Insensitive Munitions Analytical Compliance System (I · PDF fileCommunication. Options. ......

Insensitive MunitionsAnalytical Compliance System

(I-MACS) Concept

UNCLASSIFIED. APPROVED FOR PUBLIC RELEASE.

George R. Thompson, Ph.D.Chemical Compliance Systems, Inc.

Lake Hopatcong, NJ

2007 Insensitive Munitions & Energetic Materials Technology SymposiumMiami, FLOctober 16, 2007

CCS

Insensitive Munitions(OSD & NATO)

“…munitions which reliably fulfill their performance, readiness and operation requirements on demand, but which minimize the probability of inadvertent initiation and severity of subsequent collateral damage to weapon platforms, logistic systems, and personnel, when subjected to unplanned stimuli.”

BENEFITS

• Enhanced survivability of logistical and tactical systems

• Reduced risk of injury to personnel

• Applicability across services/platforms

• More efficient to transport, store and handle

• More cost effective

Insensitive Munitions Analytical Compliance System (I-MACS) Concept

CCS Chemical Compliance Systems, Inc.

Historic Incidences(Four Aircraft Carrier Accidents in 1966, 1967, 1969 & 1981)a

Lives Lost

Injuries

Aircraft Lost

Aircraft Damaged

Potential Total $ Savings

220

709

42

72

72

132

10

12

67

81

76

83

$148M

577M

32M

60M

$1.4B

ACTUALSTATISTICS

IM MUNITIONEST’D % ↓

EST’D SAVINGS

________________a From 1991 CNA Study



Munitions Life Cycle Unplanned Stimuli

RIPLost Lives

Personal

Injuries

Damaged

Facilities


Dropping

Temperature(FCO, SCO)

Penetration(FI, BI)

Pressure

Incompatibility

SympatheticDetonation

HumidityVibrationLeakage Aging


Storage

Usage

Demilitarization

Research &Development

Shipping

Manufacturing

MUNITIONLIFE CYCLE

Sources of Weapon System VulnerabilitiesInsensitive Munitions Analytical Compliance System (I-MACS) Concept

ExternalStimuli

InternalConstituentSensitivities

IncompatibleConstituentProximity


IMIM

ChemicalIncompatibilities

CHEMICAL CAS #&

SYNONYM DICTIONARY

CHEMICAL CAS #&

SYNONYM DICTIONARY

Enthalpy

ParticleSize/Form

PhysicalState

HazardClassification

Heat ofFormation

Entropy

Ammo & ExplosivesCompatibility Groups

Vapor Pressure

SpecificGravity

Density

HeatCapacity

EnergeticFamily

CHEETAHCalculated

Temperature/Pressure


CorrosivityGradeConductance

CorrosionSusceptibility

Static ChargeAccumulation

Sensitive Constituents Database Endpoints


Incompatible Chemical Proximity Database

LocationsEnhancedMIDAS

INCOMPATIBLEMUNITION

CONSTITUENTS

AgingImpact

Improved DesignBarriers/Buffers



Hurdles for Developing Insensitive MunitionsInsensitive Munitions Analytical Compliance System (I-MACS)

