rd,, i~E!T 1 u Diu ' :TI3 3 ~!'~5" "s . ' SACUM 69®5

4 it 13 W 1969

0 T. V. 11 . Carpenter (4) 1 N. V. SuttonAddeo D/022, S311 aid , e D/991..363, SS11

M.S, hM

5081

Sub1966 HEXAVAIENT CHRQ1IUM CO=I=TION OF

SSFL AREA I RESERVOIR

D BA08RJ Thong son, Jr

D o OJ SilvermanBL TaftlyEFC Cain

D 6 BAmTS XacDosa 4

A Ameday

D/022,SS11.

T Carter

The folloving tive, prepared at Mr. J. C. FoleY43 request,

repaeoex*s only that portion of the problem that was relevant to

and performed by the SSFL Analytical Chemistry unit , form arty

D/99l.359. The entire assig=mt wen in eazpport of the Industrial

Engineering Departamts

BACKROJND CcNTROIs

In 1963, the State Water Pwl?utiona Control Board had been deserted

as the state agency with which the U.S. Public Health Service deals

for purposes of the Federal Water Pollution Control Act . The state

board has ultimate over-all peer and responsibility for enforcing

the state laws relating to water pollution . "Pollution is defined

as an lmpeisraent of the quality of the waters of the State by

se'.mge or industrial waste to a degree which does not create an

actual haurd to public health, but .i.ch does adversely and

unreasonably affect each 'tt 'e for de stir, industrial, ari.

cultural, navigational, i c rational, or other beneficial use, or

which does adversely and st ' . cn bly affect the ocean waters and

bays of the State dated to ;°°blic r i'eation."1

'Jack Edward McKee and MM -old ,'J . Wolf, I-Tatar Criteria(Sacramento : State Water Qa 21ty Ccrd;o1 Pc rd, 1963 , p -I dl, 1-6,

iimm u imi i imimmmm i mm u iBNA0255158 1

HDMSE00638020

SACUM 69-58e 2

In C.a3iforrds, the peotx1ea of eat at or potential pollution 1a studied on

the basis of loe si conditions and onrzent kx rledge. Far Rookstd s, the

setcl~ast a11atiab1s caaioii*t„in by 5wft00 drainage an perc&ation for the

Stmt and San Fsrasaada~ V311eys scan obtained by Industrial Eng nsra~ing fl -on

the State Water Pblbtasa CcnExes3 Board,, August 29,, 1958. The tables are

lied below. In addition, ou August 17, 2966, Mr. Thcaa~s Carter at

Roc1eetdyT~ Indjxa at . 3. Enrglaedng pstaad 3xd o tram the t atmr . Fo1

lather Controtl Board tet thew is i* lisndt on tadsaslant don or total

~. The sate does a ttor far the leer eh and has

deed tlast the 0.05 ppo► tm aiaan 14 be kept.. The wire of the

trite chtm are amt belisled is be p edaegi a UJ haefu1, but

the State Water pMrllud ion Co~ira3 . Board hes rsted tlnltt Boeketd zae adds

these it the age' cantalne gest lda ppa~ Cr+3.

IXDWM ALIAfJLE CA TION

Ssrta oa Drainage to Simi U.y and Peno1ati

Total dissollyad solids

Thlarid.

Sulfate

B

trsgen tea Nc

Fbmide

Hexamlent Chraduta

Turbidity

Total Oil and Grease (inclnding fats & eau,eattz*ction shod)

Flstabls tail and Grease

wet

l~ neex.

2400

175

500

1.0

50

1.5

0.05

5.5 to u

100

25

None visible .

II0I muimiiimimmmm mumm iBNA0255158 2

HDMSE00638021

T*43. Dis 1 ed 83da

Tetal. Baz .s Casa caco3) (vim Metd

~3 3ride

S,~1fatst plus 0 o tda Sol i

Nt,~ngen (ss a

Cbrcsniu~

F3uo g de

T+ntyr

c_ eM .)

F1asb1s Oil a~a r

1000

5.5

20

Tait. Qil snd Grssas (insb'din tta msaass,ate, ms d). 25

D ubL b. hers , $ y to I~ P a rt da*ln

gem frame Lxe I to t2 &1a t Va12q .. The dxa3xnge

Arsa I surd ANi U o darat Hell C ito the 3&n F.rnda Via.

MDcPI Fit

The 2esposie bi]it, r for two pa].7a~ tioa a~ot at the Rocketdjra Fie't4

IAb y s soh t~ I~ a1 Znving r~. Thia

crgunit1eu is rse bls asanpIaa a to he tom, ,t *ml? 71.s

at*a to be o duc ed, awd u t mama tee. Tba Rah Div Esn

II0I muimiiimimmmm iumi I IBNA02551583

- I Er~inseasttg teeh 1 t tbrsugh oa~telt

c*iiW'1 *a* ais, and The samples are pbysicssl3s'

obta iad by tits ' 1 ~texanas Derptzat aad then ibssttted to the C ry

Sab rssa at SSFL ahers the specified aaa3yees are efod by

tpesa of the &esasah DLTSalam. he a salts are rspetsd to Iisdarial

The aoctoeed ~stsr stam is epmpr~issc! of tie ►fim pornis ix 3rsssd

arcs I aa<3 ArM, u xl.th a total .t zt n

s12,' . he ampp2y is used fbr fly bCst cocl4i f all of the

ros~ost eagisra te .

