Ics Chemical Appendex

8/4/2019 Ics Chemical Appendex

1/81

APPENDXA

3 Tnandd tihft vdre CrLu.1 PRuti@ry pdndpLs5 Tdic vapour dcie.tld.nd F'3hil prctibk cquipndl

Al IMO Cod. R.quiEndb

: H@ io @gn&. Fdroin'g3 Ficr.id.na tuihE.e4 Emgart hl'Errrcrdiry lo *F @Eof .xptu

1"4 Eo.rg.fty S.idul6 (EDs)

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TOXICPRODUCTS

This ryfltlt drltib6 tlc ututz al tarnitlt in thehnnb, ond ndmts htu to abid or lihit .tnfurcoldtun bE b th,n 4fuh rt rt{ bti4tv ooti"s !|ip d6ist ltdw6 ana ?qnpn?nt "td,1t,lbr.hn. p,oxdtot t\hert ta f"d titi.. d tatwnt in ttu 4,1 ot tidukt .rwn E r"ddtn.Th, app.ndit dlpsmt kwt alL.he i'ntnnt an qJe th.wal t'ntu pmtk '.orkifl.d

i, ,t

able c,u$ cirh{ hrm b human 6lrh, Fious iniu^,ordth Toxi. m@ns hc *mc ns poisonoB. Toiicity is an inrinsic proFdy or a.hennaLwhich mu l]amor n ditu, :nd ie efiid i3 a tundion of ex@fte rn sne crs,.orrrbpotue ro ib erf(b afrer erpGur .'n dininish ns .onsequa*.

rnerc rF rhR mnnon ways rhat: .argo can b bxi.r swanowed orrr roxic y), absoddrhtuu8h rhe skin, cy6 d mucos mebbrancs deml bxicity) or innmkt (inhalati.n rni.,iv) A .hemnar may b biic by moF dun mc ot rhe bukr roicxanpre, bnc \lpoun ,nd nisb aft{r prcptc m6r via rhe apnab.y sysLn bui ihey cmalso be bso6ed rhrush rh. srin.

Thesm ler rh quanriry or de) of the suSshnc har s requied b ham hhh, ihe mopb( a subshnc is. rn $me cass rhe r.!ic efret ot a cheni.al ce b..tunbrd bvdominLFn13dlhd,,N. bl r

'nm6r,,q ln. t:,rd r J{ bedo'dd o! rcp r;eo.

proar\p. o' n r3 r.,cr nlsdpp" atu"4nd vcnrit 'o' p'rpd nF I'i, L b lvFpGuF bthe chmical or il cxposup is rdu.ed b sare s cls, rhere can be no bri. frrr.

ln tanler opratim, snra.i wnh a hquid or inlulabon of a vap.rr a dr n$i l*cly fomsol exposuF rn 3.nRL propr pr.edoEs and prcper u? of peEonar prorRtive equipndrwir prtvdr etArurc rnd ihus rhe dr(6 af bxn y.

Ton ilv d be a.!rq sub a.ut and hmni..

Asrbsbn.ehasaorroxicityif asnrgleapdrft is rfi.ientbcau-hamalno*imdiahly. sub*anc shnonly called ponms have rrrem acur bi.iry.

A slb.bn e w h suEaoh bxicity dbprays b en{h afhr a puMn has had repeabderFosor b d.s too shall b cau* m .rure .ffet. Exrmples arc alleic ensitisa, whi.hindu.e rcachoB io oiher strbsbn

Astbshcehaschldi.toxicitydms io ros b caue any a.uretflthgas and muia8ens shich

Ar3 Tht6hotdint utre trLv)

if ib elfecb .pp.ar rlrer a priodeffd Ebmpre.aE.amrcsms

A thftshold linii $tue r.!, givd tub8iare n lhe ]ruinum .omnhtim ol ib lapor in an bwhich t is brieed Lhar Fa:dmr mayh. eiFEd unds.dah dmtubnc wirhour ff.rinsadvft efhrs. vrnous Sovemnmbl b.di6 publish ws. Ihe shoJd n t b eearded 35L\e

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fie bn krom list of TLV5 s isued by the Amsi.an Council of Covmnmtal IndlsbialHy3i6isb (ACCIH).The al@,re qdar.d .mually in the ight or lw knowlcd8s $ it nimponanr b Ftur b rhe akr edfiim. rre AccrH def@ rh@ careaorie or Trvsl

. Tlv - TwA Gihe weighed aver.E): rh. .ftdhihon of vapour . aft whrh m.y brery.rio@d ror an i3ht hoLr .tay or a0 hori wr rhsr8nod a pe6m's workine lire.

. rlv srEL (shod rem Exp6m Limii)r ihe maxinnm [email protected] vap.rr in aiiallowable n a pnod of up b ]s minurs, pmvided that thep aF nor noF rhm fourexposub pe. diy ,nd it leai.ne h.ur bcklt. 6ch li is alu)3 sf! tlun th Twaft h n.t givs tor all !ap.r6.

. TI-V- C (Ccilins)ran rbsolute maxihum wh(h should uve. b exded.li is sivm mlyror rasi a.tins slbsbn@s. rhis is the hh6r or the $ie !al!6 60r a sivo slbst ne.

A.r.4 tu.alti.nry pnn tpht

abelub dividinA im btuen ef and h:zrdos ondiii(m It is good olEnting pndi.e rolep,ll vipod st1sb,ri.6 60, dininm ,nd a st tuin blow dE Tlv

Mo$ .hemi..l rapouE aE hrvier th.n a' and end b no* ,1..9 the d6k rd ,ccumlah hlow spob, tor exrmple brld punpi)m llmr plates. TheFrore ahcph* mples shouldalways be hka in su.h low poinb whF concobarions rR likcly io bc hi8hc$. vapourderRtion is covred n stjm t 3

r, F if pondnr n,rr ful.h.a.,n.ua . hom bJ pq- m"L $hel. iNpedina pipelincs Jnd nachinery lor leaks,. dealms with a..idenlal leakr and spillaee,. .onndinSand di{onnsringhlrsand ld,ring.rm;. iarj$ urhses and s.mpl{s fron bnle (wheto r*nded 3au3i.3 is peiniffd),. enftrin8 flclGtd spr.F iu.h as prmprmff, .o{terdans and aks

. opning up pumps rnd lluiPment(mls

cadified 8as ree).PeF.i:| prdRhon is!.\emd'nthapFrc.

conraimeni is rhe iret objRtiv when any rori. subdamA are handled, by ma*ing surc harihey shy msde th. crrso synen Fnginenns rnd ship dsian featorus will prcvide a *o(stirrgespre Ird'eEisnoerposue heft sndbiicirydrig6,how$erh:7:rd.usthe.henical.an be . kakageofliquid or rcl.aeolvipourmnstbprcvend by repinA rhe..rso synen .1@d unb$ n is ,bsolubly unavoid,ble ro opd i

However, $me operations n vibbly involvc opmiry ih. sy$cm; for exanpl, dis.onNhng. hR trcm thc shjp's man,told Jtt. htnstu! of.iiso Alihoush (his sshould br rgarded as Nnp,rabie hoopning p a cao line elsewhee on dEIe andoperdoB nusr weai rhe neesry p.Mnal pmidive equipmmt

A | 5 Tti. Mptut de{han r t ptaomt pmirdiu stripntnt

The BC Code sp.ifie ways o linii *pcuF ot ptMnnel ro biic vapou^ Nhil .a$o isbehE hmdled, or durins caria8t ar $a.

issions by .mbollins how car8. vaPor6 are b be vPntedor fttumd b shoF, .nd how tanr ontdrs ap b be 3,u3d Virruatty aU oxi. .a$6rcquirc clo-,i or rshi.6t bnr gaugs to prevenr aes bcing drposed o lnsate

Se6nd, it spdfics vmtiiarim oI wor*ing spe su.h as punPens, tquiG Lhe hiP b.airy equipment o dcrRi vrpouB, rcquias th pDvnim .r pe6mal Peiive equiPmot

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and, ro tuue rhrt bxr rapoE ae dilured b sre oNentations b.60rt rhey .n rcacha..ommddatun are,s, r4uics that tank rcni svsrem ouilds are mhd at, satu disb@Gn. $fe disianc sp


5/81

^11Fn 4 aid ndfuth.t er

A ri^i aider s mt jrsr a peen piin good,iu, but: pMn wiih rainiry MFAG setion 5outlines nmdiaie li6r aid, i.e. heahent lor finor.asuar66. or b cn$L a vicrin ro bmoved so dEi flrdEr rdrheni .an b adninisrPd.

'Il1esiS and synpr.re ofnird pobni$ usuany slvc rer a few houF in the majoriry olincidenb, padiculany ir the degr ot exposuF s small Holever, ita gFatu,ntunt b bkcnin, or ihe period or exp.suE is FolonSd d rhe.hmnJ is vdy bxn, symprom my peaisrror nu.h lm.er, evd n)! ene davs

The parimt's ndihm nay onrinvap.!r, and sydda aItu ts may appear. Fimltt rhe waminS n giren rhat deaih nay (.u'

^] 4 Enqh.! nnndt addi4 ta th, to,k oltxls"t?

In Chaptrr 3 oI rhc MFAC, Senerar dvi. .an b rtund d rhe mery{.y rFainhr ro b.adminnEd a.odfg b rhc w.y ihe cheni.al has drered rhe body, fo. sample by skin oreye onrad, i$esrian .r inhararion rf rhe chemical has a t{rpd botn inelarb sh@ld 8er pdodry for arknrion. t nre .hem,car ha3 brq insesed, ft pariar sh.ltdmt be nade b $nit bc.au* rhe vonir nat enrer he 6p;arory sysrem and add ro rh.

Appmpnah FachoN after exposuF b $e btn .ar8c lnrd in rhe Mo cod6 aft Sivm byrabl6 in MFAG Chape.9. ]neF ae 12 Ssup bbr6, brt five .hemicars cquiE rheir omsiryle subsbn@ abl6, b(ruf they pa- panicular .ombimrions of bii. hurds (cirb..disurphide, allyr al.ohol, bruenq a.rylamide ,nd bia.syt ph6phrk).

the key pnoriri$ ro rmcmber l hm FadinS ro a .asu,rry 3r:. md for herP a.d frorm the msbl

. remove he idin fron th. d.nsn or vi.e vereal

. u$ brainin8 apFa6rN ir rhde i! any suspKrm of toxic Sass or

Tne Enegen.y Schedlre, are an apFnd*

oprarioml Suidrce is Siva in sdim 33. rn brGf, ir it n $fe ro do s, spilase should becouRd for sub*qu.ni dispNl, bui iJ ther s any doubi, the spillageoverb@id sith pl6ty of w.br bMus the stety of the cta ta*s priority over ponltiM

b th. IMDG code ad provide masks wi$in os ol a.cidmb such as spilhge or leak"ge of

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a,r

APPENDIXB

.2 Ptediory Prin.ipre

.4 Balicor alr,lire eubobl

.5 PM.r Prcte.riv qliPhot

.3 FiBr.id and unher are

En.ra.ng Sch.dur6 (Ens)

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CORROSIVESUBSTANCES

mis @di,dstib6 th.tutlt of @n6iw63it.rfliak,r i iiltslw k md u Lmilcp6un aJituMb.E k its 4Jtds. w! or,,in8 sh,p daignlet 6 [email protected] thituptutdbn,tndptnia6 ad!tuon tetmt h th, Mt tniddhterp6u.. tltappddit tl6 ,ot t p&t tLl h. 8lidrha o, srf. .htni&l tar*rt ptu tn6 .nhivd tn th. op?ntnml

Cotusjv subita.es dBtoy hunan ti$u on .oniad (.9.skin, ey6in rhe mourh and rhe piniory raco; metal d other mardial Lcd r. ship oNhchd canrlso b..oroded * an ex.esive rab.

In .hdmnal Gms, an ,cid ie a bsh.e mtainin8 hydngd whi.h, when diselved inwab, b.om dismiahd and generars hydrcm ioB. In hid .oncmbations, mm/inorsanic or niner,l) ..ids pasivat. ni ld 6el rathd th.n odrltc it 8ut if th. add $dilutt l by waer thd rapid corosion will r.ur.

lhe mon .on6ivc oncmhabd aod .a'8e in lude n,h. ,.id, sulphuric acid,.hloosulphoni. a.id rd .hldoPnpimi. &id Fl]mn acid ed a.di. acid d al$ highly.omsive in MentatioN abd 90/. S.me acids ar calld miry rods beeue or a.harachnsfi. apFara*c as hey gile otr .@nve a.id vapou6, dunng whih lar8quantitiei oI acidi. lunes ar Seneratd.

A.idsc.nalehavcoiherdange6 Nibi. acid s a p.rdtul oridisin8 ge

never b trsd b sllRt spitted niti. acid or ottur didtins asenb Su phu nc .cid ,ndchloculphonic ..id 6d violstly with w'r.r, ine eaction Siva orr alge amomh ot h.atwhth.'us6dEwaldlob.jl,s.mdahage b rhe body as well as h. acid bum ai ihe point ot onbct

rhe m6r omnon .omsive liquids ar rids a,d bas (ohlr,ld), and an be orsanr or

'noBantrIt m6t dangerow .otmives caR *ver bum arier a very shod rime. som

n rft prenc ot warer, or pmdu.e .oncivc v.pour whm

8.r.7 P atti.tuty ptintiptts

ce&in prorEtion a8ai.s dP advePer$nnel should w6r suitable and ompleE prcEdile clothins whm .otMive sub*ansmbc,ag\dndred qirhpdJ ur.tr,rhn'ioa onA pmF. non

The ship itselr al$ neds proretid agajn*.on6jv6. Trl sfe snbinment ot onGivecac requnE the up or corGio dion or crSo ianrs andthehandlinssFtm, n.ludingcverrthmsth*iseven emohlyli*lywith ihe c,r8o. OF,toc ,nd crew nrsr unde6bnd rhe danger or.dosid to iom, ship

er e h3v n .rs or ships einB Atoyed aftd str.h

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chromsulphoni. acid, dicNobpnpioni. a.id, hydrehrori. acid and olem n bnc byinhalation; chlordnc ..id h bnc by lr36tion. Adi. a.id and aetic anhydnde arcnamhable Most orher acids ar. thenelvs non-fl.mn$le but, in FneBl, acids Fad widrndals io evolve hydbq which is htNy na.dabL.

s.me acid s have a ret lilely hrsh fczing poini, and nccd to be heard oi ea h4poi bprcvsi solidilicrion. Exanpls aF aeri. acid, reun (who* frezinf, pconcentntion)mdsupe.phosphorica.id.

