Hydrogen and Fuel Cells--Emerging Technology and...

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Hydrogen and Fuel Cells - Emerging Technology and Safety Related Issues June 5, 2017 1 / / Hydrogen and Fuel Cells - Emerging Technology and Safety-Related Issues Nick Barilo PNNL Hydrogen Safety Program Manager NFPA Conference and Expo Boston, MA, June 5, 2017 1 PNNL-SA-125732 June 5, 2017 / 2 Who are the Pacific Northwest National Laboratory (PNNL) and the Hydrogen Safety Panel (HSP)? June 5, 2017 / PNNL’s Hydrogen Safety Resources 3 Identify Safety-Related Technical Data Gaps Review Safety Plans and Project Designs Perform Safety Evaluation Site Visits Provide Technical Oversight for Other Program Areas Hydrogen Lessons Learned Hydrogen Best Practices Hydrogen Tools Web Portal (http://h2tools.org) Online Awareness Training Operations-Level Classroom/Hands-On Training National Hydrogen and Fuel Cell Emergency Response Training Resource HYDROGEN Safety Panel HYDROGEN Tools HYDROGEN Emergency Response Training Resources June 5, 2017

Transcript of Hydrogen and Fuel Cells--Emerging Technology and...

Page 1: Hydrogen and Fuel Cells--Emerging Technology and …/media/9F50BB8A578C43A1AB97879ECE1DCFD9.pdfTechnology and Safety Related Issues June 5 ... Hydrogen and Fuel Cells - Emerging Technology

HydrogenandFuelCells- EmergingTechnologyandSafetyRelatedIssues

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Hydrogen and Fuel Cells -Emerging Technology and Safety-Related IssuesNick BariloPNNL Hydrogen Safety Program ManagerNFPA Conference and Expo Boston, MA, June 5, 2017

1PNNL-SA-125732 June 5, 2017

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WhoarethePacificNorthwestNationalLaboratory(PNNL)andtheHydrogenSafetyPanel(HSP)?

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PNNL’sHydrogenSafetyResources

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▶ IdentifySafety-RelatedTechnicalDataGaps▶ ReviewSafetyPlansandProjectDesigns▶ PerformSafetyEvaluationSiteVisits▶ ProvideTechnicalOversightforOtherProgramAreas

▶ HydrogenLessonsLearned▶ HydrogenBestPractices▶ HydrogenToolsWebPortal(http://h2tools.org)

▶ OnlineAwarenessTraining▶ Operations-LevelClassroom/Hands-OnTraining▶ NationalHydrogenandFuelCellEmergencyResponseTraining

Resource

HYDROGENSafety Panel

HYDROGENTools

HYDROGENEmergency Response Training Resources

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OverviewoftheHydrogenSafetyPanel

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CurrentHydrogenSafetyPanelMembership▶ Formedin2003tosupportU.S.DOEHydrogenandFuelCellsProgram

▶ 400+yearsofexperience,representingmanyhydrogensectorsandtechnicalareasofexpertise

▶ Completedover465safetyreviewscoveringvehiclefuelingstations,auxiliarypower,backuppower,combinedheatandpower,industrialtruckfueling,portablepowerandR&Dactivities

▶ Produceswhitepapersandindustryguides▶ Supportsthedevelopmentand

disseminationofsafetyknowledgethroughtheHydrogenToolsPortal(h2tools.org)

▶ Conducted23HydrogenSafetyPanelmeetingssince2003,engagingabroadcross-sectionofthehydrogenandfuelcellcommunity

Name Affiliation

NickBarilo,Manager PacificNorthwestNationalLaboratory

Richard Kallman,Chair

CityofSantaFeSprings, CA

EricBinder SantaMonica FireDepartment

KenBoyce ULLLC

DavidFarese AirProductsandChemicals

DonaldFrikken BechtEngineering

Livio Gambone CSA

AaronHarris Air Liquide

ChrisLaFleur SandiaNationalLaboratories

MiguelMaes NASA-JSCWhiteSandsTestFacility

SteveMathison HondaMotorCompany

Larry Moulthrop Proton OnSite

GlennScheffler GWSSolutionsofTolland

TomWitte WitteEngineeredGases

RobertZalosh Firexplo

Moreinformationisavailableathttp://www.h2tools.org/hspJune 5, 2017

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TheHydrogenSafetyPanelisateamofhighlyexperiencedindividualscreatedtoaddressconcernsabouthydrogenasasafeand sustainableenergycarrier.

PrincipalObjective:Promotethesafeoperation,handling, anduseofhydrogenandhydrogensystemsacrossallinstallationsandapplicationsby:

▶ identifyingandaddressingsafety-relatedtechnicaldatagaps;▶ makingdesign,construction,andoperationspersonnelawareofrelevantissuesand

bestpracticesthataffectsafeoperationandhandlingofhydrogenandrelatedsystems;and

▶ convincingdesign,construction,andoperationspersonneltogivesufficientprioritytosafetyintheirdaily,ongoingwork.

HydrogenSafetyPanelMission

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Moreinformationisavailableathttp://www.h2tools.org/hspJune 5, 2017

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TheHydrogenSafetyPanelcontributestoitsobjectiveby:

▶ participatinginsafetyreviews;▶ providingsafetyplanning

guidance;▶ reviewingprojectdesigns

andsafetyplans;▶ sharingsafetyknowledge

andbestpractices;▶ presentingandrecognizing

safetyasapriority;and▶ participatinginincident

investigations.

HydrogenSafetyPanelActivities

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HydrogenSafetyPanelmembersattheCaliforniaFuelCellPartnershipinWestSacramento,CA,forthe21stmeeting.

Moreinformationisavailableathttp://www.h2tools.org/hspJune 5, 2017

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TopicsforToday’sPresentation

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▶︎FuelCellBasicsandApplications• PropertiesofHydrogen• PrimaryCodesandStandards• FundamentalSafetyConsiderations• HydrogenSafetyResources• ConcludingThoughts

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WhyFuelCells?

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Source:Toyota

VideodownloadURL:https://h2tools.org/sites/default/files/barilo/Intro_GameChanger.mp4

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WhyHydrogen?

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▶ Excellentenergycarrier▶ Nonpolluting▶ Economicallycompetitive▶ Assafeasgasoline▶ Usedsafelyforover80years▶ Producedfromavarietyof

sources

PhotocourtesyoftheCaliforniaFuelCellPartnership

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WhereDoWeGetHydrogenFrom?

