Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis
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Highly Efficient Molybdenum-based Ca talysts for Enantioselective Alkene Metathesis Nature 2008, 456, 933-937
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Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis. Nature 2008 , 456 , 933-937. Organomet. Chem. 2005 , 15 , 271–278. Organomet. Chem. 2005 , 15 , 271–278. Nature 2007 , 450, 243–251. Moreover, by monitoring the reaction progress spectroscopically - PowerPoint PPT Presentation
Transcript of Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis
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Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis
Nature 2008, 456, 933-937
![Page 2: Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis](https://reader035.fdocuments.in/reader035/viewer/2022072014/56812c81550346895d9136f3/html5/thumbnails/2.jpg)
Organomet. Chem. 2005, 15, 271–278
![Page 3: Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis](https://reader035.fdocuments.in/reader035/viewer/2022072014/56812c81550346895d9136f3/html5/thumbnails/3.jpg)
![Page 4: Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis](https://reader035.fdocuments.in/reader035/viewer/2022072014/56812c81550346895d9136f3/html5/thumbnails/4.jpg)
Organomet. Chem. 2005, 15, 271–278
![Page 5: Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis](https://reader035.fdocuments.in/reader035/viewer/2022072014/56812c81550346895d9136f3/html5/thumbnails/5.jpg)
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Nature 2007, 450, 243–251
![Page 7: Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis](https://reader035.fdocuments.in/reader035/viewer/2022072014/56812c81550346895d9136f3/html5/thumbnails/7.jpg)
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Moreover, by monitoring the reaction progress spectroscopically(400-MHz 1H NMR) in the presence of 13b, generated in situ:98% of the major isomer is consumed, the minor diastereomerremains largely intact (95%)
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