Basicoralkalinesub$bi.s rethwhrch.onbjn theoxidrile bupoin wars, basn subsran.es 3d dissi,ied and g6n:e oH, ds Basic luriore .onrain su.hots- ions n hisher conenrGtim rhan pnrc wier For eranpre sdiuh hy,lrcxide (causticsod:, NaOH) n a basn subst.n.e; dissolrcd in w*er ii gds dissiatd

Comnon ino4ani. allnlb such as pob$iun hydmxidc and $dium hy&to aruminim, zinc Salveisd (Rl and ne@ry s rhof makri.ls nar not b Fd in tneclao.onrrimr slsrn wh5 dryi.g such chdicah. other oiiclve alkalis aF aliphahc:nd alicycl{ rnires, pyridines, edium sulphidc elurions and ammonium slrphide $tu6mt

he pnnary tuk or rhe *ondiry risk aftr tambiliiv.

A.id and birc substan.es ad to8ether o fom slh and wahr, orhnof heai. For aampre sodiun hydroxide and surphuri. acid reacr o tom s.dim sulphare md

81.5 Pnimt .lakdtu ?qtipnQrl

As'ready

indrared, ihe p.incipal Fokhon i3 o avoid *pcuie by abinside rhe .ff3o syshn H.e ever, pior&ti.n i! a15o ed..d is' in * rccdorhes and edher looeear pbvide no badid aSainsr orosie riquds Therefore uirableprot


9/81

systeh. Cdhl ot leak m dE co der h ako addE*d. Spmy shjelds m rtqrnd 60rd8o mani6old mehft, ro pBent.a4o spraying o o sumrdins {ruduF.

'Ir1. C.d6 prvmt my cFsHonbnination or the fuel oit sydn wfth a .odGive .a4oi bydipurariq rhar he r*o liquid handling sysreN aF tuul ssEsabd

A r* ,cid eFs aF flamble bui ih. nd flrhmrble acids d Fad widl netab 60prcdue hydog6. TheEfoe ii is podmr ro hat acid oes as housh rhey weFtlanmable liqlids. A Ilammabre bospheR nu* b sGprkd iNide rhe caryo sy{em. in

vdd sP,G ,rdund ca'ao hrs, in co plnpooms ek. Ehcbical equipmr in su.h spic6n6r mmply wnh flammabte hospheP rcquiFmenh for hydrusen-air mixruns

'nle eo tundrn4ral 3uid6 tor nedi.at 6rd 'idon bGrd shiF, which Sive adviG on

dshS wnh elposuft b onGive .argG, arc he rnisna6onal Mdicl cuide tor ships(IMCS)and the Medical Fid Aid cuide ror Use n Addenh tnvotring Dansercus Co.ds(MFAC) soth an published ioinrryby IMo, n.o and wHo. Tne rMcs

3iv Saidan.eon

onmon i[n*s6 and s not elely .mcemed widr .hemicat &.dnb. Tne MFAG issuppkmmhry to th IMCS and o ams dvie lor Roanis4 and ftatins .hemi..l bums,w hin the his or the facilihes avaitabte n bo:id

TlleFeneral ulc k rhar t dtrdng d\. handlins ol chdicals, any peeD shows symprons tharsr$e* .hemial bumms, they should b. hated in

'..ordancwjrh I

ddbr as sNn :s pi;c6cabre Med cal ad v should b sought by rrdio, while iil ar *a.Asnhnc may lso be available nm rnother ship wjlh a ddbr d board

spRifi.advnefo.hcfistaid rEabarol.hemicalbums b3 en n sub*dion 6.7ol $e

MFAC. Cheni.ar blms ard very smilar ro fiF or etdri.al buns bur wnh rhe added dsk iharthe heni.al may be abslbd drblgh rhe d,nrlred skin and aus tunher dahag thowhpokoniry Th@ rynpbm rre dribd b hetp eosni (diaSnR) burns:. burning pai4 wiL\ rdn65 alh poinr ol onbcr (rhotrgh breds onty an i.ibhnS

. in s ere.a$s, blnLrin& tos of skh md unddlyinS ssuel

. naRa, vonilin3, h6d,.he brarhin dilfiduies and .onfuad henbt *areunM$iousn6implipokoniqomplicabons

'Ihe basi. iRmnfd*ion b b ch(* rhe h.nical dtu sher jhnedbely and adio fo.

813 FiEt't a

an a nr n nr t

MFAC sedim 5 oudins imncdiate li6r aid, i.e. ermmt ror iinor csualiies, or ro mble aEahent.d be adminnired.

Il'e k.y prioii66 hust bc rtncmbered when reacting o a. sPnd or helP and nr.m rhe ft*er;. do noi brcnc rhc ncxi viciin youNrf ifrh. espons

. ftnove rhe vidih fron $e danSs or via vre;

. w braihiry .ppararus fien is any sNpicnr ofroia gas.r vrpous m the area

nh very raBe qEnliri$ .t wae! rhe vi.iin s.lothrngrnd shH shourl be rs.vdd while under the showd Il a d a ninuenrered h eye, nGi b r4ared dmediary wnh pteniy ot wab for a nininm of 15

r rfa.iqc cye"8ar

i,^Jnhn

nd)bisn you lme rhm wiir

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FFt aid6 nct al*ays w,sh dEirreahdt, 6 bum may sily devlop ib n'rRtim. cotm wol d dhr lity mhdalsshould notb u*d tor cleaning bums, as hey aE likely ro leave bib in the bum Blish3hould be .rt inrrct. vaslin gau. drsiry shoold be 8d b ovd be ftat tne desing dc nor nk b the dffiagd tr6h

FiEr aid advic cmcmiry gmupa of oreive cnenicak r siryle chenicals s sivn in a

nuhbd of bble6 n MFAG Chaprs 9. C6op blle 7tr0svm acidr iftlldin8 inR subjRt bihe sF.ial Fqdrmenh ot rhe IBc code. Tabl 610appu6 ro nitic r.lows rhan 704r,, s i n Ikcly b grv ofi nituga orid6 shi.h aE h*) y bxi. b the ugs

eftd by bble 235, L\eSraup bble Io

The Enelatuy S.hed sae an appddt ta L\e MDG cade md pmvide ,mteB wioradvi@ on rhe mmdiar adid b b br{ in cap of addenb su.h a spill.g or le.kaAe ol

Tr'e espde ro a spilage will deFnd on wheF rh spillage NN, rhe quutity nNolved andit Fmedi6 omr h:n wat.r aie avrilable. f it is slt b do e, spillas should b oll


11/81

APPENDXC

.1 Pq.tid.h|lfridis: IMO Cod eqd@b

c-, ClEic.l. *Iici R.d with ol'!.n.1 [email protected] cha6-rrdi6.2 MOCod Fqui@rs

or crtdkar. whrch ln cdr.cr *t0l wr.c En n ns@r c.4

.2 DdOCd. equillEb

c.5 rn mPrribL chdJor!.1 Reclid clEEcErbriG.2 lMocode Equlftmdb.3 TlP USCG mp,rib fty d,r

cJ Gui.bna rn di. abme of ad.quE r.divfty Drh

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REACTIVE HEMICALS NDRELATEDPRECAUTIONS

ThE wndi, d6tib4 th, phr"Mtn olin@tunt ehtni&l tddins, and attuttzs h. paiiylrls4.tr h.ads to 3hry! M tt ri6 tn tuntu DJ h. sh+ d6itn utt6 atut,quipn ^t

intntut toratil,ltotttbn ,sai6t .!ch @dions,6 x:]t 's

q'id'nQ Dnel. laeduEfu datins uik thd.

In gendaL chmiols .am.d by e. a iabl md, povid.d prcpr and appropririe caF isbken. ..n be rdded, s!o&d and di


13/81

is exdhemic It p.lymristion n sbn sp6tans6ly, !h. sub.hne i3 called sll-porFqising. Alrhough sponhnsu polyndisalim .a lftr at a6bidmore ofrd inuiaied by a. deivdy hisn tupon FnFne.

A spdtandus porymsjetion of ine ca$o plsb eo khds or danerG Fi*r, har n3neiakd &riry d1e aciim, which hay Eulr in overpre$uE iBide in bnr, wiihrcRquenr ruptn of lne onrainmar. send, ,hile the monome. s ofin a ishi andvolatile iquid, a5 polymerishon pMeeds pnnre heaviE and nor visus lqude or{en slids, which my brek irr bnk venb $ thar ne DHsw icide

hdher. Molwr, il dE pmblen is not deh.red in rine, the hnt nay implode while bin8

Sl1-pobmsierion is pa{rd by in addition or a slfficidr anounr ot an apprcpdahinhibnor b dr drgo and by onrrclli$ rh hmpratue ol driag.

C22 tMO Code quneme"ts

Tne rBc code sFirislhe pRaorioG 60 b bkm asri.* spmhAx dRompditi.n'nd

na$ of th. prddud, and by ontul of the Gdiage knpmim.

Tlp Cod m.ks the mulacturr oi ine unsbble chenical bin3 canied, who is noi.c$nly the shippr, Bponsible for providing dE ship with r nmb.r of.dn.3l efery,nnn, no, mn plM3 rhp"dd ovp d JF fom of4 ed'fic.b +obm3:. what add,nve h3 bn or should b hblu.d inro ihe podu.r, and how muchl. when rhe additive was or should be nrFduced, and for how ronS n is *F-trd b be

nd h dder b prese rhe elfe.rilens and ifetim of

. wheihs oxySen nu* b pl?gr in dE liquid in! ar jnhibiior b be etfective,

. what adion should be raken I (he voya8e asb lm8ei than the efre.t of rhe addfiive

b .arry a pi.dud pdeed by ,n addiiive rhai neds

volaile, $ ih.y do ..t vaArds sih r6e arso and apunlik ly !o b pent in ca$o vrpouB. TnercfoFi wheft carao vaFac condee, nritubnce icide vent v,lves and .ne rnBt6, pol)meistim mav m.ur.

real $lidi6.ation ot polynensins carses, $metin6 relrred o as rtsb.a4. systen sholld be pr*entd, ,s it may alfect he unitom disbibution oI th. addirivcwirhin dE lllN or rhe ar3o and rhpfoF anow err porymeiisarion o srad n pad of dr

ThelBccodeaIs.onlainsPmvisionsa3aindiheexPoslrcof6qobpreveniive usure indude prohibrhon ron c.ri.se in bnks or pipNd for prdo.rs whN refpeadF h high

6ough biinae

a Ei.tioh in rh unsbblechemical, nd .ontols on hahng oiG and N ol d{* ranrs.

rhe tanr shoold be e+ipped wiih a hh hnpdatore alam

C\1 Ranio^ Jatrdti.tns

S.de chenicals ca.i unh orygen d6 *uhout any nput orddidon,l en.r8} One E6rp o{$ch $bsbnG rec slowly wid\ ort8en h dE an and wiin ory8m drh i'tuid, ro orm lmhbL peoxids In mother aroup, nai.ly naiural produds, th. oxysenjn ,n alhws a pcs .f dshp.sni.n calld puteradon, Buauy by dE acton or ba.reria

Or8mic pmxid6, onc fomed, n th.mally lmtable, .nd the nain drger is that ai nonalor elevaed ehF.r,tue, rh.y are I

110


14/81

dmmpc,uol


15/81

speined a $t predure lor doiry s Eitner ditfeqr w4hing 6ans shdld be dployed,or tne FoceduE uFd nu* asume rh.t dan3eous Eas will b ditrd md .oddmasu sriplrahd b avoid eiA*ing psennd ro danSer or tne snip b harn.

Ch.mi.ah belonsins d dain laniliE rre kn()M ro Fad with thos oldims .an be hazardds cener.iion ot bnc 3rs, heahS

of ttu liquids, overnow and ruFtuE oI co hnks, and fi& and eiprGid are pBibte.on-qutrcs Ar rhe very lea* the (ar3e will hrve .han3d heir mtuF, and equiF

Tle cla$i. case of imompatibility is rhai bdrm an acid and an alblidher b rorm a sau prf sarer. sulph!,i. acid s in onpahbte with aery other 3mup. Niknn.i,r is 8enrally mmpatible wiih o$er a.ide ex.ept sllphunc. IneE i $ne ohp:tibilitybd{en o$ani. acids on rhe me hand and .mid.s and aronaiic mh o. Lhe du AnonSalkalis, aliphari. anin6 aft a sdsiiive 8rtup ,s they ar in.onp.rible wiih al1 oiher Smups

c.5.2 rMA Ca,1? trnddh

Ii.onpatible cheni.ab mud of .ouF b *ept sbictly s.parared rom sch dhd i]'nu3nodih diire .al8o.oniainment and hmdliry syseh, !n ordc! io

'void:ccidenial nixina

sparahon hould be achised by h:lina ho barricB b.tun rhe conrainment ysrem of ihein.ompatible chemi.ab. The bnks sh.nld be sepa!,red brr a co#erdrm, rn enpry r.nl, a voidspae. r tur conr.ini$ a mduny onparibre .aq or a pipinS tunnel T]le pipins orvdtins sysEtu for inonpatible .ac should be sp.nt.d by rmoving a vake or spmlpiRe and blankinS orf d,e xp@d pip en.L, oi in*anb3 Ro sptade lr.ng6 wth ableder or equivalmt maE b ddEt lea*a8 n dr piF betuR. the sFdade nanSs.

clonha a bnk and rhe prared crSo handrinS syskm sh.urd be p. omed t&ioughry if.msutfie caac .re inonprtible.

. 1.1 Ih utcc,anp'tibi|4,hat

sveEr aurhoribrive bodis haE d,vided .hemi.al c{scs inro Sroups, detiniry. .ria forin.omFaribiriiy been 8rcups, and h,ve published hb of tuonpatible .ai8s Tr,e no*lanilhr is published by the Us cd$ cudd. Accordiq! ro $is burc, a nn&rc or eo.hemrak is .oNidered haardo$ (and he.hemi.als in quBtion ddaEd inompatibl)

Th.ompaiibiljry guide asigns ea.h bulk chemical aBo ro on ot 22 Rcrive cbup. and 14Caqo Coups Readive ruups mtain tho* .hem(rls whichare h md,nseous re,ctions cin b. iddtified bereen nehbec ot dirsdr Reactive Coups ,nd

psand c*Socoups chmicals signed o caocrcups ap mu.h lss LE.hve, and do not anct dans.rously q{cth.r

whe$er .ar8R wirhin a pair of grcups ar in ompriible is indnad in r t.bl., lnown as hecompaiibilfty ch.n I r is imponani h noe $ar wh,l. ihe table give 3tfmbotB rnd ddi shes ror iwo partidlai .ai3es shobld alsays be

tt2


16/81

It c.nnotbe str.$.d too 3trcnelv h.t Duels o( (hemiels should nor!! ij!:pt"1J",1:llfT:"t -

lo:iled nro ship unr6arDeitiv..as6urance s available that the various.hemi.ab arc compar'ible wirhin thes.gtgation ..pability of th. e$3e1.