Tire Ara I VStemt has ors half of the p ds aM hs7As about ft's tWcn

aa11nas of aatar The Area I resaitir,, alas Iaasm as 8•S aid 2senata•

Paard, held th'ss.mi7] iem ~7.hsas of qr► at the tiete of the itd,nt.

cmmt Std SPILL

' tai ;~ . ;`s . : •1 N :E ; r ~~~ : . ~• .+ ~ : :u ;.: M ♦ ;,

Generel.b, aabr*1 abromt a has best reeagittsed as a pisaicide, iae.,

tm n to fish aM aq~Lia It!.. ~eweFtsrt, the twelfth editian of the

o Water ~d

sod pubUaied Jointly hY the as icsu Public Health Assoal e ►t1an, the

II0I muim i iimimmmm mi iumu

3ACUH 69-5S

As»riesn Water Whe Asooa1at1~, aar~d the Water Ceuta1

Fedeaatin, 2965) Ma the fo21ng to a abort vmcs

"Tba erdn*gas is pet.nLil et hem oa~yoed * is geed reesen

to pe+s+teat a potsb1. s e app1 r +r rinst its indamstiaz. Thos

heaau ahresdura rieutsat1iaa at B.S. dlrU iatsr has barn

reported to y b can 0.0C and 0404 3 , with a maau at

o.cxr3a pit"..

In chrea isn, the +2, +3, and +6 aidd states are quite omo-on.. The

+3 steels is teaesed tri~e1rantj the is qs 1ed heaoaeralent. . The he vsl1mtt

apscis is the a t high1 used aM the >s at reataited b~ the Steti

Water N 1 tto Aeead. The eha in eediaes Wa2Cr41,, the

spedfisd eiaania~ se2eI3sq, is taaarsalam thi'u .

Haoraavs rheaii rssata with 4iha 1oastsl,de to pdao iucs s r isls-

purgio eSte is aodd er ns. This eheatl seta is

idde

Be de fin

etfis peaoee1ix re cited is the S'$ pp 123I24., >~ lined

for a] the iMar seer, fibs tstal ehsastlaD► deddThIt aegis -

by ~adSt isg the teat gtien in the ar rsfe~aaae, pp 474.479, with the

edaptatia s 3s the digM at the zm4 1se to eecoun for the itt •

to a ces 4ias. In 35FL asi1. (SM Attaa~ea I, Wthod ,tee' Total

Cbt~edvm ;~2

2 aas P*b1t Seilth Ate,, Sat Taut and tr,ter . ~ Edit3ez, Prepared apd P b

else ar-bg the UeHlth Aswe af1± n, Ameriae n Trier West aotii~autm sad Aareri 1''- 4 Cet.rat Fsd'*i (Neat TO*i Aeeart Pab3 1

Hessith AroadatI . 1965).

II0I muimiiimimmmm ium iBNA02551585

UHDMSE00638024

SAM 69-5Page 6

ThImttedf$te awl rda 4zwlnbd *mmdnwtim of o4e, 4=-

vas as as mre3st the oeiete wataae. T ene. sopl,ss bee►e

tderrtLfieed as the ae mQ idum the of nauLlow tad to the pwmdo

the reeaeaey'd~xe the U%* spledled a" muwwn", the glat#.er 1es4im

to the p4nk at the dLLoh m*mmm to Mw=ur P w4 and egbolt mwplmw

C the atft*Ad am* 41mg the oaf. gamraea chrodus +a da we

1a 4hvgmto .&a*, La rum, end the Mdomde

ten, Cr " ! die titetei vl tom,: the a+mLrd mum mad* No not diftimu

to 'wee. Isad al shat g amuse w ab t s0 _alma at the

sera=had ptuft late losom Pnmd.

The O U MiV2W a the IAGLdw* .Ceirv a ShMod 0.0 - 0.05% Cyr .

An asphalt ssa~le at the an=ted maw =a the TxaasPWatUn B

erg avd 2.6 ag Cs'6 Qu a pdese% The off2wo suipu fray the

Via' alms the a#dte a@ the CES , .efIi 3001D l_ Caro. all WO&NOWv

4A D/668 diW of the 3rm idts>t, the as to IaeMW Pgs'rd dwwd

] 40 p¢s Cr'. xtiwacifat lye Tom. Indmaduff atdtetrad the 1#am to

the Bons =rd Ca gwaa sun TUXIMIS as ,eU, as the Al rs•a t teed lima to

than Alta b s t.. nu No to Abop oe a ed Veber fm gait

t=hat A . aeri at tans saran 2 ponds

an van an the Aa„* resisl* um* Awmad at thte aoer a d=*ad

e*aar mh that enly the rwd Eros M add the Axes I >eeaar r owte

heated.

iimmuimiiimimmmm miuuBNA02551586

I IHDMSE00638025

SACS 69+5Page ?

