How to Prepare Gases

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    How to Prepare Gases

    Chemistry Lab Instructions

    You can use common chemistry lab chemicals and equipment to prepare several gases. A conical

    flask, thistle funnel, delivery tube, pneumatic trough, and beehive are useful items to have on hand.Please make sure you are familiar with the use and functioning of the laboratory equipment you use,are aware of the characteristics of the substances (toxicity, flammability, explosivity, etc.), and takeproper safety precautions. Use a ventilation hood (fume cupboard) and keep flammable gases awayfrom heat or flame. I've tried to be as accurate as possible in my instructions, but you use them atyour own risk. For convenience, I've listed the gases in alphabetical order.

    Gas Reagents Method Collection Reaction

    Ammonia

    NH3

    Ammonium

    chloride

    Calcium

    hydroxide

    Gently heat a mixture of

    ammonium chloride andcalcium hydroxide in water.

    Upward

    displacementof air in a

    hood.

    Ca(OH)2 +

    2NH4Cl

    2NH3 + CaCl2+ 2H2O

    Carbon

    DioxideCO2

    Calcium

    carbonate(marble chips)

    5 M

    Hydrochloric

    acid

    Add 5 M hydrochloric acid to 5

    - 10 g marble chips.Upward

    displacementof air in a

    hood.

    2HCl +CaCO3 CO2

    + CaCl2 +H2O

    Chlorine

    Cl2

    Potassium

    permanganate

    Conc.Hydrochloric

    acid

    Add concentrated hydrochloric

    acid dropwise onto a small

    amount of potassiumpermanganate crystals (in

    flask).

    Upward

    displacement

    of air in ahood.

    6HCl +

    2KMnO4 +2H+ 3Cl2 +

    2MnO2 +

    4H2O + 2K+

    Hydrogen

    H2Zinc

    (granulated)5 M

    Hydrochloric

    acid

    Add 5 M hydrochloric acid to 5

    - 10 g granulated zinc pieces.Collect over

    water.

    2HCl + Zn

    H2 + ZnCl2

    Hydrogen

    ChlorideHCl

    Sodium chloride

    Conc. Sulfuricacid

    Slowly add concentrated

    sulfuric acid to solid sodiumchloride.

    Displacement

    of air in ahood.

    2NaCl +H2SO4

    Na2SO4 +2HCl

    Methane

    CH4

    Sodium acetate

    (anhydrous)Soda lime

    Mix 1 part sodium acetate with

    3 parts soda lime. Heat in adry pyrex test tube or flask.

    Collect over

    water.

    CH3COONa +

    NaOH

    CH4+ Na2CO3

    Nitrogen

    N2Ammonia

    Calciumhypochlorite

    (bleachingpowder)

    Shake 20 g calcium

    hypochlorite into 100 mLwater for several minutes,

    then filter. Add 10 mL conc.ammonia and heat mixture.

    Use extreme caution!

    Displacement

    of air.2NH3 +

    3CaOCl2 N2

    + 3H2O +

    3CaCl2

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    Chloramine and explosive

    nitrogen trichloride may beproduced.

    Nitrogen

    N2Air

    Lighted

    Phosphorus (orheated Fe or

    Cu)

    Invert a bell jar over lighted

    phosphorus. Oxygen and

    phosphorus combine to formphosphorus pentoxide, which

    is absorbed by the water over

    which the bell jar stands (maybe violent reaction), producing

    phosphoric acid and leaving

    the nitrogen behind.

    Removal of

    oxygen.

    5 O2 + 4 P

    P4O10

    NitrogenDioxide

    NO2

    Copper(turnings)

    10 M Nitric acid

    Add concentrated nitric acid to5 - 10 g copper.

    Upwarddisplacement

    of air in ahood.

    Cu + 4HNO3 2NO2 +

    Cu(NO3)2 +

    2H2O

    Nitrogen

    MonoxideNO

    Copper

    (turnings)5 M Nitric acid

    Add 5 M nitric acid to 5 - 10 g

    copper.Collect over

    water.3Cu + 8HNO

    3

    2NO +

    3Cu(NO3)2 +

    4H2O

    NitrousOxide

    N2O

    Sodium nitrateAmmonium

    sulfate

    Mix 10 g powdered sodiumnitrate and 9 g ammonium

    sulfate. Heat well.

    Displacementof air.

    NH4NO3

    N2O + 2H2O

    Oxygen

    O2

    6% Hydrogen

    peroxideManganese

    dioxide

    (catalyst)

    Add hydrogen peroxide to

    about 5 g of MnO2.

    Collect over

    water.

    2H2O2

    2H2O + O2

    Oxygen

    O2Potassium

    permanganateHeat solid KMnO4. Collect over

    water.

    2KMnO4

    K2MnO4 +MnO2 + O2

    Sulfur

    DioxideSO2

    Sodium sulfite

    (or sodiumbisulfite)

    2 MHydrochloric

    acid

    Add dilute hydrochloric acid to

    5 - 10 g sodium sulfite (orbisulfite).

    Upward

    displacementof air in a

    hood.

    Na2SO3 +2HCl SO2

    + H2O +2NaCl

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    It's easy to generatehydrogengas at home or in a lab using common household materials. Here'show to make hydrogen safely.