1. The problem is extremely complex

2. IM is only one of the problems

3. Some test protocols are not standardized

4. Some IM test results are not standardized, nor shared

5. IM Test Data must be secure

6. Incident “Root Cause” Analyses are not in a database

1. Utilize “outside the box” thinking

2. Start — Integrate — Enhance

3. Begin with a standardized data repository

4. Develop a Centralized Database--require submissions

5. Obtain DoD & NSA clearance for I-MACS Security

6. Develop a chemical-based “Root Cause” for each incident

“HURDLE”“HURDLE” SOLUTIONSOLUTION


5Chemical Security Risk List

Precursor Chemical Security Risk ListTheft & Population Risks

Accessibility Factors

12650 Total Regulations

LocalState

FederalInternational

Non-governmentCorporate or Trade Association

12 Regulations12 Regulations

11 Radioisotopes11 Radioisotopes

10 Bioterrorism Agents10 Bioterrorism Agents

9 Agent Simulants9 Agent Simulants

8 Chemical Agents8 Chemical Agents7 Munitions – Midas7 Munitions – Midas

6 Biobased Ratings6 Biobased Ratings

5 Security Factors5 Security Factors

4 Green Criteria4 Green Criteria

3 Commercial Products3 Commercial Products

2 Alternative Chemicals2 Alternative Chemicals

1 Chemicals1 Chemicals

CCSCENTRALIZED

DATABASE

CCSCCSCENTRALIZEDCENTRALIZED

DATABASEDATABASE

1Cross-Reference DictionaryChemical Compound Dictionary

Chemical AlternativesToxicology Data

Holistic Hazard RatingsPersonal Protective Equipment

SAF-T-LABEL©Safe Storage CodesSafe Disposal Codes

Alloy ConstituentsEmergency ResponseElemental Composition

IncompatibilitiesPhysical/Chemical Parameters

239 Generic Categories, e.g.,

Solvents Reducing AgentsAcids SurfactantsBases BindersOxidizers AlloysAntioxidants Metal Compounds

80 Subcategories3

Product DescriptionsProduct Components

MSDS ImagesMSDS Index

Generic CategoriesManufacturersUser Director

ProcessesGreen Ratings

Corrosive RatingsBiobased Ratings

443 Endpoint Criteria

Ecological—Air, Water, SoilHealth—Acute, Chronic

Safety—Fire, Reactivity, SpecialChemical-based

Objective & Quantitative

7Munitions Characterization—MIDAS

Demil ProcessesConstituent ChemicalsChemicals Released

Green CriteriaInsensitive CriteriaCorrosive CriteriaPackaging Criteria

Transportation/Storage FactorsReliability Factors

Hazardous Waste FormsRegulations

8/9Properties

Toxicology DataHazard Issues

IncompatibilitiesStorage Recommendations

TICs/TIMs10

20+ AgentsDisease Descriptors

PathogenesisProphylaxis

Emergency ResponseDecontamination

Treatment11Generic Families

PropertiesEffects & Actions

Storage & SecurityDiagnosis & Treatment

DecontaminationEmergency Response

613 Endpoint Criteria

Biomass ScoreRegulatory ScoreEconomic Score

The CCS Relational Chemical & Product Database (R–CPD)


Insensitive Munitions Analytical Compliance System (I-MACS)

CCS Capabilities

BIOLOGICAL HOMELANDSECURITY SYSTEM

[B-HoSS]

CHEMICAL HOMELANDSECURITY SYSTEM

[C-HoSS]

BIOLOGICAL HOMELANDSECURITY SYSTEM

[B-HoSS]

RADIOLOGICAL HOMELANDSECURITY SYSTEM

[R-HoSS]

MUNITIONS ANALYTICALCOMPLIANCE SUITE

[MACS]

CENTRALIZED CHEMICAL HAZARDand ENVIRONMENTALMANAGEMENT SUITE

[C-CHEMS]

ISO 14001 EMS

Web-based ISO 14001 System

reduces implementation

time and cost by 300-400 manhours

ISO 14001 drawsregulatory data

(Air, Water, etc.)to expedite compliance,highlight conformance

and reduce wastestreams

SecureWeb Access

Options

GISData

Sources

SensorDataInput

WirelessCommunication

Options

Regulations

Bioterrorism Agents

Radioisotopes

Security Factors

Agent Simulants

Chemical Agents

Chemicals

Munitions –

MIDAS

Commercial Products

CCSCentralizedDatabase



MACS–3Theoretical

Compliance Analyses(Web)

MunitionLife CycleMLCMT(Concept)

ARASAmmo Reliability

(Concept)

TRACSHazardous Waste

(Web)

I–MACSInsensitive Munitions

(Proposal)

MACS–PODS(Client–Server)

INC-FRCS(Web)

MACS–1Demil(Web)

DispersionRISK(Web)

MACS–4Sources & Shortages

(Proposal) MACS–5Manufacturing

(Proposal)

C–MACSCorrosives(Proposal)

GreenEnergetics

(Proposal)

GreenLife Cycle(Concept)

G–MACSGreen Munitions

(Web)

U–MACSUXO Remediation

(Concept)

MACS–2Ranges

(Web)

RATSRange

Assembly(Concept)

Modules currently available on the World Wide WebModules currently with submitted proposals Modules currently available as a client–server system

Modules in the defined concept stage

MACS–6Storage & Packaging

(Concept)

