Highly Durable Anti-Reflective Anti-Soiling Coating for · PDF fileTitle: Highly Durable...

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CA-3 AZ-2 NM-1 CA-5 NM-2 CA-4 NV-1 NM-3 CA-1 CA-2 0% 5% 10% 15% 20% 25% 30% 35% % of days Anti-Soiling Gain Highly Durable Anti-Reflective Anti-Soiling Coating for PV Module Glass Reflection Before and After Abrasion Damp Heat Performance Test Abstract While the traditional film show a higher initial performance, the degradation is far worse and they failed the test criteria, with greater than 0.5% loss. The Enki CleanARC ® coating passed the specification and had higher energy gains than the traditional coating after abrasion. Brenor Brophy², Sergiu C. Pop¹, Venkata Abbaraju¹, Ralf Schulze 1 , Y. Sam Yang², Sina Maghsoodi², Peter Gonsalves² ¹Yingli Green Energy Americas, San Francisco, CA 94108, USA ²Enki Technology, San Jose, CA 95131, USA Traditional Coating Enki CleanARC ® Coating Control (uncoated) Initial coating performance is expressed as the percentage increase of transmittance (%ΔT/T) of solar weighted photons. Below are the initial optical gains of the Enki CleanARC ® coating vs. a traditional coating on different glass substrates, and the loss due to standard abrasion testing. The change of I sc and P max of the modules after the DH test was measured at UL using a flash tester . CleanARC ® coated and uncoated modules have no reduction in I sc. Power loss is highest for the traditional coatings, and lowest for the CleanARC ® coating Module with the CleanARC ® coating displayed on average a lower loss than the control glass, exhibiting the added protective capability of this film against glass degradation by severe moisture exposure. Greater than 4% of light is lost due to reflection at the interface of air and glass Soiling losses in arid regions have been reported as high at 30% per month Desert environments provide the most challenging conditions for coating durability Enki CleanARC ® coating, a new highly durable anti-reflection and anti-soiling coating was compared to traditional coatings for durability and field tested at several US locations demonstrating significant anti-soiling performance The results were used to model project level value creation, and showed up to a 3x increase in value compared to traditional coatings Testing of CleanARC ® coating’s anti-soiling performance was performed at 10 sites across the USA in collaboration with a major system operator. Data has been collected for over 1 year. E C Dirty Cleaned Coated Uncoated E HC E D E HD E C E D = Cleaning Gain E HC E C = Anti-Reflection Gain (E HD E D ) (E HC E C ) = Anti-Soiling Gain Isolating both the Anti-Reflection and Anti- Soiling components of the power required four calibrated cells from Atersa, with half of the cells periodically cleaned. 0 2 4 6 8 10 12 -1.0% -0.5% 0.0% 0.5% 1.0% 1.5% 2.0% 2.5% 3.0% 3.5% 4.0% Rain [mm] Power Gain % Site CA-1: Gains Gain from AntiSoiling Rain [mm] Cleaned Gain from Cleaning Gain from AR A B C D Hydrophobic is better Anti-Soiling Field Test For 7 of 10 sites, the Anti-Soiling gains were clearly positive with an overall average daily gain of 0.35%. Three of the sites demonstrated negative gains, indicating that for these climates and soiling types, perhaps a hydrophobic coating is not preferred. Field Performance Test Array 10kW Yingli Test Array at Sandia National Laboratories, Albuquerque, New Mexico, USA. Comparative energy generation between Enki CleanARC ® coating and a competing traditional coating. 30 day moving average shows about 0.5% positive difference between Enki CleanARC ® and the competing coating. * Project-level anti-soiling and cleaning value varies based on site specific conditions. The example assumes the solar project is located in central California with a baseline production of 1,738 MWh/MWdc; PPA rate of $70/MWh; 6% discount rate;0.5% baseline annual power degradation; 4% baseline soiling loss fraction, and one module wash per year. The CleanARC ® coating can increase a project’s energy yield and ROI through its anti-soiling properties and long-term durability. Our analysis shows it can deliver up to 3x more value than traditional coatings, resulting in over 1% additional energy production over the modules’ lifetime. Test modules after 1000 hours damp heat (DH) testing at Underwriters Laboratories (UL). The modules with the CleanARC ® coating were visibly defect free after cleaning with water, as opposed to the traditionally coated and control module Anti-Reflection power gains were typically between 2-4%. Cleaning (soiling) gains ranged between 1-2% for certain periods. Anti-Soiling could be seen between rain cleaning and rain events (e.g. A-B and C-D in graph). Conclusions and Result Laboratory Soiling Test Wet Dust Dry Wind Test SOILING TEST CYCLE -25 -20 -15 -10 -5 0 Cycle: Pre #1 #2 #3 #4 #5 - "Rain" Transmission Drop [%] 25° 40° 80° 90° 120° A selection of glass coatings with different surface energies were subjected to a series of soiling test cycles Each test cycle included wetting the surface, applying dust with blowing air, drying, removal of loose dust with blowing air, and then testing for optical transmission loss. There is a very clear correlation between soil accumulation and surface energy as measured by water contact angle. Hydrophobic coatings with low surface energy and high contact angle performed best. Enki CleanARC ® is represented by the coating with a 90° water contact angle.

Transcript of Highly Durable Anti-Reflective Anti-Soiling Coating for · PDF fileTitle: Highly Durable...