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RenewableSources

Solar,wind,geothermal,hydro,biomass,algae

TraditionalSources

Naturalgas,gasoline,nuclear,coal

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PrivateIndustryHasUsedHydrogenSafelyForEightDecades

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▶︎ 9milliontons/yearhydrogenproducedandusedinUSA▶︎ 62milliontons/yearproducedglobally

PetroleumrefiningGlasspurification

AerospaceapplicationsFertilizers

Annealingandheattreatingmetals

Pharmaceuticalproducts

Petrochemicalmanufacturing

SemiconductorindustryHydrogenationofunsaturatedfattyacids

invegetableoilWelding

Coolantinpowergenerators

TheAirProductsandChemicalshydrogenproductionfacilitiesinPortArthur,Texas,isfundedbyDOEthroughthe2009RecoveryAct.|PhotocourtesyofAirProductsandChemicalshydrogenproductionfacilities.

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HowaHydrogenFuelCellWorks

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Source:http://www.toyota-global.com/

Howelectricityisgeneratedfromhydrogenandoxygeninafuelcell:1.Hydrogenissuppliedtotheanodeside(negativeelectrode).2.Hydrogenmoleculesactivatedbytheanodecatalystreleasetheirelectrons.3.Thereleasedelectronstravelfromtheanodetothecathode,creatinganelectricalcurrent.4.Thehydrogenmoleculesthatreleaseelectronsbecomehydrogenionsandmovethroughthepolymerelectrolytemembranetothecathodeside.5.Thehydrogenionsbondwithairborneoxygenandelectronsonthecathodecatalysttoformwater(positiveelectrode).

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FuelCellsHaveaBroadRangeofApplications

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▶︎ Transportation• Lightandmediumduty• Heavydutyandtransit• Auxiliarypower,refrigerationtrailers,trucks• Forklifts• Maritime

▶︎ Stationarypower• Backuppowerforcelltowersites• Combinedheatandpower• Datacenters,etc.

▶︎ Portablepower• Auxiliary powerunits• Lighttowers

PhotocourtesyofNuvera

PhotocourtesyofCellcom

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FuelCells- WhereareWeToday?

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▶︎ Thelargestmarketsforfuelcellstodayareinstationarypower,portablepower,auxiliarypowerunits,andforklifts.

▶︎ Morethan60,000fuelcells(300MWcapacity)shippedin2015(~aconsistent30%annualgrowthsince2010).

▶︎ Fuelcellscanbeacost-competitiveoptionforcritical-loadfacilities,backuppower,andforklifts.

FuelCellsforStationaryPower,AuxiliaryPower,andSpecialtyVehicles

Seealso:StateoftheStates:FuelCellsinAmerica2016,7thEditionhttps://tinyurl.com/mrj8spu

Source:TheBusinessCaseforFuelCells:DeliveringSustainableValue(http://www.fchea.org/s/2016-Business-Case-dwcy.pdf)

RecentActivities• HomeDepotnowcountry’slargest

stationaryfuelcellcustomer,withmorethan140sites

• IKEA installingfuelcellsat4morestoresinCaliforniaandoneinConnecticut

• eBay adding3.75MWtoitsUtahdatacenter,bringingitto~10MW

• Morethan15,000 fuelcell-forkliftsinoperationoronorder

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IndustrialTrucks

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▶︎ Forkliftsareequippedwithfuelcellsasareplacementfortraditionalbatterypacks.

▶︎ Atypicalprojectconsistsofarefuelingsystem(tank,compressor,piping,etc.)providinghydrogentoadispenserlocatedinsideawarehouse.

TypicalHydrogenFuelingInfrastructure(CourtesyofAirProductsandChemicals,Inc.)

ForkliftEquippedwithFuelCells

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FuelCellElectricVehicles(FCEV)areHere!

ToyotaMiraiFuelCellElectricVehicle

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HyundaiTucsonFuelCellElectricVehicle

ChevroletColoradoZM2– MilitaryVehicle

HondaClarityFuelCellElectricVehicle

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FCEVSystemLayout

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Source:Toyota

H2 fueltanks

FuelCellStack

Booster HighVoltageBattery

H2 fillingport

Compressor ElectricalMotor

PowerControlUnit

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FCEVOperatingPrincipal

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STEP1. Air(oxygen)takenin

STEP2. Oxygenandhydrogensuppliedtofuelcellstack

STEP3. Electricityandwatergeneratedthroughchemicalreaction

STEP4. Electricitysuppliedtomotor

STEP5. Motorisactivatedandvehiclemoves

STEP6. Wateremittedoutsidevehicle

A. MotorB. FuelcellstackC. BatteryD. High-pressurehydrogentank

Source:http://www.toyota-global.com/June 5, 2017

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FCEVOperatingPrincipal

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Source:Toyota

VideodownloadURL:https://h2tools.org/sites/default/files/barilo/Fuel_Cell_Animation.mp4

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FCEVHydrogenTankExampleofThermalPressureReliefDevice(TPRD)– Toyota

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TPRDopensat110°C

DirectionofH2 dischargeonTPRDactivation

Source:ToyotaJune 5, 2017

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H2 FuelingStations

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ExampleH2 StationConfiguration

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H2 InfrastructureDevelopmentandStatus

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NEstates,CaliforniaandHawaiihaveH2 infrastructureeffortsunderway

(27 already opened)

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TypicalH2 StationConfigurations

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▶︎ Hydrogencanbedeliveredormadeonsite

▶︎ Gaseousdeliveredorpiped® boostercompressedgaseousH2

▶︎ Liquiddelivered® gaseousH2

▶︎ Naturalgas® gaseousH2

▶︎ Water+electricity® gaseousH2

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H2 FuelingStationsGaseousHydrogenStorage

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Gaseoushydrogenis:▶︎ Deliveredtofuelingstation

bytrailer,orgeneratedonsite

▶︎ Compressedandstoredonsiteincylinders

▶︎ Pipedtodispenserforfuelingvehicles

HydrogenStorageCylinders

HydrogenDispenser

GaseousHydrogenDeliverybyTubeTrailer

HydrogenCompressor

GraphiccourtesyofPacificNorthwestNationalLaboratory

GaseousHydrogenbywaterelectrolysis

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Supply/lowpressure storage

Low/mediumpressurebufferstorage

Compressionandhighpressurestorage(classifiedskid)

Ventstack

Nonclassified skid

Coolingwaterunit

Nitrogensupplyandmanifold

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2

4

3

10

9

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H2 FuelingStationsGaseousH2 StorageSystemLayout

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H2 FuelingStationsGaseousH2 StorageSystemFlowDiagram

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Source:AirLiquideJune 5, 2017

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Liquidhydrogencanbedeliveredtothefuelingstationbytankertruck,asisshownforthishydrogenandgasolinestation.