Th@ r6pdsibb n, soticiiinS, sheduling md lddhg parcels ot chemi.erisfy rhmplvA dut tne adors parck rhdule'i far any Sivd voyase of any BivenshipaF mrtuaxy conpatible and cu be sat ly loaded and c ied wihin ihe nomat

-sEAationaPabir * ofrered by rhe shiP.

Tn uhn,e rporejbiliiy ror the srery of the ship ti6 wi$ in maste!, who should erounfidr rhp,do d \h,burnn prcpos-d ora \ovdBp ..'d.. omppr*3F3ar,or o

vlll rl--.hpn,.,t. In br tuded n rheddd +4 F'd,l

tpiovide the ne.csry inlormation, the masb should dcfer Gding rhe.ri8 unhl.os'trarion wirh rhe owner or oih.r aurhoi y has poducd satisla.bry asuran@ rhd rheproposed $gre8arion prr f.r .argdr b b sded ir stu.

113


17/81

APPENDIXD

.1 GeHarid of dcturic chrgs Lside a dftip's brlr

.2 Ele-rcbd. fild,.h.rge Elaarim rnd sunae volb8

.3 Chir3 a@ulatim Md rlaxarion in liquidr

.4 GdEarim of dEr3ed nisb

.s Potenaialderbd6lor sprls ro mp h,on

c6tol of sbric Eldri.i9

.5 C.s bnbbling up ihough rh ffIed bik,5 RlaMrim rin doffirEm or filt f

3 Pmietiffi and Pob6 in bn*s.9 Caugiry dd empliry ot hks


18/81

STATICELECTRICITY

mir dpp.tdix dltlin* th2 pt%s b! rhkh sbtn d.dn iry k gd.totei, ani wts ta nlrt? 6 tndsudt sddttion. ]n vitu aJth.pttubv al ud,ttun ohosph.aa tl th. &tso t nk olehdiathnkr, it is twnn nt inpdtttu to rt id tn 3oM* of ittition

D2.1 cdddrrnot.t t 6htn.tus' insinx a ship\ bnk

Tleliqlidflowingi o.hetanl6bed..3dbyhictidwiththeloadingpiplireandwfthin rhe ffi ol np liqui4 pdicurarv iJ t is pasd drough a nicmp.F filhr, whep rhcmbd 3lrlaa b ldgq I rhe iguid is dlowd ro ldl fraly inb tE b'* Gplarh 6llin3)hi.rion wih r|t at rh@3h which ft frns adds urrhq ch,rgs ro n. r{'ha tne Lqnid is nor

sbri. ledj.fty is eosrted by rri.tion tnar rcuB betuen dil{eent materiats du.ins relrtivemotion. ErKr6btic .h.4s ., inen aeunulaE in mabnab which aeldricitv o. {hi.h aE rood mnducbE bur aF iadiied rf h{o su.h 60di6 witha..unulabd *ari. eled.jty cha.g6 .E buSN do* bdher, and r rh dirleEnc otpohtiar i53Rar noqn, lh ac.mula&d .harge wiu junp bhen rhm. Anyore who ha(dived a nild shm* whm iouching a dmrlmb atiei walring ams a ..rFrd rmn hasepeden ed snch a phdonenm rn such .s dE individuar h,s bRme .haed by fri.tionbe$m the carpi rd in el6 of Lhe h6 and the pormti.l a(umulared in dF b.dy isdikha*ed b the tnob Thit rhough amoyh& is hln'ie$. 3d it, sbois dixh.r8e of dari.mur a a spail shd. a lrnoabl ahospheE is pffit rheF h a iisr ot ignitinE t]'e

The prNs whe4by &n may happen n a cnenic.l bd


19/81

hi*ible with ware bur onbire wah drcpld, tridim r.E wha thR dnpra dde byravity thiolgh of ri+id d d bnl. sinibrry, if tlle tjquid snbiB m ufflislved Nas. he\uid n clBr8ed wha ilp ga bdb16 rie ribngh it.

rn odd of Lnpodarte, oE pmcipal .hirgig mehrnishs duins finiry ot shiF cir3o hr*saE tine ilbri.& splash illiry &d rie $dliry of w,ier drcprers.

D.2.7 Ebdtdhti. fdd, ttfl.8t t2tofltiM tnd st4a4 @ftdq.

!'\,lFn a chfiged liquid nows nro a 3hip'3 ank. i afrads a chary of dFoppGih Frarii/ lq $ itrer $Jfa.e of oE hnr w,ll sihurbMftly a cha$r equl ro rhati. rhe iquid (i. m3nftud md polarity) is Fpelld ro the srsal s!rta.. of the bnk wall,wheF it G nnediaEl/ tuhlis.d bdau* dc ship s arthd hou8h llre warer

lrBide tn bnl a difterm in voftage xisb been ihe .haig on the wall and rhat n rhliqud, The volhge at tne eanhd w.ll is ao. Ttc volrrye in tF liquiddish

'rml}F wan' TrEr is a volbge dbhibuho. in ihe bn* spae, caled m ele.*6htic

6eld L hme, tu dEr3 in rh iquid hiqiab b the wall or ihe bnr, where t cmbin6 ,iorthe chaq of rhe opposiE risn on tne mer surfac, ihe lRbratic fPld d{reag andurinably diqppeaE. Tnis p@$ is alled ch:rge elaiahon lb spea depnds upon $e

wnd wab dmpleb or orlEr .ha,rd panides (inpudnd) .eht by Snvity rhrcqh theliquid in tF shjpr tu*, a vdicar erdricar (:llllmr n bbhhed and , hiSh votr.se nay6ult at dE suda.e of L\e iquid. .alled suda.e volt.g.

ozj Chtt* ondulrtan rnn ftbetnn n lqutds

In the ms of $e liquid, charF ge@rli6 orpb wnh chrrse rehxafion: if the fomer isfasr, charye s a(murakd. Tn higher th.mdu.rivity of a riqlid, rh ra$d n rbx6erdctalic .harses. Eldd.al condudivity is a popdt of a Siven iquipi.dilffis pr mdre. chilae a.mulaiid de n r a.!r in liquids having .dductivtywetl above 10piosimem Ipr ndre. such iquids aF clld mndm abn. AtMdudivity beldw l0 pi.cidds pr ndE, howffi, rhe .omularim of cnarye nay b

s*nifk t. Li,ruids ot row .mddiviiy m .alled *aic a@nrr,rm For sfer,, rh b.rder itconventiomlly put rt s piciens per mete

chad rMn, 3enn&d shen splash iftng sl)m li+ids, fty rehh ii3 crDrg 6!ch r@gerrhu dre bull liguid, becaR the rhi. nlm in th oh bubblB poid6 o.ry a vry nrowpath ror th now ot lh .hae rla*tid.

D2.4 Cen-atffi al chae..d n6i5

sbam islin3 rbm a wzre .an rorm a .haBed clord or waler dDplet' A chaigd mist i!als. Iomd duiry {p washi$ oI bb witl high veloc y wab j*. stm3 lriction r.kespla.e alh no,?lei ,lon8 rhe er and by iapad .8ain* the tant wall Mkb cn ltmin

chaqed mu.n bnger $an bulk li'tuids rlanrim NUB only 6 tasi as he dmplebaaSlmsatr an,l edl, 3ine ai. is practic.lly a nd{ndu.br. sucn hBh volh36 can bD.odu.ed thar 50ark! on @r evd in an.

D2.5 lab.i't ekrtna6 f, spn*s b tmp lran

$,no m hrlaid oI Uftadhd el ratic rpl4 ir bcon6chij3d rhre$n the stu lrKnmien d*ib.d for rhr t nk wall, but dE chaB ha3 c p.thbearrh. Aspa can hd jnp rrm ihe ele.hode ro oE hnl< wan. f $e volage is sufijcienrand r tne ah6pheF n flamhable ign id will Kur. Exanpl6 ol such obi{h a a nehlsupll$ m loweEd by a mp. d a thin hetal sap buoyed by foan. If the voltaS s bi3nowh, !t snr prl6s .an br pla@ dm it ihe objed n a nm mbxi. $Jid. At hjshrurfa@ volbes, spark.an iump to rie liquid $rlac i&lt This L c.lk a bmh di$hase.

Lons slug3 ot wrEr pft)d(d by th. hth cpa.ity w,lhing trcnh otnoueht ro have usd incndive disc\arys ro brl stuctu in p.d accidab

118


20/81

conbnh3 ey one of ihe fi6i ih@ sleF liskd in sdim D.t can elimiDk isr ion dm belRhdati. sparl.s. 1P nrmnabl ahosphe is a$uhed b be a.apred.

spldhhg :nd rprryrg of dari. a(l]mularon shoutd gmdally b. avoided, as hey ead b rherdmation of.h,rged mhis or f@N A .haqed mbr.an be 3.iid sa iI the rehperarmd6 not Each rh fash poinf $ sprash 6xin3 and sFaydg ar a dansft vm with relativelyhigh tl,rh point .arg6

Filliry of a ship s ranl should no any b rhfto3h a pip.h.e whnh ends mrr the boron oIdE 6r so $at i L\c cany shs6 ot lordinS, ihe uquid is Sady laid d rhe botud wnmine risinS rrquid mvs rh piFrine .!det, b.bulenc in ihe ran* is considenbly Fdn d andfewe shri. charaB aE 3enftihd.

The ashr the iquid flosr throush ihe pipeline b $e shipt bnr, dE h*ner ,s rh.lRhiatic charg4 To Noid acRsile ruibulflG w hin a *aric a.omularor caq rhveldiy of liguid eni.ring . bnk should b very low mrir the ld n w.r overcd GR s(hon5.3.5).Lw vlo.iy aho linir. any niriry w h water thar nighr be pF*nr in the hnr

Afd $e inld has h.6 subnelg d, rhe flowninimjs rubdre md avoid [email protected] rhe

M6r sbh. :cmulabF are not mi{ibl w h wa6. rre eren.e orr(hoqruf t dr lpr ;Fdde w,rerd;p cFdFpcvd

wfthin rhe rarao rrquid, s far nort iaiic charges re generard han f the caryo iquid didnor onbin the warer. second, h. chaed dmpreb *{re rhmuSh he riquid ,nd Sather ai aninreda.e, prcducing a high v.lbge ,r rh. l4ujd surfae Tnis pr(rqs mykn* nling has easd.

D3.5 cas btbbtinsrplhtoqhut f ,'lhnk

vld t may b ndasd, bor ir should sii

Alier lcdm8, piplines aF orien bloM thrcugh usinS an, nft%en or dhei 3ns. wnd $ega3 die6 rhe bnr fr.n dE bohm rt will is throush thc tiquid in snall bubbles, aenentinaa hi3h vork3e ar $ suda.e. u il is ncsary io blow rhooSh afrer dd;ng a dahcaaunulabr th amout of sas auowd o mter the ship s tanl should b kepr ro a pracri.al

o 3 6 R.tafltkn tin dassrred oJ |tft

Mi.bpor rilkB made ot paper, ddb ten, hmois d a mdal gdd, pddcularly ir dep mdrhick, aE prclific sqerabc ot elftshiic char36 sraineB su.h a prforakd nehl bakeb

Tne hquid b hjghly.harsed whn t levs rhe 6lre i. the oadiry lin Fo. su.h chaq b beftlared, &e liquid has o fiow quidly in tne piplim lar some ini bero s&ring ine shiplhr Preiicl experien.e has shoM rhrt 30 studs is s!ficior. Filh6 aF lsully lfated.shore s the batuit nme tu adequE, but if the dishne bekd tlr 6lE! and tlr ship'r hnk

is not gt emogh, eiiher tne now n& sholld b rtdu.ed, oi tne pip hnglh im*d d itsdimde e'n.r8ed, or a El.xarion ian* should be pditled in ttetum tlE filre and the

r19


21/81

D37 Unanh.dandrctu

A cmdudd hav4 m dRbd s act sith an$ @ bKm clur3ed dd iis in lolbgrrhoush induction (wfthoui physi.al tmlei ot charge) and .ollecrim (w h plrysicartansts). An un@rthd ondu.ior noaiina on dE suria or a .hirged liquid atu.lly ollRbcturge fron it. A .mdudd lcated i. , charsed nis! bftms chaBed ro appDiimately thelane volbge .s tE nisr, evm rhdgh ii .,nnot colld any charye. n summary a ris i.loltase is Pdslble without.ha$e hnsler ro m rarthed .oducb If a spark h4 junps

nd an snhed metat surtae att r}le ened ihe romd h.s

a.tunrlar.d floh, trkrly inro t..pr-r \h,ct rhe'ebE has h'gh**i',.o *.g

Avoidiry tlp pEsmce oI ueiftd onduc!06 in shiF' hk5 i3 of fundamenral mp.dd.eb pevdt i@dive spa*s, b$aus they provide the le.hode tiofr whid a spark can mp.Tn ollowinS re ermphe of oeadhcd ondu.bB which niEhr b prenr inside a shipis

. tninmdlehP3,indudi$rusrrheydonorlroat,[email protected],ed

. r mebr coupli$ ar rF nd or a non


22/81

Duing bnr washinS, a ch,raed mhi is poduced and 5 pFmt rhb!3nod lhe s?r.e. suchnier peFnb for a few houF afis washhg has 6m ro f end. t an unadhd onducior Elowered nb rhe chirged hi*, n b(om6 cn.r8ed to a volbg whi.h my b. hiBh .nolgh ioran n@ndiv sparr b jump ro sme part of rhe bnk stubre.

