'International Congress on Catalysis ; 10 (Budapest) : 1992.07.19 … · 2008-07-15 · The...
Transcript of 'International Congress on Catalysis ; 10 (Budapest) : 1992.07.19 … · 2008-07-15 · The...
Studies in Surface Science and Catalysis
Advisory Editors: B. Delmon and J. T. Yates
Vol. 75
NEW FRONTIERS
IN CATALYSIS
Proceedings of the 10th International Congresson Catalysis,Budapest, July 19-24, 1992
PARTC
Editors
L. GUCZI
Institute of Isotopes of the Hungarian Academy of Sciences
P. 0. Box 77, H-1525 Budapest, Hungary
F. SOLYMOSI
Institute of Solid State and Radiochemistry, Jdzsef Attila UniversityP. 0. Box 168, H-6701 Szeged, Hungary
P. TETENYI
Institute of Isotopes of the Hungarian Academy of Sciences
P. 0. Box 77, H-1525 Budapest, Hungary
ELSEVIER Amsterdam-London-New York-Tokyo 1993
XV
Scanning Tunneling Microscopy Study of Pd/Graphite: Microstructure and
ReactivityK. L. YeungandE. E. Wolf 1851
IR Study of Adsorption and Dcuteration of d6-Acetone on Pt/ZnO Catalysts: Effects
of the Sample PretreatmentsF. Boccuzzi, G. Ghiotti and A, Chiorino 1855Surface Energetic Characterization of Supported Metal Catalysts by Gas/SolidTitration MicrocalorimctryJ. M. Guil, A. P. Masia, A. R. Paniego and J. M. T. Menayo 1859
Study of the Effects of Annealing on the Morphology of Platinum Cluster Size on
Highly Oriented Pyrolytic Graphite by Scanning Tunneling MicroscopyS. Lea, H. Pcrmana andK. Y.S.Ng 1863
Distribution of Mo Oxidation States in Reduced Mo/Al203 Catalysts, Correlation
with Catalytic ActivityJ. Yasumaru, M.Yamada, M. Houalla and D. M. Hercules 1867
Effect of Catalyst Preparation on the Performance of Supported Ru-Cu Bimetallic
SystemsR. Maggiore, C. Crisafulli, S. Scire andS. Galvagno 1871
Revisiting Diffuse Reflectance Spectroscopy for the Characterization of Metal and
Semiconducting Oxide CatalystsA. Rakai, A. Bensalem, J. C. Midler, D. Tessier andF. Bozon-Verduraz 1875
The Thermal Stability of the Adsorbed/Lattice Oxygen Species on the Oxide
Catalysts Surfaces
M. Caldararu andN. I. Ionescu 1879
Chemical Anchoring of Noble Metal Amine Precursors to Silica: An in situ UV
Diffuse Reflectance StudyW. Zou andR. D. Gonzalez 1883
Reaction Sites on the AI0O3 Support of Pd/Al^J, L Falconer, B, Chen,S. A, Larson andE. C. Hsiao 1887
The External Magnetic Field Effect on the H2-02 Reaction on the Sn02 Surface
//. Ohnishi, H. Sasaki andM. Ippommatsu 1891
Characterization of Different Surface Mo Species in Mo/Al203 Catalysts by Time
Differential Perturbed Angular Correlation
S. Guida, Y. Tingyun, Y. Fushan, R. Liguo andN. Xinbo . 1895
PARTC
New Catalytic Phases for the HDN and MHC Reactions in CoMoP-Alumina
CatalystsA, Morales, R. Prada-Silvy and V. Leon 1899
Multi-Purposc Ni-Mo/Al^ Catalysts for Gas Oil HydrotreatingA. F. Somogyydri, M. C. Obalk and P. S. Herrera 1903
Characterization of Phosphorus Containing Ni-W/AljO;) CatalystsP. Aianasova and T, Halachev
*
1907
Concerted Mechanism of Thiophene Hydrogcnolysis by Sulfide HDS CatalysisA. N. Siansev • 1911
Highly Active Ni-W/Al203 Catalyst for Upgrading Unconventional Feedstocks
H. Shimada, T. Kameoka, H. Yanase, M. Watanabe, A. Kinoshita, T. Sato,Y, Yoshimura, N. MastubayashiandA. Nishinma 1915
Adsorption and Activaiion of Thiophene on MoS2, Co9S8 and RuS2C RongandX. Gjn 1919
Correlation of HDS Aclivity with Heal of Adsorption over Carbon Supported CoMoOfitftlv&ts
S.-K. Ihm, Y,-H. Moon andC.-D. lhm 1923
XVI
Effect of Fluoride on the Surface Structure of WOyAl203 Hydrotreating CatalysisR. L. Cordero, J. R. Solis, J. V. G. Ramos, A. B. Patricio and A. L. Agudo 1927
Hydrodesulfurization Activity of Zeolite Supported Nickel- and Cobalt Sulfide
CatalystsW. J. J. Welters, T. LKordnyi, V. H. J. da Beer andR. A. van Santen 1931
Enhanced HDS Activity via Multiple Impregnation of Sulfided Mo/Al203 CatalysisC.-S. Kim, F. E. Massoth, C. Geantet andM. Breysse 1935
Surface Structure of Molybdenum Nilridc and its Activity for Hydrodesulfurizationand HydrodenilrogenationM. Nagai, T. Miyao, T. TsuboiandT. Kusagaya 1939
Hydrocracking Gas Oils from Synthetic Crude with Mixed Pillared Clay-AluminaSupported CatalystsJ. Monnier, J.-P. Charland, J. R. Brown andM. F. Wilson 1943
Transformations of Thiophene, Tetrahydrothiophene and Butanclhiol over Co-Black,Co/AUO^ Mo/AlvO-j and Co-Mo/Al263 during Temperature-Programmed ReaciionV. V. Rozanov, Y. TzaoandO. V. Krylov 1947Partial Oxidation Reaction of Methane with Oxygen or Carbon Dioxide byTransition Metal Catalysis Supported on Ultrafine Single-Crystal Magnesium Oxide
