Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting...

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Inkjet Prin+ng [email protected]

Transcript of Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting...

Page 1: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

Inkjet  Prin+ng

[email protected]  

Page 2: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+   Ink-­‐jet  technology

•  The  ink-­‐jet  technology  is  a  contact  free  dot  matrix  prin+ng  procedure.  Ink  is  issued  from  a  small  aperture  directly  onto  a  specific  posi+on  on  a  medium

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+   Ink-­‐jet  technology

! 39

Figure 29. Map of current and new applications [13].

At present time, both TIJ and PIJ printing turned out to be the two most important

technologies when it comes to printing. Even though initially TIJ has advantages over

PIJ, these have been leveled over the years by further development of the PIJ

technology.

The strength of the PIJ technology is represented by its ability to deposit a wide

variety of materials on various substrates in well-defined patterns. Lately emerged

many other applications than printing onto paper [62–69]. In the display market,

inkjet technology is mainly used to manufacture Flat Panel Displays (FDP), Liquid

Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes

(PLED), and flexible displays. The accompanying performance criteria are among the

major driving forces behind much research and development efforts. Within the

chemical market, the inkjet technology is mainly used as a tool for research purposes.

The unique capacity of the technology for dispensing small doses of liquids makes it

very useful for this market. Applications include material and substrate development

as well as coating purposes.

In the electronic market, inkjet print heads are used to create functional electrical

traces using conductive fluids on both rigid and flexible substrates [10].

3.6 FUTURE DEMANDS

The requirements for the inkjet printing technology are continuously increasing. The

near future demands require the achievement of smaller drops, higher drop velocities,

higher drop repetition rates, smaller print head designs, a maximum jetting stability,

 X.  Wang.  Nanotech  Conference  &  Expo  2009,  Houston,  TX,  (2009)  

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+   Ink-­‐jet  technologies

Ink-­‐jet  Technology

Con+nuous Drop-­‐on-­‐demand

Acous+c El.sta+c Piezo Thermal

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+  Mechanisms  of  drop  forma+on

1.1. HISTORICAL OVERVIEW ON INKJET TECHNOLOGY 3

in the Mingograph, which was released in 1952. Instead of being an inkjet printer,it was merely a medical voltage recorder (e.g. for ECG and EEG). The deflectingof the drops was driven through analog voltages from a sensor, quite similar tocurrent seismic apparatus.

In the early 1960s Sweet of Stanford University demonstrated that, by apply-ing a pressure wave pattern to an orifice, the ink stream could be broken intodroplets of uniform size and spacing [147]. When the drop break-up mechanismwas controlled, the drops could be charged selectively and reliably as they emergedout of the continuous ink stream. The charged drops were deflected, when pass-ing through an electric field, to form an image on the substrate. The unchargeddrops were captured by the gutter and re-circulated in the system. This versionof the printing process is known as the Continuous Inkjet (CIJ) printing process(US Patent 3,596,275), with the Inkjet Oscillograph as first device. This devicewas elaborated for use by the Stanford Research Institute (SRI) for inkjet bar cod-ing work for Recognition Equipment Incorporated (REI). The A.B. Dick Companyelaborated Sweets invention to be used for character printing. With their Videojet9600 in 1968, it was the first commercial CIJ printing product.

Figure 1.2: Classification of inkjet printing technologies, adapted from [97].

The binary deflection was further developed, not only for bar code printing, butalso for advertising purposes, with the so-called DIJIT printer, introduced in 1973by the Mead company. Developments were boosted by the huge research effortsof IBM in the 1970s, which resulted in 1976 in the IBM 6640, a word processinghardcopy-output peripheral application [27]. Two companies were involved inthe multiple drop deflection, the Sharp and the Applicon company. The formerreleased their Jetpoint in 1973, the latter their color image printer in 1977. Inthe same period Hertz of the Lund University of Technology in Sweden developed

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+  Con+nuous  Ink-­‐Jet  (CIJ)

•  Plateau-­‐Rayleigh  instability –  A  falling  stream  of  fluid  breaks  up  into  smaller  drops  (the  liquid    is  unstable) –  When  a  jet  is  thin  enough,  the  effect  of  gravity  is  negligible  compared  to  

surface  energy

–  The  jet  changes  its  shape  to  reduce  the  total  surface  energy –  Liquid  flow  sets  the  +me.

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.1.1. Ink-Jet Technology: History (1)

� 1878: Lord Rayleigh� Breaking of liquid jets into individual droplets� [On the instability of jets, in Proc. London Math. Soc. 10 (4), 4R13

(1878)]� Surface-tension related stable minimum of energy

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+  Con+nuous  Ink-­‐Jet  (CIJ)

•  Minimum  of  surface  energy •  Varicose  perturba+on  (unstable  system)

•  No  constant  radius  of  curvature •  Time  and  length  scale

•  Drop  radius

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+  Con+nuous  Ink-­‐Jet  (CIJ)

•  Mathema+cal  modelling

Lcrit = f ρ,R,Ujet,γ( )

LcritR

= 2.74 U ρRγ

!

"#

$

%&

12

'

(

))

*

+

,,

Tcrit = 2.74ρR3

γ

!