    Make Hydrogen Gas - Method 1

    One of the easiest ways to obtain hydrogen is to get it from water, H2O. This method employselectrolysis, which breaks water into hydrogen and oxygen gas.

    water 9-volt battery 2 paperclips

    1. Unbend the paperclips and connect one to each terminal of the battery.2. Place the other ends, not touching, into a container of water. That's it!3. You'll get bubbles off both wires. The one with more bubbles is giving off pure hydrogen. The

    other bubbles are impure oxygen. You can test which gas is hydrogen by lighting a match orlighter over the container. The hydrogen bubbles will burn; the oxygen bubbles will not burn.

    4. Collect the hydrogen gas by inverting a water-filled tube or jar over the wire producing thehydrogen gas. The reason you want water in the container is so you can collect hydrogen withoutobtaining air. Air contains 20% oxygen, which you want to keep out of the container in order tokeep it from becoming dangerously flammable. For the same reason, don't collect the gas comingoff both wires into the same container, since the mixture could burn explosively upon ignition. Ifyou wish, you can collect the oxygen in the same way as the hydrogen, but be aware this gas is

    not very pure.5. Cap or seal the container before inverting it, to avoid exposure to air. Disconnect the battery.

    Make Hydrogen Gas - Method 2

    There are two simple improvements you can make to improve the efficiency of hydrogen gasproduction. You can use graphite (carbon) in the form of pencil "lead" as electrodes and you can add a

    pinch of salt to the water to act as an electrolyte. The graphite makes good electrodes because it iselectrically neutral and won't dissolve during the electrolysis reaction. The salt is helpful because itdissociates into ions which increase the current flow.

    2 pencils salt cardboard water battery (could go as low as 1.5 V with the electrolyte) 2 paperclips or (better yet) 2 pieces of electrical wire

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  • 7/31/2019 How to Prepare Gases

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    1. Prepare the pencils by removing the erase and metal caps and sharpening both ends of thepencil.

    2. You're going to use the cardboard to support the pencils in the water. Lay the cardboard overyour container of water. Insert the pencils through the cardboard so that the lead is submerged

    in the liquid, but not touching the bottom or side of the container.3. Set the cardboard with pencils aside for a moment and add a pinch of salt to the water. You could

    use table salt, Epsom salts, etc.

    4. Replace the cardboard/pencil. Attach a wire to each pencil and connect it to the terminals of thebattery.

    5. Collect the gas as before, in a container that has been filled with water.Make Hydrogen Gas - Method 3

    You can get hydrogen gas by reacting hydrochloric acid with zinc.

    hydrochloric acid (muriatic acid) zinc granulesHydrogen gas bubbles will be released as soon as the acid and zinc are mixed. Be very careful to avoid

    contact with the acid. Also, heat will be given off by this reaction.

    You can prepare sodium silicate or water glass from gel beads (silica) and drain cleaner (sodiumhydroxide). Sodium silicate can be used to make chemical gardens, like those that result from MagicRocks (which you canmake yourself).

    Sodium Silicate Materials

    All you need to make a sodium silicate solution are water, silica, and sodium hydroxide. Silica comesin those little packets labelled 'do not eat' with electronics, shoes, etc. Sodium hydroxide is readilyavailable in its pure form or can be found as drain cleaner.

    6 g silica gel beads (crushed) 4-8 g sodium hydroxide (4 g for water glass, used in the magic rock project, or 8 g for the

    stoichiometric ratio for sodium silicate)

    10 ml waterPrepare Sodium Silicate

    1. Wear proper safety gear, which includes gloves.2. Heat 4-8 grams of sodium hydroxide in 10 ml of water.3. Once the sodium hydroxide is dissolved, slowly add the 6 grams of crushed silica gel beads. Heat

    the solution between additions. If the crushed beads won't dissolve, add a little more water to thesolution.

    http://chemistry.about.com/od/growingcrystals/a/aa060704a.htmhttp://chemistry.about.com/od/growingcrystals/a/aa060704a.htmhttp://chemistry.about.com/od/growingcrystals/a/aa060704a.htmhttp://chemistry.about.com/od/growingcrystals/a/aa060704a.htm
  • 7/31/2019 How to Prepare Gases

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    Sand that you find on a beach consists of several minerals and organic matter. If you could separateout the impurities, you would have pure sand, which is silica or silicon dioxide. Here is how to preparepure sand yourself in the lab. It is an easy project that only requires a few chemicals.

    Ingredients for Sand

    sodium silicate (make sodium silicate yourself) sodium bisulfate waterMake Pure Sand

    1. Mix together 5 ml sodium silicate solution and 5 ml water.2. In a separate container, use a glass stirrer to mix 3.5 grams sodium bisulfate into 10 mL of

    water. Keep stirring until the sodium bisulfate dissolves.3. Mix the two solutions together. The resulting gel that forms at the bottom of the liquid is

    orthosilicic acid.4. Place the orthosilicic acid into a heat-safe glass or porcelain dish and heat it over a burner flame

    for about 5 minutes. The orthosilicic acid dries to form silicon dioxide, SiO2, which is your puresand. Sand is non-toxic, but it presents an inhalation hazard since the small particles couldbecome trapped in your lungs if inhaled. Therefore, enjoy your sand, but don't play with it likeyou might with natural sand.

    These are easy instructions for making sodium carbonate, also known as washing soda or soda ash,from baking soda or sodium bicarbonate.

    Make Sodium Carbonate

    Sodium bicarbonateis CHNaO3 whilesodium carbonateis Na2CO3. Simply heat baking soda or sodium

    bicarbonate in a 200F oven for about an hour. Carbon dioxide and water will be given off. Dry sodium

    carbonate will remain.

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