0. Takayasu, I. Matsuura, K. NittaandY. Yoshida 1951Surface Oxygen Species and their Reactivities in the Oxidation of CH4, C2H6 and
C2H4 over Cerium Oxide at Mild TemperaturesC. Li, Q. Xin, X. Guo andT. Onishi 1955Oxidative Catalytic Conversions of Tetrahydrofuran Derivatives
R. Skolmcistere, L, Leitis, M. Fleisher andM. Shymanska 1959
Role of Mo and Sb in Oxide Catalysts for Selective Oxidation of PropyleneB. Zhou, X. Guo andK. T. Chuang 1963Partial Oxidation of Methane at Low Pressure over Silica Gel and Silica-SupportedSn, Zr and Gc OxidesT. Ono, K. Ikuta andY. Shigemura 1967The Influence of the Support on ihe Performance of Heterogeneous Catalysis for theWacker Oxidation of Alkencs
A. W. Stobbe-Kreemers, J. J. F. Scholten, M. SoedeandJ. W. Vcenman 1971
Optimization of Ni0/Mo0yTcO2 Catalytic System for Direct Oxidation of Propcneto Acrylic AcidC. Mazzocchia, JR. Anouchinsky, A. Kaddouri andE. Tempesti 1975Role of Amorphous Phase and its Modification in V-P-0 Catalysts for Maleic
Anhydride Synthesis from ButaneN. Yamazoe, H. Morishige, J. Tamaki andN. Miura 1979Selective Oxidation and Ammoxidation of Propane to form Acrolein andAcrylonitrilcY. Mow-oka, N. Miura, N. Fujikawa, Y.-C. Kim and W. Veda 1983Oxidation of Propcne on Alkaline Metal-Doped MoOj/Ti02 Catalysis: A FT-IRStudyC. Martin, I. Martin, C. Mendizahal and V. Rives 1987Oxidation of Methanol to Formaldehyde over Antimony-Molybdenum OxideCatalystR. S. Mann andR. A. Diaz-Real 1991A Comparison between Epoxidation and Degradation of Ethylene and Propyleneover SilverC. Henriqucs, M. F. Portela, C Mazzocchia andE. Guglielminotti 1995Liquid-Phase Oxidation of Benzene with Molecular Oxygen Catalyzed byCu-Zcoliles
T. Ohtani, S. Nishiyama, S, Tsuruya andM. Masai 1999
XVII
Formation of Formaldehyde from Methanol over Supported Titanium Oxide
H. Imai, Y. Murakami andH. Irikawa2003
A Study on P-Mo-As Heteropoly Compounds as Catalyst for Selective Oxidation ofMethacrolein
B. Zhong, W. Zheng, R. He, G. Huang andX. Li 2007Silica as an Ammoximation Catalyst for the Production of Cyclohexanone Oxime
D. P. Dreoni, D. Pinelli, F. Trifiro, Z. Tvaruzkova, K. Habersberger and P. Jim... 2011
Kinetics of the Redox Reactions of the 02:Propylene:y-Bismuth Molybdate System:A TAP Reactor StudyD. R. Coulson, P. L. Mills, K. Kourtakis, P. W. J. G. Wijnen, J. J. Lerou and
L. E. Manzer 2015
Partial Oxidation of Propcne in the Presence of Steam
Y. A. Saleh-Alhamed, R. R. Hudgins and P. L. Silveston 2019The Kinetics of Activation of Industrial and Model Iron Catalysts for Ammonia
Synthesis in Dried and Wet AtmosphereA. Baranski, A. Kotarba, J. M. Lagan, A. Pattek-Janczyk, E. Pyrczak andA. Reizer
, . 2023The Modifying Role of Ru, Mo and Rare-Earth Elements (REE) in the Creation of
New Generation of Catalysts Based on Iron HydroxidesR. V. Chesnokova, L. M. Dmytrienko, I. G. Brodskaja, A. M. Alekseev,A. A. Vasilevitch, N. A. Dubyaga and 1.1. Bondartsova 2 027
The Role of Various Modes of Adsorbed CO in Synthesis Gas Conversion on
Lanthanidc Ions Promoted by Supported Pd CatalystsYu. N. Nogin, N. V. Chesnokov and V. I. Kovalchuk 2031
Influence of the Interaction of Support with Active Species on Sintering and Stabilityof Alumina Supported Oxide CatalystsO. A. Kirichenko, M. P. Vorob'cva and V. A. Ushakov 2035
Structural Transformation and Catalytic Behaviors of Rhodium Ternary Oxides
during Calcination and Reduction TreatmentsK. Kunimori, H. Oyanagi, H. Sltindo, T. Ishigakiand T. Uchijima 2039Marked Support Effect of Dispersed Zr02 Catalysts in Propene-Dcuterium Addition
and Exchange Reaction
S. Nailo, M. Tanimoto, M. Soma andY. Udagawa 2043
Acidity Generation of Binary Metal Oxide CatalystsA. Gcrvasini, G.Bellussi, J.FenyvesiandA.Auroux 2047
Effects of Potassium Addition on the Performance of a Nickel/Magnesia Catalyst for
Steam Reforming of Methane
S. Kitabayashi, Y. Ogino, T. Yamazaki andS. Ozawa 2051
Weakening of Hydrogen Poisoning by Sm203 Promoter in Activation of Dinitrogenon Ru/Al203 CatalystY. Kadowah, S. Murata andK.-1. Aika 2055
XANES, EXAFS and Reaction Studies of Some Well-Dispersed Ferric Oxide
CatalysisW. Ji, Y. Kuo, S. Shen, S. Li andH. Wang 2059
C02 Derivatives Adsorbed on Promoted Surfaces
J. A. K. Paul, Y. Shao andO.Axelsson Z063