"#

$

%&

12

R 'R0

≈π

0.697"

#$

%

&'

12≈ 2.1

Page 9: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  Con+nuous  Ink-­‐Jet  (CIJ)

•  Dedicated  charging  of  droplets

•  Recircula+on  by  deflec+on  in  transversal  electrical  field

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.1.2. cIJ: Setup

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+  Con+nuous  Ink-­‐Jet  (CIJ)

•  Binary  deflec+on –  Uncharged  droplets  dispended  on  substrate –  Charged  droplets  recirculate

•  MulEple  deflecEon  –  Uncharged  droplets  recirculated  by  guJer  –  Charged  droplets  deflected  according  to  q/m  raEon  –  2-­‐dimensional  wriEng  of  small  areas  with  single  

nozzle  Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.1.2. cIJ: Binary Deflection

�Uncharged droplets dispensed on substrate�Charged droplets recirculate

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.1.2. cIJ: Multiple Deflection

�Uncharged droplets recirculated by gutter�Charged droplets deflected according to q / m-ratio�2-dimensional writing of small areas with single nozzle

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+  Con+nuous  Ink-­‐Jet  (CIJ)

•  Droplet  delivery –  Emission  of  cylindrical  plug  from  orifice

–  S+mulated  break-­‐off  (induced  varicosity)

–  Charging  by  passing  electric  field  (ring  or  tunnel) –  Orifice  diameter  50-­‐80  um

–  Droplet  size  ≅  120  um  (volume  4fl  –  1pl) –  Droplet  frequencies  in  order  of  100  kHz   –  Frequently  satellite  droplets  formed

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.1.2. Droplet Delivery� Droplet formation

� Emission of cylindrical plug from orifice� Varicosity

- Sectioning into thinner and thicker zones

� Ligaments break- Electrical connection to print head cut

� Stimulated break-off� cIJ: disintegration induced by regular

wave patterns applied to orifice� Growth of perturbations� Predetermined breaking points� Critical parameters

0.20 ms

0.25 ms

0.30 ms

0.35 ms

0.40 ms

0.50 ms

0.60 ms

0.70 ms

nozzle

Ekin

surfacetension

Ekin

viscosity

Weber numberReynolds number

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+  Con+nuous  Ink-­‐Jet  (CIJ)

•  Drawbacks –  Complex  recircula+on – Deflec+on  according  to  charge-­‐to-­‐mass  ra+o  (limited  accuracy)

–  Restric+on  to  conduc+ng  ink  formulas –  Low  quality

•  Applica+on •  Industrial  small-­‐character  prin+ng  (SCP) –  Zanasi –  hbp://www.youtube.com/watch?v=BZgcNDj4uY

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DROP  ON  DEMAND  (DOD)  

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+  Drop  On  Demand  (DoD)

•  Mechanism  of  droplet  forma+on: – Thermal – Piezo-­‐electric – Electrosta+c – Acous+c

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.1. Impulse Method: Setup

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+  DoD  –  Thermal  Ink-­‐Jet  (TIJ)

•  Roof  shooter –  Heater  above  orifice  

(HP,  Lexmark,  Olivei)

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.4. Thermal Ink-Jet Technology

� Commercially most successful

� Variant 1: roof shooter� Heater above orifice� Hewlett-Packard, Lexmark and Olivetti

� Variant 2: side-shooter� Heater lateral to orifice� Canon and Xerox

•  Side  shoother  –  Heater  lateral  to  horifice  

(Canon  and  Xerox)  

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.4. Thermal Ink-Jet Technology

� Commercially most successful

� Variant 1: roof shooter� Heater above orifice� Hewlett-Packard, Lexmark and Olivetti

� Variant 2: side-shooter� Heater lateral to orifice� Canon and Xerox

Page 16: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  DoD  –  Thermal  Ink-­‐Jet  (TIJ)

•  Phase  of  droplet  forma+on •  Hea+ng

–  Overheated  ink  (over  the  spinodal  limit,  around  300°C  for  water)

–  At  300°C:  nuclea+on  of  bubble

•  Expansion –  Ejec+on  of  ink –  Parallel  to  bubble  expansion

•  Droplet  forma+on –  Collapsing  vapour  bubble –  Retrac+on  of  bulk  ink –  Refilling  of  cavity  (80-­‐200  us,  

speed  cri+cal  step)

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.4. tIJ: Phases of Droplet Formation

�Heating (some µs)�Overheated ink�At 300°C: nucleation of bubble

LExpansion�Ejection of ink�Parallel to bubble expansion�Bubble pressure (empirical)

�Droplet formation�Collapsing vapor bubble�Retraction of bulk ink�Refilling of cavity (80-200 µs)

-Speed-critical stepJens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.4. tIJ: Droplet Formation

!" #$%&'()&*+ *, )-$ .)()$ ./(0$ 1&2$%$+)&(3 $45()&*+.