Munitions Analytical Compliance Suite (MACS)

MACS–COCChemicals of Concern

RDX

MACS–ERAEmission Risk

(Web)

MACS–HRAHealth Risk

(Web)

Regulations

Hazardous Waste Forms

Reliability Factors

Transportation/Storage Factors

Packaging Criteria

Corrosive Criteria

Insensitive Criteria

Green CriteriaConcern Criteria

Chemicals Released

Constituent Chemicals

Demil Processes

Munitions Characterization – MIDAS

MACS Centralized Databases



Significance of each sub-score can be individually weighted

HEALTHSCORE

(0-100%)

_____% A.W.

SAFETYSCORE

(0-100%)

_____% A.W.

FINALGREENGRADE

(0 -

100%)

ECOLOGICALSCORE

(0-100%)

_____% A.W.

“Endpoint” Criteria

LONG-TERM EFFECTS -

SOILGroundwater Mobility Factor

CERCLA RQ

TOXICITY-WATERFish LC50

Daphae

LC50Green Algae EC50

(Solubility W-LC50) BCF

LONG-TERM EFFECTS -

WATEREutrophication

Theoretical Oxygen Demand

LONG-TERM EFFECTS -

AIRGlobal Warming PotentialOzone-Depleting Potential

SmogAcidification

(“Green” Munitions Analytical Compliance System)G–MACS “Green” Score Scheme

TOXICITY -

AIR(V.P. LC50) BCF

TOXICITY -

SOIL(Koc O-LD50) BCF

14-day Worm LC50

PersistenceExposureToxicityLong-Term Effects



Oral LD50Dermal LD50IDLHSTEL/CeilingInhalation LC50Skin IrritationEye IrritationOdor Threshold Value

Flammability

RadioactivityOxidizerWater-ReactiveCorrosive

Water Score

Air Score

Soil Score

Acute Health Score

Fire Score

Special Score

ExplosivityReactivity Score

Chronic Health Score

FLAMMABILITYFlash PointBoiling Point

Reproductive EffectsCarcinogenicityRfCRfDRadioactivitySensitizerNeurotoxicityTLV



MunitionSensitivity

Risk Assessment

MunitionTest PlanStatus

IM TestResult

Analyses

IMDocumentTracking

I-MACS System Components



IMTest PlanStatus

IMDocumentTracking

IMTest Result

Analyses

MACS-1Analytical

Input Results

I-MACSAnalytical

Results Output(to G-MACS)

MunitionSensitivity

RiskAssessment

Main Menu ScreenInsensitive Munitions Analytical Compliance System (I-MACS)


Munition Sensitivity Risk Assessment AlgorithmsInsensitive Munitions Analytical Compliance System (I-MACS)

CorrelationAnalysis

CorrelationAnalysis

HistoricIncidentsDatabase

HistoricIncidentsDatabase

“At Risk”Sensitive

ConstituentsDatabase

“At Risk”Sensitive

ConstituentsDatabase

Risk SourcesDatabase

Risk SourcesDatabase

Risk SourcesCompensation

StrategiesDatabase

Risk SourcesCompensation

StrategiesDatabase

ENERGETICSCORROSIVESCORROSION SENSITIVEHEAT SENSITIVEINCOMPATIBLES

Risk SourceTest ResultsRisk SourceTest Results

Risk SourceCompensation

StrategyTest Results

Risk SourceCompensation

StrategyTest Results

CorrelationAnalyses

CorrelationAnalyses


IMHazard

AssessmentTest

Results

IMLife Cycle

EnvironmentalProfile

IMThreatHazard

Assessment

IMTest Plan

&Results

IMTest Plan

SafetyGoals

IMTest

Report

Review&

Approval

Review&

Approval

Review&

Approval

Review&

Approval

Review&

Approval

Review&

Approval

IMFINAL

RECOMMEND.