The Effect of Metallic Promoters on Supported Cobalt CatalystsA.Hoff,E.A.Blckkan,A.HolmenandD.Schanke 2067
The Structure-Activity Relationship of Re207 Metathesis Catalysis Supported on
Phosphated Alumina and Silica-Alumina
R. SpronkandJ. C.Mol , 2071
Modification of the Site Structure of MoS2/y-Al203 Catalysts by Addition of
P, F and Alkaline Elements
O. Poulel, R. Hubaut, S. Kasztelan and J. Grimblot 2075
XVIII
Cerium Oxides Supported on Alumina-Crystallite Structures and Catalytic ActivityM. Haneda, T. Miki, T. Mizushima, N. Kakuta andA. Ueno 2079
The Role of Zirconium Dioxide in the Activation of Water and as the Catalytic Site
for Low-Temperature Steam Reforming over Rh/Zr02A. Igarashi, T. Ohtaka, T. Honnma and C. Fukuhara 2083
Surface Structure and Reactivity of Magnesia-Supported Nickel Catalysts: A Model
SystemA. Parmaliana, F. Arena, F. Frusteri, N. Mondello andN. Giordano 2087
Effect of Tin and Iron Deposition on the Catalytic Properties of Platinum Supportedon GraphiteE. Lamy-Pitara, L.El Ouazzani-BenhimaandJ. Barbier 2091
Properties of a Lalcrite Iron Mineral: Characterization, Catalytic Behavior and
Promoter Effect
M. R. Goldwasser, M. L. Cubeiro, M. J. Perez Zurita andC- Franco 2095
Platinum Catalysts Supported on High Surface Area Molybdenum or TungstenTrioxides for Hydrogenation Reactions
C. Hoang-Van, O. Zegaoui andY. Arnaud 2099
Pt-C Interaction in Catalyst Supported on a Carbon Black Subjected to Different
Heat TreatmentsF. Colotna, C. Prado-Burguete and F. Rodriguez-Reinoso 2103
Mechanism of the Effect of Additives on Catalytic Properties of Palladium
L. N. Edygenova, N. V. Anisimova, A. V. Korolev andD. M. Doroshkevich 2107
Pt-Ge/Al203 Catalysts: Influence ofthe Thermal Treatments and the Redox CyclesJ. A. M. Correa, S. R. de Miguel, G. T. Bawnetti, A. A. Castro and O. A. Scelza
.... 2111
Effect of the Support on the Copper State in Copper-Titanium Oxidation CatalystsT. S. Petkevich, L. Ya. Mostovaya, Yu. G. Egiazarov andN. A. Kovalenko 2115
Effect of Addition of Pd, Co and Pd-Co on Ce02. Syngas Conversion and
Acetaldehyde Reaction
H. Idriss, C. Diagne, J. P. Hindennann, A. Kinnemann andM. A. Barteau 2119
The Role of Electric Field Acting on the Characteristic of Adsorption of Solid
Surface, the Oxygen Adsorption on Tin Oxide Film in an External Electric Field
jR. Zhou 2123
Catalytic Behaviour of LiFe02 Anode for Solid Oxide Fuel Cells
R. T. Baker, I. S. Metcalfe, P. H. Middleton, P. Petrolekas andB. C. H. Steele 2127
Electrochemical Modification of the Activity and Selectivity of Metal CatalysisM. Stoukides, D. Eng, P.-H. Chiang and H. Alqahtany 2131
The Selective Hydrogenation of Acetylene by the Electrochemically PumpedHydrogen over Cu in the Presence of Abundant EthyleneK, Otsuka, T. Yagi andM. Hatano 2135
Solid Electrolytes for in situ Promotion of Catalyst Surfaces: The NEMCA Effect
C. G. Vayenas, S. Bebelis, I, V. Yentekakis, P. Tsiakaras, H. Karasali and
Ch. Karavasilis 2139
Theory and Experiment of Photo-Activation of Catalytic Sites and Active Site-
Support Interactions
O. Novaro and J. Garcia-Prieto 2143
Photocatalytic and Physicochemical Studies on Metallised Titania SystemsB. Viswanathan, U. D. Mary andR. P. Viswanath 2147
Heterogeneous Pholocatalysts: Mechanistic Considerations of PhotocatalyticReductions and Photocatalytic Oxidations on Semiconductor Oxide Surfaces
RJ.Bickley,L.Palmisano,M.SchiavelloandA.Sclafani 2151
De-NOjj-ing Photocatalysis - Excited States of Copper Ions Anchored onto Zeolite
and their Role in Photocatalytic Decomposition of NO at 275 K
M.Anpo, T. Nomura, Y. Shioya, M. Che, D. Murphy and E. Giamcllo 2155
XIX
A Novel Series of Pholocatalysts with an Ion-Exchangeable Layered Structure of
Niobate
K. Domen, J. Yoshimura, T. Sekine, J. Kondo, A. Tanaka, K. Maruya andT. Onishi 2159
Photocatalysis by Coordinatively Unsaturated Rhodium Complex Stabilized on
Porous Glass for Alkane DehydrogenationY. Wada, C. Nakano, Y. Yamauchi andA. Morikawa 2163
Heterogeneous Photocatalysis as a Method of Water Decontamination: Degradationof 2-, 3- and 4-Chlorobenzoic Acids over Illuminated Ti02 at Room TemperatureJ.-C. D'Oliveira, W. D. W. Jayatilake, K. Tennakone, J.-M. Herrmann and
P. Pichat 2167
Investigation of the Electron Transfer Mechanism between Methyl ViologenRadicals and Protons Via a Noble Metal CatalystR. Bauer andH. A. F. Werner 2173
Metal Fibre - A Novel Catalyst Material for Selective Dehydrogenation of Alcohols