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Page 17: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  DoD  –  Thermal  Ink-­‐Jet  (TIJ)

•  Example:  nozzle  of  DJ  850C  color  printhead

•  Roof  shooter •  6000  droplets  a  32  pl  per  second  (cycle  

+me  170  us) •  Widht  and  height  of  ink  channel  on  um  

range •  Cri+cal  produciton  parameters

–  Dimensional  stability –  Precision –  Uniformity  of  nozzles

•  Drop  performance –  Frequency –  Volume –  Speed

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.4. tIJ: Nozzle of DJ 850C Color printhead

� Heater (roof shooter, aperture plate removed)� 6000 droplets à 32 pl per second

� Cycle time 170 µs

� Width and height of ink channel on µm range� Critical production parameters

� Dimensional stability� Precision� Uniformity of nozzles

� Drop performance� Frequency� Volume� Speed

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+  DoD  –  Thermal  Ink-­‐Jet  (TIJ)

•  A  case  of  study A K Sen and J Darabi

Ink manifold

Ink chamber

Heater

Nozzle guide Ink channel

Passivation layer

Figure 1. A cross-sectional view of the inkjet print head.

saturation pressure corresponding to liquid temperature Tl,coefficients cevap and ccon are the accommodation coefficientsfor evaporation and condensation, respectively. The energychanges in the fluid are computed as follows. If !m is themass exchange between fluid and vapor in an element, thecorresponding change in the liquid energy in the element is

!E =∣∣∣∣∣!m(Hlv + el), if !m ! 0

!m(Hlv + c

vapv Tv

), if !m " 0

(8)

where Hlv denotes the latent heat of vaporization and el is thespecific energy of the liquid at temperature Tl. The fluid–airinterface is tracked using the volume of fluid (VOF) technique[17]. The motion of the interface between the liquid and air isdefined by a volume fraction function F in equation (9), andthe interface is tracked using the conditions in equation (10):

dF

dt+ u⃗ · ∇F = 0 (9)

F (x, y, z, t) =

⎧⎨

0 outside the liquid1 inside the liquid>0,<1 on the free surface.

(10)

Equation (9) also represents the kinematic condition at theinterface. The simulation tool solves equations (1)–(10) withappropriate boundary conditions, as applicable to any specificprint head design.

3. Simulation of the proposed TIJ print head

3.1. Description of the device structure

A cross-sectional view of the structure of the proposed TIJprint head is depicted in figure 1. The device comprises anink manifold, dome-shaped ink chamber, a thin film nozzleguide, ring-shaped heaters and a passivation layer in betweenthe heater and the ink chamber. The design has the inkchamber and the nozzle inline, thus higher nozzle density canbe achieved. It includes a passivation layer between the heaterand the ink chamber thereby eliminating heater burn out issues.The shape of the ink chamber is hemispherical (dome-shaped)which can be fabricated on a Si-substrate using isotropic wetbulk micromachining. The nozzle guide and the heater can beformed using thin film deposition.

D dw

t

L

x

Figure 2. Computational model of the inkjet print head.

3

4

21

Figure 3. Boundaries of the computational domain.

3.2. Description of the computational model

A schematic diagram of the computational model of the inkjetprint head simulated in the present study is depicted in figure 2.The diameter of the ink chamber is D, the nozzle diameter is d,the heater width is w and the thickness of the passivation layeris t. x defines the location of the heater w.r.t. the nozzle. Thewidth of the thermal pulse applied to the heater element is τ .The printing surface is located at a distance L from the nozzleorifice. The ink present inside the ink chamber is of density ρ,viscosity µ and surface tension γ . The thermal conductivityof the passivation layer is k.

3.3. Boundary conditions

A two-dimensional axi-symmetric model is considered forsimulation. The boundary conditions for the model areillustrated with reference to figure 3. Boundary 1 (inletboundary)—stagnation pressure boundary conditions thatrepresent the external ambient conditions as a large reservoirof stationary fluid, and fluid fraction function F = 1, boundary2—symmetry boundary condition which indicates that thesame physical processes exit on the two sides of the boundary,boundary 3 and 4—continuative boundary condition whichrepresents zero normal derivative at the boundary for allquantities, F = 0, all the solid boundaries: no-slip boundaryconditions. The contact angle used in the simulation was10◦ which represents the full-wetting condition. The initialtemperature in the computational domain is 300 K.

3.4. Model validation

The numerical model is validated by comparing the modelpredictions with the experimental data and results of a lumpedmodel for the axi-symmetric TIJ print head reported by Leeet al [18]. The droplet momentum as a function of nozzlediameter predicted by the present model is compared withthat measured in the experiments and obtained from thelumped model in figure 4. The agreement between the modelpredictions and the experimental data is within 10% indicatingthe validity of the model and modeling methodology.

1422

A K Sen and J Darabi

t = 2.1 µs

t = 4.5 µs

t = 9 µs

t = 15 µs

t = 22 µs

t = 27 µs

t = 31 µs

Figure 7. Time evolution of the liquid profile along with thetemperature (K) contours inside the liquid.

adjusted during the microfabrication process. The operatingparameters include thermal energy and pulse width, whichcan be controlled during operation of the device. The fluidproperties include the density, surface tension and viscositythat can be tuned by the ink manufacturers. The dropletvolume and speed of the droplets can be precisely modulatedby adjusting the print head geometry, operating conditionsand fluid properties. The droplet volume and speed controlthe printing precision and speed. Another design goal is tominimize the formation of satellite droplets to improve theprint quality. The droplet volume and speed (average) arecalculated by the simulation tool at a distance of 0.5 mm

