method of Test,Rcf to IS

(4)

326 (Part2)

2284

326 (part 3)

326 (Part4)

326 (Part S)

326 (Part7)

326 (Part 8)

326 (Part 13)

1)The ~omection factor for relative densitY[see 1S326 (part 3)] and refractive index [see IS 326 (part 5)] for each degree cekius change in

temperature is 0.00064 and 0.00038 respectively.

Table 2 Chromatographic Profile

(Clauses 4.3,4.4 and 7.1)

Components Minimnm Maximum

(1) (2) (3)

Sabinene 2.0 5.0

l,8Cineole 26.0 41.0

LinalooI 0.5 4.0

Linalyl acetate 1.5 8.0

Alpha-terpinyl acetate 30.0 42.0

d) Month and year of manufacture;

e) 1,8 Cineole content;

t) Batch number; and

g) Cautionary notice, if any.

5.2.1 BIS Certl~cation Marking

The containers may also be marked with the StandardMark.

5.2.1.1 The use of the Standard Mark is governed bythe provisions of Bureau ofIndian Standard Act, 1986

and the Rules and Regulations made thereunder. Thedetails of conditions under which the licence for theuse of Standard Mark maybe granted to manufactureror producers may be obtained from the Bureau ofIndian Standards.

6 SAMPLING

Representative samples of the materials, each samplecontaining not less than 50 ml shall be drawn asprescribed under IS 326 (Part 1).

7 NUMBER OF TESTS

7.1 Test for the determination of all the characteristicsshall be conducted on the composite sample asprescribed in 4.1,4.2, Table 1 and Table 2,

7.2 Quality of Reagents

Unless specified otherwise, pure chemicals anddistilled water shall be used in tests (see IS 1070).

NOTE— ‘Pure chemicals’ shall mean chemicals that do notcontain impurities which affect the result of t!seanalysis.

*

.

,,, ,.“6<

A-1 GENERAL

IS 15068:2001

ANNEX A

(Clause 4,4)

GAS CHROMATOGRAPHIC ANALYSIS OF OIL OF CARDAMOM

The chromatographic analysis is given on capillarycolumn. The chromatographic conditions given hereare for information and guidance.

A-2 PROCEDURE

A-2.1 The analysis shall be done as per IS 326 (Part 19).The typical chrolnatograms for oil of cardamomin capillary column with the following chromato-graphic conditions is shown in Fig. 1, Fig. 2 andFig, 3.

A-2.1.1 Capilla?y Column-Polar

Column HP-FFAP

a) Size 50 m X0.2 mm x 0.2 pm

b) Carrier gas Nitrogen

c) Flow rate 30 ml/min

d) Head pressure 207 kPa (30 psi)

2oooao-1

1oooOO

80000

maoo

400clo

2aooo

Conditions

a) Oven temperature 60-220”C

b) Ramp 30/rein

c) Injection port temperature 230”C

d) Time 20 min

Detector

a) Type FID

b) Temperature 250”C

Split 120:1

Volume of the sample 0.2 pl

A-2. 1.2 CapiUary Column-Non-Polar

Column DB-I

a) Length 30 m

b) I.D. 0.25 mm

““‘,

I:!,,

—.—.. -.,

.,

i$”,.!“ .’+,

“.~

i

. “

I I I I I I I I Io 10 2a so 40

FIG. 1 OIL OF CARDAMOM — TYPICAL CHROMATOGRAM

-.. ...........---------- ,----------, ---------- .-----------.-----------,....

—[

—1

t,

, it! ?.--. -L.....

~= .L-----

i--- .--. ---; ---------

FIG. 3 OIL OF CARDAMOM — TYPICAL CHROMATOGRAMFIG.2 OiL OF CARDAMOM — TYPICAL CHROMATOGRAM

c) Injection port temperature 230”C

d) Time 20 min

Detector

a) Type FID

b) Temperature 250”C

Nitrogen

30 ml/min

Carrier gas

Flow rate

Conditions

a) Oven temperature

b) Ramp

1OO-22O”C

5°1min

4

IS 15068:2001

ANNEX B

(Foreword)