B. Zhang, L. Lu, Y.Xiao, D.Jin, J. AlandZ. Zhou 2177
Use of Electron Spectroscopy Methods in the Study of the Structure of Surface
Layers of Hydride CatalystsR. Kh. Ibrasheva, R. G. Baisheva, Z. Kaizi, T. A. Solomina, G. I. Leonova and
K. A. Zhubanov 2181
Shape-Selectivity of Alkali Metals Graphite Intercalation Compounds for CatalyticIsomerization, Hydrogenation and Alkylation of Aliphatic and Aromatic
HydrocarbonsS. Tsuchiya, S. Sakai, M. Kikugawa, T. Mitsuno and Y. Sakata 2185
Activation and Reactivity of Titanium Oxynitrides in Ammonia DecompositionC.H.Shin, G. Bugli and G. Djega-Mariadassou 2189
A Study on the Preparation and Characterization of a NiP CatalystsJ. Shen, Z. Li, Q. Zhang, Y. Chen, Q. Bao andZ. Li 2193
Investigations of Hydrodcnitrogcnation of Quinoline over Molybdenum Nitride
K. S. Lee, J. A. Reimer andA. T. Bell 2197
CO Oxidation, NO Decomposition and NO Reduction by CO on Superconductingand Related Cupralcs/. Haldsz, A. Brenner, M. ShelefandK. Y. S. Ng 2201
The Active Oxygen on the Li/La203 Catalyst Surface and its Catalytic Behavior in
the Oxidative Coupling of Methane"
L. Wang, J. Wang, S. YuanandY.Wu 2205
Oxidative Coupling of Methane over SrO Promoted La^yCaO: A ComparativeStudy of the Kinetics and Mechanism
Y.-D. Xu, L. Yu,J.-S. Huang andZ.-Y. Lin 2209
Oxidative Coupling of Methane over Sol-Gel Magnesium Oxide Catalysts: Effect on
Selectivity to Olefin Formation
R. Gomez, T. Lopez, L. Hcrrera, A. A. Castro, 0. Scelza, G. Baronetti, E. Lazzari,
A. Cuan,M. Campos, E.Poulain, A. Ramirez-Solis and O. Novaro 2213
Influence of the Ion Charge and Coordination State on Catalytic Properties of
Barium Ferroniobale for Methane Oxidation
D. Filkova, I. Mitov, L. Petrov, V. Bychkov, M. Sinev, Yu. Tulenin and P. Shiryaev . .2217
Reaction Performances of Methane Oxidative Coupling Along Catalyst Bed with
Sm-CaO CatalystC. Tang, L. Lin, Z. Xu andJ. Zang 2221
Effect of Pressure on the Methane Oxidative Dimerization
Yu. P. Tulenin, A. A. Kadushin, V.A. Seleznev and A. F. Shestakov 2225
XX
Methane Oxidative Coupling over Complex Metal Oxides Possessing K2NiF4 and
Related Structure
Q. Yan, Y. Jin, Y. Wang, Y. Chen andX. Fu 2229
Oxidative Coupling of Methane over PbO/PbAl204 CatalystsS.-E. Park andJ.-S. Chang 2233
Characterization of TiLaNa Catalysts in the Oxidative Coupling of Methane
S. Rossini, S.-T. Brandao, O. Forlani, L. Lietti, A. Santucci, D. Sanfilippo and
P. Villa 2237
Catalytic Properties of Ca-Doped La203 Catalysts for Coupling of Methane
X. Yang, Y. Bi, K. Zhen andY. Wu 2241
Synergy between High Temperature Stable Carbonates and Irreducible Oxides:
Destruction of Non-Selective Surface Oxygen on Oxidative Coupling of Methane
CatalystsJ.-L. Dubois andC. J. Cameron 2245
Laser Stimulated Oxidative Coupling of Methane to Ethenc on LiCl04/Pb3(P04)2S-H. Zhong andH-Q. Ma '. 2249
Temperature-Programmed Studies of Surface Oxygen Species in the Oxidative
Coupling of Methane
G. W. Keulks, N. Liao, W. An andD. Li 2253
Oxidative Dimerization of Methane on Alkali Chloride Promoted Co304M. Gratzel, D. Klissurski, J. Kiwi andK. R. Thampi 2257
Oxidative Coupling of CH4+CD4 Mixture over Manganese Oxide CatalystsY. G. Borodko andL. M. loffe 2261
A Comparison of the behavior of Catalysts for Methane Coupling by Transient
AnalysisR. Spinicci andA. Tofanari 2265
Oxidative Coupling of Methane to C? Hydrocarbons over Doped Titania CatalystsD. Papageorgiou, D. VamvoukaandX. E. Verykios 2269
The Importance of Carbon Dioxide in Oxidative Coupling of Methane
A. Machocki 2273
Kinetic Effects in Conversion of Propane, Isobutane and Propane-Isobutanc Mixtures
on K-Pt/Y-A^OgCatalysts, Modified by Sn and In
L. C. Loc, H. S.'Thoang, N.A. Gaidai andS. L. Kiperman 2277
The Reaction of Reduction Catalyzed by Homogeneous and Immobilized Binuclear
Rh(II) Complexes with Rh-Rh Bond
V. Z. Sharfand V. L Isaeva 2281
A Highly Active, Heterogeneous Hydroformylation Catalyst: Rh(CO)(acac)L,L==poly-TRIM Bound PhosphineJ. Hjortkjaer, B. Heinrich, C. Andersson andA. Nikitidis 2285
Selective Hydrogenation of C4 - Acetlylencs over an Ion-Exchanged Copper on
Silica CatalystJ. T. Wehrli, D. J. Thomas, M. S. Wainwrighl, D. L. Trimm andN. W. Cant 2289
Chiral Metal Transition Complexes in Zeolites: Enantioselective Hydrogenation of
Dehydrophenylalanine DerivativesA. Corma, M. Iglesias, C. del Pino and F. Sdnchez 2293