H2 FuelingStationsLiquidH2 Delivery

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PhotoCourtesyofCaliforniaFuelCellPartnershipandLinde

IC90Compressor LH2 tank

Fuelingdispenser&canopy

Compressedgasstorage

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LiquidH2 is:▶︎ Deliveredtofuelingstationbytankertruck▶︎ Storedasaliquid▶︎ Vaporizedinabove-groundvessel▶︎ Compressedandstoredonsite

incylinders▶︎ Pipedtodispenserforfuelingvehicles

H2 FuelingStationsLiquidH2 Storage

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LiquidHydrogenDeliverybyTankerTruck

HydrogenStorageCylinders

HydrogenDispenser

LiquidHydrogenStorageTank

VaporizerHydrogenCompressor

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▶︎ Onsitehydrogengenerationmaybeperformedbyseveralways,including• Waterelectrolysis– renewableorgridpowertohydrogen• Gasreformation– naturalgasorbiogastohydrogen

▶︎ AdvantagesincludereductioninonsiteH2 storageandtie-intorenewables• OnsiteH2 generatorsaresuppliedpackagedandlisted,orfield-listed• Manufacturersmustidentifyandmanagespecifichazards

H2 Fueling Stations Onsite H2 Generation

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200kgH2/daywaterelectrolyzer

CodesandStandards:NFPA2Chapter13

PhotocourtesyofProtonOnSite

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TopicsforToday’sPresentation

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• FuelCellBasicsandApplications▶PropertiesofHydrogen• PrimaryCodesandStandards• FundamentalSafetyConsiderations• HydrogenSafetyResources• ConcludingThoughts

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HydrogenPropertiesandBehavior

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▶︎ Gas atambientconditions

▶︎ Liquid at-423°F(-253°C)– acryogen• Compressingthegasdoesnotliquefyit• NoliquidphaseinacompressedgaseousH2 storagetanks• LH2 storedatlowpressure(50psi)invacuuminsulatedtanks

▶︎ Volumetricratioliquidtogasis1:848• Comparewatertosteam(1:1700)

▶︎ Energycontent:1kgofH2 ~1gallongasoline• 33.3kWh/kgH2 vs32.8kWh/galgasoline

MolecularHydrogen

CodesandStandards:IFGCChapter7,ASMEB31.12,CGAG5.5June 5, 2017

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▶︎ Flammablerange4-75%inair▶︎ Canriseanddisperserapidly(14x

lighterthanair)▶︎ Diffusesthroughmaterialsnot

normallyconsideredporous▶︎ Minimalignitionenergy

(0.02mJ atoptimalconcentrations)▶︎ Burnswithpaleblue,almost

invisibleflame▶︎ Canembrittlesomemetals

GaseousHydrogen

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HydrogenProperties:AComparison

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Hydrogen NaturalGas Gasoline

Color No No Yes

Toxicity None Some High

Odor Odorless Mercaptan Yes

BuoyancyRelativetoAir

14XLighter

2XLighter

3.75XHeavier

EnergybyWeight

2.8X>Gasoline

~1.2X>Gasoline 43MJ/kg

EnergybyVolume

4X<Gasoline

1.5X<Gasoline 120MJ/Gallon

Source:CaliforniaFuelCellPartnershipJune 5, 2017

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StoringHydrogen

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LH2 Storage▶︎ Gas atambientconditions▶︎ Volumetricratioliquidtogasisatrelativelylow

pressure(50psi)▶︎ Doublewalled,vacuuminsulatedtankswithburst

disks,vents,andPRDs

GH2 Storage▶︎ Atrelativelyhighpressure(upto15,000psi)▶︎ Thickwalledmetallicorreinforcedplastictanks

withPRDs(TypeIIIorTypeIV)

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Source:Toyota

VideodownloadURL:https://h2tools.org/sites/default/files/barilo/BurnDemo.mp4

DemonstrationofHydrogenFlames

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TopicsforToday’sPresentation

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• FuelCellBasicsandApplications• PropertiesofHydrogen▶︎PrimaryCodesandStandards• FundamentalSafetyConsiderations• HydrogenSafetyResources• ConcludingThoughts

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CodesandStandardsMapforFCEVs

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FuelCellVehicleSystemGTR(harmonizedwithISOandSAEJ2978)FMVSSSAEJ2615– SystemPerformanceSAEJ2572– FuelConsumptionMeasurementSAEJ2574– GeneralVehicleSafetySAEJ2617– StackPerformanceSAEJ2574– DesignforRecyclingPEMstacks

StationRefueling Guidelines

SAEJ2601

Vehicle

DispenserComponentStandardsCSAHGV4.1- DispenserCSAHGV4.2- HoseCSAHGV4.4- BreakawayCSAHGV4.5- PriorityandSequencingCSAHGV4.6- ManualValvesCSAHGV4.7- AutomatedValves

InstallationNFPA2andLocalCodesNECASME31.12CSAHGV4.9- StationsISO19880-1

Compression&StorageNFPA2andLocalCodesASMEBPVC- StorageCSAHGV4.8– Compressors

InterfaceStandardsHGV4.3– TemperatureComp.

SAEJ2719OIMLandNISTHandbook44

Source:AirLiquideJune 5, 2017

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FocusonCriticalCodes&Standards

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CriticalH2 infrastructuredocuments:▶︎ NFPA2HydrogenTechnologies

Code▶︎ InternationalFireCode(IFC)

Manyorganizationsworkingcodes,standards,andguides.Trackover300documentsat

https://h2tools.org/fuelcellstandards-view

2016

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ImportantICC2015CodeReferences

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▶︎ IFCSection2309– HydrogenMotorFuel-DispensingandGenerationFacilities

▶︎ IFCChapter50– HazardousMaterials- GeneralProvisions▶︎ IFCChapter53– CompressedGases▶︎ IFCChapter58– FlammableGasesandFlammable

CryogenicFluids▶︎ InternationalFuelGasCode(IFGC)Chapter7– Gaseous

HydrogenSystems

Note:Significantchangesinthe2015IFC“Compressedhydrogen(CH2)foruseasavehicularfuelshallalsocomplywithChapters23and58ofthiscode,theInternationalFuelGasCodeandNFPA2.”(IFC5301.1)“Hydrogenmotorfuel-dispensingstationsandrepairgaragesandtheirassociatedabove-groundhydrogenstoragesystemsshallalsobedesigned,constructedandmaintainedinaccordancewithChapter23andNFPA2.”(IFC5801.1)

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TheNeedforaNationalHydrogenCode:NFPA2

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Inthecourseofthispresentation,anycommentastothe“meaning” ofanypartofanyNFPAcodeorstandardisonlytheopinionofthepresenterandisNOTtoberelieduponaseitheraccurateorofficial.OnlytheNFPAmayissueaformalinterpretationofitscodesandstandards.

