Hydrothermal Synthesis and Characterization of Two Organically Templated Cadmium Borophosphates with...
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2004 Cadmium Cadmium I 1800 Hydrothermal Synthesis and Characterization of Two Organically Templated Cadmium Borophosphates with Novel Structures. — The structures of compounds (II) and (III) are determined by single crystal XRD. Both compounds crystallize in the orthorhombic space group Pbca with Z = 8 but with very different structures. (II) has a complex layered structure with a 9MR channel system formed by vertex-sharing CdO 5 Cl octahedra and BO 4 and PO 4 tetrahedra. The inorganic layers are separated by the triprotonated amine molecules. In (III) corner-sharing CdO 6 octahedra and BO 4 and PO4 tetrahedra built a three-dimensional open framework structure with different types of intersecting channels, which are occupied by the protonated ethylenediamine mole- cules. — (LIU, W.; GE, M.; YANG, X.; CHEN, H.; LI, M.; ZHAO*, J.; Inorg. Chem. 43 (2004) 13, 3910-3914; State Key Lab. High Perform. Ceram. Superfine Microstruct., Shanghai Inst. Ceram., Shanghai 200050, Peop. Rep. China; Eng.) — Schramke 36- 014
Transcript of Hydrothermal Synthesis and Characterization of Two Organically Templated Cadmium Borophosphates with...
2004 Cadmium
CadmiumI 1800 Hydrothermal Synthesis and Characterization of Two Organically Templated
Cadmium Borophosphates with Novel Structures. — The structures of compounds (II) and (III) are determined by single crystal XRD. Both compounds crystallize in the orthorhombic space group Pbca with Z = 8 but with very different structures. (II) has a complex layered structure with a 9MR channel system formed by vertex-sharing CdO5Cl octahedra and BO4 and PO4 tetrahedra. The inorganic layers are separated by the triprotonated amine molecules. In (III) corner-sharing CdO6 octahedra and BO4 and PO4 tetrahedra built a three-dimensional open framework structure with different types of intersecting channels, which are occupied by the protonated ethylenediamine mole-cules. — (LIU, W.; GE, M.; YANG, X.; CHEN, H.; LI, M.; ZHAO*, J.; Inorg. Chem. 43 (2004) 13, 3910-3914; State Key Lab. High Perform. Ceram. SuperfineMicrostruct., Shanghai Inst. Ceram., Shanghai 200050, Peop. Rep. China; Eng.) — Schramke
36- 014