Ihe limibliN d wahr 0w Gk Fr nozzle, pr mchim and pr bnr h.!e bM $rablislEdby exrensiv us(h (* Se.lion 23.1t and should not be aded Il $ wa@ onbic

.leaniryaddiiivGorisreqded,ordpwashinSned mi.sdherrl,an.tdnearE,wsninsshould b .onduded in a non,n.hnable .h6phE i . rhe bnl shonld b mad e ned.'rheprerimrasFhof bnkw,shinSaie[\eEfdFihp.rhniioobsv rheopsationalF(aution6 ar tutly dKribd in ch,prer z where emphisis G plred d ue ol. $udin3

skm issu4 rmm a nu re wir Benerare, nbr of .haryed warft dmplcb Tnrcfop damshould neer b nidcd inb a r.n* rhat mry mnbin a namnabr. ahcpher

D3.12 Ba.liqtndeaihkE

A sparl cannd ruhp besai tuo onducbrs which aE eirher l&hi.ally boided bgdhd oiboih earrhd, au* ihy aF rept * the efre voliase

Frtudile bondiry is'.h,eved

by .dnNtins a mdal bh betuen objRb rh obl is$miim pefiamn y fired ro one onduck), and botkd or ctampcd b rh orher Ai therem6 able end, ontact should bc metal ro mel and .are should b bledid or ru* dc nor hanpe n Thc oble should b ro$ emugh ro have B..d eisrane nwar md hr B..dhg ad dnhing obres should be nspErd priodically and thcirEbtame d(ld with a metcr.

Mary hcs ed in lMine operarions aie nade ddnca y condudiv. A pair ot nans6bolkd bsdh.r cm be relied upm lor being rdri.any mnrinloos, as cai neiible tohrs ot

mel rdding afr' $ b.nding or jA ditlimr eldnd phsommd is expnemd when a bnrei b .omeled b a shochhnation by a s.dudive he o! a nebl lodins .m. ship, ho*, drelemnk or a badery and a a+ .frent .an now throush the tos Esisbnc ho-, even f rhevolbgediftemcbemshipmdshon issmall. B lnis is nor sraiic eldi.ity. vlhn thehos is di@rd th [email protected] $ suddenly nhnupkd dd an le.rrical rrc .an b ,ormedbeen lhe lla46. r]reft is a risr or iSniing a flrmiabt ahospheE exjsrins at themnifold To pEvmr suh a haad, rhe ship h.s ro be iBuladl riom $e shd piFlire byI@G ot an ituuLhng nange.r a ldsrh of noHonductive ho*, as daribal h Sction, 11.1. js kecs rhe .ntuI of dE bahry optn, and prvdb, spa'k.

He4er, rhee h no ned 60 ooer a rankei b the dek by a tlondins .able sine both aferdhed by rh warer. rhe oFrariml pra.ti.ariry or bnnding abl6 ir addessed n seiid

t21


23/81

APPENDIXE

EJ G.@u Nltrlld Sqplt d tDn ShoE

EJ Conped Nibs&n sbEd on Bo{d

E,s Liquid Nitu8.n shd m Eo.rd

3.6 Pftiv( Ssin3 Adelpdon (PSA)Nitug.n C.n.nb-

E.7 Mdtld.s.p.ntiu Nibg.n c.ndb6

t23


24/81

INERTGASSYSTEMS

ThE pwnnia outlires h? slsm tuihbt an.hthi.'t etnas Jo hdnS at poa.ciry.arya 'nkscturtd 6 {thd suiceptuides eJz\ atuke bdt op.athn l aqfds aJ usins kt 3B tnd trci lcas

ln dr snre{ ot chemical bn*e. opnhoro .nd .hemi.ar ams, an tud gas 6y6efr nayhale rhR disti.d

',grprevenhg a fiE, pEvmtins . clpnical readim or mainbining.ao

Flambre 3as nomary en.oonbd in .hemkal r.nteB camor bh in a ahcpheewhich is delicimr in oxruen, md { inen 8as s undesrod b b a sas used b produc auch:n arncpher by dsplaciry air solAs spe.iiis rhe tndards nR6gry b do thn ri hay brachieved y usi$ eitner nk%en or oir fired fue 3$, w h a ponabh or likd piphaananSement suppry rhe .ed 36 b rhe cargo anb and, t:pplicable rhe placsunoundins rh .ar8o hk Mand.bry $tery Fquircnhb lor ianl< ahsphere .6bd ,egilen in the rBc code, rfr ennple or sysem n$r b able b ompMF for normal

rreru are *venr 9p6 of inefr 8as sysrN dDr on be used on chmic.l canieB. rre noi

. Samus nftrc34 suPPlid bn shm)

. nrbgen aemnbB !ss3 ffihratu epar'6onl

. oil trcd irei aas aemrabB.

'lhere aF (llxioru wh6 inedin8 n not approprtre lor sGt rabnr bu* qcluion ofox$m .our,r .sb haado6 silurim wilh a nunbei of .hdirs who ehippd inmonond tom. Such.hemk.b (e.8. acrylk acid, stlam and vinyl adre) hav adddinnibiioB io psent polyndis.dm turiry b4pdtinM r. order b b. effetiv., thei.niblo6 require dp pl*me oI ox$a dislvd h the nommei, and nar orygd isobbined t om the air in th ulldse spaa. hhibftd nonomB mud thrlorc b.artid inbnls whF ine aimospher h,s m oxygen evel sof6cienr or rhe nhibibr b tolfil ib

M6r nitu8m rsed s ined 3a m .hemical bnle6 is nd ed ior sldy E.soE but forcarao 9uli9 .mhd shipp* ofte. h.ve iheir od speal 6quirh66 bo 6sure ca'a.quality, whi.h 6 ftqun inert 3d or iEm purfty, &d nay spRll $,r nitu8en for iniiiarimdi.g oI crtao st:kG pnor b lcdiry . car8o will b suppli'l trm rhe oadins tdjtul.

Snaller anouts or pu nitqn d mme lom onpresd or uquid nitq{ .mbheBsioEd m bM,l, anl Edled 6!m shoE whm sgui.ed, but a very htl qualiry 6 bFodued d berd by niboAd gturaiG ba*d 6 nerbrft epaiatioq or swi.g

125


25/81

whd shg rn oil fird ind AasBElrmtu, e oryga levl oI lrs rhan 5%@n g*r.lly bobhirFd, deFndhA o it'e qualiy of cmb6dd Mnol .nd the cd m rhe boiier Tr\e gahGt b mled .nd yrutt)d w h wrhr b lmee srot and sllphur a.i& beloE binssuppl.d 60 he care. bnr!. But cftin c.'a6, Ior iBhce $emk,rry r@div 6196, aE56iliv b orygo @hais a td a3 2 0% bt voluhe. Sone c.:Amdioxid n nue 3ffi. orher ..rgG rre hbhry ssitive ro moctu$, or ar li.ble rodisl@tio. Fd rh* @sns oil nEd flue As systu aF rdly used o chemi.al arieFwhh caryinA chmi.al 6196, beaus dmnds td shid ontul of .hospheE srrdeds.annot be d. Tne followina is an i.dicarim of ptuti,r peblefs thd my (Iar:.

acid oblyed hydolysis(..9

wnh 6eB,.cbk or adyr,r6);. rid ar.rysd p.ryffibation (e.3.wih allyl chloiide). fom.rid of .ar60n.k (e.a wi{r mirc);. il'maed a.idity (.9 conlaninaiie ot roluE rd irlene by carbon dioxide),. rutim with wak (.s. wi$ a@6one i erhaml),. deadivarim or po\mrisrion innibibE (e.8.wilh vinyl,ebte);. s'rrphr onhie6@ (.9 wfth herh:ml),. hti cl oride m loels (e.9.beauF of s rad..ny ove trtrm L\e mbher/warer ear

,hkh eld aftd rhe blwr in subs.uent RdioE).

8(rR of th* Mr and poienrial p@brens wnh euch c.rg6, .haftm nN pple rhrt drynthoen 5 u*d fo. irertinS a t nl, rd when pEparhg a bk ahcpher fo. ledins.

suPpli6 of Pur nih%m, for initial iding of crgo hnks pdd ro lcdin3 a ca*o will3nerany be providd diftt ftm rhe rcdhg bminal. ck .simll, shm suppried nftoamis rlb red ror han br,4 m fed 3as overpe$ue while mlmdins. such nhoaen i3 inEas6 {om, md cm b pbvid.d .i hiSh now rahs, gra{y ex.eding nmar liquid flowmG. AldroSh rh opntion b f inpdbnr sbse in c.rao handli.& il is ars pobtianyhaar,rous b{ase h8h pre$m 3as s bin3 nlrcducd inro a ranl not desianed o*nh3bnd inh.l P6ua, and rhe shtu of rlp bnk m.y lail due b ovrPrane Forrhe assiaGl risks or the opeiatioa F Setion 5 7

High ptarF Sasus nitum .r b doed in stel ylhdesJ rh .mhd 6ize s 50 itucaprcity, plsuised ro 200 bar, whi.h wil supply ron: of 8&tus nitogo rt.an be usd bonpeet fo. I1mal btuporbtitr lffi rd h minhin the roqnired ow.plsnm. Arypi.ar irohllation n a ship cmists of a nunbr of suh cyrindd Mdbd in par.llel brom r brkry whj.h

'lga prsn r+niiror rhat s d 60 uinbin ih. rqund psirive

pEsuE in lhe caqo bnk withour liilinE th. tut pl6w rliet valve

Compl*d niboam c.n b obbi.d in seralBBd6

of purily.

Nih%m cm lle sb.ed o bcd in liguid fom, ar rh cryo8aic bFratur of -1%'c. rt kdord in insulaed bnks nade ftoh oldieisbnt naEnaL usuaur sbinl* 3iel pEsurvesls Tn cry%ni. rbk has n dhr casi$ or srel, Forehd by se6l l,ye6 ot rnti-olcion print. Tlp Ep{e bd{6 ih imer and dk tuL3 is lepr md* v.rum ad isfilld with a non'flrhnabl, high ffciency tuulatid whi.h ,lloc dtu96 fo b sbrd Nereie.ded psiods witnod appRiable lcs.

Liqud nituEd storrge bnk 6lt rd m .he6i.al b.rss aE @filled n po* 6m h@rsurs. when Sasus nit%en is rcqtried ror u$ in cao ianrs, ihe i$id i! mvcredb.c* ro gas usinS finnd tob evapdabr that obbin6 rh. n@rt hc.r for v.porerid

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nitogen elpplied b a ship 6on d indushial .ry%6i. plant n:

,dbrption is a p'rc in whi.h a sub*arc, $u.lly a as, adnllab on dr sudac of a$lid b rom a very L\in nh PlsUF swing ads.rpritr (PSA) lanb woir m ir* piin.iple *'aiine major oslibdb of .i. - nit%m and or$d art ad$ib.d ba dilfmiabi whenp.sd ovs a Glbon mld:J sjeve nabn.l Tlp mobi ot 6d e6 ad$ird depnds nL\e 6re of cxpGuE It the s)a,b is adjusrd .odlr the sifle adbrbs n6r of $e oxySh hine aii auo*ing rh nihsen b pas thrcugh md b ou.rd. The dysa cm rha b dslbat(frmcd io a 3as) dd erhaBied !o ah6plEE. rheFby ps@6rins rhe siwe.

To Sive a oniinuous nnrcsen now, I5A planb are ihed wnh eo or more .kro']ddprsuns.d v*ls (.aued bedo khi.h onbin dp mole.'rar sieve nardi, An is.onp@i*d by an oil,Ire onprcs, ,nd passd vs oft *r ot beds hd aF aderbinSwhjle th orher &t or b& is dslbing. Dudng tF pnrrnon .ycle, rh@fop, rhe plmr {in

us bc th4L'h'l ro d rc ,r,

rn addnim b nibod and ory8m, rhe carb.n-mole.ular siev. 6aerd also ads6s anumb.r of orher 3as, ananS rhm carbd dioxide ud warer apor. rn nomil

mrmt in an ! very mll e rhc prRne ol.arbondiond has egligible e{lict on the plant opsation and any dbo. doxide adbrbed is qRftdwith the wish 8as dnrinS rh desdpdon .y.tc. A nu'rber o, propriebry s

air nGr be parsd hroud a dryer ro Fmove m6r or rheabcphsi. tumidit bfoft pasiry ova rh bds. n maiim eflne, the rn jnr.1 ro the rsa

Hs nu{ alw.ts b prded trcm spray'Ih gas psd(d by th PSA prcs nay hale an oxrca .onhni v,rying bers d 0 t,r, and,% by vorun dependirg on rne nM nh Typic,r pran6 produ.e aas wiinin 50 C and a crddn dioxide snrnr ol l6s ihe 2rm bv voluqE

Mnbrm mib aft basd on the rad rhar ditfeEni gass p.mcare at dinrcni n&s rhnghthe walb of a rhin, hollos membrane. he slow gas a4 n rhanc, nihsm and cdbonmmoadq th.'med!!n' grs ,re am .nd ory3e4 ed ihe ta{'8as ar w,er vrpo!,

-rhe a.r rh'r rh wo nain cmpoMrsrak nm dDy an be sparaied. Trethenitrcgd pnduc.d is als very dry.

rlF n,rbrm m b mde up r6m brndrF of thin holos fibres whi.h siv. a lalg wa]la@ lor *p.ranon. Th m.nbr.ne bmdls aF eml@d in presurt vesel pip.s oI abdt rmb 200 nillimle diameter, everat of ther bundtes nay b anmSd in Frauel

Cled conpEsrd .ir is pred i.io rh* trhdles whrc n oxygd ancmded. TrE oesb6n6 aE hdtssihve and t n.y be nRsry io @l rhe .onpa*d

of air, nitugen ed oxrca hive difreimr pmeationfad thd wats vapour pnearB quiclly means hi

fte nok is adilsred b giveT.e erriciency rLhe pararim detods d the now rab throughvarve s usd o FSubb L\e row and *reby rhe oiySm onienr.

727


27/81

nih%m of the punty ftgun.d qi6ly wnh an oyes .ontent va2%by vollft, aiL\ waid and carbd dioxide onhnb rdow tppm.

Oxy8en ennched an is rnted as a waste gas, hich mus b. e*aNred ro'

slp aRa

Oilfirdineds6bEendallya.epbbleroruswithpeioleumpndr.bb irhasbentound L\at the qualiiy ot ihe imd 8as 3oe'ared by rhis rl? of syskm is not suiiable or ewith mby chehical prcdRb, baue ii .an aff{t the crrso qlality

k n [email protected] rFdmddd rhat when nnine or padding s rcquired by the IBC Codc or .padicular .a4o, nit%en is u*d ro ind or prd rha! .rso uds thc shiPPdr i 6uPPli6 hassbhd that oil nred ftd sas n acpbble ror su.h purp(e.