300

400

500

600

700

800

900

0 10 20 30 40 50Time (µs)

Tem

pera

ture

(K

)

Heater

Fluid-film

Figure 8. Variation of the temperature (K) of the heater and fluidfilm with time.

from the nozzle orifice. The threshold energy is calculated bydetermining the minimum thermal energy for which dropletejection is observed. The tail length is calculated soon afterthe droplet is detached from the chamber–fluid interface.Figure 10 shows effects of the nozzle diameter on dropletvolume and speed. It is observed that there is an increase of thedroplet volume with increase in nozzle diameter. The surfacetension force acting on the fluid–air interface is lower for alarger nozzle, thus more volume of fluid can be ejected for thesame thermal energy. The decrease in the speed of the dropletsmay be due to increase in the droplet mass with increasein the nozzle diameter. Similar trends have been observedin previous experiments [8]. Variation of droplet volumeand threshold thermal energy with the width of the heateris depicted in figure 11. The results show that droplet volumeincreases with increase in the heater width. Increase in dropletvolume is possibly due to formation of a larger thermal bubbleat a higher heater width, which displaces more fluid fromthe chamber. The results also show a decrease in thresholdthermal energy with increase in the heater width which maybe due to a higher rate of heat transfer to the fluid because ofthe higher bottom surface area of the heater. The influence ofchamber size and heater location on threshold thermal energyis presented in figure 12. There is an increase of thresholdthermal energy with increase in the chamber size which maybe due to the increase in static pressure in the chamber for alarger chamber size. A higher thermal energy is required togenerate a thermal bubble that can generate enough pressurefor the droplet ejection. The results also show increase in thethreshold thermal energy with increase in the distance betweenthe heater and the nozzle orifice. This is possibly because alarger amount of heat is transferred (heat loss) to the substratewhich could have been otherwise transferred to the fluid, asthe heater is located far away from the nozzle. The choice ofpassivation layer between the heater and the ink chamber is animportant design factor.

Variation of the threshold thermal energy with thermalconductivity of the passivation layer (for different materials)is depicted in figure 13. It is observed that there is a significantdecrease of threshold thermal energy with increase in thethermal conductivity of the passivation layer, as expected.

1424

Droplet ejection performance of a monolithic thermal inkjet print head

t = 2.1 µs

t = 4.5 µs

t = 9 µs

t = 15 µs

t = 22 µs

t = 27 µs

t = 31 µs

Figure 9. Axial-velocity contours (m s−1) in the fluid.

Four different materials have been evaluated—SiO2, SiN,SiC, AL and CVD diamond in increasing order of thermalconductivity.

The influence of the nozzle-guide length on dropletvolume and speed is depicted in figure 14. The results showthat both droplet volume and speed decrease with increase inthe nozzle guide length. This may be due to the fact thata longer nozzle guide increases the pressure drop or flowresistance, thus resulting in a smaller and slower droplet.Decrease in the momentum of the ejected droplet with increasein the length of the nozzle guide has been reported by [18].Figure 15 presents influence of thermal energy on the droplet

0

10

20

30

40

50

5 15 25 35 45Nozzle diameter (µm)

Dro

ple

t v

olu

me

(pl)

a

10

11

12

13

14

15

Dro

ple

t sp

eed

(m

/s)

Droplet speed

Droplet volume

Figure 10. Influence of nozzle diameter on droplet volume andspeed.

0

2

4

6

8

10

0 5 10 15 20 25 30Heater width (µm)

Dro

ple

t v

olu

me

(pl)

a

5

10

15

20

Th

resh

old

th

erm

al e

ner

gy

J)

Threshold energy

Droplet diameter

Figure 11. Influence of heater width on droplet volume andthreshold thermal energy.

0

6

12

18

24

30

20 40 60 80 100Chamber diameter (µm)

Th

resh

old

ener

gy

J)

0 3 6 9 12 15Heater location (µm)

Heater location vs. threshold energy

chamber diameter vs. threshold energy

Figure 12. Influence of chamber size and heater location onthreshold thermal energy.

volume and speed. The results show that both droplet volumeand speed increase with increase in the thermal energy. Ahigher thermal energy results in faster droplets, thus reducingthe printing time but at the same time the droplet volume

1425

Droplet ejection performance of a monolithic thermal inkjet print head

0

15

30

45

60

75

0.1 1 10 100 1000 10000µ(mPas) γ (mN/m) ρ(kg/m3)

Tail

len

gth

m)

a

DensitySurface tensionViscosity

Figure 18. Influence of ink density, surface tension and viscosity ontail length.

surface tension and increases slowly with increase in viscosity.This trend is consistent with the results reported by [19].

