History - pmi-hvl.compmi-hvl.com/files/PMI_PPP_V5.pdf · History PMI-107 has its origins 20 years...

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History PMI-107 has its origins 20 years ago in the Western Canadian Sedimentary Basin. This development was a new approach to dealing with the heavy paraffin waxes and asphaltenes present in those limestone, shale and sandstone formations. The product has now been refined and has built on those early successes with current activity in the Middle East, backed up with independent third party verification.

Transcript of History - pmi-hvl.compmi-hvl.com/files/PMI_PPP_V5.pdf · History PMI-107 has its origins 20 years...

History

PMI-107 has its origins 20 years ago in the Western

Canadian Sedimentary Basin. This development was

a new approach to dealing with the heavy paraffin

waxes and asphaltenes present in those limestone,

shale and sandstone formations. The product has

now been refined and has built on those early

successes with current activity in the Middle East,

backed up with independent third party verification.

Services with PMI-107

Equipment cleaning Crude tank cleaning

Demulsifying Pit Cleaning

Services with PMI-107

Services with PMI-107

Well stimulation Hot oil services

Chemical injection

Services with PMI-107

• Paraffin and asphaltene wax formation

• Pipeline plugging or restrictions

• Corrosion of pipeline, tanks and equipment

• Wax build up in pipeline or plant facilities

• Scaling and emulsions

• Difficulties in removing H2S

• Excessive pressure, reduced volumes

• Low productivity

• High maintenance costs

Common problems

• PMI-107 is formed by using molecular chemistry to

make a charged or an anionic blended compound.

• It has an affinity for any positively charged carbon

or stainless steel surface, where it is drawn to the

steel it forms a protective barrier film

• Typically, results can vary depending on

project but can be as short as 24 hours

What is PMI-107?

Features of PMI-107

• Single product – multi purpose anionic compound

• Corrosion control and prevention

• Paraffin/asphaltene control and prevention (incl. crystalline wax)

• Drag reducer

• Cleans pipe lines, pumps, valves and equipment

• Cleans tanks and facilities

• Chemical injection services

• Well stimulation and work over

• Emulsion control and breaking

• Reduces maintenance down time

• Single product corrosion and wax inhibitor

• Solution drops out into the water and is water soluble

• Environmentally friendly and safe to administer

• Effective for onshore/offshore operations

• Cost effective and will reduce overall costs of chemical

program

Benefits of using PMI-107

• Pipeline dimensions

• Product being transported

• Flow rates

• Gas and oil analysis

• Facility size

• Availability of injection points, pumps

• Services available: power, water, workforce camp

• Brief history of identified problems

• Specifications of equipment related to problem

Application Considerations

for PMI-107

Application benefits

of PMI-107

• No limiting or restricting flow during injection process

• PMI-107 works quickly giving improved performance of valves, instrumentation and plant efficiency

• Results often seen in just 24 hours:• sales tanks cleaned• flare tanks cleaned• process vessels and lines cleaned• clean and clear separation of water

12” in-field pipe line pig returns

Field performance of

PMI-107

after 9 months with market leader’s inhibitor 6 months later with PMI-107

16” export pipe line pig returns

after 9 months with market leader’s inhibitor 6 months later with PMI-107

Field performance of

PMI-107

Pigging with confidence! One year earlier, this pipeline was 100% plugged with wax

and suffering from corrosion. They now have a 0% BSW and visible results.

Field performance of

PMI-107

Thermal image of a 300,000 BBL tank BEFORE cleaning

Field performance of

PMI-107

Thermal image of a 300,000 BBL tank AFTER cleaning

There was zero entry into the

tank and all but the in-organics

were recovered, shipped and

sold with zero downtime, while

dropping the emulsions to zero

and shipping 30,000 recovered

barrels of oil!

We can also remove the in-

organics without man entry into

the tank.

Field performance of

PMI-107

Field performance of

PMI-107

Increased production

Pre

treatment

Post treatment

with PMI-107 BPD increase

Post-treatment

production %

Well 31 296 461 165 156%

Well 42 33 227.7 194.7 690%

Well 56 77 336.1 259.1 436%

Total 406 1025 619 252%

An increase of 619 BPD, which at $100 per barrel = more than

$22,000,000 pa increased revenue

Payback was 48 hours in this application

Laboratory tests by independent UK Lab - Wax Inhibition

Coaxial Shear Test Method

PMI-107@ 220ppm 85% Inhibition

Leading Competitor @ 500ppm 44% Inhibition

Cold Finger Test

PMI-107@ 220ppm 80% Inhibition

Performance

verification of PMI-107

Laboratory tests by independent UK Lab- Corrosion Inhibition

Target reasonable rate (ref:NORSOK M-001) <0.10 mm/yr

Leading market competitor @ 220ppm >10.00 mm/yr

PMI-107@ 220ppm 0.07 mm/yr

Lab report – “For both the welded and parent metal coupons,

general corrosion rates of approximately 0.06-0.07 mm/yr

were obtained at both concentrations of corrosion inhibitor,

indicating satisfactory corrosion inhibition and/or protective

film formation as the value is lower than 0.1 mm/yr.”

Rotary Cage Autoclave

Welded and Parent metal coupon average weight loss calculated to corrosion rate over one year

Performance

verification of PMI-107

Performance

verification of PMI-107

AIE report – “As with the tests performed at 220 ppmv, no

significant pitting was noted on the parent material of either

the welded or parent metal samples at a corrosion inhibitor

concentration of 300 ppmv. The absence of significant pitting

corrosion confirms the performance of the corrosion

inhibitor against pitting corrosion. .”

Performance

verification of PMI-107

Performance

verification of PMI-107

PMI-107

Performance

verification of PMI-107

PMI-107

Performance

verification of PMI-107

PMI-107

Figure 1 – Results of

emulsion separation

at 38 °C with no

PMI-107. Separation

time is the time after

turning off the mixing,

i.e. 5 minutes means

it has been five

minutes since mixing

was stopped.

Performance

verification of PMI-107

Figure 1 – Results of

emulsion separation

at 38 °C with 300

ppm PMI-107.

Separation time is

the time after turning

off the mixing, i.e. 5

minutes means it has

been five minutes

since mixing was

stopped.

Performance

verification of PMI-107

“The well produces very high internal corrosion rates and the pipelines suffer from high levels of wax deposition

which resulted in one of the pipelines becoming fully blocked.

PMI-107 was introduced into the field as a multipurpose product to primarily manage the internal corrosion risk and

prevent future blockages due to wax build up. Following its introduction into the field some 12 months ago, PMI-107

has marked a step change in terms of managing corrosion and wax in our pipelines.

During a stringent corrosion testing programme undertaken in the UK, the inhibitor was shown to exhibit the

corrosion rates to below industry standards and the field water sampling and coupon results have backed up its

solid performance in the field.

In addition to the wax and corrosion inhibition, we have gone from measureable amounts of water in the export

crude to virtually no water in the crude. Based on this product, we have been very impressed with the performance

of this chemical in both lab trials and field performance”

Endorsement from major middle-east oil producer

Field validation

of PMI-107