'Ite basi. prin.iple oI oil liFd plrb s that the oxys!. .ontdt ot th. an n onv.rd toc6on dioxide by snbwnon of oil *hile rh. nnrogen conidr

'!mi6la4ely unchrged.

fte oil tuel s brmt in r onbstion chrmber and rhe.ombuiion (or nue) gas s pasdth'ol3n a warer rMer (or $rubber) to.ml it and rcDovc no* or th. sllphur dioride,parri.ulats and mpurftiG Thn rcqun6 .dhd bdw@i the l@ gas and lae quaniiliB of

Th. Eas nay then be dned by bing Pa$d eirher rhe!3h a .mler or d alurlnu bed d4,s(o! even bodr). chenical hks are usually fird wirh tuo non-dum v.lv6 in snes as aneqivaldr to a d{r wahr *al, rhereby arcidins thc risk dr w:te! .3fty .vei ido dE oiSoAs a fudhd s.ltsuard a8ainn brckflw, d'* is ustally n holating lalvp or a spml piRe d

'Ihc ined sas producd by oil 6rd smdaroc depdds on rhe 'toalityoI rhe uel oil and he

cfh.fty or the @nbGtim and {nbbing pre. ftR fados influere, for exanple theanomr ot surphides n the net a* Podu.ed - *hich $ why the solPhis limii.d in the olant sdifi.ano.. Likewie, iner,cimt conbrrion .an cau* smt, which

clog6 he *tubbi and, n padi.ular, rhe dryer sy6hn, rhcreby prcduci$ se! and dif.y infr

Ir rh. pbnr b ef{n6{y buning go.d qulity tuel, the nen gas cm b expeEd b h'veapproinahly d\ orowins omp6'hon

sulphur dioxide dd sulphur hioride

118


28/81

APPENDXF

C.dn d S.f. tL.triol EqripMt.1 InhiEnany $G quipMt.2 ExPlGim F@f E frlme prl equiPmt

El6tl..lM.i 6rre rnd R.p.i'

LN


29/81

ELECTRICAL QUIPMENTAND INSTALLATIONSNHAZARDOUSAREAS

'rre eleckicar quipmmr and iNralrarions on chenicit hnkeB rF subjd b Fqui@enb ofrhe flas adminisbahon, dasificaiion sietiA, lMo and dr rnremaiiocmission (rrc) The pu+w of rh* Fqunemab n b ensure hathe etdncal

as b ninini- the risk of lire

AFas and spa.6 ae cr,rsifilrl a3 aas $te, or ,8as dary@d depndis on rhe bk of carsovapour bin3 Fegr. Ashoft, the definnion of aas daryerous plaes b.ohnuow or inremfihnt plen e of

Basb eipeed on ships, neP

3nd a prae is .mbuouJy dher 3.s sle or 8as dmSerors.

Eldn.alequipmmt imt lcd in a p1a.e egardd as dangerous on ship or ashor) s b beot sp. .l .onsitu 6dn, ,nd ..d 6cd e fe or rh aFa and rh va pdr .6Md Podable4uiDmenr rakm inb rhe aFas shourd also b .edi6ed efe.

one of rhe main onnddarids ,board .heni.at i&kc is ro ensue thrt !h su.facehmperarue ot any ek$l eqripneit dcs not xcecd h auto-ign ion ierprarrre ot

'iycrqorhalheshipmaycanv.Alhoughiheraftanunb.rofrc.osnised.enificaiionrr? sli8hfly difiprenr red pftedorF and w,ys ofsroupins rhe surfac enperatuF .aregorjes, he tBc code spe.ifi.s the mpenrureEaoups, nd eguipmenr usr r indaned nd mainiained n .dnprirn.c wnh thp

Inrnlcrlrr sale eguipmcnr c1i6 on low power ciruih ro Lmn ft. n,rinuh ene!8yro ,snire a fl:mnable nixture mde

The use ol inrinsi.ally saia sysbhs is Inndd b msrumenhrion, .onbNaua.or the very los eneqy lev

Erptasiotpn\t n llan? prdrf.qtiptun

Thek,ms'erplGion prcf equipnenr'and lam.preof quipmenr'arpsynonynsand hcone hN. depend! n rhe drnry .r .n8f .r app(x, Iof thc d.vrc rnc quipm m r isdsisned w h air saps (soneiim6 .aned nane parhs) bNeen ovss or emovable parrs ndthe fl.losure The ar saps are dcly ontolLd, md arc ndior' .nough ro cnsurc hri il aniSniiion wer b f.ur in rhe equipne.r rh. 4suxing hdr g,ses or naFe would .nqre ar suchveldftis ihat sumundins flammable 8as would .ot be *flted by the eiplosio.

The on.pr is :ppriobrd ro mdbs, jun.ii.i bqs, .ndi b6kss dd a wide !'n8c of orherel{ticil equipment. A .pdiri..ie tor the nr$riit ot nre eqdpreni is is!d afier laboratory

ih. dc,sn r.abres arc not dskotred. rnrc assmbly ot rhis rypP or equipmparhcul ,ftenan p h should r kcpi dry and

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30/81

sho,nd n*er b rirhd willr johriry.ompoud. rne ofd srs n6r h. 6iied at cabrepnehatioc .s rhe coniribure b rhe xplGim pmf i.kar y oI rhe equipnar.

S(rm el{bical bondiry of the ship s shdE, includlag ndpadent ca'Ao hk, will havebe6 a6ng.d dlnng il3 deign However, t nay b approptat b ch{k dr.r mov.ble

equiplrHt, such as elRti. mdor housin8s, mared n any ol dp hadeldially bonded b rhe hull

m working srre.ny srord rever b by,pis*d,owrdddm or is.l.ted; such achon ould enda$er rhe slly oI rhe ship. Dekiv .ndibhay b by pa.red temporaiily in c& of an dqgEncy, but this rction should only b akenw nthef, agrmnrof dE r6p'Nibl orficer,rd dr dRisim sho,nd be sided nudet{t shald be dified and dE cinit FpaiEd .s stn rs po$ible, md ine by [email protected]. Conpltid or the kotl should al$ b ftuded.

Cedi6ed ere eq pne.t should beoGtully namrained, pdeably by qulifid Ipt:tmel,ld b su3ht in c& ot donbt. [quipn

3hould b Esul. y irupbd.

Erdric lthr fttings ap dh nad w h a rmprarm erpebrion wnhin a grdp t}lirdepsds on rhe power of dE lanp {bulb) cr.lld cEt l]n nud b? rakd b rQlace inedefe.nre bnp with de of th ehe po. Fitiry a higra powa lanp rh:n $e origrMl canater rhe rdpemdre Snup of the fidi$ wiih..ru.qenr ahtriN m dE ot8es $,r rhe

wnd qnipment n a 8as deSd'N ana is dismlRr for si.in& ii,e a$Fabd witug

{d condudoB should p olRdy hmiMrd or .dequably ireulahd

ff il ir n@ry lor the Plrp@ oI epais tr aftEatioG io !e soldeiing pparabe or otheihes involyiry h6t or lhnq or b apply volb8 b app.rar6 lor r6bn& the aR n6r bm.de sfe rnd dined s$ 6E by d authorisd pt:m, aid rhm minrri.ed in tlEtcddinon 601 lmg r ine wo* ie in Fog@. wrE slch hd worr is cMrdsed ,l@ry

o a trn'i'al whm a hrer is alonsside rhe Fntagr.llHr oI the hin.l md r..*.r should ,iBt b obt ined and a hot wor* Frnii i$ued

732


31/81

APPENDIXG

c.2 G.n.ran6 or Pq.uE SrA.

133


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PRESSURE URGE

A pEsw su4e k Senera&d n a piFline sFrn when rhep is any .han3e n rhe rare of flowot liqujd in the ine. Tn su,tc.an b dangrm il the.hfge df now nh k ro rapid.PFsuft IE af l@r Lrery ro b.E.ed duriry al8o rmsfer as a r6ulr of one of the

. dcure oi rn aubmaric em.cocy shuidow. (EsD) v,rvei

. - ,Did.rcdpn.p.113.rrm4nLdto 'pdp-op. idhd\r \c

. slan,uSshuroran. Ftumb|veror

. *aning or sbppin8 or a punp.

Il the rotal pES@ 3oerad in $esysbm upstsn of the ralve which

pipelii erc& the strngth of any pad oI $e pipelineis ded, rher nav be a tupturc readins o .n exh e

The,eatnm,la, , . . t ! , Id !"\f ,opcrpd idpd\ rL["a.waheaf . j . rcm

Th pa$ure at any point in the .ao tunsler syien l hile liqrid n nowing undc! nodal

rond idshas inrP.ompoMb:. rhe hydrGirhc PAsur;. the vapour prsure of the prcducr iI rhe rank k closd, oi rinospheric pre$ure iI the

. rhe prsurc f,enerared y rhe php whi.h is hi3h6r alh pump ouder bur fatk sreadil/wnh disran e ahns the ine due to lri.tioml ll]gs.

aE 6Gbni and wil be refeftd to as rhe sraticohpondL The thF omponenB ot rhe nomal flow arc shown in D

Rapid d$re of a vrlye superimpNs an addidml ransimt pe$u Thi is due ro thesuddei onvssion or the *inehc fleray ol ihe moving iquid inro $min oe4y by

.ompHsion ol $e flujd and $d.hin3 or $e pip.TrIestoP n the now ot lquid F prcpa3.kd back.ld3 thc piFlin d rhe spd olsoun,i andas ea.h pad of rhe iqnid c.nes ro at ine pfsuie ts mddsed lr is tha disturbane rhar $lnown as a prsu r surAe The hei8ht ol rhe sur8 depends on L\d dsity dr ttu liquid, ihrde of ib d*rerarion ,nd the el(iry ol sound tuo%I ii.

Diisram II shows he d*elopmmt ot rhe surAe as he valve shub. Dia8ran III shoss ihatupsbeah of the surse he iquid conrhues b move orward and iill h6 the prt$urdistibuiion aFplid . it by rhe puhp. Downdre:m .r the sui8e, L\e iqlid is {atunary and

dornsbean p6sur gradienr behindadiudmab rrks place n rhis pad or rhe piFline b e'tualis th pasm tni(r8hou rhp$dionar_viquid Thcs prssurc adjush.nb.lso havel hrouSh he iquid d rhe p.cd.f

valvcl(r* jniantmusly Ihe *qrd in Daslus ll vt in fuuE c l, md n dFribed bd6

l15


33/81

wha ihe suq. ra.hcs rh punp (DiagEm Iv) lhe now d\nugh $e pmp *s Thepasure at the puhp outler (le,ving ,sid the st.tic.ompomno bNms apprc\imrelyequar b lhe sm or rhe sr pKUr and tne ortptt pe$ut d rh. pump ,t arothroughpd Tnc pc6 ol prcsure cqu.lisation oniinues dowBean oI ihe php. Il noieliNed in

'nyway, the pr$ur thoughoulhe whole mgrh o, $arionary iquid @ch

approxinarely rhe suh oI rhe surye pGsuft, ine punp ourrd p6ut ar zem rhroushpui:ndthedati.cmpmt.Th.fina1plesuPadiUslmenlba.hievedisprnP rs sM as he o.grnal surg dv6, and tavels back ro th varve d thp spd of sund.

the rime regund fo. the wholc pMcs is theidoF + trcn therEtmt

of valve .lNue,wtuft L is dE lengdr or the ire rnd . is th. speed of sud in the iquid

r,ncously, rhe iguid upsftm i. rhe ine e\periff anabrupr incFa* in pFsure fo owed by a sroeer (!ut still rapid) tunhr imd- unrit rhcpHur ra.hcs .pprcxim.i.ly the sum or rhe su pHsurq n\e prmp outlet pasur. aiEo thitughpur and rhe 6tad. ohp.ndt

ln pnctical .irumsknc6 the ralve dosur is nor hnuhous and thot rhe srrge pG$ure through the v,lve whilc n r clci.B. T1p pPsuF lront h ls srep andas a r6ult tne hi8ht of rhe prsuF sn is 165 hri if.losuE had bm insbnranrcus. ftepHsur ns f,carcd will bc l6s and thc pndd Fesuru d* $in b relieved uou8h rhe

At the upsbam end ol rhe ine som. pEsurc nliel NUB ihrcugh d\ punp and rhis akosda ro reian the miimun prssur. ea.hed; however f a .hRk valv s lilkd il mya$ralare itu {e. rf rhe efr{rive dosure tine .r rhe v,rre is seral tines 8Hb rhan rhepipeline pdiod rhm surge prsuft allevi.iion may be sElificant

i*d pF-ia $rftsh'n .

prmp nFn"l+u'l hepHure dmughout the im beeen the pump d the closd valve s rednad b in pmport?d pr$snr * ao fttughpd Thn is the sitoahm thar would hnv psdred Isn a ve4,slow clcu or rhe valve bur rhp prsrp surye wourd nor then have c.uftd.

Dorc66m or rhe valve an analogo$ pr@$ n inihatd whd ihe valve los, exepr rhas ne r,tuid is brcqhr ro 16r there s a rall of pre$ffq rhicn ralels dvldiy of eud. HN.var, the psuE dbp m.y b relieved by vapour volurion om therqud shh.ugh the $b&+sr srhp+ or the vapou! butb16 hay sE'E sh(* wav6, tor'mple, if $e dowmrem liqnid nows np and down ihfu3h rhe kansrd am or ho*.