Selective Vapor Phase Hydroformylation of Olefins over Cluster-Derived Cobalt
Catalysts Promoted by Alkaline Earth Oxides
K. Takeuchi, T. Hanaoka, T. Matsuzaki, Y. Sugi, M. Reinikainen andM. Huuska...
2297
Design of Platinum Based Metallic Catalysts for Selective Hydrogenation of
CrotonaldehydeA. Jentys, C. G. Raab andJ. A. Larchcr 2301
1,3-Butadiene Hydrogenation in 1-Butene over Alumina Supported Pd-Ag Catalysts/. W. Hightower, B. Furlong, A. Sdrkdny andL. Guczi 2305
Oxidative Dehydrogenation of Propane in Presence of Rare Earth VanadatesJ. Castiglioni, P. Poix andR. Kieffer 23ngReactions of Cyclopropane and 1-Butene over Reduced Molybdena-AluminaCatalystsI. Oliveros, C. Bolivar, P. Marcano, C. Scott, M.J. Perez Zurita andJ. Goldwasser
. . 2313Effects of Mixtures of Modifiers on Optical Yield in EnantioselectiveHydrogenation: a Test of the Template Model
K. E. Simons, P. A. Meheux, A. Ibbotson and P. B. Wells 2317Ni/M Type Bimetallic Reducing SystemsZs. Bodnar, T. Malldt and J. Petro 2321New Aspects on the Mechanism of Olefin Polymerization with Reduced PhilippsCatalystsH. L. Krauss, H.A. Schmidt, B. Siebenhaar, P. Wolff and Q. Xing 2325The Role of Porosity in Ethylene Polymerization on Cr/Si02 Catalysts/. G.DallaLana,J.A.SzymuraandP.A.Zielinski 2329Partial Hydrogenation of Alkynes and Dienes on Highly Selective Fe-Cu/Si02Catalystsy. Nitta, Y. Hiramatsu, Y. Okamoto and T. Imanaka 2333
Supported Dehydrogenation Catalysts Based on Iron OxideD. E. Stobbe, F. R. van Buren, A. J. vanDillen and J. W. Geuss 2337
Sulfur Resistance of Nickel Catalysts Supported on K-Clinoptilolite Containing Ironin Ethylbenzene HydrogenationA.Arcoya,X.L.SeoaneandJ.Soria 2341
Heterogeneous Ethylene Hydroformylation Catalyzed by Oxide-Supported[Rhi2(CO)30]2' Anion: Influence of the Nature of the SupportC. Dossi, A. Fusi, L. Garlaschelli, R. Psaro andR. Ugo 2345Isolated and Competitive Hydrogenation to Characterize Ni-B CatalystsG. Jannes, P. Kerckx, B. Lenoble, P. Vanderwegen, C. Verlinden and
J.P. Puttemans 2349The Role of Surface Fugacities and of Hydrogen Desorption Sites in CatalyticReactions of Alkancs
E. Iglesia, J. E. Baumgartner and G. D. Meitzner 2353
Heterogeneous Catalysis of a-Octene Hydroformylation. the Catalytic Behaviors of
Non-Homodisperse EGG-Shell CatalystsW. Huang, L.-H. Yin andC.-Y. Wang 2359
Hydroformylation of Ethylene over Silica-Supported Pt/Sn CatalystsP. Ramirez de la Piscina, J. L. G. Fierro, G. Muller, J. Sales andN. Horns 2363
Kinetics of 2,2,3,3-Tctramethylbutane Hydrogenolysis over Rh/Al203 CatalystsB. Coq, T. Tazi, R. Dutartre andF. Figueras 2367
Surface Organomctallic Chemistry on Metals: Role of a Surface OrganometallicFragment Sn(n-C4H9)x on the Selective Hydrogenation of Citral with a Rh/Si02CatalystB. Didillon, A, El Mansour, J. P. Candy, J. M. Basset, F. Le Peletier and
J. P. Boitiaux 2371
Hydrogenolysis of Melhylcyclobutane on Supported Pt Model CatalystsC. Zimmermann and K. Hayek 2375
Preparation of Egg-Shcll Type Pd-Ag and Pd-Au Catalysts by Selective Depositionand Hydrogenation of 1,3-ButadieneH. Miura, M. Terasaka, K. Oki and T. Matsuda 2379
Hydrogenation and Deuteration of Butadiene and Cyclohexadiene over Reduced and
Sulfided Molibdena-Alumina
A. Re-dey, D. SmrzandW. KHall 2383
Hydrocracking Boscan Heavy Oil with Unimodal and Bimodal CatalystsM, Ternan andJ. Menashi 2387
XXII
A Kinetic Model for Aromatization Processes over ZSM-5 Catalysts. Aromatization
of Short Chain Hydrocarbons over HZSM-5
D. B. Luk'yanov, V. I. Shtral, V. I. Timoshenko andS. N. Khadzhiev 2391
On the Role of Reversible and Irreversible Adsorption Hydrogen in the
Dehydrogenation and Reforming Reactions
y. Sun, S. Chen andS. Peng 2395
Catalyst Design for the Upgrading of Australian Coal-Derived LiquidsA. T. Townsend and F. P. Larkins 2399
The Use of Intcrmelallic Hydrides on Basis Lanthan with Nickel and Cobalt for
Hydrogenation of Asphaltenes ConcentrateN. M. Parfenova, I. M. Halperin, S. R. Sergienko, V. A. Pherapontov and
E. V. Starodubtzeva 2403
n-Hexane Isomerization and Aromatization on the Catalysts Derived from Alumina-
Supported Pt-Sn ClustersX. Li, Y. Wei, J. Cheng andR. Li 2407
The Effect of Rhodium Particle Size on n-Butane Hydrogenolysis Activity and
SelectivityD. Kalakkad, S. L. Anderson andA. K. Datye 2411
Pretrcalment Effects on Active Stale and Aromatization Activity of Ga/ZSM-5
CatalystsK, M. Dooley, C. Chang, V. Kanazirev and G. L. Price 2415
New Modification Method of Pt/L Zeolite Catalyst for Hexanes Aromatization
H. Katsuno, T. Fukunaga andM. Sugimoto 2419
High Temperature Sensitivity of Paraffin HydrocrackingR. T. Hanlon, C. R. Kennedy, R. A. Ware andS. S. Wong 2423
Effect of Modification of ihe Alumo-Platinum Reforming Catalyst with Dy, Cr, Baand Nytrogen on its Catalytic and Physico-Chemical PropertiesG. M. Sen'kov, E. A. Skrigan, E. A. Paukshtis, M. F. Gorbatsevich, A. M. NikitinaandE. N. Ermolenko 2427
Transformation of Propane over Ga/HZSM-5 Catalyst: On the Nature of the Active
Sites for the Dehydrogenation Reaction
P. Meriaudeau andC. Naccache 2431
Study of the Selective Semi-Hydrogenation of Various Carbon-Carbon Triple Bondsover a Pd/Sepiolite CatalystM. A. Aramendia, V. Borau, C. Jimenez, J. M. Marinas, M. E. Sempere, F. J. UrhanoandL. Villar 2435