By Avg~sab 18, 1966, the Xas .w Pst l ~~tabd33asd a d: about, 0,8 ppt Ci .

tws a 1a* In tbs dam, a4~ the awe at abm~ anr-~33a.t p.s' adanad e,

bt$ he p Vtd tst r lid to ;pmt ths sv4M gii4 ~fIt1im ti's and.

pssaalsted ash ales t the aa€alaar simppb! fa ems,. p8

and id.th aill*ti 1ta abant 1+00 pyat Sans then a~ Ae II aapp at

3T0 p~•

Atteralas~ 11 , Ft & 2 .359, domed A , 1966, +dssaslbes in d#a

tber tlr* sd ead this alt. i s 3sasowmncMd.

hs D4" A 44j It t - a~ ty 1 sda1 na.oCitig

.I r the stab L2 a paa~3 amd . a the d vs

cysad.7:~3rg 4 sIXUdIXh ]q+r at M4U1. Dntd.s the V..1C at O tabV 9-5. 3.966k

twottae lee tyre Led heU #se e3 In the dag

ta''t31 t at atht tddi& t A~ 1 toss tws bdag m1rd ti pssp.~r.

This t tsr '-t ann ' ~T I1 Eameiag tt isl

aets3n tttat4 the ttlaspL a +rtattta.3atd.d.

8a~asta~nrtw? , . bs191r~s the paced l+o s ?Md @e>ssd ant I .4 io? to

datdl#.4x~g pnrMrr,~ .ash ettd the alas a 7la ss of the

t wts r * 1 m r s ed ZO be a .s md. 8Iaoa BostB ] srt sitaty

s*ge2atiaasr it hdag as ee aw d* , to ss mars Lis

a~lageas ~a d y ah aall. #3met ash at the nsa p.itvrzwsd an the

II0I muimiiimimmmm m iBNA0255158]

HDMSE00638026

&9 (BLUP* r0400.0 ffi 6,7)

22.6 (Aver o ,01 2.5, 23.2)

'D.~T]waSl4i ne

Ismw and Swill l for Tool Mavadus

isoir IM ample 03 211i' Total M=Id=

I& MM lid SWg1 #4 Adha. at P dftr Taus Cbp=dm

Iue& rssn

3

$5

6

#7

#8

c- 41 ppR

-Or w 67 nu

Or 14 WK

Or is 33 An

14.E

7.2 (A i'a.. d 9.0,9 5.Q

15.0 'sorer x14.6,V-38 I

164

18.7

14-4

9.7

20.5

18. `

10.8

iimmuimiiimimmmm imiiuuBNA02551588

3ACUM 69-3pap 9

d=RW - t td)

#11 10.1

#12 M9

7.1

34.7

21.4

► 30.7

#17 1..1 Ye s 36.4,40-80 "

The at" of one - t. to t. tYZal. $ngLmwlzg De &WIM t

W111aeadiR aaaiEaedaajaai =dada tar i 1 i2y r eed bar tb. Zn

a U%4/n, the, a UVAtSM hW eaaas 'rbUL1t i' Z RAMS

Tm odsmse xeep m toter. dba"m IVAN <s syoa s parani ml

to g*. we* dorso xamr .

2) 8UItsdrisd i poaa. (s eg., MMUMMI =wttcr1eg plug cmdnW=

at mmm mis aoarp ,s is tsr 4=4 m airs awSA ed IW be*-

- 3ntrtam.ar) 3aMaiitr.is =001 4080 owatime, rq-isse tus

peo 4 1 labmmau7 A •11 Uiaae, at tbmn xwA

be a . Tla s, end VIN aff-p"Orta "loam at taw

LZ~ra .-acf311Ib Maas = at mltWj it use aae m3 for tw people

to be m dry dr+lt the 32 hamea5/dgr > 1 .

iimmuimiiimimmmm mumiuBNA02551589

HDMSE00638028

IIDI muimiiimimmmn ium nm i

punp.:

1

ion cn

ca ALFA

Industrial Fxag .neei•i .na .ad:tanks but not, vice ve'ha <

11'

~+`: { iori I ~rae~rlel fie: ineerirg

j K tie1g.. )

Os K

yy"'I 'I Alga C-1

` krA i ou_1

AX3l ,s ?@_i. o s )

SK 1,14 pord

r ?W :~ iit Ord

1,7

(3 .: ~Za Zonis )

r Fly

r

~L"u~S25 t_ ._.. ..f-:xt