'Ih de{riprm abNe Fre6 b in sinple cs or a snele pipIift. h pBdicar c$s rhd6ign ol a pcsibly conplex sysem should b blcn into a.omt For rnple, the onbiftdeffEb ot valv$ in pantlel or in *ri6 have o b ehmied. In ehe crs rhe sor8f etia.t

inae tn? low in th. other Line bIore his ift in ib tum b shut down. Horeve.. .odoperanon ot valve in ercs h a ltu tr nifri& suee p'anre

Tne nainrmR m


34/81

Dil'9..nlrE$cpmfle'de|ldg

rrt L/i suru .tfjy L? pipetiEihgis

DsEmrv im. Va su'!. E&h.r pump,

MJdmma4pl@E,ltlDva|E

figuE G.] oqdopmni ol p6ru rurge n a line altr ntiant ne3 6lv. d@c

Di.gahv rire-rr' va sry'.fleccd

b rlD varE

137


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H2

APPENDIXH

.3 cdb.n diuide and vrpori3i$ liquidr

..r T6iniry and eqlipl@r PrFEdn6s

139


36/81

FIREFIGHTINGTHEORY ND EQUIPMENT

crrrrnr rn qftlliDnrrpntuln t\ lo. d.at'tNa\ t an'stftiaa,i htt att k ch,yn 3 rh!rwt tx d*ttb$ tht tDk thd lny b. bd, ,o rrrt'r'trrtrta o, ? ddtrrt k"krt,\trtitty j,.sint'hn\rhn&rts, d,trhrd6 adrn or srm tudnn'rt ddq.^ al uhrh h o'as al nMiatttrktB,hrntd b? tnt HrMn, t a6 nat 3a ntu ddrits lat d.h dpnnor ht i.tt b. itnt1ttl,\r .ti!^s t tfruh{,l 1 o1(t litt tttiryuishtns ,turtn cenml Jitt flqtnnlt turry is w.t,,Ldin ltt ht.n1r||,aat srl.tv critu lat oit r kd' m1d rtitiut:

rf a tu e Nua,ihe.dion raken n I an o. ihe sFor h.uldon. np efer3enq plan shcutdbe mFlcmmrcd p

llreninimom equ&hcn$ tG,nrr shjpt rire ighiin8equipne arelad dosn by hc lasadminiskarion The Sulatirns i G senera y Sascd n rhp pin.ipl6 oconvmbon lor ih. salry ol Life d sa (solAs) nd, fu ships ditidch.mi.ag an the Mo Burk chcmi equipneni io a high{andard spedarisr rai.i4 ni.Ew nenber, in pariiculr $ reglned for .hmi.alendo -ment of o 6.c6 prelcsiona r .edifi.ars, sh.uld be suppicnen ed by rqula r drils on

Fift requirs'

.onbin$on of rhr.a elemenk fuel, o\yg. md hear i ,n*ion D order b burn fic pnn.ipal nans or .onro inS

and extinguishina rirc h ro rnov r by rnovn ot ihf!el, by .mlin8, .r by dr.lud ins a supp y ot oxyaen air) But in chem diSniiio. may be haar ui a rta.ridn wirhD the cheni.at ielt or tbn r rcacrion fier mjxinS.henicars. A suppry or oxyacn may b Fra*d frm dE chmnal rhrcush h.ltins by ihe fires. rin r*hbng }dl be nde noa d fi.ult. without doubr, he bes col]F is b prveni any

s.ne liqlid .hdbls h3ve ptuperies whnh ness ar 6r fishiina h.hniqus rhai difkrrnm rho* usd on sinple oil fiFs. Ine blosins rin indrcare sne ol rhR popcdiB. $ne chnicals ar s1ub1c n war$ and ai enain mnenraridns my h nahn,ble;. .hemfals *hth ,re Eoluble n wak' $ill senrarry 6hy nornar tcm, s armhol

resisrani or dur p!r!.* foan is rtqded,4 an'l insolubl n, wabr tney .an b. smorhered y r

bbnrei of wah!, pnvided ppric,nd $ scndc:r ro prodre heai and tnus grve off

flamable (md i. emc .a$s roxic) Aass:. vJne ch.ni.als evolve alce voluhes oI txic vapouG when h.ridl

mexpehd 6oin Yapouc whd buhins;. ihe conpiraiiv.ry los rurcigniion remperatur ol $me .hemi.ar

Th. .argo data shct for r chenical will dnw aitcnrion to ihc uusu.l pFp.ni6 didnrk dE ort4i fie fighring medilm and sped pe.autnfs tu 6r. fi8hr-s

141


37/81

Cheniolt nkccn mally have o oain 6r hghdns md n rv Lrblewatcrrnd.ith.rd.ypowderoran l.ohornsisranr dn sysrem. te minimtn.apa.ity and.(\,e6ge.f rhesy$ens is diPul.td in s)LAs andp(pt.h!5 th,r artunc sproal ha nghbng equipm$t such a5a wrtcr spabiriry d.arwirha fircin unoslar.hemnak sa riteri.n nrSaininS he eniricare fFitns to carry tho{ cirym'

'Ihe b6r w:y ordealin8wirhr a o riF in a bnkisfoin, .a$m dio\idc, r n eme ca$s

'lry.hemi.al

off the bnr rd .oolis rdracd r4$ o! sp{s

by means r sndtheriig gent, u. h aspowder,ilposibleoupll wiih palin8

watcr is thc m6r onmon oliry mcdium, bui his limited elfed on nod .hemi.rl fins. lfui\i, vrtd sholld br rpPlni asa 6pry or wrbr iis, o! D tun lb u* should nnarily bf.r .mrin3 down rhc hemi.ar i&lr and suroundin8 srru.rue, ny


38/81

D


39/81

An pDdv d.d!$.hodd be rpt Fra$re.nd dry, dd rhqnd b pFpaly tuladwl lsbhgwoh.Prtudrc.rodli.gcqldb.drrd'Ettffta!rlu.mbinbEoinS

Ii i. of tE utui ir'ldre {'ai FsrEl dlr.dly iNolwd in frghri.a a [email protected] 6F w@(old peluur pftdE.qu&ffir. Mnv chniLr'u rcl@toi. tlllGwhmbuhin& dd b@dl't .?pnnr sh.rtd b. glh 6y 6E 63hh to gu.rd ag.ir5t illlEligtdi. v.poos d d4e ool. Advi! o pm.l pftdn.bd'4 6r [email protected] haard! irmbied h Ch.ph9.

H.aa ratnnt ond ELvMt pttpo*ta

TtEc aE senl isport nt fict$ iivok d in 6E 63htin& dE'Ei

sig.if@t bin8 rpEvmdm, l]'w bni.g md d! odid6 ard sdi'g of 6ie 6gl*iry.4ripmarC.rp.nyrad:nmviub.biloadtoindividd,lllF,aidw deoiSdftarim.ndtsrinina of p.ml rrd intlfu ot 6E fuhring quipmsn. FiE fghdle md Drumnn ud6 rn eCuip@t ir op@ddl ord rI FndEl E wdl hiEd in il' @ aJdiieP4acyprtr dllB. Pndi! rrLp.r&.l, dd pF ld69port6i6..t r@iddadm ot van@ gl|u.ti*

lll4


40/81

APPENDIXT

,.2 ALld .t shrr.tdn Clmlt!

.3 Radd, urramic or nircwrYe galg6

.5 TapAa$ sy6hns

J.4 onrfl Deion sFr.m!

.2 Tanr old0ow.dhl 5y5bm

,.t PduE Indi({ing Dvi..3

3 CaPacitive rsure hnsn hE.,1 c@al Fsuhons

J.5 T.mpahE Monnoriq Eqripn.nr

.2 TyFs of rhemomehF

.3 Cderd pKautioc

: rdel or otygd i. rn3 Eldnlyr. @G'{ Paramagndi. sM65 shive chehic.l liquid ab6orytion sMB6 PeMml oxyg{ nmibG

J.3 C.rro v.F!. Delddd Eqlipndl

.2 ConbErible 3E detu3 rn@l ondlctivitl hete6

.5 Clmical dffir tub6

.6 G6e6l prclnN

JJ An Supply b Irohnab rd Conblr

I45


41/81


42/81

A. imp.nani tuaturt .r mny m.dm ne'surcn!{ ,nd conrol inshumcnb c ih. $ilih ioisrr l iFdiiL dr, i ' r. i f ih , .*rb", main"p-d1. $ : l r, r r r rs . f 4 nd."

' , ; .d

prc


43/81

. whm bP6 a@ rmewed, d a gauge Rsmbled after nainrmne, allosare shourd beor ner bcsim to rifi. Manuldrcls iatu.665 should b

. paa shtuld b. sdrdy'enbled

spial dre is n@s$ry with bpcicood and hp

orha dajSns .r g,ug6 us floab ihar rip and fall d $e oubde oi a clNd pipe ,NchFmraies rhe main d


44/81

Radar BauAes F Bderally rcliable, and m6r ruhrenan.e .an be pern. Partialar care s

'rffi'ryto prd{t the delicate

tansih4 and e.oie^, ind whd .al$radng dis typ. .t gaugc

Pe$u gal8es mre !s ar the difiern.e bsen armospheii. pasurc and $d pasun inrhe iquid near he tmk borbm. Somchmes n .dditionil $n$r is momhd neii nid-dcprhin i tanr to ihpr.ve a.d ra.y ind reliab ny ln ene casos syseh .an diu* lor c,rso

dmsiry by s ol PMn ar km$nwiih spRilicgraviry snNtsry. Arhemomebiswunlyindu,lcd in rh. sne6, buidFdvanb8t oI presure g,ug is th' rhe cargo hpcGba n y v,rJ,b&ars mret density k dependent m hnpentorc, e eror in eadings nay develdp

Tlr delicatc nab4 oI n&B and ther su&cptibihy to c&go l6kas. nrk6 rcsulr! *ryi.ing

Figurel.4 re$ure auqe ysrem

The sysems use a rape o .hRk the vel or ca$o in a iank Tr'e measu

iNned into rhc tar* thrcush a small d,aheerpIPe wnh

a ballvalve ar he

6d,and

Fodablanomt ot .argo released Ihey smehnes have an ine ..e det(hi a.d a tdPe6he*nsor built in, r'ith apprcpiate mdiob^ ii the dnPhys. A sy{em emPloyinS his t}F oI

150


45/81

Fiqu'er s Tape 9au9. yried

cnain cl8ms eqund the desil{ured rrr b be ri(ed wnh a *panrc high tevel alarn rosjk wmi$ bpfoF ihe bnk b


46/81

PFsu. gaw.s arc fithd ni varioutanls, $meotshnhare sp{lfied,n rhe MO Col6 They ray be u*d b iddi.ate Essuruh r liquid bing purpd i.t or ort or a bn( oi nat piesure su.h as neit gasovprprcsurc.Ircy.rn ndicatcnc ,nd cnbc linkcdb

lu s imP.nmi ihat poedurs {nftl,braied m ac.ordan@ wnh nanu

Trese n*dndt measuF psurc by rhe m.vemenr ot a .oiled or hbiJl3diRrlt propotionnl ro thc apphcd pcsur. ftc mov.nent $ uai to dnvc , port.rtor l(al readinss, o! b conrtul g,s prt$urc !:lve .r t, rher a v:riabsede indiiRt adjn8s Indd readings niy bp nRpsry b avoid dt{r connedionbeken $Ie md ddgerous aFas

Th nnbwing pauriN should be obervd:. rhe ndi.aior should b periodi{rlly ch.rkcd ro. z.(,.JlDrahon;. thesau8eshould orbe urd t,...sisr. ly indi.ab ptussurtsbey.nd s!;orib

maxjmum rcading l the ?rpRied prsuru is nady, or 60L ir ii is rlu.tuating;. Boudon iubs ma)' b. dana8.

laner.an beeliminaed y he u* ora n.s redri.n'

t.s 3 ctw.itiv p6tre tmsmtk^

Pnsur in v,pouj sp..es oI .r8o bnks (and clscwhcr) .an bc non orcd by measurjns heelled ol ihe existing rsurc m a.,led unib thaihave: nown ntomlprsure. BtBiablGhinsrhe erereie ahosphee n rhe aled ,nns ar a krs pisue, roresnple03biirbsolub or s00 millibau, r s po$i nd.rFsure $irh'n rranl as weu as overp6surc ftfle.ti.n or the se,led unn n neasurtd br an hremalc.Fa.ior, which sfltl s an eledrn,. siSnal 6 a remore d splay a. exrhospheri.pr*trrc isne.esary or hc dnpl.y to sho$ giuge Fr$ur. Alarm ek|scanbe

L2Figure 6 capacilive rcsurctansm'ter


47/81

Th physi.al 3iz. of rhe ensoG is quib f, , md whn red ior ined gas moniior tndevnes aF often lmrpoGhd into hoBirys .t other tuF, such asSinilrr ur cr be Fd b inditaE high.r pr*res in liquids.

]r'e folosing pKaufions apply ro an prsure sensina quipnenf. mdFnr.of.f .h.nun.hould Fiondr bleqfh rhc. ,r3. . Fo.pdrph. brus mu,r

ai b Lid rorp'\L?3: ,pe'nr.mr.

tor dim.:rs "u hd.4n)Lrcd,am,e the

lm code g{ guidane on.a$e wh.e sp.ial ad566 husr be paid ro makriats of. b.rd{ meGurmenb aF bken, all valves in the did trnc ahould be opded and au

. nop'4ueB;LC. ihould b""uoF H i.qorerr pl^uPiibg.

. i shi}. .nin8.:r8F rhtrh.cn{|dif) o.bm tuLmpFip.s .ph4i, t . l -rIereap{h!ervr ir tuv b. nl'G$B ro rJ.h qrur lF drd {{' \hdmbqi

. if + Fo' linF re mpJ,dnl! d-

o'ld.d du'ir8 mdntu hcy.\vi db.bLnled

Tenpenruc ensoF ar 6ncd e rhar dr hnpc,atuF oI rhe argo can be mmirorcd,espd.lly shere requiFd by thc rDc cod It is inporanr ro tnow d\e .a4o renpsatop inords r. bc able o cLurare the weisir oI .arso on bsrd, and b&u? iaJ*s or ineir o:tinssorh hav naxinum hmperarure iait. Mrny. sH ae bpsatoE Rnsitivc, nd on bedanagcd by ovAearing o! ir pcrnn&d io $tidiri. SMs nay at$ bhnp..tur.u or the nrudur :ound rhe caryo stsrem.

Li,tuid/vapour themonei4 Rty on $e eipan$m or (uradim of tiquid in a {ry dne-borccalibntcd rube oi cpillary The iquids mcr mmnoly ued a{ mer.ru inporrnr ro mure rhat the riquid olum in rh nsrrmdt n (ntinuo6, oiheRi* rh

Liquidhnlt rhemomhnha\ea he6lbulb cmraininSa nid *hnh ch ssvotmewirhMprar@ .ha.s. Ite chan36 rre ransmilted via capiurry rubiq r. an indicabr orre.onr.r. nre sy{em ts sred unds .ociderable prsua ro oveNmepre$u rron the iquid Me@ry rilled rhemoneeE sholld nor be u&d wfih alminimmd cdain dher mreriak.

3i mdaui. thenomhs.msisr oI tuo metah w h dilfrcnt.at6.ien6 0f exunsion whi.hde weldd r.gethe. b tom a bi-nebrri. drip. whcn he*ed, rhe ship sin bnd be,us of

rhe mequar xpansian, nd he ndins novaenr .an be usd o driyetarric hemon&B ar su*ptible b vibDhm ind shouldonlv be tr+alled in MiiioN fR fmm thh eftud

ThltmFouples rely on heai applied ro rhe mciio ol rwo dissimilar msmall v.lb8r which cm b nc6uFd. A chege will indnre I chmEe n hnp.rahre.Normlly ih valbSe n ensd ele

Resi4an.e h.momehG u- rh. Iad md $e ered.al r$ishn.c of csictsrmD.drur Tn emrrerkl

.h6 r fine platinm wir. rh isbn.e is mdsried bymeans of

'neldical BisiaN bridee .onRtrd b an indjcrtu or R

lecrmnic uans, and dE @d{ut k Enoh.