n-Arylhydroxylamines Transformation in the Presensc of Heterogeneous Catalysis/. A. Makaryan and V. I. Savchenko 2439
Highly Efficient Enantio-Differentiating Hydrogenation Catalyst Prepared from
Ultrasonicated Raney Nickel by Asymmetric ModificationA. Tai, T. Kikukawa, T. Sugimura, Y. Inoue, S. Abe, T. Osawa and T. Harada 2443
New Vapor Phase Process for Synthesis of Ethylenimine by Catalytic Intramolecular
Dehydration of MonoethanolamincM. Ueshima, Y. Shimasaki, K. Ariyoshi, H. Yano andH. Tsuneki 2447
Catalyst for Vinyl Chloride SynthesisN. A. Prokudina, V. V. Chesnokov, B. P. Zolotolvskii, L. N. Yelesina,V. G. Yenakaeva and V. F. Tarasov 2451
A New Process for Production of 1,3-DimelhyladamantaneK, TakagiandY. Naruse 2455
Palladium Based Catalysts for Hydrogenation of Nitrobenzene
E. Brazi, G. Cordier and G. N. Sauvion 2459
Modification of Pd and Pt by Thiophene and Carbon Tetrachloride duringHydrogenation and Isomerization of (+)-ApopincneG. V.Smith, F. Notheisz, A. G. ZsigmondandM. Bartdk 2463
Selective Hydrogenation of Carbonyl Groups by Means of Hectorite-IntercalatedRhodium ComplexesS. Shimazu, T. Chiaki andT. Uematsu
2467Enantioselective Hydrogenation of cc-Keto Esters over Pt/AUO-j Catalyst: kineticAspects of the Rate Acceleration Effect Induced by Addition ofCinchonidine/. L. Margitfalvi, B. Minder, E. Tdlas, L. BotzandA. Baiker 2471Crolonaldehyde Hydrogenation over Pt/Ti02 Catalysts. Influence of the CatalystsPretreatments
R. Makouangou, A. Dauscher andR. Touroude 2475Selective Hydrogenation of a,p-Unsaturated Aldehydes over Supported RuA. Waghray, R. Oukaci andD. G. Blackmond
2479Hydrogenolysis of Telrahydrofurane on PlatinumK. Kreuzer andR. Kramer
2483Influence of Polymer Support Morphology on Ion-Exchanger Catalysts Activity intort.-Alky1-Methyl Ethers SynthesisK. Jerabek, T. Hochmann andZ. Prokop 2487Mechanism of Catalytic Organic Solid-Gas ReactionsR. Lamartine, F. SabraandA. Selatnia
2491Infrared Study ofCoke Deposition on AluminaJ. Dalka andR. P. Eischens
2495Hydrogen Surface Concentration Effect on the Temperature-ProgrammedHydrogenation of Adsorbed Carbonaceous Species on an Iron/Alumina CatalystH. Halaft, E. Borgstedt, A. M. Efstathiou, S. L. Suib andD. Bianchi 2499FTIR and Catalytic Studies of the Effects of Sulphur Poisons on Cu/Al203 CatalystSelectivityM. B, Padley, C. H. Rochester, G. J. Hutchings, P. I. Okoye and F. King 2503Enhancement of the Stability of PtSn Catalysts in Regeneration Cycles by A1203Doping with Rare-Earth OxidesK Fan, L. Lin, J. ZangandZ. Xu
2507Development of a New Catalyst for the Hyd reconversion of Heavy OilsM. M. Ramirez de Agudelo and C. Galarraga 2511Molecular Poisoning of Ni/Si02 Catalyst. A Magnetic and Catalytic Study of theEffect of Thiophene, Carbonyl Sulfide and Carbon Disulfide AdsorptionJ. B. Baumgartner, R. Frety andM. Guenin 2515Effect of Sintering in 02 Atmosphere on the Surface Properties of PtRh/Al203CatalysisS. Kacimi, C. Kappenstein andD. Duprez 2519Coke Deposits on Pl/Al203 Catalysis: FTIR and HRTEM StudiesL. Marchese, E. Borello, S\ Coluccia, G. Martra andA. Zecchina 2523Molecular Orbital Study of the Chemisorption of Small Molecules on MgO SurfacesH. Kobayashi, A. St. Amant, D. R. Salahub andT. ho 2527
Applications of a New Isothermal Single Pellet Diffusion Reactor5. S. Au, J. B. Butt andJ. S. Dranoff 2531
Coke Elimination from Pt-Re/Al203 by Ozone Containing MixturesC. L. Pieck, E. LJablonski andJ. M. Parera 2535New Model of Deactivation of Iron Catalysis for Ammonia SynthesisW. Arabczyk andK. Kalucki 2539
Pore Restriction in Resid Hydrolreating CatalystsP.-S. E. DaiundB. 11.Barllcy 2543
Effect of the Internal Mass Transfer Resistance on the Ni/Al203 Deactivation byThiopheneS. Zrncevic and V. Tomasic 2547
A Study of Coke Formation in Resid Catalytic CrackingT.C.Ho 2551
XXIV
Selective Hydrogenation of Adiponitrile (ADN) to Hexamethylenediamine (HMD)in the Liquid Phase on Raney Catalysts: Synergetic Effect between the Base in the
Solution and the Iron Dope on the CatalystJ. F. Spindler, G. Cordier,J.JenckandP.Fouilloux 2555
Acid Resistant Copper Chromium Oxide Catalysts Used in the Hydrogenolysis of
Fatty Acids
K. Kochloefl, G. Maletz, G. Hausinger andM. Schneider 2559
Synthesis of Anthraquinones by Cyclization of Ortho-Benzoylbenzoic Acids in the
Presence of Solid Acid CatalystsS. A. Amitina and V. G. Shubin 2565
Acid-Base Properties of Sulfided Ni-Mo-Y Zeolite Catalysts for Water-Gas Shift
Reaction
M. Laniecki and W. Zmierczak 2569
Investigation on Adsorption and Acid-Base Properties of Solid Catalysts by Infrared
ThermographyS.Marengo, G. Raimondini and P. Comotti 2573Nature of the Extra-Framework Aluminum in MFI Type Zeolites Synthesized inFluoride Medium. Influence on the Catalytic Properties of Zeolites
Q. Chen, J. L. Guth andJ. Fraissard 2577
Boron - an Acidity and Texture Modifier for Alumina Supported CatalystsS. Engels, E. Herold, H. Lausch, H. Mayr, H.-W. Meiners andM. Wilde 2581
Sulfate-Modified Superacid Zr02 Catalysts: Study of the Surface Acidity and of the
Activity towards Alcohols
C. Morterra, G. Cerrato, C. Emanuel andV. Bolis 2585
Highly-Dispersed Heteropoly Anions on Metal Oxide Carriers Modified with Silane
Coupling Agents and their Catalytic Propertiesy. Kera, H. Nishizima andM. Kamada 2589New Catalytic Systems: Heteropolyanions Doped Conjugated Polymers as the