5. Conclusion

The droplet ejection performance of a thermally-drivenmonolithic inkjet print head based on a dome-shaped inkchamber, a nozzle guide and a ring-shaped heater wassimulated. The design employs a passivation layer as anintermediate layer between the ink and the heater, thuseliminating heater burnout issues and improving reliability.The design configuration is such that the ink chamber andthe nozzle are inline, thus higher nozzle density can beachieved. The numerical model is validated by comparing themodel predictions with experimental results for a previouslyreported print head design. The agreement between themodel predictions and the experimental results is within10%, indicating the validity of the model and modelingmethodology. The droplet ejection performance of theproposed print head design was simulated including thenucleation and growth of the thermal bubble. A thermalpulse was used as the driving mechanism for the dropletejection. Coupled flow and energy along with bubbledynamics equations were solved to predict the time evolutionof the fluid interface, droplet volume and speed, heater andfluid-film temperature and temperature distribution in the inkpresent in the chamber. The model was used to investigatethe effects of print head geometry including nozzle diameter,nozzle-guide length, chamber size, heater location and thermalconductivity of the passivation layer, operating conditionsincluding thermal energy and pulse width, and ink propertieson droplet volume and speed. The influence of ink propertieson tail length was also studied. The results of the parametricstudy are expected to facilitate the design and operation of theproposed print head design.

References

[1] Doane I G 1981 A review of ink-jet printing J. Appl. Photogr.Eng. 7 121–5

[2] Meinhart C D and Zhang H 2000 The flow structure inside amicrofabricated inkjet printhead J. Microelectromech. Syst.9 67–75

[3] Lee J D, Yoon J B, Kim J K, Chung H J, Lee C S, Lee H D,Lee H J, Kim C K and Han C H 1999 Thermal inkjetprinthead with a monolithically fabricated nozzle plate andself-aligned ink feed hole J. Microelectromech.Syst. 8 229–36

[4] Beeson R 2000 Desktop inkjet-redefining: the competitivelandscape Proc. 9th Ann. Inkjet Printing Conf. (Scottsdale,AZ, 4–12 Oct. 2000) (Kingfield: IMI)

[5] Lee Y S, Shin S J, Kuk K, Kim M S, Shin S and Sohn D K2004 Lumped modeling of crosstalk behavior of thermalinkjet print heads Proc. ASME Fluids Engineering Division2004 vol 260, pp 391–8

[6] Tseng F G, Kim C J and Ho C M 2002 A high-resolutionhigh-frequency monolithic top-shooting microinjector freeof satellite drops—part I: concept, design, and modelJ. Microelectromech. Syst. 11 427–47

[7] Lee S W, Kim H C, Kuk K and Oh Y S 2002 A monolithicinkjet print head: dome jet Sensors Actuators A 95 114–9

[8] Tseng F G, Kim C J and Ho C M 1998 A novel microinjectorwith virtual chamber neck, Micro Electro MechanicalSystems MEMS 98 Proc.: The 11th Annual InternationalWorkshop (Heidelberg, Germany, Jan 1998) pp 57–62

[9] Yan W, Jeffrey B and Lee A 2004 Maskless lithography usingdrop-on-demand inkjet printing method EmergingLithographic Technologies VIII: Proc. SPIE 5374 628–36

[10] Park J H and Oh Y S 2005 Investigation to minimize heaterburnout in thermal thin film print heads MicrosystemTechnologies vol 11 (Berlin: Springer) pp 16–22

[11] Bae K D, Baek S S, Lim H T, Kuk K and Ro K C 2005Development of the new thermal inkjet head on SOI waferMicroelectron. Eng. 78–79 158–63

[12] Baek S S, Choi B and Oh Y 2004 Design of a high-densitythermal inkjet using heat transfer from CVD diamondJ. Micromech. Microeng. 14 750–60

[13] Huang C M, Chen C T, Liou J C, Chiao C C, Wang C Y,Chuang Y H, Mao C Y and Chen C J 2004 Design andfabrication of the monolithic inkjet print head 2004 Int.Conf. on Digital Printing Technologies, (Salt Lake City, UT)

[14] Asai A, Hara T and Endo I 1987 One-dimensional model ofbubble growth and liquid flow in bubble jet printers Japan.J. Appl. Phys. 26 1794–801

[15] Chen P H, Chen W C, Ding P P and Chang S H 1998 Dropletformation of a thermal side-shooter inkjet printhead Int. J.Heat Fluid Flow 19 382–90

[16] Theofanous T, Biasi L and Isbin H S 1969 A theoretical studyon bubble growth in constant and time-dependent pressurefields Chem. Eng. Sci. 24 885

[17] Hirt C W and Nichols B D 1981 Volume of fluid (VOF)method for the dynamics of free boundaries J. Comput.Phys. 39 201–25

[18] Lee Y S, Kim M S, Shin S H and Shin S J 2003 Lumpedmodeling of thermal inkjet print head Nanotech2 488–91

[19] Lindemann T, Sassano D, Bellone A, Zengerle R and Coltay P2004 Three-dimensional CFD simulation of a thermalbubble jet print head Nanotech 2 227–30

1427

Droplet  ejecEon  performance  of  a  monolithic  thermal  inkjet  print  head  -­‐  2007  J.  Micromech.  Microeng.  17  1420  

Page 19: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  Exercise

•  Es+mate  the  penetra+on  depth  of  the  temperature  into  a  drop  during  thermal  inkjet  printer.

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.4. tIJ: Droplet Formation

Page 20: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  DoD  –  piezo-­‐electric  IJ

•  Deforma+on  of  piezo-­‐ceramics

•  Change  in  volume •  Pressure  wave  propagates  to  

nozzle

•  Deflec+on  of  piezo-­‐ceramics  in  submicrometric  range

•  Piezo-­‐element  has  to  be  much  larger  than  orifice

•  Main  problem:  miniaturiza+on  

1.1. HISTORICAL OVERVIEW ON INKJET TECHNOLOGY 5

DOD electrostatic pull principle was abandoned due to poor printing quality andreliability, although research activities continues until today [153, 154].