AddressesallaspectsofH2 storage,use,andhandling▶︎ Technicalcommitteeformedin2006

• 2011,2016versions– nextis2020• DrawsfromNFPA52,55and853• Newspecificapplicationrequirements

▶︎ Identifies,fillstechnicalgapsforcompletefunctionalrequirementset

▶︎ Developedforcodeusersandenforcers▶︎ Structuredsothatitworksseamlesslywith

buildingandfirecodes

2016

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NFPA2Scope

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▶︎ Appliestogaseousandliquidhydrogenstorage,transfer,production,anduse

▶︎ Stationary,portable,andvehicularinfrastructureapplications

▶︎ Fundamentalrequirementsforstorage,piping,installation,handling,andgeneration

TheCodedoesnot cover:

• Onboardvehicleormobileequipmentcomponentsorsystems• Mixturesofgaseoushydrogenandothergaseswithahydrogenconcentration

<95%byvolume

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Chapter1,AdministrationChapter2,ReferencedPublicationsChapter3,DefinitionsChapter4,GeneralFireSafetyRequirementsChapter5,Performance-BasedOptionChapter6,GeneralHydrogenRequirementsChapter7,GaseousHydrogenChapter8,LiquefiedHydrogenChapter9,ReservedChapter10,GH2Vehicle FuelingFacilitiesChapter11,LH2FuelingFacilitiesChapter12,HydrogenFuelCellPowerSystemsChapter13,HydrogenGenerationSystemsChapter14,CombustionApplicationsChapter15,SpecialAtmosphereApplicationsChapter16,LaboratoryOperationsChapter17,ParkingGaragesChapter18,RoadTunnelsChapter19,Repair GaragesAnnexesA- M

NFPA2,HydrogenTechnologiesCode,2016Ed.

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Fundamental Chapters

Use-specific Chapters

2016

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NFPA2- 2016hasprescriptiverequirementsforHydrogenEquipmentEnclosures1(HEE),including:

▶ Ventilation▶ Isolation(gasandfirebarrier)▶ Electricalrequirements▶ Bonding/grounding▶ Explosioncontrol▶ Detection

NewRequirementsforNFPA2-2016

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1 Aprefabricatedareaconfinedbyatleastthreewallsandaroof,notroutinelyoccupiedorusedinalaboratory,withatotalarealessthan450ft2 designedtoprotecthydrogen.

CodeandStandards:NFPA2-7.1.23(2016Edition)June 5, 2017

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CompartmentsoftheGreenenergy BoxTM

Hydrogen-based Energy Storage Systems

Source:EuropeanUnionHyResponseProject,May,2016June 5, 2017

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TopicsforToday’sPresentation

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• FuelCellBasicsandApplications• PropertiesofHydrogen• PrimaryCodesandStandards▶︎FundamentalSafetyConsiderations• HydrogenSafetyResources• ConcludingThoughts

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Hydrogensafety,likeallflammablegassafety,reliesonfivekeyconsiderations:

▶ Recognizehazardsandeithereliminateordefinemitigationmeasures

▶ Ensuresystemintegrity▶ Provideproperventilationto

preventaccumulation(managedischarges)

▶ Ensurethatleaksaredetectedandisolated

▶ Trainpersonnel

TheBasics…

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Fuelcellbackuppowerconnectedtoadatacenter

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AhazardanalysisisrequiredbyNFPA2forfuelingstations,butshouldbeconductedoneverysignificanthydrogenandfuelcellprojectbyaqualifiedpersonwithprovenexpertiseinhydrogenfuelingsystems,installations,andhazardanalysistechniques.

HazardAnalysisandRiskAssessmentSteps1. Definethescopeofwork2. Identifyhazards3. Evaluatetheimpactofthehazardson

a) theenvironmentandpublicb) thefacilityandinstitutionc) theequipmentandpersonnel

4. Assessthelikelihoodandseverityofeachhazard5. Resolvehazards6. Followupactivelywithperiodicreviewofwork

scopeandhazards

AnalyzingtheHazards

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Seehttps://h2tools.org/bestpractices/safety_planning/hazard_and_risk,andhttps://h2tools.org/sites/default/files/h2_snapshot_v2i2.pdf June 5, 2017

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GeneralConsiderations– OutdoorStorage

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CodeandStandards:IFC,IBC,IFGC,NFPA2,NFPA70

Storehydrogencylindersandstoragetanksoutsideatsafedistancesfrom:▶︎ structures▶︎ ventilationintakes▶︎ vehicleroutes▶︎ evenwhileinuse

Bestpracticesforcompressedhydrogencontainerssupplyingamanifold:▶︎ locateoutside▶︎ useweldedlinestoconnecttoindoor

equipment▶︎ beprovidedwithanexteriorshutoff

valveandflowrestrictororexcessflowvalve

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Safetyconsiderationsforindoorstorageoruseofbulkgaseoushydrogeninclude:▶ Buildingsshouldbeconstructedofnoncombustiblematerials.

▶ MechanicalorpassiveventilationsystemsHydrogensensorsshouldbeinstalledattheexhaustwithintheenclosure.

▶ Installautomaticshutoffthatactivatesifaleakorfireisdetectedinthefacilitythatisbeingsuppliedwithhydrogen.

▶ Avoidignitionsourcesinstorageareas.

▶ Classifiedelectricalequipmentshouldbebeincloseproximitytostoragesystems.

▶ Electricalbondingandgrounding.Gaseoushydrogensystemcomponentsshouldbeelectricallybondedandgrounded.

IndoorStorage- SafetyConsiderations

50

CodeandStandards:IFC,IBC,IFGC,NFPA2,NFPA70June 5, 2017

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▶︎ ReducelikelihoodofflammableH2-airmixincaseofreleaseorleakwithairdilution

• Ventilation(passiveoractive)shallbenotlessthan1scf/min/ft2 (0.3048Nm3/min/m2)offloorareaovertheareaofstorageoruse

• MinimumairratesdiluteapotentialH2 leakto<25%oflowerflammabilitylimit(LFL)foralloperationsandcredibleaccidentscenarios.[25%LFL=1%H2 inair]

VentilationReducesChanceofFlammableMix

51

Isthereaproblemhere?

CodeandStandards:IFC2311.7.1/5808.3.1,IFGC703.1.1,NFPA2-6.17

Exhaustairintake

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▶︎ PassiveventilationwithrooforeaveventscanpreventH2 buildupifaleakordischargeoccurs

• Evaluatepassiveventilationthoroughlytoensurethatahydrogenleakwilldissipatesafelybothnormalconditionsandemergencysituations.

• LocateInletopeningsatfloorlevelinroomexteriorwalls.• Locateoutletopeningsathighestpointinroomexteriorwallsortherooftoavoidpockets

ofH2.

▶︎ Passive/naturalventilationeasilyappliedoutdoors• Avoidpocketsunderweatherawnings.• Ensureatleast75%openonsides.

Passive Ventilation, Indoors and Outdoors

52

CodeandStandards:IFC2311.7.1/5808.3.1,IFGC703.1.1,NFPA2-6.17June 5, 2017

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▶︎ Whenpassiveventilationisinsufficient,activeventilationcanbeusedtopreventtheaccumulationofflammablemixtures.

• Usefanmotors,actuatorsforventsandvalveswithapplicableelectricalclassification,approvalforH2 use.

• EnsureactiveventilationisoperationalatalltimeswhenH2 ispresentorcouldbeaccidentallyreleased.