Catalysts for Ethyl Alcohol ConversionJ. Pozniczek, I. Kulszewicz-Bajer, M. Zagorska, M. Hasik, A. Bielanski and
A. Pron 2593
Effects of Thermal Treatment on Surface Properties and Catalytic Activities of a
Prepared TiO?-Zr02 CatalystJ. A. Navio, M. Macias, F. J. Marchena, J. M. Campelo andJ. M. Marinas 2597
Gas Phase Synthesis of MTBE over Acid ZeolitesA. Nikolopoulos, T. P. Palucka, P. V. Shertukde, R. Oukaci, J. G. Goodwin, Jr. and
G. Marcelin 2601
Acidity-Tunable Pillared Mica Catalyst Derived from TalcK. Urabe, I. Kenmoku, K. Kawabe andY. Izumi 2605Beckmann Rearrangement over Solid Acid CatalysisT. Curtin, J. B. McMonagle andB. K. Hodnett 2609
Synthesis of Solid Superacids of Tungsten Oxide Supported on Tin Oxide, TitaniumOxide and Iron Oxide and their Catalytic ActionK. Arata andM. Hino 2613Effect of the Method of Platinum Inclusion into Spherical Promoter of CatalyticCracking Termofor on its Activity in CO Combustion
M. I. Levinbuk, V. B. Melnikov, H. K. Shapieva, V. I. Vershinin, V. A, Kuz/nin andV. Je. Varshaver 2617
Cooxidation CO and H2on Palladium CatalystN. A. Boldyreva and V. K. Yatsimirsky 2621The Structure of Supported Pd, Kinetics and Mechanism of the Low-TemperatureOxidation of Carbon Monoxide
S. N. Pavlova, V. A. Sadykov, D. I. Kochubei, B. N. Novgorodov, G, N. Kryukova andV. A. Razdobarov 2625
Transition Metal Compound Oxide Catalysts for Lowering the LightOff-Temperature of Particles from Diesel ExhaustC. Setzer, W. SchutzandF. Schilth 2629FTIR Study of Reduction Mechanism of NO by C2H4 and'c3Hg on' VanadiumOxides Layered on Zr02T. Ohno, F. Hatayama, T. Maruoka andH. Miyata 2633The Selective Catalytic Reduction of Nitrogen Oxides with Ammonia in a
Catalytically Active Ljungstroem Heat ExchangerH.-G. Lintz andT. Turek
2637Evaluation of Nitrous Oxide Formation over Rhone-Poulenc's DN 110 SCR CatalystE. Garcin andF. Luck 2641
Catalytically Accelerated Solid-Gas Reaction between NO and Ba-Cu-6 forEfficient NO Removal
M. Machida, S. Ogata, K. Yasuoka, K Eguchi andH. Aral 2645Catalytic Property of Perovskite-Type Oxides for the Direct Decomposition of NitricOxide
Y. Teraoka, T. Harada, H. Furukawa andS. Kagawa 2649TPD-Analysis of Metallic Three-Way Catalysts. Effect of Zr, Si, La and Ba on
Thermal AgingM. Huuska andT. Maunula
2653Mechanistic Studies of CO Oxidation on Highly Dispersed Gold Catalysts for Use in
Room-Temperature Air PurificationM. Haruta, S. Tsubota, T. Kobayashi, A. Ueda, H. Sakurai andM. Ando 2657
Low-Temperature Oxidation of Light Paraffins and Olefins at Solid Surfaces: FT-IR
Studies
G.Busca, V. Lorenzelli, G. Ramis and V. S. Escribano 2661
Catalytic Diesel Engine Emission Control, - Studies on Model Reactions over a
EUROPT-1 (Pt/SiCM CatalystE. Xue, K. Seshan, f.G. van Ommen andJ. R. H. Ross 2665
Carbon-Oxygen Reaction on Cu/V/K Catalyst for Soot Oxidation
P. Ciambelli, V. Raima andS. Vaccaro 2669Kinetics of the Selective Catalytic Reduction of NO by NH3 over a Commercial
CatalystW. R. A. M. Robinson, J. G. van Ommen, A, Woldhuis andJ. R. H. Ross 2673
Selective Catalytic Reduction of NO on Copper-on-AJumina in the Cleanup of HighSulfur Content Flue Gas: Catalyst Development and DesignG. Centi, N. Passarini, S. Perathoner, A.Riva 2677
The Role of N02 in the Selective Catalytic Reduction of NOx/. Blanco, P. Avda andJ. L. G. Fierro 2681
Catalysts for the Elimination of Sulphur Dioxide from Streams by the Claus Reaction
at Low TemperatureE.Alvarez, A. Mendioroz andJ. M.Palacios 2685Promoter Effects on Platinum Catalysts for Automotive Exhaust Control/. R. Gonzalez-Velasco, J. Entrena, J. A. Gonzalez-Marcos, J. I. Gutierrez-Ortiz and
M. A. Gutierrez-Ortiz 2689
Correlation of Bulk and Surface Thermodynamics of some Transition Metal Oxides;Application to Exhaust Gas CatalystsA. D, van Langeveld, A, C. T. van Duin, J. W. Bijsterbosch, F. Kapteijn and
J. A. MoulijnCoadsorption and Reaction of NO and CO on Cu/Al203 CatalystsR. Hierl, H.-P. Urbach andH. KntSzingerActivity and Electronic Properties of Automotive Emission Control CatalystsB. H. Engler, D. Lindner, E. S. LoxandP. Albers 2701
XXVI
Alumina Supported Manganese Catalysts for Low Temperature Selective CatalyticReduction of NO with NH3L. Singoredjo andF. Kapteijn 2705
Reduction of Nitric Oxide by Carbon Monoxide on Palladium Based Bimetallic
CatalystsJ. Massardier, A. ElHamdaoui, G. Bergeret andA. Renouprez 2709
Activity and Characterization of Palladium Catalysts for Nitric Oxide DecompositionA. Ogata, A. Obuchi, K.Mizuno,A. OhiandH. Ohuchi 2713
Effect of Calcination on V-O-Ti-P CatalystsJ. Soria, J. C. Conesa, M. Lopez-Granados, J. L. G. Fierro, J. F. Garcia de la Banda
andH. Heinemann 2717
Methanol Synthesis over Copper Based Catalysts: Comparison of Co-Precipitated,Raney-Type and Catalysts Derived from Amorphous Alloy Precursors
A. C.Sofianos,J.Heveling,M.S.ScurrellandA.Armbruster 2721
Activity and Selectivity of Ruthenium-Cobalt Bimetallic Catalysts in Carbon
Monoxide HydrogenationS. A. Korili andG. P. Sakellaropoulos 2725
Surface Kinetics and Periodic Operation of Higher Alcohol SynthesisJ.-L. Li, Q.-M. Zhu, J.-L. Hu andN.-J. Yuan 2729Mechanism of Selective CO Hydrogenation to Isobutenc over Oxide CatalystK. Maruya, A. Takasawa, T. Haraoka, M. Aikawa, T. Arai, K. Domen and
T. Onishi 2733
Conversion of CrC4 Alcohols into Aromatics on the Modified ZSM-5 Zeolites.