Generally, the basis of piezoelectric inkjet (PIJ) printers is attributed to threepatents in the 1970s. Common denominator of these three patents is the use ofa piezoelectrical unit to convert an electrical driving voltage into a mechanicaldeformation of a ink chamber, which generates the pressure required for the dropformation from a nozzle. The first one is that of Zoltan of the Clevite company in1972 (US Patent 3,683,212), proposing a squeeze mode of operation [28]. In thismode, a hollow tube of piezoelectric material is used. When a voltage is appliedon the piezoelectric material, the ink chamber is squeezed and a drop is forced outof a nozzle.

Figure 1.4: Classification of piezo inkjet (PIJ) printhead technologies by the de-formation mode used to generate the drops.

The second patent of Stemme of the Chalmers University in 1973 (US Patent3,747,120) utilizes the bend mode of piezoelectric operation. In this mode, thebending of a wall of the ink chamber is used to eject a drop. The third patentof Kyser and Sears of the Silonics company in 1976 (US Patent 3,946,398) alsoused the bend mode operation. Both bend-mode patents were filed in the sameyear. The minor difference between the two is that Stemme used a flat disc ofpiezoelectric material to deform a rear wall of an ink chamber and that Kyser andSears used a rectangular plate to deform the roof of an ink chamber. The firstPIJ printer to reach the market was in 1977 with the Siemens PT-80, which usedthe squeeze mode. Silonics was the second company to introduce a piezoelectric

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+  DoD  –  piezo-­‐electric  IJ

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.3. pIJ: Types

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.3. pIJ: Shear Mode

Page 22: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  DoD  –  piezo-­‐electric  IJ

•  OmniJet  100  –  samsung  cartridges  •  Signal  waveform  

!

! !

!

Page 23: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  DoD  –  piezo-­‐electric  IJ

•  Lumped  model •  Electromechanic  modelling  (Maxwell  Approach)

50 / APRIL 2008 INTERNATIONAL JOURNAL OF PRECISION ENGINEERING AND MANUFACTURING Vol. 9, No.2

NOMENCLATURE

��

q = flow rate C = compliance M = inertance p = pressure R = resistance V = volume change V = applied voltage

1. Introduction

Recently, inkjet printing methods have been examined with the aim of replacing conventional high-cost micro patterning processes on electronic devices, which include repeated mask masking, UV exposure, developing, chemical etching, resist stripping, cleaning, water rinsing, and drying.1 With recent advances in the synthesis and stabilization of nano-sized particles in a specific medium, direct inkjet printing has become a promising solution for the deposition of materials in a wide variety of applications. Compared with conventional processes, inkjet printing technology has low costs, simpler processing, and a high rate of material utilization. The adoption of a reliable piezoelectric inkjet printing head is desirable for ejecting fine droplets, without variations in the droplet velocity and size. However, the absence of a reliable piezoelectric inkjet head for various functional inks prevents the application of inkjet printing technology during the manufacture of electronic products.2 In this study, a bending-mode piezoelectric inkjet head was investigated for directly printing on printed circuit boards (PCBs) using liquid metal ink. A lumped element model was developed to predict the performance of the inkjet head for various head design parameters.

2. One Dimensional (1D) Lumped Model

A schematic view of the piezoelectric-driven drop-on-demand inkjet head is shown in Fig. 1. When an electric field is applied to a piezoelectric material, it changes its planar dimensions. If it is rigidly attached to the vibratory plate, bending occurs. This bending increases the pressure in a chamber and causes an ink droplet to be ejected through the nozzle. Demand ink jet heads are composed of a composite system of electrical, mechanical, and fluidic elements. However, the mathematical difficulty of predicting the performance of a printing head is greatly reduced by replacing the distributed components with equivalent lumped elements.3-5 The displacement of a piezoelectric vibrator in a pressurization chamber and the resulting ink stream may be analogized to the electric circuit shown in Fig. 2, where C, M, and R illustrate the compliance, inertance, and resistance of the lumped elements, respectively. The fluid compressibility in the pressurization chamber is represented by C. The elastic deformation of the vibratory plate also acts as compliance. When accelerated ink flows through a thin passage, the mass of the ink acts as an inertance. In the notation, the subscript denotes the component of the inkjet head (e.g., “p” for piezoelectric vibrator, “c” for pressure generating chamber, “r” for restrictor, “n” for nozzle, “res” for reservoir, and “m” for meniscus). Fig. 1 Schematic diagram of the inkjet printing head

Performance Analysis of an Industrial Inkjet Printing Head Using the 1D Lumped Model

Won-Chul Sim1, Sung-Jun Park2, # and Jaewoo Joung1 1 eMD Center, Central R&D Institute, Samsung Electro-Mechanics Co., Ltd., #314, Maetan-3-dong, YeongTong-gu, Suwon, Gyeonggi-do, South Korea, 443-743