COMMITTEE COMPOSITION

Natural and Synthetic Fragrance Materials Sectional Committee, PCD 18

Organization

Bush Boake Allen (India) Ltd, Mumbai

Camphor&Allied Products Ltd, Barcilly

CarishmaFood ConsultancyServices,New Delhi

CentralFood TechnologicalResearchInstitute,Mysore

Central Instituteof Medicinal AromaticPlants,Lucknow

Central RevenuesControl Laboratory,New Delhi

Dkectorate of Marketing& hrspecti~n,Faridabad

EssentialGil Associationof India,Ncw Delhi

Fragrancesand Flavours Associationoflndiaj Mumbai

Fragrance& Flavours Development Centre, Kannauj

ForestResearch Instituteand Colleges, DehraDun

Gupta& Company Ltd, Delhi

HhrdustanLever Ltd, Mumbai

IndianPharmacopoeiaCommittee (Ministryof Health& Family Welfare),New Delhi

Institute of HlmalayarrBioresourcesTechnology,Palarnpur,H.P.

KarnatakaSoaps and DetergentsLtd, Bangtdore

Mhsistryof Industry,Governmentof India

National Bureau of Plant Genetic Resources,Delhi

NishantAromas, Mumbai

Procter& Gamble India Ltd, Mumbai

RegionalResearchLaboratory, Itanagar

Som ExtractsLtd, Delhi

SynthiteIndustrialChemicals, Cocbin

The Development,Commissioner,Small Scale Industries,New Delhi

Ultra InternationalLtd, New Delhi

In personal capacity (8/S,Street E, Mayapuri, New DeVri-/ltX264)

BIS DirectorateGeneral

Representative(s)

DR G. S. RANADE(Chafrntun).!krr A. BEWOOR(A/ternare)

DRA.P. Srr@rDRB. S. PANGE(Alternate)

DR J.S. PRurMWG CDRP. S. PRuna (Alternate)

DRN.KSUSHNAMURTHVDRK. M. APPAtAH(Alternate)

DRSusraLKwDRA. K. SrNGH(Ar’ternde)

TNSClaw CrumsrsrTHEDtmmvCrrrsFCmmrsT(Akernde)

DRG. R. BHATTASHSUS.PRASAO(Alternate)

PRFsrDmVICEPRESrOENT(Alternate)

PREsDmi=rVICEPm.sroarw(Alternate)

Srau K.N. DwrvEDIDR ALOK LAHIRI(Alternate)

SmrrG. S. RAWAT

DR D.C. CHAuDrr,wrr(Alternate)

Smu SumrtRJMNSHSUSHSAMBEHASULAL(Alternate)

Mu C. K. LAGOGDRV. R. GAOGIL(Alternate)

Smr AstrwrNsKrrhmrtDR S. K. TALWAR (Alternate)

DRv. IL KAUL

Ssous. s. RsvAra

DRK. B. PATIL(Alierrrate)

$%rra!klSH KUMARSmr B. B. SHARMA(Alternate)

DRS. K. Pmam

sHrrrRAMAxAmHAruAxA

DRArroNvteHwAtwH

SW SHWETAPrnuwoArrsAlternate)

DrrR.K.MA-

Smus. c. vAmmJEV

SsriUsANJAYVARSHNEV(Alternate)

%KI @ORGSPAUL

SmrrS.R. SrNorsSrrruD.P. SINGH(Altesvute)

SHRISANTK.SANGAMRIA

SwrBHIJVNANAGESHWARAN(Alternate)

DRM.L. Mmmswmu

SmuAWANKm Dkector& Head (PCD)

@representingDirector General (Ex-@cioMember)]

Member Secretary

MIT. IWMVANAN

Joint Dke.ctor(PCD), BIS

5

! ..

Bureau of Indian Standards

BIS is a statutory institution established under the Bureau of Indian Standards Act, 1986 to promoteharmonious development of the activities of standardization, marking and quality certification of goodsand attending to connected matters in the country,

Copyright

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Review of Indian Standards

Amendments are issued to standards as the need arises on the basis of comments. Standards are also reviewedperiodically; a standard along with amendments is reaffirmed when such review indicates that no changes areneeded; if the review indicates that changes are needed, it is taken up for revision. Users of Indian Standardsshould ascertain that they are in possession of the latest amendments or edition by referring to the latest issue of‘BIS Catalogue’ and ‘Standards: Monthly Additions’.

This Indian Standard has been developed from DOC : No. PCD 18 (1651).

Amendments Issued Since Publication

Amend No. Date of Issue Text Affected

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