• AutomaticallyshutdownH2 equipmentand/orisolateH2 sourceifactiveventilationsystemfails.

• InstallH2 sensorsattheexhaustwithintheenclosure.

Active (Mechanical or Forced) Ventilation

53

Beawarethatnopracticalindoorventilationfeaturescanquicklydispersehydrogenfromamassivereleasebyapressurizedvessel,piperupture,orblowdown.

CodeandStandards:IFC2311.7.1/5808.3.1,IFGC703.1.2,NFPA2-6.17

CompressorHEEwithmechanicalventilation

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▶︎ DetectionmayberequiredbyAHJ▶︎ Detectionenhancessafetyofoperation

Provideleakdetectionby:▶︎ Hydrogen(orflammablegas)detectorsinaroomor

enclosure,or▶︎ Monitoringinternalpipingpressuresand/orflowrates

forchangesthatsuggestaleak

Othermethods:▶ H2 detectorsincloseproximitytoexteriorpiping▶ locatehydrogenpipingwithinanotherpipeandmonitor

annulusforleaks

HydrogenLeakDetection

54

CodeandStandards:IFC5003.2.2,NFPA2-7.1.22June 5, 2017

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▶︎ Provideforautomaticshut-offandisolationofhydrogensources

▶︎ Shutdownprocessequipmenttoasafemode

▶︎ Controlactiveventilation

▶︎ Activateaudibleandvisualalarms

H2 LeakDetectionGoals

55CodeandStandards:IFC5003.2.2,NFPA2-7.1.22

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H2 Leak Detection Performance

56

CodeandStandards:IFC5003.2.2,NFPA2:2016-7.1.22,7.1.23,103.1.18

▶︎ Detectionsensitivityof+/-0.25%byvolumeofH2inair

▶︎ Responsetimeof<1secondat1%H2 inair▶︎ EnsureanyleakinghydrogenwouldpassbyH2

detector.▶︎ Considerdetectorsensitivitytoothergases,vapors

• Explainsuchinterferencetopersonnel▶︎ Recommendalarmat1%H2 /air[25%LFL]▶︎ Requiremanualresettorestartautomatic

shutdownsystems▶︎ Performroutinemaintenance/recalibrationper

manufacturer’sinstruction,typicallyevery3-6months

• Recordeventsinfacilityrecords

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CheckingforH2 LeaksBestPractices

57

HydrogenandpropaneflamesindaylightPhotocourtesyofHAMMER

BurningH2 haspaleblueflame,nearlyinvisibleindaylightH2 flamesemitlowradiantheat- maynotfeelheatuntilveryclosetoflame

▶︎ Useportableflamedetector(e.g.,thermalimagingcamera)ifpossible

▶︎ Otherwise,listenforventinggas,watchforthermalwavesthatsignalheatandflame

▶︎ Useacombustibleprobe(e.g.,broom)

▶︎ Allowenoughtimetotroubleshoot/debugmonitoringsystembeforeplacingitinservice

▶︎ Wheremultiplegasesareco-located,investigateandmitigatemosthazardous

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▶︎ Powderedmetalsfacilityoperatorsheardhissingnoisenearfurnaces;determineditwasgasleakintrenchcarryingH2,nitrogen,coolingwaterpipes,andfurnaceventpipe.

▶︎ Maintenancepresumedleakwasnonflammablenitrogen;duetorecentN2 pipingleakelsewhere.

▶︎ Broughtinforkliftwithchaintoremovetrenchcoverinleakarea;eyewitnesseslaterstatedthatascoverwaswrenchedup,friction-createdsparkswerefollowedimmediatelybypowerfulexplosion.

▶︎ Severaldaysafterexplosion,ChemicalSafetyBoardinvestigatorsobservedlargehole(~3x7in)incorrodedsectionofH2 ventpipingintrench

▶︎ WhenH2/airmixinthepartiallyopentrenchexploded,resultingoverpressuredispersedquantitiesofirondustfromtheraftersandothersurfaces;somedustsubsequentlyignited.

▶︎ Eyewitnessesreportedemberswererainingdownandignitingirondustflashfiresinthearea.Visibilitywassopoorduetodustandsmokethatevenwithaflashlight,itwasimpossibletoseemorethan3or4feet.

▶︎ Threeplantemployeeseventuallydiedfromburninjuriesdespitewearingflash-fire-resistantgarments.Twootherssufferedsmoke-inhalation.DuetoextensivenatureofinjuriesandabundanceofbothH2 andcombustibledustpresentatthetime,itisdifficulttospecificallydeterminewhichfuel,ifnotboth,causedthefatalinjuriestothevictims.

58

H2 Explosion/IronDustFlashFiresinPowderedMetalsPlant

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Hydrogenflamesarealmostinvisible- thermalandopticalsensorsused▶ Tocoverlargeareaorvolume,manythermaldetectorsareneededandshouldbe

locatedatornearthesiteofapotentialfire▶ OpticalsensorsfordetectingH2 flamesoperateinthe

ultravioletorinfraredspectralregion• H2 specificTripleIRdetectorsaretheleastlikelyto

besusceptibletotofalsetrips

FlameDetection/ThermalDetectors

59

CodeandStandards:NFPA2-10.3.1./11.3.3

FlamedetectorsarerequiredinapplicationssuchasH2fuelingstationdispensers.Detectorsystemsshould:▶ Providerapidandreliableflameindication.▶ ProvideforH2 sourceautomaticshut-off/isolation▶ Shutdownthesystemtoasafemode▶ Controlactiveventilation▶ Activateaudibleandvisualalarms

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ElectricalEquipmentConsiderations

60

▶︎ VentFansshouldbenon-sparking(typical:aluminumorplastic)

▶︎ Equipment designedforuseinH2 service▶︎ H2 systemsshouldbeelectricallybonded

andgrounded▶︎ EquipmentnotconformingtoNEC(NFPA

70)requirementsshouldbelocatedoutsidetheareaclassifiedashazardous

CodeandStandards:IFC2309.2.3,NFPA2-10.3.1.16June 5, 2017

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ElectricalEquipmentRequirementsforBulkH2 Systems

61

Location Classification* DistanceAreacontaininggaseoushydrogenstorage,compressionorancillary

equipmentClass1,Division2 Upto15ft fromstorage/equipment

Areacontainingliquefiedhydrogenstorage

Class1,Division1

Class1,Division2

Within3ft frompointswhereconnectionsareregularlymadeanddisconnected

Upto25ft fromthestorageequipment,excludingthepipingsystem,downstreamofthesourcevalve

Interiorofdispensingequipment Class1,Division2Uptothesupportmechanism(anchoringthedispenser)orconnectiontothegroundlevel

Exteriorofoutdoordispensingequipment Class1,Division2 Upto5ft fromdispenser

Exteriorofindoordispensingequipment Class1,Division2 Upto15ft fromthepointoftransferfromfloortoceiling