Active Centres and Reaction PathwaysD.-Z. Wang, J.-Y. Wang andX.-D. Lu 2737Activities and Selcctivities of Supported Co-Ru, Co-Pd and Co-Pt Bimetallic
Catalysts in Fischer-Tropsch SynthesisM. P. Kapoor, A. L. Lapidus and A. Yu. Krylova 2741New Ternary Cu-V-Zn Catalyts for Conversion of C02 by H2 into Methanol
N. Kanoun, M. P. Astier, F. Lecomte, B. Pommier and G. M.Pajonk 2745Alkali-Promoted MoS2 Catalysts for Alcohol Synthesis: The Effect of Alkali
Promotion and Preparation Condition on Activity and SelectivityH. C. Woo, T. Y. Park, Y. G. Kim, In-S. Nam, J. S. Lee andJ. S. Chung 2749
New Alkenc Oligomerization Catalyst NiS04/y-Al203 and its Characteristics
T. Cai, D. Cao andL. Li 2753
Catalytic Properties of Partially Reduced Fc/Si02 in CO HydrogenationS. H. Moon, C. W. Park andH. K. Shin 2757
Hydrogenation of Carbon Monoxide over Rh/Zr02 Catalysts Promoted byMolybdenum Oxide
£. Guglielminotli, E. Giamello, F. Pinna, G. Strukul, S. Martinengo and
L. Zanderighi , 2761
Identifying the Reaction Network of the Higher Alcohol Synthesis over Alkali-
Promoted ZnCrO CatalystsL. Lietti, E. Tronconi and P. Forzatti 2765Effects of Formic Acid and C02 in CO Hydrogenation to Methanol over Copper-Based Catalysis and Nature of Active Sites
J. Cai, Y. Liao, H. Chen andK. R. Tsai 2769
Comparison of ZnO-Supported Cu, Cu-Mn, Cu-Fc, Cu-Co and Cu-Ni Catalysts in
CO HydrogenationP. A. Sermon, M. A. M. Luengo (Yates) andY. Wang 2773Methanol Synthesis from C02 and H2 over Supported Copper-Zinc Oxide Catalyst.Significant Influence of Support on Methanol FormationH. Arakawa andK. Sayama 2777
XXVII
C02 Hydrogenation over Platinum Group Metals Supported on Ce02: Evidence for a
Transient Metal-Support Interaction
A. Trovarelli, G. Dolcetti, C. deLeitenburgandJ. Kaspar 2781Potassium Promotion of Cu-ZnO-Al203 Catalysts for Higher Aicoho'l Synthesis'/. Boz, D. Chadwick, I. S. Metcalfe andK. Zheng 2785Conversion of Syngas to Aromatic Hydrocarbons on Coball-Manga'nese-ZcoliteCatalysisG. Bixurle, K. Guse, M. Lohrengel andH. Papp 2789
Light Olefins Formation from Syngas over ZrO?-ZnO CatalystsW. Zhang, R. Gao, G. Su and Y.Yin 2793
High Selectivity of Diesel Fraction in Fischer-Tropsc'h Synthesis with Co/Nb205A. Frydman, R. R. Soares andM. Schmal 2797The Catalytic Behavior of Some Zr-Ni-Co-Cu-Ru Intermetailic Compounds inFischer Tropsch Reactions
I. R. Harris, I. T. Caga, A. Y. Tata andJ. M. Winterbottom 2801
X-Ray Powder Diffraction In Situ Characterisation of the (Cu, Zn, Al)-HydrotalcitePhase in Cu-ZnO-Al2OrCatalysts Highly Active in Methanol SynthesisK. Richter, W. Kraus, G. Nolze andB. Peplinski 2805
Catalyst Component Interactions in Ag-Cu/ZnO/Al203 Catalyst for Carbon
Oxygenate SynthesisE. Kis, G. Lomic, G. Boskovic, R, Neducin and P. Putanov 2809
Cobalt Reducibility and Magnesium Promotion in Silica-Supported Fischer-TropschCatalystsI.Puskds, T. H. Fleisch, J. B.Hall, B.L.Meyers andR. T.Roginski 2813Transient Response Study of the Oxidation and Hydrogenation of Carbon Monoxide
Adsorbed on Pd/Al203G. Kadinov, S. Todorova andA. Palazov 2817
Higher Alcohol Synthesis over Functionalized Solid-Base Catalysts from Methanol
as a Building Block
W. Veda, T. Ohshida, T. Kuwabara andY, Morikawa 2821
In Situ *H NMR Study of the Adsorption of Hydrogen and Formic Acid on CopperBased Methanol Synthesis CatalystsA. Bendada, J. B. C. Cobb, B. T. Heaton andJ. A. Iggo 2825
Isomcrisation of Long-Chain n-Alkancs on Pt/H-ZSM-22 and Pt/H-Y Zeolite
Catalysts and on their Intimate Mixtures
/. A. Martens, L. Vytterhoeven, P. A. Jacobs and G. F. Froment 2829
Kinetics of Bimodal Grain Size Distribution of a Ni Catalyst During Hydrogenationof CO
M. Kolb, M. Agnelli and C. Mirodatos 2833
Critical Point Properties of the Surface Structure During CO Oxidation
M. Kolb 2837
Selectivity Effects Related with Reaction Mechanism and Diffusion Limitations over
Deactivating CatalystsK. Kumbilieva, S, L Kiperman andL. Petrov 2841
Author index 2845
Studies in Surface Science and Catalysis (other volumes in the series)