2 Department of Mechanical Engineering, Chungju National University, 72 Daehak-ro, Chungju, Chungcheongbuk-do, South Korea, 380-702 # Corresponding Author / E-mail: [email protected], TEL: +82-43-841-5130, FAX: +82-43-841-5120

KEYWORDS: Inkjet printing, Inkjet head, 1D lumped model, Direct writing

A design approach using a one-dimensional (1D) lumped model was studied and applied to an industrial inkjet printing head design for micro patterning on printed circuit boards. For an accurate analysis, a three-dimensional piezoelectric-driven actuator model was analyzed and its jetting characteristics were applied to 1Danalysis model. The performance of the 1D lumped model was verified by comparing measured and simulated results. The developed 1D model helped to optimize the design and configuration of the inkjet head and could be implemented in the design of multi-nozzle inkjet printing heads to improve the jetting frequency and minimize crosstalk.

Manuscript received: January 2, 2008 / Accepted: January 13, 2008

Copyright (c) 2008 by KSPE

INTERNATIONAL JOURNAL OF PRECISION ENGINEERING AND MANUFACTURING Vol. 9, No.2, pp.50-53

INTERNATIONAL JOURNAL OF PRECISION ENGINEERING AND MANUFACTURING Vol. 9, No.2 APRIL 2008 / 51 Fig. 2 Equivalent circuit diagram of the inkjet printing head

By using a lumped element model of the inkjet printing head, we obtain following equations.

��

���

��

��

��

��

��

���

respcp

pn

cpr

cprr

rr VV

CCC

qCC

qCC

qRM

q111

�� (1)

��

���

��

��

��

��

��

��� mpcp

pn

cpr

cpnn

nn VV

CC

Cq

CCq

CCqR

Mq

111 .��

(2)

Where rq�� and nq�� are flow rates at the restrictor and nozzle, respectively. Figure 3 shows a block diagram of the equivalent circuit for the inkjet printing head. Compared with the inertance and resistance of the nozzle and restrictor, Mc and Rc are sufficiently small that they can be neglected. 2.1 Piezoelectric Vibrator

An AC voltage Vp was applied across the piezoelectric vibrator to generate an effective pressure that drove the diaphragm into oscillation. Thus, a conversion ratio Keq from the electrical domain to the fluidic domain with units of Pa/V must be considered.6 Keq can be calculated by comparing the displacement generated by the applied voltage and by the pressure. To obtain the compliance of the piezoelectric vibrator and Keq, a finite element (FE) analysis was performed using the commercial FEM package CoventorWare. Figure 4 shows the simulated displacement contour of the piezoelectric vibrator used to acquire its compliance and the conversion ratio of the voltage to pressure:

P

VC a

p � (3)

VCv

K a

V

eq

���

����

� (4)

where Va is the volume change due to the pressure, P is the applied pressure, vV is the volume change due to the voltage, and V is the applied voltage. 2.2 Compliance

The fluid compressibility of the pressurization chamber acts as a compliance. The compliance of the pressurization chamber is given by

2��

cc

VC � (5)

where Vc is the volume of the pressurization chamber, � is the density of the ink, and � is the speed of sound in the ink, which is approximately 1500 m/s.

2.3 Resistance The pressure drop is caused by viscous losses in the inkjet

channels. In addition, when fluid moves through the flow passages, a sudden change of the cross-sectional area occurs between both Fig. 3 Block diagram of the one-dimensional lumped model used for the analysis of inkjet head Fig. 4 Simulated displacement corresponding to an applied voltage for calculating the compliance of the vibrator and KVtoP in the lumped element analysis the pressurization chamber and the restrictor and nozzle, as shown in Fig. 5. Thus, the effect of the sudden expansion and contraction must be considered when calculating the pressure drop:

22

���� qRqRqRP scse (6)

where

q is the flow rate and Rse and Rsc are the resistances at the sudden expansion and contraction. Based on Eq. (4),

22

isciseirres qRqRqRP

���� (7)

2

_ oseoninnoz qRqRP

��� (8)

2

_ osconoutnoz qRqRP

��� (9)

where Rr and Rn are

2_

128reff

rr

D

LR �� (10)

2128n

rn

D

LR

�� (11)

Here, Lr is the length of the restrictor, Ln is the length of the nozzle, � is the ink viscosity, Deff_r is the effective diameter of the restrictor, and Dn is the nozzle diameter. The resistance due to the change of the cross-section is given by

INTERNATIONAL JOURNAL OF PRECISION ENGINEERING AND MANUFACTURING Vol. 9, No.2 APRIL 2008 / 51 Fig. 2 Equivalent circuit diagram of the inkjet printing head

By using a lumped element model of the inkjet printing head, we obtain following equations.