OutdoordischargefromreliefventsClass1,Division1

Class1,Division2

Upto5ft fromthesource

5-15ft fromthesourceDischargefromreliefventswithin15

degreesofthelineofdischarge Class1,Division1 Within15ft fromsource

*AllequipmentmustberatedforGroupBapplications(NFPA70-500.6)

CodeandStandards:IFC2309.2.3,NFPA2-10.3.1.16June 5, 2017

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AddressingtheCertificationChallenge

62

BenefitsProvided▶︎ Enablescodeuserstobetterapplytherequirementswheretheuseof

listed,labeled,certified,or approved equipmentormethodsisrequired,andtoincreaseawarenessandunderstandingofwhattheequipmentisexpectedtodo

▶︎ Increasedconsistencyintheapplicationofrequirementswiththeexpectationofanexpeditedpermittingprocess

AHydrogenEquipmentCertificationGuide hasbeenreleasedtoassistcodeofficials,designers,owners,evaluators,andotherswiththeapplicationofthelistingandapprovalrequirementspertinenttothedesignand/orinstallationofhydrogenequipmentasregulatedbythemodelcodes.GapsAddressed▶︎ Intheearlymarket,theavailabilityofsystemsorequipmentthatare

listed,labeled,orcertifiedislimited.

▶︎ Whenequipmentisnotlistedoravailable,“approval”bythecodeofficialisrequiredbeforeinstallationoccurs.

CodeandStandards:IFC2309.2.2,NFPA2-7.1.3DownloadURL:https://h2tools.org/hsp/hecg

▶ Consistentapplicationofrequirementsamongproviders,regardlessofhydrogenexperience,resultsinalevelplayingfieldasthetechnologyemerges

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GeneralESSConsiderations▶︎ ESSshouldoperateon:

• Detectionalarms• Firealarms• Lossofventilation• Activationofmanualemergencyshutdown

devices(ESD)

▶︎ Whenactivated,theESSshould:• De-energizeunclassifiedelectrical• Closeallautomaticshutoffcontrolvalves

▶︎ ESDsshouldbelocated:• OnHEEs• Nearfueldispensers• HavearemoteESDlocated25to100feetfrom

theequipmentitisserving

EmergencyShutdownSystem(ESS)

63June 5, 2017

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ESSShutdownMatrix

64

▶︎ Usedtoidentifysafetycriticalequipmentandfunctions

▶︎ Enablesdesignersandreviewerstoensurethatcriticalactionsarealignedwithappropriateequipment

▶︎ Canaidinequipmentapproval

Exampleofasimpleshutdowntable

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▶︎ Hydrogencylindersandstoragetanksshouldbestoredoutsideatasafedistancefromstructures,ventilationintakes,andvehicleroutes

▶︎ Separationdistancerequirementsbasedonquantityofhydrogen

▶︎ Abulkhydrogencompressedgassystemhasacapacityofmorethan5,000scfandconsistsof:

• storagecontainers• pressureregulators• pressurereliefdevices• compressors• manifoldsandpiping

Notethatthestoragesystemterminatesatthesourcevalve

GaseousH2 OutdoorStorage

65

CodeandStandards:NFPA2-7.3.2.3

PhotocourtesyofShellHydrogen

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OutdoorSeparationDistances– NFPA2/55

66CodeandStandards:NFPA2-7.3.2.3

Currentseparationdistancegroups

June 5, 2017

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Pressure(psig) >15to≤250

>250to≤3000

>3000to≤7500

>7500to≤15000

ExposureGroup1a) Lotlinesb) Airintakes(HVAC,compressors,Other)c) OperableopeningsinbuildingsandStructuresd) Ignitionsourcessuchasopenflamesandwelding

0.231d 0.738d 1.105d 1.448d

ExposureGroup 2a) Exposedpersonsotherthanthoseservicingthesystemb) parkedcars

0.12584d−0.47126

0.43616d−0.91791

0.68311d−1.3123

0.92909d−1.6813

ExposureGroup 3a) Buildingsofnon-combustiblenon-fire-ratedconstructionb) Buildingsofcombustibleconstructionc) Flammablegasstoragesystemsaboveorbelowgroundd) Hazardousmaterialsstoragesystemsaboveorbelowgrounde) Heavytimber,coal,orotherslow-burningcombustiblesolidsf) Ordinarycombustibles,includingfast-burningsolidssuchas

ordinarylumber,excelsior,paper,orcombustiblewasteandvegetationotherthanthatfoundinmaintainedlandscapedareas

g) Unopenableopeningsinbuildingandstructuresh) Utilitiesoverheadincludingelectricpower,buildingservicesor

hazardousmaterialspipingsystems

0.096d 0.307d 0.459d 0.602d

67

Source:NFPA2

d=Diameter(mm)

CodeandStandards:NFPA2-7.3.2.3.1.1

CalculationsforOutdoorBulkH2 SeparationDistances

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▶︎ MaterialsusedinH2 piping,valves,tanksandsealsmustbecarefullyselectedtoaccountfordeteriorationwhenexposedtoH2 atmaximumoperatingconditions

▶︎ ExposureofsomemetalstoH2 canleadto:• embrittlement• crackingand/orsignificantlossintensilestrength• ductility• fracturetoughnessThesecanresultinprematurefailureinload-carryingcomponents

▶︎ Additionally,hydrogendiffusesthroughmanymaterials,particularlynonmetals,duetoitssmallmolecularsize

68

CodesandStandards:IFGC5003.2.2.1,IFGC704.1.2.3,NFPA2-10.3.1.3

Seehttp://www.h2tools.org/tech-ref/technical-reference-for-hydrogen-compatibility-of-materials

Preferred• austeniticstainlesssteels,

aluminumalloys,copper,andcopperalloys.

Avoid• Nickelandmostnickelalloys

- subjecttoseverehydrogenembrittlement

• Gray,ductile,andmalleablecastirons

SelectionofMaterials

June 5, 2017

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Apressurereliefdevice(PRD)valvefailedonahigh-pressurestoragetubeatahydrogenfuelingstation,causingthereleaseofapproximately300kilogramsofhydrogengas.Thegasignitedattheexitoftheventpipeandburnedfor2-1/2hoursuntiltechnicianswerepermittedbythelocalfiredepartmenttoenterthestationandstoptheflowofgas.

ALessonLearnedonMaterialSelection

69

▶ Therootcauseoftheincidentwasafailedpressurereliefvalve;and

▶ Anextensivemetallurgicalanalysisofthefailedvalveconcludedthatimpropermaterialselectionanddeviationsfromvalveproductionprocessesledtothevalvefailure.

Thegoodnews…Therewerenoinjuriesandverylittlepropertydamage.Thecorrugatedroofonanadjacentcanopyoverafuelingdispenserwasslightlysingedbytheescapinghydrogenflame,causinglessthan$300indamage.