153


48/81

'It follNi$ pK.ubro should b. ob.fled wfth aI 6pddm hdi.aiina devics:. the hemometeE,sd shorld be suftable or the onpl* ra$e of kmprrtoE

. dp s$r shodd mke 36d thmal conb.t wirh ihe mterial whN remperahF i5 b

. it rsdin8s do mt chrg whn erpded, t}E inshneni shdld b chked,

. fimondm e asily d.fra8d,eFiaxy thr wiih.apinary tubs. Ttey mouu b

h.ndled with .are and pote.d tmm nRhmicar damge md exftmes or kmt rabr.beyondd'ef{al6,dhgrui*lhey. whn a ixed rhemomeer $ rmved rr.n ib worr.inS llaiioa.aE

avoid lrening or enoving ib pdkd, sp.jany I rhe syshm is pKunsd,. whm a henomehr is rplaced n a wnkins lfahon, care should b tn*.n ih,t it d

nor bdrom in ib po.kd whm *rwd i4 as hn e d dr* dm3. ffrhe $e omererk slack m the pc*i a maisial with high thcmal o"drtiyity Guch s . {itabrlubriGtina oil) .m b usd b eNur ac.uratr radin3s;

. elRtkal comdioE should br cled, tghr rd mrd care shoulintinsically saft leads ae not @$


49/81

Parmagndi. inlhunnb n6su the dehetion of a mgnd pivohd in a symdical no.,m omnaSndicfild.Tr'emSneri5swFnddinrchmbri.bwhichtn a6sdphnintiodued, rhe delldion n diRrly proporhml b oxyga oncmbalid th* inshnmbcm b rd ror deding oxy8en n nnbE or othq v.pd6.

It should be nord h.i sn orhr Bas, nobbly oxides of nfi@gen, have ohp.rabteparamSme propnies o or:yten. n'h rehniqu. camo(heP or b used f $.h orhd

sas n8hr be pffit in more han b,e amounbt.73 szkdiu &?ntut tiqrid h*tnn neE

I. liquid dbsorprion n*rumnb a rnMn volume ol dE aimGphec ro be snpled is pasPdrhruAh d iqL d +Fr.h, b{.b. th. o!)Bcn (auqn8d votumechrg. h rr LqLd 1e fin.l!olum' n maa.rFd.r a rte Ehrih

'nd'..hth. oflgh(Mkrr oIlh. on8 t$rpt.Bi,

1.7.6 Pnoul al!&dmnn s

snall itutuntrb arc availabl which ,e.ap.ble ol cdrinuo6ly m63utus the oxysmnp. d be,1:(hd o do us or bmri'r ar {ppl'ed rrh dF

fnbfld llc] .hcdld aJrotuh!ally pmvidcf,udidhfd u6u.l,ldr whm dcahospheF b(on6 deticiar h dyg6, $ as o Sive $e w6's adeq*E wamiry of lrete

'Inc prcvisim and u* ol vapournumbr of frdionsi in ludins:. masudn3 mnentniions ol

. dehhC low onentatiom

. neasui.S oftmhatioN of

de&d'on6qu'pmnr requned y rh BC Code ora

ss in or near rhe lamable ianS,

ol .a. vapour n rir md in imd 8as, or in the valDur ot

o9tenmre*gasd.aryav'pourdinen ledspaes.

PeMnmr shdld tully undmtand rh pr+o* and inibtions of ditfear vapoul dddion.quiPment, whdher tued or ponable.

t 3.2 Cmbdibt? 3 d.tetds

Combudible s.s drRbE aie very dmhon ,nd are usd b ddd md ndsure .oobusribleaas, bually within the onenhtim tr8 of 0 tc{er LFLj dur i, up b ine poinr ornamnabiriiy Eqdpment .an br fixed or potubl..

A ansoi.draining a hlahdt of a spdrl neiar is tuaed elebiolly Td a smpL ot 3.s ispa$d over i. Any onbusrible ga8 n rhe $nplc is oxidi*d .aralyn.any.T he hear givd out,lrs rhe elddcal roistde ol ih firanenr in pDpodion io the ,as oetfet is displayed d a suitably narket ne. Ihe fira'@r on Esily b d..adivar.d bymkdds such as sjiioms, haLmted s.s, acids, warr, oil and 6d. Fiue4 may rhd.roebe Huid in the mDle lin6.

'IrE eguipmeni Rds oxrun ro opsae, ,nd can only b mlied upon rosas m an ahospheEs, nor in inrd aimosphG. ft a hirture of ind sas and crrso vapourhas o be tested, eithd an inh.ftd or rhm.t codudiviiv nds n(d b. !s!d, or a inole

mbuslible sas dd{br cd b ued. A conbBribl 8asd.hor wil d indic.h a sle ahdpherc it a bii. vapolr is invo[ea: in su.h a .a* adiffrmftvle or iGbuhenr shtuld be usd.

n iGhmenb are alibrared a8.iNt a known Bat .arred a sprn ga3 Pdtoman e m usemay be artu red r rhe ga3 snpred is diflsmr from dur u*d for caribratim, rd an.pprcpnak .onv6io. fador my har ro be rpplied b the radhg3

155


50/81

Poilable onbustible g6 dete6oE are riequarly Rd b orlin ttu sbh or .h6phEsb.liNed b be tR ol cryo vrpoux, such s Fid ro bnk dtr or hot wor*. whd led iorlAnpurp@,Eadiry!shouldb.bk6bydutui.rtne pflisimorar6poreibloftirwho 3hould be ehsfied tnd lhe cinterPrekd, blore allowin8 the stety of peGdrel b dcpend upon thd. Th. calibraiidshould be oninmed, .nd Eadin$ dDurd b bkm fbn oE rop or bobm or a spcedepmding on the apour ds y or rhe cargo. Readhgs will b n(uare il i.ed gas s

whd *jn3 rhd nsttunent eve.y ftadion oI rhe mbr is inporhr, rd mr iu* tI 6n.lftsiinA p6irion. Ihe liBt movcment ndi.rEs the preke of Mbusnbb vapdr, *hile iheliml Fn p6ilim mdibs th. .dsharim, a rallowsi. a tinal re6t pdiiion wiLhin ]'e ale indi.ar6 a gas mncenharion blow LFL, erp6*d rs

. a liml re* Posibon byond 00

. a nedle no\mst n6t $.vc 10c,6 LFL.nd then to a 6nal Kt F tion of ze( indi.asr .on.enhfion rbore UFL

It is iheFlore srrcngly mmmdcd thar whm a spac is bein8 heked the Gpdsibleoffner mould nd b dhsfi.d tn r,n ahspher d etu mtil oBishntao @d4s apobtained. Fixed gas detedos working on rhk primiplp have dp $ne lin ariom as ponabb

PeEonal oibusiible gas dereroG, .apable or.mri.uo6ly simpliry m armcphre io d.hidE premc ot small amounb of conbNrible E!s, .re als avalable They +ouldaul1)mri6ly poide an aud[lo and vilal alam whm tn ael o( .ombustible 3as na.h6a et lflel, b sN. the wea4r adequah w.mha oI u$le ondftioro.

1.3.1 Thmnt &ndu.tioitu n t.ts

Ih* tuiflNnk worl by neasunry theml.mductivity ot sanplB of sas nty aesmtinA carkd ..tftainoh El


51/81

extmt ot ab$rption is in popodid b the 3.s u.enration, ,nd rhe ourpur tion thc Mosb.s i3conp.nd le.rmi.any. rhe el..tbnjc sBtut ..n b ued ro drive m inddtjnsmehr or a ps ftdd, or ro hiAApr dher equipnmi suh a! an .hm. Calibrarion oI rheinshneni is d for a.h 3a b b ndsuEd.

lnfrarcd duie6o6 wjl nor Ftiably ddd cheni.ar 3e, a.d arc noi olmody Fd on

t.3.5 Ctuiiut,Lttttt t b.r

I!* ituhnmb, oftm RlerEd ro as DraeS* tub6, nomally tunciion by drawiry a snpleor the:hospher to be kshd through a Fopriebry.hemic,l easn! in r glN tuh Ihderdin3 rcaBe.i b..ohee prorssively diyolded ir a .onbnient vapour k pltmt in rhcshpt The kryrh ol th dj$oloration sbin giv6 a mesuP ot rhe.oncaralion or rhe.hd ica va pour which can b ead fbm the graduared .ale prinred on rh ub! DrRbrtub6 give an a(uak idnation of chenical vapour.mMrarid, wharver rhe ovSen

It is impoianr that the 6Gt volune ot ahGpherp sahple, a(ording b rhe manufadH,sinshchms, n pas*d rhrc!3h rhe obe, othefrise ihe ftasuremmr wsnalla samplerclunewillaivca helengrhothpisaaitical rador inobbiningaconNtre in8. IrF presrn or a R)nd gas may atfd radin3s.nd ..w im(uraci. chdical dderor bb6 ar spdific for padi.utar 3a* or vapoortehi.h ne,1 or have namniblc or combunibh pr.prbes - ro! sample, or)'3o or waervaPour 0o esrablish ewpoht

Tr'e tub6 aa di6n.d b mc6uP low vrpau onent bd6 .a..bly, d aE Fobabtyqurpnenr ro se. rhey shtuld atways b usd {hen rhe

Gr8o v4our plenb a serious nnalanon haa.d, e a aaylonihile.

Tr,e domge rife of the$ hb.s is usua y tinihd, and t k n@s$ry i. tuur rhd out of datr

vrpdur dekrion is a nns ol mc.surin8 vapour cdMtariont and geai.ar is'ressa.yo ensure har he ie,din36 ar @urrb, sp{ially whm dp liv6 or ps@l depend poi

them. The followiry prRautim shoord b ob$tudl. the 6ike/s hmdbmk should be stodied belore caliblrdon oi o$,. pro poinb shorld be ch


52/81

Fiorll,rcof 'd6id ntul! dcp6& @ aow rat ,dd fructlutim tu q*

ill:roacy, nmr should *.pt 3bd, &d doH frh gp,Ete poinrrshodd bc

aF batuy volqe or potubre tu 3ho'nd b. derd tuq@dy bo us dirotuat win pwi& .ffik Ediry&

TIE PrfoM oI itutub dd .fltul sFtu dBr d.Fnd upo a eupply of .i6, dryair 6n b degradd ery qulc*ly tf Otealr {pply Ir d.gaded or d.plrd{mhilEr whidrcn Bivris bffiim bd+ip,6t@ltun tim. Lubriqbg oil d.[- crF pro6lem. Soth dnld De Lained oll qrlar9. Air supply pip6 $odd b. krr6Snt rid filieF 6d dts 3h6uld b cher.d tuqhtlt.

158


53/81

APPENDXK

x.2 c.fift:ri.4 Mddn! !.r T6dn3

lca Hddlir& Co'|dim ad U!.

xJ shldshoE lrEd.do4 &nnh3.nd Bondlng

L6 Sror.t ril Mdnrada

K7 &mPl. Fod.t for c:rlo Hor F.d

159


54/81

CARGOHOSES

A nodem calgo hGe Epcsb slillcd s8indng and, unlers wrdgly us.d, crn bc rlidupon to onrain rhe.a4.. NevddEleis, n shoutd alw43 be rFared as rcarso onbinmmr md tmter sysim, e dyNt haidlin8 and u* of h@s is impodanr Use.nd handlingmaydiffer roh tyFroiyFof hose,orby ma.nraduq fte!?.5drhoscsnomally smunrercd arc either metallic onpc , PTIE (polyranuoreinylen.) .r

A shipk own .aryo hGes art rquoiry $ed on board chemicl rank s, during ldins ,idrinS al8. ransinE bem ships nd dunns hn k

derninB A5hipshould aveonbcd ippopriarena.lfadrrsr narsi:rdmbinsrh.hNs caried, and sp.iryiry any rihnahons in lheir uF

A ship's osn c'o hlxa m6r b. bbd ind aitficd s equird. rr nininm rtquilmenbrd $c onshdim {d et$ oI shiF' .ao hM,rc lpeitid in rhe MO CodG. All caohlrs aF rquind b b d6iF1ed fd i buEting plsup nor * thtr 5 tire rh. mtihunpsuF rhar he he will be subjRbd b duins Glgo hansler oprarim Ns tmSLl1s f.alB.hd, belop beiry placd n *riG, should bhydGbti.ally bhd at ambient .npcdtuN b ip6ur not rs rh,n rr tire i6 spdn d mximun wdlina prsuf, bufitursof ib buntin8 pl8of. A manufa.tuftt?s r difi.ar t iu povidh(E's Gtu.tion method, b prrom rm3. and L\ uEiEr s,6

wl,ire in *wi.p, h@s should ftgoraily h. lisurly ffpcd.d, and rhey should b pFsrr6rcd ar re.* nuary. Tes rsLdb shoord be ftrorded in a ca so h6e ond ition los book Aneiahpbtumat fo. su.h a los is Bivm in Scdion K 7. cao hNs ar re,tuiftd t b mark.dwiih thn spdjf,d naximon worbng p@ssur, which shoutd noi be

H@s uFd i. tne k mtr ot carsG .t orher rhan ambisi kmDeBbre should be nark dwiih ih appricable inimrn and 6aimm ivi@ bmp.oturc ranse

i.al iqrids and ap.us dunng.a!Eo andlins perahonsshould be.omp.tible w h rhe natuF and tenpeiarur ot rhe .hemi.al. Any linjiations ot theorso prcpsti6 and empratuEs lbkd by the hF mufacrun should alw.rs bt

r{hen a hF is bing mded ab.Lt rhe shipnor be dE&led over the ship's firtings suchthat eisb the body o{ the h, no hoisEd

it shdld always be iried and caiiid. n sha!ldas pipwork or walh ays, or rolled in a mannero a crane or denct usins a sinsre wire *op

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.bour i6 mid-lenarh Hos should nor be an.wed b $ne inro onra.t with hoi surfaes such

B.rore .ot]lErion, .ar3o hos shorrd be ehnined n, any po$ibte defds ih* mry b.vrible inside rhe h or m rh oui.r .overing. rr* may ndlde siSrs .f bldenng,ab6sim, nahmin3 or.vdene or rc,ks Hs with ydmaaeshourdp.siiive ddsio. made on whether heJ' 6n onhnue b be ued safety. senousty damarn orleakin8 wsshould not bcu*d.

rh eship snaiifotd shoutd e ch(kcd for suihbitftybefoE ue Flinses on both rhc hos r.rsnliGs antl smd

.ondnim B.lis and nub uii should bc of the oret si? md mabial wnh a bou firted roaery hol n rhe danSe and tighrded .ofEd]

whd r u$, r .a.go hu should b prcper\ supponed alde ih length 60 avdid eicesivebe.dinS or rhe hose or ih weighr h,nginE fron rhe manitotd onNtion. rhis ; espRiallyimp.flinr whcn signifi..ni ridrr or ,rrauShr variaiim .e .au* rhe (ra6vc hc,3h6 of rhestup nd sh.p manrtord! b .rhn src* dea1, d rhe h@ suppod ro mquirt frequenradju*ndi. Fendein& srmls o! .hdr$ .an be Ed ro prcvide 3uppoi und.r ihe hN,pani.u li ny ar rhc mani old and a rh shipsjde ar wnen , h6e is 6upFrrd trom abov.,b.dles rnd sddlcs should b. u*d to spread he oad, ud may ieqritu n.re than onesuPPdiinS poinr A sinSle wie nrcp should noi be used b suppoi a ca$o hok near b nidrflarh. Pr.rNhm should be provided ai poinb almg the h.s whfc .hJtins or rubbins .ould

Hos should nor bc subjeded o pumpins pFsures rh,i ei.ed rhe rabd worlins pmsurelfihnh,PPcns,ihchosc5hou]dbrePla.edbymoihel,andFckdbe

Afto ur, hos shourd be depresuried and drained befo& dikdnlthon

ft i3 ]sniiar thar rhe ar8o ho* d@s nor prcvide rhe pdh'ry p'rh rd nrhc cr.dncitybetullr thc ship and rhc e y, dhrsie rheE s a p.sibilly of a dati. ere.hi.ity di*h:r8e aithe miirold who.ffering up the hGe ror.onnedion r when bn ing h onndion lrerrhc calgo rarofer Th nRsry .rdri.ar diKnrinufty sholld b ,chieved wnh ,niNulaiins nang. or. snsle loath of non.ondudinA h@ in dre h@ shiry beeM Lhe hip

tu. r full crphnrhon . S.ction .11 nd Appendix .