Page 1: Highly Durable Anti-Reflective Anti-Soiling Coating for · PDF fileTitle: Highly Durable Anti-Reflective Anti-Soiling Coating for PV Module Glass Author: Brenor Brophy Subject: This

CA-3

AZ-2

NM-1

CA-5

NM-2

CA-4

NV-1

NM-3

CA-1

CA-2

0%

5%

10%

15%

20%

25%

30%

35%

% o

f d

ays

Anti-Soiling Gain

Highly Durable Anti-Reflective Anti-Soiling Coating for PV Module Glass

Reflection Before and After Abrasion

Damp Heat Performance TestAbstract

While the traditional film show a higher initial performance, the degradation is far worse and

they failed the test criteria, with greater than 0.5% loss. The Enki CleanARC® coating passed

the specification and had higher energy gains than the traditional coating after abrasion.

Brenor Brophy², Sergiu C. Pop¹, Venkata Abbaraju¹, Ralf Schulze1, Y. Sam Yang², Sina Maghsoodi², Peter Gonsalves²

¹Yingli Green Energy Americas, San Francisco, CA 94108, USA

²Enki Technology, San Jose, CA 95131, USA

Traditional Coating Enki CleanARC® Coating Control (uncoated)

Initial coating performance is expressed as the percentage increase of transmittance (%ΔT/T) of

solar weighted photons. Below are the initial optical gains of the Enki CleanARC® coating vs. a

traditional coating on different glass substrates, and the loss due to standard abrasion testing.The change of Isc and Pmax of the modules after the DH

test was measured at UL using a flash tester.

• CleanARC® coated and uncoated modules have no

reduction in Isc.

• Power loss is highest for the traditional coatings,

and lowest for the CleanARC® coating

• Module with the CleanARC® coating displayed on

average a lower loss than the control glass,

exhibiting the added protective capability of this

film against glass degradation by severe moisture

exposure.

• Greater than 4% of light is lost due to reflection at the interface of air and glass

• Soiling losses in arid regions have been reported as high at 30% per month

• Desert environments provide the most challenging conditions for coating durability

• Enki CleanARC® coating, a new highly durable anti-reflection and anti-soiling coating was

compared to traditional coatings for durability and field tested at several US locations

demonstrating significant anti-soiling performance

• The results were used to model project level value creation, and showed up to a 3x increase

in value compared to traditional coatings

Testing of CleanARC® coating’s anti-soiling performance was performed at 10 sites across the

USA in collaboration with a major system operator. Data has been collected for over 1 year.

EC

Dirty Cleaned

Co

ate

dU

nc

oa

ted

EHC

ED

EHD

EC – ED = Cleaning Gain

EHC – EC = Anti-Reflection Gain

(EHD – ED ) – (EHC – EC) = Anti-Soiling Gain

Isolating both the Anti-Reflection and Anti-

Soiling components of the power required four

calibrated cells from Atersa, with half of the

cells periodically cleaned.

0

2

4

6

8

10

12

-1.0%

-0.5%

0.0%

0.5%

1.0%

1.5%

2.0%

2.5%

3.0%

3.5%

4.0%

Rain

[m

m]

Po

we

r G

ain

%

Site CA-1: Gains

Gain from AntiSoiling Rain [mm] Cleaned Gain from Cleaning Gain from AR

A B C D

Hydrophobic is better

Anti-Soiling Field Test

For 7 of 10 sites, the Anti-Soiling gains were

clearly positive with an overall average daily gain

of 0.35%.

Three of the sites demonstrated negative gains,

indicating that for these climates and soiling types,

perhaps a hydrophobic coating is not preferred.

Field Performance Test Array

10kW Yingli Test Array at Sandia National Laboratories,

Albuquerque, New Mexico, USA.

Comparative energy generation between Enki CleanARC®

coating and a competing traditional coating.

30 day moving average shows about 0.5% positive difference

between Enki CleanARC® and the competing coating.* Project-level anti-soiling and cleaning value varies based on site specific conditions. The example assumes the solar

project is located in central California with a baseline production of 1,738 MWh/MWdc; PPA rate of $70/MWh; 6% discount

rate;0.5% baseline annual power degradation; 4% baseline soiling loss fraction, and one module wash per year.

The CleanARC® coating can increase a

project’s energy yield and ROI through its

anti-soiling properties and long-term

durability. Our analysis shows it can deliver up

to 3x more value than traditional coatings,

resulting in over 1% additional energy

production over the modules’ lifetime.

Test modules after 1000 hours damp heat (DH) testing at Underwriters Laboratories (UL). The

modules with the CleanARC® coating were visibly defect free after cleaning with water, as

opposed to the traditionally coated and control module

Anti-Reflection power gains were typically between 2-4%. Cleaning (soiling) gains ranged

between 1-2% for certain periods. Anti-Soiling could be seen between rain cleaning and rain

events (e.g. A-B and C-D in graph).

Conclusions and Result

Laboratory Soiling Test

Wet

Dust

DryWind

TestSOILING

TEST

CYCLE

-25

-20

-15

-10

-5

0

Cycle: Pre #1 #2 #3 #4 #5 - "Rain"

Tra

ns

mis

sio

n D

rop

[%

]

25° 40° 80° 90° 120°

• A selection of glass coatings with different surface energies were subjected to a series of

soiling test cycles

• Each test cycle included wetting the surface, applying dust with blowing air, drying, removal

of loose dust with blowing air, and then testing for optical transmission loss.

• There is a very clear correlation between soil accumulation and surface energy as measured

by water contact angle. Hydrophobic coatings with low surface energy and high contact angle

performed best.

• Enki CleanARC® is represented by the coating with a 90° water contact angle.