��

���

��

��

��

��

��

���

respcp

pn

cpr

cprr

rr VV

CCC

qCC

qCC

qRM

q111

�� (1)

��

���

��

��

��

��

��

��� mpcp

pn

cpr

cpnn

nn VV

CC

Cq

CCq

CCqR

Mq

111 .��

(2)

Where rq�� and nq�� are flow rates at the restrictor and nozzle, respectively. Figure 3 shows a block diagram of the equivalent circuit for the inkjet printing head. Compared with the inertance and resistance of the nozzle and restrictor, Mc and Rc are sufficiently small that they can be neglected. 2.1 Piezoelectric Vibrator

An AC voltage Vp was applied across the piezoelectric vibrator to generate an effective pressure that drove the diaphragm into oscillation. Thus, a conversion ratio Keq from the electrical domain to the fluidic domain with units of Pa/V must be considered.6 Keq can be calculated by comparing the displacement generated by the applied voltage and by the pressure. To obtain the compliance of the piezoelectric vibrator and Keq, a finite element (FE) analysis was performed using the commercial FEM package CoventorWare. Figure 4 shows the simulated displacement contour of the piezoelectric vibrator used to acquire its compliance and the conversion ratio of the voltage to pressure:

P

VC a

p � (3)

VCv

K a

V

eq

���

����

� (4)

where Va is the volume change due to the pressure, P is the applied pressure, vV is the volume change due to the voltage, and V is the applied voltage. 2.2 Compliance

The fluid compressibility of the pressurization chamber acts as a compliance. The compliance of the pressurization chamber is given by

2��

cc

VC � (5)

where Vc is the volume of the pressurization chamber, � is the density of the ink, and � is the speed of sound in the ink, which is approximately 1500 m/s.

2.3 Resistance The pressure drop is caused by viscous losses in the inkjet

channels. In addition, when fluid moves through the flow passages, a sudden change of the cross-sectional area occurs between both Fig. 3 Block diagram of the one-dimensional lumped model used for the analysis of inkjet head Fig. 4 Simulated displacement corresponding to an applied voltage for calculating the compliance of the vibrator and KVtoP in the lumped element analysis the pressurization chamber and the restrictor and nozzle, as shown in Fig. 5. Thus, the effect of the sudden expansion and contraction must be considered when calculating the pressure drop:

22

���� qRqRqRP scse (6)

where

q is the flow rate and Rse and Rsc are the resistances at the sudden expansion and contraction. Based on Eq. (4),

22

isciseirres qRqRqRP

���� (7)

2

_ oseoninnoz qRqRP

��� (8)

2

_ osconoutnoz qRqRP

��� (9)

where Rr and Rn are

2_

128reff

rr

D

LR �� (10)

2128n

rn

D

LR

�� (11)

Here, Lr is the length of the restrictor, Ln is the length of the nozzle, � is the ink viscosity, Deff_r is the effective diameter of the restrictor, and Dn is the nozzle diameter. The resistance due to the change of the cross-section is given by

Page 24: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  Nozzle  design •  Geometry  parameters  of  nozzle

–  Diameter –  Depth

•  Effect  on  droplets –  Volume –  Speed –  Deflec+on  angle

•  Effect  on  ink  supply  (refilling) –  Capillary  forces

•  Fabrica+on  tolerances  limit  picture  quality

•  Fabrica+on  of  orifice  plates –  Laser-­‐abla+on  in  polyimide,  

 especially  for  small  nozzles  (10  pl,  20  um)

–  Nickel-­‐electropla+ng –  Electro-­‐discharge  machining  (EDM) –  Micro-­‐punching –  Micro  pressing

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.7. IJ-Technology: Nozzle Design (2)

Jens Ducrée and Roland Zengerle

Praxis beispie l: Ausa rbeitu ngsphaA usarbe itung d er Stan dard-Z

8. Ink-Jet Technology

8.2.7. IJ-Technology: Nozzle Design (3)

Electroplated Ni-nozzle

Page 25: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  Nozzle  design

Page 26: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  Cartridge  Design

•  HP  cartridge – Bubble  generator – Accumulator

Page 27: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

OTHER  TYPES  

Page 28: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  Ultrasonic  droplet  genera+on

•  Acous+c  transducer •  Construc+ve  interference  of  waves – Similar  to  Fresnel  lens

Page 29: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  Valve  jet

•  Non-­‐contact  principle – Drop-­‐on-­‐demand – Ooen  confused  with  impulse  jet

•  Working  principle –  Ink  hold  under  pressure – Dynamic  opening  of  valve •  Micro-­‐electromechanical

•  Spraying  of  fine  jet

Page 30: Inkjet’Prin+ng · Crystal Displays (LCD), color filters (a part of LCDs), Polymer Light Emitting Diodes (PLED), and flexible displays. The accompanying performance criteria are

+  Valve  jet IniEal  posiEon   NC  (Normally  closed)  

Shot  size   From  3  nl  

Viscosity  range   0.5  –  10,000  mPas  (thixotropic)  

Accuracy   >  97  %  (Dispensing  tolerance  <  3  %)  

Frequency   Up  to  280  shots/sec  (Hz)  

Fluid  pressure   0.2  to  6  bar  (up  to  100  bar)  

OperaEng  medium   dry  compressed  air,  oil-­‐free,  filtered  (filter  unit  40  µm)  

OperaEng  pressure   4  to  8  bar  

Switching  Eme   StarEng  at  2  ms  

Electrical  input   24  V,  PLC  compaEble  

Service  life   >  100,000,000  cycles  

Weight   270  g  

Ambient  temperature   -­‐5  to  +40  °C  

Actuator   ElectropneumaEc  

ConstrucEon   Robust  industrial  design,  class  II  equipment,  splashproof  in  accordance  with  IP  65