Source:http://h2tools.org/lessonsJune 5, 2017

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▶︎ Designinaccordancewithapplicablecodesandstandards▶︎ Minimizeleaks- useofweldedjointswherepossible▶︎ Totheextentpossible,donotconcealH2 piping- arrangeforeasyjoint/fittings

access(tocheckforleaks)▶︎ Minimizechanceofpersonalinjury(i.e.,contactwithcoldsurfaces,headimpact,

trippinghazards,etc.)▶︎ Minimizestresses(structuralandthermal)inpipingcomponentsandconnected

equipment▶︎ Providepropersizesandsettingsofpressurereliefdevices▶︎ Includeproperlylabeledshutoffvalvesatsafelocations▶︎ Labelpipingtoindicatecontent,flowdirection,anddesignandtestpressures

Flowrestrictors,suchasorificemeters,insupplylinesareeffectivemeansoflimitingsupplyflowrateandcontrollingleakagerate.

HydrogenPipingSystemLayoutandDesign

70

CodesandStandards:IFGC704.1.2.3,ASMEB31.12,CGAG-5.5June 5, 2017

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Hydrogen Vent Lines

71

CodesandStandards:CGAG-5.5

H2 ventlines(includingpressurerelieflinesandcryogenicboil-off)shouldbeventedtosafeoutsidelocationsVentsshouldbedesignedto:▶ beunobstructedandprotectedfromthe

weather• moistureoricecanaccumulateandrestrictflow

▶ carrytheexcessflowoftheventinggasorliquid▶ beleaktightanduseweldedornon-fusiblejoints▶ avoidairintrusionorbedesignedtohandlepossibleH2 ‘pop’

deflagrationinside(~145psig/1000kPa)▶ safelyreleasetheunusedhydrogenataheightabovethe

facilityroof,overhangs,personnel,equipment,andexposures.

SeeCGAG-5.5foradditionaldesigncriteria

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GoodandBadVentStackDesigns

72

Source:CGAG-5.5

Bestconfigurations

June 5, 2017

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Aliquidhydrogenreleasewilllooksimilartothisliquidnitrogenrelease.

PhotocourtesyofS.Stookey

CodesandStandards:IFCChapter58,NFPA2Chapter8

▶︎ Coldburnsoccurfromcontactwithfrostedlines,liquidairdripfromcoldlines,orventstacks,vaporizers,andvaporleaks.

▶︎ OxygenenrichmentoccurswhenaircondensesatLH2 temperaturesandbecomesoxygen-enrichedduetothevaporizationofnitrogen.Oxygen-enrichedairincreasescombustionrateofflammable/combustiblematerials,includingclothing.

Presentsadditionalhazardsdueto-423.2°F (-252.9°C)temperatures

CryogenicLiquidH2 Storage/SupplySystems

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SafetyConsiderationsforLiquidHydrogen(LH2)

74

▶︎ Continuousevaporationgeneratesgaseoushydrogenandanincreaseinpressureinsidealiquidhydrogenstoragevesselifnotproperlyreleased.

▶︎ Ifaliquidhydrogenleakorspilloccurs,ahydrogencloudcouldflowhorizontallyforsomedistanceorevendownward,dependingontheterrainandweatherconditions.

▶︎ Icefouling- Externallyicedvents/valvescanmalfunction;airleakageintoLH2storage(e.g.inadequatepurging)introducesmoisture,willformicetopluglinesorfailinstruments.

IceandvaporonLH2 lines

CodesandStandards:IFCChapter58,NFPA2Chapter8June 5, 2017

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TopicsforToday’sPresentation

75

• FuelCellBasicsandApplications• PropertiesofHydrogen• PrimaryCodesandStandards• FundamentalSafetyConsiderations▶︎HydrogenSafetyResources• ConcludingThoughts

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ThePanelisauniqueresourceandcanbeavaluableassetforsupportingthesafecommercialrolloutoffuelcellvehicles,stationaryapplicationsandthesupportinginfrastructure.

CanProvideSupportto:▶ Otherfederalagencies▶ Stateagencies,codeofficials,and

permittingauthorities▶ Privateindustryandcommercial

installers

TypesofActivities:▶ Designanddocumentreviews▶ Participationinorreviewofriskassessments▶ Sitereviews

HydrogenSafetyPanel

76

Moreinformationisavailableathttp://www.h2tools.org/hsp

Safetyisparamount- itsthefirstquestionwegetaskedinCaliforniawhenwegointolocalcommunities.Ifanything,weneedtofigureouthowtoexpandtheSafetyPanel'sreach.ThereviewsfromthePanelhavealreadyshownbenefittothestate- itsacrucial,trusted3rdpartyresource. – 2015DOEAMRReviewerComment

PhotocourtesyoftheCaliforniaFuelCellPartnership

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A Transformative Step Towards Hydrogen Adoption

HydrogenTools

77

/

▶ IntroductiontoHydrogen• Soyouwanttoknowsomethingabout

hydrogen?▶ HydrogenProperties

• Hydrogencomparedwithotherfuels▶ SafetyPractices

• Safetyculture• Safetyplanning• Incidentprocedures• Communications

▶ DesignandOperations• Facilitydesignconsiderations• Storageandpiping• Operatingprocedures• Equipmentmaintenance• Laboratorysafety• Indoorrefuelingofforklifts

H2tools.org/bestpractices…SharingExperience,ApplyingBestPractices

Safetyeventsfrom“H2incidents.org”illustratewhatcangowrongifbestpractices

arenotfollowed.

78

URL:http://h2tools.org/bestpracticesJune 5, 2017

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Eachsafetyeventrecordcontains:▶ Description▶ Severity(Washydrogenreleased?

Wasthereignition?)▶ Setting▶ Equipment▶ Characteristics(Highpressure?Low

temperature?)▶ DamageandInjuries▶ ProbableCause(s)▶ ContributingFactors▶ LessonsLearned/Suggestionsfor

Avoidance/MitigationStepsTaken

H2tools.org/lessons…CapturingtheEvent,FocusingonLessonsLearned

79

Tubetrailerrollover

URL:http://h2tools.org/lessonsJune 5, 2017

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▶︎ OriginallydevelopedbytheHSPfortheU.S.DepartmentofEnergyin2005

▶︎ Thedocumentprovidesinformationonsafetypracticesforhydrogenandfuelcellprojects

▶︎ Theprojectsafetyplanningprocessismeanttohelpidentifyrisksandavoidpotentialhydrogenandrelatedincidents.

▶︎ Thisdocumentcanaidingeneratingagoodsafetyplanthatwillserveasaguideforthesafeconductofallworkrelatedtothedevelopmentandoperationofhydrogenandfuelcellequipment.

GuidanceforSafetyPlanningofH2 Projects

80

URL:https://h2tools.org/hsp/reviews

SafetyplanningshouldbeanintegralpartofthedesignandoperationofanH2 system.