Afi.r rhcy have b(s u{d for .arso ransler, h@s shoLdd e washed oIry should be s6oEd hdtdrally d $lid suppofr It hos ar srord n ihe oF4 rheyshould be Pmre.hd frcm did sunrignl

No anehpr should be nide d bNrd 60 eprn damasd or leaki$ h(]g

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Cargo Hose Record

MainmwrrjnS P6re

64tifu|fu@e'qhfufulcfu'Mr

TdPlElE .nd Poed@ tu tuat tu tuddq@r, tudtuddqnqdd-.&@dedturtffitue,,4,ry@6,beM)


58/81

APPENDXL

SiiD/SioE s.t iy chRldi.i

cuia.Ind lor Conpl.d4 th. Shlp/ShoF S.f.ty CieLlid

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SHIP/SHORE AFETY CHECKLIST

fhEawudranpn*sthtshiplshot'rl.t!

clm,Js! | PNk A a B), jointddrntion mtdSrit]itk* 'tldtt's to nmptdian.

U.roE liquid dmgeroB slb{anes in bulk ar pumped nro oi ort.t any ship, or inro r shoFinsralbtion, the m6h. ol rhc ship and fie bedh operaror should:. sgrp in aninS m ihr handlina uedrres includins he ma\imun 1mdin3 i

. .onplet and sign, d appmpiaie, the Ship/Shor s ery chekikr, sh.wins rhe mainsfeiy pF.adio{s (, b. hken betoF and drring such handtin8 opqationsl

. l8re in wriiina m rhe :ction ro be tatm in rhe eveni al an ene4rn.y during hmdlinB

while ihe ship/shde saf.ry cheklkr has bem develoFd wi& .a.so handling opeRiions nhind, it is Konn.n,le.l ihar rhe rame nutoal ex.minarioD usinB he che(*h* assppbpriarq be .ai.!\d our when a hnrer pftsors irsetf ar a benh for iank cl6ni$ ahd.ariaSe or rqdd daqetuus sub*ancs in bu1k.

The o owiq Suderines have bM prcdu.ed 6D ssi5t nh opraroG and ship masds inrheir oini use of rhe ship/shore safeiy ch(rlisi.

Th ?Mrrnt SrfdyEtu'rnuhan

A bn*er phmrinS il*rf io a roadhg or di{haqi.3 Frminal neds 60 che.k ns oqp4pa'bm and

'bfihs for rhe slery of ihe inknded .a$o operahd Add ionany, ie

ndrei ot a ship ha! , lesponsibility ro a$uF himelf rhar dE tenitut opraior h.s rrsisnade proper ppparaiioro ror rhe etu opdlarion of his hrninal

similarly, ttu reminal neds b ch(k ib ol n prepararioN and b be assured hrr the ranler\crL :nd h:, madc.rPmP-idh af 8l'm1l

'Il. Ship/Shor. Snfty Ch(UnL by ih querions and requirhenb fo. cx.h seofwrilhaSRmmb ror cnain pnedles, shout,l be .onsideFd a ninimm bais Lr rhe snhal

luded . such a nuto:l exaninaiion

s.ne ol ine chdrlht qu6riN a4 drded ro .msideratioN for whi.n & ship his pina.yGponsibiuty, while odreE apply b both ship and remiml.

An nems yiq wiihin the r6p.cib ) olrhe ianker shourd b chrred peGmuy by theianker's epFsrriive ed sinilarly an items *hich ar rh rsponsibitity ot ihe remimlshou d br chFked peGomlly by the redinal t rcpresn rati ve Horder, !n .adying out therrull pdsibilities both Gpr*ntanv6 should, by ,tuErioning th orhd, by sighiing orEords u,r, whrc teu appropriah, by jdt visuar n6pedion asN rhem*tv6 rh.(h.*and:rds of slery on borh sidc oI rhe operarim aft fl y acepiabl.

Tne oinr dRlantion should nd b siBnar untir su.h nubat a$um.e is achi6 ed

thus an appli.able qoee6one hould 6ult in an afiinriive nar* in iheditfel?re ot opinion aris o. the adqucy of,ny anan8tfrnb mad. or .ondihore found,the opnhm should nor be shdd urir masuFs bken arc oindy acepted.

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a rE3.rir mws b llE qErim .oded ,P m rhe ctekrisr dG nor nffirily nan rhatthe ntaded op.radd ffid b. dded @r. h 6u.n .ffi, hNs*, pmision b prredshourd b obhind lion rhe pd au.ndity. riG d)ded ,R rhould b Hh(kd .r in6al3nd ex.Ediry lhat aScd i. rhe dd.ratim. wlpF m ihm is aaed ro b rct applicabre othe ship, o 0E temiml or b lhe oFrlid envie8rd, a noh b 16.r effect should b dbd

TlE ondihm uder whi.n ttu oprarion bra d.e may d,n3 dliing the ples, TIEdun86 rut b 3!.h rhat efery 6 no longd be Ea.ded as Bunnkd. TrF par9 noiici.gorahAihe rNfe ddftim is 6der m obligdtid b t *rll nkesry.di(x bIEshblish sl condfii(N, wlich my includ etopping he op&dii6. fte plge of thuMfe Mdition ehould bc Eponed b ihe orh* parry .nd, whm nA]sry 6 oFatimwiin the olrE P,rry $dld b eueh|

'It'e qBtiffi m hk .lening ap prcvided in tE CherliJt in ods to inlom rhe eninal.nd rhe pod authority of the ship's .hrios qardiry th* adir i6.

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Ship/Shore Safety Checklist

Brft , , . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .-.. .. . . . . , . , Po d

D.h of a,iyrl ._.................,.,..-..,.,., .,..,...............lmolafivr!

Intrrd@ ro. @d.d6

TtF eft{y of op6dd. EquiG .l qs6@ hob .w.rd ,f6EDiiv.ly by &arty tdng(4 ds.p?Fp.Lt hd If m.f6ldiE NE t not pdlbL, dE M rlulu b. Si6.nd r8@r @cIEd btrEr dE dnp &d dE tnnd 6 appbpn bpurim t'tkld, wE !y qdi6 i. @id@d ro b. d dgplirblq rtE ' iot. ro dut.fL.t'lnLt6inFt dhOEqE oslllm

A bd ln.toE or horh of dE cd'l@ gip'o.d 'T.mind'indiab tlllr dEb Culd bdnd aiby dE F.ty mmeit

nE p@ of dE lh rrv P d r in lhe.dffi 'Code'hdift rh. 6touins:

A - AlV Ei.mcd prced|e aid agffib.loJd 5. in wdrbs h dE ffiL6.olllm otthir che*in r odE nutrdly aprlbL 6Dr In dth.r @, Or rigrbr of bo,l p.rri..

P- In 0E @ oI. n 8.ri* dw6 t1FoF6t 6 slEdd tur h. ffii.d d widqrpshi$i6ottE F tauthait

R-It m toh.F+-k(ted duftu dE.?4no. ar ni.d.l,daadinsd{|aFd inrhe

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P.rt A Au|k Uquid Gft.ral

5 i rhia^.thdiE der w.kh o

6tslh!agcedship7,]qeffihunGion

gxpiiiedandUiddlood)

qoodondroi p,oF t, qqed d

13 Are *uppa etrftdf y duqqd,^d

uiinq he h*ffi ia. rry where ned'

24 are w id& tF it 6nd rion q

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( r (d) .ordt d .id ro(|edl

^

Arcbd.En iq oFalos drnd duru

siso 'ha*lhe@d:dhol lya^dternn,

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Prn ! Bult Liquid chl|ni.alr

(ftruding dr .dd,ind b'6sin9 :ppa6d9mdp'dRidothhg'dyjo,mm.diik

sArctaBlelhogol,a6bemddJ'

Fm.iedinft|Edpipli6?

F'pp'op'iac loi

ry. he sn m ,h 3 d'

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CUIDELINES OR COMPLETING HESHIP/SHORE SAFETYCHECKLIST

rn answdng o s qlsrid, d ud re8.rd shoutd be 8ivtr 6D hu need or adegua c tcnddn8

shipJ sho,rd remain ad.quddry aored in rher modnSs. Atonssde pieB or qu.y, r ginaor rhe ship should b pFvdred by rEpins r mmdng lines raui: aih.rion sh.utd be givd rothe novehmt ol the ship ou*d by wind, .uddb, hde or pasing ships and ne op.ratn)iin Fogrs wire rop$ and fibre rop6 shourd nor b used qrther r the $me dirc.rion (i.e.brads, spriry' head or {em) be:us of the diffeRncc n their ladi. pnpds

on@ mmred, ships ifrd lnh:do * such winche in rhc

The wind \rrdiiy :r whd rcdins rms shourd be di*me.led,.ao opratiom sropp.d orthe v*1 ubeihed sh.nld b sbred

Merns shoord be provided t enabtc quic* and sl rle&orfi. ship in cae of ancncr8mcy. rnsp{rive of rhe nmdne ndhod urd, rhe eme4cncy reteak qxrarion shootdbe asrcd, 6*ns inro iccmt the pNible risrs involved

rn porb wheF amhoB are qnied 60 b usd, sF.i.l comideraiion should b 3ivn b ihisnaftr AnchoB rcr in us should be proFr\ !trrd

2 At. tnis.n v tntry utB rndtu p$itird?

EmeBn.y bwing wie (firsn6) 3hould be posiioned boin m in oIlshoF bok andquarhr or rh ship Ai a buoy ndin& eme6.y rdwins wirs should bc pcitiond on rhe$de opposib b rh he sbins

TreE aF varioE mdhods ror ii$ing ddge.cy rdinS wlFs curmdy in us. sonbminalsmyFquiEap.ni.ularndhodrobusdandrhshipsh. dbadvied

k thdr srJ. u6s b.tuen shtr"td

shan?

ft" +^

+o'id be po..riord 6 rdawd) id r rhenan'rold!dp.d idble

Tre m're of'@

6 rhe ship sho'id b efe and tuy .min ot in aa.o:modarim lrddr wi$ r pmperly surd stely net 6{ed b il.

Particulai addiid ho efe aees sh@ld b Aiv6 kh@ rh djf{dee in lev.l bed tlEport ol {cs o dE vspl {d dE Fny or quay k larg or IreV b bRm lii3e.

when tehinal d@ racilide are ct available dd a ehipt gangway s uscd, lere slDlld bem adequh laidiry aRa on rhe br$ b pmide rF gmSwry wiL\ a sspae and e minbin sfe rnd cmvai{t K..s b rhe ship .t .u sbb of tid md .hr36

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N@r rhe,G,shoro, apprDpri,k lifesvinA quipmr slrc d h pNided by rhehmiEl. A liiebuoy sluld b .v.il.bh on 6o.d th shit ft.r rh. Sa.gway or,emrbdatio Lrd&r.

Tne a(s should b. sfely and propdlt illuniniEd dudng dar*n*.

PeeN who have no l%itifrh b$iffi m boid, or who do nd lEve tie nEielspmisjm, slDuld b Etued Ks b rfie 3hip.

ThermiMlsno dconhlaffirotheitryorbrinhagFmntwilnL\eship.

4. k th, shh tu4 k m !nd6 tls M rtuv?

]le ship sheld b able o hde undd ib fln pwer at shon di., unls pmision roiffobilie lhe ship h6 bs gnnd by tne pd aofiority ,nd rhe .rniml nmger

cdain codinoN tuy hav b b net lor pnisim b b 3h.!ed.

5. k r6e.n qdiu de.kwt.h it'thdarc.

an epA Md"nrttob

supm'in M th! bnid ad ot

]1E op?rarim should e undsr llntmr ontol borh on ship ana shoE.

slpwbion shodd b ained at praenthg dE dadopmdt or hMrdoG situiim, ifhow*s sucn a sib.rion &is, tp ontouinA pMlwl should hav rdequrh nmavaihble ro bte ondiv adid,

The cdrsujng pers'ml on ship {'l shore shoul.l minrrin an elrdiv comuicrhonwit' t'eir cspetive suPdvi*B.

All pelgnwl ffibt wirtr the oprariom should be f.nili.r with the d.ngeB of the

6. k it asmd stlip/sinn urmuni@tid t\ttd oprntiu?

CDlmmiarion should b minbined in ihe nos er'cinr way bd,en rhe aponsibleoner o dury on lne snip md rh M?dsible pe6m dhne.

wten blephonA aF ued, $e hlephone boln on bo.d and ashop should b cmhnuo

Ics Chemical Appendex

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