Test Plan Status & Document Tracking

PRO

GR

AM

M

AN

AG

ERSE

RVI

CE

REV

IEW

OR

GA

NIZ

ATI

ON



________________Specialty

Test

________________Specialty

Test

________________Specialty

Test

________________Specialty

Test

________________Specialty

Test

28-DayTemperature

&Humidity

Test

VibrationTest

4-DayTemperature

&Humidity

Test

12-MeterDropTest

FastCook-Off

Test

SlowCook-Off

Test

BulletImpactTest

FragmentImpactTest

SympatheticDetonation

Test

ShapedCharge Jet

ImpactTest

SpallImpactTest

Test Plan & Results



MunitionSensitivity

Risk Assessment

MunitionTest PlanStatus

IM TestResult

Analyses

IMDocumentTracking

System ComponentsInsensitive Munitions Analytical Compliance System (I-MACS)

Risk Source Test Results

Risk Source Compensation Strategies Test Results

Test Results

Reviews & Approvals

Standardized Test Data Tables

Historic IM Test Data

Munition Constituents (MIDAS)

IM Criteria

Printed Reference DocumentsIM File Creation

Risk Sources Compensation StrategiesHistoric Incidents

“At Risk”

Sensitive Constituents

Risk Sources

Life Cycle Environmental Profile

Threat Hazard Assessment

Test Plan

Chemical Reference Databases

Thermodynamic Parameters

Incompatible Chemicals

Reference Document Images


Significance of each sub-score can be individually weighted

I–MACS Report Card & Scoring SchemeInsensitive Munitions Analytical Compliance System (I-MACS)

“At Risk”

Constituents Score

Risk Sources (RS) Score

RS Component Strategies Score

INCOMPATIBLE CONSTITUENT

PROXIMITYSCORE

(0-100%)

_____% A.W.

EXTERNAL STIMULI

SCORE

(0-100%)

_____% A.W.

FINALIM

GRADE

(0 -

100%)

CONSTITUENT SENSITIVITY

SCORE

(0-100%)

_____% A.W.

“Endpoint” Criteria

CORROSIVESpKapKb

ENERGETICSEnthalpyEntropy

CHEETAH T/PHeat of Formation

Heat CapacityHazard ClassificationParticle Size/Form

—

Energetics— Corrosives—

Corrosion Vulnerability—

Heat Sensitivity

— Incompatibles— Corrosion—

Temperature—

Humidity—

Static Charge Accumulation— Shock— Vibration— Age

—

Design Barriers— H/T Control— Grounding—

Protective Packaging— Reliability Tests

Mil-STD 2105B Score

External Score

Internal Score

— Ambient T/H— Salt Air—

Package Design

—

Within Munition— Within Component— Within Part—

Design Barriers

—

Fast Cook-Off—

Slow Cook-Off—

Bullet/Fragment/Spall

Impact—

Vibration Test— Drop Test


Constituent Sensitivity Score“At Risk”

Constituent ScoreRisk Sources (RS) Score

RS Component Strategies Score

Incompatible Constituent

Proximity ScoreExternal ScoreInternal Score

External Stimuli ScoreMil-STD 2105B Score

FINAL IM GRADE

Components

Parts

Alternates

Physical Hazards

Health Hazards

Fed Regs

State Regs

Client ModuleData Input Analytical Queries

Client ModuleData Input Analytical Queries

I-MACS HubData Tables &

Analytical Algorithms

I-MACS HubData Tables &

Analytical Algorithms

I-MACSAnalytical Results

Output

I-MACSAnalytical Results

Output

MACS-1Analytical

Input Results

MACS-1Analytical

Input Results

Data Acquisition & Analytical Report Capabilities

IMTest Plan Status

IMTest Plan Status

IMTest Results

IMTest Results

28-day T&H

4-day T&H

Vibration

12-M Drop

Fast C-O

Slow C-O

Bullet Imp.

Frag. Imp.

Sym. Deton.

Shp. Chg. Jet Imp.

Spall Imp.

Special

PM SRO

Life CycleEnv. Profile

ThreatHaz. Assess.

Test Plan& Results

SafetyGoals

TestReport

Haz. Assess.Test Results

Reviews

Approvals

FinalRecommend


Document TrackingDocument Tracking

IM TestsIM Tests


Insensitive Munitions Analytical Compliance System(I-MACS)

Dr. George Thompson973-663-2148

[email protected]

For more information on I-MACS, or a remote demonstration of

other MACS modules,please contact . . .

Chemical Compliance Systems, Inc.706 Route 15 South, Suite 207• Lake Hopatcong, NJ 07849

www.chemply.com

CCS

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