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▶︎ Intendedusers• Thosedevelopingdesignsfor

hydrogensystems• Thoseinvolvedwiththerisk

assessmentofhydrogensystems.

▶︎ Whilefairlyinclusive,itisnotpossibletoincludeallvariablesthatneedtobeconsidered

▶︎ Ahazardanalysisprocessshouldinclude

• Personnelwhoarefamiliarwithapplicablecodesandstandards

• Teammemberswithexpertiseinthetechnicalaspectsofthespecificproject

HydrogenSafetyConsiderationsChecklist

81

URL:https://h2tools.org/sites/default/files/HydrogenSafetyChecklist.pdfJune 5, 2017

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QuantitativeRiskAssessment

82

▶︎ Developedtoolkittoenableintegratedprobabilisticanddeterministicmodeling

• RelevantH2 hazards(thermal,mechanical)• Probabilisticmodels(traditionalQRA

models)&H2-specificcomponentdata• H2 phenomena(gasrelease,heatflux,

overpressure)▶︎ VariableUsers

• Highlevel,genericinsights(e.g.,forC&Sdevelopers,regulators)

• Detailed,site-specificinsights(e.g.,forAHJs,stationdesigners)

▶︎ Currently,twointerfaces(views):• “QRAmode”and“Physicsmode”• Planned“performance-baseddesign”

modefortargetedanalyses

First-of-its-kindsoftwaretoolforintegratingH2consequencemodelsw/QRAmodels

Includesbehaviormodels&datadevelopedthroughFY12

URL:http://hyram.sandia.govJune 5, 2017

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Introduction to Hydrogen for Code Officials

Providesanoverviewofhydrogenandfuelcelltechnologies,discusseshowthesetechnologiesareusedinreal-worldapplicationsanddiscussesthecodesandstandardsrequiredforpermittingthem.

▶ Hydrogenandfuelcellbasics▶ Hydrogenandfuelcell

applications▶ Hydrogenfuelingstations▶ Fuelcellfacilities

83

DevelopedbytheNationalRenewableEnergyLaboratory

URL:http://h2tools.org/content/training-materialsJune 5, 2017

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▶︎ GivesAHJs,ProjectDevelopers,andotherinterestedpartiesaquickorientationinpermittinghydrogenfuelingstations.

▶︎ Providesbasicbackgroundinformationonhydrogentechnologiesfollowedbyadescriptionofthepermittingprocessincludinganoverviewofkeycodesandstandards.

▶︎ Containsinterviewswithcodeofficials,emergencyresponders,andtechnicalexpertsaswellasfootageofhydrogenstations.

H2 FuelingStationPermittingVideos

84

Videosavailableathttps://h2tools.org/videosJune 5, 2017

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Consistsofmaterialspecificchapters(asindividualPDFfiles)summarizingmechanical-propertydatafromjournalpublicationsandtechnicalreports

TechnicalReferenceforHydrogenCompatibilityofMaterials

▶ PlainCarbonFerriticSteels

▶ Low-AlloyFerriticSteels

▶ High-AlloyFerriticSteels

▶ AusteniticSteels

▶ AluminumAlloys

▶ CopperAlloys

▶ NickelAlloys

▶ Nonmetals

85

URL:http://h2tools.org/tech-ref/technical-reference-for-hydrogen-compatibility-of-materials June 5, 2017

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H2USAPublic-PrivatePartnershipAddressingH2 InfrastructureChallenges

86

ThemissionofH2USAistopromotethecommercialintroductionandwidespreadadoptionofFCEVsacrossAmericathroughcreationofapublic-privatecollaborationtoovercomethehurdleofestablishinghydrogeninfrastructure.

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WorkingwithFirstResponders

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Volpentest HAMMERFederalTrainingCenter

CodeandStandards:IFC5003.9.1

Preplanning▶ Facilityownersandfirstrespondersshould

worktogethertoperformpreplanningactivities.Thisshouldincludeatourofthehydrogenfacilitieswithfocusedattentiononsafetyfeaturesandemergencyshutoffs.

Training▶ Trainingofemergencyresponsepersonnel

shouldbeahighprioritytoensurethatthesepersonnelunderstandhowtoproperlyrespondtoahydrogenincident.

▶ Avarietyofresourcesareavailabletoassistwiththistraining(anddiscussedinlaterslides).

Equipment▶ Ahydrogenfireisoftendifficulttodetect

withoutathermalimagingcameraorflamedetector.Firstrespondershaveoneavailablefortheiruse.

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FirstResponderHydrogenSafetyTraining

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▶ NationalGoal• Supportthesuccessfulimplementationofhydrogenandfuelcell

technologiesbyprovidingtechnicallyaccuratehydrogensafetyandemergencyresponseinformationtofirstresponders

▶ IntegratedActivities• Online,awareness-leveltraining

(http://hydrogen.pnl.gov/FirstResponders/)• Classroomandhands-onoperations-leveltraining• Nationaltrainingresource(enablingtrainers)

(http://h2tools.org/fr/nt)

Aproperlytrainedfirstrespondercommunityiscriticaltothesuccessfulintroductionofhydrogenfuelcellapplicationsandtheirtransformationinhowweuseenergy.

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TopicsforToday’sPresentation

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• FuelCellBasicsandApplications• PropertiesofHydrogen• PrimaryCodesandStandards• FundamentalSafetyConsiderations• HydrogenSafetyResources▶︎ConcludingThoughts

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▶︎ Thefuturewilllikelyseeanincreaseintheuseofhydrogenandfuelcelltechnologies

▶︎ Safepracticesforproduction,storage,distribution,anduseofhydrogenareessentialfordeploymentofhydrogenandfuelcelltechnologies.

▶︎ Becausehydrogenasafuelisstillrelativelynew,bestmethodsofhandling,storage,transport,andusemaynotbewellunderstoodbyparticipants.

▶︎ TheIFC,IFGC,andNFPA2codesprovidefundamentalrequirementsfortheuseofhydrogenandfuelcells.

▶︎ Onlineresources(http://h2tools.org)areavailabletohelpcodeofficialsandprojectproponentsunderstandandapplysafepracticesforsuccessfuluse.

Concluding Thoughts – H2 Can Be Used Safely

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ThankYouforYourAttention!

TheauthorwishestothanktheU.S.DepartmentofEnergy’sFuelCellTechnologiesOffice(SunitaSatyapal,Director,WillJames,Safety,CodesandStandardsLeadandLauraHill),andtheCaliforniaFuelCellPartnershipfortheirsupportofthiswork.

MyContactInformation:

NickBarilo,P.E.HydrogenSafetyProgramManagerPacificNorthwestNationalLaboratoryP.O.Box999,MSINK7-76Richland,WA 99352USATel:[email protected]://h2tools.org

April 27, 2017 91June 5, 2017